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CN1688733A - Steel material for mechanical structure excellent in suitability for rolling, quenching crack resistance, and torsional property and drive shaft - Google Patents

Steel material for mechanical structure excellent in suitability for rolling, quenching crack resistance, and torsional property and drive shaft Download PDF

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CN1688733A
CN1688733A CN02829773.3A CN02829773A CN1688733A CN 1688733 A CN1688733 A CN 1688733A CN 02829773 A CN02829773 A CN 02829773A CN 1688733 A CN1688733 A CN 1688733A
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CN1307319C (en
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大森靖浩
松崎明博
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JFE Engineering Corp
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NKK Corp
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium

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  • Shafts, Cranks, Connecting Bars, And Related Bearings (AREA)
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Abstract

The present invention relates to a steel used by mechanical structures and a transmission shaft. Represented by mass percent, the steel contains C with a mass percent of more than 0.35 percent and less than 0.5 percent, Si with a mass percent of less than 0.15 percent, Mn with a mass percent of more than 0.2 percent and less than 1.1 percent, P with a mass percent of less than 0.02 percent, S with a mass percent of more than 0.005 percent and less than 0.035 percent, Cr with a mass percent of more than 0.1 percent and less than 0.2 percent, Mo with a mass percent of more than 0.05 percent and less than 0.5 percent, Ti with a mass percent of more than 0.01 percent and less than 0.05 percent, Al with a mass percent of more than 0.01 percent and less than 0.05 percent, N with a mass percent of less than 0.01 percent, B with a mass percent of more than 0.0005 percent and less than 0.005 percent, Cu with a mass percent of more than 0.06 percent and less than 0.25 percent and Ni with a mass percent of more than 0.05 percent and less than 0.2 percent, the rest part is composed of Fe and inavoidable impurities, and moreover, the LD value represented by the formula (1) is less than 120. LD equal to 0.569 multiplied by (7.98 multiplied by (C)<1 / 2> multiplied by (1 added by 4.1mn)(1 added by 2.83P)(1 minus 0.62S)(1 added by 0.64Si)(1 added by 2.33Cr)(1 added by 0.52Ni)(1 added by 3.14Mo)(1 added by 0.27Cu)(1 added by 1.5 (0.9 minus C))) added by 52.6 minus (1).

Description

滚轧成形性、耐淬裂性及扭转特性优 异的机械结构用钢材以及传动轴Steel materials for machine structures and propeller shafts with excellent roll formability, quench cracking resistance, and torsional properties

技术领域technical field

本发明涉及一种机械结构用钢材。特别涉及滚轧成形性、耐淬裂性及扭转特性优异的机械结构用钢材。提供使用电炉材料代替高炉材料制造的机械结构用钢材,该钢材即使混入Cu和Ni等夹杂元素,上述诸特性也不劣化。The invention relates to a steel material for mechanical structure. In particular, it relates to a steel material for machine structural use having excellent roll formability, quench cracking resistance, and torsional properties. To provide steel materials for machine structures manufactured using electric furnace materials instead of blast furnace materials, which do not deteriorate the above-mentioned properties even if inclusion elements such as Cu and Ni are mixed into the steel materials.

背景技术Background technique

对于汽车用传动轴和等速万向节等机械结构用构件要求有所需的扭转强度。为了确保扭转强度,过去一般地将热轧棒钢热锻,必要的场合实施正火处理,通过切削、冷锻等加工成所规定的形状之后,实施高频淬火、回火。The required torsional strength is required for mechanical structural members such as automotive propeller shafts and constant velocity joints. In order to ensure torsional strength, in the past, hot-rolled bar steel was generally hot-forged, normalized when necessary, processed into a predetermined shape by cutting, cold forging, etc., and then subjected to induction hardening and tempering.

近年来为了保护环境,以改善汽车的油耗为目的谋求着车体的重量减轻。为了减轻汽车部件的重量,希望提高汽车用构件的扭转强度。另一方面,在汽车部件的制造工序中,要求钢材的被切削性、耐淬裂性。In recent years, in order to protect the environment, the weight of the vehicle body has been reduced for the purpose of improving the fuel consumption of the vehicle. In order to reduce the weight of automobile parts, it is desired to increase the torsional strength of automobile members. On the other hand, machinability and quench cracking resistance of steel materials are required in the manufacturing process of automobile parts.

为了提高扭转强度,考虑通过高频淬火来增加淬火硬度和淬火深度。可是,要增加淬火硬度和深度只有改变高频淬火条件、或增加钢材的合金元素量,制造成本均增加。为了能够同时满足汽车用构件的扭转强度和被切削性、耐淬裂性,例如如专利文献1所示,提出了限定了合金元素量的技术。In order to improve the torsional strength, it is considered to increase the quenching hardness and quenching depth by induction quenching. However, to increase the quenching hardness and depth, only changing the high-frequency quenching conditions or increasing the amount of alloying elements in the steel will increase the manufacturing cost. In order to simultaneously satisfy the torsional strength, machinability, and quench cracking resistance of automotive components, for example, as shown in Patent Document 1, a technique of limiting the amount of alloy elements has been proposed.

可是,只采用上述技术限定化学成分,能同时满足被切削性、耐淬裂性和扭转特性的组成范围极为狭窄,存在这一问题。另外,还有品质不稳定的问题。However, there is a problem that the chemical composition is limited only by the above-mentioned technology, and the composition range that satisfies machinability, quench cracking resistance, and torsion characteristics at the same time is extremely narrow. In addition, there is a problem of unstable quality.

于是,作为解决上述问题的方案,本发明人通过在调整钢材的成分组成的同时,控制钢组织,例如如专利文献2所示,率先提出了被切削性、耐淬裂性及扭转特性优异的机械结构用钢材。Therefore, as a solution to the above-mentioned problems, the present inventors controlled the steel structure while adjusting the composition of the steel material. Steel for mechanical structures.

专利文献1:特开平4-218641号公报(权利要求书)Patent Document 1: JP-A-4-218641 (Claims)

专利文献2:专利第3288563号公报(权利要求书)Patent Document 2: Patent No. 3288563 (Claims)

可是,当使用电炉制造上述专利文献2所公开的机械结构用钢材时,得不到所要求的特性,特别判明滚轧成形性降低显著。与高炉材料比较,用电炉冶炼出的钢材中混入Cu和Ni等夹杂元素不能避免。认为该夹杂元素使滚轧成形性恶化。However, when the steel material for machine structural use disclosed in the aforementioned Patent Document 2 is produced using an electric furnace, desired properties cannot be obtained, and it has been found that the roll formability is significantly lowered. Compared with blast furnace materials, it is unavoidable to mix Cu and Ni and other inclusion elements into the steel smelted by electric furnace. It is considered that this inclusion element deteriorates roll formability.

本发明以解决上述问题为目的。即,目的是提供即使代替高炉材料使用电炉材料制造,也有效果地防止滚轧成形性劣化,同时具有优异的耐淬裂性及扭转特性的机械结构用钢材。另外,提供使用该钢材形成的传动轴。The present invention aims to solve the above problems. That is, the object is to provide a steel material for machine structural use that effectively prevents deterioration of roll formability even if it is manufactured using an electric furnace material instead of a blast furnace material, and has excellent quench cracking resistance and torsional characteristics. In addition, a propeller shaft formed using the steel material is provided.

发明内容Contents of the invention

本发明人为达到上述目的而反复刻苦研究的结果得到下述见解。The inventors of the present invention have obtained the following findings as a result of painstaking studies to achieve the above objects.

(1)  为了减轻夹杂元素的坏影响,增加Cr量有效;(1) In order to reduce the bad influence of inclusion elements, it is effective to increase the amount of Cr;

(2)  可是,Cr量的增大招致以滚轧成形性为首的扭转特性及被切削性降低;(2) However, the increase in the amount of Cr leads to a decrease in torsional characteristics and machinability including roll formability;

(3)  与Cr量的增大相伴的扭转特性及被切削性的降低,通过增加Si量、且降低Mn量而被消除;(3) The reduction in torsional characteristics and machinability associated with the increase in the amount of Cr is eliminated by increasing the amount of Si and reducing the amount of Mn;

(4)  滚轧成形性的降低,通过将作为以淬透性来决定的硬度和组织的指标的LD值控制在所规定的范围而被消除;(4) The reduction of roll formability is eliminated by controlling the LD value, which is an index of hardness and structure determined by hardenability, within the specified range;

本发明立足于上述知识见解而完成。发明的特定内容如下。The present invention has been accomplished based on the above knowledge and findings. The specific contents of the invention are as follows.

1.一种滚轧成形性、耐淬裂性及扭转特性优异的机械结构用钢材,其特征在于,为下述组成:用质量%表示,在用下述式(1)表示的LD值满足120以下的范围内含有1. A steel material for machine structures excellent in roll formability, quench cracking resistance and torsional properties, characterized in that it is the following composition: expressed in mass%, when the LD value represented by the following formula (1) satisfies The range below 120 contains

C:0.35%以上、0.50%以下、C: 0.35% or more, 0.50% or less,

Si:0.15%以下、Si: 0.15% or less,

Mn:0.2%以上、1.1%以下、Mn: 0.2% or more, 1.1% or less,

P:0.020%以下、P: less than 0.020%,

S:0.005%以上、0.035%以下、S: 0.005% or more, 0.035% or less,

Cr:超过0.1%、0.2%以下、Cr: more than 0.1%, less than 0.2%,

Mo:0.05%以上、0.5%以下、Mo: 0.05% or more, 0.5% or less,

Ti:0.01%以上、0.05%以下、Ti: 0.01% or more, 0.05% or less,

Al:0.01%以上、0.05%以下、Al: 0.01% or more, 0.05% or less,

N:0.01%以下、N: 0.01% or less,

B:0.0005%以上、0.0050%以下、B: 0.0005% or more, 0.0050% or less,

Cu:0.06%以上、0.25%以下及Cu: 0.06% or more, 0.25% or less and

Ni:0.05%以上、0.2%以下,Ni: 0.05% or more and 0.2% or less,

剩余部分为Fe及不可避免的杂质,The remainder is Fe and unavoidable impurities,

LD=0.569×{7.98×(C)1/2×(1+4.1Mn)(1+2.83P)(1-0.62S)(1+0.64Si)LD=0.569×{7.98×(C) 1/2 ×(1+4.1Mn)(1+2.83P)(1-0.62S)(1+0.64Si)

    (1+2.33Cr)(1+0.52Ni)(1+3.14Mo)(1+0.27Cu)(1+1.5(0.9-C))}+52.6(1+2.33Cr)(1+0.52Ni)(1+3.14Mo)(1+0.27Cu)(1+1.5(0.9-C))}+52.6

                                                          ---(1) ---(1)

其中,式中的C、Mn、P、S、Si、Cr、Ni、Mo、Cu意指各个元素的含量(质量%)。However, C, Mn, P, S, Si, Cr, Ni, Mo, and Cu in the formula mean the content (mass %) of each element.

2.根据上述第1项所述的滚轧成形性、耐淬裂性及扭转特性优异的机械结构用钢材,其特征在于,钢材为下述组成:用质量%表示,还进一步含有2. The steel material for machine structure excellent in roll formability, quench cracking resistance, and torsional properties according to the above item 1, characterized in that the steel material has the following composition: expressed in mass %, and further contains

V:0.01%以上、0.30%以下以及V: 0.01% or more, 0.30% or less and

Nb:0.005%以上、0.050%以下。Nb: 0.005% or more and 0.050% or less.

3.一种传动轴,其特征在于,采用上述第1项或第2项所述的机械结构用钢材形成,进行高频淬火、回火从而设置了固化层。3. A transmission shaft, characterized in that it is formed by using the steel material for mechanical structure as described in the above item 1 or 2, and is subjected to high-frequency quenching and tempering to provide a hardened layer.

附图的简单说明A brief description of the drawings

图1是表示LD值对滚轧成形性的影响的图。Fig. 1 is a graph showing the effect of LD value on roll formability.

图2是通过静态强度试验测定传动轴的静态强度的结果。Fig. 2 is the result of measuring the static strength of the propeller shaft through the static strength test.

图3是通过疲劳强度试验测定发明例的传动轴和比较例的传动轴的疲劳强度的结果。FIG. 3 shows the results of measuring the fatigue strength of the propeller shaft of the inventive example and the propeller shaft of the comparative example by a fatigue strength test.

具体实施方式Detailed ways

以下具体说明本发明。说明在本发明中将钢材的成分组成限定在上述的范围的理由。关于成分的“%”表示只要不特别声明就意指质量%。The present invention will be specifically described below. The reason why the component composition of the steel material is limited to the above-mentioned range in the present invention will be described. "%" about a component means mass % unless otherwise stated.

C:0.35%以上、0.50%以下C: 0.35% or more and 0.50% or less

C是对高频淬透性的影响最大的元素,是在提高淬火固化层的硬度和深度、确保在高频淬火回火后扭转强度为1400MPa以上的方面有用的元素。可是,含量不足0.35%时其添加效果不足,而超过0.50%时招致被切削性及耐淬裂性降低,因此将C量限定在0.35%以上、0.50%以下的范围。C is an element having the greatest influence on induction hardenability, and is an element useful in increasing the hardness and depth of a quenched solidified layer and securing a torsional strength of 1400 MPa or more after induction quenching and tempering. However, if the content is less than 0.35%, the addition effect is insufficient, and if it exceeds 0.50%, the machinability and quench cracking resistance will be reduced, so the amount of C is limited to the range of 0.35% to 0.50%.

Si:0.15%以下Si: 0.15% or less

Si除了作为脱氧元素而起作用外,还是通过固溶在铁素体中强化钢来提高扭转强度的元素,优选添加量超过0.05%。可是,当Si量超过0.15%时,使被切削性显著劣化,因此限定在0.15%以下的范围。In addition to functioning as a deoxidizing element, Si is also an element that strengthens steel by solid solution in ferrite to increase the torsional strength, and the added amount is preferably more than 0.05%. However, if the amount of Si exceeds 0.15%, the machinability is remarkably deteriorated, so it is limited to a range of 0.15% or less.

Mn:0.2%以上、1.1%以下Mn: 0.2% or more and 1.1% or less

Mn是提高淬透性、通过加深高频淬火时的硬度深度而有助于提高扭转强度的有用元素。可是,当含量不足0.2%时其添加效果不足,而超过1.1%时,不仅滚轧成形性劣化,也使被切削性和扭转强度劣化,因此将Mn量限定在0.2%以上、1.1%以下的范围。优选为0.2%以上、0.8%以下的范围。Mn is an element useful for improving hardenability and increasing the depth of hardness during induction hardening, thereby contributing to the improvement of torsional strength. However, when the content is less than 0.2%, the effect of adding is insufficient, and when it exceeds 1.1%, not only the roll formability but also the machinability and torsional strength are deteriorated, so the amount of Mn is limited to 0.2% or more and 1.1% or less. scope. Preferably, it is the range of 0.2% or more and 0.8% or less.

P:0.020%以下P: 0.020% or less

P在淬火时偏析于奥氏体晶界,助长淬火裂纹发生,因此优选极力降低,从该观点出发,规定抑制在0.020%以下。P segregates at the austenite grain boundaries during quenching and promotes the occurrence of quenching cracks, so it is preferable to reduce it as much as possible, and from this point of view, it is prescribed to be suppressed to 0.020% or less.

S:0.005%以上、0.035%以下S: 0.005% or more and 0.035% or less

S具有在钢中形成MnS并提高被切削性的效果,因此规定含有0.005%以上。可是,MnS易成为龟裂的起点,招致强度、韧性降低,因此S量的上限限定在0.035%。优选为0.010%以上、0.035%以下的范围。S has the effect of forming MnS in steel and improving machinability, so it is specified to be contained in an amount of 0.005% or more. However, MnS tends to be the starting point of cracks, leading to a decrease in strength and toughness, so the upper limit of the amount of S is limited to 0.035%. Preferably, it is the range of 0.010% or more and 0.035% or less.

Cr:超过0.1%、0.2%以下Cr: more than 0.1%, less than 0.2%

Cr在本发明中是特别重要的元素,通过含有Cr,能够利于消除引起滚轧成形性和扭转特性、被切削性等降低的Cu和Ni等夹杂元素的坏影响。可是,Cr量为0.1%以下时,缺乏其添加效果,而超过0.2%时,滚轧成形性、被切削性及扭转强度降低,因此规定在超过0.1%、0.2%以下的范围含有Cr。Cr is an especially important element in the present invention, and containing Cr can advantageously eliminate the adverse effects of inclusion elements such as Cu and Ni that cause reductions in roll formability, torsional properties, machinability, and the like. However, when the amount of Cr is 0.1% or less, the effect of the addition is lacking, and when it exceeds 0.2%, the roll formability, machinability, and torsional strength decrease, so Cr is specified to be contained in the range of more than 0.1% and 0.2% or less.

Mo:0.05%以上、0.5%以下Mo: 0.05% to 0.5%

Mo不仅对提高淬透性有用,还促进贝氏体生成,有提高被切削性的作用。为此,需要含有0.05%以上,但含量超过0.5%时,招致被切削性劣化,因此将Mo量限定在0.05%以上、0.5%以下的范围。优选是0.1%以上、0.5%以下的范围。Mo is not only useful for improving hardenability, but also promotes the formation of bainite, and has the effect of improving machinability. For this reason, it is necessary to contain 0.05% or more, but if the content exceeds 0.5%, the machinability will be deteriorated, so the amount of Mo is limited to the range of 0.05% or more and 0.5% or less. Preferably, it is the range of 0.1% or more and 0.5% or less.

Ti:0.01%以上、0.05%以下Ti: 0.01% to 0.05%

Ti与N结合形成氮化物,微细化高温加热时的奥氏体晶粒。是为确保对提高淬透性有用的固溶B而必需的元素。为此,需要含有0.01%以上,但超过0.05%时损害韧性,因此将Ti量限定在0.01%以上、0.05%以下的范围。Ti combines with N to form nitrides, and refines austenite grains during high-temperature heating. It is an element necessary to secure solid solution B useful for improving hardenability. For this reason, it is necessary to contain 0.01% or more, but when it exceeds 0.05%, the toughness is impaired, so the amount of Ti is limited to the range of 0.01% or more and 0.05% or less.

Al:0.01%以上、0.05%以下Al: 0.01% or more and 0.05% or less

Al作为脱氧剂而有用,因此需要至少含有0.01%,但超过0.05%时,生成粗大的氧化铝,它成为疲劳破坏的起点,降低疲劳强度,因此将Al量限定在0.01%以上、0.05%以下的范围。Al is useful as a deoxidizer, so it needs to contain at least 0.01%, but if it exceeds 0.05%, coarse alumina is formed, which becomes the starting point of fatigue fracture and reduces the fatigue strength, so the amount of Al is limited to 0.01% or more and 0.05% or less range.

N:0.01%以下N: 0.01% or less

N是通过与Al或Ti结合形成氮化物,细化高温加热时的奥氏体晶粒,从而提高疲劳强度的有用元素。可是含量超过0.01%时,氮化物粗化,反倒使疲劳强度劣化。另外,过剩的N添加形成BN,也有使对淬透性有效的固溶B量降低的不利方面。因此N量限定在0.01%以下。N is an element useful for improving fatigue strength by combining with Al or Ti to form nitrides, refining austenite grains during high-temperature heating. However, if the content exceeds 0.01%, the nitrides will coarsen, conversely deteriorating the fatigue strength. In addition, excessive addition of N forms BN, which also has the disadvantage of reducing the amount of solid-solution B effective for hardenability. Therefore, the amount of N is limited to 0.01% or less.

B:0.0005%以上、0.0050%以下B: More than 0.0005% and less than 0.0050%

B提高淬透性,提高高频淬火时的淬火深度,由此有提高扭转强度的效果。为此,需要添加0.0005%以上,但超过0.0050%时招致韧性劣化,因此将B限定在0.0005%以上、0.0050%以下的范围。B improves the hardenability, increases the quenching depth during induction hardening, and thereby has the effect of increasing the torsional strength. For this reason, it is necessary to add 0.0005% or more, but if it exceeds 0.0050%, the toughness will deteriorate, so B is limited to the range of 0.0005% or more and 0.0050% or less.

Cu:0.06%以上、0.25%以下Cu: 0.06% or more and 0.25% or less

Cu是作为夹杂元素而不可避免地混入的元素。当含量超过0.25%时,招致滚轧成形性等劣化,因此定为0.25%以下。而降低至小于0.06%时,制造成本增加,因此规定为0.06%以上。Cu is an element that is inevitably mixed as an inclusion element. If the content exceeds 0.25%, the roll formability and the like will deteriorate, so it is made 0.25% or less. On the other hand, if it is reduced to less than 0.06%, the production cost will increase, so it is made 0.06% or more.

Ni:0.05%以上、0.2%以下Ni: 0.05% or more and 0.2% or less

Ni是作为夹杂元素而不可避免地混入的元素。当含量超过0.2%时,招致滚轧成形性等劣化,因此定为0.2%以下。而降低至小于0.05%时,制造成本增加,因此规定为0.05%以上。Ni is an element that is inevitably mixed as an inclusion element. If the content exceeds 0.2%, the roll formability and the like will deteriorate, so it is made 0.2% or less. On the other hand, if it is reduced to less than 0.05%, the production cost will increase, so it is made 0.05% or more.

以上说明了基本成分,但本发明除此之外还可适宜当有以下叙述的元素。The basic components have been described above, but the present invention may suitably contain elements described below in addition to these.

V:0.01%以上、0.30%以下,Nb:0.005%以上、0.050%以下V: 0.01% or more and 0.30% or less, Nb: 0.005% or more and 0.050% or less

V和Nb均形成碳氮化物,使奥氏体晶粒微细化,有效地有助于提高强度。可是,当V、Nb量分别为小于0.01%、小于0.005%时,缺乏其添加效果,而分别为超过0.30%、超过0.050%时,析出物粗化,损害韧性,因此分别限定在V:0.01%以上、0.30%以下、Nb:0.005%以上、0.050%以下的范围。Both V and Nb form carbonitrides, refine the austenite grains, and effectively contribute to the improvement of strength. However, when the amounts of V and Nb are less than 0.01% and less than 0.005%, respectively, the effect of the addition is lacking, and when the amounts exceed 0.30% and 0.050%, respectively, the precipitates are coarsened and the toughness is impaired, so they are limited to V: 0.01. % to 0.30%, Nb: 0.005% to 0.050%.

以上说明了适当的成分组成范围,但在本发明中,各成分只单单满足上述的组成范围是不充分的,有必要进行成分调整以使用下述式(1)表示的LD值达到120以下。The appropriate composition ranges of the components have been described above, but in the present invention, it is not sufficient for each component to satisfy the above-mentioned composition ranges alone, and it is necessary to adjust the components so that the LD value represented by the following formula (1) becomes 120 or less.

LD=0.569×{7.98×(C)1/2×(1+4.1Mn)(1+2.83P)(1-0.62S)(1+0.64Si)LD=0.569×{7.98×(C) 1/2 ×(1+4.1Mn)(1+2.83P)(1-0.62S)(1+0.64Si)

    (1+2.33Cr)(1+0.52Ni)(1+3.14Mo)(1+0.27Cu)(1+1.5(0.9-C))}+52.6(1+2.33Cr)(1+0.52Ni)(1+3.14Mo)(1+0.27Cu)(1+1.5(0.9-C))}+52.6

                                                          ---(1) ---(1)

其中,式中的C、Mn、P、S、Si、Cr、Ni、Mo、Cu意指各个元素的含量(质量%)。However, C, Mn, P, S, Si, Cr, Ni, Mo, and Cu in the formula mean the content (mass %) of each element.

该LD值是通过淬透性来决定硬度和组织的指标。The LD value is an index for determining the hardness and structure by hardenability.

图1中关于本发明的高Cr、高Si钢显示出调查上述的LD值对滚轧成形性的影响的结果。另外,该图中,为了比较也一并显示出关于上述专利文献2中记载的低Cr、低Si钢的调查结果。FIG. 1 shows the results of investigating the influence of the above-mentioned LD value on roll formability for the high-Cr and high-Si steel of the present invention. In addition, in this figure, the investigation result about the low-Cr and low-Si steel described in the said patent document 2 is also shown together for comparison.

应注意的是,用滚轧试验中的模具寿命评价滚轧成形性。It should be noted that the roll formability was evaluated by the die life in the rolling test.

如该图所示,当任何场合LD值都超过120时,模具寿命急剧降低,但LD值在120以下的范围的模具寿命即滚轧成形性,本发明的高Cr、高Si钢极为优异。As shown in the figure, when the LD value exceeds 120 in any case, the die life decreases rapidly, but the die life in the range of LD value below 120, that is, the roll formability, the high Cr and high Si steel of the present invention is extremely excellent.

因此,本发明进行了成分调整以使上述的LD值为120以下。Therefore, in the present invention, the components are adjusted so that the above-mentioned LD value is 120 or less.

在本发明中,钢组织没有特别限定,但优选为以铁素体为主体、含有面积率5-30%左右的贝氏体相的组织。In the present invention, the steel structure is not particularly limited, but is preferably a structure mainly composed of ferrite and containing a bainite phase with an area ratio of about 5 to 30%.

以上说明的本发明的钢材,用于动力传动部件、尤其是汽车用传动轴和等速万向节是最佳的。加工性优异不用说,由于负载容量增加,因此得到能够减轻重量这一大的效果。The steel materials of the present invention described above are most suitable for use in power transmission parts, especially automotive propeller shafts and constant velocity joints. It goes without saying that the processability is excellent, and since the load capacity increases, a great effect of being able to reduce the weight is obtained.

其次,说明本发明的优选制造条件。Next, preferred production conditions of the present invention will be described.

本发明钢材的冶炼方法,按照常规方法制造即可,不特别限定。本发明提供的机械结构用钢,即使含有使用电炉冶炼时难以除掉的Cu和Ni,也具有良好的滚轧成形性,因此特别适合于采用电炉冶炼。也可以附加RH脱气等真空脱气、在铁水包中精炼等。钢水用连铸法或铸锭法凝固,凝固后,经由热轧或热轧·中温锻造,制成规定形状的坯材。这些坯材根据需要实施正火、球化退火、软化退火等中间热处理,通过切削、锻造、滚轧等冷加工精加工成所要求的形状。The smelting method of the steel material of the present invention may be manufactured according to a conventional method, and is not particularly limited. The steel for mechanical structure provided by the invention has good roll formability even if it contains Cu and Ni which are difficult to remove when smelted in an electric furnace, so it is particularly suitable for smelting in an electric furnace. Vacuum degassing such as RH degassing, refining in a ladle, etc. may also be added. The molten steel is solidified by continuous casting or ingot casting. After solidification, it is hot-rolled or hot-rolled and medium-temperature forged to make a billet of a specified shape. These billets are subjected to intermediate heat treatments such as normalizing, spheroidizing annealing, and softening annealing as required, and are finished into required shapes by cold working such as cutting, forging, and rolling.

在本发明中,实施热轧或热锻、或者进一步正火处理,并精加工成制品形状。该热轧或热锻后进而正火等的奥氏体化后的冷却,为了生成适当量的贝氏体,优选在0.2-2.0℃/s左右。特别是粗径的棒钢,优选为调整了冷却的加速冷却。In the present invention, hot rolling or hot forging, or further normalizing treatment is carried out, and the product shape is finished. The cooling after austenitization such as normalizing after hot rolling or hot forging is preferably about 0.2 to 2.0° C./s in order to generate an appropriate amount of bainite. In particular, for large-diameter steel bars, accelerated cooling with adjusted cooling is preferable.

另外,最终的高频淬火回火,使用15kHz左右的高频淬火装置,在输出功率:120kW左右下实施0.2-1.0秒左右的加热后,淬火,在170℃下实施30分左右的回火即可。In addition, for the final induction quenching and tempering, use an induction quenching device of about 15kHz, heat for about 0.2-1.0 seconds at an output power of about 120kW, and then quench and temper at 170°C for about 30 minutes. Can.

实施例Example

用转炉熔炼表1所示的成分组成的钢,通过连铸制成400×540mm的钢锭后,通过热轧制成150mm见方的坯段。接着将该坯段加热至1030℃后,通过热轧制成Ф25mm的直棒后,以冷却速度0.7℃/s空冷。The steel with the composition shown in Table 1 was smelted in a converter, and a steel ingot of 400×540 mm was produced by continuous casting, and then a billet of 150 mm square was produced by hot rolling. Next, after heating the billet to 1030°C, it was hot-rolled into a Ф25mm straight bar, and air-cooled at a cooling rate of 0.7°C/s.

表2表示出关于这样得到的棒钢的组织、滚轧成形性、扭转特性以及耐淬裂性进行调查的结果。Table 2 shows the results of investigations on the microstructure, roll formability, torsional characteristics, and quench cracking resistance of the steel bars thus obtained.

钢的组织和各特性的评价方法如下。The evaluation methods for the structure and properties of the steel are as follows.

(1)组织(1) Organization

关于冷却后的直棒,采用光学显微镜拍摄显微组织,从该照片解析钢的组织的同时,利用图象解析装置测定了贝氏体相的面积率。The microstructure of the straight bar after cooling was photographed with an optical microscope, and the structure of the steel was analyzed from the photograph, and the area ratio of the bainite phase was measured with an image analyzer.

(2)滚轧成形性(2) Roll formability

用滚轧试验中的模具寿命评价滚轧成形性。用能够滚轧直到由于模具的缺齿、表面破皮剥离、齿磨损等以至于不能滚轧为止的材料的个数评价该模具寿命。Roll formability was evaluated by the die life in the rolling test. The die life was evaluated by the number of materials that could be rolled until they could not be rolled due to tooth chipping, surface peeling, tooth wear, etc. of the die.

模具材质是SKD11,齿条数据如下。The mold material is SKD11, and the rack data is as follows.

齿形:渐开线形,模数:1.27,压力角:30o,齿数:21,节距直径:26.27mm,大径:28.1mm,小径:24.88mm,滚柱直径(Ф2.5mm销(pin)):30.49mmTooth shape: involute, modulus: 1.27, pressure angle: 30o, number of teeth: 21, pitch diameter: 26.27mm, major diameter: 28.1mm, minor diameter: 24.88mm, roller diameter (Ф2.5mm pin (pin) ): 30.49mm

(3)扭转特性(3) Torsion characteristics

从直棒制作平行部:Ф20mm的平滑圆棒扭转试验片,使用频率:15kHz的高频淬火装置对其淬火,实施170℃、30分的回火处理后,进行扭转试验。将高频淬火回火后的淬透深度定为约4mm。扭转试验使用4900J(500kgf·m)的扭转试验机求出最大扭转剪切强度,将它作为扭转强度。Make a parallel part from a straight bar: a Ф20mm smooth round bar torsion test piece, quench it with a high-frequency quenching device with a frequency of 15kHz, perform a tempering treatment at 170°C for 30 minutes, and then perform a torsion test. The depth of hardening after the induction hardening and tempering was set to about 4 mm. In the torsion test, a 4900J (500kgf·m) torsion testing machine was used to obtain the maximum torsional shear strength, which was used as the torsional strength.

(4)耐淬裂性(4) Quenching cracking resistance

耐淬裂性,从上述的Ф25mm的直棒加工表面带有轴向的V字沟槽的圆棒(Ф20mm),进行与上述(3)同样的高频淬火后,抛光观察圆棒的C截面10个部位,用其裂纹发生个数评价。Quenching cracking resistance, process a round bar (Ф20mm) with an axial V-shaped groove on the surface from the above-mentioned straight bar of Ф25mm, perform the same high-frequency quenching as the above (3), polish and observe the C-section of the round bar The 10 parts are evaluated by the number of cracks.

(5)被切削性(5) Machinability

被切削性试验使用SKH4、Ф4mm的钻头,在转速:1500rpm的条件下进行12mm长的穿孔,求出直到不能切削为止的总开孔长(mm),将它作为工具寿命评价。In the machinability test, SKH4 and Ф4mm drills were used to drill holes with a length of 12 mm at a rotational speed of 1500 rpm, and the total hole length (mm) until cutting was not possible was obtained and used as tool life evaluation.

由表2明确知道,按照本发明得到的钢材都具有优异的滚轧成形性、扭转特性、耐淬裂性及被切削性。It is clear from Table 2 that the steels obtained according to the present invention have excellent roll formability, torsional properties, quench cracking resistance and machinability.

关于使用本发明的钢材形成,进行高频淬火、回火设置固化层而制造的传动轴的静态强度及疲劳强度,分别参照图2、图3说明。发明例的传动轴,使用表1的No.2钢材制造。比较例的传动轴,使用表1的No.18钢材制造。图2是通过静态强度试验测定传动轴的静态强度的结果。所谓静态强度试验(static strength test),是测定传动轴破坏时的最大扭矩,评价静态强度的试验。供试验的传动轴根数,比较例为1根,发明例为2根。图2中,分别表示为比较例、发明例1、发明例2。将比较例的传动轴断裂时作用的最大扭矩记为1,用与它的比表示发明例的传动轴断裂时作用的最大扭矩。可知相对于比较例的传动轴,发明例的传动轴提高The static strength and fatigue strength of the propeller shaft manufactured by induction hardening and tempering to form a solidified layer using the steel material of the present invention will be described with reference to FIG. 2 and FIG. 3 , respectively. The propeller shaft of the inventive example was manufactured using No. 2 steel material in Table 1. The propeller shaft of the comparative example was manufactured using No. 18 steel material in Table 1. Fig. 2 is the result of measuring the static strength of the propeller shaft through the static strength test. The so-called static strength test (static strength test) is a test to measure the maximum torque when the propeller shaft breaks and evaluate the static strength. The number of transmission shafts for the test is 1 for the comparative example and 2 for the inventive example. In FIG. 2 , the comparative example, the inventive example 1, and the inventive example 2 are respectively shown. The maximum torque acting when the propeller shaft of the comparative example was broken was denoted as 1, and the maximum torque acting when the propeller shaft of the inventive example was broken was expressed as a ratio thereto. It can be seen that with respect to the transmission shaft of the comparative example, the transmission shaft of the invention example improves

静态强度约1.17倍。The static strength is about 1.17 times.

图3是通过疲劳强度试验测定发明例的传动轴和比较例的传动轴的疲劳强度的结果。所谓疲劳强度试验(fatigue strengthtest),是测定反复负荷扭矩时的疲劳强度的试验。对传动轴反复给予所规定的负荷扭矩,求出直到断裂为止的负荷反复数N。纵坐标是负荷扭矩除以比较例的传动轴的静态强度而得的值,为无量纲。横坐标是传动轴直到断裂为止的负荷的反复次数。从该试验结果知道,例如反复次数为10000次的场合,比较例的传动轴的纵坐标值为约0.49,发明例的传动轴的纵坐标值为约0.55,发明例的传动轴的疲劳强度提高约10%。FIG. 3 shows the results of measuring the fatigue strength of the propeller shaft of the inventive example and the propeller shaft of the comparative example by a fatigue strength test. The so-called fatigue strength test (fatigue strength test) is a test to measure the fatigue strength when repeated load torque. The specified load torque is repeatedly applied to the propeller shaft, and the number N of load repetitions until fracture is obtained. The ordinate is a value obtained by dividing the load torque by the static strength of the propeller shaft of the comparative example, and is dimensionless. The abscissa is the number of repetitions of the load on the propeller shaft until it breaks. From the test results, it is known that, for example, when the number of repetitions is 10,000 times, the ordinate value of the transmission shaft of the comparative example is about 0.49, and the ordinate value of the transmission shaft of the invention example is about 0.55, and the fatigue strength of the transmission shaft of the invention example is improved. About 10%.

工业实用性Industrial Applicability

根据本发明,能够从使用Cu和Ni等夹杂元素不可避免地混入的电炉制造的机械结构用钢材消除夹杂元素的坏影响。能够得到具有优异的滚轧成形性、扭转特性、耐淬裂性及淬透性的钢材。本发明的钢材,通过在动力传动部件、尤其是汽车用传动轴和等速万向节中采用,加工性优异不用说,由于为高强度,因此能够得到可减轻重量这一大的效果。According to the present invention, it is possible to eliminate the adverse effects of inclusion elements from a steel material for machine structural use manufactured using an electric furnace in which inclusion elements such as Cu and Ni are unavoidably mixed. A steel material having excellent roll formability, torsional characteristics, quench cracking resistance, and hardenability can be obtained. When the steel material of the present invention is used for power transmission parts, especially automobile propeller shafts and constant velocity joints, it is excellent in workability, and since it has high strength, it can achieve a great effect of weight reduction.

表1 No.                                                                    成分组成(质量%) LD值   C   Si   Mn   P   S   Cu   Ni   Cr   Mo   Al   Ti   B   N   V   Nb     1   0.37   0.05   0.83   0.015   0.030   0.08   0.05   0.08   0.19   0.028   0.030   0.0032   0.0051   -   -     98.4     2   0.40   0.08   0.45   0.013   0.018   0.16   0.16   0.16   0.17   0.032   0.019   0.0022   0.0044   -   -     89.3     3   0.39   0.08   0.25   0.011   0.020   0.16   0.15   0.15   0.16   0.040   0.020   0.0020   0.0038   -   -     77.3     4   0.47   0.06   0.56   0.009   0.022   0.12   0.10   0.09   0.17   0.015   0.024   0.0017   0.0076   -   -     88.3     5   0.42   0.10   0.65   0.013   0.020   0.11   0.10   0.11   0.25   0.025   0.015   0.0023   0.0041   0.11   -     101.7     6   0.40   0.08   0.95   0.016   0.015   0.16   0.16   0.16   0.12   0.023   0.024   0.0022   0.0045   -   0.020     109.8     7   0.41   0.06   0.70   0.019   0.006   0.11   0.12   0.12   0.36   0.026   0.019   0.0019   0.0048   -   -     116.1     8   0.40   0.08   0.60   0.019   0.007   0.22   0.16   0.16   0.35   0.026   0.025   0.0020   0.0052   -   -     116.0     9   0.40   0.04   0.88   0.019   0.006   0.06   0.06   0.06   0.35   0.022   0.020   0.0025   0.0044   -   -     116.4     10   0.41   0.07   0.60   0.016   0.015   0.11   0.10   0.12   0.15   0.023   0.024   0.0022   0.0045   0.15   0.032     91.1     11   0.40   0.06   0.84   0.018   0.007   0.11   0.11   0.11   0.35   0.025   0.023   0.0020   0.0041   -   -     122.2     12   0.41   0.08   0.73   0.019   0.007   0.16   0.16   0.15   0.34   0.023   0.024   0.0023   0.0047   -   -     122.6     13   0.42   0.04   0.99   0.018   0.006   0.06   0.06   0.06   0.35   0.024   0.021   0.0018   0.0045   -   -     121.5     14   0.61   0.06   0.63   0.012   0.021   0.13   0.12   0.13   0.16   0.022   0.019   0.0019   0.0054   -   -     94.2     15   0.31   0.08   0.57   0.011   0.020   0.15   0.16   0.13   0.17   0.031   0.020   0.0018   0.0060   -   -     90.9     16   0.40   0.04   1.22   0.014   0.023   0.16   0.15   0.17   0.26   0.034   0.017   0.0018   0.0065   -   -     143.0     17   0.42   0.23   0.70   0.025   0.024   0.14   0.11   0.10   0.16   0.025   0.024   0.0016   0.0056   -   -     100.8     18   0.39   0.04   0.54   0.014   0.045   0.32   0.26   0.26   0.15   0.022   0.023   0.0022   0.0048   -   -     101.2     19   0.40   0.05   0.48   0.014   0.020   0.11   0.10   0.11   0.62   0.024   0.020   0.0025   0.0046   -   -     116.0     20   0.38   0.05   0.52   0.013   0.018   0.11   0.11   0.09   0.03   0.025   0.022   0.0017   0.0049   -   -     76.4     21   0.37   0.02   1.00   0.015   0.030   0.08   0.05   0.03   0.35   0.021   0.023   0.0032   0.0052   -   -     114.3 Table 1 No. Composition (mass%) LD value C Si mn P S Cu Ni Cr Mo Al Ti B N V Nb 1 0.37 0.05 0.83 0.015 0.030 0.08 0.05 0.08 0.19 0.028 0.030 0.0032 0.0051 - - 98.4 2 0.40 0.08 0.45 0.013 0.018 0.16 0.16 0.16 0.17 0.032 0.019 0.0022 0.0044 - - 89.3 3 0.39 0.08 0.25 0.011 0.020 0.16 0.15 0.15 0.16 0.040 0.020 0.0020 0.0038 - - 77.3 4 0.47 0.06 0.56 0.009 0.022 0.12 0.10 0.09 0.17 0.015 0.024 0.0017 0.0076 - - 88.3 5 0.42 0.10 0.65 0.013 0.020 0.11 0.10 0.11 0.25 0.025 0.015 0.0023 0.0041 0.11 - 101.7 6 0.40 0.08 0.95 0.016 0.015 0.16 0.16 0.16 0.12 0.023 0.024 0.0022 0.0045 - 0.020 109.8 7 0.41 0.06 0.70 0.019 0.006 0.11 0.12 0.12 0.36 0.026 0.019 0.0019 0.0048 - - 116.1 8 0.40 0.08 0.60 0.019 0.007 0.22 0.16 0.16 0.35 0.026 0.025 0.0020 0.0052 - - 116.0 9 0.40 0.04 0.88 0.019 0.006 0.06 0.06 0.06 0.35 0.022 0.020 0.0025 0.0044 - - 116.4 10 0.41 0.07 0.60 0.016 0.015 0.11 0.10 0.12 0.15 0.023 0.024 0.0022 0.0045 0.15 0.032 91.1 11 0.40 0.06 0.84 0.018 0.007 0.11 0.11 0.11 0.35 0.025 0.023 0.0020 0.0041 - - 122.2 12 0.41 0.08 0.73 0.019 0.007 0.16 0.16 0.15 0.34 0.023 0.024 0.0023 0.0047 - - 122.6 13 0.42 0.04 0.99 0.018 0.006 0.06 0.06 0.06 0.35 0.024 0.021 0.0018 0.0045 - - 121.5 14 0.61 0.06 0.63 0.012 0.021 0.13 0.12 0.13 0.16 0.022 0.019 0.0019 0.0054 - - 94.2 15 0.31 0.08 0.57 0.011 0.020 0.15 0.16 0.13 0.17 0.031 0.020 0.0018 0.0060 - - 90.9 16 0.40 0.04 1.22 0.014 0.023 0.16 0.15 0.17 0.26 0.034 0.017 0.0018 0.0065 - - 143.0 17 0.42 0.23 0.70 0.025 0.024 0.14 0.11 0.10 0.16 0.025 0.024 0.0016 0.0056 - - 100.8 18 0.39 0.04 0.54 0.014 0.045 0.32 0.26 0.26 0.15 0.022 0.023 0.0022 0.0048 - - 101.2 19 0.40 0.05 0.48 0.014 0.020 0.11 0.10 0.11 0.62 0.024 0.020 0.0025 0.0046 - - 116.0 20 0.38 0.05 0.52 0.013 0.018 0.11 0.11 0.09 0.03 0.025 0.022 0.0017 0.0049 - - 76.4 twenty one 0.37 0.02 1.00 0.015 0.030 0.08 0.05 0.03 0.35 0.021 0.023 0.0032 0.0052 - - 114.3

表2 No.   组织  *   贝氏体比率(%) 模具寿命(个)   扭转强度(MPa) 淬裂个数(个)   工具寿命(mm) 备注   1   F+P+B     12     610     1540     15     2430   发明例   2   F+P+B     14     624     1580     16     2480     ″   3   F+P+B     10     642     1570     10     2300     ″   4   F+P+B     13     588     1630     19     2390     ″   5   F+P+B     18     591     1590     18     1740     ″   6   F+P+B     8     525     1570     18     2110     ″   7   F+P+B     23     493     1580     19     2470     ″   8   F+P+B     21     469     1590     19     2450     ″   9   F+P+B     20     512     1580     20     2440     ″   10   F+P+B     10     658     1620     16     2120     ″   11   F+P+B     21     253     1590     18     2300   比较例   12   F+P+B     19     218     1580     19     2320     ″   13   F+P+B     22     226     1600     21     2310     ″   14   F+P+B     11     599     1650     45     1120     ″   15   F+P+B     7     635     1190     4     2130     ″   16   F+P+B     14     151     1430     19     1940     ″   17   F+P+B     17     585     1560     24     1290     ″   18   F+P+B     16     523     1400     17     1270     ″   19   F+P+B     45     514     1600     16     1510     ″   20   F+P     0     663     1550     11     1330     ″   21   F+P+B     26     360     1530     17     2400     ″ Table 2 No. organization * Bainite ratio (%) Mold life (pieces) Torsional strength (MPa) Number of Quenching Cracks (pieces) Tool life(mm) Remark 1 F+P+B 12 610 1540 15 2430 Invention example 2 F+P+B 14 624 1580 16 2480 " 3 F+P+B 10 642 1570 10 2300 " 4 F+P+B 13 588 1630 19 2390 " 5 F+P+B 18 591 1590 18 1740 " 6 F+P+B 8 525 1570 18 2110 " 7 F+P+B twenty three 493 1580 19 2470 " 8 F+P+B twenty one 469 1590 19 2450 " 9 F+P+B 20 512 1580 20 2440 " 10 F+P+B 10 658 1620 16 2120 " 11 F+P+B twenty one 253 1590 18 2300 comparative example 12 F+P+B 19 218 1580 19 2320 " 13 F+P+B twenty two 226 1600 twenty one 2310 " 14 F+P+B 11 599 1650 45 1120 " 15 F+P+B 7 635 1190 4 2130 " 16 F+P+B 14 151 1430 19 1940 " 17 F+P+B 17 585 1560 twenty four 1290 " 18 F+P+B 16 523 1400 17 1270 " 19 F+P+B 45 514 1600 16 1510 " 20 F+P 0 663 1550 11 1330 " twenty one F+P+B 26 360 1530 17 2400 "

*  F:铁素体、    P:珠光体、    B:贝氏体* F: ferrite, P: pearlite, B: bainite

Claims (3)

1. the machine structural steel product of a rollforming, quenching crack resistance and torsional property excellence is characterized in that, be following composition: % represents with quality, is that scope below 120 contains satisfying the LD value of representing with following formula (1),
More than the C:0.35%, below 0.50%,
Below the Si:0.15%,
More than the Mn:0.2%, below 1.1%,
Below the P:0.020%,
More than the S:0.005%, below 0.035%,
Cr: surpass 0.1%, below 0.2%,
More than the Mo:0.05%, below 0.5%,
More than the Ti:0.01%, below 0.05%,
More than the Al:0.01%, below 0.05%,
Below the N:0.01%,
More than the B:0.0005%, below 0.0050%,
Reach more than the Cu:0.06%, below 0.25%
More than the Ni:0.05%, below 0.2%,
Remainder is Fe and unavoidable impurities,
LD=0.569×{7.98×(C) 1/2×(1+4.1Mn)(1+2.83P)(1-0.62S)(1+0.64Si)(1+2.33Cr)(1+0.52Ni)(1+3.14Mo)(1+0.27Cu)(1+1.5(0.9-C))}+52.6
---(1)
Wherein, the C in the formula, Mn, P, S, Si, Cr, Ni, Mo, Cu refer to the content (quality %) of each element.
2. the machine structural steel product of rollforming according to claim 1, quenching crack resistance and torsional property excellence is characterized in that, be following composition: % represents with quality, and steel also further contain,
Reach more than the V:0.01%, below 0.30%
More than the Nb:0.005%, below 0.050%.
3. a transmission shaft is characterized in that, adopts claim 1 or 2 described machine structural steel products to form, thereby carries out high-frequency quenching, tempering is provided with cured layer.
CNB028297733A 2002-10-18 2002-12-26 Steel materials for machine structures and propeller shafts with excellent roll formability, quench cracking resistance, and torsional properties Expired - Fee Related CN1307319C (en)

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