CN1506220A - Method for manufacturing continuous roll type elastic cloth laminated rubber material - Google Patents
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Abstract
Description
技术领域technical field
本发明是有关于一种连续卷式弹性布贴合橡胶材的制造方法,其主要是经由薄膜产生装置形成的橡胶薄膜贴合弹性布,在常压热风状态下进行高温加硫的制法,即形成厚度均一的连续卷式橡胶布,其所形成的橡胶布具有良好的弹性及柔软性。The present invention relates to a manufacturing method of continuous roll-type elastic cloth laminating rubber material, which is mainly a method of laminating elastic cloth with a rubber film formed by a film generating device, and performing high-temperature vulcanization in the state of hot air at normal pressure. That is to form a continuous rolling rubber cloth with uniform thickness, and the formed rubber cloth has good elasticity and softness.
背景技术Background technique
一般传统的弹性布加工方式是以热压成型方式进行,其弹性布分为针织布及平织弹性布,其中针织布结构分为单向伸缩结构及双向伸缩结构二种;平织弹性布为平织布添加高弹性纤维于长纤中,形成具有弹性伸缩性的弹性布,其也分为单向伸缩结构及双向伸缩结构二种。其主要缺陷在于:Generally, the traditional elastic fabric processing method is carried out by hot pressing. The elastic fabric is divided into knitted fabric and flat woven elastic fabric. The knitted fabric structure is divided into two types: one-way stretchable structure and two-way stretchable structure; plain woven elastic fabric is Plain woven fabrics add highly elastic fibers to the long fibers to form elastic fabrics with elastic stretchability, which are also divided into two types: one-way stretchable structure and two-way stretchable structure. Its main flaws are:
一般传统的弹性布贴合橡胶及塑胶材料的加硫制法,为密闭式热压成型加硫,所生产的制品为不连续性,生产过程断断续续,能源耗费较高。Generally, the traditional vulcanization method of laminating elastic cloth with rubber and plastic materials is a closed hot press molding vulcanization method. The products produced are discontinuous, the production process is intermittent, and the energy consumption is high.
发明内容Contents of the invention
本发明的主要目的是提供一种连续卷式弹性布贴合橡胶材的制造方法,其主要是一种以基材贴合弹性布,再与薄膜产生装置形成的橡胶薄膜贴合后,经开放式热风加硫的制法,达到形成连续卷式弹性布贴合橡胶材制品的目的。The main purpose of the present invention is to provide a manufacturing method of continuous rolling elastic cloth laminated rubber material, which is mainly a method of laminating elastic cloth with a base material, and then laminating with the rubber film formed by the film generating device, and then opening The production method of hot air and vulcanization achieves the purpose of forming continuous rolling elastic cloth laminated rubber products.
本发明的第二目的是提供一种连续卷式弹性布贴合橡胶材的制造方法,是将橡胶组成物,经混炼装置混合形成连续片状胶片,再将其经过薄膜产生装置与弹性布贴合,以开放式热空气装置进行加硫反应,随后卷出进行裁边,将基材剥离并同时卷出绕取,达到形成连续卷式的弹性布贴合橡胶材的制品的目的。The second object of the present invention is to provide a method for manufacturing a continuous rolling elastic cloth laminated rubber material, which is to mix the rubber composition through a kneading device to form a continuous sheet film, and then pass it through a film generating device and an elastic cloth. For lamination, use an open hot air device for vulcanization reaction, then roll out for edge trimming, peel off the base material and roll out at the same time, to achieve the purpose of forming a continuous roll elastic cloth laminated rubber material product.
本发明的第三目的是提供一种连续卷式弹性布贴合橡胶材的制造方法,弹性布可进行特殊处理,包括防霉处理或耐燃处理或抗静电处理,达到增加产品的多样性、提高附加价值及多用途的目的。The third object of the present invention is to provide a method for manufacturing continuous rolling elastic cloth laminated with rubber materials. The elastic cloth can be specially treated, including anti-mildew treatment or flame-resistant treatment or anti-static treatment, so as to increase product diversity and improve Added value and multi-purpose purpose.
本发明的第四目的是提供一种连续卷式弹性布贴合橡胶材的制造方法,其生产的弹性布贴合橡胶材制品,可作为胶作面及布作面用途,达到提高使用上的多应用的目的。The fourth object of the present invention is to provide a method for manufacturing continuous rolling elastic cloth laminated rubber material, the elastic cloth laminated rubber material products produced by it can be used as glue surface and cloth surface, so as to improve the efficiency of use. purpose for multiple applications.
本发明的第五目的是提供一种连续卷式弹性布贴合橡胶材的制造方法,其中弹性布可为各种纺织品,包括圆编及经编针织布或平纹织物弹性布,达到开发多品种的目的。The fifth object of the present invention is to provide a method for manufacturing continuous rolling elastic cloth laminated with rubber materials, wherein the elastic cloth can be various textiles, including circular knitting and warp knitting cloth or plain weave elastic cloth, so as to achieve the development of multiple varieties the goal of.
本发明的目的是这样实现的:一种连续卷式弹性布贴合橡胶材的制造方法,其特征是:它主要包含下列步骤:The object of the present invention is achieved like this: a kind of manufacture method of continuous rolling type elastic cloth laminating rubber material is characterized in that: it mainly comprises the following steps:
(1)将一弹性布与一基材以一贴合装置进行同步贴合,再同时卷出绕取;(1) Laminate an elastic cloth and a substrate synchronously with a laminating device, and then roll out and take it out at the same time;
(2)将至少一橡胶组成物置入一加压式混合装置中,充分搅拌互相混合,使其混合物均匀分散;(2) Put at least one rubber composition into a pressurized mixing device, fully stir and mix each other, so that the mixture is evenly dispersed;
(3)将该弹性布经过一裱糊装置涂布一粘接剂层,再经过加热干燥处理;(3) The elastic cloth is coated with an adhesive layer through a pasting device, and then subjected to heating and drying treatment;
(4)将该混合后的胶料,经一混合装置与一添加剂进行混合;(4) mixing the mixed sizing material with an additive through a mixing device;
(5)将该加压式混合装置混合的橡胶混合物,送至一常压连续卷式薄膜产生装置,以产出一薄膜并与该弹性布贴合;(5) The rubber mixture mixed by the pressurized mixing device is sent to a normal pressure continuous roll film production device to produce a film and bond it with the elastic cloth;
(6)将该贴和后的薄膜带入一连续开放式加硫热风装置中加硫,加硫完成后冷却绕取成卷;(6) Bring the pasted film into a continuous open vulcanization hot air device for vulcanization, and after vulcanization is completed, cool and wind to form a roll;
(7)将该加硫完成后成卷的制品与该基布分离,即得连续卷式弹性布贴合橡胶材制品。(7) Separate the rolled product after vulcanization from the base cloth to obtain a continuous rolled elastic cloth laminated rubber product.
该将多数种橡胶组成物置入一加压式混合装置的步骤中,其温度控制在80-120℃。该操作的温度是由常温至80-110℃,时间为5-10分钟。In the step of putting multiple kinds of rubber compositions into a pressurized mixing device, the temperature is controlled at 80-120°C. The temperature of this operation is from normal temperature to 80-110 ℃, and the time is 5-10 minutes.
该涂布一粘接剂后的加热干燥处理的步骤中,其加热温度为100-130℃。In the step of heating and drying after coating an adhesive, the heating temperature is 100-130°C.
将该混合后的胶料经一混合装置与一添加剂进行混合的步骤中,其温度控制在50-70℃,混合时间为5-10分钟。In the step of mixing the mixed rubber material with an additive through a mixing device, the temperature is controlled at 50-70° C., and the mixing time is 5-10 minutes.
该常压连续卷式薄膜产生装置以产出一薄膜并与该弹性布贴合的步骤中,其操作温度为80-100℃,且其胶料温度为50-70℃。该连续开放式加热风装置中的加硫步骤中,其加热温度控制在120-170℃,加热时间控制在10-30分钟。该加压式混合装置是万马力混炼机或密闭式捏合机。In the steps of producing a film and laminating it with the elastic cloth by the normal pressure continuous rolling film production device, the operating temperature is 80-100° C., and the glue material temperature is 50-70° C. In the vulcanizing step in the continuous open heating air device, the heating temperature is controlled at 120-170° C., and the heating time is controlled at 10-30 minutes. The pressurized mixing device is a 10,000-horsepower mixer or a closed kneader.
该至少一橡胶组成物是选自天然橡胶、合成橡胶或其混合物所组成的群组。该至少一橡胶组成物是橡塑胶的混合物。该至少一橡胶组成物为直接贴合于裱糊面上。该弹性布与基材贴合所用的粘接剂成份是选自聚氨基甲酸酯、丙烯酸酯、天然橡胶或合成橡胶所组成的群组。该聚氨基甲酸酯为一湿气硬化型聚氨基甲酸酯。该湿气硬化型聚氨基甲酸酯粘接剂为溶剂型或薄膜型,以全面上胶方式或不连续上胶式涂布,或点状上胶方式涂布。该天然橡胶或合成橡胶为一加热硬化型,其加热温度为100-120℃,加热时间为5-10钟。该弹性布与该基材贴合是通过一聚合物经加热后贴合的方式,其涂布温度为70-90℃,涂布的粘度为3000-5000厘泊,涂布的厚度为0.02-0.03mm。The at least one rubber composition is selected from the group consisting of natural rubber, synthetic rubber or a mixture thereof. The at least one rubber composition is a mixture of rubber and plastic. The at least one rubber composition is directly pasted on the pasting surface. The adhesive component used for bonding the elastic cloth to the substrate is selected from the group consisting of polyurethane, acrylic ester, natural rubber or synthetic rubber. The polyurethane is a moisture-curing polyurethane. The moisture-curing polyurethane adhesive is solvent-based or film-based, and is applied in the form of full-surface gluing, discontinuous gluing, or point-like gluing. The natural rubber or synthetic rubber is a heat hardening type, the heating temperature is 100-120°C, and the heating time is 5-10 minutes. The elastic cloth is bonded to the base material by heating a polymer, the coating temperature is 70-90°C, the coating viscosity is 3000-5000 centipoise, and the coating thickness is 0.02- 0.03mm.
该基材是一纤维织物。该纤维织物是选自聚酯纤维、尼龙纤维、棉纤维或其中二者的混纺纤维所组成的群组。该纤维织物为泼水布或不泼水布。该纤维织物为一平纹组织。该弹性布材质是选自聚酯纤维、尼龙纤维、棉纤维、粘液螺萦或其中二者的混纺纤维,或其中三者的混纺纤维的所组成的群组。该弹性布是针织布或平织布混掺弹性纤维纱的弹性布。该弹性布为经过防霉处理或耐燃处理或抗静电处理。该针织布是单向弹性布或双向弹性布。该针织布是圆编针织布或经编针织布。该平织弹性布是单向弹性布或双向弹性布。The substrate is a fiber fabric. The fiber fabric is selected from the group consisting of polyester fibers, nylon fibers, cotton fibers or blended fibers of the two. The fiber fabric is a water-splashing cloth or a non-water-splashing cloth. The fiber fabric is a plain weave. The material of the elastic cloth is selected from the group consisting of polyester fiber, nylon fiber, cotton fiber, viscose spiral or blended fibers of two of them, or blended fibers of three of them. The elastic cloth is an elastic cloth in which elastic fiber yarn is mixed with knitted cloth or flat woven cloth. The elastic cloth is processed through anti-mildew treatment or flame-resistant treatment or antistatic treatment. The knitted fabric is one-way elastic fabric or two-way elastic fabric. The knitted fabric is a circular knitted fabric or a warp knitted fabric. The flat-woven elastic cloth is one-way elastic cloth or two-way elastic cloth.
该混合装置是一开放式双滚轮。该开放式双滚轮的粗轮的间距大,主要用于混合经过混炼制程的混合物与后段添加剂的混合;该细轮的间距小,主要用于第二次的混合及供应薄膜产出装置所须的橡胶混合物。该混合装置的操作温度控制在50-70℃。The mixing device is an open double roller. The distance between the coarse wheels of the open double roller is large, and it is mainly used for mixing the mixture after the mixing process and the additive in the later stage; the distance between the fine wheels is small, and it is mainly used for the second mixing and supplying film output The rubber compound required for the device. The operating temperature of the mixing device is controlled at 50-70°C.
该添加剂是加硫架桥剂、加硫促进剂或同时含有加硫架桥剂及加硫促进剂所组成的群组。该薄膜产生装置是压延机。该压延机为生产45-50英寸宽的制品。该贴和后的薄膜带入一连续开放式加热风装置中,在加硫的步骤之前,尚包含一将贴上薄膜的弹性布的薄膜表面撒粉的步骤。该撒粉的粉末成份为玉米粉、滑石粉、云母粉、硬脂酸锌或碳酸镁。The additive is a sulfur bridging agent, a vulcanization accelerator or a group consisting of a sulfur bridging agent and a vulcanization accelerator. The film producing device is a calender. The calender was designed to produce 45-50 inch wide articles. The pasted film is brought into a continuous open heating air device, and before the vulcanizing step, it also includes a step of dusting the film surface of the elastic cloth pasted with the film. The dusting powder contains corn flour, talcum powder, mica powder, zinc stearate or magnesium carbonate.
该加硫装置是开放式热空气加硫烘箱。该加硫温度是控制在140-160℃,停留时间为20-40分钟。该开放式热空气加硫烘箱是一针式加硫机。将该制品与该基布分离的同时,尚包含一裁边的步骤。该裁边的装置是一直立式及中心卷取方式的结构。该制造方法所生产的制品是一种橡胶贴合弹性布形成连续成卷的制品。The vulcanizing device is an open hot air vulcanizing oven. The vulcanization temperature is controlled at 140-160° C., and the residence time is 20-40 minutes. The open hot air vulcanizing oven is a needle vulcanizing machine. While separating the product from the base cloth, a step of trimming is also included. The trimming device is a vertical and center winding structure. The product produced by the manufacturing method is a product in which rubber is laminated with elastic cloth to form a continuous roll.
本发明的连续卷式弹性布贴合橡胶材的压延制法,主要为生产弹性布连续贴合橡胶材橡胶布,先进行基材与弹性布的贴合,再以压延装置与橡胶材进行贴合及以针板传送方式开放式烘箱加硫架桥,实质突破热风加硫时,因生产设备上的限制,具有提供连续的制品卷出及提高生产能力、产品价值及多用途,还具有制造厚度均一,具有弹性、重量轻及柔软性佳的连续卷式弹性布贴合橡胶制品。The calendering method of the continuous rolling elastic cloth laminating rubber material of the present invention is mainly to produce the elastic cloth continuously laminating the rubber material rubber cloth, first laminating the base material and the elastic cloth, and then laminating the rubber material with the calendering device Combination and open oven vulcanization bridging by way of needle plate transmission, a substantial breakthrough in hot air vulcanization, due to the limitation of production equipment, it can provide continuous product roll-out and increase production capacity, product value and multi-purpose, and also has the advantages of manufacturing Uniform thickness, elastic, light weight and soft continuous roll elastic cloth laminated rubber products.
下面结合较佳实施例和附图进一步说明。Further description will be given below in conjunction with preferred embodiments and accompanying drawings.
附图说明Description of drawings
图1是本发明的流程示意图。Fig. 1 is a schematic flow chart of the present invention.
图2是本发明的制造步骤方块示意图。Fig. 2 is a schematic block diagram of the manufacturing steps of the present invention.
具体实施方式Detailed ways
参阅图1所示,本发明是一种连续卷式弹性布贴合橡胶材的制造方法,该方法其主要包含下列步骤:Referring to shown in Fig. 1, the present invention is a kind of manufacturing method of continuous rolling elastic cloth laminating rubber material, and this method mainly comprises the following steps:
步骤10:将一弹性布与一基材通过一贴合装置进行同步贴合,再同时卷出绕取;Step 10: Synchronously laminating an elastic cloth and a base material through a laminating device, and then unwinding and rewinding at the same time;
步骤20:将至少一橡胶组成物置入一加压式混合装置中,充分搅拌互相混合,使其混合物均匀分散;Step 20: Put at least one rubber composition into a pressurized mixing device, fully stir and mix with each other, so that the mixture is evenly dispersed;
步骤30:将该弹性布经过一裱糊装置涂布一层粘接剂,再经过加热干燥处理;Step 30: Pass the elastic cloth through a pasting device to coat a layer of adhesive, and then heat and dry it;
步骤40:将该混合后的胶料,经一混合装置与一添加剂进行混合;Step 40: Mix the mixed rubber material with an additive through a mixing device;
步骤50:将该加压式混合装置混合的橡胶混合物,送至一常压连续卷式薄膜产生装置,以产出一薄膜并与该弹性布贴合;Step 50: sending the rubber mixture mixed by the pressurized mixing device to an atmospheric pressure continuous roll film production device to produce a film and bond it to the elastic cloth;
步骤60:将该贴和后的薄膜带入一连续开放式加热风装置中加硫,加硫完成后,冷却绕取成卷;Step 60: Bring the laminated film into a continuous open heating air device for vulcanization, after the vulcanization is completed, cool and wind it into rolls;
步骤70:将该加硫完成后成卷的制品与该基布分离,即得连续卷式弹性布贴合橡胶材制品。Step 70: Separating the rolled product after vulcanization from the base fabric to obtain a continuous rolled elastic cloth laminated rubber product.
其中,步骤20的温度控制在80-120℃,一般是由常温升至80-110℃,时间为5-10分钟;Wherein, the temperature in
步骤30的加热温度为100-130℃;The heating temperature in
步骤40的温度控制在50-70℃,混合时间为5-10分钟;The temperature in
步骤50的操作温度为80-100℃,且其胶料温度为50-70℃;The operating temperature in
步骤60的加热温度控制在120-170℃,加热时间控制在10-60分钟。The heating temperature in
其中,步骤20的加压式混合装置是万马力混炼机或密闭式捏合机,且,其中该至少一橡胶组成物是选自天然橡胶、合成橡胶或两者的混合物所组成的群组,或为一橡塑胶的混合物,其是将该至少一橡胶组成物为直接贴合于裱糊面上,其贴合所用的粘接剂成份是选自一聚氨基甲酸酯、丙烯酸酯、天然橡胶或合成橡胶的其中之一。Wherein, the pressurized mixing device in
其中,聚氨基甲酸酯为一湿气硬化型聚氨基甲酸酯,该湿气硬化型聚氨基甲酸酯粘接剂可为溶剂型或薄膜型,其是以全面上胶方式或不连续上胶式涂布或点状上胶方式涂布。Among them, the polyurethane is a moisture-curing polyurethane, and the moisture-curing polyurethane adhesive can be solvent-based or film-based, which is fully glued or discontinuous Glue coating or dot glue coating.
其中,该天然橡胶及合成橡胶为一加热硬化型,其加热温度为100-120℃,加热时间为5-10分钟。Wherein, the natural rubber and the synthetic rubber are heat hardening type, the heating temperature is 100-120° C., and the heating time is 5-10 minutes.
其中,该弹性布与该基材贴合是通过一聚合物经加热后贴合的方式,其涂布温度为70-90℃,涂布的粘度为3000-5000厘泊,涂布的厚度为0.02-0.03mm。Wherein, the bonding of the elastic cloth and the base material is through the bonding of a polymer after heating, the coating temperature is 70-90°C, the coating viscosity is 3000-5000 centipoise, and the coating thickness is 0.02-0.03mm.
其中,该基材为一纤维织物,选自一聚酯纤维、一尼龙纤维、一棉纤维或其中二者的混纺纤维所组成的群组,该纤维织物为泼水布或不泼水布,且为一平纹组织;Wherein, the base material is a fiber fabric selected from the group consisting of a polyester fiber, a nylon fiber, a cotton fiber or a blend of the two, the fiber fabric is a water-repellent cloth or a non-water-repellent cloth, and is a plain weave;
其中,该弹性布材质是选自一聚聚酯纤维、一尼龙纤维、一棉纤维、一粘液螺萦或其中二者的混纺纤维或其中三者的混纺纤维的组成的群组,该弹性布为一针织布或一平织布混掺弹性纤维纱的弹性布,也可经过一防霉处理或一耐燃处理或一抗静电处理,该针织布为一单向弹性布或为一双向弹性布,或为一圆编针织布或为一经编针织布,而其该平织弹性布可为一单向弹性布或为一双向弹性布。Wherein, the material of the elastic cloth is selected from a group consisting of a polyester fiber, a nylon fiber, a cotton fiber, a viscose spiral or a blend of two of them or a blend of three of them, the elastic cloth It is a knitted fabric or a plain woven elastic fabric mixed with elastic fiber yarn, which can also undergo a mildew-resistant treatment or a flame-resistant treatment or an antistatic treatment. The knitted fabric is a one-way elastic fabric or a two-way elastic fabric, Or it is a circular knitted fabric or a warp knitted fabric, and the flat woven elastic fabric can be a one-way elastic fabric or a two-way elastic fabric.
该混合装置为一开放式双滚轮,其中该开放式双滚轮包含一粗轮及一细轮,主要用于第二次的混合及供应薄膜产出装置所须的橡胶混合物,其中该混合装置的操作温度控制在50-70℃,其中该添加剂可为一加硫架桥剂、一加硫促进剂或同时含有加硫架桥剂及加硫促进剂所组成的群组;The mixing device is an open double roller, wherein the open double roller includes a coarse wheel and a fine wheel, mainly used for the second time mixing and supplying the rubber compound required by the film output device, wherein the mixing device The operating temperature is controlled at 50-70°C, wherein the additive can be a sulfur bridging agent, a vulcanization accelerator or a group consisting of a sulfur bridging agent and a sulfur accelerator;
其中,该薄膜产生装置为一压延机,其中该压延机可生产45-50英寸宽的制品。Wherein, the film producing device is a calender, wherein the calender can produce products with a width of 45-50 inches.
其中,该贴和后的薄膜带入一连续开放式加热风装置中加硫的步骤之前,尚包含一将贴上薄膜的弹性布的薄膜表面撒粉的步骤,该撒粉的粉末成份为一玉米粉、一滑石粉、一云母粉、一硬脂酸锌或一碳酸镁。Wherein, before the step of bringing the pasted film into a continuous open heating air device to add vulcanization, it still includes a step of dusting the film surface of the elastic cloth pasted with the film, and the powder composition of the dusting is a Corn flour, talc, mica powder, zinc stearate or magnesium carbonate.
该加硫装置为一开放式热空气加硫烘箱,该加硫温度是控制在140-160℃,停留时间为20-40分钟,该开放式热空气加硫烘箱为一针式加硫机,将该制品与该基布分离的同时,尚包含一裁边的步骤,该裁边的裁边装置为一直立式及一中心卷取方式。经由本发明的制造方法所生产的是一种橡胶贴合弹性布形成连续成卷制品。The vulcanizing device is an open hot air vulcanizing oven, the vulcanizing temperature is controlled at 140-160°C, and the residence time is 20-40 minutes. The open hot air vulcanizing oven is a needle vulcanizing machine. While separating the product from the base cloth, it also includes a step of trimming, and the trimming device for trimming is a vertical type and a center winding mode. Produced by the manufacturing method of the present invention is a rubber-laminated elastic cloth formed into a continuous roll product.
本发明的橡胶组成物包含有合成橡胶、加硫剂、活性剂、防老剂、内外部滑剂、加硫促进剂、发泡剂、填充剂、加工助剂、其它添加剂、色料或补强剂等。The rubber composition of the present invention contains synthetic rubber, vulcanizing agent, active agent, anti-aging agent, internal and external slip agent, vulcanization accelerator, foaming agent, filler, processing aid, other additives, colorant or reinforcement agent etc.
合成橡胶为氯平橡胶(Polychlorinated Rubber);The synthetic rubber is Polychlorinated Rubber;
加硫剂为硫磺;The vulcanizing agent is sulfur;
活性剂为氧化锌及硬脂酸;The active agent is zinc oxide and stearic acid;
防老剂为酚类防老剂;The anti-aging agent is a phenolic anti-aging agent;
内外部滑剂为PE Wax及脂肪酸类;Internal and external lubricants are PE Wax and fatty acids;
填充剂为轻质碳酸钙、碳酸镁处理的碳酸钙、滑石粉、锻烧土等;The filler is light calcium carbonate, calcium carbonate treated with magnesium carbonate, talcum powder, calcined clay, etc.;
其它添加剂可为加工油、硬脂酸锌、硬脂酸钙、氧化锌、氧化锑等;Other additives can be processing oil, zinc stearate, calcium stearate, zinc oxide, antimony oxide, etc.;
色料为有机及无机颜料;The pigments are organic and inorganic pigments;
补强剂为白烟(Silica)及碳黑(Carbon Black)。The reinforcing agent is white smoke (Silica) and carbon black (Carbon Black).
本发明的另一橡胶组成物是含有合成橡胶、加硫剂、活性剂、防老剂、内外部滑剂、加硫促进剂、耐燃剂、填充剂、加工助剂、色料等。Another rubber composition of the present invention contains synthetic rubber, vulcanizing agent, active agent, anti-aging agent, internal and external slip agent, vulcanization accelerator, flame retardant, filler, processing aid, colorant, etc.
合成橡胶为氯平橡胶、聚乙烯一丙烯橡胶及天然橡胶;Synthetic rubber is chloropine rubber, polyethylene-propylene rubber and natural rubber;
加硫剂为硫磺;The vulcanizing agent is sulfur;
活性剂为氧化锌及硬脂酸;The active agent is zinc oxide and stearic acid;
防老剂为酚类防老剂及胺类防老剂;The anti-aging agent is phenolic anti-aging agent and amine anti-aging agent;
内外部滑剂为PE Wax及脂肪酸类;Internal and external lubricants are PE Wax and fatty acids;
耐燃剂为无机耐燃剂、有机耐燃剂;Flame retardants are inorganic flame retardants and organic flame retardants;
填充剂为轻质碳酸钙、碳酸镁处理的碳酸钙、滑石粉、锻烧土等;The filler is light calcium carbonate, calcium carbonate treated with magnesium carbonate, talcum powder, calcined clay, etc.;
其它添加剂可为加工油、硬脂酸锌、硬脂酸钙、氧化锌、氧化锑等;Other additives can be processing oil, zinc stearate, calcium stearate, zinc oxide, antimony oxide, etc.;
色料为有机及无机颜料;The pigments are organic and inorganic pigments;
补强剂为白烟(Silica)及碳黑(Carbon Black)。The reinforcing agent is white smoke (Silica) and carbon black (Carbon Black).
其各组成成分的重量份数配比为:Its parts by weight ratio of each constituent is:
合成橡胶为氯平橡胶50-80份、The synthetic rubber is 50-80 parts of clopine rubber,
乙烯一丙烯橡胶30-10份、Ethylene-propylene rubber 30-10 parts,
天然橡胶10-20份、10-20 parts of natural rubber,
加硫剂为硫磺1-3份、The sulfur adding agent is 1-3 parts of sulfur,
活性剂为氧化锌4-5份、The active agent is 4-5 parts of zinc oxide,
硬脂酸1-2份、1-2 parts of stearic acid,
防老剂为酚类防老剂1-2份、The anti-aging agent is 1-2 parts of phenolic anti-aging agent,
内外部滑剂为PE Wax1-2份及脂肪酸类1-2份、Internal and external lubricants are 1-2 parts of PE Wax and 1-2 parts of fatty acids,
耐燃剂30-50份、30-50 parts of flame retardant,
填充剂30-50份、Filling agent 30-50 parts,
其它添加剂3-10份、3-10 parts of other additives,
色料为有机及无机颜料3-30份、The coloring material is 3-30 parts of organic and inorganic pigments,
补强剂为10-30份。The reinforcing agent is 10-30 parts.
本发明的制法所生产的连续卷式弹性布贴合橡胶材产品,应用相当广泛,主要用途在于皮包、手提袋、手套、护膝、鞋材及医疗床垫制品等。The continuous rolling elastic cloth laminated rubber product produced by the method of the present invention is widely used, mainly in leather bags, handbags, gloves, knee pads, shoe materials and medical mattress products.
本发明的制法与一般传统相比较,具有生产效率高的特点,一般传统的弹性布加工方式是以热压成型方式进行,本发明为一种连续卷式弹性布贴合橡胶材的压延制法,以压延装置进行贴合及以开放式烘箱进行加硫架桥,实质突破生产设备上的限制,提供了连续的弹性布制品及大大的提高生产能力、产品价值及实际用途。Compared with the general tradition, the production method of the present invention has the characteristics of high production efficiency. The general traditional elastic cloth processing method is carried out by hot pressing. Using calendering device for lamination and open oven for vulcanization and bridging, it substantially breaks through the limitation of production equipment, provides continuous elastic cloth products and greatly improves production capacity, product value and practical use.
以下配合实施例进一步说明。Below cooperate with embodiment to further illustrate.
实施例1Example 1
本实施例1所用的组成物为为氯平橡胶100份、加硫剂3份、氧化锌5份、硬脂酸1份、PE Wax1份、脂肪酸皂类1份、酚类防老剂1份、填充剂50份、加工油20份、补强剂30份及色料5份。The composition used in the present embodiment 1 is 100 parts of clopine rubber, 3 parts of vulcanizing agent, 5 parts of zinc oxide, 1 part of stearic acid, 1 part of PE Wax, 1 part of fatty acid soap, 1 part of phenolic antioxidant, 50 parts of filler, 20 parts of processing oil, 30 parts of reinforcing agent and 5 parts of coloring material.
实施例2Example 2
本实施例2所用的组成物为合成橡胶为氯平橡胶50份、乙烯一丙烯橡胶30份及天然橡胶20份;加硫剂为硫磺2份;活性剂为氧化锌5份及硬脂酸1份;防老剂为酚类防老剂2份;内外部滑剂为PE Wax2份及脂肪酸1份;耐燃剂50份;填充剂30份;其它添加剂为5份;色料为有机及无机颜料30份;补强剂为30份。The composition used in the present embodiment 2 is that synthetic rubber is 50 parts of chloropine rubber, 30 parts of ethylene-propylene rubber and 20 parts of natural rubber; the vulcanizing agent is 2 parts of sulfur; the active agent is 5 parts of zinc oxide and 1 part of stearic acid 2 parts; anti-aging agent is 2 parts of phenolic anti-aging agent; internal and external slip agent is 2 parts of PE Wax and 1 part of fatty acid; 50 parts of flame retardant; 30 parts of filler; 5 parts of other additives; 30 parts of organic and inorganic pigments ; The reinforcing agent is 30 parts.
实施例3Example 3
其组成成分同实施例2,但是具体加工条件不同,详见表1-表2所示。Its composition is the same as that of Example 2, but the specific processing conditions are different, as shown in Table 1-Table 2 for details.
参阅图2所示,本发明的制造步骤如下:Referring to shown in Figure 2, the manufacturing steps of the present invention are as follows:
一橡胶原料150先经过一混炼装置160混炼混合,并通过一加硫剂172与一混合装置170进行混合,并将一伸缩布120与一基材100于一贴和装置110进行贴和后,其表面经过一裱糊装置130涂布一层橡胶粘接剂后,与一混合装置混合的胶料送至一薄膜产出装置140的胶料贴合;再经过一撒粉装置180撒粉后,送至一加硫制程190,于常压下加硫;之后,再卷出裁边及分离基材的成卷及裁边制程200,即卷出绕取210,以形成一连续的弹性橡胶布制品。A rubber raw material 150 is first kneaded and mixed by a kneading device 160, and then mixed with a vulcanizing agent 172 and a mixing device 170, and a stretch fabric 120 and a base material 100 are pasted in a pasting device 110 Finally, after its surface passes through a pasting device 130 and coats a layer of rubber adhesive, the sizing material mixed with a mixing device is sent to the sizing material of a film output device 140 for lamination; After that, it is sent to a vulcanization process 190, and vulcanization is added under normal pressure; after that, the coiling and trimming process 200 of trimming and separating the base material is rolled out again, that is, coiling 210 is rolled out to form a continuous elastic Rubber cloth products.
其具体加工条件如表1所示。The specific processing conditions are shown in Table 1.
然后测其比重、重量、抗张强度、撕裂强度、粘接强度、耐热性、耐寒性、耐水压的数值,其测定结果如下表2所示。Measure its specific gravity, weight, tensile strength, tear strength, bonding strength, heat resistance, cold resistance, the numerical value of water pressure resistance then, and its measurement result is as shown in table 2 below.
表1本发明的加工条件
表2本发明的产品物性
注1:上述物性检测依下列方法:Note 1: The above physical properties are tested according to the following methods:
(1-1)木尼粘度及加硫时间依ASTM-D1646-61标准测试。(1-1) Mooney viscosity and vulcanization time are tested according to ASTM-D1646-61 standard.
(1-2)总重以精密度0.01×10mm的厚度计测试。(1-2) The total weight is tested with a thickness gauge with a precision of 0.01×10mm.
(1-3)比重依JIS K6350标准测试。(1-3) Specific gravity is tested according to JIS K6350 standard.
(1-4)硬度依JIS K6350标准测试。(1-4) Hardness is tested according to JIS K6350 standard.
(1-5)粘接强度依ASTM D412标准测试。(1-5) Adhesive strength is tested according to ASTM D412 standard.
(1-6)撕裂强度依ASTM D624标准测试。(1-6) Tear strength is tested according to ASTM D624 standard.
(1-7)耐热性及耐寒性依JIS K6328及ASTM D2136准测试。(1-7) Heat resistance and cold resistance are tested according to JIS K6328 and ASTM D2136.
(1-8)耐燃性依FTMS 1915903-1978标准测试。(1-8) Flame resistance is tested according to FTMS 1915903-1978 standard.
(1-9)水压依JIS K6328标准测试。(1-9) Water pressure is tested according to JIS K6328 standard.
注2:Note 2:
加硫时间TS2(分-秒)定义:达到平衡扭矩2%所须要的时间;Vulcanization time TS2 (minute-second) definition: the time required to reach 2% of the balance torque;
加硫时间TS90(分-秒)定义:达到平衡扭矩90%所须要的时间;Vulcanization time TS90 (minute-second) definition: the time required to reach 90% of the balance torque;
注3:N表示无法剥离。Note 3: N means that it cannot be peeled off.
以上所述,仅为本发明的较佳实施例而已,并非用来限定本发明的保护范围,凡依本发明的形状、构造、特征及精神所为的均等变化与修饰,均应包括于本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the protection scope of the present invention. All equivalent changes and modifications made according to the shape, structure, characteristics and spirit of the present invention shall be included in this invention. within the scope of protection of the invention.
综上所述,本发明具有新颖性、创造性及实用性。In summary, the present invention has novelty, creativity and practicability.
Claims (40)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
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| CN 02155244 CN1220586C (en) | 2002-12-10 | 2002-12-10 | Manufacturing method of continuous roll type elastic cloth laminated rubber material |
| HK04109837.4A HK1066762B (en) | 2004-12-13 | A method of the manufacture of continuous rolling elastic cloth adhesive rubber material |
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| CN 02155244 CN1220586C (en) | 2002-12-10 | 2002-12-10 | Manufacturing method of continuous roll type elastic cloth laminated rubber material |
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| CN1220586C CN1220586C (en) | 2005-09-28 |
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| CN100358614C (en) * | 2005-01-10 | 2008-01-02 | 宁波大学 | Manufacturing method of polytetrafluoroethylene supported composite filter membrane |
| CN101100551B (en) * | 2006-07-07 | 2010-12-01 | 厚生股份有限公司 | Continuous wide-width independent cell foamed silicone rubber composition and processing method thereof |
| CN101210389B (en) * | 2006-12-30 | 2011-09-14 | 厚生股份有限公司 | Processing method of low-smoke and flame-resistant rubber cloth |
| CN102234936A (en) * | 2010-04-30 | 2011-11-09 | 厚生股份有限公司 | Manufacturing method of double-knitted rubber cloth |
| CN102452143A (en) * | 2010-10-27 | 2012-05-16 | 厚生股份有限公司 | Method for manufacturing multilayer airtight rubber protective clothing material |
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| CN103568413A (en) * | 2012-07-20 | 2014-02-12 | 厚生股份有限公司 | Composite material and method for producing same |
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| CN100358614C (en) * | 2005-01-10 | 2008-01-02 | 宁波大学 | Manufacturing method of polytetrafluoroethylene supported composite filter membrane |
| CN101100551B (en) * | 2006-07-07 | 2010-12-01 | 厚生股份有限公司 | Continuous wide-width independent cell foamed silicone rubber composition and processing method thereof |
| CN101210389B (en) * | 2006-12-30 | 2011-09-14 | 厚生股份有限公司 | Processing method of low-smoke and flame-resistant rubber cloth |
| CN102234936A (en) * | 2010-04-30 | 2011-11-09 | 厚生股份有限公司 | Manufacturing method of double-knitted rubber cloth |
| CN102452143A (en) * | 2010-10-27 | 2012-05-16 | 厚生股份有限公司 | Method for manufacturing multilayer airtight rubber protective clothing material |
| CN103158305A (en) * | 2011-12-14 | 2013-06-19 | 常熟市新华化工有限公司 | Rubber fabric |
| CN103568413A (en) * | 2012-07-20 | 2014-02-12 | 厚生股份有限公司 | Composite material and method for producing same |
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| CN103653463A (en) * | 2012-09-07 | 2014-03-26 | 厚生股份有限公司 | Continuous diving suit cloth and manufacturing method thereof |
| CN103660450A (en) * | 2012-09-07 | 2014-03-26 | 厚生股份有限公司 | Rubber and thermoplastic polyurethane composite adhesive tape and manufacturing method thereof |
| CN103653463B (en) * | 2012-09-07 | 2015-12-09 | 厚生股份有限公司 | Continuous diving suit cloth and manufacturing method thereof |
| CN103965520A (en) * | 2013-01-25 | 2014-08-06 | 厚生股份有限公司 | Rubber composition, rubber layer and method for manufacturing double-sided rubber composite layer |
| CN103965520B (en) * | 2013-01-25 | 2016-06-08 | 厚生股份有限公司 | Rubber composition, rubber layer and method for manufacturing double-sided rubber composite layer |
| CN104512074A (en) * | 2013-09-27 | 2015-04-15 | 厚生股份有限公司 | Composite adhesive tape of thermosetting rubber and thermoplastic polyvinyl chloride and its manufacturing method |
| CN106564251A (en) * | 2015-10-07 | 2017-04-19 | 厚生股份有限公司 | Washable antibacterial composite fabric and manufacturing method thereof |
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| HK1066762A1 (en) | 2005-04-01 |
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