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CN1699613A - High-strength wear-resistant steel and manufacturing method thereof - Google Patents

High-strength wear-resistant steel and manufacturing method thereof Download PDF

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CN1699613A
CN1699613A CN 200510078257 CN200510078257A CN1699613A CN 1699613 A CN1699613 A CN 1699613A CN 200510078257 CN200510078257 CN 200510078257 CN 200510078257 A CN200510078257 A CN 200510078257A CN 1699613 A CN1699613 A CN 1699613A
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CN100449027C (en
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关铁
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Zhejiang Desheng Railway Equipment Co ltd
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Abstract

The present invention relates to a high strength and wear resistant steel and its production process, which is particularly suitable for application in railway intersections. The compositions (wt%) are : C 0.25-0.55, Si 0.6-1.5,Mn 0.8-1.5,Cr 1-1.5,Mo 0.3-0.5, V 0.15-0.25, Ti 0.05-0.15, P<=0.03, S<=0.025. The production flow sheet is as follows: refining by arc furnace - refining by vacuum furnace - ladle refining outside of furnace - casting ingot - primary rolling in billet - forging in form - deforming heat treatment. As compared with the existing technologies, the present steel has the advantages of excellent wear resistance, high strength, high toughness, stable quality and low production cost.

Description

高强度耐磨钢及其制造方法High-strength wear-resistant steel and manufacturing method thereof

技术领域technical field

本发明涉及合金钢,具体说是一种可用于铁路道岔的高强度耐磨钢及其制造方法。The invention relates to alloy steel, in particular to a high-strength wear-resistant steel that can be used for railway turnouts and a manufacturing method thereof.

背景技术Background technique

随着铁路运输向重载和高速发展,对铁路的材料和内在质量提出了更高的要求。现役的高锰钢道岔已越来越难以满足铁路运输重载高速发展的需要,特别是服役条件恶劣的道岔心轨,不仅要有足够的耐磨性,而且要求有足够的强、韧性,同时应具有稳定的内在质量。为此,国内外都在力图研制出能够满足铁路重载高速运输要求的高性能耐磨钢,例如申请号为98112095.4的高速准高速铁路道叉高性能耐磨钢,采用Si-Mn-Cr-Mo-Ni主系合金元素,其耐磨钢的综合性能有所提高。但实验证明,主系合金元素Ni的加入对改善耐磨钢性能的效果不明显,并且由于Ni合金材料价格昂贵,还会导致耐磨钢生产成本的增加。另外,由于耐磨钢制造过程缺少精炼工序,特别是缺少脱除有害气体氢的措施,导致在制件内部有形成氢聚集的可能,从而使产品存在对铁路运输构成极大危害的延迟裂纹现象。With the development of railway transportation towards heavy load and high speed, higher requirements are put forward for the materials and inherent quality of railways. The high-manganese steel turnouts in active service have become more and more difficult to meet the needs of high-speed development of heavy-duty railway transportation, especially for turnout core rails with harsh service conditions, which must not only have sufficient wear resistance, but also require sufficient strength and toughness. Should have a stable inner quality. For this reason, both at home and abroad are trying to develop high-performance wear-resistant steel that can meet the requirements of heavy-duty and high-speed railway transportation. For example, the application number is 98112095.4. Mo-Ni is the main alloying element, and its comprehensive performance of wear-resistant steel has been improved. However, experiments have proved that the addition of the main alloying element Ni has no obvious effect on improving the performance of wear-resistant steel, and because Ni alloy materials are expensive, it will also lead to an increase in the production cost of wear-resistant steel. In addition, due to the lack of refining process in the manufacturing process of wear-resistant steel, especially the lack of measures to remove harmful gas hydrogen, there is a possibility of hydrogen accumulation inside the product, so that the product has delayed cracking that poses a great hazard to railway transportation. .

发明内容Contents of the invention

本发明的目的在于针对上述问题,提供一种强度高,耐磨性好且生产成本低的高强度耐磨钢。该高强度耐磨钢特别适用于铁路道岔。The object of the present invention is to solve the above problems and provide a high-strength wear-resistant steel with high strength, good wear resistance and low production cost. The high-strength wear-resistant steel is especially suitable for railway turnouts.

本发明的目的还在于提供一种可有效保证本高强度耐磨钢具有稳定的内在质量的制造方法。The object of the present invention is also to provide a manufacturing method that can effectively ensure the stable internal quality of the high-strength wear-resistant steel.

实现本发明目的的技术方案是:一种高强度耐磨钢,其化学成份(重量%)为:The technical solution for realizing the object of the present invention is: a kind of high-strength wear-resistant steel, its chemical composition (weight %) is:

C 0.25-0.55  Si 0.6-1.5    Mn 0.8-1.5  Cr 1-1.5  Mo 0.3-0.5C 0.25-0.55 Si 0.6-1.5 Mn 0.8-1.5 Cr 1-1.5 Mo 0.3-0.5

V 0.15-0.25  Ti 0.05-0.15  P≤0.03     S≤0.025V 0.15-0.25 Ti 0.05-0.15 P≤0.03 S≤0.025

其余为Fe和不可避免的杂质。The rest is Fe and unavoidable impurities.

本发明高强度耐磨钢优选的化学成份(重量%)为:The preferred chemical composition (% by weight) of the high-strength wear-resistant steel of the present invention is:

(1)C 0.25-0.35  Si 0.6-0.9  Mn 0.8-1.2  Cr 1-1.2  Mo 0.3-0.4(1) C 0.25-0.35 Si 0.6-0.9 Mn 0.8-1.2 Cr 1-1.2 Mo 0.3-0.4

   V 0.15-0.2   Ti 0.05-0.09  P≤0.03     S≤0.025V 0.15-0.2 Ti 0.05-0.09 P≤0.03 S≤0.025

其余为Fe和不可避免的杂质。The rest is Fe and unavoidable impurities.

(2)C 0.28-0.4   Si 0.8-1.2    Mn 1.1-1.5  Cr 1.2-1.5  Mo 0.4-0.5(2)C 0.28-0.4 Si 0.8-1.2 Mn 1.1-1.5 Cr 1.2-1.5 Mo 0.4-0.5

   V 0.18-0.25  Ti 0.06-0.1   P≤0.03     S≤0.025V 0.18-0.25 Ti 0.06-0.1 P≤0.03 S≤0.025

其余为Fe和不可避免的杂质。The rest is Fe and unavoidable impurities.

(3)C 0.3-0.48   Si 0.6-0.8    Mn 0.9-1.2  Cr 1.1-1.3  Mo 0.3-0.4(3) C 0.3-0.48 Si 0.6-0.8 Mn 0.9-1.2 Cr 1.1-1.3 Mo 0.3-0.4

   V 0.18-0.24  Ti 0.08-0.12  P≤0.03     S≤0.025V 0.18-0.24 Ti 0.08-0.12 P≤0.03 S≤0.025

其余为Fe和不可避免的杂质。The rest is Fe and unavoidable impurities.

本发明高强度耐磨钢的制造方法是采用下述工艺流程:The manufacture method of high-strength wear-resistant steel of the present invention is to adopt following technological process:

电弧炉冶炼→真空炉精炼→炉外钢包精炼→铸锭→初轧成坯→锻造成型→形变热处理。Electric arc furnace smelting→vacuum furnace refining→ladle refining outside the furnace→ingot casting→brief rolling→forging forming→deformation heat treatment.

本发明高强度耐磨钢的含碳量控制在0.25-0.55之间,以保证材料具有优良的拉伸、扭转、弯曲性能,得到良好的强韧性材料。合金元素Si、Mn、Cr、Mo、V、Ti的加入及合适配比的选择能有效抑制奥氏体的再结晶,延长形变后淬火前的停留时间,并细化晶粒,提高材料的强度和塑韧性。The carbon content of the high-strength wear-resistant steel of the present invention is controlled between 0.25-0.55 to ensure that the material has excellent tensile, torsion, and bending properties, and obtains a good toughness material. The addition of alloying elements Si, Mn, Cr, Mo, V, Ti and the selection of a suitable ratio can effectively inhibit the recrystallization of austenite, prolong the residence time before quenching after deformation, and refine the grains to improve the strength of the material and plasticity.

其高强度耐磨钢制造工艺流程中各工序的作用为:The role of each process in the high-strength wear-resistant steel manufacturing process is as follows:

电弧炉冶炼:控制调整化学成份,通过造渣过程初步净化钢水。Electric arc furnace smelting: control and adjust the chemical composition, and initially purify the molten steel through the slagging process.

真空炉精炼:将电弧炉冶炼后成份合格的钢水倒入真空炉中,进行抽气精炼,使钢水中的有害气体充分脱除。Refining in vacuum furnace: Pour the molten steel with qualified composition after smelting in electric arc furnace into the vacuum furnace for extraction and refining to fully remove the harmful gas in the molten steel.

炉外钢包精炼:将真空抽气后的钢水倒入钢包之后,再进行钢包吹氢精炼,使钢中的各种有害杂质充分上浮,得到最终的净化钢水。Out-of-furnace ladle refining: Pour the vacuum pumped molten steel into the ladle, and then carry out hydrogen blowing refining on the ladle to fully float various harmful impurities in the steel to obtain the final purified molten steel.

铸锭:将最终净化的钢水浇注成锭或连铸坯,为轧制做好准备。Ingot casting: The final purified molten steel is poured into ingots or continuous casting slabs, ready for rolling.

初轧成坯:将钢锭或连铸坯轧制成条状钢坯,为锻造做好准备。Blooming: The rolling of steel ingots or continuous casting slabs into strips in preparation for forging.

锻造成型:将初轧钢坯下料,加热锻造成型。Forging and forming: blanking the blooming steel billet, heating and forging and forming.

形变热处理:将锻后成型的锻件利用其余热进行控制冷却,得到预期的组织和性能。Deformation heat treatment: the forging formed after forging is controlled and cooled by the remaining heat to obtain the expected structure and performance.

本发明相比现有技术,具有如下优点:Compared with the prior art, the present invention has the following advantages:

1、具有优良的耐磨性能和高强度、高韧性指标。1. It has excellent wear resistance, high strength and high toughness indicators.

2、具有稳定的内在质量。2. It has stable internal quality.

3、生产成本低。3. Low production cost.

具体实施方式Detailed ways

主要原材料准备:Preparation of main raw materials:

A3废钢,无严重锈蚀,A3 steel scrap, no serious corrosion,

高碳铬铁FeCr67C6.0High carbon ferrochromium FeCr67C6.0

中碳锰铁FeMn80C1.5Medium carbon ferromanganese FeMn80C1.5

硅铁FeSi75-AFerrosilicon FeSi75-A

钼铁FeMo60-AFerromolybdenum FeMo60-A

钒铁FeV75-AFerrovanadium FeV75-A

钛铁FeTi30-AFerro-Titanium FeTi30-A

按电弧炉冶炼→真空炉精炼→炉外钢包精炼→铸锭→初轧成坯→锻造成型→形变热处理工艺过程生产铁路道岔心轨。According to the process of electric arc furnace smelting→vacuum furnace refining→ladle refining outside the furnace→ingot casting→brief rolling→forging molding→deformation heat treatment process, the railway turnout center rail is produced.

实施例一Embodiment one

化学成份及含量按下列比例配比(重量%):Chemical composition and content are proportioned according to the following ratio (weight %):

C 0.27、Si 0.8、Mn 1.0、Cr 1.1、Mo 0.35、V 0.17、Ti 0.09、P≤0.03、S≤0.025。C 0.27, Si 0.8, Mn 1.0, Cr 1.1, Mo 0.35, V 0.17, Ti 0.09, P≤0.03, S≤0.025.

形变油淬后,于480回火,得到回火索氏体组织。After deformation oil quenching, temper at 480 to obtain tempered sorbite structure.

机械性能如下:The mechanical properties are as follows:

强度σb=1410Mpa,硬度HRC=43,冲击韧性αku=51J/cm2,延伸率δ5=10%。Strength σ b = 1410Mpa, hardness HRC = 43, impact toughness α ku = 51J/cm 2 , elongation δ 5 = 10%.

实施例二Embodiment two

化学成份及含量按下列比例配比(重量%):Chemical composition and content are proportioned according to the following ratio (weight %):

C 0.36、Si 1.1、Mn 1.2、Cr 1.2、Mo 0.4、V 0.18、Ti 0.08、P≤0.03、S≤0.025。C 0.36, Si 1.1, Mn 1.2, Cr 1.2, Mo 0.4, V 0.18, Ti 0.08, P≤0.03, S≤0.025.

形变正火后,于380℃回火,得到贝氏体+残余奥氏体组织。After deformation normalizing, temper at 380°C to obtain bainite + retained austenite structure.

机械性能如下:The mechanical properties are as follows:

强度σb=1420Mpa,硬度HRC=42,冲击韧性αku=65J/cm2,延伸率δ5=9.5%。Strength σ b = 1420Mpa, hardness HRC = 42, impact toughness α ku = 65J/cm 2 , elongation δ 5 = 9.5%.

实施例三Embodiment Three

化学成份及含量按下列比例配比(重量%):Chemical composition and content are proportioned according to the following ratio (weight %):

C 0.45、Si 0.7、Mn 0.8、Cr 1.15、Mo 0.36、V 0.19、Ti 0.10、P≤0.03、S≤0.025。C 0.45, Si 0.7, Mn 0.8, Cr 1.15, Mo 0.36, V 0.19, Ti 0.10, P≤0.03, S≤0.025.

形变油淬后,于520℃回火,得到回火索氏体组织。After deformation oil quenching, temper at 520°C to obtain tempered sorbite structure.

机械性能如下:The mechanical properties are as follows:

强度σb=1620Mpa,硬度HRC=48,冲击韧性αku=50J/cm2,延伸率δ5=9%。Strength σ b = 1620Mpa, hardness HRC = 48, impact toughness α ku = 50J/cm 2 , elongation δ 5 = 9%.

Claims (5)

1, a kind of high-strength abrasion-proof steel is characterized in that its Chemical Composition (weight %) is as follows:
C?0.25-0.55 Si?0.6-1.5 Mn?0.8-1.5 Cr?1-1.5 Mo?0.3-0.5
V?0.15-0.25 Ti?0.05-0.15 P≤0.03 S≤0.025
All the other are Fe and unavoidable impurities.
2, high-strength abrasion-proof steel according to claim 1 is characterized in that its Chemical Composition (weight %) is as follows:
C?0.25-0.35 Si?0.6-0.9 Mn?0.8-1.2 Cr?1-1.2 Mo?0.3-0.4
V?0.15-0.2 Ti?0.05-0.09 P≤0.03 S≤0.025
All the other are Fe and unavoidable impurities.
3, high-strength abrasion-proof steel according to claim 1 is characterized in that its Chemical Composition (weight %) is as follows:
C?0.28-0.4 Si?0.8-1.2 Mn?1.1-1.5 Cr?1.2-1.5 Mo?0.4-0.5
V?0.18-0.25 Ti?0.06-0.1 P≤0.03 S≤0.025
All the other are Fe and unavoidable impurities.
4, high-strength abrasion-proof steel according to claim 1 is characterized in that its Chemical Composition (weight %) is as follows:
C?0.3-0.48 Si?0.6-0.8 Mn?0.9-1.2 Cr?1.1-1.3 Mo?0.3-0.4
V?0.18-0.24 Ti?0.08-0.12 P≤0.03 S≤0.025
All the other are Fe and unavoidable impurities.
5,, it is characterized in that manufacturing process flow is according to the manufacture method of claim 1,2,3 or 4 described high-strength abrasion-proof steels:
Outer ladle refining → the ingot casting of electric arc furnace smelting → vacuum oven refining → stove → just roll into base → forging molding → thermomechanical treatment.
CNB200510078257XA 2005-06-09 2005-06-09 High-strength wear-resistant steel and manufacturing method thereof Expired - Fee Related CN100449027C (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100434538C (en) * 2006-09-01 2008-11-19 西安交通大学 A method for purification and alloying of wear-resistant steel melt
CN101775550B (en) * 2009-01-14 2012-05-30 常州朗锐活塞有限公司 Piston head material for combined piston of large-bore diesel engine
CN103252449A (en) * 2013-05-08 2013-08-21 青岛钰鑫车辆工程有限公司 Production method of composite material stirring wing
CN106566982A (en) * 2016-10-26 2017-04-19 刘海华 Preparing method for air cooling steel throat pipe liner plate
CN113774986A (en) * 2021-08-11 2021-12-10 宁波吉威熔模铸造有限公司 Impact-wear-resistant excavator bucket tooth and production process thereof

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CN1032198A (en) * 1988-10-19 1989-04-05 乐山冶金机械轧棍厂 The vanadium and titanium containing low-manganese wear resisting steel
CN1025506C (en) * 1991-06-24 1994-07-20 河北工学院 High-toughness antiwear lining plate of big ball mill and making technology thereof
AU663023B2 (en) * 1993-02-26 1995-09-21 Nippon Steel Corporation Process for manufacturing high-strength bainitic steel rails with excellent rolling-contact fatigue resistance
CN1140205A (en) * 1995-03-28 1997-01-15 王宇辉 Medium-carbon medium-alloy wear-resisting steel
CN1034678C (en) * 1995-03-28 1997-04-23 王宇辉 Low-alloy wear-resisting steel
CN1182142A (en) * 1996-11-07 1998-05-20 鞍山钢铁集团公司 A wear-resistant cast steel
CN1061385C (en) * 1998-06-19 2001-01-31 四川工业学院 High-performance abrasion-resistant steel for switch tongue of high-speed or quasi high-speed railway
CN1128245C (en) * 2001-10-22 2003-11-19 刘承刚 High-strength alloyed cast steel with high resistance to wear and impact and its preparing process

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100434538C (en) * 2006-09-01 2008-11-19 西安交通大学 A method for purification and alloying of wear-resistant steel melt
CN101775550B (en) * 2009-01-14 2012-05-30 常州朗锐活塞有限公司 Piston head material for combined piston of large-bore diesel engine
CN103252449A (en) * 2013-05-08 2013-08-21 青岛钰鑫车辆工程有限公司 Production method of composite material stirring wing
CN103252449B (en) * 2013-05-08 2015-12-02 青岛钰鑫车辆工程有限公司 Composite stirs wing production method
CN106566982A (en) * 2016-10-26 2017-04-19 刘海华 Preparing method for air cooling steel throat pipe liner plate
CN113774986A (en) * 2021-08-11 2021-12-10 宁波吉威熔模铸造有限公司 Impact-wear-resistant excavator bucket tooth and production process thereof

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