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CN1770041B - Cleaning device, process cartridge, and image forming device - Google Patents

Cleaning device, process cartridge, and image forming device Download PDF

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Publication number
CN1770041B
CN1770041B CN 200510119274 CN200510119274A CN1770041B CN 1770041 B CN1770041 B CN 1770041B CN 200510119274 CN200510119274 CN 200510119274 CN 200510119274 A CN200510119274 A CN 200510119274A CN 1770041 B CN1770041 B CN 1770041B
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cleaning
cleaned
image carrier
cleaning device
cleaning blade
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CN1770041A (en
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渡边一彦
赤藤昌彦
成瀬修
矢野英俊
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Ricoh Co Ltd
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Ricoh Co Ltd
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Abstract

In the cleaning device, the process cartridge, and the image forming apparatus, a cleaning structure with low linear pressure and high surface pressure is obtained by specifying the material and shape of the cleaning blade and the supporting structure. A tip edge line portion of an elastic cleaning blade 38 supported by a supporting member 37, which is a so-called sheet holder, is pressed against a roller-shaped and belt-shaped image carrier 10 to remove toner remaining on the image carrier after image transfer. In the cleaning device (16), the angle (theta) of the cleaning blade forming the front end edge line part (36) is formed into an obtuse angle, and is greater than or equal to 2.0g/mm2The front end edge line part is pressed on the image carrier by the surface pressure. The surface pressure is a value obtained by dividing the total load applied to the cleaning blade by the contact area of the cleaning blade with the member to be cleaned.

Description

清洁装置、处理盒以及图像形成装置Cleaning device, process cartridge, and image forming device

技术领域 technical field

本发明涉及转印机、打印机、传真机或这些的复合机等的图像形成装置。其中,特别是涉及在载像体上形成调色剂图像并将该调色剂图像直接或间接转印,在纸张、OHP胶片等记录介质上记录图像的电子写真式的图像形成装置。并且涉及在这样的图像形成装置中去除残留在图像复制后还残留在载像体上的调色剂的清洁装置。以及,涉及至少一体地具备清洁装置和载像体,且它们相对于图像形成装置主体一并自如地装拆的处理盒。The present invention relates to an image forming apparatus such as a transfer machine, a printer, a facsimile machine, or a composite machine of these. Among them, in particular, it relates to an electrophotographic image forming apparatus that forms a toner image on an image carrier, transfers the toner image directly or indirectly, and records the image on a recording medium such as paper or OHP film. It also relates to a cleaning device for removing toner remaining on an image carrier after image reproduction in such an image forming apparatus. And it is related with the process cartridge which at least integrally includes a cleaning device and an image carrier, and these are attached to and detachable from the main body of an image forming apparatus together.

背景技术 Background technique

以往,在电子写真式的图像形成装置中,与辊状和带状的载像体的旋转一同地由带电装置使其周面一样地带电,然后由曝光装置进行写入,在载像体上形成静电潜像,然后通过显影装置附着调色剂而将该静电潜像可视像化而在载像体上形成调色剂图像。并且,使用转印装置在记录介质上转印该调色剂图像之后,由定影装置将转印图像定影,在记录介质上记录图像。调色剂图像转印后的载像体周面由清洁装置清洗,在向载像体再次形成图像中使用。Conventionally, in an image forming apparatus of an electrophotographic type, the peripheral surface of a roll-shaped and belt-shaped image carrier is uniformly charged by a charging device together with the rotation of the image carrier, and then written by an exposure device. An electrostatic latent image is formed, and the latent electrostatic image is visualized by attaching toner by a developing device to form a toner image on an image carrier. Then, after the toner image is transferred on the recording medium by the transfer device, the transferred image is fixed by the fixing device, and the image is recorded on the recording medium. The peripheral surface of the image carrier after the transfer of the toner image is cleaned by a cleaning device and used for forming an image on the image carrier again.

在清洁装置中,由于一般能够使结构简单,清洁性能也优良,故作为清洁部件使用由聚氨酯橡胶等弹性材料构成的清洁刮板,其基端由支承部件支承,将前端棱角线部按压在载像体的周面上,通过将残留在载像体上的调色剂堵住而剥落并除去,进行清洁。In cleaning devices, since the structure is generally simple and the cleaning performance is excellent, a cleaning blade made of an elastic material such as polyurethane rubber is used as a cleaning member. The peripheral surface of the image body is cleaned by clogging, peeling off and removing the toner remaining on the image body.

另一方面,在这种电子写真式图像形成装置中,近年来强烈要求图像品质的提高,响应该要求而促进调色剂的小粒径化及球形化,将使用了聚合法的球形调色剂作为主流而使用。On the other hand, in such electrophotographic image forming apparatuses, there has been a strong demand for improvement in image quality in recent years, and in response to this demand, the reduction in particle size and spherical shape of the toner has been promoted, and spherical toner using the polymerization method has been promoted. Agents are used as the mainstream.

但是,调色剂小粒径化及球形化使采用清洁刮板的转印残留调色剂的彻底去除成为困难,而出现清洁不良。这是因为在清洁刮板对载像体的按压位置上,调色剂产生转矩,压起清洁刮板而使调色剂容易潜入清洁刮板与载像体之间。However, the reduction in particle size and spheroidization of the toner makes it difficult to completely remove the transfer residual toner using a cleaning blade, resulting in poor cleaning. This is because the toner generates torque at the position where the cleaning blade presses the image carrier, and the cleaning blade is pushed up so that the toner easily sneaks into the gap between the cleaning blade and the image carrier.

因此,在使用进行了小粒径化及球形化的调色剂的情况下,必须增强清洁刮板对载像体的按压力,阻止调色剂的潜入。现有作为表示阻止调色剂潜入清洁刮板的力的特性值,一般使用有“线压”。所谓“线压”是指赋予清洁刮板的总荷重除以清洁刮板按压在载像体上的前端棱角线部的长度的值“gf/cm”。Therefore, in the case of using a toner whose particle size has been reduced and spheroidized, it is necessary to increase the pressing force of the cleaning blade against the image carrier to prevent infiltration of the toner. Conventionally, "line pressure" is generally used as a characteristic value indicating the force that prevents toner from sneaking into the cleaning blade. The "linear pressure" refers to the value "gf/cm" obtained by dividing the total load applied to the cleaning blade by the length of the front end corner line portion of the cleaning blade pressed against the image carrier.

具体的是指,刮板前端部形成杆状态而将清洁刮板的前端按压在载像体上,在该按压位置上夹入厚度0.1(mm)的片状传感器,该传感器的输出值(作用在该按压位置上的荷重“g”)除以该按压位置的载像体轴向长度“cm”的值。Specifically, the front end of the scraper is formed into a rod state to press the front end of the cleaning scraper against the image carrier, and a sheet sensor with a thickness of 0.1 (mm) is sandwiched at the pressed position, and the output value (function) of the sensor is The value of dividing the load "g" at the pressing position by the axial length "cm" of the image bearing body at the pressing position.

另外,片状传感器具有向在内部分别相互正交的两个方向(行方向、列方向)排列的多个电极,其表面覆盖膜树脂。这些电极中压敏电阻性物质和电荷发生物质以格子状设置,在该格子状的交点上施加外压,则根据其荷重而电阻值变化。该电阻值的变化表现为向行方向及列方向流动的电流值的变化,故可根据其电流值求出总荷重。In addition, the sheet sensor has a plurality of electrodes arranged in two directions (row direction, column direction) which are respectively perpendicular to each other inside, and its surface is covered with film resin. In these electrodes, the piezoresistive material and the charge generating material are arranged in a grid pattern, and when an external pressure is applied to the intersection points of the grid shape, the resistance value changes according to the load. Changes in this resistance value appear as changes in the current value flowing in the row and column directions, so the total load can be obtained from the current value.

但是,若该“线压”增大,则能够改善对清洁困难的小粒且球形的调色剂的清洁性能,但是却产生促进载像体磨损、载像体的驱动转矩增加、及清洁刮板磨损增大等的危害。However, if the "linear pressure" is increased, the cleaning performance of the small and spherical toner that is difficult to clean can be improved, but it causes the wear of the image carrier to be promoted, the driving torque of the image carrier to increase, and the cleaning blade to be damaged. Hazards such as increased plate wear.

另外,该特性值“线压”不能充分评价阻止调色剂潜入的能力。其理由是,实际中在清洁刮板的按压位置上,与载像体之间形成夹持部,不是以线而是以面与载像体接触,但如上所述,“线压”是赋予清洁刮板的总荷重除以清洁刮板的按压位置的载像体轴向长度的值,可以完全不考虑清洁刮板对载像体的接触面积。In addition, this characteristic value "linear pressure" cannot sufficiently evaluate the ability to prevent toner from sneaking in. The reason is that in reality, at the pressing position of the cleaning blade, a clamping portion is formed between the image carrier, and the image carrier is not contacted with a line but with a surface, but as mentioned above, "line pressure" is given The value obtained by dividing the total load of the cleaning blade by the axial length of the image bearing body at the pressing position of the cleaning blade does not consider the contact area of the cleaning blade with the image bearing body at all.

即,仅通过将以往使用的特性值“线压”增大,则不一定能够清洁小粒且球形的调色剂,相反而产生促进载像体磨损、载像体驱动转矩增加等危害。That is, simply increasing the conventionally used characteristic value "linear pressure" does not necessarily clean the small and spherical toner, but instead causes damage such as accelerated image carrier wear and increased image carrier drive torque.

在此,作为表示阻止调色剂潜入的力的新的特性值,考虑使用赋予清洁刮板的总荷重除以清洁刮板对载像体的接触面积的“面压”。该“面压”在向清洁刮板赋予同一荷重的情况下也根据橡胶刮板的硬度及厚度、自由长度、形状等变化清洁刮板接触载像体的接触面积,根据清洁刮板的材质、形状、支承方法等来变动。Here, as a new characteristic value representing the force of preventing toner from infiltrating, it is considered to use "face pressure" which is divided by the total load applied to the cleaning blade by the contact area of the cleaning blade with the image carrier. This "surface pressure" also changes according to the hardness, thickness, free length, shape, etc. of the rubber blade even when the same load is applied to the cleaning blade. Changes in shape, support method, etc.

例如图19(A)及(B)所示,使用具有形状不同的清洁刮板1a、1B的清洁装置。并且,如图19(A)所示,一个清洁刮板1a为平刮板状,将其基端粘附在单面上而由支承部件2支承,将前端棱角线部3a按压在载像体4上。另外,如(B)所示,另一个的清洁刮板1B具有突部5,将其基端粘附在单面上而由支承部件2支承,将前端棱角线部3B按压在载像体4上。此时,将突部5抵接在支承部件2上,避免清洁刮板1B折曲而刮板前端脱离。For example, as shown in FIGS. 19(A) and (B), a cleaning device having cleaning blades 1a and 1B having different shapes is used. And, as shown in Figure 19 (A), a cleaning blade 1a is a flat blade shape, and its base end is adhered on one side and supported by the support member 2, and the front end corner portion 3a is pressed against the image carrier. 4 on. In addition, as shown in (B), the other cleaning blade 1B has a protrusion 5, and its base end is adhered to one side to be supported by the support member 2, and the front end corner portion 3B is pressed against the image carrier 4. superior. At this time, the protrusion 5 is brought into contact with the supporting member 2 to prevent the cleaning blade 1B from being bent and the blade tip being detached.

在这样的图19(A)所示的清洁装置中,对清洁刮板1a赋予荷重,则如图示变形,在支承部件2的前端位置产生应力集中引起的压曲,并且如图20(A)所示在清洁刮板1a的前端a产生翘曲,同时在前端附近B产生与载像体4的周面接触的腹当たり。因此,如图21(A)所示,荷重分散而形成小的压力分布。In such a cleaning device shown in FIG. 19(A), when a load is applied to the cleaning blade 1a, it is deformed as shown in the figure, and buckling due to stress concentration occurs at the front end position of the support member 2, and as shown in FIG. 20(A) ) shows that the front end a of the cleaning blade 1a is warped, and at the same time, the front end is in contact with the peripheral surface of the image carrier 4. Therefore, as shown in FIG. 21(A), the load is dispersed to form a small pressure distribution.

另一方面,在图19(B)所示的清洁装置中,即使在清洁刮板1b上施加荷重,也不如图示程度变形,不像图20(B)所示那样腹当たり,由片翘曲部分按压在载像体4上,如图21(B)所示,形成在清洁刮板1b的前端集中有应力的大的压力分布。On the other hand, in the cleaning device shown in FIG. 19(B), even if a load is applied to the cleaning blade 1b, it is not deformed as shown in the figure, and it is not bent as shown in FIG. 20(B). The curved portion is pressed against the image carrier 4, as shown in FIG. 21(B), forming a large pressure distribution in which stress is concentrated at the tip of the cleaning blade 1b.

这样,由于清洁刮板的形状不同,清洁刮板对载像体的接触面积变化,而面压变化,在清洁性能上出现差异。Thus, due to the difference in the shape of the cleaning blade, the contact area of the cleaning blade to the image carrier changes, and the surface pressure changes, resulting in a difference in cleaning performance.

因此,在以往的清洁装置中,例如专利文献1及专利文献1所记载的,提案有考虑面压的方案。另外,例如专利文献3及专利文献4所记载的,提案有将刮板边缘形成为钝角的方案。另外,如专利文献5所记载的,提案有在刮板边缘上附加曲率5~15μm的倒角的方案,如专利文献6所记载的,提案有将刮板形成为锥形的方案。Therefore, in the conventional cleaning apparatuses, for example, as described in Patent Document 1 and Patent Document 1, it has been proposed to consider the surface pressure. In addition, for example, as described in Patent Document 3 and Patent Document 4, it is proposed to form the blade edge into an obtuse angle. Also, as described in Patent Document 5, it is proposed to chamfer the blade edge with a curvature of 5 to 15 μm, and as described in Patent Document 6, it is proposed to form the blade into a tapered shape.

专利文献1:特开2000-75527号公报Patent Document 1: JP-A-2000-75527

专利文献2:特开平11-237819号公报Patent Document 2: Japanese Unexamined Patent Publication No. 11-237819

专利文献3:特开2002-268487号公报Patent Document 3: JP-A-2002-268487

专利文献4:特开平5-19671号公报Patent Document 4: Japanese Unexamined Patent Publication No. 5-19671

专利文献5:特开平6-332350号公报Patent Document 5: Japanese Unexamined Patent Publication No. 6-332350

专利文献6:专利2962843号公报Patent Document 6: Patent No. 2962843

但是,在专利文献1~6中都没有涉及能够清洁小粒且球形的调色剂的低线压且高面压的清洁结构。However, none of Patent Documents 1 to 6 relates to a low linear pressure and high surface pressure cleaning structure capable of cleaning small and spherical toner particles.

发明内容 Contents of the invention

本发明的目的在于在清洁装置、处理盒及图像形成装置中,通过将清洁刮板(Blade)的材质、形状及支承结构特定而得到低线压且高面压的清洁结构。The object of the present invention is to obtain a cleaning structure with low linear pressure and high surface pressure by specifying the material, shape and supporting structure of a cleaning blade (Blade) in a cleaning device, a process cartridge and an image forming device.

为实现上述目的,本发明第一方面提供一种清洁装置,其将由作为刮板固定装置的支承部件支承的聚氨酯橡胶制等的弹性清洁刮板的前端棱角线部向相反方向按压到表面移动的被清洁部件上,而与该被清洁部件的移动方向逆向,去除该被清洁部件的表面上的调色剂,其特征在于,将所述清洁刮板的形成前端棱角线部的角度形成为钝角,并且,在将所述清洁刮板的与被清洁部件压接部分的厚度设为t1、所述清洁刮板的自由长度设为t3时,形成1.75≤t3/t1≤3的关系。在此,所谓面压是指施加在清洁刮板上的总荷重除以清洁刮板对被清洁部件的接触面积的值。被清洁部件中例如有载像体及带电辊等。In order to achieve the above object, a first aspect of the present invention provides a cleaning device that presses the front end corner line portion of an elastic cleaning blade made of polyurethane rubber or the like supported by a support member as a blade fixing device to the surface moving side in the opposite direction. On the member to be cleaned, and opposite to the moving direction of the member to be cleaned, the toner on the surface of the member to be cleaned is removed, characterized in that the angle forming the front edge portion of the cleaning blade is formed as an obtuse angle , and when the thickness of the part of the cleaning blade that is pressed against the member to be cleaned is t1, and the free length of the cleaning blade is t3, a relationship of 1.75≦t3/t1≦3 is formed. Here, the so-called surface pressure refers to the value obtained by dividing the total load applied to the cleaning blade by the contact area of the cleaning blade with the member to be cleaned. The member to be cleaned includes, for example, an image carrier, a charging roller, and the like.

本发明第二方面,在第一方面所述的清洁装置中,所述被清洁部件是辊状及带状的感光体或中间转印体等载像体,图像转印后仍残留在该载像体上的调色剂由所述清洁刮板去除。In the second aspect of the present invention, in the cleaning device described in the first aspect, the member to be cleaned is an image carrier such as a roll-shaped or belt-shaped photoreceptor or an intermediate transfer body, and the image remains on the carrier after image transfer. The toner on the image body is removed by the cleaning blade.

本发明第三方面,在第一方面或第二方面所述的清洁装置中,所述钝角形成从95度到140度的范围。According to the third aspect of the present invention, in the cleaning device described in the first aspect or the second aspect, the obtuse angle forms a range from 95 degrees to 140 degrees.

本发明第四方面,在第三方面所述的清洁装置中,通过倾斜切割所述清洁刮板的前端面而形成所述钝角。可以在清洁刮板成形时倾斜切割而形成,也可以在成形后倾斜切割而形成。According to a fourth aspect of the present invention, in the cleaning device according to the third aspect, the obtuse angle is formed by obliquely cutting the front end surface of the cleaning blade. It may be formed by oblique cutting when the cleaning blade is formed, or may be formed by oblique cutting after forming.

本发明第五方面,在第四方面所述的清洁装置中,倾斜切割清洁刮板的前端面时的切割宽度,在所述清洁刮板的厚度方向上为200μm,在与该厚度方向正交的长度方向上为100μm。According to the fifth aspect of the present invention, in the cleaning device according to the fourth aspect, the cutting width when the front end surface of the cleaning blade is obliquely cut is 200 μm in the thickness direction of the cleaning blade, and is perpendicular to the thickness direction. 100 μm in the length direction.

本发明第六方面,在第一至第五任一方面所述的清洁装置中,所述面压形成为大于或等于3.0MPa。According to a sixth aspect of the present invention, in the cleaning device according to any one of the first to fifth aspects, the surface pressure is formed to be greater than or equal to 3.0 MPa.

本发明第七方面,在第一至第六任一方面所述的清洁装置中,以大于或等于10μm的接触宽度将所述前端棱角线部按压在所述被清洁部件上。在此,所述接触宽度是指前端棱角线部所接触的载像体的移动方向的宽度、即所谓的夹持部宽度。According to a seventh aspect of the present invention, in the cleaning device according to any one of the first to sixth aspects, the front edge portion is pressed against the member to be cleaned with a contact width greater than or equal to 10 μm. Here, the contact width refers to the width in the moving direction of the image carrier with which the leading edge corner portion contacts, that is, the so-called nip width.

本发明第八方面,在第一至第七任一方面所述的清洁装置中,以小于或等于40μm的接触宽度将所述前端棱角线部按压在所述被清洁部件上。According to an eighth aspect of the present invention, in the cleaning device according to any one of the first to seventh aspects, the front end corner line portion is pressed against the member to be cleaned with a contact width of less than or equal to 40 μm.

本发明第九方面,在第八方面所述的清洁装置中,以小于或等于30μm的接触宽度将所述前端棱角线部按压在所述被清洁部件上。According to a ninth aspect of the present invention, in the cleaning device according to the eighth aspect, the front edge portion is pressed against the member to be cleaned with a contact width of 30 μm or less.

本发明第十方面,在第一至第九任一方面所述的清洁装置中,以0.2N/cm至1.2N/cm范围的线压将所述清洁刮板按压在所述被清洁部件上。在此,线压是指施加在清洁刮板上的总荷重除以清洁刮板按压在载像体上的前端棱角线部的长度的值。In the tenth aspect of the present invention, in the cleaning device according to any one of the first to ninth aspects, the cleaning blade is pressed against the cleaned part with a linear pressure ranging from 0.2N/cm to 1.2N/cm . Here, the linear pressure refers to the value obtained by dividing the total load applied to the cleaning blade by the length of the front end corner line portion of the cleaning blade pressed against the image carrier.

本发明第十一方面,在第十方面所述的清洁装置中,以小于或等于0.9N/cm的线压将所述清洁刮板按压在所述被清洁部件上。According to the eleventh aspect of the present invention, in the cleaning device according to the tenth aspect, the cleaning blade is pressed against the member to be cleaned with a linear pressure less than or equal to 0.9 N/cm.

本发明第十二方面,在第一至第十一任一方面所述的清洁装置中,在所述清洁刮板上形成突部,防止所述清洁刮板的前端按压在所述被清洁部件上时抵接在所述支承部件上而所述清洁刮板脱离。即,突部抵接在支承部件上,限制清洁刮板的挠曲。According to the twelfth aspect of the present invention, in the cleaning device according to any one of the first to eleventh aspects, a protrusion is formed on the cleaning blade to prevent the front end of the cleaning blade from pressing against the member to be cleaned. The cleaning blade abuts against the supporting member when it is lifted up, and the cleaning blade is released. That is, the protruding portion abuts against the supporting member, thereby restricting the deflection of the cleaning blade.

本发明第十三方面,在第一至第十一任一方面所述的清洁装置中,将所述清洁刮板的厚度设为t1、从支承部件突出的清洁刮板的自由长度设为t3时,形成1.75≤t3/t1≤3的关系。In a thirteenth aspect of the present invention, in the cleaning device according to any one of the first to eleventh aspects, the thickness of the cleaning blade is t1, and the free length of the cleaning blade protruding from the support member is t3 , a relationship of 1.75≤t3/t1≤3 is formed.

本发明第十四方面,在第一至第十一任一方面所述的清洁装置中,在所述清洁刮板的自由长度部分上垫加加强部件,防止将清洁刮板的前端按压在所述被清洁部件上时所述清洁刮板脱离。即,通过垫加加强部件,限制清洁刮板的挠曲。In the fourteenth aspect of the present invention, in the cleaning device described in any one of the first to eleventh aspects, a reinforcing member is placed on the free length portion of the cleaning blade to prevent the front end of the cleaning blade from being pressed against the cleaning blade. When the cleaning blade is on the part to be cleaned, the cleaning blade is disengaged. That is, the deflection of the cleaning blade is restricted by adding the reinforcing member to the pad.

本发明第十五方面,在第一至第十一任一方面所述的清洁装置中,作为所述清洁刮板的材质,使用JISA硬度为60度到80度的橡胶。In a fifteenth aspect of the present invention, in the cleaning device according to any one of the first to eleventh aspects, rubber having a JISA hardness of 60 to 80 is used as a material of the cleaning blade.

本发明第十六方面,在第一至第十一任一方面所述的清洁装置中,将所述清洁刮板的回复弹性形成为在23℃小于或等于30%。In a sixteenth aspect of the present invention, in the cleaning device according to any one of the first to eleventh aspects, the resilience of the cleaning blade is formed to be less than or equal to 30% at 23°C.

本发明第十七方面,在第一至第十六任一方面所述的清洁装置中,将所述清洁刮板按压在所述被清洁部件上的所述前端棱角线部进行低摩擦化处理而低摩擦系数化。According to the seventeenth aspect of the present invention, in the cleaning device according to any one of the first to sixteenth aspects, the front end edge portion of the cleaning blade is pressed against the member to be cleaned for low-friction treatment. And low friction coefficient.

本发明第十八方面,在第十七方面所述的清洁装置中,所述前端棱角线部用氟类树脂含浸,使其前端棱角线部低摩擦系数化。In an eighteenth aspect of the present invention, in the cleaning device according to the seventeenth aspect, the front edge corners are impregnated with a fluororesin to lower the friction coefficient of the front edge corners.

本发明第十九方面,在第一至第十八任一方面所述的清洁装置中,将所述调色剂的球度形成为大于或等于0.95。In a nineteenth aspect of the present invention, in the cleaning device according to any one of the first to eighteenth aspects, the sphericity of the toner is formed to be greater than or equal to 0.95.

本发明第二十方面提供一种处理盒,其特征在于,至少一体地具有第二方面至第十九任一方面所述的清洁装置和所述载像体,其相对于图像形成装置自如地拆装。The twentieth aspect of the present invention provides a process cartridge, which is characterized in that at least integrally has the cleaning device according to any one of the second to nineteenth aspects and the image carrier, which can be freely moved relative to the image forming device. disassembly.

本发明第二十一方面提供一种图像形成装置,其特征在于,具有第二方面至第十九任一方面所述的清洁装置。A twenty-first aspect of the present invention provides an image forming apparatus, characterized by having the cleaning device according to any one of the second to nineteenth aspects.

本发明第二十二方面,在第二十一方面所述的图像形成装置中,在所述载像体上设置含有无机微粒子的保护层。In a twenty-second aspect of the present invention, in the image forming apparatus described in the twenty-first aspect, a protective layer containing inorganic fine particles is provided on the image carrier.

本发明第二十三方面,在第二十一方面所述的图像形成装置中,在所述载像体的保护层上具有带交联结构的粘合树脂。According to a twenty-third aspect of the present invention, in the image forming apparatus according to the twenty-first aspect, the protective layer of the image carrier has an adhesive resin having a cross-linked structure.

本发明第二十四方面,在第二十三方面所述的图像形成装置中,在所述粘合树脂的结构中具有电荷运送层。In a twenty-fourth aspect of the present invention, in the image forming apparatus according to the twenty-third aspect, a charge transport layer is included in the structure of the binder resin.

本发明第二十五方面,在第二十一至第二十四任一方面所述的图像形成装置中,具有例如使用毛刷(フア一ブラシ)等在所述载像体上涂敷润滑剂的润滑剂涂敷装置。In a twenty-fifth aspect of the present invention, in the image forming apparatus according to any one of the twenty-first to twenty-fourth aspects, there is a method of applying lubricant to the image carrier, for example, using a brush (Fa-Brush) or the like. Lubricant applicator for lubricants.

根据本发明第一方面,由于将所述清洁刮板的形成前端棱角线部的角度形成为钝角,能够不减小接触宽度来提高线压,而是提高面压,并且由于以大于或等于2.0MPa的面压将该前端棱角线部按压在被清洁部件上,即使是小粒且球形的调色剂等也能够可靠地清洁。即,通过将清洁刮板的形状特定,而能够得到低线压、高面压的清洁结构。According to the first aspect of the present invention, since the angle of the front end corner line portion of the cleaning blade is formed as an obtuse angle, the line pressure can not be reduced by reducing the contact width, but the surface pressure can be increased. The surface pressure of MPa presses the front edge portion against the member to be cleaned, and even small and spherical toner particles can be reliably cleaned. That is, by specifying the shape of the cleaning blade, a cleaning structure with low linear pressure and high surface pressure can be obtained.

根据本发明第二方面,由于被清洁部件是感光体及中间转印体等的载像体,图像转印后仍残留在该载像体上的残留调色剂由清洁刮板去除,故能够不减小清洁部件对载像体的接触宽度而提高线压,而是提高面压,与施加在清洁部件上的荷重相比能够高效防止调色剂的滑脱,并且以大于或等于2.0的面压将前端棱角线部按压在载像体上,故能够可靠地清洁图像转印后仍残留在载像体上的残留调色剂。即,通过将清洁刮板的形状特定,能够得到低线压、高面压的清洁结构。According to the second aspect of the present invention, since the member to be cleaned is an image carrier such as a photoreceptor and an intermediate transfer body, and the residual toner remaining on the image carrier after image transfer is removed by the cleaning blade, it is possible to Increasing the line pressure without reducing the contact width of the cleaning member to the image carrier, but increasing the surface pressure, can effectively prevent toner from slipping compared with the load applied to the cleaning member, and with an area greater than or equal to 2.0 The pressure presses the front corner portion against the image carrier, so the residual toner remaining on the image carrier after image transfer can be reliably cleaned. That is, by specifying the shape of the cleaning blade, a cleaning structure with low linear pressure and high surface pressure can be obtained.

根据本发明第三方面,进而由于将所述钝角形成从95度到140度的范围,故能够更加可靠地不减小接触宽度来增加线压,而提高面压。According to the third aspect of the present invention, since the obtuse angle is formed in a range from 95 degrees to 140 degrees, the surface pressure can be increased more reliably without reducing the contact width to increase the line pressure.

根据本发明第四方面,进而由于通过倾斜切割清洁刮板的前端面,故能够更加简单地将形成前端棱角线部的角度形成为钝角,能够不减小接触宽度来增加线压而提高面压。According to the fourth aspect of the present invention, furthermore, since the front end surface of the cleaning blade is cut obliquely, the angle forming the front edge portion can be more easily formed into an obtuse angle, and the surface pressure can be improved by increasing the line pressure without reducing the contact width. .

根据本发明第五方面,进而,倾斜切割清洁刮板的前端面时的切割宽度,在清洁刮板的厚度方向上为200μm,在长度方向上为100μm,因此能够更加可靠地将形成前端棱角线部的角度形成为钝角,而能够不减小接触宽度来增加线压而提高面压。According to the fifth aspect of the present invention, furthermore, the cutting width when cutting the front end surface of the cleaning blade obliquely is 200 μm in the thickness direction of the cleaning blade and 100 μm in the longitudinal direction, so that the front end edge can be formed more reliably. The angle of the portion is formed as an obtuse angle, and the surface pressure can be increased without reducing the contact width to increase the line pressure.

根据本发明第六方面,进而由于还将面压设定成大于或等于3.0MPa,故能够更好地清洁小粒且球形的调色剂。According to the sixth aspect of the present invention, further, since the surface pressure is also set to be greater than or equal to 3.0 MPa, it is possible to better clean the small and spherical toner.

根据本发明第七方面,进而由于以大于或等于10μm的接触宽度将所述前端棱角线部按压在被清洁部件上,故不会因清洁刮板相对被清洁部件出现接触不均,或受到被清洁部件表面的损伤或受到突起物等的影响而清洁不良,而能够对小粒且球形的调色剂进行良好的清洁。According to the seventh aspect of the present invention, furthermore, since the front end edge portion is pressed against the member to be cleaned with a contact width greater than or equal to 10 μm, there will be no uneven contact between the cleaning blade and the member to be cleaned, or the impact of the cleaning blade on the member to be cleaned. If the surface of the cleaning member is damaged or affected by protrusions, etc., the cleaning will be poor, but small and spherical toner particles can be cleaned well.

根据本发明第八方面,进而由于以小于或等于40μm的接触宽度将前端棱角线部按压在所述被清洁部件上,故不增加线压而增高面压,并且不产生促进被清洁部件的磨损或被清洁部件的驱动转矩增加、或清洁刮板磨损增大的危害,能够改进清洁困难的小粒且球形的调色剂的清洁性能。According to the eighth aspect of the present invention, furthermore, since the front end corner portion is pressed against the member to be cleaned with a contact width of 40 μm or less, the surface pressure is increased without increasing the line pressure, and the abrasion of the member to be cleaned is not promoted. Either the increase in the driving torque of the member to be cleaned or the increase in the wear of the cleaning blade can improve the cleaning performance of the small and spherical toner that is difficult to clean.

根据本发明第九方面,进而由于以小于或等于30μm的接触宽度将所述前端棱角线部按压在所述被清洁部件上,故能够更加可靠地不增加线压而提高面压。According to the ninth aspect of the present invention, furthermore, since the front corner portion is pressed against the member to be cleaned with a contact width of 30 μm or less, the surface pressure can be increased more reliably without increasing the line pressure.

根据本发明第十方面,进而由于以0.2N/cm至1.2N/cm范围的线压将清洁刮板按压在被清洁部件上,故能够在确保小粒且球形的调色剂的清洁性能的同时,消除线压过度提高而产生的危害。According to the tenth aspect of the present invention, since the cleaning blade is pressed against the member to be cleaned with a linear pressure in the range of 0.2 N/cm to 1.2 N/cm, it is possible to ensure the cleaning performance of the small and spherical toner. , Eliminate the hazards caused by excessive increase in line voltage.

根据本发明第十一方面,进而由于以小于或等于0.9N/cm的线压将清洁刮板按压在被清洁部件上,故能够更加可靠地防止线压过度增高带来的危害的产生。According to the eleventh aspect of the present invention, since the cleaning blade is pressed against the part to be cleaned with a linear pressure less than or equal to 0.9 N/cm, it is possible to more reliably prevent damage caused by excessively high linear pressure.

根据本发明第十二方面,进而由于在所述清洁刮板上形成突部,防止清洁刮板前端按压在被清洁部件上时抵接在支承部件上时而清洁刮板脱离,抑制清洁部件的腹接触产生的面压的降低,能够通过将清洁刮板的形状特定,而得到低线压、高面压的清洁结构。According to the twelfth aspect of the present invention, furthermore, since the protrusion is formed on the cleaning blade, the front end of the cleaning blade is prevented from coming off when it abuts against the supporting member when it is pressed against the member to be cleaned, and the belly of the cleaning member is suppressed. The reduction of surface pressure due to contact can provide a cleaning structure with low linear pressure and high surface pressure by specifying the shape of the cleaning blade.

根据本发明第十三方面,进而由于在将清洁刮板的厚度设为t1、从支承部件突出的清洁刮板的自由长度设为t3时形成1.75≤t3/t1≤3的关系,故能够抑制清洁部件的腹接触产生的面压的降低,通过将清洁刮板的形状特定,而得到低线压、高面压的清洁结构。According to the thirteenth aspect of the present invention, since the relationship of 1.75≦t3/t1≦3 is formed when the thickness of the cleaning blade is t1 and the free length of the cleaning blade protruding from the supporting member is t3, it is possible to suppress The reduction of the surface pressure due to the belly contact of the cleaning member is achieved by specifying the shape of the cleaning blade to obtain a cleaning structure with low linear pressure and high surface pressure.

根据本发明第十四方面,进而由于在清洁刮板的自由长度部分上垫加加强部件,将防止清洁刮板的前端按压在载像体上时所述清洁刮板脱离,故抑制清洁部件的腹接触产生的面压的降低,通过将清洁刮板的形状特定,能够得到低线压、高面压的清洁结构。According to the fourteenth aspect of the present invention, further, since a reinforcing member is placed on the free length portion of the cleaning blade, the cleaning blade is prevented from detaching when the front end of the cleaning blade is pressed against the image carrier, so that the cleaning member is suppressed. In order to reduce the surface pressure due to belly contact, a cleaning structure with low linear pressure and high surface pressure can be obtained by specifying the shape of the cleaning blade.

根据本发明第十五方面,进而由于作为清洁刮板的材质使用JISA硬度从60度到80度的橡胶,故能够抑制清洁部件的腹接触(腹当たり)产生的面压的降低,通过将清洁刮板的材质特定,而得到低线压、高面压的清洁结构。According to the fifteenth aspect of the present invention, further, since rubber having a JISA hardness of 60 to 80 degrees is used as the material of the cleaning blade, it is possible to suppress the decrease in the surface pressure caused by the belly contact of the cleaning member. The material of the scraper is specific to obtain a cleaning structure with low linear pressure and high surface pressure.

根据本发明第十六方面,进而由于将所述清洁刮板的回复弹性形成为在23℃小于或等于30%,防止清洁刮板的粘滑,能够抑制清洁刮板的磨损,并且通过将清洁刮板的材质特定,而得到低线压、高面压的清洁结构。According to the sixteenth aspect of the present invention, since the resilience of the cleaning blade is formed to be 30% or less at 23° C., stick-slip of the cleaning blade can be prevented, wear of the cleaning blade can be suppressed, and by cleaning The material of the scraper is specific to obtain a cleaning structure with low linear pressure and high surface pressure.

根据本发明,如上所述,由于将清洁刮板的形成前端棱角线部的角度形成为钝角,能够不减小接触宽度来提高线压而将面压提高,与施加在清洁部件上的荷重相比效率高地防止调色剂的滑脱。另外,由于以大于或等于2.0MPa的面压将该前端棱角线部按压在被清洁部件上,即使是小粒且球形的调色剂等也能够可靠地清洁。但是,另一方面,由于高面压,无论如何增大摩擦阻力也会增大被清洁部件的驱动转矩。特别是在适用于最近的彩色图像形成装置中成为主流的串联方式的感光体清洁装置中时,单纯地以与感光体的个数对应的量而增大驱动转矩,使驱动感光体的驱动电机大型化,妨碍装置整体的小型化,成本也提高。According to the present invention, as described above, since the angle of the front edge portion of the cleaning blade is formed as an obtuse angle, the surface pressure can be increased without reducing the contact width to increase the line pressure, which is comparable to the load applied to the cleaning member. I prevent the slipping of the toner efficiently. In addition, since the front edge portion is pressed against the member to be cleaned with a surface pressure of 2.0 MPa or more, even small and spherical toner particles can be reliably cleaned. However, on the other hand, due to the high surface pressure, any increase in the frictional resistance also increases the driving torque of the cleaned part. Especially when it is applied to the tandem-type photoreceptor cleaning device that has become the mainstream in the recent color image forming apparatuses, simply increase the drive torque by an amount corresponding to the number of photoreceptors, so that the drive for driving the photoreceptors The increase in the size of the motor hinders the miniaturization of the entire device and increases the cost.

而根据本发明第十七方面,由于将清洁刮板的按压在被清洁部件上的前端棱角线部低摩擦系数化,故能够降低清洁刮板对被清洁部件的摩擦阻力,将被清洁部件的驱动转矩抑制得很小,防止驱动电机的大型化,防止成本增高。And according to the seventeenth aspect of the present invention, since the front end corner line portion of the cleaning blade pressed on the cleaned part is made to have a low friction coefficient, the frictional resistance of the cleaning blade to the cleaned part can be reduced, and the friction of the cleaned part can be reduced. The driving torque is suppressed to be small, and the increase in size of the driving motor is prevented, which prevents the cost from increasing.

根据本发明第十八方面,由于前端棱角线部用氟类树脂含浸,将其前端棱角线部低摩擦系数化,故能够以简单的方法降低清洁刮板对被清洁部件的摩擦阻力,将被清洁部件的驱动转矩抑制得很小。According to the eighteenth aspect of the present invention, since the front end corners are impregnated with a fluorine-based resin to lower the friction coefficient of the front corners, the frictional resistance of the cleaning blade to the parts to be cleaned can be reduced in a simple way, and the parts to be cleaned will be reduced. The driving torque of the cleaning member is suppressed to be small.

根据本发明第十九方面,进而由于将所述调色剂的球度形成为大于或等于0.95,故能够通过低线压、高面压的清洁结构进行可靠的清洁的同时,能够得到良好的图像品质。According to the nineteenth aspect of the present invention, furthermore, since the sphericity of the toner is formed to be greater than or equal to 0.95, reliable cleaning can be performed by a cleaning structure with low linear pressure and high surface pressure, and good cleaning performance can be obtained. image quality.

根据本发明第二十方面,能够提供至少一体地具有第一至第十六任一方面所述的清洁装置和载像体,且相对于图像形成装置自如地拆装,故可得到可靠地清洁小粒且球形的调色剂的、低线压、高面压的清洁结构的处理盒。另外,通过形成处理盒,容易进行更换、修理、补给等的维护,并且能够实现图像形成装置主体的小型化。According to the twentieth aspect of the present invention, at least one of the cleaning device and the image carrier according to any one of the first to sixteenth aspects can be provided, and it can be freely attached to and detached from the image forming apparatus, so reliable cleaning can be achieved. A process cartridge with a clean structure for small and spherical toner, low linear pressure, and high surface pressure. In addition, by forming the process cartridge, maintenance such as replacement, repair, and replenishment can be easily performed, and the main body of the image forming apparatus can be downsized.

根据本发明第二十一方面,由于是具有第一至第十六任一方面所述的清洁装置的图像形成装置,故能够提供可得到可靠地清洁小粒且球形的调色剂的、低线压、高面压的清洁结构的图像形成装置。According to the twenty-first aspect of the present invention, since it is the image forming apparatus provided with the cleaning device according to any one of the first to sixteenth aspects, it is possible to provide a low-line cleaning device capable of reliably cleaning small and spherical toner particles. Image forming apparatus with a clean structure of high pressure and high surface pressure.

根据本发明第二十二方面,进而由于在载像体上设置含有无机微粒子的保护层,故能够提供提高载像体的耐磨损性的图像形成装置。According to the twenty-second aspect of the present invention, further, since the protective layer containing inorganic fine particles is provided on the image carrier, it is possible to provide an image forming apparatus in which the abrasion resistance of the image carrier is improved.

根据本发明第二十三方面,进而由于在所述载像体的保护层上具有是交联结构的粘合树脂,同样地,能够提供提高载像体的耐磨损性的图像形成装置。According to the twenty-third aspect of the present invention, furthermore, since the protective layer of the image carrier has the binder resin having a cross-linked structure, it is also possible to provide an image forming apparatus in which the wear resistance of the image carrier is improved.

根据本发明第二十四方面,进而由于在所述粘合树脂的结构中具有电荷运送层,能够提供具有提高电气稳定性的载像体的图像形成装置。According to the twenty-fourth aspect of the present invention, furthermore, since the charge transport layer is included in the structure of the binder resin, it is possible to provide an image forming apparatus having an image carrier with improved electrical stability.

根据本发明第二十五方面,进而由于具有在载像体上涂敷润滑剂的润滑剂涂敷装置,能够提高载像体的膜剥落少,提高耐久性的图像形成装置。According to the twenty-fifth aspect of the present invention, furthermore, since the lubricant coating device is provided for coating the lubricant on the image carrier, it is possible to improve the image forming apparatus with less peeling of the film of the image carrier and improved durability.

附图说明 Description of drawings

图1是具有本发明的清洁装置的直接转印式的单色图像形成装置的示意内部构图;1 is a schematic internal composition of a direct-transfer type monochrome image forming apparatus having a cleaning device of the present invention;

图2是该图像形成装置上所具有的载像体的局部放大结构图;Fig. 2 is a partially enlarged structural diagram of an image carrier on the image forming device;

图3是载像体和带电装置的位置关系图;Fig. 3 is the position relationship figure of image carrier and charging device;

图4(A)表示实际的调色剂的投影形状、(B)表示与其面积相同的正圆形状;Fig. 4 (A) shows the projected shape of the actual toner, (B) shows the perfect circle shape with the same area;

图5是清洁装置的放大图;Figure 5 is an enlarged view of the cleaning device;

图6是清洁装置的其他例的放大图;Figure 6 is an enlarged view of another example of the cleaning device;

图7(A)是表示将清洁刮板的前端面局部剖开时的清洁刮板前端放大图、(B)是表示全部剖开时的清洁刮板前端放大图;7(A) is an enlarged view showing the front end of the cleaning blade when the front end surface of the cleaning blade is partially cut away, and (B) is an enlarged view showing the front end of the cleaning blade when the front end surface of the cleaning blade is completely cut;

图8(A)是比较例的清洁刮板A、(B)是本发明的清洁刮板B、(C)是作为比较例的现有的清洁刮板C的支承结构图、(D)是本发明的清洁刮板B的前端放大图;8(A) is a cleaning blade A of a comparative example, (B) is a cleaning blade B of the present invention, (C) is a support structure diagram of a conventional cleaning blade C as a comparative example, and (D) is An enlarged view of the front end of the cleaning scraper B of the present invention;

图9是图8所示的清洁刮板A、B、C的线压与夹持部宽度的关系图;Fig. 9 is a graph showing the relationship between the linear pressure of the cleaning blades A, B, and C shown in Fig. 8 and the width of the clamping portion;

图10是这些清洁刮板A、B、C的线压与面压的关系图;Fig. 10 is the relationship diagram between the line pressure and the surface pressure of these cleaning blades A, B, C;

图11是清洁刮板的自由长度和厚度为一定的关系时的清洁刮板支承结构图;Fig. 11 is a structural diagram of the cleaning blade supporting structure when the free length and thickness of the cleaning blade have a certain relationship;

图12(A)是表示清洁刮板的形成前端棱角线部的角度为90度的情况的刮板支承结构图、(B)是表示清洁刮板的形成前端棱角线部的角度为钝角的情况的刮板支承结构图;12(A) is a blade support structure diagram showing the case where the angle at which the front end corner line portion of the cleaning blade is formed is 90 degrees, and (B) is a view showing the case where the angle at which the front end corner line portion of the cleaning blade is formed is an obtuse angle. Scraper support structure diagram;

图13(A)是加强部件垫加在清洁刮板上的情况的一例、(B)是其他例的刮板支承结构图;Fig. 13 (A) is an example of the situation where the reinforcing component pad is added on the cleaning scraper, and (B) is the supporting structure diagram of the scraper of other examples;

图14是具有润滑剂涂敷装置的图像形成装置的一例的示意内部构图;14 is a schematic internal composition diagram of an example of an image forming apparatus having a lubricant applying device;

图15是其他例的示意内图构图;Fig. 15 is a schematic inner picture composition of other examples;

图16(A)是低摩擦系数化前的刮板支承结构图、(B)是低摩擦系数化之后的刮板支承结构图;Fig. 16(A) is a view of the scraper support structure before low friction coefficient, and (B) is a view of the scraper support structure after low friction coefficient;

图17是具有作为被清洁部件的中间转印体的中间转印单元及其周围的示意结构图;17 is a schematic configuration diagram of an intermediate transfer unit having an intermediate transfer body as a member to be cleaned and its surroundings;

图18是具有作为被清洁部件的带电辊的带电装置及其周围的示意结构图;Fig. 18 is a schematic configuration diagram of a charging device having a charging roller as a member to be cleaned and its surroundings;

图19(A)、(B)是以往的形状不同的清洁刮板的支承结构图;Fig. 19 (A), (B) is the support structure diagram of the cleaning blade of different shape in the past;

图20(A)、(B)是按压在载像体上的状态下的刮板前端的放大图;20(A), (B) are enlarged views of the front end of the squeegee pressed against the image carrier;

图21(A)、(B)是该状态下的压力分布图。21(A) and (B) are pressure distribution diagrams in this state.

符号说明Symbol Description

10载像体(被清洁部件)10 image carrier (parts to be cleaned)

16清洁装置16 cleaning device

23电荷运送层23 charge transport layer

24保护层24 layers of protection

37支承部件37 supporting parts

38清洁刮板38 cleaning scraper

38b前端棱角线部38b front edge corner

40突部40 protrusion

41加强部件41 reinforcement parts

42润滑剂涂敷装置42 lubricant coating device

111转印辊(被清洁部件)111 transfer roller (cleaned part)

210中间转印带(被清洁部件)210 intermediate transfer belt (cleaned parts)

θ形成前端棱角线部的角度θ is the angle formed by the corner line of the front end

具体实施方式 Detailed ways

以下,参照附图说明本发明的最佳实施方式。Hereinafter, the best mode for carrying out the present invention will be described with reference to the drawings.

图1表示具有本发明的清洁装置的直接转印式的单色图像形成装置。FIG. 1 shows a direct transfer type monochrome image forming apparatus provided with a cleaning device of the present invention.

图中符号10可以是带状,但在本实施例中是辊状的载像体,图中顺时针旋转。在载像体10的周围,从上侧的带电装置11开始沿顺时针方向在右侧配置曝光装置12、显影装置13,在下侧配置转印装置14,在左侧配置除电装置15、清洁装置16等。在载像体10的下侧设有经过与转印装置14之间的转印位置而从右侧向左侧而运送纸张、OHP胶片等的记录介质的记录介质运送路17。在记录介质运送路17上转印位置的下游设置定影装置18。The symbol 10 in the figure may be a belt, but in this embodiment it is a roll-shaped image carrier, which rotates clockwise in the figure. Around the image bearing body 10, the exposure device 12 and the developing device 13 are arranged on the right side clockwise from the charging device 11 on the upper side, the transfer device 14 is arranged on the lower side, and the static elimination device 15 is arranged on the left side. Device 16 etc. On the lower side of the image carrier 10, there is provided a recording medium transport path 17 for transporting recording media such as paper, OHP film, etc. from the right side to the left side via a transfer position with the transfer device 14. A fixing device 18 is provided downstream of the transfer position on the recording medium transport path 17 .

随着载像体10的旋转,一边由带电装置11旋转辊状的带电部件一边将载像体10的周面一样地带电成规定的极性。接着,由曝光装置12进行写入,在载像体10的带电区域上形成静电潜像。之后,利用显影装置13而附着调色剂,使该静电潜像可视像化,在载像体10上形成调色剂图像。Along with the rotation of the image carrier 10 , while the roller-shaped charging member is rotated by the charging device 11 , the peripheral surface of the image carrier 10 is uniformly charged to a predetermined polarity. Next, writing is performed by the exposure device 12 to form an electrostatic latent image on the charged region of the image carrier 10 . Thereafter, toner is adhered by the developing device 13 , the electrostatic latent image is visualized, and a toner image is formed on the image carrier 10 .

另一方面,从未图示的给纸盒等抽出的记录介质通过记录介质运送路17运送,与载像体10的旋转时间一致且与该载像体10上的调色剂图像位置对齐,向载像体10的下侧送入。并且,在转印位置,由转印装置14一边运送记录介质一边将载像体10上的调色剂图像转印到该记录介质上。图像转印后的记录介质从载像体10机械地分离,继续通过记录介质运送路17而运送,在下游位置通过定影装置18将转印图像定影,并且向未图示的排纸堆叠装置排出。On the other hand, the recording medium drawn out from the unillustrated paper feeding cassette etc. is conveyed through the recording medium conveying path 17, and is aligned with the toner image position on the image carrier 10 at the same time as the rotation time of the image carrier 10. Feed to the lower side of the image carrier 10. Then, at the transfer position, the toner image on the image carrier 10 is transferred onto the recording medium by the transfer device 14 while conveying the recording medium. The recording medium after the image transfer is mechanically separated from the image carrier 10, continues to be transported through the recording medium transport path 17, and the transferred image is fixed by the fixing device 18 at a downstream position, and is discharged to a paper discharge stacking device not shown in the figure. .

图像转印后的载像体10的周面由除电装置15进行除电后,通过清洁装置16去除图像转印后仍残留在载像体10上的残留调色剂,从带电装置11开始再次形成图像。The peripheral surface of the image carrier 10 after the image transfer is destaticized by the static elimination device 15, and the residual toner remaining on the image carrier 10 after the image transfer is removed by the cleaning device 16, starting from the charging device 11. Image is formed again.

(关于载像体10的结构)(About the structure of the image carrier 10)

在本实施例中使用的载像体10是提高耐磨损性的带负电性的有机载像体,在直径30〔mm〕的辊状导电性支承体上设有感光层等。图2表示其局部剖面。在作为基层的导电性支承体20上设有作为绝缘层的底层21。在其上设有作为感光层的电荷发生层(CGL)22、电荷运送层(CTL)23。然后,在其上层积有构成载像体10表面的保护层(FR)24。The image carrier 10 used in this embodiment is a negatively chargeable organic image carrier with improved abrasion resistance, and a photosensitive layer and the like are provided on a roll-shaped conductive support with a diameter of 30 [mm]. Figure 2 shows its partial section. A base layer 21 as an insulating layer is provided on a conductive support 20 as a base layer. A charge generating layer (CGL) 22 and a charge transporting layer (CTL) 23 as a photosensitive layer are provided thereon. Then, a protective layer (FR) 24 constituting the surface of the image carrier 10 is laminated thereon.

(导电性支承体20)(conductive support 20)

作为导电性支承体20能够使用表示体积电阻小于或等于1010Ω·c m的导电性的物质。例如能够使用铝、镍、铬、镍铬耐热合金(ニクロム)、铜、金、银、白金等金属、氧化锡、氧化铟等金属氧化物由蒸镀或溅射覆盖在薄膜状或圆筒状的塑料、纸上而得的制品、或者铝、铝合金、镍、不锈钢等刮板以及它们由挤压拉制等工艺形成管坯后进行切削、超精加工、研磨等表面处理而得的管等。另外,也可使用特开昭52-36016号公报公开的将环状镍带、环状不锈钢带作为导电性支承体20使用。As the conductive support 20 , a substance showing conductivity with a volume resistance of 10 10 Ω·cm or less can be used. For example, metals such as aluminum, nickel, chromium, nichrome, copper, gold, silver, and platinum, and metal oxides such as tin oxide and indium oxide can be used to coat the film or cylinder by vapor deposition or sputtering. Shaped plastic, paper products, or scrapers such as aluminum, aluminum alloy, nickel, stainless steel, etc., and they are obtained by cutting, superfinishing, grinding and other surface treatments after forming tube blanks by extrusion and drawing processes tube etc. Alternatively, an endless nickel belt or an endless stainless steel belt disclosed in JP-A-52-36016 may be used as the conductive support 20 .

另外,在上述构成的支持体上,再使导电性粉末分散在适当的粘接树脂中后进行涂敷,用作导电性支持体20。作为该导电性粉末,可以举出炭黑、乙炔黑、铝、镍、铁、镍铬、铜、锌、银等金属粉、或导电性氧化锡、ITO等金属氧化物粉末。另外,同时采用的粘接树脂,可以举出聚苯乙烯、苯乙烯-丙烯腈共聚物、苯乙烯-丁二烯共聚物、苯乙烯-马来酸酐共聚物、聚酯、聚氯乙烯、氯乙烯-醋酸乙烯共聚物、聚醋酸乙烯、聚偏二氯乙烯、聚芳基化合物树脂、苯氧基树脂、聚碳酸酯、醋酸纤维素树脂、乙基纤维素树脂、聚乙烯基丁缩醛树脂、聚乙烯基缩甲醛树脂、聚乙烯基甲苯、聚-N-乙烯基咔唑、丙烯酸类树脂、硅树脂、环氧树脂、蜜胺树脂、聚氨酯树脂、酚醛树脂、醇酸树脂等热塑性、热固性树脂或光固化性树脂。这种导电性层,系把这些导电性粉末与粘接树脂分散在例如四氢呋喃、二氯甲烷、甲乙酮、甲苯等中通过涂敷设置。In addition, conductive powder is dispersed in a suitable binder resin on the support having the above-mentioned structure, and then coated, and used as the conductive support 20 . Examples of the conductive powder include metal powders such as carbon black, acetylene black, aluminum, nickel, iron, nickel chromium, copper, zinc, and silver, and metal oxide powders such as conductive tin oxide and ITO. In addition, the adhesive resin used at the same time includes polystyrene, styrene-acrylonitrile copolymer, styrene-butadiene copolymer, styrene-maleic anhydride copolymer, polyester, polyvinyl chloride, chlorine Ethylene-vinyl acetate copolymer, polyvinyl acetate, polyvinylidene chloride, polyarylate resin, phenoxy resin, polycarbonate, cellulose acetate resin, ethyl cellulose resin, polyvinyl butyral resin , polyvinyl formal resin, polyvinyl toluene, poly-N-vinyl carbazole, acrylic resin, silicone resin, epoxy resin, melamine resin, polyurethane resin, phenolic resin, alkyd resin and other thermoplastic, thermosetting resin or photocurable resin. Such a conductive layer is provided by dispersing these conductive powders and a binder resin in, for example, tetrahydrofuran, methylene chloride, methyl ethyl ketone, toluene, etc., by coating.

另外,在适当的圆筒基体上,用聚氯乙烯、聚丙烯、聚酯、聚苯乙烯、聚偏二氯乙烯、聚乙烯、氯橡胶、特氟隆(注册商标)等原材料中含有上述导电性粉末的热收缩管,设置导电性层而构成,可良好地用作导电性支持体20。In addition, on a suitable cylindrical substrate, use polyvinyl chloride, polypropylene, polyester, polystyrene, polyvinylidene chloride, polyethylene, chlorine rubber, Teflon (registered trademark) and other raw materials containing the above-mentioned conductive The heat-shrinkable tube of conductive powder is provided with a conductive layer, and can be used as the conductive support 20 well.

其次,对感光层加以说明。感光层既可以是单层也可以是叠层,但从说明便利考虑,首先对电荷发生层22与电荷输送层23构成的叠层结构进行说明。Next, the photosensitive layer will be described. The photosensitive layer may be a single layer or a stacked layer, but for convenience of description, first, the stacked structure of the charge generation layer 22 and the charge transport layer 23 will be described.

<电荷发生层22><Charge generation layer 22>

电荷发生层22是以电荷发生物质作为主成分的层。电荷发生层22中可采用公知的电荷发生物质。作为电荷发生物质的代表,可以举出单偶氮颜料、双偶氮颜料、三偶氮颜料、苝类颜料、苝醌类颜料、喹吖啶类颜料、醌类缩合多环化合物、方形酸类染料、其他酞菁类颜料、萘菁类颜料、吖丙啶鎓(アズレニウム)盐类染料等,这些是优选的。这些电荷发生物质既可以单独使用,也可以2种或2种以上混合使用。The charge generating layer 22 is a layer mainly composed of a charge generating substance. A known charge-generating substance can be used for the charge-generating layer 22 . Representative examples of charge generating substances include monoazo pigments, disazo pigments, trisazo pigments, perylene pigments, perylenequinone pigments, quinacridine pigments, quinone condensed polycyclic compounds, and squaric acids. Dyes, other phthalocyanine-based pigments, naphthalocyanine-based pigments, azirenium salt-based dyes, and the like are preferable. These charge generating substances may be used alone or in combination of two or more.

电荷发生层22,电荷发生物质可根据需要与粘接树脂一起用球磨机、立式球磨机、砂磨机、超声波等进行混合,将其涂敷在导电性支持体20上或底涂层21上,通过干燥而形成。In the charge generating layer 22, the charge generating material can be mixed with the bonding resin by ball mill, vertical ball mill, sand mill, ultrasonic wave, etc., and coated on the conductive support 20 or the primer layer 21, formed by drying.

电荷发生层22中,可根据需要在粘接树脂中分散上述电荷发生物质。作为可以使用的粘接树脂的例子,可以举出聚酰胺、聚氨酯、环氧树脂、聚酮、聚碳酸酯、硅树脂、丙烯酸类树脂、聚乙烯基丁缩醛树脂、聚乙烯基缩甲醛树脂、聚乙烯基甲苯、聚乙烯基酮、聚苯乙烯、聚砜、聚-N-乙烯基咔唑、聚丙烯酰胺、聚乙烯基亚苄、聚酯、苯氧基树脂、氯乙烯-醋酸乙烯共聚物、聚醋酸乙烯、聚苯醚、聚酰胺、聚乙烯基吡啶、纤维素类树脂、酪蛋白、聚乙烯醇、聚乙烯基吡咯烷酮等。粘接树脂的量对电荷发生物质100重量份达到0~500重量份,优选10~300重量份是适当的。粘接树脂可在分散前或分散后的任何一种状态下添加。In the charge generating layer 22, the above-mentioned charge generating substance may be dispersed in the binder resin as needed. Examples of adhesive resins that can be used include polyamide, polyurethane, epoxy resin, polyketone, polycarbonate, silicone resin, acrylic resin, polyvinyl butyral resin, polyvinyl formal resin , polyvinyltoluene, polyvinyl ketone, polystyrene, polysulfone, poly-N-vinylcarbazole, polyacrylamide, polyvinylbenzylene, polyester, phenoxy resin, vinyl chloride-vinyl acetate Copolymer, polyvinyl acetate, polyphenylene ether, polyamide, polyvinylpyridine, cellulose resin, casein, polyvinyl alcohol, polyvinylpyrrolidone, etc. The amount of the binder resin is suitably 0 to 500 parts by weight, preferably 10 to 300 parts by weight, based on 100 parts by weight of the charge generating material. The binder resin may be added either before dispersion or after dispersion.

作为这里使用的溶剂,可以举出异丙醇、丙酮、甲乙酮、环己酮、四氢呋喃、二噁烷、乙基溶纤剂、乙酸乙酯、乙酸甲酯、二氯甲烷、二氯乙烷、单氯苯、环己烷、甲苯、二甲苯、挥发油等,特别优选使用酮类溶剂、酯类溶剂、醚类溶剂。这些既可以单独使用,也可以2种以上混合使用。Examples of the solvent used here include isopropanol, acetone, methyl ethyl ketone, cyclohexanone, tetrahydrofuran, dioxane, ethyl cellosolve, ethyl acetate, methyl acetate, dichloromethane, dichloroethane, Monochlorobenzene, cyclohexane, toluene, xylene, volatile oil, etc., especially ketone solvents, ester solvents, and ether solvents are preferably used. These may be used individually or in mixture of 2 or more types.

电荷发生层22,以电荷发生物质、溶剂及粘接树脂为主成分,但其中可以含有光敏剂、分散剂、界面活性剂、硅油等任何一种添加剂。The charge generating layer 22 is mainly composed of a charge generating material, a solvent, and an adhesive resin, but may contain any additives such as a photosensitizer, a dispersant, a surfactant, and silicone oil.

作为涂敷液的涂敷方法,可以采用浸渍涂敷法、喷涂法、加热涂敷法、喷嘴涂敷法、旋转涂敷法、环涂敷法等方法。电荷发生层22的膜厚达到0.01~5μm左右是适当的,优选0.1~2μm。As the coating method of the coating liquid, methods such as dip coating, spray coating, heat coating, nozzle coating, spin coating, and ring coating can be used. The film thickness of the charge generating layer 22 is suitably about 0.01 to 5 μm, preferably 0.1 to 2 μm.

<电荷输送层23><Charge transport layer 23>

电荷输送层23是把电荷输送物质及粘接树脂溶解或分散在适当的溶剂中,将其在电荷发生层22上涂敷、干燥而形成。另外,根据需要还可以添加1种或2种以上的增塑剂、调平剂、抗氧剂等。The charge transporting layer 23 is formed by dissolving or dispersing a charge transporting substance and a binder resin in a suitable solvent, applying them on the charge generating layer 22 and drying them. In addition, one or more types of plasticizers, leveling agents, antioxidants, etc. may be added as needed.

电荷输送物质有正孔输送物质和电子输送物质。The charge transporting substances include positive hole transporting substances and electron transporting substances.

作为电子输送物质,例如,可以举出氯醌、溴醌、四氰基乙烯、四氰基醌二甲烷、2,4,7-三硝基-9-芴酮、2,4,5,7-四硝基-9-芴酮、2,4,5,7-四硝基呫吨酮、2,4,8-三硝基噻呫吨酮、2,6,8-三硝基-4H-茚并[1,2-B]噻吩-4-酮、1,3,7-三硝基二苯并噻吩-5,5-二氧化物、苯醌衍生物等电子接收性物质。Examples of electron transporting substances include chloranil, bromoquinone, tetracyanoethylene, tetracyanoquinodimethane, 2,4,7-trinitro-9-fluorenone, 2,4,5,7 -Tetranitro-9-fluorenone, 2,4,5,7-tetranitroxanthone, 2,4,8-trinitrothiaxanthone, 2,6,8-trinitro-4H Electron-accepting substances such as indeno[1,2-B]thiophen-4-one, 1,3,7-trinitrodibenzothiophene-5,5-dioxide, and benzoquinone derivatives.

作为正孔输送物质,例如,可以举出聚-N-乙烯基咔唑及其衍生物、聚-γ-咔唑乙基谷氨酸酯及其衍生物、芘-甲醛缩合物及其衍生物、聚乙烯基芘、聚乙烯基菲、聚硅烷、噁唑衍生物、噁二唑衍生物、咪唑衍生物、单芳基胺衍生物、二芳基胺衍生物、三芳基胺衍生物、均二苯乙烯衍生物、α-苯基二苯乙烯衍生物、联苯胺衍生物、二芳基甲烷衍生物、三芳基甲烷衍生物、9-苯乙烯基蒽衍生物、吡唑啉衍生物、二乙烯基苯衍生物、腙衍生物、茚衍生物、丁二烯衍生物、芘衍生物、二芪衍生物、烯胺衍生物等、其他公知的材料。这些电荷输送物质可以单独,或2种或2种以上混合使用。Examples of positive pore transport substances include poly-N-vinylcarbazole and its derivatives, poly-γ-carbazole ethyl glutamate and its derivatives, pyrene-formaldehyde condensate and its derivatives , polyvinylpyrene, polyvinylphenanthrene, polysilane, oxazole derivatives, oxadiazole derivatives, imidazole derivatives, monoarylamine derivatives, diarylamine derivatives, triarylamine derivatives, homogeneous Stilbene derivatives, α-phenyl stilbene derivatives, benzidine derivatives, diarylmethane derivatives, triarylmethane derivatives, 9-styryl anthracene derivatives, pyrazoline derivatives, Vinylbenzene derivatives, hydrazone derivatives, indene derivatives, butadiene derivatives, pyrene derivatives, bistilbene derivatives, enamine derivatives, etc., and other known materials. These charge-transporting substances may be used alone or in combination of two or more.

作为粘接树脂,可以举出苯乙烯、苯乙烯-丙烯腈共聚物、苯乙烯-丁二烯共聚物、苯乙烯-马来酸酐共聚物、聚酯、聚氯乙烯、氯乙烯-醋酸乙烯共聚物、聚醋酸乙烯、聚偏二氯乙烯、聚芳基化合物树脂、苯氧基树脂、聚碳酸酯、醋酸纤维素树脂、乙基纤维素树脂、聚乙烯基丁缩醛树脂、聚乙烯基缩甲醛树脂、聚乙烯基甲苯、聚-N-乙烯基咔唑、丙烯酸类树脂、硅树脂、环氧树脂、蜜胺树脂、聚氨酯树脂、酚醛树脂、醇酸树脂等热塑性或热固性树脂。Examples of the binder resin include styrene, styrene-acrylonitrile copolymer, styrene-butadiene copolymer, styrene-maleic anhydride copolymer, polyester, polyvinyl chloride, vinyl chloride-vinyl acetate copolymer Polyvinyl acetate, polyvinylidene chloride, polyarylate resin, phenoxy resin, polycarbonate, cellulose acetate resin, ethyl cellulose resin, polyvinyl butyral resin, polyvinyl acetal Formaldehyde resin, polyvinyltoluene, poly-N-vinylcarbazole, acrylic resin, silicone resin, epoxy resin, melamine resin, polyurethane resin, phenolic resin, alkyd resin and other thermoplastic or thermosetting resins.

电荷输送物质的量对粘接树脂100重量份达到20~300重量份,优选40~150重量份是适当的。另外,电荷输送层的厚度,从分辨度、响应性考虑,达到25μm或25μm以下是优选的。其下限值因使用的系统(特别是带电电位等)而异,但达到5μm或5μm以上是优选的。The amount of the charge transporting substance is suitably 20 to 300 parts by weight, preferably 40 to 150 parts by weight, based on 100 parts by weight of the binder resin. In addition, the thickness of the charge transport layer is preferably 25 μm or less in terms of resolution and responsiveness. The lower limit value varies depending on the system used (especially charging potential, etc.), but it is preferably 5 μm or more.

作为这里使用的溶剂,可以举出四氢呋喃、二噁烷、甲苯、二氯甲烷、单氯苯、二氯乙烷、环己酮、甲乙酮、丙酮等。这些既可以单独使用,也可以2种或2种以上混合使用。Examples of the solvent used here include tetrahydrofuran, dioxane, toluene, methylene chloride, monochlorobenzene, dichloroethane, cyclohexanone, methyl ethyl ketone, acetone and the like. These may be used individually or in mixture of 2 or more types.

其次,对感光层为单层结构时加以介绍。感光层是把上述电荷发生物质、电荷输送物质、粘接树脂溶解或分散在适当的溶剂中,将其在导电性支持体50上或底涂层51上进行涂敷、干燥而形成的。不含电荷输送物质而由电荷发生物质与粘接树脂构成也可。另外,根据需要,还可以添加增塑剂或调平剂、抗氧剂等。Next, the case where the photosensitive layer has a single-layer structure is described. The photosensitive layer is formed by dissolving or dispersing the above-mentioned charge generating substance, charge transporting substance, and binder resin in a suitable solvent, coating it on the conductive support 50 or the undercoat layer 51, and drying it. The charge-transporting substance may not be included, but may be composed of a charge-generating substance and a binder resin. In addition, a plasticizer, a leveling agent, an antioxidant, and the like may be added as needed.

作为粘接树脂,除上述在电荷输送物质23中列举的粘接树脂以外,在电荷发生层中列举的粘接树脂也可以混合使用。当然,使用先前列举的高分子电荷输送物质也是优选的。电荷输送物质的量对粘接树脂100质量份达到5~40质量份是优选的,电荷输送物质的量0~190质量份是优选的,50~150质量份是更优选的。As the binder resin, in addition to the binder resins listed above for the charge transport material 23 , the binder resins listed for the charge generating layer may be mixed and used. Of course, it is also preferable to use the polymeric charge-transporting substances listed above. The amount of the charge transporting substance is preferably 5 to 40 parts by mass relative to 100 parts by mass of the binder resin, preferably 0 to 190 parts by mass, and more preferably 50 to 150 parts by mass.

感光层是电荷发生物质、粘接树脂与电荷输送物质一起,采用四氢呋喃、二噁烷、二氯乙烷、环己烷等溶剂,用分散机等分散的涂敷液,用浸渍涂敷法或喷涂法、加热涂敷法、环涂敷法等进行涂敷而形成的。感光层的膜厚5~25μm左右是适当的。The photosensitive layer is a coating solution dispersed with a disperser, etc., using solvents such as tetrahydrofuran, dioxane, dichloroethane, and cyclohexane together with a charge-generating substance, a binder resin, and a charge-transporting substance. Formed by spray coating, heating coating, ring coating, etc. The film thickness of the photosensitive layer is about 5 to 25 μm is appropriate.

<底涂层21><Undercoat 21>

在图示例的图像载体10中,在导电性支持体20与感光层之间设置底涂层21。底涂层21一般以树脂作为主成分,当考虑把这些树脂在其上用溶剂涂敷感光层时,希望采用对一般的有机溶剂的耐溶剂性高的树脂。作为这种树脂,可以举出聚乙烯醇、酪蛋白、聚丙烯酸钠等水溶性树脂;共聚尼龙、甲氧基甲基化尼龙等醇可溶性树脂;聚氨酯、蜜胺树脂、酚醛树脂、醇酸-蜜胺树脂、环氧树脂等形成三元网状结构的热固性树脂。在底涂层21中,为了防止绉纹、残留电位的下降,也可以添加氧化钛、二氧化硅、氧化铝、氧化锆、氧化锡、氧化铟等列举的金属氧化物的细粉末颜料。另外,这些底涂层21,可以采用上述感光层那样适当的溶剂及涂敷方法形成。另外,作为图中列举的底涂层21,还可以采用硅烷偶合剂、钛偶合剂、铬偶合剂等。另外,在底涂层21上通过阳极氧化设置Al2O3,或聚对二甲苯(异戊烯炔)等有机物,或SiO2、SnO2、TiO2、ITO、CeO2等无机物,用真空薄膜制备法设置也是优选的。另外,还可以采用公知的。底涂层21的膜厚0~5μm是适当的。In the image carrier 10 of the illustrated example, an undercoat layer 21 is provided between the conductive support 20 and the photosensitive layer. The undercoat layer 21 generally has a resin as a main component, and when it is considered that the photosensitive layer is coated with a solvent on these resins, it is desirable to use a resin having high solvent resistance to common organic solvents. Examples of such resins include water-soluble resins such as polyvinyl alcohol, casein, and sodium polyacrylate; alcohol-soluble resins such as copolymerized nylon and methoxymethylated nylon; polyurethane, melamine resin, phenolic resin, alkyd- Melamine resin, epoxy resin and other thermosetting resins that form a three-dimensional network structure. In the undercoat layer 21 , fine powder pigments of metal oxides such as titanium oxide, silicon dioxide, aluminum oxide, zirconium oxide, tin oxide, and indium oxide may be added in order to prevent wrinkles and a decrease in residual potential. In addition, these undercoat layers 21 can be formed using appropriate solvents and coating methods like the above-mentioned photosensitive layers. In addition, as the undercoat layer 21 shown in the figure, a silane coupling agent, a titanium coupling agent, a chromium coupling agent, etc. can also be used. In addition, Al 2 O 3 , or organic substances such as parylene (prenyne), or inorganic substances such as SiO 2 , SnO 2 , TiO 2 , ITO, and CeO 2 are provided on the undercoat layer 21 by anodic oxidation. A vacuum thin film preparation setup is also preferred. In addition, known ones can also be used. The film thickness of the undercoat layer 21 is suitably 0 to 5 μm.

<保护层24的第1例><The first example of the protective layer 24>

为了防止对图像载体10的最表面层机械摩耗,也可以设置保护层24。例如,为了提高耐摩耗性,用无定形硅涂敷表面的图像载体,或另外在电荷输送层23的表面设置分散了氧化铝或氧化锡等的最外面层的有机图像载体等也可以采用。设置含无机微粒的保护层24也可。In order to prevent mechanical wear on the outermost layer of the image carrier 10, a protective layer 24 may also be provided. For example, an image carrier whose surface is coated with amorphous silicon in order to improve wear resistance, or an organic image carrier in which an outermost layer such as aluminum oxide or tin oxide is dispersed on the surface of the charge transport layer 23 may also be used. A protective layer 24 containing inorganic fine particles may also be provided.

如上所述,在该实例中使用的图像载体10的结构,不限于特定的结构。在导电性支持体20上仅设置电荷发生物质和电荷输送物质作为主成分的感光层的1层结构;或在导电性支持体20上设置电荷发生物质作为主成分的电荷发生层和以电荷输送物质作为主成分的电荷输送层的叠层结构;或在导电性支持体20上设置电荷发生物质与电荷输送物质作为主成分的感光层,再在其上设置保护层的结构;或者,在导电性支持体上层叠以电荷发生物质作为主成分的电荷发生层和以电荷输送物质作为主成分的电荷输送层,在该电荷输送层上设置保护层的结构;或者,在导电性支持体上层叠以电荷输送物质作为主成分的电荷输送层和以电荷发生物质作为主成分的电荷发生层,在该电荷发生层上设置保护层的结构等,具有各种层结构的图像载体均优选使用。As described above, the structure of the image carrier 10 used in this example is not limited to a specific structure. A one-layer structure in which only a photosensitive layer having a charge generating substance and a charge transporting substance as main components is provided on the conductive support 20; The laminated structure of the charge transport layer with the substance as the main component; or the structure in which the photosensitive layer with the charge generating material and the charge transport material as the main component is provided on the conductive support 20, and a protective layer is provided thereon; A charge-generating layer mainly composed of a charge-generating substance and a charge-transporting layer mainly composed of a charge-transporting substance are laminated on a conductive support, and a protective layer is provided on the charge-transporting layer; or, a conductive support is laminated. Image carriers having various layer structures such as a charge transporting layer mainly composed of a charge transporting substance, a charge generating layer mainly composed of a charge generating substance, and a structure in which a protective layer is provided on the charge generating layer are preferably used.

<保护层24的第2例><The second example of the protective layer 24>

另外,在保护层24上使用具有交联结构的粘合树脂的保护层也是有效的。为了形成交联结构,使用1个分子内有多个交联性官能基的反应性单体,用光或热能使发生交联反应,形成3元网状结构。该网状结构作为粘接树脂可呈现高的耐摩耗性。In addition, it is also effective to use a protective layer having an adhesive resin having a crosslinked structure on the protective layer 24 . In order to form a cross-linked structure, a reactive monomer having multiple cross-linkable functional groups in one molecule is used, and a cross-linking reaction occurs with light or heat energy to form a ternary network structure. This network structure exhibits high wear resistance as an adhesive resin.

从电稳定性、耐刷性、寿命的观点考虑,作为上述反应性单体,使用全部或一部分具有电荷输送能力的单体是非常有效的措施。通过使用这种单体,可在网状结构中形成电荷输送部位,作为保护层24的功能可以充分呈现。From the viewpoint of electrical stability, brush resistance, and lifetime, it is very effective to use all or part of the monomer having charge transport capability as the above-mentioned reactive monomer. By using such a monomer, charge transport sites can be formed in the network structure, and the function as the protective layer 24 can be fully exhibited.

作为具有电荷输送能力的反应性单体,可以举出在同一分子中含有至少1个以上具有电荷输送性成分与水解性取代基的硅原子的化合物,在同一分子中含有电荷输送性成分与羟基的化合物,在同一分子中含有电荷输送性成分与羧基的化合物,在同一分子中含有电荷输送性成分与环氧基的化合物,在同一分子中含有电荷输送性成分与异氰酸酯基的化合物。具有这些反应性基的电荷输送性材料既可以单独使用,也可以2种或2种以上并用。Examples of reactive monomers having charge-transporting ability include compounds containing at least one silicon atom having a charge-transporting component and a hydrolyzable substituent in the same molecule, and compounds containing a charge-transporting component and a hydroxyl group in the same molecule. A compound containing a charge-transporting component and a carboxyl group in the same molecule, a compound containing a charge-transporting component and an epoxy group in the same molecule, a compound containing a charge-transporting component and an isocyanate group in the same molecule. The charge transporting materials having these reactive groups may be used alone or in combination of two or more.

作为具有电荷输送能力的单体,更优选电气·化学稳定性高者,从载体的移动度快等考虑,使用具有三芳基胺结构的反应性单体是有效的。As a monomer having charge-transporting ability, one with high electrical and chemical stability is more preferable, and it is effective to use a reactive monomer having a triarylamine structure in view of fast carrier mobility and the like.

除此之外,从涂敷时的粘度调整、交联型电荷输送层的应力缓和、低表面能化及摩擦系数降低等目的考虑,可以并用单官能及双官能的聚合性单体及聚合性低聚物。作为这些聚合性单体及低聚物,可以利用公知的那些。In addition, monofunctional and bifunctional polymerizable monomers and polymerizable Oligomer. As these polymerizable monomers and oligomers, known ones can be used.

另外,在图示例中,用热或光进行正孔输送性化合物的聚合或交联,但在用热进行聚合反应时,可以举出仅用热能进行聚合反应以及必须用引发剂的场合,但为了在较低温度更有效地进行反应,添加引发剂是优选的。In addition, in the illustrated example, the polymerization or crosslinking of the positive hole transport compound is carried out by heat or light, but when the polymerization reaction is carried out by heat, it can be mentioned that the polymerization reaction is carried out only by heat energy and an initiator must be used, but In order to carry out the reaction more efficiently at lower temperatures, addition of an initiator is preferred.

用光进行聚合时,用紫外线作光是优选的,但仅用光能进行反应是特别稀少的,一般并用光聚合引发剂。此时的所谓光聚合引发剂,主要系指吸收波长400nm或400nm以下紫外线,生成自由基或离子等活性种,使聚合开始的引发剂。还有,在该例中,上述热及光聚合引发剂也可以并用。When photopolymerization is performed, it is preferable to use ultraviolet light as the light, but since the reaction is particularly rare only by light energy, a photopolymerization initiator is generally used in combination. The so-called photopolymerization initiator at this time mainly refers to an initiator that absorbs ultraviolet light with a wavelength of 400 nm or less, generates active species such as free radicals or ions, and initiates polymerization. In addition, in this example, the thermal and photopolymerization initiators mentioned above may be used in combination.

具有这种形成的网状结构的电荷输送层23,耐摩耗性高,但在交联反应时体积收缩加大,而形成相当厚的膜,故有时生成裂缝等。在这种情况下,当保护层采用层叠结构时,下层(感光层侧)使用低分子分散聚合物的保护层,在上层(表面侧)形成具有交联结构的保护层也可。The charge-transporting layer 23 having such a formed network structure has high abrasion resistance, but volume shrinkage increases during the crosslinking reaction to form a relatively thick film, which may cause cracks or the like. In this case, when the protective layer has a laminated structure, the lower layer (photosensitive layer side) may use a low-molecular dispersion polymer protective layer, and the upper layer (surface side) may form a protective layer having a cross-linked structure.

例如,在电子照相图像载体中,除保护层涂敷液及膜厚·制作条件用下述代替外,进行同样的操作,制成电子照相图像载体A。For example, in the electrophotographic image carrier, the electrophotographic image carrier A was produced in the same manner except that the protective layer coating liquid, film thickness and production conditions were replaced by the following.

把甲基三甲氧基硅烷182份、二羟甲基三苯基胺40份、2-丙醇225份、2%醋酸106份、三乙酰基乙醇铝1份加以混合,配制保护层用涂敷液。把该涂敷液在上述电荷输送层23上涂敷、干燥,干110℃加热固化1小时,形成膜厚3μm的保护层24。Mix 182 parts of methyltrimethoxysilane, 40 parts of dimethyloltriphenylamine, 225 parts of 2-propanol, 106 parts of 2% acetic acid, and 1 part of aluminum triacetylethoxide to prepare a protective layer for coating liquid. The coating liquid was applied on the above-mentioned charge transporting layer 23, dried, and cured by heating at 110° C. for 1 hour to form a protective layer 24 with a film thickness of 3 μm.

另外,在电子照相图像载体中,除保护层涂敷液及膜厚·制作条件用下述代替外,进行同样的操作,制成电子照相图像载体B。In addition, in the electrophotographic image carrier, the electrophotographic image carrier B was produced in the same manner except that the protective layer coating solution, film thickness and production conditions were replaced by the following.

把正孔输送性化合物(下列化1结构式)30份、丙烯酸类单体(下列化2结构式)以及光聚合引发剂(1-羟基-环己基-苯基-酮)0.6份,溶解在单氯苯50份/二氯甲烷50份的混合溶液中,配成表面保护层用涂料。把该涂料用喷涂法在先前的电荷输送层23上涂敷,用金属卤灯用500mW/cm2光强度使固化30秒,形成膜厚5μm的表面保护层24。Dissolve 30 parts of the positive hole transport compound (the following formula 1), acrylic monomer (the following formula 2) and 0.6 parts of the photopolymerization initiator (1-hydroxy-cyclohexyl-phenyl-ketone) in monochloro In a mixed solution of 50 parts of benzene/50 parts of dichloromethane, it is formulated as a coating for surface protection. This paint was sprayed on the previous charge transport layer 23 and cured for 30 seconds with a metal halide lamp at a light intensity of 500 mW/cm 2 to form a surface protection layer 24 with a film thickness of 5 μm.

[化1][chemical 1]

Figure G2005101192743D00181
Figure G2005101192743D00181

[化2][Chem 2]

Figure G2005101192743D00182
Figure G2005101192743D00182

(关于带电装置11)(About charging device 11)

关于附图所示的带电装置11的结构,表示其一例。An example of the structure of the charging device 11 shown in the drawing is shown.

作为带电装置,以往具有使用利用电晕放电的电晕带电方式的装置。电晕带电方式将充电线靠近被带电体设置,通过向充电线施加高电压,在充电线和被带电体之间产生电晕放电,由此使被带电体带电。但是,在电晕带电方式的情况,伴随电晕放电产生臭氧及氮族氧化物(NOx)等放电生成物质。由于放电生成物质会形成图像形成时对载像体产生不良影响的硝酸或硝酸盐的膜,故尽可能避免其的产生。Conventionally, as a charging device, there is a device using a corona charging method using corona discharge. In the corona charging method, the charging line is placed close to the object to be charged, and a high voltage is applied to the charging line to generate a corona discharge between the charging line and the object to be charged, thereby charging the object to be charged. However, in the case of the corona charging method, discharge generating substances such as ozone and nitrogen oxides (NO x ) are generated along with corona discharge. Since the discharge-generated substance forms a nitric acid or nitrate film that adversely affects the image carrier during image formation, its generation should be avoided as much as possible.

因此,近年来,替代电晕放电方式,放电生成物质的产生少、能够以低电力带电的接触带电方式或接近带电方式的开发正在盛行。这些方式是将辊、刷或刮板等带电部件与载像体等被带电体接触相对或接近相对,通过向带电部件施加电压而使被带电体表面带电。根据该方式,与电晕带电方式相比,由于放电生成物质的产生少,能够实现低电力化,故实用性高。另外,由于不需要大型的带电装置,故能够实现装置的小型化,与希望装置小型化的要求一致。Therefore, in recent years, instead of the corona discharge method, the development of a contact charging method or a proximity charging method that generates less discharge-generated substances and enables low-power charging has been actively developed. In these methods, a charging member such as a roller, a brush, or a blade is placed in contact with or close to a charged body such as an image carrier, and a voltage is applied to the charging member to charge the surface of the charged body. According to this method, compared with the corona charging method, since there is less generation of discharge generation substances and lower power can be achieved, the practicality is high. In addition, since a large charging device is not required, it is possible to reduce the size of the device, which meets the demand for a smaller device.

在图示例中,作为实现上述的低电力化、低危险化、小型化的要求的一例,使用以下所示的非接触辊带电方式。In the illustrated example, a non-contact roller charging method shown below is used as an example of realizing the above-mentioned requirements for lower power consumption, lower risk reduction, and smaller size.

另外,在使用球形调色剂的情况,如上所示,与现有的粉块调色剂相比容易产生清洁不良。在可使用由不定形调色剂的堆积层来清洁球形调色剂的图像形成装置中,万一产生调色剂不良,若为非接触辊带电方式,则由于清洁不良的调色剂不附着在带电装置上,故具有不引起带电异常所产生的异常图像的发生。In addition, in the case of using a spherical toner, as described above, poor cleaning tends to occur more easily than conventional powder lump toners. In an image forming apparatus that can clean a spherical toner from an accumulated layer of amorphous toner, if a toner defect occurs, if the non-contact roller charging method is used, the toner due to the cleaning defect will not adhere. On the charging device, it does not cause abnormal images generated by abnormal charging.

图示例中的带电装置通过非接触而接近相对配置的带电部件所产生的交流施加放电,使载像体10带电。另外,还具有通过接触相对配置的带电部件的交流施加放电而使载像体10带电的方法。在使用该方法的情况下,最好提高载像体10表面和带电部件的接触性,并且使用不赋予载像体10机械压力的弹性部件。其中,若使用弹性部件,则带电夹持部宽度扩大,这样而保护物质易附着在带电辊侧。这样,在被带电体的高耐久化上,通过非接触而带电的方法是有利的。The charging device in the illustrated example charges the image carrier 10 by applying an AC discharge generated by non-contact approaching charging members arranged oppositely. In addition, there is also a method of charging the image bearing member 10 by contacting the charging member arranged oppositely with an AC applied discharge. In the case of using this method, it is preferable to increase the contact between the surface of the image carrier 10 and the charging member, and to use an elastic member that does not apply mechanical pressure to the image carrier 10 . However, if the elastic member is used, the width of the charging nip portion will be enlarged, and thus the protective substance will easily adhere to the charging roller side. In this way, the method of non-contact charging is advantageous in improving the durability of the charged body.

图3中表示带电位置的载像体10和带电装置11的位置关系、在带电装置11上具有作为带电部件的带电辊26、衬垫27、弹簧28以及电源30等。在带电辊26上设置轴部26A和作为带电部的辊部26b。其中,辊部26b与载像体10相对,具有使载像体10表面带电的功能,通过轴部26A的旋转而能够转动。带电辊26的辊部26b相对载像体10表面以微小间隙相对配置而在带电辊26上设置作为间隙保持部件的衬垫27。通过该衬垫27,与载像体10表面中形成有图像的图像形成区域A相对的部分与载像体10非接触而配置。辊部26b长度方向的尺寸设定成比载像体10的图像形成区域长,通过使衬垫27抵接在载像体10的非图像形成区域b上,形成上述微小的间隙c。经由该衬垫27,带电辊26绕载像体10表面并相连着旋转。微小间隙c构成带电辊部26b和载像体10最接近部为1~100μm。该最接近距离最好为30~65μm。3 shows the positional relationship between the image carrier 10 and the charging device 11 at the charging position, and the charging device 11 has a charging roller 26 as a charging member, a spacer 27, a spring 28, a power source 30, and the like. On the charging roller 26, a shaft portion 26A and a roller portion 26b as a charging portion are provided. Among them, the roller portion 26 b faces the image carrier 10 , has a function of charging the surface of the image carrier 10 , and is rotatable by rotation of the shaft portion 26A. The roller portion 26 b of the charging roller 26 is disposed opposite to the surface of the image carrier 10 with a slight gap, and a spacer 27 as a gap maintaining member is provided on the charging roller 26 . Through this spacer 27 , a portion facing the image forming region A on the surface of the image carrier 10 on which an image is formed is arranged without being in contact with the image carrier 10 . The dimension in the longitudinal direction of the roller portion 26b is set to be longer than the image forming region of the image carrier 10, and the aforementioned minute gap c is formed by abutting the spacer 27 on the non-image forming region b of the image carrier 10. The charging roller 26 rotates around the surface of the image bearing member 10 through the spacer 27 and continuously. The minute gap c constituting the closest portion between the charging roller portion 26b and the image carrier 10 is 1 to 100 μm. The closest distance is preferably 30 to 65 μm.

在轴部26A上安装有用于将带电辊26A向被带电体按压的弹簧28。由此,能够精度良好地维持上述微小间隙c。A spring 28 for pressing the charging roller 26A against the charged body is attached to the shaft portion 26A. Thereby, the above-mentioned small gap c can be maintained with high precision.

在带电辊26上连接有带电用的电源30。电源30在载像体10表面和带电辊26表面间的微小空隙中,通过交流施加放电而使载像体10表面均匀带电。在该实施例中,将在作为直流成分的D C电压上重叠了作为交流成分的AC电压的交变电压向带电辊26施加。通过使用交变电压,抑制引起微小间隙变动的带电电位的波动等的影响,能够均匀带电。A power supply 30 for charging is connected to the charging roller 26 . The power source 30 uniformly charges the surface of the image carrier 10 by applying an AC discharge to the minute gap between the surface of the image carrier 10 and the surface of the charging roller 26 . In this embodiment, an alternating voltage in which an AC voltage as an alternating component is superimposed on a DC voltage as a direct current component is applied to the charging roller 26. By using an alternating voltage, influences such as fluctuations in charging potential that cause minute gap fluctuations are suppressed, enabling uniform charging.

上述带电辊26由呈圆柱状的导电性支承体的芯骨和在该芯骨的外周面上形成的电阻调整层构成。在该实施例中,带电辊26的直径形成10mm。The charging roller 26 is composed of a core bar of a cylindrical conductive support and a resistance adjustment layer formed on the outer peripheral surface of the core bar. In this embodiment, the diameter of the charging roller 26 is formed to be 10 mm.

带电辊26的表面能够使用例如橡胶部件等公知的材料,但理想的是由树脂材料构成。若使用橡胶部件,则由于橡胶吸水和挠曲的发生,难以维持与载像体10的微小间隙。根据成像条件,仅带电辊26的中央部能够突发地接触载像体10表面。难以应对这样的局部、突发的带电辊26向载像体10的接触引起的载像体10表面层的紊乱。因此,通过非接触带电方式使载像体10带电时,最好使用能够均匀地维持带电辊和载像体的微小间隙的硬质材料。The surface of the charging roller 26 can be made of a known material such as a rubber member, but is preferably made of a resin material. If a rubber member is used, it is difficult to maintain a small gap with the image carrier 10 due to water absorption and deflection of the rubber. Depending on image forming conditions, only the central portion of the charging roller 26 can contact the surface of the image bearing body 10 suddenly. It is difficult to cope with the disturbance of the surface layer of the image carrier 10 caused by such local and sudden contact of the charging roller 26 to the image carrier 10 . Therefore, when charging the image carrier 10 by the non-contact charging method, it is preferable to use a hard material capable of uniformly maintaining a small gap between the charging roller and the image carrier.

<带电辊表层><Surface layer of charging roller>

作为带电辊26表面的硬质材料,例如,可以采用下列材料。作为电阻调整层,可由高分子型离子导电剂分散的热塑性树脂组合物(聚乙烯、聚丙烯、聚甲基丙烯酸甲酯、聚苯乙烯及其共聚物等)形成,电阻调整层表面用固化剂进行固化被膜处理等。固化被膜处理,例如把电阻调整层浸渍在含异氰酸酯化合物的处理溶液中来进行处理。或者,把电阻调整层的表面改性,形成固化处理被膜层也可。As the hard material for the surface of the charging roller 26, for example, the following materials can be used. As the resistance adjustment layer, it can be formed of a thermoplastic resin composition (polyethylene, polypropylene, polymethyl methacrylate, polystyrene and its copolymer, etc.) dispersed with a polymer ion conductive agent. Cured film treatment and the like are performed. The curing coating treatment is performed by, for example, immersing the resistance adjustment layer in a treatment solution containing an isocyanate compound. Alternatively, the surface of the resistance adjustment layer may be modified to form a cured coating layer.

(显影装置13)(developing device 13)

如图1所示,在显影装置13上,在显影壳体32内例如具有:搅拌运送显影剂的搅拌运送部件33、将由其运送的显影剂进行补给的显影剂补给辊34、将由其补给的显影剂的调色剂附着在载像体10上的显影辊35、在附着在载像体10上之前将显影辊35上的显影剂薄层化的薄层化部件(省略图示)等。As shown in FIG. 1, in the developing device 13, there are, for example, inside the developing housing 32: an agitating and conveying member 33 for agitating and conveying the developer, a developer replenishing roller 34 for replenishing the developer conveyed by it, and a developer replenishing roller 34 for replenishing the developer therefrom. Toner of the developer adheres to the developing roller 35 on the image carrier 10 , and a thinning member (not shown) that thins the developer on the developing roller 35 before adhering to the image carrier 10 .

近年来,在使用调色剂进行图像形成的图像形成装置中,要以更高的精度形成高精细的图像,高分辨率的要求提高。作为实现高分辨率的方法,公知使用减小粒径且接近球形的球形调色剂是有效的。因此,在显影装置13中为了提高画质而使用球度大于或等于0.95的球形调色剂。In recent years, image forming apparatuses that use toner to form images have been required to form high-definition images with higher precision, and the demand for high resolution has increased. As a method for achieving high resolution, it is known to be effective to use a spherical toner having a reduced particle diameter and a nearly spherical shape. Therefore, a spherical toner having a sphericity of 0.95 or more is used in the developing device 13 in order to improve image quality.

这里的“球度”是由流动式例子像分辨装置FPIA-2000(東亜医用電子株式会社(东亚医用电子株式会社)生产,商品名)测出的平均球度。具体的是,在容器中的预先去除了杂质固形物的水100~150ml中,作为分散剂加入界面活性剂,最好加入0.1~0.5ml的烷基苯磺酸盐,另外加入0.1~0.5g左右的测定试料(调色剂)。然后,由超声波分散器对该调色剂分散了的悬浊液进行大于1~3分钟的分散处理,使分散液浓度成为3000~1万/μl,将所得物设于上述分析装置,测定调色剂形状及分布。并且,基于该测定结果,将图4(A)所示的实际调色剂投影形状的外周长设为L1、将其投影面积设为S、将与该投影面积S相同的图4(B)所示的正圆的外周长设为L2时,求出L2/L1,将其平均值作为球度。The "sphericity" here is the average sphericity measured by a flow-type sample image resolution device FPIA-2000 (manufactured by Toa Medical Electronics Co., Ltd. (Toa Medical Electronics Co., Ltd.), trade name). Specifically, in the 100-150ml of water in the container from which impurities and solids have been removed in advance, a surfactant is added as a dispersant, preferably 0.1-0.5ml of alkylbenzene sulfonate, and another 0.1-0.5g left and right measurement samples (toner). Then, the toner-dispersed suspension was subjected to dispersion treatment for more than 1 to 3 minutes by an ultrasonic disperser to make the concentration of the dispersion liquid 3000 to 10,000/μl, and the resultant was set in the above-mentioned analyzer to measure the concentration of the toner. Toner shape and distribution. And, based on the measurement result, the outer circumference of the actual toner projected shape shown in FIG. When the outer circumference of the shown perfect circle is L2, L2/L1 is obtained, and the average value thereof is defined as the sphericity.

作为球形调色剂,可使用通过现在广泛使用的粉块法对形状歪斜的异形的调色剂(粉块调色剂)进行加热处理等而球形化的调色剂,和通过聚合法制造的调色剂等。As the spherical toner, a toner obtained by heat-treating a distorted irregular toner (powder toner) by the currently widely used powder agglomerate method, and a toner produced by a polymerization method can be used. Toner etc.

(清洁装置)(cleaning device)

例如图5所示,清洁装置16将作为刮板固定装置的刮板状的支承部件37的单面粘附在弹性清洁刮板38的基端,将其前端棱角线部38b按压在载像体10的周面。清洁刮板38例如使用JISA硬度从60度到80度的橡胶,使用在23℃使回复弹性小于或等于30%的材料。并且,制成沿载像体10的轴向细长的刮板状。清洁刮板38不限于上述形状,也可以例如图6所示,将支承部件37的前端部嵌合粘附在其基端台阶部上,形成具有突部40的形状,防止前端棱角线部38b按压在载像体10上时抵接在支承部件37而清洁刮板38向箭头方向脱离。For example, as shown in FIG. 5 , the cleaning device 16 adheres one side of a blade-shaped supporting member 37 as a blade fixing device to the base end of an elastic cleaning blade 38, and presses its front end corner portion 38b against the image carrier. 10 weeks. For the cleaning blade 38 , for example, rubber having a JISA hardness of 60 to 80 degrees and a material having a recovery elasticity of 30% or less at 23° C. is used. Furthermore, it is formed in the shape of a thin and long blade along the axial direction of the image carrier 10 . The cleaning scraper 38 is not limited to the above-mentioned shape, and can also, for example, as shown in FIG. 6 , fit and adhere the front end of the supporting member 37 on its base end step to form a shape with a protrusion 40 to prevent the front end corner portion 38b from When the image carrier 10 is pressed, it comes into contact with the support member 37 and the cleaning blade 38 is released in the direction of the arrow.

在此,清洁刮板38的形成前端棱角线部38b的角度θ,例如图7(A)所示,通过倾斜切割前端面38c的一部分而形成切割面38A,而形成钝角。另外,如图7(B)所示,也可以通过倾斜切割前端面38c的全部,将前端面38c整体作为切割面38A,将形成前端棱角线部38b的角度θ构成为钝角。钝角最好在95度~140度的范围。并且,清洁刮板38以等于或等于2.0MPa的面压将前端棱角线部38b按压在载像体10上。理想的是大于或等于3.0MPa。Here, the angle θ of the cleaning blade 38 forming the front end ridgeline portion 38b forms an obtuse angle by obliquely cutting a part of the front end surface 38c to form a cutting surface 38A as shown in FIG. 7(A), for example. In addition, as shown in FIG. 7(B), the entire front end surface 38c may be cut obliquely so that the entire front end surface 38c is a cut surface 38A, and the angle θ forming the front end ridgeline portion 38b may be formed as an obtuse angle. The obtuse angle is preferably in the range of 95 degrees to 140 degrees. And, the cleaning blade 38 presses the front end corner line portion 38 b against the image carrier 10 with a surface pressure equal to or equal to 2.0 MPa. Ideally, it is greater than or equal to 3.0 MPa.

以下详述清洁球形调色剂时所必须的面压。面压是将清洁刮板38按压在载像体10上时所施加的总荷重除以清洁刮板38和载像体10的接触面积而得的值。清洁刮板38和载像体10的接触面积可通过测定清洁刮板38按压在透明的模拟载像体上时的接触面积而容易求得。The surface pressure necessary for cleaning the spherical toner will be described in detail below. The surface pressure is a value obtained by dividing the total load applied when the cleaning blade 38 is pressed against the image carrier 10 by the contact area between the cleaning blade 38 and the image carrier 10 . The contact area between the cleaning blade 38 and the image carrier 10 can be easily obtained by measuring the contact area when the cleaning blade 38 is pressed against a transparent dummy image carrier.

以下实验是表示在施加有同一荷重(线压)时由于面压的不同而清洁性能不同的结果的实验,具体的是,在清洁刮板38上施加有一定荷重(线压)时,使接触面积变化,算出此时的面压,调整与清洁性能的关系。The following experiment is an experiment showing the results of different cleaning performances due to different surface pressures when the same load (linear pressure) is applied. Specifically, when a certain load (linear pressure) is applied to the cleaning blade 38, the contact Area change, calculate the surface pressure at this time, and adjust the relationship with the cleaning performance.

(实验:面压和清洁性能)(Experiment: Surface pressure and cleaning performance)

以下的表1是在清洁刮板上施加某一荷重时观察清洁刮板和载像体的接触面积算出面压的结果。具体的是,由于判定清洁刮板与载像体接触的主扫描方向的长度,由观察图像求出载像体和清洁刮板的接触宽度,用接触宽度除线压(g/cm)而得的值。Table 1 below shows the results of calculating the surface pressure by observing the contact area between the cleaning blade and the image carrier when a certain load was applied to the cleaning blade. Specifically, since the length in the main scanning direction in which the cleaning blade is in contact with the image carrier is determined, the contact width between the image carrier and the cleaning blade is obtained from the observed image, and the contact width is divided by the line pressure (g/cm). value.

在此,表1所示的清洁性能参考清洁后的载像体表面的剩余调色剂量而判定。表中的符号◎表示完全被清洁的情况,○表示残留有极少量调色剂的情况,△表示局部出现筋状的清洁不良的情况或整个面残留有一些调色剂的情况,×表示整个面残留有筋状或大量的调色剂的情况。Here, the cleaning performance shown in Table 1 was judged with reference to the remaining toner amount on the surface of the image bearing member after cleaning. The symbol ◎ in the table indicates the case of complete cleaning, ○ indicates the case where a very small amount of toner remains, △ indicates the case of partial streaky cleaning failure or the case where some toner remains on the entire surface, and × indicates the case of the entire surface. When there are streaks or a large amount of toner remaining on the surface.

  线压(N/cm)Line pressure (N/cm)  接触长度(μm)Contact length (μm)   面压(MPa)Surface pressure (MPa)   清洁性cleanliness   1.201.20   55   24.0024.00   △   1.201.20   1010   12.0012.00   ○   1.201.20   2020   6.006.00   ◎   1.201.20   3030   4.004.00   ◎   1.201.20   5050   2.402.40   ○   1.201.20   6060   2.002.00   ○   0.950.95   55   19.0019.00   △   0.950.95   1010   9.509.50   ○   0.950.95   2020   4.754.75   ◎   0.950.95   3030   3.173.17   ◎   0.950.95   5050   1.901.90   ××

  线压(N/cm)Line pressure (N/cm)  接触长度(μm)Contact length (μm)   面压(MPa)Surface pressure (MPa)   清洁性cleanliness   0.950.95   6060   1.581.58   ××   0.950.95   9090   1.061.06   ××   0.400.40   55   8.008.00   △   0.400.40   1010   4.004.00   ○   0.400.40   2020   2.002.00   ○   0.400.40   3030   1.331.33   ××   0.400.40   4040   1.001.00   ××   0.400.40   5050   0.800.80   ××   0.200.20   55   4.004.00   △   0.200.20   1010   2.002.00   △   0.200.20   2020   1.001.00   ××

在本实验中,使线压在0.2~1.2N/cm之间变动,使接触宽度在5~90μm之间变动。在将1.2N/cm的线压施加到刮板上时,在2.4~12.0MPa的面压之间能够得到良好的清洁性能(◎或○)。相反,在2.4MPa的面压下产生清洁不良。这是由于接触宽度为5μm这样窄,从载像体精度等考虑,主要在主扫描方向上产生接触不均,不能局部地施加充分的面压。另外,在刮板上施加0.95N/cm线压时,能够在3.17~9.50MPa的面压下得到良好的清洁性能,但在1.9MPa的面压下,由于接触宽度窄,为5μm,还是会因为接触不均而产生清洁不良。另外,在小于或等于1.9MPa的面压下产生清洁不良。In this experiment, the line pressure was varied between 0.2 and 1.2 N/cm, and the contact width was varied between 5 and 90 μm. When a linear pressure of 1.2 N/cm is applied to the blade, good cleaning performance (⊚ or ○) can be obtained between a surface pressure of 2.4 to 12.0 MPa. On the contrary, poor cleaning occurred at a surface pressure of 2.4 MPa. This is because the contact width is as narrow as 5 μm, and contact unevenness occurs mainly in the main scanning direction in view of the accuracy of the image carrier, and sufficient surface pressure cannot be applied locally. In addition, when a line pressure of 0.95N/cm is applied to the scraper, good cleaning performance can be obtained under a surface pressure of 3.17-9.50MPa, but under a surface pressure of 1.9MPa, due to the narrow contact width of 5μm, it will still Poor cleaning due to uneven contact. In addition, poor cleaning occurs at a surface pressure of 1.9 MPa or less.

另外,在线压为0.4N/cm时,在2.0~4.0MPa的面压下能够得到良好的清洁性能,但是在8.0MPa的面压(接触不均)、小于或等于1.33MPa的面压下,产生清洁不良。In addition, when the line pressure is 0.4N/cm, good cleaning performance can be obtained under the surface pressure of 2.0-4.0MPa, but under the surface pressure (non-uniform contact) of 8.0MPa and the surface pressure less than or equal to 1.33MPa, Poor cleaning occurs.

由以上结果可以判定,即使施加相同线压,也由于根据清洁刮板和载像体的接触状态(接触面积),每单位面积的荷重即面压(MPa)不同,而当将线压设定高时,若面压低,则不能清洁球形调色剂。From the above results, it can be judged that even if the same linear pressure is applied, the load per unit area, that is, the surface pressure (MPa) is different according to the contact state (contact area) between the cleaning blade and the image carrier, and when the linear pressure is set When it is high, the spherical toner cannot be cleaned if the surface pressure is low.

另外,由表1的结果,通过将面压设定成大于或等于2.0MPa,能够清洁球形调色剂,但是接触宽度为10μm左右时,或者面压为2.0MPa左右时,调色剂残留很少(○),而不能成为完全清洁。这是因为,接触面积越小,越能够施加高面压,但刮板和载像体的接触宽度过窄时,由于与载像体的接触不均和载像体表面的损伤、突起物等原因而易引起清洁不良。为了清洁球调色剂,如图5及图6所示,理想的是将面压设定成大于或等于2.0MPa,最好大于或等于3.0MPa,将接触宽度设定成大于或等于10μm。In addition, from the results in Table 1, by setting the surface pressure to be greater than or equal to 2.0 MPa, the spherical toner can be cleaned, but when the contact width is about 10 μm, or when the surface pressure is about 2.0 MPa, the toner remains Less (○), and can not be completely clean. This is because the smaller the contact area, the more high surface pressure can be applied, but when the contact width between the scraper and the image carrier is too narrow, due to uneven contact with the image carrier and damage to the surface of the image carrier, protrusions, etc. It is easy to cause poor cleaning. In order to clean the toner balls, as shown in FIGS. 5 and 6, it is desirable to set the surface pressure to 2.0 MPa or more, preferably 3.0 MPa or more, and set the contact width to 10 μm or more.

如上所述,为了清洁球形调色剂,需要将刮板和载像体的接触宽度设定成大于或等于10μm,将面压设定成大于或等于2.0MPa,最好大于或等于3.0MPa。在此,为了抑制载像体的膜剥落、载像体驱动转矩的增加、刮板磨损等,理想的是,将接触宽度设为大于或等于10μm小于或等于40μm,最好小于或等于30μm。其原因是,即使在刮板和载像体的接触宽度非常大的情况下(例如接触宽度100μm),若面压大于或等于2.0MPa或大于或等于3.0MPa,则也阻止球形调色剂的侵入而清洁。但是,例如在接触宽度为100μm时,为了将面压形成为2.0MPa,必须施加2.0N/cm的线压,需要非常大的线压。为了清洁球形调色剂,必须尽量减小刮板和载像体的接触面积,尽量利用小的线压而施加高的面压。为了阻止球形调色剂的侵入,也考虑载像体的精度和调色剂粒径,最好将载像体和刮板的接触宽度设为大于或等于10μm,但上限值通过设定成小于或等于40μm,最好小于或等于30μm,而能够将为使面压大于或等于2.0MPa或大于或等于3.0MPa而施加的线压设定在0.2~1.2N/cm之间。最好是将线压设定成小于或等于0.9N/cm。As described above, in order to clean the spherical toner, it is necessary to set the contact width between the blade and the image carrier to be 10 μm or more and the surface pressure to be 2.0 MPa or more, preferably 3.0 MPa or more. Here, in order to suppress film peeling of the image carrier, an increase in the driving torque of the image carrier, blade wear, etc., it is desirable to set the contact width to be 10 μm or more and 40 μm or less, preferably 30 μm or less . The reason is that even when the contact width between the blade and the image carrier is very large (for example, a contact width of 100 μm), if the surface pressure is greater than or equal to 2.0 MPa or greater than or equal to 3.0 MPa, the formation of the spherical toner is prevented. Invasive and clean. However, for example, when the contact width is 100 μm, in order to set the surface pressure to 2.0 MPa, it is necessary to apply a linear pressure of 2.0 N/cm, which requires a very large linear pressure. In order to clean the spherical toner, it is necessary to minimize the contact area between the blade and the image carrier, and to apply a high surface pressure with a small linear pressure as much as possible. In order to prevent the intrusion of the spherical toner, the precision of the image carrier and the particle size of the toner are also taken into consideration. It is preferable to set the contact width between the image carrier and the scraper to be greater than or equal to 10 μm, but the upper limit value is set to It is less than or equal to 40 μm, preferably less than or equal to 30 μm, and the linear pressure applied to make the surface pressure greater than or equal to 2.0 MPa or greater than or equal to 3.0 MPa can be set between 0.2 and 1.2 N/cm. It is best to set the line pressure to be less than or equal to 0.9N/cm.

接下来说明通过将清洁刮板38的前端形成为钝角,与刮板前端为90度的情况相比,线压小且能够施加用于阻止球形调色剂侵入的面压。Next, it will be described that by forming the front end of the cleaning blade 38 at an obtuse angle, compared with the case where the front end of the blade is 90 degrees, the linear pressure is smaller and the surface pressure for preventing the entry of the spherical toner can be applied.

如上所述,为了清洁球形调色剂,需要以大于或等于2.0MPa的面压将刮板抵接在载像体上,但是在施加相同面压的情况下,由于刮板的形状而施加在刮板整体上的荷重(线压)不同。由于线压对载像体驱动转矩的大小、载像体10的寿命以及清洁刮板38的磨损影响很大,而要尽量减小线压。As mentioned above, in order to clean the spherical toner, it is necessary to abut the blade against the image carrier with a surface pressure of 2.0 MPa or more, but when the same surface pressure is applied, due to the shape of the blade, the The load (line pressure) of the entire scraper is different. Since the linear pressure has a great influence on the size of the driving torque of the image carrier, the life of the image carrier 10 and the wear of the cleaning blade 38, the linear pressure should be reduced as much as possible.

为于清洁球形调色剂,可以施加与用于清洁现有粉块调色剂的线压相比大的线压,故目前为止考虑清洁刮板的材质,另外,研究了消除支承部件前端的清洁刮板的压曲而能够施加高线压的刮板形状。In order to clean the spherical toner, it is possible to apply a larger linear pressure than that used to clean the conventional powder block toner. Therefore, the material of the cleaning blade has been considered, and the elimination of the front end of the support member has been studied. Squeegee shape that can apply high linear pressure due to buckling of the cleaning blade.

但是,如上所述,调色剂去除性能不由线压而是由面压决定。因此,关于能够清洁球形调色剂而必须的2.0MPa的面压以更低的线压施加的刮板形状进行了研究。其结果,通过将清洁刮板38压接在载像体10上的前端棱角线部38b加工成钝角,与将前端棱角线部38b形成90度的情况相比,能够以低线压施加可清洁球形调色剂的面压。即,通过将前端棱角线部38b加工成钝角,在施加相同荷重时,与前端棱角线部38b为90度的情况相比,刮板切割面的翘曲减少,接触面积减小,故能够提高并单位面积上的阻力即面压。However, as described above, the toner removal performance is determined not by the line pressure but by the surface pressure. Therefore, studies have been made on a blade shape in which a surface pressure of 2.0 MPa necessary to clean a spherical toner is applied with a lower linear pressure. As a result, by processing the front end corner portion 38b of the cleaning blade 38 in pressure contact with the image carrier 10 into an obtuse angle, compared with the case where the front end corner portion 38b is formed at 90 degrees, it is possible to apply a lower line pressure and clean it. Surface pressure of spherical toner. That is, by processing the front end corner portion 38b into an obtuse angle, when the same load is applied, compared with the case where the front end corner portion 38b is 90 degrees, the warpage of the cut surface of the blade is reduced, and the contact area is reduced, so it is possible to improve And the resistance per unit area is the surface pressure.

下面,关于图8(A)所示的前端阻力集中形状的清洁刮板A、将抵接在载像体上的前端棱角线部切割成钝角的图6所示相同的图8(B)所示的前端阻力集中形状的钝角清洁刮板B以及(C)所示的现有粉块调色剂用的清洁刮板C这三种,说明线压和接触宽度、线压和面压的关系。Next, regarding the cleaning blade A of the front end resistance-concentrated shape shown in FIG. Three types of obtuse-angle cleaning blade B with the tip resistance concentrated shape shown in (C) and conventional powder block toner cleaning blade C shown in (C) explain the relationship between line pressure and contact width, and line pressure and surface pressure. .

首先说明比较线压和接触宽度的刮板A、B、C的刮板形状。刮板C粘贴在支承部件37的单侧,厚度为2mm,从支承部件37的前端到刮板前端的自由长度为7mm,JISA硬度为70度。First, the shape of the squeegee A, B, and C for comparing the linear pressure and the contact width will be described. The squeegee C is attached to one side of the support member 37 with a thickness of 2 mm, a free length from the tip of the support member 37 to the tip of the squeegee 7 mm, and a JISA hardness of 70 degrees.

接下来说明前端阻力集中形状的刮板A和钝角刮板B。首先,在刮板A和刮板B形成共通的形状,为了在刮板前端有效地施加高面压而构成防止成为面压降低原因的腹接触。即,如图8(A)和(B)所示,刮板A和刮板B紧密接合在支承部件37上并形成突部40,防止将前端棱角线部38b按压在载像体上时与支承部件37抵接而清洁刮板逃脱。即,为形成大致凸形状而由大致中央部的壁厚部和两端的壁薄部构成,通过使壁厚部和壁薄部的台阶部与支承部件37紧密接合而被支承。通过如此形成刮板的形状,能够防止支承部件37的前端部的刮板的压曲,故抑制清洁刮板对载像体的腹接触,能够使荷重集中在刮板前端。Next, the scraper A and the obtuse-angled scraper B of the front-end resistance-concentrated shape will be described. First, the squeegee A and the squeegee B have a common shape to effectively apply a high surface pressure to the tip of the squeegee to prevent belly contact that causes a drop in surface pressure. That is, as shown in FIGS. 8(A) and (B), the scraper A and the scraper B are tightly bonded to the supporting member 37 to form a protrusion 40, which prevents contact with the front edge corner line portion 38b when it is pressed against the image carrier. The support member 37 abuts and the cleaning blade escapes. That is, to form a substantially convex shape, it is composed of a thicker portion at the center and thinner portions at both ends, and is supported by making the stepped portions of the thicker portion and the thinner portion tightly bonded to the support member 37 . By forming the shape of the blade in this way, buckling of the blade at the front end of the support member 37 can be prevented, so that the cleaning blade is prevented from coming into contact with the abdomen of the image carrier, and the load can be concentrated on the blade tip.

具体的是,刮板A及刮板B的刮板形状为,t1=1.7mm,t2=3.5mm,t3=7mm,t4=11mm,L=3.8mm,d=1.2mm,支承部件37的厚度T=1.6mm,JISA硬度为70度。Specifically, the scraper shapes of scraper A and scraper B are t1=1.7mm, t2=3.5mm, t3=7mm, t4=11mm, L=3.8mm, d=1.2mm, and the thickness of the supporting member 37 is T=1.6mm, JISA hardness is 70 degrees.

并且,在钝角刮板B的情况下,在上述结构的基础上,与图7(A)同样,具有将刮板压接在载像体上的前端棱角线部38b切割成钝角的形状。具体的是,如图8(D)所示,通过将长度方向切割成100μm,将厚度方向切割成200μm,将形成前端棱角线部38b的角度θ构成为钝角。In addition, in the case of the obtuse-angled blade B, in addition to the above-mentioned structure, it has a shape in which the front edge portion 38b of the blade is cut into an obtuse angle as in FIG. 7(A). Specifically, as shown in FIG. 8(D), by cutting 100 μm in the longitudinal direction and 200 μm in the thickness direction, the angle θ forming the front end ridge line portion 38 b is formed as an obtuse angle.

图9表示上述三种刮板A、B、C的线压和接触宽度的关系,图10表示上述三种刮板A、B、C的线压和面压的关系。FIG. 9 shows the relationship between the linear pressure and the contact width of the above three scrapers A, B, and C, and FIG. 10 shows the relationship between the linear pressure and the surface pressure of the above three scrapers A, B, and C.

如图9所示,在施加有一定的线压的情况下,比较三种刮板A、B、C的接触宽度,则刮板C与其他两种前端阻力集中形状的刮板A、B相比,由于构成腹接触,故接触宽度增大。另一方面,比较两种前端阻力集中形状的刮板A、B抵接在载像体上时的接触宽度,则将刮板前端切割成钝角的刮板B与无加工的刮板A相比,接触宽度更小,在施加有相同线压的情况下面压也容易增高。As shown in Figure 9, when a certain linear pressure is applied, comparing the contact widths of the three types of scrapers A, B, and C, the scraper C is comparable to the other two types of scrapers A, B with the front-end resistance concentration shape. Compared with that, due to the formation of abdominal contact, the contact width increases. On the other hand, when comparing the contact widths of the squeegee A and B with two kinds of front-end resistance-concentrated shapes abutting against the image carrier, the squeegee B with the front end of the squeegee cut at an obtuse angle is compared with the squeegee A without processing. , the contact width is smaller, and the lower pressure is easy to increase under the same line pressure.

图10是曲线表示各刮板A、B、C的线压和面压(从图9来看,除线压以接触宽度而求得)的关系。Fig. 10 is a graph showing the relationship between the linear pressure and the surface pressure (obtained from Fig. 9 except for the linear pressure and the contact width) of the respective scrapers A, B, and C.

在现有的粉块调色剂用的刮板C中,增大刮板压附在载像体上的位移量d,线压增高的情况下,仅增大接触面积,面压不能充分增大,产生清洁不良。另一方面,前端阻力集中形状的刮板A、B中,增大位移量d时,也是由于腹接触而接触宽度不增大,故能够赋予清洁球形调色剂所必须的面压。在此,清洁球形调色剂所必须的面压,如前所述,大于或等于2.0MPa,最好大于或等于3.0MPa。In the conventional scraper C for powder block toner, increasing the displacement d of the scraper against the image carrier and increasing the line pressure only increases the contact area, but the surface pressure cannot be sufficiently increased. Large, resulting in poor cleaning. On the other hand, when the displacement amount d is increased for the blades A and B having the shape where the resistance is concentrated at the front end, the contact width does not increase due to the belly contact, so the surface pressure necessary for cleaning the spherical toner can be applied. Here, the surface pressure necessary to clean the spherical toner is, as described above, equal to or greater than 2.0 MPa, preferably equal to or greater than 3.0 MPa.

另外,比较刮板A、B,将刮板前端加工成钝角的刮板B能够以与刮板A相比小的线压来施加高的面压。In addition, comparing the squeegee A and B, the squeegee B having the tip of the squeegee processed into an obtuse angle can apply a high surface pressure with a lower linear pressure than the squeegee A.

在刮板A中,为了施加清洁载像体上的调色剂(○)所必须的最低面压2.0MPa,需要施加线压约0.2N/cm,为了形成能够完全清洁(◎)的面压3.0MPa,需要施加线压约0.3N/cm。另一方面,在刮板B中,为了施加面压2.0MPa而需要施加线压约0.4N/cm,为了施加面压3.00MPa而需要施加线压约0.6~0.8N/cm。这样,通过将刮板前端加工成钝角,能够以更小的线压施加大的面压。例如,能够将为使可完全清洁调色剂的面压为3.0MPa而施加的线压设定小,大约为0.3~0.5N/cm。In the scraper A, in order to apply the minimum surface pressure of 2.0MPa necessary to clean the toner on the image carrier (○), it is necessary to apply a linear pressure of about 0.2N/cm, in order to form a surface pressure that can be completely cleaned (◎) 3.0MPa, need to apply a line pressure of about 0.3N/cm. On the other hand, in the squeegee B, it is necessary to apply a linear pressure of approximately 0.4 N/cm to apply a surface pressure of 2.0 MPa, and to apply a linear pressure of approximately 0.6 to 0.8 N/cm to apply a surface pressure of 3.00 MPa. In this way, by processing the tip of the blade into an obtuse angle, it is possible to apply a large surface pressure with a smaller linear pressure. For example, the linear pressure to be applied so that the surface pressure of the completely cleanable toner is 3.0 MPa can be set as low as about 0.3 to 0.5 N/cm.

这样,通过将刮板前端加工成钝角,与前端90度的情况相比,能够减小片和载像体的接触面积。图9、10所示的结果中,仅将刮板B的前端部分切割成100μm×200μm(角度大于115度),形成钝角。即,如图7(A)、(B)所示,若将切割面整体切割成钝角,则接触宽度与90度的情况相比能够变窄。在此,所谓钝角是指大于90度的角度,大于或等于95度且小于或等于140度。若是前端角度近似90度的值,则不能发挥钝角带来的降低接触面积的效果。另外,清洁刮板将图5及图6所示的初始接触角度β设定在15度~30度之间而组装到装置中。因此,在将前端角度设为140度,将初始接触角度设为30度时,切割面和刮板构成的角度成为10度。该角度成为小的值,则在楔部分堆积调色剂,由于实质上刮板和载像体的接触面积增加,故面压降低,其结果会产生清洁不良。In this way, by forming the front end of the squeegee at an obtuse angle, it is possible to reduce the contact area between the sheet and the image carrier compared to the case where the front end is 90 degrees. In the results shown in FIGS. 9 and 10 , only the front end portion of the squeegee B was cut into 100 μm×200 μm (the angle is greater than 115 degrees), forming an obtuse angle. That is, as shown in FIG. 7(A) and (B), if the entire cut surface is cut at an obtuse angle, the contact width can be narrowed compared to the case of 90 degrees. Here, the so-called obtuse angle refers to an angle greater than 90 degrees, greater than or equal to 95 degrees and less than or equal to 140 degrees. If the tip angle is close to 90 degrees, the effect of reducing the contact area due to the obtuse angle cannot be exerted. In addition, the cleaning blade was incorporated into the device by setting the initial contact angle β shown in FIGS. 5 and 6 to be between 15 degrees and 30 degrees. Therefore, when the tip angle is 140 degrees and the initial contact angle is 30 degrees, the angle formed by the cutting surface and the scraper is 10 degrees. If the angle is small, the toner accumulates on the wedge portion, and since the contact area between the blade and the image carrier substantially increases, the surface pressure decreases, resulting in poor cleaning.

图11表示图5所示的清洁刮板的具体例。在该例中,将清洁刮板38形成长条形状,在自由长度t3和厚度t1之间形成满足1.75≤t3/t1≤3的关系的形状。这样,能够防止支承部件37的前端部的清洁刮板38的压曲。FIG. 11 shows a specific example of the cleaning blade shown in FIG. 5 . In this example, the cleaning blade 38 is formed in an elongated shape, and has a shape satisfying the relationship of 1.75≦t3/t1≦3 between the free length t3 and the thickness t1. In this way, buckling of the cleaning blade 38 at the front end portion of the support member 37 can be prevented.

另外,粉块调色剂清洁用的刮板的形状例如为自由长度t3=8mm,厚度t1=2mm(t3/t1=4),由于压曲而腹接触,不能施加清洁球形调色剂所需要的面压,但通过设定满足上述关系式的形状,则能够抑制支承部件37的前端部的清洁刮板38的压曲。In addition, the shape of the scraper for cleaning powder lump toner is, for example, free length t3 = 8 mm, thickness t1 = 2 mm (t3 / t1 = 4), due to buckling and abdominal contact, it is impossible to apply the cleaning required for spherical toner. However, by setting a shape that satisfies the above relational expression, buckling of the cleaning blade 38 at the front end portion of the support member 37 can be suppressed.

在此,在图11所示的比以往的量厚的长条形状中,在将形成片的前端棱角线部38b的角度θ构成钝角时,同样减小片和载像体的接触面积,与形成片的前端棱角线部38b的角度为90度的情况相比,能够以更低的线压施加可清洁球形调色剂的面压。Here, in the elongated shape shown in FIG. 11 that is thicker than the conventional amount, when the angle θ forming the front end corner portion 38b of the sheet is formed as an obtuse angle, the contact area between the sheet and the image carrier is similarly reduced, and the contact area with the image carrier is reduced. Compared with the case where the angle of the leading edge corner line portion 38b of the forming sheet is 90 degrees, the surface pressure for cleaning the spherical toner can be applied with a lower linear pressure.

以下,表示刮板前端部为90度的刮板D(图12(A))和将前端部加工成钝角(100μm×200μm)的刮板E(图12(B))的线压和面压的关系。在此,钝角加工前的刮板形状形成比通常厚,t1=3.6mm,t3=7mm(t3/t1≈1.95)的长条刮板状。The following shows the linear pressure and surface pressure of the squeegee D (Fig. 12(A)) with the tip of the squeegee at 90 degrees and the squeegee E (Fig. 12(B)) with the tip processed into an obtuse angle (100μm×200μm) Relationship. Here, the shape of the blade before the obtuse processing is thicker than usual, and is a long blade shape with t1=3.6mm and t3=7mm (t3/t1≈1.95).

图8(C)所示的刮板C不能附加清洁球形调色剂所必须的面压,但在刮板D、E中,能够施加清洁球形调色剂所必须的面压2.0MPa、3.0MPa。另外,清洁刮板E通过将形成刮板的前端棱角线部38b的角度θ构成为钝角,与刮板D相比,即使以小线压也能够施加清洁球形调色剂所必须的面压。The blade C shown in FIG. 8(C) cannot apply the surface pressure necessary for cleaning the spherical toner, but the blades D and E can apply the surface pressure of 2.0 MPa and 3.0 MPa necessary for cleaning the spherical toner. . In addition, the cleaning blade E can apply the surface pressure necessary for cleaning spherical toner even with a lower line pressure than the blade D by making the angle θ forming the front end ridge line portion 38b of the blade an obtuse angle.

如图7(A)、(B)所示,图12(B)所示的刮板E无论是切割片的前端面整体,还是切割一部分,都能够得到同样的效果。As shown in FIGS. 7(A) and (B), the same effect can be obtained regardless of whether the scraper E shown in FIG. 12(B) cuts the entire front end surface of the cutting sheet or cuts a part thereof.

另外,本发明的刮板的橡胶硬度,如前所述,在JISA硬度下在60~80度之间便可。在将硬度形成为小于或等于60度的情况下,产生支承部件的前端部的片的压曲,不能赋予充分的面压。相反,在橡胶硬度过高时,与载像体的密合性变差,产生不能局部施加充分的面压的位置,具有清洁不良的情况。In addition, the rubber hardness of the squeegee of the present invention may be between 60 and 80 degrees in JISA hardness as described above. When the hardness is set to be 60 degrees or less, buckling of the sheet at the tip of the supporting member occurs, and sufficient surface pressure cannot be applied. Conversely, when the rubber hardness is too high, the adhesiveness to the image carrier deteriorates, and a location where sufficient surface pressure cannot be applied locally occurs, resulting in poor cleaning.

接下来说明使用了加强部件的刮板支承结构。Next, the blade support structure using a reinforcing member will be described.

图13(A)是设置与厚度2mm的支承部件37相同厚度的清洁刮板38,并将该刮板粘附在加强部件41而将刮板的自由长度形成为3mm。作为加强部件41设置与支承部件37相同的金属材料。自由长度可以适当选择,不限于上述长度。另外,加强部件41所使用的材料也不限于上述材料,最好使用大于或等于片的硬度的材料。FIG. 13(A) provides a cleaning blade 38 having the same thickness as a supporting member 37 having a thickness of 2 mm, and attaches the blade to a reinforcing member 41 to form a free length of the blade to 3 mm. The same metal material as the supporting member 37 is provided as the reinforcing member 41 . The free length can be appropriately selected and is not limited to the above-mentioned length. In addition, the material used for the reinforcing member 41 is not limited to the above-mentioned materials, and it is preferable to use a material having a hardness greater than or equal to that of the sheet.

另外,图13(B)中将比厚度2mm的支承部件37薄的加强部件41粘附在刮板38上。在图13(B)中,直到刮板38的最前端未粘附加强部件41,但不限于此,可以将加强部件41的长度任意设定。In addition, in FIG. 13(B), a reinforcing member 41 thinner than the supporting member 37 having a thickness of 2 mm is attached to the scraper 38 . In FIG. 13(B), the reinforcing member 41 is not attached up to the front end of the scraper 38, but the present invention is not limited thereto, and the length of the reinforcing member 41 can be set arbitrarily.

下面说明清洁刮板38的回复弹性。Next, the resilience of the cleaning blade 38 will be described.

在本发明中,将使用于清洁刮板38的弹性材料的回复弹性设定为23℃小于或等于30%。作为将回复弹性设定为小于或等于30%的理由如下两方面。一,为了清洁球形调色剂而刮板前端的振动少的清洁刮板为好。二,相对刮板的磨损,回复弹性低的清洁刮板为好。In the present invention, the recovery elasticity of the elastic material used for the cleaning blade 38 is set to be 30% or less at 23°C. The reasons for setting the resilience to 30% or less are as follows. First, in order to clean the spherical toner, a cleaning blade with less vibration at the tip of the blade is preferable. Second, relative to the wear of the scraper, it is better to clean the scraper with low resilience.

以往,在清洁粉块调色剂时,刮板具有使接触到刮板前端的调色剂弹飞的作用,故在回复弹性率低的情况下,存在弹飞效果不能充分发挥的问题。但是,在球形调色剂的情况下,在调色剂弹回之前,由于使刮板滑脱,而弹飞效果不发挥作用。在回复弹性高,刮板前端相对载像体易微小振动时,反而助长球形调色剂的滑脱。In the past, when cleaning powdery toner, the scraper has the function of bouncing the toner that comes into contact with the front end of the scraper. Therefore, when the elastic modulus of recovery is low, there is a problem that the bouncing effect cannot be fully exerted. However, in the case of a spherical toner, the flying effect does not work because the blade slips off until the toner bounces back. When the recovery elasticity is high, when the front end of the scraper is easy to slightly vibrate relative to the image carrier, the sliding of the spherical toner is promoted instead.

另一方面,回复弹性低的,针对刮板的磨损是有利的。即,在反复成像的过程中,清洁刮板通过与载像体的滑动摩擦而渐渐磨损。刮板磨损发生机构要考虑刮板自身的粘滑运动的结果,构成刮板的高分子(例如聚氨酯橡胶)扯裂,疲劳破损的结果,产生磨损。在这样的情况下,刮板前端部被扯碎,由此产生清洁不良。On the other hand, low resilience is advantageous against scraper wear. That is, during repeated image formation, the cleaning blade is gradually worn by sliding friction with the image carrier. The scraper wear generation mechanism should consider the result of the stick-slip motion of the scraper itself, the tearing of the polymer (such as urethane rubber) constituting the scraper, and the result of fatigue damage to generate wear. In such a case, the front end portion of the blade is torn to pieces, thereby causing poor cleaning.

在回复弹性降低的情况下,由于抑制刮板自身的粘滑运动,即使经过了反复的成像工序,刮板前端部分的累积振动次数也比高回复弹性刮板小,疲劳破损也能够抑制。其结果,经过了反复的成像工序,也不出现刮板磨损,能够长期良好地维持清洁性能。In the case of reduced resilience, since the stick-slip motion of the squeegee itself is suppressed, even after repeated imaging processes, the accumulated vibration frequency of the front end of the squeegee is smaller than that of a squeegee with high resilience, and fatigue damage can be suppressed. As a result, the blade is not worn even through repeated image forming steps, and the cleaning performance can be maintained favorably over a long period of time.

由于以上两个理由,需要将回复弹性设定成23℃小于或等于30%。For the above two reasons, it is necessary to set the recovery elasticity to be 30% or less at 23°C.

在本发明中,为了清洁球形调色剂,承受高的荷重而将清洁刮板38压接在载像体10上。由此,刮板磨损及载像体的膜剥落变大。在此,通过在载像体10表面涂敷润滑剂,从而能够抑制刮板38的磨损、载像体10的膜剥落。另外,通过上述使用了放电的带电装置11而使载像体10带电时,通过放电渐渐使载像体10表面改性,提高表面能量。这时,由于易产生球形调色剂的清洁不良,故通过涂敷润滑材料来抑制载像体10表面的改性,从而能够长时间维持球形调色剂的清洁性能。因此,在本发明的图像形成装置上也可以具有在载像体10上涂敷润滑剂的润滑剂涂敷装置。In the present invention, in order to clean the spherical toner, the cleaning blade 38 is pressed against the image carrier 10 under a high load. Accordingly, abrasion of the blade and film peeling of the image carrier increase. Here, by applying a lubricant to the surface of the image carrier 10 , abrasion of the blade 38 and peeling of the film of the image carrier 10 can be suppressed. In addition, when the image carrier 10 is charged by the above-mentioned charging device 11 using discharge, the surface of the image carrier 10 is gradually modified by the discharge to increase the surface energy. At this time, since the cleaning failure of the spherical toner tends to occur, the modification of the surface of the image carrier 10 is suppressed by applying a lubricating material, so that the cleaning performance of the spherical toner can be maintained for a long time. Therefore, the image forming apparatus of the present invention may also include a lubricant application device for applying lubricant to the image carrier 10 .

图14表示润滑剂的一例。图14所示的润滑剂涂敷装置42将润滑剂43成型为固状,用加压弹簧44按压在毛刷45,旋转毛刷45而涂敷在载像体10表面上。另外,还有将粉末状的润滑剂的蓄溜剂与载像体表面相对配置而向载像体供给的方法。图14中,润滑材料的涂敷位置相对于载像体10的移动方向为清洁刮板38的上游侧。此时,具有与被刮板38去除的调色剂一同将润滑材料去除的情况,有不能在载像体10表面均匀地形成润滑材料膜的情况。Fig. 14 shows an example of a lubricant. The lubricant application device 42 shown in FIG. 14 molds the lubricant 43 into a solid shape, presses the lubricant 43 against the brush 45 by the pressure spring 44, and rotates the brush 45 to apply the lubricant 43 on the surface of the image carrier 10 . In addition, there is also a method of supplying a powdery lubricant accumulator to the image carrier by arranging it to face the surface of the image carrier. In FIG. 14 , the position where the lubricating material is applied is on the upstream side of the cleaning blade 38 with respect to the moving direction of the image carrier 10 . At this time, the lubricating material may be removed together with the toner removed by the scraper 38 , and a lubricating material film may not be uniformly formed on the surface of the image carrier 10 .

如图15所示,在清洁刮板38的下游、带电装置11的上游配置润滑剂涂敷装置42,由该润滑剂涂敷装置42涂敷润滑剂,则由于在调色剂去除后的载像体10表面涂敷润滑剂,故能够均匀地涂敷。另外,理想的是,如图所示,在润滑材料涂敷装置42的下游配置用于拉伸涂敷在载像体10表面的润滑材料的拉伸部件46。作为拉伸部件46,能够以适当的压力将聚氨酯橡胶刮板等的弹性体及弹性辊等抵接在载像体10即可。As shown in FIG. 15, a lubricant application device 42 is arranged downstream of the cleaning blade 38 and upstream of the charging device 11. The lubricant is applied by the lubricant application device 42. Since the lubricant is coated on the surface of the image body 10, it can be evenly coated. In addition, preferably, as shown in the figure, a stretching member 46 for stretching the lubricating material coated on the surface of the image bearing member 10 is disposed downstream of the lubricating material applying device 42 . As the stretching member 46 , an elastic body such as a urethane rubber blade, an elastic roller, or the like may be brought into contact with the image carrier 10 with an appropriate pressure.

作为润滑材料43,采用硬脂酸锌等刮板状结晶粉末是优选的。刮板状结晶具有两亲溶剂性分子自组织化层状结构,当施加剪断力时,在层间结晶被破坏而容易滑动。该作用对降低摩擦系数有效。润滑材料43,除上述以外,还可以使用各种脂肪酸盐、蜡、硅油等其他物质。As the lubricating material 43, it is preferable to use scraper-like crystalline powder such as zinc stearate. Scraper-like crystals have a self-organized layered structure of amphiphilic solvate molecules, and when a shear force is applied, the crystals are broken and easily slide between layers. This action is effective in reducing the coefficient of friction. As the lubricating material 43, other substances such as various fatty acid salts, waxes, and silicone oils may be used in addition to the above.

作为脂肪酸,可以举出十一烷酸、十二烷酸、十三烷酸、十四烷酸、十六烷酸、十五烷酸、十八烷酸、十七烷酸、花生酸、油酸、花生油烯酸、辛酸、癸酸、己酸等,作为其金属盐,可以举出锌、铁、镁、铝、钙等金属的盐。Examples of fatty acids include undecanoic acid, dodecanoic acid, tridecanoic acid, myristic acid, hexadecanoic acid, pentadecanoic acid, octadecanoic acid, heptadecanoic acid, arachidic acid, oil acid, arachidic acid, caprylic acid, capric acid, caproic acid, etc., and examples of the metal salt thereof include salts of metals such as zinc, iron, magnesium, aluminum, and calcium.

接下来说明将具有钝角形状的清洁刮板38的前端棱角线部38b低摩擦系数化的情况。Next, the case where the coefficient of friction of the front end corner line portion 38b of the cleaning blade 38 having an obtuse angle shape is reduced will be described.

具体的是,如图16(A)所示,由支承部件37支承弹性橡胶制的清洁刮板38。清洁刮板38,为不产生压曲而以3.6mm的厚度将刮板下面的自由长度设为7mm,刮板上面的自由长度设为8.8mm,将构成刮板下面和前端面的前端棱角线部38b的角度θ形成钝角形状。通过形成这样的刮板形状,如上所述,适当地设定清洁刮板38和载像体10的接触宽度,确保清洁球形调色剂所必须的2.0~3.0MPa的面压。Specifically, as shown in FIG. 16(A), a cleaning blade 38 made of elastic rubber is supported by a support member 37 . To clean the scraper 38, set the free length of the bottom of the scraper to 7mm and the free length of the top of the scraper to 8.8mm with a thickness of 3.6mm in order not to buckle. The angle θ of the portion 38b forms an obtuse angle shape. By forming such a blade shape, as described above, the contact width between the cleaning blade 38 and the image carrier 10 is appropriately set to ensure a surface pressure of 2.0 to 3.0 MPa necessary for cleaning spherical toner.

清洁刮板38将按压在作为被清洁部件的载像体10上的前端棱角线部38b低摩擦系数化,降低与载像体10之间的摩擦系数。具体的是,可以如图16(B)所示在清洁刮板38的表面实施用于低摩擦系数化的涂层p,但是更好地,图示省略,清洁刮板38用氟含浸而低摩擦系数化,这能够将氟浸入到刮板内而时效(经时)地维持低摩擦系数化的效果。The cleaning blade 38 lowers the coefficient of friction of the leading edge portion 38 b pressed against the image carrier 10 as a member to be cleaned, thereby reducing the friction coefficient with the image carrier 10 . Specifically, as shown in FIG. 16(B), a coating p for lowering the coefficient of friction can be implemented on the surface of the cleaning blade 38, but it is preferable that the cleaning blade 38 is impregnated with fluorine to reduce the friction coefficient. The coefficient of friction can be reduced by impregnating fluorine into the blade to maintain the effect of reducing the coefficient of friction over time.

如下说明清洁刮板38前端的低摩擦系数化处理的效果。The effect of the treatment for reducing the coefficient of friction at the tip of the cleaning blade 38 will be described below.

一般,将把清洁刮板38按压在载像体10上的线压设为f(N/cm),将清洁刮板38长度方向的宽度设为L(cm),则将清洁刮板38按压在载像体10上的总荷重N=f×L(g)。此时,在清洁刮板38和载像体10之间的摩擦系数设为μ,则在清洁刮板38和载像体10之间作用的摩擦力F=μN。Generally, the linear pressure that the cleaning blade 38 is pressed on the image carrier 10 is set as f (N/cm), and the width of the cleaning blade 38 in the longitudinal direction is set as L (cm), then the cleaning blade 38 is pressed The total load N=f×L(g) on the image bearing body 10 . At this time, if the coefficient of friction between the cleaning blade 38 and the image bearing body 10 is set to μ, then the frictional force F=μN acting between the cleaning blade 38 and the image bearing body 10 .

在此,由于载像体10和清洁刮板38的滑动摩擦而产生的转矩T,使用载像体10的半径r而由Here, the torque T generated due to the sliding friction between the image carrier 10 and the cleaning blade 38 is given by using the radius r of the image carrier 10

T=r×F=r×μNT=r×F=r×μN

表示。刮板的形状、材质相同,在抵接的载像体直径相同的情况下,施加清洁球形调色剂所必须的面压则必须施加一定的总荷重N。express. The shape and material of the scraper are the same, and in the case of the same diameter of the contacting image carrier, a certain total load N must be applied to apply the surface pressure necessary to clean the spherical toner.

因此,必须一边为了清洁球形调色剂而维持必要的荷重,一边为了降低转矩T而降低清洁刮板38和载像体10之间的摩擦系数μ。以往,作为降低载像体10表面的摩擦系数μ的方法公知有涂敷润滑剂等的方法,但由我们的研究结果可知,在涂敷润滑剂的情况下转矩不一定降低。以下是表示其一例的实验结果。Therefore, it is necessary to reduce the coefficient of friction μ between the cleaning blade 38 and the image carrier 10 in order to reduce the torque T while maintaining the necessary load for cleaning the spherical toner. Conventionally, as a method of reducing the friction coefficient μ of the surface of the image carrier 10, a method of applying a lubricant or the like is known. However, according to the results of our research, the torque does not necessarily decrease when the lubricant is applied. Experimental results showing one example are as follows.

实施例2Example 2

在AC叠加的辊带电方式的图像形成处理中,在载像体10表面上涂敷硬脂酸锌时和不涂敷硬脂酸锌时清洁刮板38和载像体10之间作用的转矩。In the image forming process of the AC superimposed roller charging method, the transition between the cleaning blade 38 and the image carrier 10 is performed when zinc stearate is coated on the surface of the image carrier 10 and when zinc stearate is not coated. moment.

(实验条件)(experimental conditions)

清洁刮板38:使用现有的粉块调色剂的清洁刮板(厚度2mm、自由长度7mm)Cleaning blade 38 : A cleaning blade (thickness 2mm, free length 7mm) using the existing powder block toner

(清洁刮板的长度方向的长度:325mm)(Length in the longitudinal direction of the cleaning blade: 325mm)

使用Jupiter机,测定清洁动作时,比较平均值。When measuring the cleaning action using a Jupiter machine, compare the average values.

载像体10的直径:φ30The diameter of the image carrier 10: φ30

(结果)(result)

表2Table 2

  条件 condition   转矩(kg·cm)Torque (kg cm)   硬脂酸锌涂敷无Zinc stearate coating without   1.31.3   涂敷硬脂酸锌有Coated with zinc stearate   1.91.9

如该表所示,在作为润滑剂涂敷硬脂酸锌时,反倒转矩增加。这考虑是由于,当意在使载像体10表面低μ化而涂敷润滑剂时,也是硬脂酸锌由带电装置的放电而劣化,丧失润滑性,反而载像体10表面的表面能量等增加,结果清洁刮板38和载像体10的滑动摩擦的转矩变大。As shown in the table, when zinc stearate was applied as a lubricant, the torque increased on the contrary. The reason for this is that when a lubricant is applied to reduce the surface of the image carrier 10, zinc stearate is also degraded by the discharge of the charging device, and the lubricity is lost, and the surface energy of the image carrier 10 surface is reversed. etc. increase, as a result, the torque of the sliding friction between the cleaning blade 38 and the image carrier 10 becomes larger.

这样,即使在载像体10表面涂敷润滑剂,为了维持载像体10表面的低μ状态,将硬脂酸锌的涂敷量最佳化,硬脂酸锌的润滑效果以超出硬脂酸锌的劣化产生的表面能量的增加这样的涂敷平衡为必要,故将润滑剂涂敷的载像体10表面低μ化,降低清洁刮板38和载像体10之间的转矩是困难的。In this way, even if a lubricant is applied on the surface of the image carrier 10, in order to maintain the low μ state of the image carrier 10 surface, the coating amount of zinc stearate is optimized, and the lubricating effect of zinc stearate exceeds that of stearate. The coating balance of the increase of the surface energy due to the deterioration of the acid zinc is necessary, so the surface of the image carrier 10 coated with the lubricant is reduced, and the torque between the cleaning blade 38 and the image carrier 10 is reduced. difficult.

因此,反复的形成图像过程的结果、为了降低变化的载像体10表面和清洁刮板38之间的摩擦系数μ,将清洁刮板38本身低摩擦系数化是更加稳定地降低清洁刮板38和载像体10之间的转矩的方法。Therefore, as a result of repeated image forming processes, in order to reduce the friction coefficient μ between the surface of the image bearing member 10 and the cleaning blade 38 which changes, reducing the friction coefficient of the cleaning blade 38 itself is to lower the cleaning blade 38 more stably. and the method of torque between the image carrier 10.

接下来,叙述关于在使清洁刮板38的前端棱角线部38b低摩擦系数化时与载像体10滑动摩擦时产生的载像体10的驱动转矩降低的效果而进行的比较实验的结果。Next, the results of a comparative experiment will be described regarding the effect of reducing the driving torque of the image carrier 10 that occurs when the front end corner portion 38b of the cleaning blade 38 slides against the image carrier 10 when the coefficient of friction is reduced. .

(实施例3)(Example 3)

在本实验中,在以下的条件1~3中测定清洁动作时产生的转矩值,比较其大小关系。In this experiment, torque values generated during the cleaning operation were measured under the following conditions 1 to 3, and their magnitude relationships were compared.

(实验条件)(experimental conditions)

清洁刮板A:现有的粉块调色剂用的清洁刮板(厚度2mm、自由长度7mm、形状为图8(C))Cleaning blade A: A conventional cleaning blade for block toner (thickness 2mm, free length 7mm, shape as shown in Fig. 8(C))

清洁刮板B:前端钝角刮板(形状为图13(A))Cleaning scraper B: front end obtuse angle scraper (shape as Fig. 13(A))

清洁刮板C:前端钝角刮板,将前端低摩擦系数化(形状为图13(B))Cleaning scraper C: Scraper with an obtuse angle at the front end, which reduces the friction coefficient of the front end (the shape is shown in Figure 13(B))

(注:A、B、C的清洁刮板长度方向的长度:325mm)(Note: The length of the cleaning blades of A, B, and C in the length direction: 325mm)

载像体:φ30Image carrier: φ30

(结果)(result)

表3table 3

  调色剂toner   片 piece   线压(N/cm)Line pressure (N/cm)   转矩(kgf·cm)Torque (kgf cm)  条件1Condition 1   粉块调色剂powder block toner  刮板A(粉块用)Scraper A (for powder block)   0.20.2   1.81.8  条件2Condition 2   球形调色剂spherical toner   刮板BScraper B   0.950.95   3.83.8  条件3Condition 3   球形调色剂spherical toner   刮板C(低μ处理)Scraper C (low μ treatment)   0.950.95   2.72.7

为了进行比较,将由现有的清洁刮板来清洁粉块调色剂时(条件1)的转矩形成为约1.8(kgf·cm)。而在将可施加清洁球形调色剂所需的2.0~3.0MPa面压的前端加工成钝角的刮板B中,施加0.95N/cm的线压时,转矩约为3.8kgf·cm,与条件1相比为大于或等于2倍的转矩。For comparison, the torque when the powder lump toner is cleaned by a conventional cleaning blade (Condition 1) was set to be about 1.8 (kgf·cm). On the other hand, in the scraper B whose front end is processed into an obtuse angle to apply a surface pressure of 2.0 to 3.0 MPa required for cleaning spherical toners, when a linear pressure of 0.95 N/cm is applied, the torque is about 3.8 kgf·cm, which is the same as Condition 1 is greater than or equal to twice the torque.

在条件3中,使用了将刮板B的前端实施了低μ处理的刮板C的结果,在施加有0.95N/cm线压时,转矩约为2.7kgf·cm,能够降低转矩。In condition 3, when blade C was used with low μ treatment at the tip of blade B, the torque was about 2.7 kgf·cm when a linear pressure of 0.95 N/cm was applied, and the torque could be reduced.

这样,通过将清洁刮板38的前端棱角线部38b低摩擦系数化,在施加有可清洁球形调色剂的荷重的情况下也能够降低载像体10和清洁刮板38的滑动摩擦产生的转矩。在此,作为清洁刮板38的前端棱角线部38b的低摩擦系数化的方法采用了氟含浸刮板的方法。此时,为了从刮板表面向内部含浸氟树脂,可以长时间低摩擦系数化。In this way, by reducing the friction coefficient of the front end corner portion 38b of the cleaning blade 38, even when a load capable of cleaning spherical toner is applied, the friction generated by the sliding friction between the image carrier 10 and the cleaning blade 38 can be reduced. torque. Here, the method of impregnating the blade with fluorine is used as a method of reducing the coefficient of friction of the front end corner portion 38 b of the cleaning blade 38 . At this time, in order to impregnate the fluororesin from the surface of the blade to the inside, the coefficient of friction can be reduced for a long time.

另一方面,在刮板表面上也能够涂敷低摩擦系数化物质。另外,作为清洁刮板38与以往使用的聚氨脂相比,只要摩擦系数小便可,不限定于此。On the other hand, it is also possible to apply a material for reducing the coefficient of friction on the surface of the blade. In addition, the cleaning blade 38 is not limited to this as long as the coefficient of friction is smaller than conventionally used polyurethane.

在本发明的图像形成装置中,可以至少一体具备上述的清洁装置16和载像体10,构成相对于图像形成装置本体自如拆装的处理盒。由此,能够提供可得到能可靠地清洁小粒且球形的调色剂的低线压、高面压的清洁结构的处理盒。另外,通过形成处理盒,容易进行更换、修理、补给等维修,可实现图像形成装置本体的小型化。In the image forming apparatus of the present invention, at least the above-mentioned cleaning device 16 and the image carrier 10 may be provided integrally to form a process cartridge that can be attached and detached from the main body of the image forming apparatus. Accordingly, it is possible to provide a process cartridge having a low linear pressure and high surface pressure cleaning structure capable of reliably cleaning small and spherical toner particles. Also, by forming a process cartridge, maintenance such as replacement, repair, and replenishment can be easily performed, and the main body of the image forming apparatus can be downsized.

在上述例中,说明了适用于将形成于作为载像体的感光体上的调色剂图像不通过中间转印体而直接转印到记录介质上记录图像的直接转印方式的图像形成装置及其处理盒和清洁装置的情况,当然能够适用于通过中间转印体将形成于作为载像体的感光体上的调色剂图像转印到记录介质上记录图像的直接转印方式的图像形成装置以其处理盒和清洁装置。此时,对去除作为载像体的感光体上的一次转印剩余调色剂的一次清洁装置自不必说,也能够适用于去除作为载像体的感光体上的二次转印剩余调色剂的二次清洁装置。In the above example, the image forming apparatus of the direct transfer method in which the toner image formed on the photoreceptor as the image carrier is directly transferred to the recording medium without passing through the intermediate transfer body has been described. And the case of the process cartridge and the cleaning device, of course, can be applied to the image of the direct transfer method in which the toner image formed on the photoreceptor as the image carrier is transferred to the recording medium through the intermediate transfer body to record the image. A device is formed with its processing cartridge and cleaning device. In this case, needless to say, the primary cleaning device for removing the primary transfer residual toner on the photoreceptor as the image carrier can also be applied to remove the secondary transfer residual toner on the photoreceptor as the image carrier. Agent secondary cleaning device.

另外,说明了适用于单色的图像形成装置及其处理盒和清洁装置的情况,但也能够同样地适用于旋转方式和串联方式的彩色图像形成装置及其处理盒和清洁装置。并也能够同样地适用于设有多个处理盒和清洁装置的情况。In addition, although the description is applied to a monochrome image forming apparatus, its process cartridge, and cleaning device, it can be similarly applied to rotary and tandem color image forming apparatuses, their process cartridges, and cleaning apparatus. It can also be applied similarly to the case where a plurality of process cartridges and cleaning devices are provided.

能够提供可得到能可靠地清洁小粒且球形的调色剂的低线压、高面压的清洁结构的图像形成装置及其处理盒和清洁装置。It is possible to provide an image forming apparatus, a process cartridge thereof, and a cleaning device having a low linear pressure and high surface pressure cleaning structure capable of reliably cleaning small and spherical toner particles.

在图17中表示具有作为被清洁部件的中间转印体的中间转印单元300和其周围的示意结构。基于该图17说明将本发明适用于去除作为中间转印体的中间转印带210上的二次残余调色剂的二次清洁装置的情况。FIG. 17 shows a schematic structure of an intermediate transfer unit 300 having an intermediate transfer body as a member to be cleaned and its surroundings. A case where the present invention is applied to a secondary cleaning device for removing secondary residual toner on intermediate transfer belt 210 as an intermediate transfer body will be described based on this FIG. 17 .

中间转印单元300将中间转印带210绕挂在拉架辊214、驱动辊215、二次转印后支辊216、黄、青绿、深红、黑四个中间转印偏压辊62Y、62C、62M、62K、三个接地辊74等上,在周围作为二次清洁装置设置带清洁装置217。The intermediate transfer unit 300 hangs the intermediate transfer belt 210 around the tension roller 214, the drive roller 215, the post-secondary transfer support roller 216, and the four intermediate transfer bias rollers 62Y, 62C of yellow, cyan, deep red, and black. , 62M, 62K, three ground rollers 74, etc., a belt cleaning device 217 is provided around as a secondary cleaning device.

中间转印带210通过由未图示的带驱动电极驱动的驱动辊215的旋转而绕图中顺时针环状环形移动。四个中间转印偏压辊62Y、62C、62M、62K分别与中间转印带210的基底层侧(内周面侧)接触设置,从未图示的电源接受中间转印偏压的施加。另外,将中间转印带210从其基底层侧向感光体101Y、101C、101M、101K按压而分别形成中间转印夹持部。在各中间转印夹持部上由于上述中间转印偏压的影响而在感光体和中间转印偏压辊之间形成中间转印电场。Y用的感光体101Y上形成的上述Y调色剂图像由于该中间转印电场和夹持压的影响而中间转印到中间转印带210上。在该Y调色剂图像上一次重合形成于C、M、K用的感光体101C、101M、101K上形成的C、M、K调色剂图像并进行中间转印。通过该重合的中间转印而在中间转印带210上形成呈多重调色剂图像的四色重合调色剂图像(以下称为四色调色剂图像)。The intermediate transfer belt 210 is circularly moved clockwise in the drawing by the rotation of the driving roller 215 driven by a belt driving electrode not shown. The four intermediate transfer bias rollers 62Y, 62C, 62M, and 62K are provided in contact with the base layer side (inner peripheral surface side) of the intermediate transfer belt 210 , and receive an intermediate transfer bias voltage from a power source (not shown). In addition, the intermediate transfer belt 210 is pressed from the base layer side to the photoreceptors 101Y, 101C, 101M, and 101K to form intermediate transfer nip portions, respectively. An intermediate transfer electric field is formed between the photoreceptor and the intermediate transfer bias roller at each intermediate transfer nip due to the influence of the above-mentioned intermediate transfer bias. The Y toner image formed on the photoreceptor 101Y for Y is intermediate-transferred onto the intermediate transfer belt 210 under the influence of the intermediate transfer electric field and the nip pressure. The C, M, and K toner images formed on the C, M, and K photoreceptors 101C, 101M, and 101K are superimposed on the Y toner image and intermediate transferred. A four-color superposed toner image (hereinafter referred to as a four-color toner image) that is a multiple toner image is formed on the intermediate transfer belt 210 by this superimposed intermediate transfer.

在中间转印带210中,在位于各中间转印夹持部之间的部分上分别从内侧抵接有接地辊74。这些接地辊74由导电性材料构成。并且,由各中间转印夹持部阻止从中间转印偏压辊62Y、62C、62M、62K向带传递的中间转印偏压产生的电流向其他中间转印夹持部和处理盒泄露。In the intermediate transfer belt 210 , ground rollers 74 abut against each of the portions located between the intermediate transfer nips from the inner side. These ground rollers 74 are made of a conductive material. Furthermore, each intermediate transfer nip prevents current generated by the intermediate transfer bias transmitted from the intermediate transfer bias rollers 62Y, 62C, 62M, and 62K to the belt from leaking to other intermediate transfer nips and process cartridges.

重合转印到中间转印带210上的四色调色剂图像由后述的二次转印夹持部向未图示的转印纸进行二次转印。通过二次转印夹持部后残留在中间转印带210表面上的转印残留调色剂通过将带夹入到与图中左侧的驱动辊215之间的带清洁装置217的弹性橡胶制的清洁刮板38而被清洁。The four-color toner images superimposedly transferred onto the intermediate transfer belt 210 are secondarily transferred to a transfer paper (not shown) by a second transfer nip described later. The transfer residual toner that remains on the surface of the intermediate transfer belt 210 after passing through the secondary transfer nip passes through the elastic rubber of the belt cleaning device 217 that sandwiches the belt between the driving roller 215 on the left side in the drawing. Made cleaning blade 38 and cleaned.

清洁刮板38由未图示的支承部件支承,前端沿相反方向按压在表面移动的中间转印带210上。清洁刮板38的前端棱角线部与上述实施例同样,将形成其前端棱角线部的角度构成为钝角,同时以大于或等于2.0MPa的面压按压在作为被清洁部件的中间转印带210上。The cleaning blade 38 is supported by a support member (not shown), and its front end is pressed against the intermediate transfer belt 210 whose surface moves in the opposite direction. The front end corner portion of the cleaning blade 38 is the same as the above-mentioned embodiment, and the angle forming the front end corner portion is constituted as an obtuse angle, and at the same time, it is pressed against the intermediate transfer belt 210 as the member to be cleaned with a surface pressure of 2.0 MPa or more. superior.

特别地,在如中间转印带210那样承载多种颜色的调色剂的中间转印单元300中,通过良好地去除转印残留调色剂,能够防止不同颜色的转印残留调色剂附着在感光体1上而引起的混色。In particular, in the intermediate transfer unit 300 carrying toners of a plurality of colors like the intermediate transfer belt 210 , by removing transfer residual toner well, it is possible to prevent transfer residual toner of different colors from adhering. Color mixing caused on photoreceptor 1.

另外,中间转印单元300至少将带清洁装置217和中间转印带210作为一体而构成处理盒,由此能够相对未图示的图像形状装置本体进行拆装。In addition, the intermediate transfer unit 300 includes at least the belt cleaning device 217 and the intermediate transfer belt 210 integrally to form a process cartridge, and thus can be attached to and detached from the main body of the image forming device (not shown).

在图17中,附图标记220是成像装置,由黄、青绿、深红、黑四中单色成像装置218Y、218C、218M、218K构成。102是抵抗辊、222是二次转印运送装置,将转印运送带224绕挂在两个辊223上。50是定影装置。In FIG. 17 , reference numeral 220 is an imaging device, which is composed of four monochromatic imaging devices 218Y, 218C, 218M, and 218K of yellow, cyan, magenta, and black. 102 is a resist roller, 222 is a secondary transfer conveyance device, and the transfer conveyance belt 224 is wound around two rollers 223 . 50 is a fixing device.

在上述例中,说明了被清洁部件是感光体及中间转印体等的载像体10、210,由清洁刮板38去除图像转印后仍残留在该载像体10、210上的残留调色剂的情况。但是,被清洁部件不限于载像体,例如也可以是带电装置的带电辊。In the above example, it has been described that the member to be cleaned is the image carrier 10, 210 such as a photoreceptor and an intermediate transfer body, and the residue remaining on the image carrier 10, 210 after image transfer is removed by the cleaning blade 38. The condition of the toner. However, the member to be cleaned is not limited to the image carrier, and may be, for example, a charging roller of a charging device.

图18表示具有作为被清洁部件的带电辊的带电装置和其周围的示意结构。如图所示,在带电装置110上具有去除附着在带电辊111上的调色剂的带电辊清洁装置117。带电辊清洁装置117具有带电去除壳体113、支承部件37、作为弹性体清洁刮板的清洁刮板38和带电去除回收螺丝(screw)114等。Fig. 18 shows a schematic configuration of a charging device having a charging roller as a member to be cleaned and its surroundings. As shown in the figure, the charging device 110 has a charging roller cleaning device 117 for removing toner adhering to the charging roller 111 . The charging roller cleaning device 117 has a destaticizing case 113 , a support member 37 , a cleaning blade 38 as an elastic body cleaning blade, a destaticizing recovery screw 114 , and the like.

附着在感光体101上的残留调色剂中没有被感光体清洁装置完全去除的调色剂到达作为带电区域的带电辊111的相对部。带电辊111相对感光体101接近或接触而带电,故在到达带电区域的调色剂中,有的附着在带电辊111上。在带电区域中附着在带电辊111上的调色剂通过带电辊清洁装置117的清洁刮板38而从带电辊111表面去除。Of the remaining toner adhering to the photoreceptor 101 , the toner that is not completely removed by the photoreceptor cleaning device reaches the opposite portion of the charging roller 111 as a charging area. Since the charging roller 111 approaches or contacts the photoreceptor 101 to be charged, some of the toner reaching the charging area adheres to the charging roller 111 . The toner adhering to the charging roller 111 in the charging area is removed from the surface of the charging roller 111 by the cleaning blade 38 of the charging roller cleaning device 117 .

清洁刮板38由支承部件37支承,前端沿相反方向按压在表面移动的带电辊111上。清洁刮板38的前端棱角线部与上述例同样,将形成其前端棱角线部的角度构成为钝角,同时以大于或等于2.0MPa的面压按压在作为被清洁部件的带电辊111上。The cleaning blade 38 is supported by the supporting member 37, and its front end is pressed against the charging roller 111 which moves on the surface in the opposite direction. The front end corner of the cleaning blade 38 is the same as the above example, and the angle forming the front end corner is formed as an obtuse angle, and is pressed against the charging roller 111 as the member to be cleaned with a surface pressure greater than or equal to 2.0 MPa.

通过良好地去除附着在带电辊111上的残留调色剂,不需要形成用于防止调色剂附着的非接触型,能够采用接触型的带电辊111。另外,带电装置110至少将带电辊清洁装置117和带电辊111作为一体而构成处理盒,由此能够相对未图示的图像形状装置本体进行拆装。By satisfactorily removing the residual toner adhering to the charging roller 111 , it is not necessary to form a non-contact type for preventing toner adhesion, and a contact type charging roller 111 can be used. In addition, the charging device 110 constitutes a process cartridge by integrating at least the charging roller cleaning device 117 and the charging roller 111 , so that it can be attached to and detached from the main body of the image forming device (not shown).

Claims (28)

1. cleaning device, it will be pressed on the parts that are cleaned that move on the surface round about by the front end knuckle line portion of the flexible cleaning scraper plate of support unit supporting, remove the lip-deep toner of these parts that are cleaned, it is characterized in that, the angle of the formation front end knuckle line portion of described cleaning balde is formed the obtuse angle, and, when the drift that is made as t1, described cleaning balde at the thickness with the component crimping part of being cleaned with described cleaning balde is made as t3, form the relation of 1.75≤t3/t1≤3.
2. cleaning device as claimed in claim 1 is characterized in that, to press more than or equal to the face of 2.0MPa described front end knuckle line portion by being pressed on the described parts that are cleaned.
3. cleaning device as claimed in claim 1 is characterized in that, the described parts that are cleaned are image carriers, by the toner that still remains in after the transfer printing of described cleaning balde removal image on this image carrier.
4. cleaning device as claimed in claim 1 is characterized in that, described obtuse angle forms from 95 to be spent to the scope of 140 degree.
5. cleaning device as claimed in claim 3 is characterized in that, the front end face by the described cleaning balde of inclined cut forms described obtuse angle.
6. cleaning device as claimed in claim 5 is characterized in that, cutting width is 200 μ m on the thickness direction of described cleaning balde, is 100 μ m in the longitudinal direction.
7. cleaning device as claimed in claim 2 is characterized in that, described pressure is more than or equal to 3.0MPa.
8. cleaning device as claimed in claim 1 is characterized in that, with more than or equal to the contact width of 10 μ m with described front end knuckle line portion by being pressed on the described parts that are cleaned.
9. cleaning device as claimed in claim 1 is characterized in that, with the contact width that is less than or equal to 40 μ m with described front end knuckle line portion by being pressed on the described parts that are cleaned.
10. cleaning device as claimed in claim 9 is characterized in that, with the contact width that is less than or equal to 30 μ m with described front end knuckle line portion by being pressed on the described parts that are cleaned.
11. cleaning device as claimed in claim 1 is characterized in that, with the line pressure of 0.2N/cm to 1.2N/cm scope with described cleaning balde by being pressed on the described parts that are cleaned.
12. cleaning device as claimed in claim 11 is characterized in that, with the line pressure that is less than or equal to 0.9N/cm with described cleaning balde by being pressed on the described parts that are cleaned.
13. cleaning device as claimed in claim 1 is characterized in that, forms teat on described cleaning balde, the front end that prevents described cleaning balde described support unit of butt and described cleaning balde breaks away from when being pressed on the described parts that are cleaned.
14. cleaning device as claimed in claim 1 is characterized in that, pad adds strengthening part on the drift of described cleaning balde part, and the front end that prevents this cleaning balde is when being pressed on the described parts that are cleaned and described cleaning balde breaks away from.
15. cleaning device as claimed in claim 1 is characterized in that, as the material of described cleaning balde, uses JISA hardness for spending to the rubber of 80 degree from 60.
16. cleaning device as claimed in claim 1 is characterized in that, the elasticity recovery of described cleaning balde is formed 23 ℃ be less than or equal to 30%.
17. cleaning device as claimed in claim 1 is characterized in that, with described cleaning balde by the described front end knuckle line portion low-friction coefficientization that is pressed on the described parts that are cleaned.
18. cleaning device as claimed in claim 17 is characterized in that, the fluorine-type resin impregnation of described front end knuckle line portion is with its front end knuckle line portion low-friction coefficientization.
19. cleaning device as claimed in claim 1 is characterized in that, the sphericity of described toner is formed more than or equal to 0.95.
20. a handle box is characterized in that, has cleaning device and image carrier integratedly, with respect to image processing system dismounting freely,
Described cleaning device will be pressed on the parts that are cleaned that move on the surface round about by the front end knuckle line portion of the flexible cleaning scraper plate of support unit supporting, remove the lip-deep toner of these parts that are cleaned, wherein, the angle of the formation front end knuckle line portion of described cleaning balde is formed the obtuse angle, and, be made as t1 at thickness with the component crimping part that is cleaned with described cleaning balde, when the drift of described cleaning balde is made as t3, form the relation of 1.75≤t3/t1≤3, the described parts that are cleaned are image carrier, by the remaining toner that still remains in after the transfer printing of described cleaning balde removal image on this image carrier.
21. handle box as claimed in claim 20 is characterized in that, to press more than or equal to the face of 2.0MPa described front end knuckle line portion by being pressed on the described parts that are cleaned.
22. image processing system, it is characterized in that, has such cleaning device, it will be pressed on the parts that are cleaned that move on the surface round about by the front end knuckle line portion of the flexible cleaning scraper plate of support unit supporting, remove the lip-deep toner of these parts that are cleaned, wherein, the angle of the formation front end knuckle line portion of described cleaning balde is formed the obtuse angle, and, be made as t1 at thickness with the component crimping part that is cleaned with described cleaning balde, when the drift of described cleaning balde is made as t3, form the relation of 1.75≤t3/t1≤3, the described parts that are cleaned are image carrier, by the remaining toner that still remains in after the transfer printing of described cleaning balde removal image on this image carrier.
23. image processing system as claimed in claim 22 is characterized in that, to press more than or equal to the face of 2.0MPa described front end knuckle line portion by being pressed on the described parts that are cleaned.
24. image processing system as claimed in claim 22 is characterized in that, the protective seam that contains inorganic fine particles is set on described image carrier.
25. image processing system as claimed in claim 22 is characterized in that, has the binder resin of band cross-linked structure on the protective seam of described image carrier.
26. image processing system as claimed in claim 25 is characterized in that, has electric charge and transport layer in the structure of described binder resin.
27. a handle box is characterized in that, have cleaning device and on image carrier the coating lubricant lubricant applying apparatus,
Described cleaning device will be pressed on the parts that are cleaned that move on the surface round about by the front end knuckle line portion of the flexible cleaning scraper plate of support unit supporting, remove the lip-deep toner of these parts that are cleaned, wherein, the angle of the formation front end knuckle line portion of described cleaning balde is formed the obtuse angle, and, be made as t1 at thickness with the component crimping part that is cleaned with described cleaning balde, when the drift of described cleaning balde is made as t3, form the relation of 1.75≤t3/t1≤3, the described parts that are cleaned are image carrier, by the remaining toner that still remains in after the transfer printing of described cleaning balde removal image on this image carrier, this handle box can be with respect to the dismounting of image processing system subject freedom.
28. handle box as claimed in claim 27 is characterized in that, to press more than or equal to the face of 2.0MPa described front end knuckle line portion by being pressed on the described parts that are cleaned.
CN 200510119274 2004-11-01 2005-11-01 Cleaning device, process cartridge, and image forming device Expired - Lifetime CN1770041B (en)

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JP4836296B2 (en) 2011-12-14
JP2009237588A (en) 2009-10-15

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