CN1769361A - Starchiness adhesives and preparation method - Google Patents
Starchiness adhesives and preparation method Download PDFInfo
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- CN1769361A CN1769361A CN 200410088447 CN200410088447A CN1769361A CN 1769361 A CN1769361 A CN 1769361A CN 200410088447 CN200410088447 CN 200410088447 CN 200410088447 A CN200410088447 A CN 200410088447A CN 1769361 A CN1769361 A CN 1769361A
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- starch
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- 239000000853 adhesive Substances 0.000 title claims abstract description 28
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims description 6
- 229920002472 Starch Polymers 0.000 claims abstract description 73
- 235000019698 starch Nutrition 0.000 claims abstract description 73
- 239000008107 starch Substances 0.000 claims abstract description 71
- 239000000203 mixture Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 239000007787 solid Substances 0.000 claims description 14
- -1 Siloxanes Chemical class 0.000 claims description 13
- 230000004048 modification Effects 0.000 claims description 12
- 238000012986 modification Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 10
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 6
- 238000004132 cross linking Methods 0.000 claims description 5
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 4
- 240000008042 Zea mays Species 0.000 claims description 4
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 4
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 235000005822 corn Nutrition 0.000 claims description 4
- 238000006266 etherification reaction Methods 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- 239000004302 potassium sorbate Substances 0.000 claims description 4
- 235000010241 potassium sorbate Nutrition 0.000 claims description 4
- 229940069338 potassium sorbate Drugs 0.000 claims description 4
- 240000003183 Manihot esculenta Species 0.000 claims description 3
- 235000016735 Manihot esculenta subsp esculenta Nutrition 0.000 claims description 3
- MCFVRESNTICQSJ-RJNTXXOISA-L calcium sorbate Chemical compound [Ca+2].C\C=C\C=C\C([O-])=O.C\C=C\C=C\C([O-])=O MCFVRESNTICQSJ-RJNTXXOISA-L 0.000 claims description 3
- 239000004303 calcium sorbate Substances 0.000 claims description 3
- 235000010244 calcium sorbate Nutrition 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 3
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims description 2
- 244000241257 Cucumis melo Species 0.000 claims description 2
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 244000061456 Solanum tuberosum Species 0.000 claims description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- 235000021307 Triticum Nutrition 0.000 claims description 2
- 244000098338 Triticum aestivum Species 0.000 claims description 2
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 claims description 2
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 claims description 2
- 239000012346 acetyl chloride Substances 0.000 claims description 2
- 230000010933 acylation Effects 0.000 claims description 2
- 238000005917 acylation reaction Methods 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 claims description 2
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 2
- 238000009472 formulation Methods 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 2
- RZWZRACFZGVKFM-UHFFFAOYSA-N propanoyl chloride Chemical compound CCC(Cl)=O RZWZRACFZGVKFM-UHFFFAOYSA-N 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- 239000004334 sorbic acid Substances 0.000 claims description 2
- 235000010199 sorbic acid Nutrition 0.000 claims description 2
- 229940075582 sorbic acid Drugs 0.000 claims description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 2
- 235000019504 cigarettes Nutrition 0.000 abstract description 15
- 239000004368 Modified starch Substances 0.000 abstract description 3
- 229920000881 Modified starch Polymers 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 235000019426 modified starch Nutrition 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 7
- 239000003292 glue Substances 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- 229920002261 Corn starch Polymers 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000008120 corn starch Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 2
- RHAXKFFKGZJUOE-UHFFFAOYSA-N 7-acetyl-6-ethyl-3,5,8-trihydroxy-9,10-dioxoanthracene-1,2-dicarboxylic acid Chemical compound O=C1C2=CC(O)=C(C(O)=O)C(C(O)=O)=C2C(=O)C2=C1C(O)=C(CC)C(C(C)=O)=C2O RHAXKFFKGZJUOE-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 235000006491 Acacia senegal Nutrition 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- 241000282342 Martes americana Species 0.000 description 1
- 235000013829 acylated starch Nutrition 0.000 description 1
- 239000001339 acylated starch Substances 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
Landscapes
- Polysaccharides And Polysaccharide Derivatives (AREA)
Abstract
The invention discloses a starch admixture for cigarette production and its preparing process, wherein the adhesive is a starch composition comprising modified starch, modifier, defoaming agent, preservative agent and water.
Description
One, technical field
The invention belongs to field of fine chemical, at length say it is to utilize treated starch through the twice-modified starch-based adhesive and the preparation method of making that are applicable to cigarette production usefulness.
Two, background technology
The tackiness agent of three kinds of occasions commonly used was called as overlapping glue (being that the vertical limit of cigarette is bonding), connects mouth glue (cigarette and filter stick bonding) and mouth sticklac (filter tow and yew paper bonding) during cigarette was produced.Cigarette glue normally will use by the nozzle by high-speed cigarette machine, and the machine speed of this equipment has been brought up to 7000/minute by original 2000～3000/minute, even to more than 10000/minute.The starch-based adhesive of prior art is low because of solid content, and viscosity is big, and drying can not re-use slowly, and changes " cigarette white glues ", promptly poly-(ethylene-vinyl acetate) tackiness agent into.Discover that " cigarette white glues " when sucking about 750 ℃ of incendiary temperature, discharges tens kinds of obnoxious flavoures, not only harmful to health of people, and cause the mouthfeel peculiar smell; And starch-based adhesive can not produce obnoxious flavour under similarity condition, and sucks good mouthfeel.Therefore, people are interested in starch-based adhesive at present.And can be applicable to high-speed cigarette machine (more than 7000 s'/minute) starch-based adhesive, take particularly that mouthful tackiness agent then must have high solids content, rate of drying is fast, viscosity is little, fluid property is good, good penetrability, performance that bonding force is strong.Make starch-based adhesive reach the over-all properties of " cigarette white glues ", must carry out some modification to starch, before the present invention, for example: United States Patent (USP) 5,085,228 (people such as Mooney) have proposed a kind of binder composition that comprises cross-linking starch and modified starch, and the amylopection content that special requirement starch has is at least about 70% (weight).United States Patent (USP) 5,155,140 people such as () Marten have proposed to comprise complicated binder blend such as Sudan Gum-arabic, carboxymethyl starch.Chinese patent, publication number CN1135231A, application number 94194163.9, (people such as U.S. T.W. Wei Erdemu) proposed the tackiness agent of a kind of dispersed unmodified starch that contains 5～60% (weight) treated starch, multiviscosisty when 2～25% (weight) are heated to above 50 ℃, 0～5% rheology modifier component.European patent 0458233A2 has proposed a kind of with the crosslinked acetylize waxy corn starch of etherificate (hydroxypropyl alcohol) tapioca (flour) and acetic anhydride, hexanodioic acid two and the binder blend of Sodium peroxoborate; also proposed simultaneously by superheated vapour starch direct injection boiling, then the preparation technology of flash distillation starch slip under atmospheric pressure.Yet, still need to reach the tackiness agent of the fast native starch of low viscosity, high solids content, good penetrability, rate of drying that high-speed cigarette machine (7000/minute) requires, and need a kind of easy technology of producing this Starch Adhesive.
Three, summary of the invention
Purpose of the present invention, be to overcome the deficiency of prior art, viscosity is very big during according to commercially available treated starch gelatinization, only when low-solid content very, can reach low viscosity, and when solid content is very low, rate of drying does not reach the processing requirement of high speed cigarette excessively slowly, when making high starch solids glue reach low viscosity with the way of degrading, making again becomes fragile after adhesive permeation variation or the drying seam broken occurs, there are these defectives according to prior art, the present invention proposes new technical scheme, technical essential of the present invention is, this starch-based adhesive is that one or more treated starch passes through the starch-based adhesive that obtains after the modification for the second time again, it is characterized in that the weight percent of this starch-based adhesive composition is:
Treated starch 35-60
Acetic anhydride 2-10
Isothiazolinone 0.1-1
Siloxanes 0.1-1
Water 30-60
By said ratio, in its scope, select composition, constitute weight 100%.Treated starch in the proportioning is meant acetylated starch, acetylize two cross-linking starchs, etherification starch, etherificate cross-linking starch; Acetic anhydride is the properties-correcting agent second time, it can comprise: acetic acid, hexanodioic acid, toxilic acid, sebacic acid, Succinic Acid, fumaric acid, Acetyl Chloride 98Min., propionyl chloride, epoxy monochloroethane, epoxy chloropropane, persulphate, perborate, hydrochloric acid, phosphoric acid, Mono Chloro Acetic Acid and tosic acid with following a kind of, two or more equivalent replacement; Isothiazolinone is a sanitas, and it can use Sorbic Acid, calcium sorbate, potassium sorbate equivalent replacement; Siloxanes is a defoamer, and it can use mineral oil, synthetic wax defoamer, glycols and compound defoamer formulation equivalent replacement; Treated starch in the proportioning is the starch to the native starch modification, and native starch comprises cassava, corn, waxy corn, potato, wax rice, wheat and ground melon starch; The solid content of starch-based adhesive of the present invention is 35-60%, and its preparation method is that the modification second time of treated starch is carried out in the gelatigenous process of gelatinization, be acylation modification or etherification modified and the degraded carry out synchronously, it is characterized in that following these steps to finish:
(1) in container with the treated starch of weight 35-60%, the water-dispersion that adds 30-60% (weight) is even, the properties-correcting agent second time that adds weight 2-10% again is a kind of, the defoamer of two or more and weight 0.1-1%, stirs;
(2) the above-mentioned mixture that stirs is placed reactor, heat at 85-200 ℃, pressure carried out the gelatinization modification 10 minutes to 3 hours at 0.1-0.45MPa, was cooled to 25 ℃ then, added the sanitas of 0.1-1% (weight), and stirring promptly gets product.
(3) prepared mixture in the step (1) also can place microwave oven with container, and under the condition of 2.45GHz, W80% 25 minutes, when being cooled to 25 ℃, add the sanitas of 0.1-1% (weight), stirring promptly gets product.
Starch-based adhesive of the present invention is applicable to the high-speed cigarette machine of cigarette speed more than or equal to 7000/minute, this tackiness agent can use under the low viscosity situation, and have that rate of drying is fast, good penetrability, advantage that bonding force is strong, this low viscosity, fast rate of drying, high solids content and good penetration are that present many conventional starch-based adhesives institute is inaccessiable.Starch-based adhesive of the present invention is applicable to that also packaging carton, bottle label are pasted and the bonding occasion of other paper.
Four, embodiment
Further specify enforcement of the present invention and main points with following embodiment.
Embodiment 1
Mixture with 55% hydroxypropylation W-Gum, 0.4% phosphoric acid, 3.6% acetic anhydride, 40.5% water, 0.15% isothiazolinone and 0.35% siloxanes prepares tackiness agent.At first 30% starch is scattered in 32.5% water, add all acid, acetic anhydride and siloxanes, in reactor under 90 ℃, pressure boiling under 0.3Mpa, add remaining starch again after having certain fluidity, 90 ℃ of following insulations were cooled to 25 ℃ and add isothiazolinone and remainder water after 30 minutes, stir, promptly get product.
Products obtained therefrom has 52% solid content, and brookfield viscosity is 700cps in the time of 25 ℃, and the viscosity of this product was stable at two months, and has good flowability and cementability.
Comparative Examples
Mixture with 55% W-Gum, 0.4% phosphoric acid, 3.6% acetic anhydride, 40.5% water, 0.15% isothiazolinone and 0.35% siloxanes prepares tackiness agent.At first 30% starch is scattered in 30.5% water, add all acid, acetic anhydride and siloxanes, in reactor under 90 ℃, pressure boiling under 0.3Mpa, add remaining starch again after having certain fluidity, 90 ℃ are incubated half an hour down, are cooled to 25 ℃ and add isothiazolinone and remainder water, stir, promptly get product.
Products obtained therefrom has 52% solid content, and brookfield viscosity is 3500cps in the time of 25 ℃, and the viscosity less stable of this product was gelation in one month.
Embodiment 2
Mixture with 30% acidylate W-Gum, 10% cold gelatinization acylated starch, 0.1% sulfuric acid, 5% hexanodioic acid, 54.4% water, 0.2% isothiazolinone and 0.3% mineral oil prepares tackiness agent.At first all starch is scattered in water, adds hexanodioic acid and sulfuric acid and mineral oil, boiling under 120 ℃, 0.2Mpa pressure is cooled to 25 ℃ and adds isothiazolinone in autoclave pressure, stirs, and promptly gets product.
Products obtained therefrom has 37% solid content, and brookfield viscosity is 900cps in the time of 25 ℃, and the viscosity of this product was stable at two months, and has good flowability and viscosity.
Embodiment 3
Mixture with the crosslinked waxy corn starch of 38% (weight) etherificate, 58.2% water, 3% fumaric acid, 0.4% sulfuric acid, 0.3% synthetic wax defoamer and 0.1% potassium sorbate prepares tackiness agent.At first all starch is scattered in water, and adds all acid and synthetic wax defoamer,, be cooled to 25 ℃ then, add potassium sorbate and stir, promptly get this product by the gelatinization degradation modification under about 150 ℃, 0.3Mpa of boiling in autoclave pressure.
Products obtained therefrom has 35% solid content, and brookfield viscosity is 500cps in the time of 25 ℃, and the viscosity of this product was stable at two months, and has good flowability and viscosity.
Embodiment 4
Mixture with the crosslinked waxy corn starch of 45% (weight) acidylate, 53.5% water, 0.4% hydrochloric acid, 0.5% sebacic acid, 0.3% siloxanes and 0.3% calcium sorbate prepares tackiness agent.At first all starch is scattered in water, and adds all acid and siloxanes, put into microwave oven 2.45GHz, W80% condition following 25 minutes, obtain this product.
Products obtained therefrom has 42% solid content, and brookfield viscosity is 900cps in the time of 25 ℃, and the viscosity of this product was stable at two months, and has good flowability and viscosity.
Claims (8)
1, a kind of starch-based adhesive, it is by a kind of, two or more treated starch, passes through the starch-based adhesive that obtains after the modification for the second time again, it is characterized in that the weight percent of starch-based adhesive composition is:
Treated starch 35-60
Acetic anhydride 2-10
Isothiazolinone 0.1-1
Siloxanes 0.1-1
Water 30-60
By said ratio, in its scope, select composition, constitute 100% (weight).
2,, it is characterized in that treated starch is meant acetylated starch, acetylize two cross-linking starchs, etherification starch, etherificate cross-linking starch according to the described starch-based adhesive of claim 1.
3, according to the described starch-based adhesive of claim 1, it is characterized in that acetic anhydride is the properties-correcting agent second time, it can comprise: acetic acid, hexanodioic acid, toxilic acid, sebacic acid, Succinic Acid, fumaric acid, Acetyl Chloride 98Min., propionyl chloride, epoxy monochloroethane, epoxy chloropropane, persulphate, perborate, hydrochloric acid, phosphoric acid, Mono Chloro Acetic Acid and tosic acid with following a kind of, two or more equivalent replacement.
4, according to the described starch-based adhesive of claim 1, it is characterized in that isothiazolinone is a sanitas, it can use Sorbic Acid, calcium sorbate, potassium sorbate equivalent replacement.
5, according to the described starch-based adhesive of claim 1, it is characterized in that siloxanes is a defoamer, it can use mineral oil, synthetic wax defoamer, glycols and compound defoamer formulation equivalent replacement.
6, according to claim 1 or 2 described starch-based adhesives, it is characterized in that treated starch is the starch to the native starch modification, native starch comprises cassava, corn, waxy corn, potato, wax rice, wheat and ground melon starch.
7, according to the described starch-based adhesive of claim 1, the solid content that it is characterized in that this tackiness agent is 35-60%.
8, a kind of preparation method of starch-based adhesive, the modification second time of treated starch is carried out in the gelatigenous process of gelatinization, be acylation modification or etherification modified and the degraded carry out synchronously, it is characterized in that following these steps to finish:
(1) in container with the treated starch of weight 35-60%, the water-dispersion that adds 30-60% (weight) is even, the properties-correcting agent second time that adds weight 2-10% again is a kind of, the defoamer of two or more and weight 0.1-1%, stirs;
(2) the above-mentioned mixture that stirs is placed reactor, heat at 85-200 ℃, pressure carried out the gelatinization modification 10 minutes to 3 hours at 0.1-0.45MPa, was cooled to 25 ℃ then, added the sanitas of 0.1-1% (weight), and stirring promptly gets product.
(3) prepared mixture in the step (1) also can place microwave oven with container, and under the condition of 2.45GHz, W80% 25 minutes, when being cooled to 25 ℃, add the sanitas of 0.1-1% (weight), stirring promptly gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100884475A CN100556973C (en) | 2004-11-03 | 2004-11-03 | Starch adhesive and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100884475A CN100556973C (en) | 2004-11-03 | 2004-11-03 | Starch adhesive and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1769361A true CN1769361A (en) | 2006-05-10 |
| CN100556973C CN100556973C (en) | 2009-11-04 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100884475A Expired - Fee Related CN100556973C (en) | 2004-11-03 | 2004-11-03 | Starch adhesive and its preparation method |
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| Country | Link |
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| CN (1) | CN100556973C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453461A (en) * | 2010-10-21 | 2012-05-16 | 大亚科技股份有限公司 | Forming adhesive for cigarette polypropylene fiber filter tip and preparation method thereof |
| CN103773271A (en) * | 2012-10-23 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel starchy cigarette adhesive based on degradation-type gelatinized starch and esterification-type gelatinized starch |
| CN103773270A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel amyloid cigarette adhesive based on composite modified gelatinized starch |
| CN103773274A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel amyloid cigarette adhesive based on non-gelatinized starch |
| CN103773275A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel amyloid cigarette adhesive based on composite modified gelatinized starch |
| CN103773272A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel amyloid cigarette adhesive based on non-gelatinized starch |
| CN104245742A (en) * | 2012-04-26 | 2014-12-24 | 蒂西苏克拉菲纳德里有限公司 | Adhesive composition |
| CN103773277B (en) * | 2012-10-20 | 2016-04-06 | 中国烟草总公司郑州烟草研究院 | A kind of based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization |
-
2004
- 2004-11-03 CN CNB2004100884475A patent/CN100556973C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102453461A (en) * | 2010-10-21 | 2012-05-16 | 大亚科技股份有限公司 | Forming adhesive for cigarette polypropylene fiber filter tip and preparation method thereof |
| CN104245742A (en) * | 2012-04-26 | 2014-12-24 | 蒂西苏克拉菲纳德里有限公司 | Adhesive composition |
| CN103773270A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel amyloid cigarette adhesive based on composite modified gelatinized starch |
| CN103773274A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel amyloid cigarette adhesive based on non-gelatinized starch |
| CN103773275A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel amyloid cigarette adhesive based on composite modified gelatinized starch |
| CN103773272A (en) * | 2012-10-20 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel amyloid cigarette adhesive based on non-gelatinized starch |
| CN103773277B (en) * | 2012-10-20 | 2016-04-06 | 中国烟草总公司郑州烟草研究院 | A kind of based on etherificate class-pasted starch and the amyloid starchiness cigarette glue of non-gelatinization |
| CN103773272B (en) * | 2012-10-20 | 2018-04-17 | 中国烟草总公司郑州烟草研究院 | Based on the non-amyloid novel starch matter cigarette glue of gelatinization |
| CN103773274B (en) * | 2012-10-20 | 2018-04-17 | 中国烟草总公司郑州烟草研究院 | One kind is based on the non-amyloid novel starch matter cigarette glue of gelatinization |
| CN103773271A (en) * | 2012-10-23 | 2014-05-07 | 中国烟草总公司郑州烟草研究院 | Novel starchy cigarette adhesive based on degradation-type gelatinized starch and esterification-type gelatinized starch |
| CN103773271B (en) * | 2012-10-23 | 2016-05-25 | 中国烟草总公司郑州烟草研究院 | A kind of starchiness cigarette glue based on degraded class-gelatinized starch and esterification class-gelatinized starch |
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