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CN1609029A - Method of forming notched color fine pattern on the surface of glass product - Google Patents

Method of forming notched color fine pattern on the surface of glass product Download PDF

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Publication number
CN1609029A
CN1609029A CN 200410066779 CN200410066779A CN1609029A CN 1609029 A CN1609029 A CN 1609029A CN 200410066779 CN200410066779 CN 200410066779 CN 200410066779 A CN200410066779 A CN 200410066779A CN 1609029 A CN1609029 A CN 1609029A
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glass
pattern
image
spray printing
intaglio
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CN 200410066779
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Chinese (zh)
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CN100532302C (en
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高国樑
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Individual
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Individual
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Priority to CNB2004100667793A priority Critical patent/CN100532302C/en
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Abstract

The present invention is process of forming color notched fine pattern on the surface of glass and glass product and is suitable for making artistic glass and glass product. The forming process includes forming digital image file with color image, processing with grating image processor, spray printing color negative on the surface of glass and glass product with digital spray printer, chemically etching the glass and glass product, eliminating ink from the negative, and spray printing color positive pattern in the position of the negative with digital spray printer. The present invention has the advantages of copying the color image on the surface of glass and glass product precisely, forming bright and firmly attached pattern to the back side of daily used article, being suitable for mechanical production, and no negative and printing plate resulting in low cost.

Description

Form the method for colored intaglio fine pattern at glass and glass article surface
One, technical field
A kind of have the method for the colored intaglio fine pattern of photo effect at glass and glass article surface formation.The present invention relates to a kind of digital spray printing equipment of using and form the color negative pattern at glass and glasswork (hereinafter to be referred as glass) surface, carry out chemical surface treatment then, make glass surface produce the intaglio point, at the colored erect image pattern of intaglio position spray printing, make glass surface form the method for colored intaglio fine pattern then with photo effect.
Two, technical background
Form the so-called art glass of various patterns at glass surface, in fields such as building, decoration, furniture, daily necessities, artwork, more and more used in recent years.The manufacture method of art glass mainly contains multicolor printing method, etch printing method, sand-blast, frosted method, mill method at quarter, the color brilliant method of upright line etc. at present.In these methods, because the restriction of complete processing, the pattern of processing mostly is rough strip and block structure greatly, and the shade of grey and tonal variation that pattern is shown as photo almost are impossible, thereby make the artistic expression of art glass and infectivity be subjected to very big influence.
For addressing this problem, publication number provides a kind of method at glass and glass article surface formation fine pattern for the patent of CN1446703A.Can form at glass surface in this way and have the shade of grey of photo effect and the fine pattern of tonal variation.But this pattern is a simulation black and white formula, even filling colored ink in the intaglio point after chemical treatment also can only form the pattern of single color, can not satisfy the hope that modern people require real multi color pattern.
As is generally known in the typography, colored fine pattern forms by blue or green, pinkish red, yellow, black four color separation version intussusception printings on common paper.Will be in this method of application on glass, no matter, the difficulty that can't overcome is arranged all at present on the technology or on the equipment.But the new situation that colored fine pattern is manufactured has been started in the development of digital technology.Digital-code printer or digit inkjet printer can be made multi color pattern easily on common printing circle matter, comprise photochrome.Yet with common digital technology the firm colored fine pattern of formation on glass be still the difficulty.This is because glass is a kind of surface smoothing, solid inorganic materials.The bonding force of oiliness that Numerical Control Printer is used or water-based paint or dye ink and glass is very poor, and pattern adheres to not firm, sometimes even can not form pattern.Glass surface roughened (as sandblast) and use ink special, though can improve bonding force, degree is limited, and makes the gelatinization of fine pattern film before spray printing, and deleterious lacks practicality.
The glass to photosensitive pattern is arranged that the CN1446703A patent proposes carries out chemical intaglio to be handled, and can form the small intaglio point consistent with the shade of grey, the tone of pattern at glass surface.Facts have proved in these intaglio points and insert printing ink, solidify the back,, can stand daily working conditions so adhere to very firmly because the printing ink point is embedded in the glass surface.
If utilize the digital spray printing technology to form the principle of colored fine pattern, utilize chemically treated technology to form and colored fine pattern color, level, the consistent small intaglio point of tone again at glass surface, with the digital spray printing technology colored ink is sprayed in the corresponding small intaglio point then, it is fully possible forming the colored intaglio fine pattern with practicality at glass surface so.
The present invention is exactly a kind of method of utilizing digital spray printing technology and chemical surface treatment technology to form the colored intaglio fine pattern with photo effect at glass surface of finishing according to above-mentioned imagination.
Two, summary of the invention
Provided by the present inventionly form the method for colored intaglio fine pattern at glass surface, comprise following several steps: (1) makes digital document image to the coloured image original copy with digital recording device.(2) use the raster image processor screening.(3) form the color negative pattern that constitutes by spray printing printing ink at glass surface with number agate spray printing equipment.(4) glass that the surface is had a color negative pattern carries out chemical intaglio and handles.(5) remove residual printing ink, cleaning, the drying of glass surface.(6) use digital spray printing equipment at the colored erect image pattern of former negative-appearing image pattern spray printing position spray printing.
The advantage that forms the method for colored intaglio fine pattern at glass surface provided by the present invention is: (1) can verily duplicate original copy at the color and the shade of grey of glass surface well reproduced colored original image.(2) observe from the spray printing glass back, the bright especially bright-coloured and adhere firmly of pattern color adapts to daily working conditions.(3) be fit to mechanize, mass production.(4) no egative film does not have forme, low processing cost.
Below, according to above-mentioned procedure of processing, content of the present invention is elaborated:
(1) colored original is made digital document image with digital recording device.
Digital recording device refers to scanner, digital camera, computer and corresponding software.Colored original is put into scanner (or take with digital camera) input computer, make amendment, edit and make the iamge description file with image processing software, graphics software, software for composing etc.
Continuously transferring, the original image of shade stepless transition and variation becomes the digital picture that the discrete point by three kinds of colors of red, green, blue constitutes to scanner by photo-electric conversion element, finishes the color separation processing of image.The optical resolution of scanner is high more, and the picture quality of scanning is good more, and the multiple that can amplify original copy simultaneously is big more.The bit depth of scanner and color depth are big more, and image detail that can scan and number of colours are many more.
The digital picture of scanner or digital camera output is reduced into coloured image, to edit and to revise on the indicating meter of computer.The editor of image and modification are undertaken by software.Image processing software (as Photoshop) can require to carry out picture size, color, level, the processing of sharpness etc. according to spray printing.Graphics software (as Freehand) can add processing such as geometricdrawing, input characters, copy editor.Page software for composing (as Pagemaker) can carry out processing such as image mixed character typeset.Image after edit-modify is finalized a text generates iamge description file-PS file by the print driver of supporting PDL (as the Postscript language), files.The concrete operations that original image is made digital document, can be undertaken by the digital plate-making of specialty company usually, can guarantee the quality of the multi color pattern that duplicates like this.
(2) use the raster image processor screening.
As is generally known, printing dot reproduction image, its primary image unit is a bianry image.Therefore before carrying out spray printing, to be converted into the information of image the site of two-value, form the two-value dot matrix image.Common this conversion task is finished by raster image processor (RIP).
Raster image processor also is a kind of software, be installed in computer that Numerical Control Printer links to each other on.Raster image processor is accepted the PS file that sended over by application program, and image is made an explanation and forms the site.
According to the difference that forms the site method, two kinds of am screening and fm screenings are arranged for the mode of image screening.The present invention adopts the am screening mode.The screen density of am screening (line/time) has 60,80,100,120,133,150,175 and 200 etc. eight kinds.Screen frequency is high more, and the half tone image of demonstration is meticulous more, and level is abundant more.But digital spray printing equipment has the restriction in (point/time) of equipment records resolving power.For satisfying the requirement (100 grade) of human eye to the grey scale explanation, for certain spray printing equipment, screen frequency should approach 1/9.95th of equipment records resolving power.For example log resolution be 1200 points/time Numerical Control Printer, screen frequency should be 120 lines/time.Common 120 line screenings can fully manifest the photo effect of image.
That the dot shape of screening has is square, circle and rhombus.Image contrast is big, uses square and circular usually; Image contrast is little, and soft (as character image) uses rhombus.
The color form of PS file is red, green, blue (RGB) form.The color form of Numerical Control Printer is blue or green, pinkish red, yellow, black (CMYK) this common color print format.Raster image processor also has the automatic color separation function, can be automatically color conversion be can spray printing the CMYK form.The moire that produces when eliminating four look site double exposures, site angle yellow, pinkish red, blue or green, black four looks should be taken as 90 °, 15 °, 75 °, 45 °.
Image file after raster image processor is handled will generate a negative-appearing image file opposite with the erect image file by positive and negative image transformation circuit.Positive and negative picture file can directly be imported the amplitude modulation halftone dot image of digital spray printing machine controller spray printing erect image or the amplitude modulation halftone dot image of negative-appearing image in contrast.
(3) form the color negative pattern with digital spray printing equipment at glass surface.
The used digital spray printing equipment of the present invention is flat Numerical Control Printer.Because have only flat Numerical Control Printer just can carry out spray printing at surface of plate glass.
The used spray printing printing ink of the present invention is ultraviolet photo-curing printing ink.This printing ink solidifies under uviolizing rapidly, can and have certain for fastness at formation pattern on glass.Flat Numerical Control Printer has UV irradiation equipment usually.
Under suitable screen angle, blue or green, pinkish red, yellow, black four look sites can form a kind of evenly dense rose-shaped distribution at spray printing behind glass surface.Around each color dot is that barren does not have ink area.This is the situation of erect image spray printing.When the spray printing negative-appearing image, situation is opposite, and originally barren does not have ink area at this moment by the covering of printing ink point, and color dot district originally then becomes barren does not have ink area.This has created condition with regard to carry out these color dot districts of chemical surface treatment etching for next step.Based on this principle, the present invention adopts Numerical Control Printer to form the color negative pattern that is made of light-curable ink at glass surface earlier, and the position that needs is kept the glass original surface hides, and needs is carried out the position of chemical surface treatment and vacates.
For improving the tolerance of light-curable ink in chemical surface treatment, the present invention carries out post bake to the glass that is sprayed with the color negative pattern and handles, promptly be placed on and dry by the fire certain hour in the baking oven, concrete treatment temp will be given the experiment of being equipped with property with the time to different ultraviolet photo-curing printing ink and be determined.
(4) chemical surface treatment.
Chemical surface treatment of the present invention is the glass behind the post bake to be immersed in carry out the intaglio processing in the glass intaglio liquid.
The intaglio point that intaglio handle to form is should the degree of depth darker, and the intaglio face is smooth smooth.The colored erect image pattern that becomes of spray printing like this, from glass back, because the optically focused effect of glass concave point, the color that seems is bright, bright-coloured especially.Because the printing ink point of spray printing system is embedded in the glass surface, so attachment fastness is also big.
The used glass intaglio liquid of the present invention is aqueous hydrofluoric acid containing solution.
(4) striping.
After the chemical surface treatment, the negative-appearing image ink lay is ineffective, should give removal to expose following glass original surface.Ultraviolet photo-curing printing ink usually can be in 5% aqueous sodium hydroxide solution more than 50 ℃ striping.Improve the striping liquid temp and can more effectively improve striping efficient usually than improving striping liquid concentration.
Behind the striping, clean, drying enters next procedure.
(5) the colored erect image pattern of spray printing.
Glass behind the striping is placed on the digital flat spray printing machine platform, and accurately the back, location is at the colored erect image pattern of former negative-appearing image spray printing position spray printing ultraviolet photo-curing printing ink.The erect image ink dot of spray printing is just in time beaten on the small intaglio point that forms through intaglio, because flat Numerical Control Printer promptly provides uviolizing to ink dot in spray printing, so the printing ink in the intaglio point solidifies immediately.So just formed colored intaglio fine pattern with photo effect at glass surface.
In above-mentioned procedure of processing, change or flexible technology and obtain the manufacture method of derivatives, also belong to content of the present invention:
(1), uses above-mentioned operation and form the method for colored intaglio fine pattern at glass surface through frosting or sandblasting.
(2) glass of finishing after above-mentioned operation is handled is put into glass frosting liquid, make no ink area frosting and form and have the method that oyster white is carried on the back the colored intaglio fine pattern at the end.
(3) with Numerical Control Printer at glass surface spray printing ultraviolet photo-curing ink logo as barrier bed, then glass is carried out that chemical frost or intaglio are handled and the method that forms fine pattern.
Four, embodiment
Example one:
Colored original is made the positive and negative picture file (RIP file) of the raster image processing of am screening by the digital plate-making of specialty company.Screen frequency is 120 lines.6 mm thick float glass plate through surface cleaning are put into Inca Eagle digital flat spray printing machine (resolving power 800 * 1200dpi) platforms, RIP negative-appearing image file input spray printing machine controller, adopt SericolImaging Uviget printing ink, at glass surface spray printing color negative pattern.The glass that is sprayed with the color negative pattern, be placed in 140 ℃ the baking oven post bake 20 minutes.After the cooling, 1 minute afterwash in the aqueous hydrofluoric acid containing solution of immersion room temperature.With 70 ℃ 5% aqueous sodium hydroxide solutions spray stripings 5 minutes, wait glass surface printing ink to remove fully after, clean, drying.Dried glass is reentered into Inca Eagle digital flat spray printing machine platform, accurately contraposition.RIP erect image file input spray printing machine controller, with the colored erect image pattern of Uviget printing ink spray printing.The result obtains having the art glass product with original image color, the shade of grey, the on all four colored intaglio fine pattern of tone.
Example two:
At the glass surface of handling through frosting, use the technology identical to process with example one.The result obtains having the art glass product that translucent oyster white is carried on the back the colored intaglio fine pattern at the end.
Example three:
The product that above-mentioned example one obtains, put into commercially available glass frosting liquid frosting and take out after 20 seconds, clean, dry.The result obtains the art glass product of the colored intaglio fine pattern with translucent oyster white back of the body end identical with above-mentioned example two, but the sharpness of pattern is better.

Claims (10)

1, a kind of method at glass and the colored intaglio fine pattern of glasswork (hereinafter to be referred as glass) surface formation.It is characterized in that comprising the following steps: that (1) make digital document image to the coloured image original copy with digital recording device.(2) use the raster image processor screening.(3) form the color negative pattern that constitutes by spray printing printing ink at glass surface with digital spray printing equipment.(4) the his-and-hers watches glass of wearing Chromatic color negative-appearing image pattern carries out chemical intaglio and handles.(5) remove the residual printing ink of glass surface, cleaning, drying.(6) use digital spray printing equipment at the colored erect image pattern of former negative-appearing image pattern spray printing position spray printing.
2, the method for claim 1, wherein digital recording device is a scanner, digital camera, computer and image processing software, graphics software, software for composing, and the print driver of supporting PDL.
3, the method for claim 1 is the amplitude modulation net with the added net of raster image processor wherein.
4, the method for claim 1, wherein digital spray printing equipment is the flat Numerical Control Printer that has ultraviolet radiation device.
5, the method for claim 1, wherein the printing ink of spray printing multi color pattern is ultraviolet photo-curing printing ink.
6, the method for claim 1, wherein removing the residual ink layer is to adopt wet processing.
7, the method for claim 1, wherein chemical intaglio treatment solution is the aqueous solution that contains hydrofluoric acid.
8, the method for claim 1 is characterized in that on the surface processing and obtaining having the translucent oyster white back of the body colored intaglio fine pattern at the end through application present method on glass of frosting or sandblasting.
9, the method for claim 1 is characterized in that the glass of finishing whole manufacturing procedures, puts into commercially available frosted liquid frosting again, and obtains having the translucent oyster white back of the body colored intaglio fine pattern at the end.
10, the method for claim 1 is characterized in that forming the ultraviolet photo-curing ink logo at glass surface makes barrier bed, carries out then that chemical frost or intaglio are handled and the fine pattern that obtains being made of frosting point or intaglio point.
CNB2004100667793A 2004-09-29 2004-09-29 Method for forming colored intaglio fine patterns on the surface of glass and glass products Expired - Fee Related CN100532302C (en)

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CNB2004100667793A CN100532302C (en) 2004-09-29 2004-09-29 Method for forming colored intaglio fine patterns on the surface of glass and glass products

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Application Number Priority Date Filing Date Title
CNB2004100667793A CN100532302C (en) 2004-09-29 2004-09-29 Method for forming colored intaglio fine patterns on the surface of glass and glass products

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CN1609029A true CN1609029A (en) 2005-04-27
CN100532302C CN100532302C (en) 2009-08-26

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102303462A (en) * 2011-08-08 2012-01-04 宁德市聚鑫玻璃有限公司 Image printing method of decorative glass
CN102501698A (en) * 2011-10-08 2012-06-20 南京林业大学 Method for printing and decorating lacquerware surface with ultraviolet curing printing ink (UV ink)
CN102582246A (en) * 2011-12-20 2012-07-18 南京林业大学 Ultraviolet (UV) digital jet printing manufacturing method of plate-type components of floor boards and furniture
CN105922780A (en) * 2016-05-03 2016-09-07 鸿博股份有限公司 Rapid colour printing method and rapid colour printing equipment for smart cards
CN106527776A (en) * 2016-10-26 2017-03-22 郑州恒昊玻璃技术有限公司 Novel glass mouse pad manufacturing method
WO2019076291A1 (en) * 2017-10-18 2019-04-25 Oppo广东移动通信有限公司 Curved glass sheet and method for manufacturing same, and electronic device
CN110757975A (en) * 2019-11-07 2020-02-07 洪泽双友玻璃制品有限公司 Printing process not easy to wipe for glass products
CN110978837A (en) * 2019-12-31 2020-04-10 伯恩创盛技术研发(惠州)有限公司 Pattern generation method for printing glass gradient texture and printing and coloring method

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102303462A (en) * 2011-08-08 2012-01-04 宁德市聚鑫玻璃有限公司 Image printing method of decorative glass
CN102501698A (en) * 2011-10-08 2012-06-20 南京林业大学 Method for printing and decorating lacquerware surface with ultraviolet curing printing ink (UV ink)
CN102582246A (en) * 2011-12-20 2012-07-18 南京林业大学 Ultraviolet (UV) digital jet printing manufacturing method of plate-type components of floor boards and furniture
CN102582246B (en) * 2011-12-20 2014-10-29 南京林业大学 Ultraviolet (UV) digital jet printing manufacturing method of plate-type components of floor boards and furniture
CN105922780A (en) * 2016-05-03 2016-09-07 鸿博股份有限公司 Rapid colour printing method and rapid colour printing equipment for smart cards
CN106527776A (en) * 2016-10-26 2017-03-22 郑州恒昊玻璃技术有限公司 Novel glass mouse pad manufacturing method
WO2019076291A1 (en) * 2017-10-18 2019-04-25 Oppo广东移动通信有限公司 Curved glass sheet and method for manufacturing same, and electronic device
CN110757975A (en) * 2019-11-07 2020-02-07 洪泽双友玻璃制品有限公司 Printing process not easy to wipe for glass products
CN110978837A (en) * 2019-12-31 2020-04-10 伯恩创盛技术研发(惠州)有限公司 Pattern generation method for printing glass gradient texture and printing and coloring method
CN110978837B (en) * 2019-12-31 2021-12-07 伯恩创盛技术研发(惠州)有限公司 Pattern generation method for printing glass gradient texture and printing and coloring method

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