CN1775027A - Disinsection soluble granules containing methylamino avermection benzoate - Google Patents
Disinsection soluble granules containing methylamino avermection benzoate Download PDFInfo
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- CN1775027A CN1775027A CN 200510012997 CN200510012997A CN1775027A CN 1775027 A CN1775027 A CN 1775027A CN 200510012997 CN200510012997 CN 200510012997 CN 200510012997 A CN200510012997 A CN 200510012997A CN 1775027 A CN1775027 A CN 1775027A
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- Prior art keywords
- benzoate
- emamectin
- agent
- disinsection
- product
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000008187 granular material Substances 0.000 title claims abstract description 22
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 title 1
- 125000000250 methylamino group Chemical group [H]N(*)C([H])([H])[H] 0.000 title 1
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims abstract description 28
- 239000002270 dispersing agent Substances 0.000 claims abstract description 16
- 239000000080 wetting agent Substances 0.000 claims abstract description 16
- 239000011230 binding agent Substances 0.000 claims abstract description 12
- 239000003381 stabilizer Substances 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims description 11
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical group [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 7
- 229920001353 Dextrin Polymers 0.000 claims description 5
- 239000004375 Dextrin Substances 0.000 claims description 5
- 235000019425 dextrin Nutrition 0.000 claims description 5
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 3
- 108010010803 Gelatin Proteins 0.000 claims description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 claims description 3
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims description 3
- 229910000397 disodium phosphate Inorganic materials 0.000 claims description 3
- 235000019800 disodium phosphate Nutrition 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 239000008103 glucose Substances 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 2
- 125000003071 maltose group Chemical group 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 2
- 241000238631 Hexapoda Species 0.000 abstract 1
- 230000000266 injurious effect Effects 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 238000012856 packing Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 238000001291 vacuum drying Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 238000005338 heat storage Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000009736 wetting Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 230000001404 mediated effect Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 2
- 239000003708 ampul Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000238876 Acari Species 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 241001325860 Lacanobia oleracea Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241001454293 Tetranychus urticae Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 230000003915 cell function Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 229940095686 granule product Drugs 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 230000007830 nerve conduction Effects 0.000 description 1
- 210000002569 neuron Anatomy 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention discloses an insecticidal soluble granule preparation containing emamectin benzoate. Its composition includes (by wt%) emamectin benzoate 0.5-40%, dispersing agent 1-10%, wetting agent 1-5%, binder 2-4%, stabilizing agent 1-3% and the rest is filling material. It can be extensively used for controlling injurious insects of crops.
Description
Technical field
The present invention relates to a kind of disinsection soluble granules that contains emamectin-benzoate, particularly a kind of pesticide for protecting plant that contains the disinsection soluble granules of emamectin-benzoate.
Background technology
The insecticide that protective plant is used generally adopts cream preparation and wetting powder.Missible oil contain be easy in a large number volatilization catch fire, to human body and the virulent organic solvent of plant, transportation is also inconvenient; Wetting powder has a large amount of dust in producing, using, contaminated environment influences operating personnel's health.
Summary of the invention
The present invention overcomes shortcoming of the prior art, provides a kind of have safety, environmental protection, the disinsection soluble granules that contains emamectin-benzoate that result of use is good.
In order to solve the problem of above-mentioned technology, the present invention is achieved by the following technical solutions: the disinsection soluble granules that contains emamectin-benzoate, form soluble granule by emamectin-benzoate, dispersant, wetting agent, binding agent, stabilizing agent, filler, it forms content (is 100% in soluble granule weight): emamectin-benzoate 0.5-40%, dispersant 2～10%, wetting agent 1～5%, binding agent 2～4%, stabilizing agent 1～3%, all the other are fillers.
The present invention also can be achieved through the following technical solutions: the disinsection soluble granules that contains emamectin-benzoate, wherein dispersant is selected from sodium lignin sulfonate, wherein wetting agent is selected from OP-10, OP-21, lauryl sodium sulfate, GFC, wherein binding agent is selected from dextrin, polyethylene glycol, gelatin, wherein stabilizing agent is selected from BHT, tributyl phosphate, sodium hydrogen phosphate, and wherein filler is selected from maltose, glucose, solvable starch, Lactis Anhydrous, anhydrous sodium sulfate.
Compared with prior art, the invention has the beneficial effects as follows: have safety, environmental protection, result of use is good.
Embodiment
Below in conjunction with embodiment the present invention is described in further detail:
Embodiment 1: the emamectin-benzoate with 1%, 3% sodium lignin sulfonate dispersant, 2% OP-10 wetting agent, 1% BHT stabilizing agent and 91% maltose filler mixes and through comminution by gas stream, adding 2% dextrin binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; The product of not crossing sieve is mediated and extruder grain again through pulverizing, and vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Embodiment 2: the emamectin-benzoate with 2%, 5% sodium lignin sulfonate dispersant, 2% OP-21 wetting agent, 1% tributyl phosphate stabilizing agent and 88% glucose filler mixes and through comminution by gas stream, adding 2% dextrin binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; The product of not crossing sieve is mediated and extruder grain again through comminution by gas stream, and vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Embodiment 3: the emamectin-benzoate with 5%, 7% sodium lignin sulfonate dispersant, 3% lauryl sodium sulfate wetting agent, 1% tributyl phosphate stabilizing agent and 82% solvable starch filler mixes and through comminution by gas stream, adding 2% polyethylene glycol binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; The product of not crossing sieve is mediated and extruder grain again through comminution by gas stream, and vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Embodiment 4: the emamectin-benzoate with 10%, 8% sodium lignin sulfonate dispersant, 2% JFC wetting agent, 1% sodium hydrogen phosphate stabilizing agent and 77% Lactis Anhydrous filler mixes and through comminution by gas stream, adding 2% gelatin binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; Do not cross the product of sieve and mediate and extruder grain through comminution by gas stream, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Embodiment 5: the emamectin-benzoate with 30%, 10% sodium lignin sulfonate dispersant, 2% OP-21 wetting agent, 1% BHT stabilizing agent and 55% anhydrous sodium sulfate filler mixes and through comminution by gas stream, adding 2% dextrin binding agent then mediates and extruder grain, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves is the back packing after testing; Do not cross the product of sieve and mediate and extruder grain through comminution by gas stream, vacuum drying was sieved after 1 hour under 70 ℃ of temperature, and the product that sieves back packing is after testing made product of the present invention.
Emamectin-benzoate is a kind of semisynthetic antibiotics insecticides agricultural chemicals, be that a class has the bioactive insecticide of super-high-efficient, its mechanism of action is that the effect of neurotic glutamate of enhancing and γ-An Jidingsuan is that a large amount of chlorions enter nerve cell, make the cell function forfeiture, upset nerve conduction.Have stomach toxicity and action of contace poison, permeability is strong.This product can be widely used in the control of the various pests on the crops such as vegetables, fruit tree, cotton.Normally used formulation is 1% emamectin-benzoate missible oil, for reducing processing, the quantity of storing, transporting, reduce the preparation consumption, be user-friendly to, we have carried out a large amount of careful research work to the emamectin-benzoate soluble granule, develop the emamectin-benzoate soluble granule.
Emamectin-benzoate soluble granule performance indications are as follows:
| Project | Performance indications |
| Outward appearance | Yellowish or yellow loose granular particle does not have visible exogenous impurity |
| Content | ≥0.5-40％ |
| Dispersed | Adopt the graduated cylinder bulk method to carry out favorable dispersibility |
| Wetability | Adopt the measuring graduates test method(s), wetting time was less than 1 minute |
| Dissolubility | Undertaken by HG/T2467.15-2003, residue behind the 5min≤ |
| 0.5%, residue behind the 18h≤2.0% | |
| Moisture | Adopt azeotropic method or karl Fischer method, moisture is less than 3.0% |
| PH value | Undertaken by GB/T1601, measure PH5.5～7.5 |
| Lasting foaming characteristic | Carry out foam volume≤60ml behind the 1min by HG/T2467.5-2003 |
Product stability research: the emamectin-benzoate soluble granule sample that will sieve is sealed in respectively in 12 50ml ampoule bottles, about 20 gram samples in every ampoule bottle, be placed in (54 ± 2) ℃ insulating box and carry out check and analysis after two weeks of storage, calculate heat storage resolution ratio, the heat storage stability experimental result is as follows:
| Numbering | 20040801 | 20040803 | 20040805 | 20040809 | 20040901 |
| Resolution ratio, % | 2.88 | 2.97 | 3.47 | 2.43 | 2.50 |
By last table result as seen, emamectin-benzoate soluble granule heat storage stability is better, and heat storage resolution ratio is less than 5%.
Dispersant, wetting agent are to the influence of properties of product: dispersant is meant the solid chemicals particle is dispersed in the aqueous solution, makes solia particle long period in liquid phase keep a homodisperse class material.Wetting agent is after making product particle fully wetting, to play the effect of fine dissolving.Dispersant and wetting agent are most important auxiliary elements in the soluble granule, by dispersant above-mentioned, wetting agent kind are screened, composite, obtain emamectin-benzoate soluble granule product.
Soluble granule is a kind of pesticides new formulation, with the advantage of solid pharmaceutical preparation and liquid preparation, is the more comprehensive product of combination property in the current pesticidal preparations.The emamectin-benzoate soluble granule at present common crop pests as diamond-back moth, beet armyworm, tomato moth, cabbage caterpillar, two spotted spider mite, mites etc. have the incomparable result of use of general chemical pesticide, and succeeding in developing of its green novel form will further strengthen its safety to environment, people and animals, crop.No matter be various auxiliary agents sources in the prescription, or production equipment all is based on domesticly, product cost is lower, therefore, and for the suitability for industrialized production of this formulation and apply and lay a good foundation.
Claims (2)
1, a kind of disinsection soluble granules that contains emamectin-benzoate, it is characterized in that forming soluble granule by emamectin-benzoate, dispersant, wetting agent, binding agent, stabilizing agent, filler, it forms content (is 100% in soluble granule weight): emamectin-benzoate 0.5-40%, dispersant 2～10%, wetting agent 1～5%, binding agent 2～4%, stabilizing agent 1～3%, all the other are fillers.
2, the disinsection soluble granules that contains emamectin-benzoate as claimed in claim 1, it is characterized in that described dispersant is selected from sodium lignin sulfonate, described wetting agent is selected from OP-10, OP-21, lauryl sodium sulfate, JFC, described binding agent is selected from dextrin, polyethylene glycol, gelatin, described stabilizing agent is selected from BHT, tbp, sodium hydrogen phosphate, and described filler is selected from maltose, glucose, solvable starch, Lactis Anhydrous, anhydrous sodium sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510012997 CN1775027A (en) | 2005-11-21 | 2005-11-21 | Disinsection soluble granules containing methylamino avermection benzoate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510012997 CN1775027A (en) | 2005-11-21 | 2005-11-21 | Disinsection soluble granules containing methylamino avermection benzoate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1775027A true CN1775027A (en) | 2006-05-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510012997 Pending CN1775027A (en) | 2005-11-21 | 2005-11-21 | Disinsection soluble granules containing methylamino avermection benzoate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1775027A (en) |
Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100394852C (en) * | 2006-09-21 | 2008-06-18 | 栾贵书 | Methylamino avermectin benzoate soluble granule and preparation method thereof |
| WO2009086739A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of chlorfenapyr and its preparation |
| WO2009086741A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of spinosad and its preparation |
| WO2009086740A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of indoxacarb and its preparation |
| WO2009089687A1 (en) * | 2008-01-15 | 2009-07-23 | Guishu Luan | Water soluble granule of kresoxim-methyl and its preparation |
| WO2009089688A1 (en) * | 2008-01-15 | 2009-07-23 | Guishu Luan | Water soluble granule of fipronil and its preparation |
| CN101731207B (en) * | 2009-12-30 | 2013-04-03 | 北京富力特农业科技有限责任公司 | Emulsifiable grains of emamectin benzoate and preparation method thereof |
| CN103238617A (en) * | 2012-07-04 | 2013-08-14 | 河北威远生物化工股份有限公司 | Clothianidin synergia solubility granula and preparation method thereof |
| CN103858936A (en) * | 2014-02-14 | 2014-06-18 | 暨南大学 | Multifunctional environment-friendly emamectin benzoate aqueous solution and preparation method thereof |
| CN104304271A (en) * | 2011-12-09 | 2015-01-28 | 沈阳科创化学品有限公司 | Binary pesticide composition and application |
| CN104621170A (en) * | 2015-02-03 | 2015-05-20 | 河北威远生化农药有限公司 | Acetamiprid and emamectin benzoate mixed soluble granular insecticide and preparation method thereof |
| CN106259325A (en) * | 2016-08-17 | 2017-01-04 | 河北威远生化农药有限公司 | A kind of glufosinate-ammonium synergia solubility granula and preparation method thereof |
| CN106857653A (en) * | 2017-02-15 | 2017-06-20 | 华北制药集团爱诺有限公司 | Soluble granule and its application process for preventing and treating root disease |
| CN107494557A (en) * | 2017-08-02 | 2017-12-22 | 江苏仁信化工有限公司 | A kind of emamectin-benzoate granule and its production method |
| CN109042641A (en) * | 2018-09-14 | 2018-12-21 | 河北威远生物化工有限公司 | A kind of emamectin benzoate B2a/B2b benzoate granule and preparation method thereof |
| CN110519986A (en) * | 2016-09-16 | 2019-11-29 | 阿伦·沙旺特 | Stable formulation of water sensitive actives |
| CN112106769A (en) * | 2020-09-11 | 2020-12-22 | 惠州市银农科技股份有限公司 | Emamectin benzoate dry suspending agent and preparation method thereof |
| CN112970767A (en) * | 2019-12-13 | 2021-06-18 | 佳木斯兴宇生物技术开发有限公司 | Emamectin benzoate and ningnanmycin soluble granules and preparation method thereof |
-
2005
- 2005-11-21 CN CN 200510012997 patent/CN1775027A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100394852C (en) * | 2006-09-21 | 2008-06-18 | 栾贵书 | Methylamino avermectin benzoate soluble granule and preparation method thereof |
| WO2009086739A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of chlorfenapyr and its preparation |
| WO2009086741A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of spinosad and its preparation |
| WO2009086740A1 (en) * | 2008-01-09 | 2009-07-16 | Guishu Luan | Water soluble granule of indoxacarb and its preparation |
| WO2009089687A1 (en) * | 2008-01-15 | 2009-07-23 | Guishu Luan | Water soluble granule of kresoxim-methyl and its preparation |
| WO2009089688A1 (en) * | 2008-01-15 | 2009-07-23 | Guishu Luan | Water soluble granule of fipronil and its preparation |
| CN101657093A (en) * | 2008-01-15 | 2010-02-24 | 栾贵书 | Bactericidal soluble granule containing kresoxim-methyl and preparation method thereof |
| CN101657093B (en) * | 2008-01-15 | 2012-11-21 | 佳木斯兴宇生物技术开发有限公司 | Water soluble granule of kresoxim-methyl and preparation thereof |
| CN101731207B (en) * | 2009-12-30 | 2013-04-03 | 北京富力特农业科技有限责任公司 | Emulsifiable grains of emamectin benzoate and preparation method thereof |
| CN104304271A (en) * | 2011-12-09 | 2015-01-28 | 沈阳科创化学品有限公司 | Binary pesticide composition and application |
| CN104304271B (en) * | 2011-12-09 | 2016-08-17 | 沈阳科创化学品有限公司 | A kind of binary pesticide composition and purposes |
| CN103238617B (en) * | 2012-07-04 | 2015-01-28 | 河北威远生化农药有限公司 | Clothianidin synergia solubility granula and preparation method thereof |
| CN103238617A (en) * | 2012-07-04 | 2013-08-14 | 河北威远生物化工股份有限公司 | Clothianidin synergia solubility granula and preparation method thereof |
| CN103858936A (en) * | 2014-02-14 | 2014-06-18 | 暨南大学 | Multifunctional environment-friendly emamectin benzoate aqueous solution and preparation method thereof |
| CN103858936B (en) * | 2014-02-14 | 2016-06-29 | 暨南大学 | A kind of Multifunctional environment friendly emamectin-benzoate water preparation and preparation method thereof |
| CN104621170A (en) * | 2015-02-03 | 2015-05-20 | 河北威远生化农药有限公司 | Acetamiprid and emamectin benzoate mixed soluble granular insecticide and preparation method thereof |
| CN106259325A (en) * | 2016-08-17 | 2017-01-04 | 河北威远生化农药有限公司 | A kind of glufosinate-ammonium synergia solubility granula and preparation method thereof |
| CN106259325B (en) * | 2016-08-17 | 2019-11-22 | 河北威远生物化工有限公司 | A kind of glufosinate-ammonium synergia solubility granula and preparation method thereof |
| CN110519986A (en) * | 2016-09-16 | 2019-11-29 | 阿伦·沙旺特 | Stable formulation of water sensitive actives |
| CN106857653A (en) * | 2017-02-15 | 2017-06-20 | 华北制药集团爱诺有限公司 | Soluble granule and its application process for preventing and treating root disease |
| CN107494557A (en) * | 2017-08-02 | 2017-12-22 | 江苏仁信化工有限公司 | A kind of emamectin-benzoate granule and its production method |
| CN109042641A (en) * | 2018-09-14 | 2018-12-21 | 河北威远生物化工有限公司 | A kind of emamectin benzoate B2a/B2b benzoate granule and preparation method thereof |
| CN112970767A (en) * | 2019-12-13 | 2021-06-18 | 佳木斯兴宇生物技术开发有限公司 | Emamectin benzoate and ningnanmycin soluble granules and preparation method thereof |
| CN112106769A (en) * | 2020-09-11 | 2020-12-22 | 惠州市银农科技股份有限公司 | Emamectin benzoate dry suspending agent and preparation method thereof |
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