CN1632629A - "One" shape polarization maintaining optical fiber and production method thereof - Google Patents
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Abstract
Description
一、技术领域:1. Technical field:
本发明涉及一种保偏光纤,尤其是涉及一种“一”字型保偏光纤及其生产方法。The invention relates to a polarization-maintaining optical fiber, in particular to a "one"-shaped polarization-maintaining optical fiber and a production method thereof.
二、背景技术:2. Background technology:
保偏光纤又称偏振保持光纤,是特种光纤的一种。它在波分复用的通信系统和光纤传感器领域有着广泛的应用。尤其在光纤传感器领域,它是光纤陀螺、光纤水听器、光集成器件等军用传感器的核心传感元部件。Polarization maintaining fiber, also known as polarization maintaining fiber, is a kind of special fiber. It has a wide range of applications in the field of wavelength division multiplexing communication systems and fiber optic sensors. Especially in the field of fiber optic sensors, it is the core sensing component of military sensors such as fiber optic gyroscopes, fiber optic hydrophones, and optical integrated devices.
根据横截面结构的不同,国际上商用的保偏光纤常见的有四种类型,即:熊猫型、领结型、椭圆茄克型和椭圆芯型。前三种类型属于应力诱导型,后一种类型则属于形状决定型。According to the different cross-sectional structures, there are four common types of polarization-maintaining optical fibers commercially available in the world, namely: panda type, bow tie type, elliptical jacket type and elliptical core type. The first three types belong to the stress-induced type, while the latter type belongs to the shape-determined type.
目前石英光纤一般都通过先制造预制棒(保偏光纤的预制棒又称为保偏光棒),再将预制棒拉丝的办法来制得,保偏光纤也不例外。At present, silica optical fiber is generally produced by first manufacturing a preform (the preform of polarization-maintaining optical fiber is also called polarization-maintaining optical rod), and then drawing the preform, and polarization-maintaining optical fiber is no exception.
应力诱导型的保偏光棒一般是通过在纤芯的周围掺杂或放置一些膨胀系数高的物质(如硼、铝、锗等),通过某种特别的处理手段,使这些掺杂或放置的区域变成非圆对称的应力作用区而制成的。Stress-induced polarization-maintaining rods are generally doped or placed around the fiber core with substances with high expansion coefficients (such as boron, aluminum, germanium, etc.), and through some special treatment, these doped or placed The area becomes a non-circularly symmetrical stress application area.
由于硼的膨胀系数大于硅,甚至大于锗,所以掺硼后,在塌缩成棒后的冷却过程中,以及拉丝后光纤的冷却过程中,应力作用区会对芯层和内包层产生拉应力。由于应力作用区呈各向异性,所以沿光纤不同的径向,芯层受到的应力大小不同,导致芯层在不同径向上的折射率不同,这就是所谓的双折射现象。光在这样的光纤中传播时,各个方向传播的速度也不同,形成相应的快轴和慢轴。Since the expansion coefficient of boron is greater than that of silicon, even greater than that of germanium, after boron doping, during the cooling process after collapsing into a rod, and during the cooling process of the optical fiber after drawing, the stress action area will produce tensile stress on the core layer and inner cladding. . Since the stress action area is anisotropic, the stress on the core layer is different along different radial directions of the fiber, resulting in different refractive indices of the core layer in different radial directions, which is the so-called birefringence phenomenon. When light propagates in such an optical fiber, the speed of propagation in each direction is also different, forming a corresponding fast axis and slow axis.
线偏振光注入到保偏光纤芯层的某一个轴上,经过一段传输距离后,仍能基本保持其偏振态。快轴和慢轴一般与应力作用区的长短轴相重合。表征偏振保持性能好坏的参数是偏振串音或消光比。偏振串音越小(它一般是一个负数),其绝对值越大,则说明该光纤偏振保持的性能越好。Linearly polarized light is injected into a certain axis of the polarization-maintaining fiber core layer, and after a certain transmission distance, its polarization state can still be basically maintained. The fast axis and slow axis generally coincide with the long and short axes of the stress action zone. The parameter that characterizes the performance of polarization maintenance is polarization crosstalk or extinction ratio. The smaller the polarization crosstalk (it is generally a negative number) and the larger its absolute value, the better the polarization-maintaining performance of the fiber.
由于光能在光纤中的传输不仅仅局限在芯层,有相当一部分光功率在紧邻芯层的部分内包层中传输,而硼在石英光纤工作波长(1200-1600nm)区间内的衰减很大,所以在几种应力诱导型保偏光纤中一般都引入内包层,这样可以大大降低光纤的衰减,使光纤的衰减水平达到低于2.0dB/km的适用水平。Since the transmission of light energy in the optical fiber is not limited to the core layer, a considerable part of the optical power is transmitted in the inner cladding layer adjacent to the core layer, and boron has a large attenuation in the working wavelength range (1200-1600nm) of the silica fiber. Therefore, the inner cladding is generally introduced into several kinds of stress-induced polarization-maintaining optical fibers, which can greatly reduce the attenuation of the optical fiber, and make the attenuation level of the optical fiber reach the applicable level below 2.0dB/km.
一般的熊猫型和领结型的保偏光纤,要达到光纤陀螺等传感器的使用要求,其应力作用区的面积占光纤横截面积的比例一般要大于10%,有些产品的比例甚至超过15%。应力作用区往往掺硼等价格很贵的物质,应力作用区过大,除了制造成本会明显增加外,而且制造难度也会变大。另外,应力作用区面积过大,还会导致保偏光纤在环境温度适应性、耐弯曲性能、机械强度等使用性能方面出现问题,导致保偏光纤的综合性能不佳。For ordinary panda-type and bow-tie-type polarization-maintaining fibers, to meet the requirements of sensors such as fiber optic gyroscopes, the ratio of the area of the stress action area to the cross-sectional area of the fiber is generally greater than 10%, and the proportion of some products even exceeds 15%. The stress action area is often doped with boron and other expensive substances. If the stress action area is too large, not only the manufacturing cost will increase obviously, but also the manufacturing difficulty will become greater. In addition, if the area of the stress action area is too large, it will also cause problems in the performance of the polarization-maintaining fiber in terms of environmental temperature adaptability, bending resistance, mechanical strength, etc., resulting in poor overall performance of the polarization-maintaining fiber.
有些椭圆茄克型保偏光纤的应力作用区的相对面积虽然比较小,但是这些椭圆茄克型保偏光纤在一些工作波长处(如1310nm或1550nm)的拍长等技术指标,却很难符合光纤陀螺等传感器的使用要求。Although the relative area of the stress action area of some elliptical jacket-type polarization-maintaining fibers is relatively small, the technical indicators such as the beat length of these elliptical-jacket-type polarization-maintaining fibers at some operating wavelengths (such as 1310nm or 1550nm) are difficult to meet the requirements of fiber optic gyroscopes. and other sensor requirements.
三、技术内容:3. Technical content:
针对其他结构的保偏光纤的上述缺点,本发明的目的在于提供一种具有新的应力作用区形状和应力作用区的面积占光纤横截面积的比例较小的保偏光纤。In view of the above-mentioned shortcomings of other structures of polarization-maintaining optical fibers, the purpose of the present invention is to provide a polarization-maintaining optical fiber with a new shape of the stress application area and a smaller ratio of the area of the stress application area to the cross-sectional area of the optical fiber.
本发明的技术内容为:一种新型的保偏光纤,其横截面结构由外到里分别是:基管层、外包层、应力作用区、内包层和芯层,其特征为:应力作用区的形状为“一”字长条形。The technical content of the present invention is: a new type of polarization-maintaining optical fiber, its cross-sectional structure from outside to inside is: base tube layer, outer cladding, stress action area, inner cladding and core layer, which is characterized by: stress action area The shape is "one" long strip.
“一”字型保偏光纤各层的主要组分如下:The main components of each layer of the "one" shape polarization maintaining fiber are as follows:
基管层:二氧化硅;Substrate layer: silica;
外包层:二氧化硅,掺杂元素:磷和氟;Outer cladding: silicon dioxide, doping elements: phosphorus and fluorine;
应力作用区:二氧化硅,掺杂元素:硼、锗等;Stress action area: silicon dioxide, doping elements: boron, germanium, etc.;
内包层:二氧化硅,也可适当掺杂锗和氟;Inner cladding: silicon dioxide, can also be properly doped with germanium and fluorine;
芯层:二氧化硅,掺杂元素:锗。Core layer: silicon dioxide, doping element: germanium.
中国专利椭圆茄克型光纤预制棒和保偏光纤的结构和制造方法,公开号为CN1410375A,公开了椭圆茄克型光纤预制棒和保偏光纤的结构和制造方法。本发明的“一”字型保偏光纤与椭圆茄克型保偏光纤结构有相似之处:即应力作用区既有长轴又有短轴;不同的是:本发明的“一”字型保偏光纤的应力作用区的短轴与椭圆茄克型保偏光纤的应力作用区的短轴相比非常薄,这可以明显改善保偏光纤的拍长和偏振串音等重要的使用指标。The structure and manufacturing method of the Chinese patent elliptical jacket-type optical fiber preform and polarization-maintaining optical fiber, the publication number is CN1410375A, discloses the structure and manufacturing method of the elliptical jacket-type optical fiber preform and polarization-maintaining optical fiber. The structure of the "one"-shaped polarization-maintaining optical fiber of the present invention is similar to that of the elliptical jacket-shaped polarization-maintaining optical fiber: that is, the stress action area has both a major axis and a short axis; the difference is that the "one"-shaped polarization-maintaining fiber of the present invention The minor axis of the stress action zone of the polarization maintaining fiber is very thin compared with that of the stress action area of the elliptical jacket type polarization maintaining fiber, which can significantly improve important performance indicators such as beat length and polarization crosstalk of the polarization maintaining fiber.
“一”字型保偏光纤的应力作用区的面积占光纤横截面面积的比例小于10%,有些型号的比例甚至可小于5%。The proportion of the area of the stress acting area of the "one"-shaped polarization maintaining optical fiber to the cross-sectional area of the optical fiber is less than 10%, and the proportion of some models can even be less than 5%.
本发明的另一目的在于提供“一”字型保偏光纤的生产方法。Another object of the present invention is to provide a production method of "one"-shaped polarization maintaining optical fiber.
目前石英光纤一般都通过先制造预制棒,再将预制棒拉丝的办法来制得,保偏光纤也不例外。At present, silica optical fiber is generally produced by first manufacturing a preform and then drawing the preform, and polarization maintaining optical fiber is no exception.
“一”字型保偏光纤由“一”字型保偏光棒采用公知的拉丝技术,即将保偏光棒拉细成石英光纤,并在其外围马上涂上两层丙烯酸酯类的涂料进行保护,涂料再经紫外固化处理,制得“一”字型保偏光纤。The "one"-shaped polarization-maintaining optical fiber is made of the "one"-shaped polarization-maintaining rod using the known drawing technology, that is, the polarization-maintaining rod is thinned into a quartz fiber, and two layers of acrylic paint are immediately coated on its periphery for protection. The coating is then cured by ultraviolet light to produce a "one"-shaped polarization-maintaining optical fiber.
由于“一”字型保偏光纤由“一”字型保偏光棒拉细制得,所以“一”字型保偏光棒其横截面结构由外到里也应该是:基管层、外包层、应力作用区、内包层和芯层,应力作用区的形状为“一”字长条形,应力作用区的面积占光棒横截面面积的比例小于10%。Since the "one"-shaped polarization-maintaining optical fiber is made from the "one"-shaped polarization-maintaining optical rod, the cross-sectional structure of the "one"-shaped polarization-maintaining optical rod should also be: base tube layer, outer cladding 1. The stress action area, the inner cladding and the core layer, the shape of the stress action area is a "one" long strip shape, and the area of the stress action area accounts for less than 10% of the cross-sectional area of the optical rod.
MCVD法为公知的生产预制棒的方法,利用此法,生产“一”字型保偏光棒与生产领结型保偏光棒在工艺上基本相同,不同之处是:在进行定向刻蚀时领结型光棒的刻蚀工艺将基管内壁对向两侧的应力作用区刻得很透,从而使塌缩后的保偏光棒的应力作用区呈领结型;而“一”字型保偏光棒的刻蚀工艺将基管内壁对向两侧的应力作用区不完全刻透,让该处的应力作用区留有一点厚度,即使基管内沉积的应力层不完全分开,从而使塌缩后的保偏光棒的应力作用区呈“一”字长条形。The MCVD method is a well-known method for producing preforms. Using this method, the production of "one"-shaped polarization-maintaining rods is basically the same as the production of bow-tie-type polarization-maintaining rods. The etching process of the light rod carves the stress action area on both sides of the inner wall of the substrate very transparently, so that the stress action area of the collapsed polarization maintaining light rod is bow tie-shaped; The etching process does not completely penetrate the stress action area on both sides of the inner wall of the substrate tube, so that the stress action area there is left with a little thickness, even if the stress layer deposited in the base tube is not completely separated, so that the collapsed preservation The stress action area of the polarizer is in the shape of a "one" long strip.
公知的制造领结型保偏光纤的主要步骤为:The main steps of known manufacturing bow-tie type polarization maintaining optical fiber are:
1、先对基管进行预处理,预处理可以达到使基管预热和有效消除基管内壁杂质和气泡的效果;1. Pretreat the base tube first, which can achieve the effect of preheating the base tube and effectively eliminating impurities and air bubbles on the inner wall of the base tube;
2、随后进行沉积工序,沉积工序依次为外包层沉积、应力层沉积、内包层沉积和芯层沉积;其中在应力层沉积工序结束后进行刻蚀工艺,使被加热处的基管内侧的应力层被逐渐刻蚀透;2. The deposition process is carried out subsequently, and the deposition process is followed by outer cladding deposition, stress layer deposition, inner cladding deposition and core layer deposition; where the etching process is carried out after the stress layer deposition process is completed, so that the stress inside the substrate tube at the heated place The layer is gradually etched through;
3、沉积结束后对基管进行正向塌缩和反向塌缩,制成一根实心的领结型保偏光棒;3. After the deposition is completed, perform forward and reverse collapse on the base tube to make a solid bow-tie type polarization-maintaining light rod;
4、塌缩结束后,对保偏光棒进行抛光,制得呈石英的透明状的领结型保偏光棒。4. After the collapse, the polarization-maintaining light rod is polished to obtain a quartz-like transparent bow-tie type polarization-maintaining light rod.
5、将保偏光棒拉细,制得领结型保偏光纤。5. Thinning the polarization-maintaining rod to obtain a bow-tie type polarization-maintaining optical fiber.
“一”字型保偏光纤的生产方法,其生产步骤如下:The production method of "one"-shaped polarization-maintaining optical fiber, the production steps are as follows:
1、基管的预处理,使基管预热和有效消除基管内壁的杂质和气泡;1. Pretreatment of the substrate tube, to preheat the substrate tube and effectively eliminate impurities and bubbles on the inner wall of the substrate tube;
2、进行沉积工序,沉积工序依次为外包层沉积、应力层沉积、内包层沉积和芯层沉积;其中在应力层沉积工序结束后进行定向刻蚀,使被加热处的基管内侧的应力层被逐渐刻蚀,且使该处的应力作用区不被完全刻透,让该处的应力作用区留有一点厚度,基管内沉积的应力层不完全分开;定向刻蚀即为使基管不再转动,在基管内通有含氟的腐蚀性气体;在基管外用一束火头或两边对烧的两束火头沿基管的轴向来回移动;2. Carry out the deposition process. The deposition process is followed by outer cladding deposition, stress layer deposition, inner cladding deposition and core layer deposition; where after the stress layer deposition process is finished, directional etching is carried out, so that the stress layer inside the substrate tube at the heated place It is gradually etched, and the stress action area at this place is not completely etched, so that the stress action area at this place has a little thickness, and the stress layer deposited in the substrate tube is not completely separated; directional etching is to make the substrate tube not Rotate again, there is fluorine-containing corrosive gas in the base tube; outside the base tube, use a bunch of fire heads or two fire heads that burn on both sides to move back and forth along the axis of the base tube;
3、对基管进行正向塌缩和反向塌缩,制成一根实心的“一”字型保偏光棒;3. Perform forward collapse and reverse collapse on the base tube to make a solid "one"-shaped polarization-maintaining light rod;
4、对保偏光棒进行抛光,制得呈石英的透明状的“一”字型保偏光棒;4. Polish the polarization-maintaining light rod to obtain a quartz transparent "one"-shaped polarization-maintaining light rod;
5、将保偏光棒拉细成石英光纤,并在其外围马上涂上两层丙烯酸酯类的涂料进行保护,涂料再经紫外固化处理,制得“一”字型保偏光纤。5. Thin the polarization-maintaining light rod into a quartz optical fiber, and immediately coat two layers of acrylic paint on its periphery for protection, and the coating is then cured by ultraviolet light to obtain a "one"-shaped polarization-maintaining optical fiber.
以上生产方法中,当定向刻蚀时在基管外用一束火头时,该束火头沿基管一侧的轴向来回移动,一侧刻蚀完成后,将基管翻转180度,然后对基管的另一侧进行刻蚀。In the above production method, when a bundle of fire heads is used outside the substrate tube during directional etching, the bundle of fire heads moves back and forth along the axial direction of one side of the substrate tube. After one side is etched, the substrate tube is turned 180 degrees, and then The other side of the tube is etched.
以上生产方法中,当定向刻蚀时在基管外用两边对烧的两束火头时,两束火头在通过基管中心的平面内沿基管的轴向对称地在基管的两侧进行来回移动以加热管壁。In the above production method, when two beams of fire heads are used on both sides of the substrate tube for directional etching, the two beams of fire heads will go back and forth on both sides of the substrate tube symmetrically along the axis of the substrate tube in the plane passing through the center of the substrate tube. Move to heat the tube walls.
随着MCVD设备的不断改进,可使用的基管越来越粗,基管的壁厚也允许较大,由此制得的单根预制棒的体积也越来越大,可拉光纤的长度也越来越长,生产成本可以明显降低,而单批光纤各项参数的均匀性则可明显改善。With the continuous improvement of MCVD equipment, the substrate tubes that can be used are getting thicker and thicker, and the wall thickness of the substrate tubes is also allowed to be larger. It is also longer and longer, the production cost can be significantly reduced, and the uniformity of various parameters of a single batch of optical fibers can be significantly improved.
本发明可以采用多种外径(最大外径可达到30mm以上)、多种壁厚和多种截面积的基管做保偏光棒,基管外径的范围为12-35mm,壁厚的范围为1.5-3.5mm,截面积的范围为70-300mm2。The present invention can use base tubes with multiple outer diameters (the maximum outer diameter can reach more than 30mm), multiple wall thicknesses and multiple cross-sectional areas as polarization maintaining rods. The range of the outer diameter of the base tube is 12-35mm, and the range of the wall thickness 1.5-3.5mm, and the cross-sectional area ranges from 70-300mm 2 .
本发明所具有的优点是:The advantages that the present invention has are:
1、“一”字型保偏光纤具有应力作用区小的特点。1. The "one"-shaped polarization maintaining fiber has the characteristics of small stress action area.
2、“一”字型保偏光纤具有良好的保偏性能、环境温度适应性、耐弯曲性能和机械强度。2. The "one" shape polarization maintaining fiber has good polarization maintaining performance, environmental temperature adaptability, bending resistance and mechanical strength.
四、附图说明:4. Description of drawings:
图1为本发明“一”字型保偏光纤的横截面结构示意图。Fig. 1 is a schematic diagram of the cross-sectional structure of the "one"-shaped polarization-maintaining optical fiber of the present invention.
图2为本发明“一”字型保偏光棒的制造流程示意图。Fig. 2 is a schematic diagram of the manufacturing process of the "one"-shaped polarization-maintaining light rod of the present invention.
五、具体实施例:Five, specific embodiment:
如图1所示的“一”字型保偏光纤,其横截面结构由外到里分别是:基管层11、外包层12、应力作用区13、内包层14和芯层15,其应力作用区13的形状为“一”字长条形。As shown in Figure 1, the "one"-shaped polarization maintaining fiber has a cross-sectional structure from the outside to the inside: the
实施例1、如图2所示在MCVD车床上进行基管的预处理、沉积外包层、沉积应力层、定向刻蚀、沉积内包层、沉积芯层、正向塌缩、反向塌缩和抛光工序,制得“一”字型保偏光棒,应力作用区的面积占光棒横截面面积的比例为4%;其中基管外径为30mm,壁厚为2.5mm,截面积为216mm2;在定向刻蚀工序时在基管内通入六氟化硫腐蚀性气体;在基管外用两边对烧的两束火头在通过基管中心的平面内沿基管的轴向对称地在基管的两侧进行来回移动,以加热管壁使被加热处的基管内侧的应力层被逐渐刻蚀,且使该处的应力作用区留有一点厚度。Embodiment 1, as shown in Figure 2, the pretreatment of the base pipe, the deposition of the outer cladding, the deposition of the stress layer, the directional etching, the deposition of the inner cladding, the deposition of the core layer, forward collapse, reverse collapse and In the polishing process, a "one"-shaped polarization-maintaining light rod is obtained, and the area of the stress action area accounts for 4% of the cross-sectional area of the light rod; the outer diameter of the base tube is 30mm, the wall thickness is 2.5mm, and the cross-sectional area is 216mm 2 ; During the directional etching process, the sulfur hexafluoride corrosive gas is passed into the substrate tube; outside the substrate tube, two beams of fire heads that are fired on both sides are symmetrically placed on the substrate tube along the axis of the substrate tube in the plane passing through the center of the substrate tube. The two sides of the tube move back and forth to heat the tube wall so that the stress layer inside the substrate tube at the heated place is gradually etched, and a little thickness is left in the stress action zone at the place.
实施例2、将实施例1制得的“一”字型保偏光棒拉细成直径为125μm的石英光纤,并在其外围马上涂上两层丙烯酸酯类的涂料进行保护,涂料再经紫外固化处理,制得直径为125μm的“一”字型保偏光纤,保偏光纤的应力作用区的面积占保偏光纤横截面面积的比例为4%;该“一”字型保偏光纤的主要技术指标如表1。Example 2. The "one"-shaped polarizing rod obtained in Example 1 was thinned into a quartz optical fiber with a diameter of 125 μm, and immediately coated with two layers of acrylic paint on its periphery for protection. After curing treatment, a "one"-shaped polarization-maintaining fiber with a diameter of 125 μm was obtained, and the area of the stress action area of the polarization-maintaining fiber accounted for 4% of the cross-sectional area of the polarization-maintaining fiber; the "one"-shaped polarization-maintaining fiber The main technical indicators are shown in Table 1.
表1
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| CN105242348A (en) * | 2015-11-10 | 2016-01-13 | 长飞光纤光缆股份有限公司 | Twisted optical fiber and manufacturing method thereof |
| CN106630652A (en) * | 2015-10-29 | 2017-05-10 | 上海亨通光电科技有限公司 | Optical fiber preform, preparation method and application thereof |
| CN107918169A (en) * | 2017-10-27 | 2018-04-17 | 江苏法尔胜光子有限公司 | Active polarization maintaining optical fibre of line-styled and preparation method thereof |
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| CN1093174A (en) * | 1993-03-27 | 1994-10-05 | 上海科学技术大学 | Cruciform polarization maintaining optical fibre and its preparation method |
| JP3903987B2 (en) * | 2002-03-04 | 2007-04-11 | 住友電気工業株式会社 | Polarization-maintaining optical fiber manufacturing method |
| CN1224851C (en) * | 2002-11-14 | 2005-10-26 | 江苏法尔胜光子有限公司 | Structure and manufacturing method of elliptical jacket type premade stick and light bias fiber |
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| CN105242348B (en) * | 2015-11-10 | 2018-01-12 | 长飞光纤光缆股份有限公司 | A kind of twisted fiber and preparation method thereof |
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| CN110746109A (en) * | 2019-09-25 | 2020-02-04 | 无锡法尔胜光电科技有限公司 | Preparation method of polarization maintaining optical fiber |
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