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CN1625357A - toothbrush - Google Patents

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Publication number
CN1625357A
CN1625357A CNA028287282A CN02828728A CN1625357A CN 1625357 A CN1625357 A CN 1625357A CN A028287282 A CNA028287282 A CN A028287282A CN 02828728 A CN02828728 A CN 02828728A CN 1625357 A CN1625357 A CN 1625357A
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China
Prior art keywords
calcium carbonate
product
toothbrush
shell
handle
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Pending
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CNA028287282A
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Chinese (zh)
Inventor
笹谷广治
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Chafflose Corp
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Chafflose Corp
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Publication of CN1625357A publication Critical patent/CN1625357A/en
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    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B15/00Other brushes; Brushes with additional arrangements
    • A46B15/0002Arrangements for enhancing monitoring or controlling the brushing process
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/006Antimicrobial, disinfectant bristles, handle, bristle-carrier or packaging
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/04Preparing bristles
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D9/00Machines for finishing brushes
    • A46D9/06Impregnating
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1066Toothbrush for cleaning the teeth or dentures

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  • Brushes (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

通过在牙刷上提供研磨具有碳酸钙方解石型结构的晶体结构体的贝壳获得的产品来抑制口腔内的真菌活动,从而防止病变。牙刷(1)的手柄(2)或刷毛(3)由混合有通过研磨具有碳酸钙方解石型结构的晶体结构体的贝壳获得的产品的合成树脂制成。

Figure 02828728

The toothbrush (1) is made of a product obtained by grinding shells with a crystalline structure of calcium carbonate calcite, thereby inhibiting fungal activity in the oral cavity and preventing lesions. The handle (2) or bristles (3) of the toothbrush (1) are made of a synthetic resin mixed with a product obtained by grinding shells with a crystalline structure of calcium carbonate calcite.

Figure 02828728

Description

牙刷toothbrush

技术领域technical field

本发明涉及牙刷。The present invention relates to toothbrushes.

背景技术Background technique

由于事物残渣等的结果,牙齿病变导致在牙齿表面上出现牙斑,并夹有诸如链球菌突变株的链球菌菌株,在牙斑中的糖组分被链球菌突变株、乳酸菌菌株和念珠菌属菌株转化为酸,酸溶解牙齿中的钙组分。这就是提倡将刷牙作为防止牙齿病变措施的原因。Dental lesions cause dental plaque to appear on the tooth surface as a result of food debris, etc., and streptococcus strains such as Streptococcus mutants, sugar components in plaque are The genus strains convert to acid, which dissolves the calcium component in the tooth. This is why brushing is advocated as a preventive measure against dental disease.

但是,现有牙刷不能抑制如上所述的细菌和真菌的活动,尽管它们可以有效地除去牙斑。However, existing toothbrushes cannot inhibit the activity of bacteria and fungi as described above, although they are effective in removing plaque.

与上述问题相关地,本发明人注意到,从自然界获得的天然材料,尤其是通过煅烧和研磨富含钙组分的天然多孔材料诸如作为废物抛弃的贝壳所获得的产品具有抗细菌和抗真菌特性,并且对人体无害。考虑到上述状况,本发明的问题是提供一种牙刷,该牙刷包含所述产品、并且利用该产品的抗细菌和抗真菌的特性抑制口腔中的细菌和真菌的活动。本发明的目的是防止牙齿病变并且保持在口腔内使用的牙刷的卫生条件。In connection with the above problems, the present inventors noticed that natural materials obtained from nature, especially products obtained by calcining and grinding natural porous materials rich in calcium components such as shells discarded as waste, have antibacterial and antifungal properties characteristics, and harmless to the human body. In view of the above situation, the problem of the present invention is to provide a toothbrush which contains said product and uses the antibacterial and antifungal properties of this product to inhibit the activity of bacteria and fungi in the oral cavity. The object of the present invention is to prevent tooth pathology and maintain the hygienic conditions of toothbrushes used in the oral cavity.

发明内容Contents of the invention

为了解决上述问题,提出本发明。本发明的一个目的是提供一种牙刷,包括这种刷毛或者手柄中的至少一种,所述刷毛由混合有通过研磨具有碳酸钙方解石型结构的晶体结构体的贝壳获得的产品的合成树脂制成,所述手柄由混合有通过研磨具有碳酸钙方解石型结构的晶体结构体的贝壳获得的产品的合成树脂制成。In order to solve the above-mentioned problems, the present invention has been proposed. An object of the present invention is to provide a toothbrush comprising at least one of such bristles or a handle made of synthetic resin mixed with a product obtained by grinding shells having a crystal structure of calcium carbonate calcite type structure The handle is made of synthetic resin mixed with a product obtained by grinding shells having a crystal structure of calcium carbonate calcite type structure.

本发明的另一个目的是提供一种牙刷,包括这种刷毛或者手柄中的至少一种,所述刷毛涂有包含通过研磨具有碳酸钙方解石型结构的晶体结构体的贝壳获得的产品的涂料,所述手柄涂有包含通过研磨具有碳酸钙方解石型结构的晶体结构体的贝壳获得的产品的涂料。Another object of the present invention is to provide a toothbrush comprising at least one of such bristles or a handle coated with a coating comprising a product obtained by grinding shells having a crystal structure of calcium carbonate calcite type structure, The handle is coated with a paint comprising a product obtained by grinding shells having a crystalline structure of calcium carbonate calcite type structure.

优选地,根据本发明,该产品是包括多孔微粒的碳酸钙粉末与通过煅烧碳酸钙粉末制备的氧化钙粉末的混合物、或者是该混合物的水溶液,所述碳酸钙粉末是具有碳酸钙方解石型结构的晶体结构体的贝壳粉末。Preferably, according to the invention, the product is a mixture of calcium carbonate powder comprising porous particles and calcium oxide powder prepared by calcining calcium carbonate powder, or an aqueous solution of the mixture, said calcium carbonate powder having a structure of calcium carbonate calcite type The crystal structure of shell powder.

附图说明Description of drawings

图1显示了根据本发明的牙刷的示例。Figure 1 shows an example of a toothbrush according to the invention.

图2显示了根据本发明另一示例的牙刷手柄的横截面图。Fig. 2 shows a cross-sectional view of a toothbrush handle according to another example of the present invention.

图3显示了根据本发明另一示例的牙刷刷毛的横截面图。Fig. 3 shows a cross-sectional view of a toothbrush bristle according to another example of the present invention.

具体实施方式Detailed ways

以下将参照本发明的实施例对本发明进行详细描述。Hereinafter, the present invention will be described in detail with reference to examples of the present invention.

在图中,标号1表示牙刷,它包括安插在由合成树脂材料制成的手柄2末端的多根刷毛3。形成刷毛的合成树脂材料被用于安插在牙刷1末端的刷毛3,其中,通过研磨具有碳酸钙方解石型结构的晶体结构体的贝壳获得的产品与选定用于牙刷刷毛的合成树脂材料混合。In the drawings, reference numeral 1 denotes a toothbrush comprising a plurality of bristles 3 inserted at the end of a handle 2 made of synthetic resin material. A bristle-forming synthetic resin material is used for the bristle 3 inserted at the end of the toothbrush 1, wherein a product obtained by grinding shells having a crystal structure of calcium carbonate calcite type structure is mixed with the synthetic resin material selected for the toothbrush bristle.

手柄2采用形成手柄的合成树脂材料制成,形成手柄的合成树脂材料是通过研磨具有碳酸钙方解石型结构的晶体结构体的贝壳获得的产品与选定用于牙刷手柄的合成树脂材料混合而获得的。The handle 2 is made of a handle-forming synthetic resin material obtained by mixing a product obtained by grinding shells having a crystal structure of calcium carbonate calcite type structure with a synthetic resin material selected for the toothbrush handle of.

主要包括至少一种碳酸钙方解石型结构的晶体结构体的贝壳被用于获得混入牙刷1的手柄2和刷毛3的产品。这种贝壳是扇贝壳,它不同于其它贝壳,因为这种贝壳的大部分具有晶体结构体。扇贝的特征是,当通过打开和闭合贝壳使得海水从贝壳中有力地排出从而显示为在“在海中游泳”时,它在生态状态下快速移动以逃离捕食者(例如海星)。扇贝具有大的贝壳韧带以进行这种移动,同时贝壳本身相当薄、重量轻并具有高强度。碳酸钙方解石型结构的晶体结构体呈现叶片状结构以形成贝壳的内表面,同时碳酸钙方解石型结构的晶体结构体在贝壳内层(沿着贝壳厚度方向的核心层)呈现层状结构。由于贝壳的内表面和内层的结构占据了贝壳的主要部分(除表面层和铰合部之外的部分),贝壳强度较高、并且较薄和重量轻。Shells mainly comprising at least one crystalline structure of calcium carbonate calcite type structure are used to obtain a product mixed into the handle 2 and the bristles 3 of the toothbrush 1 . This shell is a scallop shell, which is different from other shells because most of this shell has a crystalline structure. A scallop is characterized by its ecological state of moving rapidly to escape predators (such as starfish) when it appears to be "swimming in the sea" by opening and closing the shell so that sea water is forcefully expelled from the shell. Scallops have large shell ligaments for this movement, while the shell itself is fairly thin, lightweight and high strength. The crystal structure of the calcium carbonate-calcite type structure exhibits a leaf-like structure to form the inner surface of the shell, while the crystal structure of the calcium carbonate-calcite type structure exhibits a layered structure in the inner layer of the shell (the core layer in the thickness direction of the shell). Since the structure of the inner surface and the inner layer of the shell occupies the main part of the shell (parts other than the surface layer and the hinge), the shell is high in strength and thin and light in weight.

如上所述,碳酸钙方解石型结构的晶体结构体在扇贝壳的主要部分的内表面上呈现叶片状结构(针状晶体紧密压实并且象kenzann(用于布置鲜花的针板)排列的一种结构),同时碳酸钙方解石型结构的晶体结构体在贝壳内层呈现层状结构(其中针状晶体沿着同一方向排列以形成象胶合板一样的多层结构、并且针状晶体的方向在各层之间不同的多层结构)。因此,通过研磨扇贝壳获得的粉末是多孔的,并且具有方解石型结构,如下所述。与此不同的是,在其它类型的贝壳中,碳酸钙晶体在平面上伸展并且层叠,由这些贝壳制备的粉末不是多孔的,尽管具有珍珠光泽。As described above, the crystal structure of the calcium carbonate calcite type structure exhibits a leaf-like structure (one in which needle-like crystals are tightly packed and arranged like kenzann (needle boards for arranging flowers)) on the inner surface of the main part of the scallop shell structure), while the crystal structure of the calcium carbonate calcite structure presents a layered structure in the inner layer of the shell (in which the needle-like crystals are arranged in the same direction to form a multi-layer structure like plywood, and the direction of the needle-like crystals is in each layer. between different multilayer structures). Therefore, the powder obtained by grinding scallop shells is porous and has a calcite-type structure, as described below. Unlike other types of shells, in which calcium carbonate crystals are stretched out and layered in planes, powders prepared from these shells are not porous, despite having a pearly luster.

当扇贝壳用作本发明如上所述的产品的原材料时,在去除贝壳韧带之后作为无用废物扔掉的贝壳可以被利用,以使废物被有效地利用。首先,废弃贝壳被收集并且通过在太阳下干燥而被硬化。接着,在太阳下干燥而被硬化的贝壳被研磨成直径大约为200μm的颗粒。研磨方法本身没有特别的限制,并且可利用现有的研磨器。这样获得的碳酸钙粉末包括多孔微粒。When the scallop shell is used as a raw material of the product of the present invention as described above, the shell discarded as useless waste after removing the shell ligament can be utilized so that the waste is effectively utilized. First, discarded shells are collected and hardened by drying in the sun. Next, the shells, which have been hardened by drying in the sun, are ground into particles about 200 μm in diameter. The grinding method itself is not particularly limited, and existing grinders can be used. The calcium carbonate powder thus obtained comprises porous particles.

一部分包括多孔微粒的碳酸钙粉末被放入回转窑,并在大约1000℃加热几分钟到几小时以获得氧化钙粉末。通过将氧化钙粉末与碳酸钙粉末混合获得本发明的产品。A part of calcium carbonate powder including porous particles is put into a rotary kiln and heated at about 1000°C for several minutes to several hours to obtain calcium oxide powder. The product of the invention is obtained by mixing calcium oxide powder with calcium carbonate powder.

该产品与选定用于刷毛的合成树脂材料混合,通过将树脂形成细丝获得刷毛3。这些刷毛被安插在手柄2的预定位置上。类似地,该产品与选定用于手柄的合成树脂材料混合,通过模制树脂材料获得手柄2。This product is mixed with a synthetic resin material selected for bristles, the bristles3 being obtained by forming the resin into filaments. These bristles are inserted at predetermined positions on the handle 2 . Similarly, this product is mixed with a synthetic resin material selected for the handle, and the handle 2 is obtained by molding the resin material.

产品中的碳酸钙粉末包括为扇贝壳粉末所特有的多孔微粒如上所述作为天然产品。由于这种产品包括作为天然产品的扇贝壳粉末,它具有为该天然产品所共有的抗细菌和抗真菌特性。这种抗细菌和抗真菌特性用于抑制细菌和真菌的繁殖。该产品暴露于牙刷的手柄2和刷毛3的表面,通过用牙刷1刷牙齿,由于该产品与天然产品所共有的抗细菌和抗真菌活动特性,细菌和真菌活动受到抑制。这里的“天然产品”是与“化学合成产品”相对的术语,人工培养的扇贝的贝壳也属于天然产品。The calcium carbonate powder in the product includes porous particles characteristic of scallop shell powder as described above as a natural product. Since this product includes scallop shell powder as a natural product, it has antibacterial and antifungal properties common to this natural product. This antibacterial and antifungal property is used to inhibit the reproduction of bacteria and fungi. The product is exposed to the surface of the handle 2 and bristles 3 of the toothbrush, and by brushing the teeth with the toothbrush 1, bacterial and fungal activity is inhibited due to the antibacterial and antifungal activity properties shared by this product with natural products. "Natural product" here is a term opposite to "chemically synthesized product", and the shells of artificially cultured scallops are also natural products.

氧化钙粉末是碱性的,并且具有强的抗细菌和抗真菌特性。当用本发明的牙刷刷牙时,通过口腔中的水的作用,氧化钙粉末转化成氢氧化钙,通过在口腔中形成碱性环境,细菌和真菌的繁殖被抑制、或者细菌和真菌被杀死。因此,该牙刷对于防止牙齿病变十分有效,而牙刷1的卫生条件在使用之后也得到保持。Calcium oxide powder is alkaline and has strong antibacterial and antifungal properties. When brushing teeth with the toothbrush of the present invention, the calcium oxide powder is converted into calcium hydroxide by the action of water in the oral cavity, and by forming an alkaline environment in the oral cavity, the reproduction of bacteria and fungi is inhibited, or bacteria and fungi are killed . Therefore, the toothbrush is very effective in preventing dental disease, and the hygienic condition of the toothbrush 1 is maintained after use.

尽管本发明的产品是包括多孔微粒的碳酸钙粉末与通过煅烧碳酸钙粉末制备的氧化钙粉末的混合物,但该产品可以是这种混合物的水溶液,其中碳酸钙粉末是具有碳酸钙方解石型结构的晶体结构体的贝壳粉末。该产品可以仅包括碳酸钙粉末或氧化钙粉末,或者碳酸钙或氧化钙的水溶液。当该产品作为水溶液与用于手柄的合成树脂材料混合,并且手柄2由这种材料模制而成时,可形成在表面上包括更稠密分布的抗细菌和抗真菌物质的手柄。类似地,当该产品作为水溶液与用于刷毛的合成树脂材料混合,并且刷毛3由这种材料模制而成时,可形成在表面上包括更稠密分布的抗细菌和抗真菌物质的刷毛。Although the product of the present invention is a mixture of calcium carbonate powder comprising porous particles and calcium oxide powder prepared by calcining calcium carbonate powder, the product may be an aqueous solution of such a mixture, wherein the calcium carbonate powder has a calcium carbonate calcite type structure Shell powder with crystal structure. The product may comprise only calcium carbonate powder or calcium oxide powder, or an aqueous solution of calcium carbonate or calcium oxide. When this product is mixed as an aqueous solution with a synthetic resin material for the handle, and the handle 2 is molded from this material, a handle comprising a more dense distribution of antibacterial and antifungal substances on the surface can be formed. Similarly, when the product is mixed as an aqueous solution with a synthetic resin material for the bristles, and the bristles 3 are molded from this material, bristles comprising a more dense distribution of antibacterial and antifungal substances on the surface can be formed.

当手柄2和刷毛3由其中混有本发明产品的材料模制而成时,手柄2和刷毛3中的任何一种可以由混有本发明产品的材料模制而成。When the handle 2 and the bristles 3 are molded from the material in which the product of the present invention is mixed, either of the handle 2 and the bristles 3 may be molded from the material in which the product of the present invention is mixed.

图2和3显示了本发明的另一实施例。在该实施例中,涂层5形成在如图2所示的牙刷1的手柄2的主体4的表面上,并且涂层5也形成在如图3所示的牙刷1的刷毛3的主体6的表面上。涂层5是通过将该产品作为粉末或者水溶液与涂料混合而形成,该产品与涂料的混合物被施加到手柄的主体4和刷毛的主体6的表面上。Figures 2 and 3 show another embodiment of the invention. In this embodiment, the coating 5 is formed on the surface of the body 4 of the handle 2 of the toothbrush 1 as shown in FIG. 2, and the coating 5 is also formed on the body 6 of the bristles 3 of the toothbrush 1 as shown in FIG. on the surface. The coating 5 is formed by mixing the product as a powder or an aqueous solution with paint, and the mixture of product and paint is applied to the surface of the body 4 of the handle and the body 6 of the bristles.

在手柄2和刷毛3的表面上设置包含该产品的涂层5使得牙刷1显示具有诸如获得抗细菌和抗真菌特性的有益效果。Providing a coating 5 comprising this product on the surface of the handle 2 and bristles 3 allows the toothbrush 1 to exhibit beneficial effects such as obtaining antibacterial and antifungal properties.

用于形成涂层的方法部局限于如上所述的涂敷方法,诸如喷射涂料和浸入涂料的其它方法也是可行的。The method for forming the coating is not limited to the coating method described above, and other methods such as spray paint and dip paint are also possible.

在该实施例中,可通过将本发明的产品混入手柄2或刷毛3中形成涂层。用于手柄的主体4和刷毛的主体6的材料不受限制。In this embodiment, the coating can be formed by mixing the product of the invention into the handle 2 or the bristles 3 . The materials used for the body 4 of the handle and the body 6 of the bristles are not limited.

工业适用性Industrial applicability

根据本发明,通过采用本发明的牙刷刷牙齿,可以很容易在口腔中形成碱性环境,这通过抑制口腔中的细菌和真菌的活动可有效防止牙齿病变。从施加在牙刷上的本发明产品溶解的钙组分可有助于牙齿的成长。本发明也通过提高牙齿自身的抗细菌和抗真菌特性以保持牙刷本身的卫生条件而具有可行的优良效果。According to the present invention, by using the toothbrush of the present invention to brush the teeth, an alkaline environment can be easily formed in the oral cavity, which can effectively prevent dental lesions by inhibiting the activities of bacteria and fungi in the oral cavity. The dissolved calcium component from the product of the present invention applied to the toothbrush may contribute to the growth of the teeth. The present invention also has the advantage of maintaining the hygienic condition of the toothbrush itself by enhancing the antibacterial and antifungal properties of the tooth itself.

Claims (3)

1, a kind of toothbrush, comprise at least a in this bristle or the handle, described bristle is made by being mixed with the synthetic resin that has a product that the shell of the crystal structure body of calcium carbonate calcite type structure obtains by grinding, and described handle is made by being mixed with the synthetic resin that has a product that the shell of the crystal structure body of calcium carbonate calcite type structure obtains by grinding.
2, a kind of toothbrush, comprise at least a in this bristle or the handle, described bristle scribbles and comprises the coating that has the product that the shell of the crystal structure body of calcium carbonate calcite type structure obtains by grinding, and described handle scribbles and comprises the coating that has the product that the shell of the crystal structure body of calcium carbonate calcite type structure obtains by grinding.
3, toothbrush as claimed in claim 1 or 2, it is characterized in that, described product is the calcium carbonate powder and the mixture of the lime powder that passes through the calcination of calcium carbonate powder preparation or the aqueous solution of this mixture that comprises small porous particle, and described calcium carbonate powder is the shell powder with crystal structure body of calcium carbonate calcite type structure.
CNA028287282A 2002-04-11 2002-04-11 toothbrush Pending CN1625357A (en)

Applications Claiming Priority (1)

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PCT/JP2002/003634 WO2003084365A1 (en) 2002-04-11 2002-04-11 Tooth brush

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Publication Number Publication Date
CN1625357A true CN1625357A (en) 2005-06-08

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CN112205746A (en) * 2020-09-28 2021-01-12 上海那博新材料科技有限公司 Nano copper toothbrush bristle and manufacturing method thereof

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US20090007357A1 (en) * 2007-05-07 2009-01-08 The Gillette Company Oral Hygiene Implements
KR102251526B1 (en) * 2019-09-18 2021-05-12 양승호 the bristle of toothbrush with zirconia and high antibacterial shell of lily clam, and manufacturing method thereof

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Publication number Priority date Publication date Assignee Title
CN112205746A (en) * 2020-09-28 2021-01-12 上海那博新材料科技有限公司 Nano copper toothbrush bristle and manufacturing method thereof

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GB2403896B (en) 2005-11-09
WO2003084365A1 (en) 2003-10-16
GB0422309D0 (en) 2004-11-10
HK1069964A1 (en) 2005-06-10
GB2403896A (en) 2005-01-19
US20060162109A1 (en) 2006-07-27
KR20040108727A (en) 2004-12-24

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