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CN1623018A - Three-dimensional sheet - Google Patents

Three-dimensional sheet Download PDF

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Publication number
CN1623018A
CN1623018A CNA028286510A CN02828651A CN1623018A CN 1623018 A CN1623018 A CN 1623018A CN A028286510 A CNA028286510 A CN A028286510A CN 02828651 A CN02828651 A CN 02828651A CN 1623018 A CN1623018 A CN 1623018A
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fiber layer
heat
fibers
dimensional sheet
fiber
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CN100347369C (en
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坂涉
种市祥一
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Kao Corp
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Kao Corp
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
    • A61F13/511Topsheet, i.e. the permeable cover or layer facing the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/539Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium characterised by the connection of the absorbent layers with each other or with the outer layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
    • A61F13/511Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/5116Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers
    • A61F2013/51182Topsheet, i.e. the permeable cover or layer facing the skin being formed of multiple layers with non-continuous bonding

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Vascular Medicine (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Biomedical Technology (AREA)
  • Veterinary Medicine (AREA)
  • Textile Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Absorbent Articles And Supports Therefor (AREA)
  • Laminated Bodies (AREA)
  • Orthopedics, Nursing, And Contraception (AREA)

Abstract

A three-dimensional sheet (10) comprising a 1 st fiber layer (1) containing heat-shrinkable fibers, a 2 nd fiber layer (2) composed mainly of non-heat-shrinkable fibers and containing heat-fusible fibers laminated on one surface thereof, and a 3 rd fiber layer (3) composed of heat-fusible fibers laminated on the other surface of the 1 st fiber layer (1), wherein the 1 st to 3 rd fiber layers have heat-fusible portions (4) formed in a predetermined pattern in the three-dimensional sheet, the heat-fusible portions (4) penetrate from the 2 nd fiber layer (2) to the 3 rd fiber layer (3), and the 2 nd fiber layer (2) is raised in a portion other than the heat-fusible portions (4).

Description

立体片Stereoscopic film

技术领域technical field

本发明涉及表面具有所希望的凹凸、具有膨松结构的立体片。The present invention relates to a three-dimensional sheet having desired unevenness on the surface and a bulky structure.

背景技术Background technique

在特许3131557号公报中记载了在含有由热收缩性纤维和熔点比该热收缩性纤维的热收缩起始温度低的树脂构成的热熔融粘合纤维的第一纤维层的一个面上层压由非热收缩性纤维构成的第二纤维层形成的多褶性无纺布。两纤维层通过线状热熔融粘合在厚度方向成为一体,热熔融粘合部分成为凹部,该热熔融粘合部分间成为凸部,在第二纤维层上形成筋状的多个褶。该多褶性无纺布按如下所述制备:使第一纤维层和第二纤维层重合,在比上述热收缩性纤维的热收缩起始温度低的温度下通过热熔融粘合使两纤维层成为一体后,吹送上述热收缩温度以上的热风,从而使上述热收缩性纤维热收缩。但是,在该无纺布中,第一纤维层和第二纤维层的热熔融粘合由于依赖于第一纤维层中含有的30~50重量%以上的热熔融粘合纤维,因此两纤维层的接合力有限。因此,第一纤维层热收缩时和无纺布后加工时及使用时上述热熔融粘合部分容易剥离,其结果是凹凸模样变得不鲜明,或者有时无法得到所希望的凹凸形状。此外,由于上述热收缩性纤维的收缩温度比热熔融粘合纤维的熔点高,因此收缩时热熔融粘合纤维熔化,质量风格变差,不适用作与肌肤直接接触的片。In Japanese Patent No. 3131557, it is described that on one side of the first fiber layer, thermally fused adhesive fibers made of heat-shrinkable fibers and a resin having a melting point lower than the heat-shrinkage initiation temperature of the heat-shrinkable fibers are laminated by A multi-pleated nonwoven fabric formed of a second fiber layer composed of non-heat-shrinkable fibers. The two fiber layers are integrally bonded in the thickness direction by linear thermal fusion bonding, the thermal fusion bonded portion becomes a concave portion, and the portion between the thermal fusion bonded portions becomes a convex portion, and a plurality of tendon-like pleats are formed on the second fiber layer. The multi-pleated non-woven fabric is prepared as follows: the first fiber layer and the second fiber layer are overlapped, and the two fibers are bonded by heat fusion at a temperature lower than the heat shrinkage initiation temperature of the above-mentioned heat-shrinkable fibers. After the layers are integrated, the heat-shrinkable fibers are heat-shrunk by blowing hot air at or above the heat-shrinkage temperature. However, in this nonwoven fabric, the thermal fusion bonding of the first fiber layer and the second fiber layer depends on the thermal fusion bonding fibers contained in the first fiber layer in an amount of 30 to 50% by weight, so the two fiber layers The joining force is limited. Therefore, when the first fiber layer is thermally shrunk, and when the nonwoven fabric is post-processed or used, the above-mentioned thermally fused bonded portion is easily peeled off, and as a result, the concave-convex pattern becomes unclear, or the desired concave-convex shape may not be obtained. In addition, since the shrinkage temperature of the heat-shrinkable fibers is higher than the melting point of the heat-fusible fibers, the heat-fusible fibers are melted during shrinkage, and the quality and style are deteriorated, making them unsuitable for direct contact with the skin.

为了提高两纤维层的接合力,考虑提高第1纤维层中含有的热熔融粘合性纤维的比例,或提高热熔融粘合加工时的温度或压力,但如果是前者,热收缩性纤维的比例降低,第1纤维层的收缩性变得不充分,有可能无法获得所希望的凹凸形状。此外,如果是后者,热熔融粘合部分变硬,其结果使片整体的柔软性下降,质量风格恶化。In order to improve the joining force of the two fiber layers, it is considered to increase the proportion of the heat-melt adhesive fibers contained in the first fiber layer, or to increase the temperature or pressure during the heat-melt bonding process, but if it is the former, the heat-shrinkable fiber If the ratio is lowered, the shrinkability of the first fiber layer becomes insufficient, and the desired concave-convex shape may not be obtained. In addition, in the latter case, the hot-melt bonded part becomes hard, and as a result, the flexibility of the entire sheet is lowered, and the quality and style are deteriorated.

此外,当将上述多褶性无纺布固定于其他材料等使用时,将第1纤维层侧的面与其他材料等相面对进行固定,但为了确保收缩力,不能在第1纤维层中大量使用热熔融粘合纤维,此外,由于热压花等热压接在热收缩纤维的收缩温度以下进行,因此热收缩性纤维不会熔化,即使采用热压花等热压接进行固定,也不能获得足够的接合强度。In addition, when the above-mentioned pleated nonwoven fabric is fixed to other materials and used, the surface on the side of the first fiber layer is fixed to the other material, etc., but in order to ensure shrinkage force, it cannot be fixed in the first fiber layer. A large amount of heat-melt adhesive fibers are used. In addition, since heat-shrinkable fibers such as heat embossing are performed below the shrinkage temperature of heat-shrinkable fibers, heat-shrinkable fibers do not melt. Sufficient joint strength could not be obtained.

特许3181195号公报记载了作为用于面扣件的凹材的无纺布,通过层压并使部分热熔融粘合的第1和第2纤维层之中的一个热收缩,使另一个突出于单面侧而形成了规则的凸部的无纺布。该无纺布通过将热收缩的上述的一个纤维层侧固定到其他构件上而使用,为了确保收缩力,在该个纤维层中无法大量使用热熔融粘合纤维,因此即使采用热压花等热压接与其他构件接合,也不能获得充分的接合强度,即使获得了,原本也不太好,肌肤接触等质量风格进一步恶化。Patent No. 3181195 describes a non-woven fabric used as a concave material for surface fasteners, by laminating and shrinking one of the first and second fiber layers partially thermally fused to make the other protrude from the surface. A nonwoven fabric with regular protrusions formed on one side. This non-woven fabric is used by fixing the heat-shrinkable one fiber layer side to another member. In order to ensure the shrinkage force, it is not possible to use a large amount of heat-melt adhesive fibers in this fiber layer. Therefore, even with heat embossing, etc. Even if thermocompression bonding is used to join other members, sufficient joint strength cannot be obtained, and even if it is obtained, it is not good at first, and the quality and style such as skin contact are further deteriorated.

发明内容Contents of the invention

因此,本发明的目的在于提供质量风格好,与其他材料等的热压接性优异,而且在制造时能形成所希望的凹凸的立体片。Therefore, an object of the present invention is to provide a three-dimensional sheet that has good quality and style, excellent thermocompression bonding properties with other materials, and can form desired unevenness during production.

此外,本发明的目的在于提供能使使用了热收缩性纤维的立体片牢固地接合于由纤维材料构成的被固定物上的立体片的固定方法。Another object of the present invention is to provide a three-dimensional sheet fixing method capable of firmly joining a three-dimensional sheet using heat-shrinkable fibers to an object to be fixed made of a fiber material.

本发明是通过提供如下的立体片而实现了上述第一个目的,该立体片是在含有热收缩了的热收缩性纤维的第1纤维层的一个面上层压(或层叠)以非热收缩性纤维为主体且含有热熔融粘合性纤维的第2纤维层,在第1纤维层的另一个面上层压含有热熔融粘合性纤维的第3纤维层,其中,第1纤维层至第3纤维层在上述立体片中形成具有预定图案的热熔融粘合部分,上述热熔融粘合部分从第2纤维层贯穿到第3纤维层,且第2纤维层在上述热熔融粘合部分以外的部分是成为凸起状(以下,称为第1发明时指的就是该发明)。The present invention achieves the above-mentioned first object by providing the following three-dimensional sheet, which is laminated (or laminated) on one side of the first fiber layer containing heat-shrinkable heat-shrinkable fibers to avoid heat shrinkage. The second fiber layer containing thermally-adhesive fibers as the main body and containing heat-melting adhesive fibers is laminated on the other side of the first fiber layer. The third fiber layer containing thermally-melting adhesive fibers, wherein the first fiber layer to the second The 3-fiber layer forms a heat-melt bonding part having a predetermined pattern in the above-mentioned three-dimensional sheet, and the above-mentioned heat-melt bonding part penetrates from the second fiber layer to the third fiber layer, and the second fiber layer is outside the above-mentioned heat-melt bonding part The part becomes convex shape (hereinafter referred to as the first invention refers to this invention).

本发明通过提供如下的立体片的固定方法而实现了上述第二个目的,该立体片的固定方法是在含有热收缩性纤维的第1纤维层的一个面上层压以非热收缩性纤维为主体且含有热熔融粘合性纤维的第2纤维层,并将第1和第2纤维层形成预定图案的接合部而形成的立体片的第2纤维层侧作为被固定物侧固定到由纤维材料构成的被固定物上,其中,使含有热熔融粘合性纤维的第3纤维层介于上述立体片和上述被固定物之间,通过热压花(或压纹)加工使它们成为一体(以下,称为第2发明时指的就是该发明)。The present invention achieves the above-mentioned second object by providing a method for fixing a three-dimensional sheet by laminating non-heat-shrinkable fibers on one surface of a first fiber layer containing heat-shrinkable fibers. The main body and the second fiber layer containing heat-melt adhesive fibers, and the second fiber layer side of the three-dimensional sheet formed by forming the junction of the first and the second fiber layers in a predetermined pattern is fixed to the side of the fixed object as the fixed object side. On the object to be fixed made of material, wherein the third fiber layer containing heat-fusible adhesive fibers is interposed between the above-mentioned three-dimensional sheet and the above-mentioned object to be fixed, and they are integrated by heat embossing (or embossing) processing (Hereinafter, this invention is referred to as the second invention).

附图说明Description of drawings

图1为表示作为本发明(第1发明)的立体片的一实施方案的立体片和将其固定使用时的被固定物的剖面示意图。Fig. 1 is a schematic cross-sectional view showing a three-dimensional sheet as one embodiment of the three-dimensional sheet of the present invention (first invention) and an object to be fixed when it is fixed for use.

图2(a)~图2(c)分别为表示立体片上形成的热熔融粘合部分的形成图案的例子的平面图。2( a ) to FIG. 2( c ) are plan views each showing an example of the formation pattern of the thermal fusion bonded portion formed on the three-dimensional sheet.

图3为表示使用立体片制造的生理用卫生巾(吸收性物品)的宽度方向剖面的剖面模式图。Fig. 3 is a schematic cross-sectional view showing a cross-section in the width direction of a sanitary napkin (absorbent article) manufactured using a three-dimensional sheet.

图4为表示本发明(第2发明)的立体片的固定方法的一实施方案的剖面示意图。Fig. 4 is a schematic cross-sectional view showing an embodiment of a method for fixing a three-dimensional sheet of the present invention (second invention).

具体实施方式Detailed ways

以下根据其优选的实施方案并参照附图对本发明进行说明。The present invention will be described below on the basis of its preferred embodiments with reference to the accompanying drawings.

图1表示作为本发明(第1发明)的一实施方案的立体片10的模式截面图。立体片10具有在含有热收缩性纤维的第1纤维层1的一个面上层压第2纤维层2,在第1纤维层1的另一个面上层压第3纤维层3的3层结构。第1纤维层1由纤维的集合体构成。另一方面,第2纤维层2和第3纤维层3分别由与构成第1纤维层1的纤维不同种类和/或混合的纤维集合体构成。第2纤维层2和第3纤维层3由同一种类和混合的纤维的集合体,或不同种类和/或混合的纤维集合体构成。FIG. 1 shows a schematic cross-sectional view of a three-dimensional sheet 10 as one embodiment of the present invention (first invention). The three-dimensional sheet 10 has a three-layer structure in which the second fiber layer 2 is laminated on one surface of the first fiber layer 1 containing heat-shrinkable fibers, and the third fiber layer 3 is laminated on the other surface of the first fiber layer 1 . The first fiber layer 1 is composed of an aggregate of fibers. On the other hand, the second fiber layer 2 and the third fiber layer 3 are respectively composed of fiber aggregates of different types and/or mixed with the fibers constituting the first fiber layer 1 . The second fiber layer 2 and the third fiber layer 3 are composed of aggregates of the same type and mixture of fibers, or aggregates of fibers of different types and/or mixtures.

俯视立体片10时,在该立体片10中形成图2(a)所示的菱形格子状图案的热熔融粘合部分4。热熔融粘合部分4通过部分地热压接处于层压状态的第1纤维层至第3纤维层而形成。When the three-dimensional sheet 10 is viewed from above, the thermally fused bonded portions 4 in a rhombic lattice pattern shown in FIG. 2( a ) are formed in the three-dimensional sheet 10 . The thermal fusion bonding portion 4 is formed by partially thermocompression-bonding the first to third fiber layers in a laminated state.

热熔融粘合部分4从第2纤维层2贯穿到第3纤维层3。在第2纤维层和第1纤维层的接合处以及第1纤维层和第3纤维层的接合处,在分别俯视立体片10的状态下完全地重合。热熔融粘合部分4通过热熔融粘合树脂的熔融固化而形成。如后所述,热熔融粘合树脂优选以含有其的热熔融粘合纤维的状态含于第2纤维层2和第3纤维层3中,这两个纤维层的热熔融粘合树脂即使第1纤维层的树脂没有完全熔化也能熔融浸透,相互粘接而成为3层的粘接。此外,根据需要,优选也含于第1纤维层中。优选热熔融粘合部分4在立体片10的各个热熔融粘合部分均从第2纤维层贯穿到第3纤维层,此外,优选各个熔融粘合部分贯穿该部分的立体片厚度方向的整个区域。The heat-melt bonding portion 4 penetrates from the second fiber layer 2 to the third fiber layer 3 . The junction of the 2nd fiber layer and the 1st fiber layer and the junction of the 1st fiber layer and the 3rd fiber layer overlap completely in the state which planarly viewed the three-dimensional sheet 10, respectively. The heat-melt adhesive portion 4 is formed by melt-solidification of a heat-melt adhesive resin. As will be described later, the hot-melt adhesive resin is preferably contained in the second fiber layer 2 and the third fiber layer 3 in the state of the hot-melt adhesive fibers containing it. The resin in the 1 fiber layer can be melted and permeated without being completely melted, and is bonded to each other to form a 3-layer bonding. Moreover, it is preferable to contain also in a 1st fiber layer as needed. It is preferred that the thermal fusion bonding part 4 penetrates from the second fiber layer to the third fiber layer in each thermal fusion bonding part of the three-dimensional sheet 10, and in addition, it is preferred that each fusion bonding part penetrates the entire area in the thickness direction of the three-dimensional sheet of this part .

此外,本实施方案中各个热熔融粘合部分可以为圆形,但各个热熔融粘合部分的形状也可以为椭圆形、三角形或矩形或它们的组合等。此外,可以形成使结合部连续的形状,例如直线或曲线等的线状。热熔融粘合部分4的形成图案可以为例如图2(b)和图2(c)所示的图案。In addition, each heat-melt bonding portion in this embodiment may be circular, but the shape of each heat-melt bonding portion may also be oval, triangular, or rectangular, or a combination thereof. In addition, a shape such as a straight line or a curved line may be formed in which the joint portion is continuous. The formation pattern of the heat-melt adhesive portion 4 can be, for example, the patterns shown in FIG. 2( b ) and FIG. 2( c ).

热熔融粘合部分4相对于立体片10的面积的面积比率(每单位面积立体片10的热熔融粘合部分4的面积)由立体片10的具体用途等决定,但从充分地提高第1纤维层至第3纤维层的接合强度方面,以及从通过第2纤维层的变形而充分形成凸状的立体形状以呈现膨松的观点出发,在热熔融粘合部分4的形成后且第1纤维层1的热收缩前,所述面积比率优选为3~50%,特别优选为5~35%,在热收缩后,其优选为6~90%,特别优选为10~70%。The area ratio (area of the thermally fused adhesive portion 4 of the three-dimensional sheet 10 per unit area) of the thermal fusion bonding portion 4 with respect to the area of the three-dimensional sheet 10 is determined by the specific use of the three-dimensional sheet 10, etc., but from fully improving the first In terms of the bonding strength of the fiber layer to the third fiber layer, and from the point of view that the convex three-dimensional shape is sufficiently formed by the deformation of the second fiber layer to exhibit bulkiness, after the formation of the heat-melt bonding portion 4 and the first Before thermal shrinkage of the fibrous layer 1, the area ratio is preferably 3-50%, particularly preferably 5-35%, and after thermal shrinkage, it is preferably 6-90%, particularly preferably 10-70%.

立体片10,在将处于层压状态的第1纤维层至第3纤维层部分地热压接而成为一体后,在第1纤维层1中含有的热收缩性纤维的收缩起始温度以上进行热处理而制造,由于第1纤维层的热收缩,第2纤维层2的上述热熔融粘合部分4以外的部分是成为凸起状。在本实施方案中,立体片10,如图2(a)所示,具有多个被菱形格子状的图案构成的热熔融粘合部分4包围的封闭的区域,在该封闭的各区域中,第2纤维层2变形为圆顶状的凸状。另一方面,热熔融粘合部分4与第2纤维层2构成凸状的部分(也称为凸部5)相比相对凹陷,因此在立体片10的第2纤维层侧的表面上形成由多个凸部和凹部构成的凹凸形状。在本实施方案中,通过第1纤维层1的收缩,在第3纤维层3侧也形成同样的凹凸形状。The three-dimensional sheet 10 is formed above the shrinkage initiation temperature of the heat-shrinkable fibers contained in the first fiber layer 1 after the first fiber layer in the laminated state to the third fiber layer are partially thermocompression-bonded to form a whole. Manufactured by heat treatment, the portion of the second fiber layer 2 other than the thermally fused bonded portion 4 becomes convex due to thermal shrinkage of the first fiber layer. In the present embodiment, the three-dimensional sheet 10, as shown in Figure 2 (a), has a plurality of closed areas surrounded by thermally fused adhesive parts 4 formed in a rhombus lattice pattern, and in each area of the closure, The second fiber layer 2 is deformed into a dome-shaped convex shape. On the other hand, the thermal fusion bonded portion 4 is relatively recessed compared with the convex portion (also referred to as the convex portion 5) of the second fiber layer 2, so that the surface of the second fiber layer side of the three-dimensional sheet 10 is formed by A concavo-convex shape consisting of a plurality of convex and concave parts. In this embodiment, the same concavo-convex shape is formed also on the third fiber layer 3 side by shrinkage of the first fiber layer 1 .

第1纤维层1含有热收缩性纤维。该热收缩性纤维,在立体片10中为热收缩的状态。作为热收缩性纤维,并无特别限制,可以使用已知的热收缩性纤维。如果使用潜在卷曲性纤维作为热收缩性纤维,由于赋予第1纤维层1弹性体的性质,即使作为立体片10整体也呈现出弹性体的性质,因此是优选的。如果立体片10具有弹性体的性质,当将立体片10用作例如后述的一次性吸收性物品的构成构件时,对于穿用者动作的随动性变得良好,该吸收性物品的适合性提高,有效地防止液体泄露,因此是优选的。The first fiber layer 1 contains heat-shrinkable fibers. The heat-shrinkable fibers are in a heat-shrunk state in the three-dimensional sheet 10 . The heat-shrinkable fibers are not particularly limited, and known heat-shrinkable fibers can be used. It is preferable to use latent crimping fibers as heat-shrinkable fibers because the properties of an elastic body are imparted to the first fiber layer 1 and the three-dimensional sheet 10 as a whole exhibits properties of an elastic body. If the three-dimensional sheet 10 has the properties of an elastic body, when the three-dimensional sheet 10 is used as, for example, a constituent member of a disposable absorbent article described later, the followability to the movement of the wearer becomes good, and the absorbent article is suitable for use. The performance is improved and the liquid leakage is effectively prevented, so it is preferable.

潜在卷曲性纤维,例如以收缩率不同的2种热塑性聚合物材料为成分的偏心芯鞘型复合纤维或并列型复合纤维构成。作为其例子,可以列举出特开平9-296325号公报或特许2759331号说明书中记载的纤维。作为收缩率不同的2种热塑性聚合物材料的例子,可以列举出例如乙烯-丙烯无规共聚物(EP)和聚丙烯(PP)的组合、聚对苯二甲酸乙二醇酯(PET)、聚对苯二甲酸乙二醇酯和聚间苯二甲酸乙二醇酯的共聚物(CoPET)的组合。热收缩性纤维可以为切断短纤维或长丝。其粗细优选为1~7dtex左右。Potentially crimped fibers, such as eccentric core-sheath composite fibers or side-by-side composite fibers composed of two types of thermoplastic polymer materials with different shrinkage rates. Examples thereof include fibers described in JP-A-9-296325 or Japanese Patent No. 2759331. Examples of two types of thermoplastic polymer materials having different shrinkage rates include combinations of ethylene-propylene random copolymer (EP) and polypropylene (PP), polyethylene terephthalate (PET), A combination of a copolymer of polyethylene terephthalate and polyethylene isophthalate (CoPET). The heat-shrinkable fibers may be staple fibers or filaments. The thickness is preferably about 1 to 7 dtex.

热收缩性纤维的热收缩起始温度例如可以为90~110℃。所谓热收缩起始温度,是指将该纤维置于可以升温的炉内,以一定速度升温时该纤维实质上开始收缩时的实测温度。The heat-shrinkage start temperature of the heat-shrinkable fiber may be, for example, 90 to 110°C. The so-called thermal shrinkage initiation temperature refers to the measured temperature at which the fiber substantially begins to shrink when the fiber is placed in a furnace that can be heated at a certain rate.

第1纤维层1可以由热收缩性纤维100%构成,或者可以含有其他的纤维。作为第1纤维层1中含有的其他纤维,可以列举出后述的热熔融粘合纤维,例如第2和/或第3纤维层中含有的热熔融粘合纤维。The first fiber layer 1 may be composed of 100% heat-shrinkable fibers, or may contain other fibers. Examples of other fibers contained in the first fiber layer 1 include thermally fusible fibers to be described later, for example, thermally fusible fibers contained in the second and/or third fiber layers.

第1纤维层1中可以含有其他纤维,在立体片制造时,从不阻碍热收缩性纤维的收缩的观点出发,热收缩性纤维的量相对于第1纤维层1的重量为70重量%以上,特别优选为90~100重量%。Other fibers may be contained in the first fiber layer 1, and the amount of the heat-shrinkable fiber is 70% by weight or more relative to the weight of the first fiber layer 1 from the viewpoint of not hindering the shrinkage of the heat-shrinkable fiber when the three-dimensional sheet is produced. , particularly preferably 90 to 100% by weight.

作为热收缩前的第1纤维层1的形态,可以列举出构成纤维处于未接合状态的纤维幅或无纺布。作为纤维幅形态的第1纤维层1,可以列举出含有热收缩性纤维并且用梳理机法形成的纤维幅。作为无纺布形态的第1纤维层1,可以列举出含有热收缩性纤维,用各种无纺布制造法制造的无纺布。作为无纺布的制造法,可以列举出热熔融粘合法、水流交络法、针刺法、溶剂粘接法、纺粘法、熔喷法。Examples of the form of the first fiber layer 1 before thermal shrinkage include a fiber web or a nonwoven fabric in which constituent fibers are not bonded. Examples of the first fibrous layer 1 in the form of a fibrous web include fibrous webs containing heat-shrinkable fibers and formed by a carding method. Examples of the first fiber layer 1 in the form of a nonwoven fabric include nonwoven fabrics that contain heat-shrinkable fibers and are manufactured by various nonwoven fabric manufacturing methods. Examples of the method for producing the nonwoven fabric include thermal fusion bonding, hydroentanglement, needle punching, solvent bonding, spunbonding, and meltblowing.

第2纤维层2以非热收缩性纤维作为主体而构成。本说明中所谓的非热收缩性纤维,包含不显示热收缩性的纤维、以及显示热收缩性但在第1纤维层含有的热收缩性纤维的热收缩起始温度以下实质上不产生热收缩的纤维的两者。The second fiber layer 2 is mainly composed of non-heat-shrinkable fibers. The so-called non-heat-shrinkable fibers in this specification include fibers that do not show heat-shrinkability, and fibers that show heat-shrinkability but do not substantially cause heat shrinkage below the heat-shrinkage initiation temperature of the heat-shrinkable fibers contained in the first fiber layer. Both of the fibers.

从第1纤维层变得更为立体的方面出发,优选的是,第2纤维层2中的非热收缩性纤维的量相对于第2纤维层2的重量至少为70重量%以上,优选为90重量%以上,特别优选为100重量%。From the perspective that the first fiber layer becomes more three-dimensional, it is preferable that the amount of non-heat-shrinkable fibers in the second fiber layer 2 is at least 70% by weight relative to the weight of the second fiber layer 2, preferably 90% by weight or more, particularly preferably 100% by weight.

此外,从进行立体性和收缩性的调整的观点出发,优选在第2纤维层中含有10~30重量%左右的与第1纤维层中的热收缩性纤维相同的热收缩性纤维。In addition, from the viewpoint of adjusting the three-dimensionality and shrinkability, it is preferable that the second fiber layer contains about 10 to 30% by weight of the same heat-shrinkable fiber as the heat-shrinkable fiber in the first fiber layer.

第2纤维层2和第3纤维层3分别含有热熔融粘合性纤维。热熔融粘合性纤维是含有热熔融粘合树脂,并由于该树脂的熔融固化使得纤维之间能够熔融粘合的纤维。从进一步使热熔融粘合部分的接合强度提高的方面出发,优选第2纤维层2和第3纤维层3中含有的热熔融粘合性纤维分别含有比第1纤维层1中含有的热收缩性纤维的熔点低的热熔融粘合树脂。当第1纤维层中的热收缩性纤维为芯鞘型(偏心或同心型)的复合纤维或并列型的复合纤维时,优选第2和第3纤维层中含有的热熔融粘合性纤维含有比芯鞘型复合纤维的鞘成分或并列型复合纤维两者的热熔融粘合成分的熔点低的树脂。The second fiber layer 2 and the third fiber layer 3 each contain heat-melt-adhesive fibers. The heat-melt-adhesive fiber is a fiber which contains a heat-melt adhesive resin, and melt-bonds between fibers by the melt-hardening of this resin. From the point of view of further improving the bonding strength of the heat-melt bonded portion, it is preferable that the heat-melt-adhesive fibers contained in the second fiber layer 2 and the third fiber layer 3 contain more heat-shrinkable fibers than those contained in the first fiber layer 1, respectively. Hot-melt adhesive resin with low melting point for fibers. When the heat-shrinkable fibers in the first fiber layer are core-sheath type (eccentric or concentric) conjugate fibers or side-by-side conjugate fibers, it is preferable that the heat-melt-adhesive fibers contained in the second and third fiber layers contain A resin having a lower melting point than the sheath component of the core-sheath conjugate fiber or the heat-melt bonding component of both side-by-side conjugate fibers.

这里,热收缩性纤维的熔点是指采用DSC(差示扫描量热计)进行熔解热测定时的峰值。Here, the melting point of the heat-shrinkable fiber refers to the peak value when the heat of fusion is measured by DSC (differential scanning calorimeter).

从在不使与皮肤接触的第1纤维层收缩的情况下,能使第2纤维层中含有的热熔融粘合纤维熔融而粘接的方面出发,优选第2纤维层2和第3纤维层3中含有的热熔融粘合性纤维中的热熔融粘合树脂的熔点比第1纤维层的热收缩性纤维的熔点低10℃以上,特别优选低20℃以上。当热熔融粘合性纤维为多成分型的复合纤维时,优选其中熔点最低的热熔融粘合树脂比第1纤维层的热收缩性纤维的熔点低。From the point of view that the thermal fusion adhesive fibers contained in the second fiber layer can be melted and bonded without shrinking the first fiber layer in contact with the skin, the second fiber layer 2 and the third fiber layer are preferably The melting point of the heat-melting adhesive resin contained in the heat-melting adhesive fibers contained in 3 is lower by 10°C or more, particularly preferably 20°C or more, than the melting point of the heat-shrinkable fibers of the first fiber layer. When the heat-melt-adhesive fiber is a multi-component type conjugate fiber, it is preferable that the heat-melt adhesive resin having the lowest melting point is lower than the melting point of the heat-shrinkable fiber of the first fiber layer.

此外,从不使第1纤维层收缩,能使第2纤维层中含有的热熔融粘合纤维熔化并具有足够的接着强度的方面出发,优选第2纤维层2和第3纤维层3中含有的热熔融粘合性纤维中的热熔融粘合树脂的熔点比第1纤维层的热收缩性纤维的热收缩温度低30℃以上,特别优选低40℃以上。In addition, from the viewpoint of not shrinking the first fiber layer, the heat-melt adhesive fibers contained in the second fiber layer can be melted and have sufficient bonding strength, it is preferable that the second fiber layer 2 and the third fiber layer 3 contain The melting point of the heat-melt adhesive resin in the heat-melt-adhesive fiber is lower than the thermal shrinkage temperature of the heat-shrinkable fiber of the first fiber layer by 30°C or more, particularly preferably 40°C or more.

此外,从可以使第1纤维层至第3纤维层的接合强度进一步提高,并且使它们一体化的热处理的温度条件可以在较低温度下进行,可以使立体片的质量风格进一步改进的方面出发,优选第2纤维层2含有的热熔融粘合纤维中的热熔融粘合树脂的熔点和第3纤维层3含有的热熔融粘合纤维中的热熔融粘合树脂的熔点相同,或这2种热熔融粘合树脂的熔点差在20℃以内,特别优选在10℃以内。In addition, from the point that the bonding strength of the first fiber layer to the third fiber layer can be further improved, and the temperature conditions of the heat treatment for integrating them can be carried out at a lower temperature, and the quality and style of the three-dimensional sheet can be further improved. Preferably, the melting point of the heat-melt adhesive resin in the heat-melt adhesive fibers contained in the second fiber layer 2 is the same as the melting point of the heat-melt adhesive resin in the heat-melt adhesive fibers contained in the third fiber layer 3, or the two The difference between the melting points of the hot-melt adhesive resins is within 20°C, particularly preferably within 10°C.

从使热熔融粘合部分4的纤维层之间的接合强度提高并且使立体片的质量风格变得良好的方面出发,优选第2纤维层含有的热熔融粘合纤维的量相对于第2纤维层2的重量为70~100重量%,特别优选为90~100重量。From the point of view of improving the joint strength between the fiber layers of the heat-melt bonding portion 4 and making the quality style of the three-dimensional sheet good, it is preferable that the amount of the heat-melt-bonding fibers contained in the second fiber layer is less than that of the second fiber layer. The weight of layer 2 is 70 to 100% by weight, particularly preferably 90 to 100% by weight.

从使热熔融粘合部分4的纤维层之间的接合强度提高并且使立体片的质量风格变得良好的方面,以及提高与其他材料等特别是与纤维材料的热压接性方面出发,优选第3纤维层含有的热熔融粘合纤维的量相对于第3纤维层3的重量为70~100重量%,特别优选为90~100重量%。From the aspects of improving the joint strength between the fiber layers of the heat-melt bonding part 4 and making the quality style of the three-dimensional sheet become good, and improving the thermocompression bondability with other materials, etc., especially with the fiber material, it is preferable The quantity of the heat-melt adhesive fiber contained in a 3rd fiber layer is 70-100 weight% with respect to the weight of the 3rd fiber layer 3, Especially preferably, it is 90-100 weight%.

作为第2纤维层2和第3纤维层3中含有的热熔融粘合纤维的例子,可以列举出聚乙烯(PE)、聚丙烯(PP)、聚乙烯-丙烯共聚物、聚对苯二甲酸乙二醇酯(PET)、聚对苯二甲酸丁二醇酯等聚酯、聚对苯二甲酸乙二醇酯-间苯二甲酸乙二醇酯共聚物、聚酰胺-乙烯-丙烯酸共聚物、乙烯-丙烯酸甲酯共聚物、乙烯-甲基丙烯酸共聚物、乙烯-甲基丙烯酸甲酯共聚物、乙烯-甲基丙烯酸乙酯共聚物、乙烯-甲基丙烯酸甲酯-丙烯酸3元共聚物等构成的纤维。此外,也可以使用由这些热塑性聚合物材料的组合构成的芯鞘型复合纤维或并列型复合纤维。这些纤维可以是短纤或长丝。其粗细优选为1~7dtex左右。在使第1纤维层1含有热熔融粘合纤维时的热熔融粘合纤维可以使用与这些相同的纤维。Examples of the heat-melt-adhesive fibers contained in the second fiber layer 2 and the third fiber layer 3 include polyethylene (PE), polypropylene (PP), polyethylene-propylene copolymer, polyethylene terephthalate Polyethylene glycol ester (PET), polyester such as polybutylene terephthalate, polyethylene terephthalate-ethylene isophthalate copolymer, polyamide-ethylene-acrylic acid copolymer , ethylene-methyl methacrylate copolymer, ethylene-methacrylic acid copolymer, ethylene-methyl methacrylate copolymer, ethylene-ethyl methacrylate copolymer, ethylene-methyl methacrylate-acrylic acid ternary copolymer composed of fibers. In addition, core-sheath type composite fibers or side-by-side type composite fibers composed of combinations of these thermoplastic polymer materials can also be used. These fibers can be staple or filament. The thickness is preferably about 1 to 7 dtex. When the first fiber layer 1 contains heat-melt-bond fibers, the same fibers as these can be used.

作为第1纤维层1热收缩前的第2和第3纤维层2、3的形态,可以列举出构成纤维处于未接合状态的纤维幅或无纺布。热收缩前的第2纤维层2和第3纤维层3的形态可以相同或不同。Examples of the form of the second and third fiber layers 2 and 3 before the first fiber layer 1 is thermally shrunk include a fiber web or a nonwoven fabric in which constituent fibers are not bonded. The forms of the second fiber layer 2 and the third fiber layer 3 before thermal shrinkage may be the same or different.

第2纤维层的形态如果为纤维幅,通过收缩使第2纤维层2的面积乃至形状变化变得容易,且容易使第2纤维层2沿厚度方向鼓起为凸状,因此特别优选。此外,由于鼓起的凸部中用纤维填满,可以得到缓冲性好,具有柔软质量风格的片,因此是优选的。当第2纤维层2和/或第3纤维层3为纤维幅的形态时,该纤维幅可以采用例如梳理机法形成。第2纤维层2在由该纤维幅形成的立体片10中形成膨松的且用构成该纤维幅的纤维填满的凸部5,而且纤维沿凸部5取向。特别地,如果第2纤维层2为采用梳理机法形成的纤维幅的形态,第2纤维层2成为极疏的结构,则本发明的立体片10可以透过或保持粘度高的液体。此外,使立体片10沿厚度方向压缩时的压缩变形性也提高。作为粘度高的液体,可以列举出软便或经血、用于人的清洁剂或保湿剂、或用于物的清洁剂。If the form of the second fiber layer is a fiber web, the area and shape of the second fiber layer 2 can be easily changed by shrinkage, and the second fiber layer 2 can easily bulge into a convex shape in the thickness direction, which is particularly preferable. In addition, since the swollen protrusions are filled with fibers, a sheet with good cushioning properties and a soft quality can be obtained, which is preferable. When the second fiber layer 2 and/or the third fiber layer 3 are in the form of a fiber web, the fiber web can be formed by, for example, a carding method. The second fiber layer 2 forms bulky convex portions 5 filled with fibers constituting the fiber web in the three-dimensional sheet 10 formed of the fiber web, and the fibers are oriented along the convex portions 5 . In particular, if the second fiber layer 2 is in the form of a fiber web formed by a carding machine method, and the second fiber layer 2 has a very sparse structure, the three-dimensional sheet 10 of the present invention can permeate or retain high-viscosity liquids. In addition, the compression deformability when the three-dimensional sheet 10 is compressed in the thickness direction is also improved. Examples of high-viscosity liquids include loose stools and menstrual blood, cleansers and moisturizers for humans, and cleansers for objects.

另一方面,如果第2纤维层的形态在接合和收缩前为无纺布,具有输送性良好以及强度大的优点。此外,由于在与第1纤维层接合后不需使第2纤维层的构成纤维之间熔融粘合,因此还具有收缩温度的选择范围宽的优点。On the other hand, if the form of the second fiber layer is a non-woven fabric before joining and shrinkage, it has the advantages of good conveyability and high strength. In addition, since it is not necessary to melt-bond the constituent fibers of the second fiber layer after bonding with the first fiber layer, there is also an advantage in that the shrinkage temperature can be selected from a wide range.

本实施方案的立体片10按如下所述制备,例如,使用已知的方法分别制造第1纤维层至第3纤维层,使它们重叠以使第1纤维层1夹持在第2纤维层2和第3纤维层3之间,然后使用由凹凸辊之间或凹凸辊和平滑辊构成的热压花辊装置,以预定图案使层压的第1纤维层至第3纤维层部分地(局部地)热压接,然后,通过第1纤维层1含有的热收缩性纤维的热收缩温度以上的热处理,使该热收缩性纤维收缩。热处理的方法除了向层压一体化的第1纤维层至第3纤维层通入吹送热风的方法外,还可以使用微波、蒸气、红外线、热辊接触等方法。The three-dimensional sheet 10 of this embodiment is produced as follows, for example, using a known method to manufacture the first fiber layer to the third fiber layer respectively, and make them overlap so that the first fiber layer 1 is sandwiched by the second fiber layer 2 And between the 3rd fiber layer 3, then use the hot embossing roll device that is made up of concave-convex roll or concave-convex roll and smooth roll, make the laminated 1st fiber layer to the 3rd fiber layer partly (partially) with predetermined pattern ) thermocompression bonding, and then, the heat-shrinkable fibers contained in the first fiber layer 1 are shrunk by heat treatment at or above the heat-shrinkage temperature of the heat-shrinkable fibers. In addition to the method of blowing hot air to the laminated and integrated first to third fiber layers, the method of heat treatment can also use methods such as microwave, steam, infrared rays, and hot roller contact.

根据本实施方案的立体片10,在俯视该立体片10的状态下,形成的预定图案的热熔融粘合部分4从第2纤维层贯穿到第3纤维层,因此可以提高从热熔融粘合部分4中的第2纤维层到第3纤维层的接合强度。因此,可以在充分地维持第1纤维层的足够的收缩性以及从第2纤维层到第3纤维层的接合强度的同时,例如,可以在较低温度的条件下进行制造时的热压接。因此,可以获得柔软的、肌肤接触感良好的质量风格的立体片。According to the three-dimensional sheet 10 of this embodiment, under the state of overlooking this three-dimensional sheet 10, the heat-melt bonding part 4 of the predetermined pattern that forms penetrates from the 2nd fiber layer to the 3rd fiber layer, therefore can improve from heat-melt bonding. Bond strength of the 2nd fiber layer to the 3rd fiber layer in part 4. Therefore, while sufficiently maintaining sufficient shrinkage of the first fiber layer and joint strength from the second fiber layer to the third fiber layer, for example, thermocompression bonding during production can be performed at a relatively low temperature. . Therefore, it is possible to obtain a three-dimensional sheet that is soft and has a good quality when touching the skin.

此外,通过将第3纤维层侧面向要固定立体片10的其他材料等(也称为被固定物6)侧进行热压接(热压花等),可以牢固地将该立体片10热压接到该其他材料等上,使立体片10和被固定物之间不易剥离。In addition, by thermally compressing (thermally embossing, etc.) the side of the third fiber layer to the side of other materials (also referred to as the object to be fixed 6) to be fixed to the three-dimensional sheet 10, the three-dimensional sheet 10 can be firmly thermocompressed. Connect to the other materials, so that the three-dimensional sheet 10 and the object to be fixed are not easy to peel off.

图3表示以下状态:以第3纤维层侧为该被固定物侧,通过热压花加工使上述构成的立体片10固定在作为纤维材料构成的被固定物6的生理用卫生巾(吸收性物品)的吸收体61和防漏片62上。Fig. 3 shows following state: take the 3rd fiber layer side as this fixed object side, make the three-dimensional sheet 10 of above-mentioned structure be fixed on the sanitary napkin (absorbency article) on the absorbent body 61 and the leak-proof sheet 62.

即,在生理用卫生巾的中央区域中,立体片10通过采用热封装置的热压花加工热压接于吸收体61的肌肤接触面侧的表面,通过该热压接部分71在生理用卫生巾的肌肤接触面上形成环状的中央防漏沟。此外,立体片10在生理用卫生巾的纵向的两侧部,同样地通过采用热封装置的热压花加工,热压接于配置在吸收体61上的防漏片上,通过该热压接部分72,在生理用卫生巾的肌肤接触面的上述中央防漏沟的两侧形成一对侧防漏沟。此外,热压接部分71的吸收体的表面采用纤维素类纤维材料构成的纸板形成,热压接部分72中的防漏片62经在纤维素类的纤维材料上层压聚乙烯而构成。此外,防漏片62的接着性更良好,因此将层压侧(聚乙烯)面向表面片侧使用(在后述的实施例和比较例中也是同样)。That is, in the central region of the sanitary napkin, the three-dimensional sheet 10 is thermocompression-bonded to the skin-contacting surface side surface of the absorber 61 by heat embossing using a heat-sealing apparatus, An annular central anti-leakage groove is formed on the skin-contacting surface of the sanitary napkin. In addition, the three-dimensional sheet 10 is similarly bonded to the leak-proof sheet arranged on the absorber 61 by thermal embossing using a heat-sealing device on both sides of the sanitary napkin in the longitudinal direction. The portion 72 forms a pair of side leakage prevention grooves on both sides of the central leakage prevention groove on the skin contact surface of the sanitary napkin. In addition, the surface of the absorber in the thermocompression bonding portion 71 is formed of cardboard made of cellulose fiber material, and the leakage prevention sheet 62 in the thermocompression bonding portion 72 is formed by laminating polyethylene on the cellulose fiber material. In addition, since the leak-proof sheet 62 has better adhesiveness, it was used with the lamination side (polyethylene) facing the surface sheet side (the same applies to Examples and Comparative Examples described later).

在两热压接部分71、72中,在采用热封装置进行热压花加工时,第3纤维层中的热熔融粘合树脂以进入被固定物6的构成纤维间的状态熔融固化,因此立体片10与这些被固定物6之间不易产生剥离。In the two thermocompression bonding parts 71, 72, when adopting heat sealing device to carry out heat embossing processing, the thermal fusion adhesive resin in the 3rd fibrous layer melts and solidifies with the state that enters between the constituent fibers of fixed object 6, so The separation between the three-dimensional sheet 10 and these fixed objects 6 is not easy to occur.

此外,作为热封装置,在生理用卫生巾、一次性尿布等中,可以使用以往使用的沟形成用热封装置或端封部形成用热封装置等。此外,在图3中,省略了立体片10的表面上形成的凹凸等图示。在图3所示的生理用卫生巾中,使用立体片10作为液体透过性的表面材料(表面片),在该立体片10和液体不透过性的背面材料(背面片)8之间存在有液体保持性的吸收体61。立体片10在吸收体61的两侧部附近用热熔粘接剂91固定于防漏片62和背面材料8上,防漏片62用热熔粘接剂92固定在背面材料8上。In addition, as the heat-sealing device, conventionally used heat-sealing devices for groove formation, heat-sealing devices for end-seal portion formation, and the like can be used in sanitary napkins, disposable diapers, and the like. In addition, in FIG. 3, illustration of the uneven|corrugated etc. formed on the surface of the three-dimensional sheet 10 is abbreviate|omitted. In the sanitary napkin shown in Fig. 3, the three-dimensional sheet 10 is used as the liquid-permeable surface material (surface sheet), and between the three-dimensional sheet 10 and the liquid-impermeable back material (back sheet) 8 There is an absorbent body 61 having liquid retentivity. The three-dimensional sheet 10 is fixed on the leak-proof sheet 62 and the back material 8 with a hot-melt adhesive 91 near both sides of the absorber 61 , and the leak-proof sheet 62 is fixed on the back material 8 with a hot-melt adhesive 92 .

图4表示本发明(第2发明)的立体片固定方法的优选实施方案,图4所示的立体片10’在含有热收缩性纤维的第1纤维层1的一个面上层压有以非热收缩性纤维为主体且含有热熔融粘合性纤维的第2纤维层2,第1纤维层1和第2纤维层2形成具有预定图案的热熔融粘合部分(接合部分)4。立体片10’除了没有在第1纤维层1的另一个面上层压第3纤维层外,具有与上述立体片10相同的构成。在立体片10’中,第1纤维层1和第2纤维层2用与立体片10同样的图案进行热熔融粘合,从而形成上述预定图案的熔融粘合部分4。第1纤维层1和第2纤维层2各自优选的构成等与立体片10中第1纤维层和第2纤维层相同。Fig. 4 shows the preferred embodiment of the three-dimensional sheet fixing method of the present invention (the 2nd invention), and the three-dimensional sheet 10 ' shown in Fig. 4 is laminated with a non-thermal The first fiber layer 1 and the second fiber layer 2 form a heat-melt bonded part (junction part) 4 having a predetermined pattern. The three-dimensional sheet 10' has the same structure as the above-mentioned three-dimensional sheet 10 except that the third fiber layer is not laminated on the other surface of the first fiber layer 1. In the three-dimensional sheet 10', the first fibrous layer 1 and the second fibrous layer 2 are heat-fused and bonded in the same pattern as the three-dimensional sheet 10, thereby forming the fusion-bonded portion 4 of the above-mentioned predetermined pattern. The respective preferred configurations of the first fiber layer 1 and the second fiber layer 2 are the same as those of the first fiber layer and the second fiber layer in the three-dimensional sheet 10 .

在本实施方案的立体片的固定方法中,在采用压花加工将立体片10’固定到作为纤维材料构成的被固定物6的生理用卫生巾(吸收性物品)的吸收体61上时,使与该立体片10’另外制造的含有热熔融粘合性纤维的第3纤维层介于立体片10’的第2纤维层2和被固定物6之间,从该立体片10’侧实施热压花加工。In the fixing method of the three-dimensional sheet of the present embodiment, when the three-dimensional sheet 10' is fixed to the absorber 61 of the sanitary napkin (absorbent article) as the object to be fixed 6 made of fibrous material by embossing, Make the 3rd fibrous layer containing thermal fusion adhesive fiber manufactured separately with this three-dimensional sheet 10' between the second fibrous layer 2 of the three-dimensional sheet 10' and the object to be fixed 6, and implement from the three-dimensional sheet 10' side Hot embossing.

采用本实施方案的固定方法,在采用热封装置实施了热压花加工的部分,与上述立体片10相同,通过第1纤维层和第3纤维层中的热熔融粘合纤维的热熔融粘合树脂的熔融固化使第2纤维层2和第3纤维层3间极其牢固地接合为一体,同时在热压花加工时,由于第3纤维层中的热熔融粘合树脂以陷入被固定物的构成纤维间的状态熔融固化,因此在立体片与这些被固定物之间可以获得足够的接合强度。Adopt the fixation method of this embodiment, adopt heat-sealing device to carry out the part of thermal embossing processing, be the same as above-mentioned three-dimensional sheet 10, through the thermal fusion bonding of the thermal fusion bonding fiber in the 1st fiber layer and the 3rd fiber layer. The melting and solidification of the bonding resin makes the second fiber layer 2 and the third fiber layer 3 extremely firmly bonded together, and at the same time, during the heat embossing process, due to the thermal fusion of the bonding resin in the third fiber layer, the object to be fixed is trapped The state between the constituent fibers is melted and solidified, so sufficient bonding strength can be obtained between the three-dimensional sheet and these objects to be fixed.

本发明并不限于述实施方案。The invention is not limited to the embodiments described.

本发明的立体片适宜用作例如使用1次或数次后便废弃的一次性物品的构成构件。此外,也可以用作面扣件的凹材(环材)或凸材。特别适宜用作生理用卫生巾或一次性尿布等一次性吸收性物品、打扫用擦拭物或用于人的擦拭物等一次性擦拭物的构成材料。当用作一次性吸收性物品,例如具有液体透过性的表面材料、液体不透过性的背面材料和介于两片间的吸收体的吸收性物品的构成构件时,其构成构件的一部分可以用作例如表面材料、背面材料或侧立体护翼的任何构件的一部分。The three-dimensional sheet of the present invention is suitably used, for example, as a constituent member of a disposable article that is discarded after being used once or several times. In addition, it can also be used as a concave material (ring material) or a convex material of a surface fastener. It is particularly suitable as a constituent material of disposable absorbent articles such as sanitary napkins and disposable diapers, cleaning wipes, and disposable wipes such as human wipes. When used as a constituent member of a disposable absorbent article, such as an absorbent article having a liquid-permeable surface material, a liquid-impermeable backside material, and an absorbent body interposed between two sheets, it constitutes a part of the member Can be used as part of any component such as face material, back material or side body flaps.

采用热压花加工将本发明的立体片固定于其他材料等(被固定物)使用时以及在立体片的固定方法中,作为固定立体片的被固定物,可以列举出一次性擦拭物的基材片等。不过,特别是在纤维材料构成的被固定物的情况下,尤其是上述的生理用卫生巾或一次性尿布等一次性吸收性物品的吸收体等、由于压缩而变形的柔软的被固定物的情况下,本发明的效果更为显著地体现。When using thermal embossing to fix the three-dimensional sheet of the present invention to other materials, etc. Sheets etc. However, especially in the case of an object to be fixed made of a fibrous material, especially the above-mentioned absorbent body of disposable absorbent articles such as sanitary napkins or disposable diapers, etc., soft objects to be fixed that are deformed due to compression Under the situation, the effect of the present invention embodies more remarkably.

以下结合实施例对本发明进行更为详细的说明。但是,本发明的范围并不限于该实施例。Below in conjunction with embodiment the present invention is described in more detail. However, the scope of the present invention is not limited to this embodiment.

实施例Example

(1)第1纤维层的制造(1) Manufacture of the first fiber layer

作为热收缩性纤维,使用ダイワボウポリテツク社制造的潜在卷曲性芯鞘型复合纤维(商品名CPP,芯:聚丙烯(熔点165~170℃),鞘:乙烯-丙烯共聚物(熔点145~147℃),芯/鞘重量比=5/5,纤度2.2dtex,纤维长51mm,热收缩起始温度90℃)。以该纤维为原料,用罗拉梳理机形成纤维幅后,通过压花辊(压花率28%,温度条件:图案145℃、速度80m/min),使其通过冷却辊,形成单位面积重量为20g/m2的第1纤维层的热辊无纺布。As the heat-shrinkable fiber, a latent crimping core-sheath composite fiber (trade name: CPP, manufactured by Daiwa Bou Polytec Co., Ltd., core: polypropylene (melting point 165-170° C.), sheath: ethylene-propylene copolymer (melting point 145-147° C.) was used. ℃), core/sheath weight ratio = 5/5, fineness 2.2dtex, fiber length 51mm, heat shrinkage initiation temperature 90 ℃). With this fiber as raw material, after forming fiber web with roller carding machine, pass through embossing roll (28% of embossing rate, temperature condition: pattern 145 ℃, speed 80m/min), make it pass through cooling roll, form unit area weight 20g/ m2 thermal roll non-woven fabric for the 1st fiber layer.

(2)第2纤维层的制造(2) Manufacture of the second fiber layer

作为热收缩性纤维,使用ダイワボウポリテツク社制造的芯鞘型复合纤维(商品名SHW6,芯聚对苯二甲酸乙二醇酯(熔点250~255℃),鞘:聚乙烯(熔点128~130℃),芯/鞘重量比=5/5,纤度2.2dtex,纤维长51mm)。以该纤维为原料,用罗拉梳理机形成纤维幅后,通过风透法热处理机(速度138m/min,贯通风速1m/sec,处理时间约10秒),形成单位面积重量为12g/m2的第2纤维层的风透法无纺布。As the heat-shrinkable fiber, a core-sheath composite fiber (trade name SHW6) manufactured by Daiwa Bou Polytec Co., Ltd. was used, the core polyethylene terephthalate (melting point 250-255° C.), sheath: polyethylene (melting point 128-130° C. ℃), core/sheath weight ratio=5/5, denier 2.2dtex, fiber length 51mm). With this fiber as raw material, after the fiber web is formed with a roller carding machine, it is passed through a wind-through method heat treatment machine (speed 138m/min, through-air velocity 1m/sec, treatment time is about 10 seconds) to form a fabric with a weight per unit area of 12g/m 2 Air-permeable nonwoven fabric for the second fiber layer.

(3)第3纤维层的制造(3) Manufacture of the third fiber layer

将与上述第2纤维层的制造相同得到的风透法无纺布作为第3纤维层。The air-through nonwoven fabric obtained in the same manner as the production of the above-mentioned second fiber layer was used as the third fiber layer.

(4)立体片的制造(4) Manufacture of three-dimensional film

将上述第1纤维层至第3纤维层重叠,用压花辊(图案辊145℃,平面轧辊135℃,压花柄图2(c),点径1.5mm,面积率7.4%)进行贴合。然后,迅速地用针板拉幅机进行热收缩处理(上下风风速约4.2m,温度110℃~116℃,处理时间约14秒),通过机械设定,使其收缩为处理前尺寸的长70%、宽70%。制备的无纺布的单位面积重量约为84g/m2The above-mentioned first fiber layer to the third fiber layer are overlapped and bonded with an embossing roll (pattern roll 145°C, flat roll 135°C, embossing handle Figure 2(c), spot diameter 1.5mm, area ratio 7.4%) . Then, heat-shrink quickly with a needle tenter (wind speed up and down is about 4.2m, temperature is 110°C to 116°C, and processing time is about 14 seconds), and it is set mechanically to make it shrink to the length of the size before processing. 70%, 70% wide. The weight per unit area of the prepared nonwoven fabric was about 84 g/m 2 .

比较例comparative example

除了不使用第3纤维层进行帖合后使其收缩外,按照与实施例相同的步骤制得立体片。A three-dimensional sheet was produced in the same manner as in the examples except that the third fiber layer was not bonded and then shrunk.

[性能评价][Performance Evaluation]

使用制备的各立体片作为吸收性物品用的表面材料,对于各片连续生产100个以上的具有图3所示截面构成的生理用卫生巾。用温度190℃的热辊(热压花加工)将各立体片固定到吸收体61(单位面积重量为约250g/m2)中由纸板(单位面积重量为约16g/m2)构成的表面上,同时用温度200℃的热辊(热压花加工)固定到由层压了防水性聚乙烯片的纸(层压单位面积重量为约7g/m2,纸定量为16g/m2)构成的防漏片62上。Using each prepared three-dimensional sheet as a surface material for absorbent articles, 100 or more sanitary napkins having the cross-sectional configuration shown in FIG. 3 were continuously produced for each sheet. Each three-dimensional sheet was fixed to the surface made of cardboard (about 16 g/m 2 ) in the absorbent body 61 (about 250 g/m 2 ) with a hot roll at a temperature of 190° C. (heat embossing) At the same time, it is fixed to the paper laminated with a waterproof polyethylene sheet (the lamination weight per unit area is about 7g/m 2 , and the basis weight of the paper is 16g/m 2 ) On the leak-proof sheet 62 formed.

对于各个制造的生理用卫生巾,对固定在吸收体61上的热压接部分71和固定在防漏片62上的热压接部分72中的密封性,目视观察图案部分有无浮起,根据下述评价标准判定为热压接部分的外观没有问题(外观良好)的卫生巾的个数示于表1(N=100)。Regarding the sealability of the thermocompression bonded portion 71 fixed to the absorbent body 61 and the thermocompression bonded portion 72 fixed to the leak-proof sheet 62 for each manufactured sanitary napkin, the presence or absence of floating of the pattern portion was visually observed. Table 1 shows the number of sanitary napkins that were judged to have no problem with the appearance of the thermocompression bonded portion (good appearance) according to the following evaluation criteria (N=100).

<评价基准><Evaluation criteria>

外观良好:按密封区的形状那样,鲜明地与基材接着,完全没有浮起(凸起)。Appearance is good: The shape of the sealing area is clearly bonded to the base material, and there is no floating (bulge) at all.

外观不良:密封区的形状的一部分少量不鲜明,一部分或全部具有浮起。Defective appearance: A part of the shape of the sealed area is not clear, and a part or the whole of the seal area has floating.

                     表1   热压接部分71   热压接部分72     实施例     100     98     比较例     0     88 Table 1 Thermocompression part 71 Thermocompression part 72 Example 100 98 comparative example 0 88

100个卫生巾中密封部外观良好的个数Out of 100 sanitary napkins, the number of seal parts with good appearance

从表1所示的结果可以看到,实施例的立体片(本发明品)与吸收体和防漏片的热压接性优异,与其他材料等,特别是纤维材料构成的被固定物的热压接性优异。From the results shown in Table 1, it can be seen that the three-dimensional sheet of the example (the product of the present invention) has excellent thermocompression bondability with the absorber and the leak-proof sheet, and has excellent thermocompression bonding properties with other materials, especially fibrous materials. Excellent thermocompression bonding properties.

与此相比,比较例的立体片的密封区的形状一部分不鲜明,或存在一部分或全部具有浮起,在制品性能上存在问题。In contrast, in the three-dimensional sheet of the comparative example, the shape of the sealing region was partly unclear, or some or all of the seal area was raised, and there was a problem in product performance.

本发明的立体片质量风格好,与其他材料的热压接性优异,而且制造时可以形成所希望的凹凸。The three-dimensional sheet of the present invention has good quality and style, excellent thermocompression bondability with other materials, and can form desired unevenness during manufacture.

采用本发明的立体片的固定方法,可以将使用了热收缩性纤维的立体片牢固地接合于纤维材料构成的被固定物上。According to the fixing method of the three-dimensional sheet of the present invention, the three-dimensional sheet using heat-shrinkable fibers can be firmly bonded to an object to be fixed made of a fiber material.

Claims (7)

1.一种立体片,其是在含有热收缩了的热收缩性纤维的第1纤维层的一个面上层压以非热收缩性纤维为主体且含有热熔融粘合性纤维的第2纤维层,在第1纤维层的另一个面上层压含有热熔融粘合性纤维的第3纤维层,其中,第1纤维层至第3纤维层在上述立体片中形成具有预定图案的热熔融粘合部分,上述热熔融粘合部分从第2纤维层贯穿到第3纤维层,且第2纤维层在上述热熔融粘合部分以外的部分是成为凸起状。1. A three-dimensional sheet comprising a second fiber layer mainly composed of non-heat-shrinkable fibers and containing heat-melt-adhesive fibers on one surface of a first fiber layer containing heat-shrinkable heat-shrinkable fibers , on the other side of the first fiber layer, laminate the third fiber layer containing heat-melt adhesive fibers, wherein the first fiber layer to the third fiber layer form a heat-melt bond with a predetermined pattern in the above-mentioned three-dimensional sheet part, the above-mentioned heat-melt bonding part penetrates from the second fiber layer to the third fiber layer, and the part of the second fiber layer other than the above-mentioned heat-melt bonding part is convex. 2.根据权利要求1所述的立体片,其中,第2纤维层和第3纤维层中含有的热熔融粘合性纤维含有熔点比上述热收缩性纤维的熔点低的热熔融粘合树脂。2. The three-dimensional sheet according to claim 1, wherein the heat-melt adhesive fibers contained in the second fiber layer and the third fiber layer contain a heat-melt adhesive resin having a melting point lower than that of the heat-shrinkable fibers. 3.根据权利要求1所述的立体片,其中,第2纤维层中含有的热熔融粘合性纤维中的热熔融粘合树脂的熔点与第3纤维层含有的热熔融粘合性纤维中的热熔融粘合树脂的熔点相同,或者这2种热熔融粘合树脂的熔点差为20℃以内。3. The three-dimensional sheet according to claim 1, wherein the melting point of the heat-melt adhesive resin in the heat-melt adhesive fibers contained in the 2nd fiber layer is the same as that of the heat-melt adhesive fibers contained in the 3rd fiber layer. The melting points of the two hot-melt adhesive resins are the same, or the difference between the melting points of the two hot-melt adhesive resins is within 20°C. 4.根据权利要求1所述的立体片,其中,通过热压花加工将第3纤维层侧作为被固定物侧固定到由纤维材料构成的被固定物上。4. The three-dimensional sheet according to claim 1, wherein the third fiber layer side is fixed to the fixed object made of a fiber material as the fixed object side by thermal embossing. 5.根据权利要求4所述的立体片,其中,所述被固定物为生理用卫生巾、一次性尿布等吸收性物品的吸收体。5. The three-dimensional sheet according to claim 4, wherein the object to be fixed is an absorber of absorbent articles such as sanitary napkins and disposable diapers. 6.一种立体片的固定方法,其中,在含有热收缩性纤维的第1纤维层的一个面上层压以非热收缩性纤维为主体且含有热熔融粘合性纤维的第2纤维层,并且将第1纤维层和第2纤维层形成预定图案的接合部而形成的立体片的第2纤维层侧作为被固定物侧固定到由纤维材料构成的被固定物上,6. A method for fixing a three-dimensional sheet, wherein, on one surface of the first fiber layer containing heat-shrinkable fibers, a second fiber layer containing non-heat-shrinkable fibers as the main body and heat-melt-adhesive fibers is laminated, And the 2nd fiber layer side of the three-dimensional sheet formed by forming the junction part of the predetermined pattern with the 1st fiber layer and the 2nd fiber layer is fixed on the to-be-fixed object made of fibrous material as the fixed object side, 而且使含有热熔融粘合性纤维的第3纤维层介于上述立体片和上述被固定物之间,通过热压花加工使它们成为一体。Furthermore, a third fiber layer containing heat-fusible fibers is interposed between the above-mentioned three-dimensional sheet and the above-mentioned object to be fixed, and they are integrated by heat embossing. 7.根据权利要求6所述的立体片的固定方法,其中,所述被固定物为生理用纸巾、一次性尿布等吸收性物品的吸收体。7. The fixing method of the three-dimensional sheet according to claim 6, wherein the object to be fixed is an absorber of absorbent articles such as sanitary napkins and disposable diapers.
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