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CN1744324A - Cell structure for reducing programming current of phase change memory - Google Patents

Cell structure for reducing programming current of phase change memory Download PDF

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Publication number
CN1744324A
CN1744324A CN 200510028672 CN200510028672A CN1744324A CN 1744324 A CN1744324 A CN 1744324A CN 200510028672 CN200510028672 CN 200510028672 CN 200510028672 A CN200510028672 A CN 200510028672A CN 1744324 A CN1744324 A CN 1744324A
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phase change
layer
heating
alloy phase
chalcogenide alloy
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冯洁
章仪
蔡炳初
陈邦明
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Shanghai Jiao Tong University
Silicon Storage Technology Inc
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Shanghai Jiao Tong University
Silicon Storage Technology Inc
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Abstract

The disclosed unit structure includes substrate of IC, lower pole, alloy phase change layer in chalcogenide, heating layer, upper pole, and layer of insulating medium. The lower pole is setup on substrate, and the upper pole is setup on alloy phase change layer. The alloy phase change layer and the heating layer are inside small hole. Being connected to the lower pole, the heating layer is setup between the low pole and the alloy phase change layer. The invention adds the heating layer of semiconductor, which does not generate phase change, in storage unit. Possessing higher resistance and lower thermal conductivity, the heating layer can lower programmed current, and can generate enough Joule heat to make material of phase change reach melting point. The invention reaches purpose of programming storage cell by using lower current.

Description

降低相变存储器编程电流的单元结构Cell structure for reducing programming current of phase change memory

技术领域technical field

本发明涉及的是一种微电子技术领域的器件,具体地说,是一种降低相变存储器编程电流的单元结构。The invention relates to a device in the technical field of microelectronics, in particular to a unit structure for reducing the programming current of a phase-change memory.

背景技术Background technique

相变存储器技术的基本原理是利用相变材料作为存储介质,相变材料在晶态和非晶态时电阻率有很大的差异,采用编程的电脉冲可以使相变存储单元在晶态和非晶态之间可逆的转换。而且存储单元的状态是非易失性的,即当设置为任意一个状态时,即使切断电源,存储单元仍保持为该状态的电阻值,除非重新设置存储单元的状态。典型的相变材料是硫族化物合金薄膜,一种特别适合的材料是GeSbTe合金。存储单元包括由电介质材料定义的细孔,相变材料沉积在细孔中,相变材料在细孔的一端上连接电极。电极接触使电流通过该通道产生焦耳热对该单元进行编程,或者读取该单元的电阻状态。当前的相变存储器采用W,或者TiW合金等作为电极材料,而W的电阻率很低(5.39×10-8Ω.m),而热导率很高(178W/mK),不利于对相变介质进行加热。当相变材料处于晶态时,存储单元的电阻很低,要产生足够的焦耳热使相变材料达到熔点,必须增加编程电流密度,由此将影响器件的稳定性和可靠性。The basic principle of phase-change memory technology is to use phase-change materials as storage media. The resistivity of phase-change materials is very different in crystalline and amorphous states. Using programmed electric pulses can make phase-change memory cells in crystalline and amorphous states. Reversible transition between amorphous states. Moreover, the state of the storage unit is non-volatile, that is, when it is set to any state, even if the power is cut off, the storage unit still maintains the resistance value of the state, unless the state of the storage unit is reset. Typical phase change materials are chalcogenide alloy thin films, and a particularly suitable material is GeSbTe alloy. The memory cell includes a pore defined by a dielectric material in which a phase change material is deposited, the phase change material being connected to an electrode on one end of the pore. Electrode contacts allow current to flow through the channel to generate Joule heating to program the cell, or to read the resistive state of the cell. The current phase change memory uses W or TiW alloy as the electrode material, and the resistivity of W is very low (5.39×10 -8 Ω.m), and the thermal conductivity is very high (178W/mK), which is not conducive to the phase change. Change medium for heating. When the phase-change material is in the crystalline state, the resistance of the memory cell is very low. To generate enough Joule heat to make the phase-change material reach the melting point, the programming current density must be increased, which will affect the stability and reliability of the device.

经对现有技术文献的检索发现,2003年,Samsung公司在每年一度的IEEE国际电子器件会议(IEDM)上提出采用TiN/W作为电极材料(“Writing currentreduction for high-density phase-change RAM”(降低高密度相变存储器的写电流),Y.N.Hwang,S.H.Lee,et al.IEDM,2003,pp893),而TiN具有较高的电阻率(2×10-7~1×10-5Ω.m)。2005年,中科院微系统与信息技术研究所夏吉林等提出在电极和相变材料之间加入一层过渡层的专利(中国专利:一种减小相变存储器写入电流的单元结构的改进及方法,专利公开号CN1564337A,公开日:2005年1月12日),所提出的过渡层为Pt,Ti,TiN。当金属过渡层的电阻低于相变介质晶态电阻时,不能产生较大的焦耳热,起不到辅助发热的作用。因此,通过采用更加适合的加热层材料,当相变介质处于低阻态时,利用加热层产生的焦耳热使相变材料达到熔点,可以更加有效的降低编程电流,从而提高器件的稳定性和可靠性。After searching the prior art documents, it was found that in 2003, Samsung proposed to use TiN/W as the electrode material ("Writing current reduction for high-density phase-change RAM" ( reduce the write current of high-density phase change memory), YNHwang, SHLee, et al.IEDM, 2003, pp893), and TiN has a higher resistivity (2×10 -7 ~ 1×10 -5 Ω.m). In 2005, Xia Jilin, Institute of Microsystem and Information Technology, Chinese Academy of Sciences, etc. proposed a patent for adding a transition layer between the electrode and the phase change material (Chinese patent: an improvement and improvement of the cell structure for reducing the writing current of the phase change memory method, patent publication number CN1564337A, publication date: January 12, 2005), the proposed transition layer is Pt, Ti, TiN. When the resistance of the metal transition layer is lower than the crystalline resistance of the phase change medium, it cannot generate large Joule heat and cannot play the role of auxiliary heating. Therefore, by adopting a more suitable material for the heating layer, when the phase change medium is in a low-resistance state, the Joule heat generated by the heating layer can be used to make the phase change material reach the melting point, which can reduce the programming current more effectively, thereby improving the stability and reliability of the device. reliability.

发明内容Contents of the invention

本发明的目的在于克服现有技术的不足,提供一种降低相变存储器编程电流的单元结构,使其在存储单元中增加一层不发生相变的半导体加热层,该加热层具有较高的电阻和较低的热传导系数,能够降低编程电流同时产生足够的焦耳热使相变材料到达熔点,从而达到使用较低的电流对存储单元进行编程的目的。The purpose of the present invention is to overcome the deficiencies of the prior art, to provide a cell structure that reduces the programming current of the phase-change memory, so that a semiconductor heating layer that does not undergo phase change is added in the memory cell, and the heating layer has a higher The resistance and lower thermal conductivity can reduce the programming current while generating enough Joule heat to make the phase change material reach the melting point, so as to achieve the purpose of using lower current to program the memory cell.

本发明是通过以下技术方案实现的,本发明包括:集成电路衬底、下电极、硫族化物合金相变层、加热层、上电极、绝缘介质层,在集成电路衬底上设有下电极,上电极设在硫族化物合金相变层上,硫族化物合金相变层和加热层设在绝缘介质层的小孔内,加热层设在下电极和硫族化物合金相变层之间,加热层与下电极相连接。The present invention is achieved through the following technical solutions. The present invention includes: an integrated circuit substrate, a lower electrode, a chalcogenide alloy phase change layer, a heating layer, an upper electrode, and an insulating medium layer, and the lower electrode is arranged on the integrated circuit substrate , the upper electrode is arranged on the chalcogenide alloy phase change layer, the chalcogenide alloy phase change layer and the heating layer are arranged in the small hole of the insulating medium layer, and the heating layer is arranged between the lower electrode and the chalcogenide alloy phase change layer, The heating layer is connected with the lower electrode.

本发明的另一种形式为:集成电路衬底、下电极、硫族化物合金相变层、加热层、上电极、绝缘介质层,在集成电路衬底上设有下电极,上电极设在硫族化物合金相变层上,硫族化物合金相变层和加热层设在绝缘介质层的小孔内,加热层设在硫族化物合金相变层中间。Another form of the present invention is: an integrated circuit substrate, a lower electrode, a chalcogenide alloy phase change layer, a heating layer, an upper electrode, and an insulating medium layer. The lower electrode is arranged on the integrated circuit substrate, and the upper electrode is arranged on On the chalcogenide alloy phase change layer, the chalcogenide alloy phase change layer and the heating layer are arranged in the small holes of the insulating medium layer, and the heating layer is arranged in the middle of the chalcogenide alloy phase change layer.

所述的下电极的面积由绝缘介质层的小孔所限制。The area of the lower electrode is limited by the small holes in the insulating medium layer.

所述的下电极的面积小于上电极的面积,以获得更大的电流密度。The area of the lower electrode is smaller than that of the upper electrode to obtain a larger current density.

所述的加热层为半导体,电阻率在10-6~102Ω.m之间。The heating layer is a semiconductor with a resistivity between 10 -6 and 10 2 Ω.m.

所述的加热层,其厚度为3-40nm。The heating layer has a thickness of 3-40nm.

脉冲电流通过一端电极,如下电极流入存储单元,电流通过加热层、硫族化物合金相变层之后从另一端电极流出,采用编程的电脉冲可以使硫族化物合金相变层在晶态(低阻态)和非晶态(高阻态)之间可逆的转换。绝缘介质层定义了存储单元尺寸并防止存储单元之间的扩散和热串扰。当较小的脉冲电流流入存储单元进行Set(晶化)过程时,其中的硫族化物合金相变层处于高阻态,流入的脉冲电流使得硫族化物合金相变层产生焦耳热,并使硫族化物合金相变层受热结晶转变为低阻态。当较大的脉冲电流流入存储单元进行Reset(非晶化)过程时,其中的硫族化物合金相变层处于低阻态,产生的焦耳热很少,如果仅仅依靠硫族化物合金相变层自身发热到达熔点,则需要很大的电流。增加了加热层之后,脉冲电流通过时,产生的焦耳热将集中在电阻较大的加热层区域,加热层产生的焦耳热可以使相邻的硫族化物合金相变层被加热。由于加热层的电阻比硫族化物合金相变层在晶态时的电阻大,较小的电流脉冲就能使硫族化物合金相变层被加热到达熔点,实现硫族化物合金相变层的非晶化,从而达到有效降低编程电流的目的。The pulse current passes through one end electrode, the lower electrode flows into the storage unit, the current flows out from the other end electrode after passing through the heating layer and the chalcogenide alloy phase change layer, and the programmed electric pulse can make the chalcogenide alloy phase change layer in the crystalline state (low Resistance state) and the reversible transition between the amorphous state (high resistance state). The insulating dielectric layer defines memory cell dimensions and prevents diffusion and thermal crosstalk between memory cells. When a small pulse current flows into the memory cell for the Set (crystallization) process, the chalcogenide alloy phase change layer is in a high-resistance state, and the incoming pulse current causes the chalcogenide alloy phase change layer to generate Joule heat and make the The crystallization of the chalcogenide alloy phase change layer is transformed into a low-resistance state by heating. When a large pulse current flows into the memory cell for Reset (amorphization) process, the chalcogenide alloy phase change layer is in a low-resistance state, and the Joule heat generated is very little. If only relying on the chalcogenide alloy phase change layer Self-heating to reach the melting point requires a large current. After the heating layer is added, when the pulse current passes, the generated Joule heat will be concentrated in the area of the heating layer with higher resistance, and the Joule heat generated by the heating layer can heat the adjacent chalcogenide alloy phase change layer. Since the resistance of the heating layer is larger than that of the chalcogenide alloy phase change layer in the crystalline state, a small current pulse can heat the chalcogenide alloy phase change layer to the melting point, realizing the chalcogenide alloy phase change layer Amorphization, so as to achieve the purpose of effectively reducing the programming current.

本发明的有益效果是:当存储器中相变介质从低阻态转变到高阻态(即Reset过程)时,由于相变介质的电阻低,如果完全依靠相变介质自身发热,则需要很大的电流。在存储单元结构中增加了加热层之后,电流产生的焦耳热将集中在电阻较大的加热层区域,利用加热层产生的焦耳热辅助相变材料达到熔点,可以更加有效的降低编程电流。由于存储器编程电流是由外围的MOSFET(氧化物场效应管)电路提供,降低编程电流可以达到减小存储器外围电路面积,降低器件功耗,提高器件稳定性的目的。The beneficial effects of the present invention are: when the phase-change medium in the memory changes from the low-resistance state to the high-resistance state (i.e. the Reset process), because the resistance of the phase-change medium is low, if relying entirely on the phase-change medium itself to generate heat, it will take a large current. After the heating layer is added in the memory cell structure, the Joule heat generated by the current will be concentrated in the area of the heating layer with higher resistance. Using the Joule heat generated by the heating layer to assist the phase change material to reach the melting point can reduce the programming current more effectively. Since the memory programming current is provided by a peripheral MOSFET (Oxide Field Effect Transistor) circuit, reducing the programming current can achieve the purpose of reducing the memory peripheral circuit area, reducing device power consumption, and improving device stability.

附图说明Description of drawings

图1为本发明实施例1的结构示意图。Fig. 1 is a schematic structural diagram of Embodiment 1 of the present invention.

图2为本发明实施例2的结构示意图。Fig. 2 is a schematic structural diagram of Embodiment 2 of the present invention.

具体实施方式Detailed ways

实施例1Example 1

如图1所示,本发明包括:集成电路衬底1、下电极2、硫族化物合金相变层3、加热层4、上电极5、绝缘介质层6,在集成电路衬底1上设有下电极2,上电极5设在硫族化物合金相变层3上,硫族化物合金相变层3和加热层4设在绝缘介质层6的小孔内,加热层4设在下电极2和硫族化物合金相变层3之间,加热层4与下电极2相连接。As shown in Figure 1, the present invention includes: an integrated circuit substrate 1, a lower electrode 2, a chalcogenide alloy phase change layer 3, a heating layer 4, an upper electrode 5, and an insulating medium layer 6, and an integrated circuit substrate 1 is provided with There is a lower electrode 2, the upper electrode 5 is arranged on the chalcogenide alloy phase change layer 3, the chalcogenide alloy phase change layer 3 and the heating layer 4 are arranged in the small hole of the insulating medium layer 6, and the heating layer 4 is arranged on the lower electrode 2 Between the chalcogenide alloy phase change layer 3 , the heating layer 4 is connected to the lower electrode 2 .

所述的下电极2的面积由绝缘介质层6的小孔所限制。The area of the lower electrode 2 is limited by the small holes in the insulating medium layer 6 .

所述的下电极2的面积小于上电极5的面积,以获得更大的电流密度。The area of the lower electrode 2 is smaller than the area of the upper electrode 5 to obtain greater current density.

所述的加热层4为半导体,电阻率在10-5~102Ω.m之间。The heating layer 4 is a semiconductor with a resistivity between 10 -5 -10 2 Ω.m.

所述的加热层4,其厚度为3-40nm。The heating layer 4 has a thickness of 3-40nm.

实施例2Example 2

如图2所示,本发明包括:集成电路衬底1、下电极2、硫族化物合金相变层3、加热层4、上电极5、绝缘介质层6,在集成电路衬底1上设有下电极2,上电极5设在硫族化物合金相变层3上,硫族化物合金相变层3和加热层4设在绝缘介质层6的小孔内,加热层4设在硫族化物合金相变层3中间。As shown in Figure 2, the present invention includes: an integrated circuit substrate 1, a lower electrode 2, a chalcogenide alloy phase change layer 3, a heating layer 4, an upper electrode 5, and an insulating medium layer 6, and an integrated circuit substrate 1 is provided with There is a lower electrode 2, an upper electrode 5 is arranged on the chalcogenide alloy phase change layer 3, the chalcogenide alloy phase change layer 3 and the heating layer 4 are arranged in the small hole of the insulating medium layer 6, and the heating layer 4 is arranged on the chalcogenide alloy phase change layer 3. In the middle of the compound alloy phase change layer 3 .

所述的下电极2的面积由绝缘介质层6的小孔所限制。The area of the lower electrode 2 is limited by the small holes in the insulating medium layer 6 .

所述的下电极2的面积小于上电极5的面积,以获得更大的电流密度。The area of the lower electrode 2 is smaller than the area of the upper electrode 5 to obtain greater current density.

所述的加热层4为半导体,电阻率在10-5~102Ω.m之间。The heating layer 4 is a semiconductor with a resistivity between 10 -5 -10 2 Ω.m.

所述的加热层4,其厚度为3-40nm。The heating layer 4 has a thickness of 3-40nm.

Claims (6)

1. cellular construction that reduces the phase transition storage program current, comprise: integrated circuit substrate (1), bottom electrode (2), chalcogenide alloy phase change layer (3), top electrode (5), insulating medium layer (6), it is characterized in that, also comprise: zone of heating (4), on integrated circuit substrate (1), be provided with bottom electrode (2), top electrode (5) is located on the chalcogenide alloy phase change layer (3), chalcogenide alloy phase change layer (3) and zone of heating (4) are located in the aperture of insulating medium layer (6), zone of heating (4) is located between bottom electrode (2) and the chalcogenide alloy phase change layer (3), and zone of heating (4) is connected with bottom electrode (2).
2. cellular construction that reduces the phase transition storage program current, comprise: integrated circuit substrate (1), bottom electrode (2), chalcogenide alloy phase change layer (3), top electrode (5), insulating medium layer (6), it is characterized in that, also comprise: zone of heating (4), on integrated circuit substrate (1), be provided with bottom electrode (2), top electrode (5) is located on the chalcogenide alloy phase change layer (3), chalcogenide alloy phase change layer (3) and zone of heating (4) are located in the aperture of insulating medium layer (6), and zone of heating (4) is located in the middle of the chalcogenide alloy phase change layer (3).
3. the cellular construction of reduction phase transition storage program current according to claim 1 and 2 is characterized in that, the area of described bottom electrode (2) is limited by the aperture of insulating medium layer (6).
4. the cellular construction of reduction phase transition storage program current according to claim 3 is characterized in that, the area of described bottom electrode (2) is less than the area of top electrode (5).
5. the cellular construction of reduction phase transition storage program current according to claim 1 and 2 is characterized in that, described zone of heating (4) is a semiconductor, and resistivity is 10 -5~10 2Between the Ω .m.
6. according to the cellular construction of claim 1 or 2 or 5 described reduction phase transition storage program currents, it is characterized in that described zone of heating (4), its thickness are 3-40nm.
CN 200510028672 2005-08-11 2005-08-11 Cell structure for reducing programming current of phase change memory Pending CN1744324A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100568569C (en) * 2007-04-10 2009-12-09 国际商业机器公司 Semiconductor structure and manufacturing method thereof
CN101308903B (en) * 2007-05-14 2011-06-08 财团法人工业技术研究院 phase change memory
CN101911296B (en) * 2008-06-18 2012-08-22 佳能安内华股份有限公司 Phase-change memory element, phase-change memory unit, vacuum processing equipment and manufacturing method of phase-change memory element

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100568569C (en) * 2007-04-10 2009-12-09 国际商业机器公司 Semiconductor structure and manufacturing method thereof
CN101308903B (en) * 2007-05-14 2011-06-08 财团法人工业技术研究院 phase change memory
CN101911296B (en) * 2008-06-18 2012-08-22 佳能安内华股份有限公司 Phase-change memory element, phase-change memory unit, vacuum processing equipment and manufacturing method of phase-change memory element

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