CN1746080A - Bearing container, process and processing apparatus for reinforced fibre polymer of it component - Google Patents
Bearing container, process and processing apparatus for reinforced fibre polymer of it component Download PDFInfo
- Publication number
- CN1746080A CN1746080A CN 200410051327 CN200410051327A CN1746080A CN 1746080 A CN1746080 A CN 1746080A CN 200410051327 CN200410051327 CN 200410051327 CN 200410051327 A CN200410051327 A CN 200410051327A CN 1746080 A CN1746080 A CN 1746080A
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- Prior art keywords
- normal pressure
- carrying container
- fiber
- pressure carrying
- mer
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- 239000000835 fiber Substances 0.000 title claims abstract description 55
- 238000000034 method Methods 0.000 title claims abstract description 25
- 229920000642 polymer Polymers 0.000 title 1
- 229920001169 thermoplastic Polymers 0.000 claims description 18
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 238000000465 moulding Methods 0.000 claims description 8
- -1 polyethylene Polymers 0.000 claims description 8
- 238000001746 injection moulding Methods 0.000 claims description 7
- 229920003023 plastic Polymers 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 239000004744 fabric Substances 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 4
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 238000007664 blowing Methods 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 229920002492 poly(sulfone) Polymers 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 4
- 229920002530 polyetherether ketone Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 229920006324 polyoxymethylene Polymers 0.000 claims description 4
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 4
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 3
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- UMIVXZPTRXBADB-UHFFFAOYSA-N benzocyclobutene Chemical compound C1=CC=C2CCC2=C1 UMIVXZPTRXBADB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- 235000012241 calcium silicate Nutrition 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000004643 cyanate ester Substances 0.000 claims description 2
- 239000002346 layers by function Substances 0.000 claims description 2
- 239000004973 liquid crystal related substance Substances 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 229920002480 polybenzimidazole Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 239000009719 polyimide resin Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 239000004800 polyvinyl chloride Substances 0.000 claims description 2
- 239000004416 thermosoftening plastic Substances 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 230000006835 compression Effects 0.000 abstract description 2
- 238000007906 compression Methods 0.000 abstract description 2
- 229920002430 Fibre-reinforced plastic Polymers 0.000 abstract 2
- 239000011151 fibre-reinforced plastic Substances 0.000 abstract 2
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 10
- 239000011521 glass Substances 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- DSCFFEYYQKSRSV-FEPQRWDDSA-N (1s,2s,4s,5r)-6-methoxycyclohexane-1,2,3,4,5-pentol Chemical compound COC1[C@@H](O)[C@@H](O)C(O)[C@H](O)[C@H]1O DSCFFEYYQKSRSV-FEPQRWDDSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003733 fiber-reinforced composite Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
An ordinary-pressure load-bearing container is fully or partly prepared from the fiber-reinforced polymer. The said fiber has the 1-30 mm in average length and weight ratio of 5-55%. Its advantages are high weight and high compression strength, impact strength and corrosion resistance. The process and apparatus for preparing said fiber reinforced polymer are also disclosed.
Description
Technical field
The present invention relates to the job operation and the equipment of a kind of novel normal pressure carrying container, its component fibre enhancing thermoplastic polymer.
Background technology
The method of making fiber reinforced composite by lamination, parcel, long filament circumvolution with thermosetting resin and/or thermoplastic base resin and fiber has been well-known.
In the patent No. is ZL00803968.2, and name is called composition reinforcing-fiber substrate such as the unidirectional material described in the Chinese patent of " glass fiber reinforced plastic tube and manufacture method thereof " with fiber, fabric, mat, sennit and is formulated in inside and outside the core body.Publication number is that the patent of invention of CN1427036A has been introduced the method for making that is applied to the electronics distribution equipment box on fiber cloth two sides with alkide resin.The fiber casing is to adopt the manufacturing of mould pressing process method in the patent of invention of ZL97107010.5.The manufacture method that adopts multilayer to be made of exocuticle in the screened housing non-woven, woven, long filament or integrated fiber woven cloth has been described in patent of invention ZL99805275.2.
In patent of invention ZL91102677.0, adopt the method for fiber and Resin Wound to make flammable storepipe and jet pipe.The formwork that is used for cylindrical columns in the patent No. is the patent of invention of ZL00804436.8 has used the surrounding layer by the glass web of rolling by helix.Adopt in the application for a patent for invention of publication number CN1082983A and predetermined number is the flat thin and long fibre thin plate of shape thermoplastic plastic of stretching intersects in regular turn and be stacked to ply wood and prepare casing through the mode of mold pressing with predetermined thickness.
Shortcoming such as the described carrying container ubiquity of above-mentioned patent manufacturing cost height, production process are many, complex process, production efficiency are low.
Though in the application for a patent for invention of publication number CN1330024A, be provided with the 1-2% glass fibre and adopt the process of injection mo(u)lding to make isolation-type paint can, but the impact strength of its normal temperature and low temperature is lower, in the load handling process, there is the hidden danger of falling leakage.
Summary of the invention
The object of the present invention is to provide the normal pressure carrying container that a kind of production method is easy, in light weight, ability to bear is strong, anti-erosion, particularly shock resistance are good.
Another object of the present invention is to provide the processing molding method of the fiber reinforced thermolplastic poly-mer of forming above-mentioned normal pressure carrying container.
Another object of the present invention is to provide the equipment of producing the fiber reinforced thermolplastic poly-mer of forming above-mentioned normal pressure carrying container.
Normal pressure normal pressure carrying container of the present invention is that 1～30mm, weight percentage are that 5%～55% fiber reinforced thermolplastic poly-mer is formed by the mean length of fiber partly or entirely.Wherein, the mean length of fiber is preferably 1～16mm, and the weight percentage of fiber is preferably 10～30%.
In the normal pressure carrying container of the present invention, fiber is to be distributed in the thermoplastic polymer uniformly, rather than the method for twining with parcel or tractive is coated on thermoplastic polymer surface, fiber cloth and/or fleece and thermoplastic polymer mold pressing neither be made.
Fiber is one or more in glass fibre, carbon fiber, metal fibre, whisker, grammite, polymer fiber, the vegetable fibre.
In the normal pressure carrying container of the present invention, thermoplastic polymer comprises polyethylene (PE), polypropylene (PP), polyamide (PA), polyvinylchloride (PVC), polyformaldehyde (POM), polymethyl methacrylate (PMMA), polystyrene (PS), polysulfones (PSO), polyphenylene oxide (PPO), polyphenylene sulfide (PPS), polyetheretherketone (PEEK), styrene/acrylonitrile copolymer (SAN), polycarbonate (PC), acronitrile-butadiene-styrene (ABS), polybutylene terephthalate (PBT), polyethylene terephthalate (PET), maleimide resin, cyanate ester resin, polyimide resin, polyurethane, the liquid crystal thermoplastic polymer, the benzocyclobutane olefine resin, in the polybenzimidazoles one or more.
Normal pressure carrying container of the present invention can be at the surfaces externally and internally application of fiber reinforced thermolplastic poly-mer and/or compound other material as functional layer.
Normal pressure carrying container of the present invention, fiber reinforced thermolplastic poly-mer can be used for the one or more structural units or the parts of carrying container, also can constitute the integral body of normal pressure normal pressure carrying container.One or more fiber reinforced thermolplastic constitutional units in the normal pressure carrying container or parts can be by supersonic weldings and/or bonding and/or link to each other with other parts by screw thread, flange fit system.
In the normal pressure carrying container of the present invention, the processing molding method of fiber reinforced thermolplastic poly-mer is for adopting injection moulding, blowing, plastic uptake, extruding process thereof moulding.
The equipment of the moulding of fiber reinforced thermolplastic poly-mer in the normal pressure carrying container of the present invention, for screw rod is extruded and/or injection-moulding device, the screw diameter that it is characterized in that device therefor is not less than 20mm, the nozzle internal diameter is not less than 4mm, the head die gap is not less than 3mm, the flow diameter of injection forming mold is not less than 6mm, and the gate area area is not less than 12mm
2And use dark screw channel screw rod and/or reduce screw speed, make screw back pressure reduce to 0～4 kg/cm
2
Above-mentioned fiber reinforced thermolplastic poly-mer has following characteristics: the mean length of fiber in plastics is preferably at 1～16mm in the following scope of 30mm, and is the staggered pattern that curls.The conservation rate of the pulling strengrth of material, bending strength, toughness, particularly low temperature impact properties (30 ℃) all is improved largely than the chopped fiber enhancing thermoplastic polymer of fibre length at 0.2～1mm.This characteristics particularly suitable has the normal pressure carrying container of anti-drop requirement, as (but being not limited to following) electric appliance casing, interior bucket, casing, the cylindrical shell of loading and/or conveying objects.Because fiber is the staggered state that curls in thermoplastic polymer, not only reduce the anisotropy of plastic product in addition, shown remarkable antifatigue and very low creep, hot expansibility simultaneously.Above-mentioned performance is enough to make this material substitution metal to be used for environment harshness, load-carrying capacity requirement height, the dimensional characteristic normal pressure carrying container that accurately, particularly shock resistance is good.
Common process equipment is done the moulding requirement that suitable improvement just can be satisfied fiber reinforced thermolplastic poly-mer of the present invention.Common Fabricating machinery since in the forming process long fibre in the thermoplastic polymer discharging opening can be stopped up, and when surpassing 16mm, can not further improve the advantage that aforementioned long fibre strengthens formed products, on the contrary, so its appearance variation is not preferred.
It strengthens effect and can reduce significantly and mean length is less than the fiber of 1mm, can not give full play to high strength, impact, good creep properties and the characteristic of the isometric fiber reinforcement formed products of vibration fatigue characteristic.The latter can only be remedied by the way that increases wall thickness and/or reinforced rib, but this will certainly gain in weight and raise the cost.
At this kind situation, solution of the present invention is to select for use screw diameter to be not less than 35mm, and nozzle (nozzle) internal diameter and/or die gap are not less than 4mm, and the mold runner diameter is not less than 5mm, and the gate area area is no less than 10mm
2Fabricating machinery.Even so, as employing extrude, the processing molding method of injection moulding, blowing or plastic uptake, when fibre length during, still have the possibility of obstruction greater than 30mm.So the scope of the length of fiber should be below 30mm.For keeping average fiber length is 1～16mm, and melt-shaping of the present invention must relax the melt-shaping condition with compound, and a little less than the promptly mixing power, feasible being applied under the condition that the shearing force on the molten resin diminishes forms.Be necessary the methods such as rotating speed reduction using the zanjon screw rod and/or make screw rod to make screw back pressure reduce to 0～4kg/mm as far as possible
2Even melt-shaping of the present invention also can fully disperse under the situation that has reduced mixing power like this with the glass fibre in the compound.
That normal pressure carrying container of the present invention has is in light weight, bearing capacity is strong, advantages such as anti-erosion, particularly good impact resistance, and manufacture method is easy, to equipment require low.
The specific embodiment
Embodiment 1:(is an example with 25 cun television rear shells)
Select screw diameter 90mm for use, the injection machine of nozzle (nozzle) internal diameter 6mm, mold runner diameter 10mm, gate area area 20mm
2Fabricating machinery.And screw back pressure transferred to 2 kilograms/mm
2
Selecting the glass weight content for use is 15% acrylic plastering, and the glass mean length is 12mm.Adopt injection molding process to make television rear shell, its wall thickness is 3mm.
Drop test: by complete machine drop test in the GB8898 national standard
Embodiment 2:
Adopt and embodiment 1 identical equipment and fabrication process condition, still use glass weight content 15%, but mean length 0.6mm short glass fiber RPP (PP).The then complete above-mentioned drop test of impassabitity.
Embodiment 3:
Select the acrylic plastering of glass weight content 20% for use, the mean length of its glass is 55mm, and Fabricating machinery and technology and embodiment 1 are identical.But nozzle in the injection molding process (nozzle) is blocked, can not get goods fully.
Embodiment 4:
Select the high-density polyethylene plastics of the fine weight content 50% of carbon for use, the mean length of its fiber is 25mm, adopt the method for extrusion-blown modling, the extruder screw diameter is 90mm, length-diameter ratio is 15: 1, and compression ratio is 1.8: 1, and storing type parison handpiece die orifice diameter is 190mm, the angle of divergence is 30 degree, and the head die gap is 6mm.Parison blowing ratio is less than 3/1, and obtaining average wall thickness is the normal pressure carrying casing of 3mm.Load the 25kg article, can pass through 140cm FCL drop test.
Embodiment 5:
Select the acrylic plastering of glass weight content 20% for use, the mean length of its glass is 55mm, use the equipment identical, but the head die gap is increased to 8mm with embodiment 4, and the normal pressure carrying container that obtains, its rough surface, the scratch resistance performance seriously descends.And impassabitity 50cm drop test.Be not suitable for using as carrying container.
Claims (12)
1, a kind of novel normal pressure carrying container is that 1～30mm, weight percentage are that 5%～55% fiber reinforced thermolplastic poly-mer is formed by the mean length of fiber partly or entirely.
2, normal pressure carrying container according to claim 1, the mean length that it is characterized in that fiber is 1～16mm.
3, normal pressure carrying container according to claim 1, the weight percentage that it is characterized in that fiber is 10～30%.
4, normal pressure carrying container according to claim 1, it is characterized in that fiber is to be distributed in uniformly in the thermoplastic polymer, rather than the method for twining with parcel or tractive is coated on thermoplastic polymer surface, fiber cloth and/or fleece and thermoplastic polymer mold pressing neither be made.
5, normal pressure carrying container according to claim 1 is characterized in that fiber is one or more in glass fibre, carbon fiber, metal fibre, whisker, grammite, thermoplastic polymer fibers, the vegetable fibre.
6, normal pressure carrying container according to claim 1 is characterized in that poly-mer is a thermoplastic base resin.
7, normal pressure carrying container according to claim 1 is characterized in that thermoplastic polymer is polyethylene (PE), polypropylene (PP), polyamide (PA), polyvinylchloride (PVC), polyformaldehyde (POM), polymethyl methacrylate (PMMA), polystyrene (PS), polysulfones (PSO), polyphenylene oxide (PPO), polyphenylene sulfide (PPS), polyetheretherketone (PEEK), styrene/acrylonitrile copolymer (SAN), polycarbonate (PC), acronitrile-butadiene-styrene (ABS), polybutylene terephthalate (PBT), polyethylene terephthalate (PET), maleimide resin, cyanate ester resin, polyimide resin, polyurethane, the liquid crystal thermoplastic polymer, the benzocyclobutane olefine resin, in the polybenzimidazoles one or more.
8, normal pressure carrying container according to claim 1, it is characterized in that can be at the surfaces externally and internally application of fiber reinforced thermolplastic poly-mer and/or compound other material as functional layer.
9, normal pressure carrying container according to claim 1 is characterized in that the fiber reinforced thermolplastic poly-mer can be used for the one or more structural units or the parts of normal pressure carrying container body, also can constitute the integral body of normal pressure carrying container body.
10, a kind of forming method of processing fiber reinforced thermolplastic poly-mer in the normal pressure carrying container body is for adopting injection moulding, blowing, plastic uptake, extruding process thereof moulding.
11, a kind of equipment of processing the moulding of fiber reinforced thermolplastic poly-mer in the normal pressure carrying container, for screw rod is extruded and/or injection-moulding device, the screw diameter that it is characterized in that device therefor is not less than 35mm, the nozzle internal diameter is not less than 4mm, the head die gap is not less than 4mm, the flow diameter of injection forming mold is not less than 5mm, and the gate area area is not less than 10mm
2And use dark screw channel screw rod and/or reduce screw speed, make screw back pressure reduce to 0～4 kg/cm
2
12, the normal pressure carrying container includes a constant volume (but being not limited to following) electric appliance casing, interior bucket, casing, the cylindrical shell of loading and/or conveying objects.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410051327 CN1746080A (en) | 2004-09-06 | 2004-09-06 | Bearing container, process and processing apparatus for reinforced fibre polymer of it component |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410051327 CN1746080A (en) | 2004-09-06 | 2004-09-06 | Bearing container, process and processing apparatus for reinforced fibre polymer of it component |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1746080A true CN1746080A (en) | 2006-03-15 |
Family
ID=36165839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410051327 Pending CN1746080A (en) | 2004-09-06 | 2004-09-06 | Bearing container, process and processing apparatus for reinforced fibre polymer of it component |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1746080A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103649616A (en) * | 2011-07-12 | 2014-03-19 | 科韦斯股份有限公司 | Method for producing pressure-resistant and/or leak-proof containers for holding gases and/or liquids |
| CN103910939A (en) * | 2014-04-24 | 2014-07-09 | 安徽绿建科技有限公司 | Optimal mixture ratio constructing method for plastic support module |
| CN104046026A (en) * | 2014-07-02 | 2014-09-17 | 广州高八二塑料有限公司 | Polyurethane co-mixed modified polyphenylene sulfide composite material and preparation method thereof |
| CN104559072A (en) * | 2013-10-11 | 2015-04-29 | 黑龙江鑫达企业集团有限公司 | A directly on-line compounded long-fiber reinforced thermoplastic material and a preparing method thereof |
| CN107739438A (en) * | 2013-06-04 | 2018-02-27 | Pbi性能产品公司 | The preparation method of polybenzimidazoles |
| CN109068934A (en) * | 2016-05-09 | 2018-12-21 | 阿塞里克股份有限公司 | Household electrical appliance with the staving made of composite material and the technique for producing such staving |
| CN113059885A (en) * | 2021-03-18 | 2021-07-02 | 浙江省林业科学研究院 | Preparation method of moso bamboo fiber bundle reinforced plastic-suction forming packaging container |
-
2004
- 2004-09-06 CN CN 200410051327 patent/CN1746080A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103649616A (en) * | 2011-07-12 | 2014-03-19 | 科韦斯股份有限公司 | Method for producing pressure-resistant and/or leak-proof containers for holding gases and/or liquids |
| CN103649616B (en) * | 2011-07-12 | 2016-01-20 | 科韦斯股份有限公司 | Method for producing pressure-resistant and/or leak-proof containers for holding gases and/or liquids |
| CN107739438A (en) * | 2013-06-04 | 2018-02-27 | Pbi性能产品公司 | The preparation method of polybenzimidazoles |
| CN104559072A (en) * | 2013-10-11 | 2015-04-29 | 黑龙江鑫达企业集团有限公司 | A directly on-line compounded long-fiber reinforced thermoplastic material and a preparing method thereof |
| CN103910939A (en) * | 2014-04-24 | 2014-07-09 | 安徽绿建科技有限公司 | Optimal mixture ratio constructing method for plastic support module |
| CN104046026A (en) * | 2014-07-02 | 2014-09-17 | 广州高八二塑料有限公司 | Polyurethane co-mixed modified polyphenylene sulfide composite material and preparation method thereof |
| CN109068934A (en) * | 2016-05-09 | 2018-12-21 | 阿塞里克股份有限公司 | Household electrical appliance with the staving made of composite material and the technique for producing such staving |
| CN109068934B (en) * | 2016-05-09 | 2022-01-18 | 阿塞里克股份有限公司 | Household appliance having a tub made of composite material and process for producing such a tub |
| CN113059885A (en) * | 2021-03-18 | 2021-07-02 | 浙江省林业科学研究院 | Preparation method of moso bamboo fiber bundle reinforced plastic-suction forming packaging container |
| CN113059885B (en) * | 2021-03-18 | 2022-04-08 | 浙江省林业科学研究院 | A kind of preparation method of bamboo fiber bundle reinforced plastic forming packaging container |
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