CN1565724A - Cerium-titanium solid solution and its preparing method - Google Patents
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Abstract
本发明提供了一种CeTi2O6固溶体及其制备方法，其化学分子式为CeTi2O6，以硝酸铈和四氯化钛溶液的前驱体为原料、混合、滴加到浓氨水中，使其沉淀、陈化、离心洗涤、洗去Cl－，真空冷冻干燥、焙烧得CeO2－TiO2粉体，将CeO2－TiO2粉体分别以650、750和800℃焙烧，CeTi2O6的晶化完成。本发明工艺过程简单，特别适用于脱NOx和脱SOx催化剂的载体。The invention provides a CeTi 2 O 6 solid solution and a preparation method thereof. Its chemical molecular formula is CeTi 2 O 6 . The precursors of cerium nitrate and titanium tetrachloride solution are used as raw materials, mixed, and dropped into concentrated ammonia water to make Precipitation, aging, centrifugal washing, washing away Cl- , vacuum freeze-drying, and roasting to obtain CeO 2 -TiO 2 powder, roasting CeO 2 -TiO 2 powder at 650, 750 and 800 °C respectively, CeTi 2 O 6 crystallization is complete. The process of the invention is simple, and it is especially suitable for the carrier of deNOx and deSOx catalysts.
Description
技术领域technical field
本发明涉及一种与单一的CeO2相比具有更高的稳定性、氧化-还原性及良好的低温活性的CeTi2O6固溶体及其制备方法。The invention relates to a CeTi 2 O 6 solid solution with higher stability, oxidation-reduction performance and good low-temperature activity compared with single CeO 2 and a preparation method thereof.
背景技术Background technique
在含氮和含硫工业废气催化脱除的实际应用中，催化剂上的主要活性组分二氧化铈(CeO2)在温度高达750℃时易烧结。因而，在实际应用过程中往往需添加一些抗烧结的氧化物制成复合氧化物或固溶体(如CeO2-ZrO2)；在含CeO2-MOx的固溶体中，CeO2晶格中的部分Ce原子被其他阳离子取代后，会引起CeO2的晶格畸变和缺陷。因此，含CeO2-MOx的固溶体比单一的CeO2具有更高的稳定性、氧化-还原性及良好的低温活性。近年来，除CeO2-ZrO2外，人们对CeO2-SnO2、CeO2-TiO2和CeO2-NiO等体系的制备及表征做了大量的工作。In the practical application of catalytic removal of nitrogen-containing and sulfur-containing industrial waste gas, cerium oxide (CeO 2 ), the main active component on the catalyst, is easy to sinter when the temperature is as high as 750°C. Therefore, in the actual application process, it is often necessary to add some anti-sintering oxides to make composite oxides or solid solutions (such as CeO 2 -ZrO 2 ); in the solid solution containing CeO 2 -MOx, part of the Ce in the CeO 2 lattice After atoms are replaced by other cations, it will cause lattice distortion and defects of CeO2 . Therefore, the solid solution containing CeO 2 -MOx has higher stability, oxidation-reduction and good low-temperature activity than single CeO 2 . In recent years, in addition to CeO 2 -ZrO 2 , people have done a lot of work on the preparation and characterization of CeO 2 -SnO 2 , CeO 2 -TiO 2 and CeO 2 -NiO systems.
CeO2-TiO2的制备大多采用溶胶-凝胶法，用无机Ce盐和钛醇盐作为原料。由于Ce和Ti离子具有多种价态，因而制得的固溶体的价态及分子式也很复杂。CeTi2O6是目前唯一已知的Ce和Ti均以+4价存在的Ce-Ti固溶体。但多数研究得到的Ce-Ti固溶体中Ce为+3价，Ti为+4价。如：Preuss A.et al.，(J.Solid State Chem.，1994，110：363-369)研究得到了Ce2TiO5、Ce2Ti2O7和Ce4Ti9O24，即分别为：Ce2O3TiO2、Ce2O32TiO2和Ce2O34.5TiO2；Bamger E.etal.，(J.Alloys Comp.，1994，204：101-107)研究得到了Ce2Ti4O11，即Ce2O34TiO2；其中Ce和Ti是以+3和+4两种价态存在的。以上这些研究说明Ce-Ti可以组成很多种化合物，但反应条件和Ce-Ti的比例都会影响到最后的产物，这是一个很复杂的体系。The preparation of CeO 2 -TiO 2 mostly adopts sol-gel method, using inorganic Ce salt and titanium alkoxide as raw materials. Since Ce and Ti ions have multiple valence states, the valence states and molecular formulas of the obtained solid solutions are also very complicated. CeTi 2 O 6 is the only known Ce-Ti solid solution in which both Ce and Ti exist at +4 valence. However, in the Ce-Ti solid solution obtained by most studies, Ce has a valence of +3 and Ti has a valence of +4. For example: Preuss A.et al., (J.Solid State Chem., 1994, 110:363-369) obtained Ce 2 TiO 5 , Ce 2 Ti 2 O 7 and Ce 4 Ti 9 O 24 , which are respectively : Ce 2 O 3 TiO 2 , Ce 2 O 3 2TiO 2 and Ce 2 O 3 4.5TiO 2 ; 4 O 11 , namely Ce 2 O 3 4TiO 2 ; where Ce and Ti exist in two valence states of +3 and +4. The above studies show that Ce-Ti can form many kinds of compounds, but the reaction conditions and the ratio of Ce-Ti will affect the final product, which is a very complicated system.
Dauscher A.et.al.，(Catal.Lett.，1992，14：171-183)以有机钛醇盐和CeCl3·7H2O为前驱体，采用水解干燥法制备的Ti∶Ce＝1的Ce-Ti复合氧化物，发现在酸性介质中，形成了表面不确定的晶相，在450-500℃焙烧后，形成了无定形TiO2上覆盖CeO2的晶体；在碱性介质中形成了CeTiO3化合物，焙烧后转变成无定形结构，其最高比表面积为95m2/g。RynkowskiJ.et al.，(Appl.Catal.A：Gen.，2000，203：335-348)制备了Ce/Ti摩尔比为2∶8和5∶5的Ce-Ti复合氧化物，发现预处理条件不同，形成的化合物不同。Ce/Ti摩尔比为2∶8时，经600℃焙烧才开始晶化，800℃焙烧时出现了CeO2、TiO2相及未知的化合物；400℃焙烧的样品在800℃ H2还原之后，分别出现了Ce4Ti9O24相；700℃焙烧的样品经XRD检测出现了金红石的衍射峰；Ce/Ti摩尔比为5∶5时，焙烧温度低于400℃时，XRD检测只有CeO2相；焙烧温度高于600℃时，有未知化合物出现；400℃焙烧的样品经900℃H2还原出现了Ce2Ti2O7相。XPS检测显示表层中Ce含量高于体相中Ce含量；Ti/Ce摩尔比为8∶2时，表面层中Ti/Ce＝1.4-1.7；Ti/Ce摩尔比为5∶5时，表面层中Ti/Ce＝0.4-0.44，甚至0.28。Dauscher A.et.al., (Catal.Lett., 1992, 14: 171-183) used organic titanium alkoxide and CeCl 3 ·7H 2 O as precursors, and prepared Ti:Ce=1 by hydrolysis drying method Ce-Ti composite oxide, it is found that in acidic medium, an indeterminate crystal phase of the surface is formed, and after calcination at 450-500 ° C, crystals covering CeO 2 on amorphous TiO 2 are formed; The CeTiO 3 compound transforms into an amorphous structure after calcination, and its highest specific surface area is 95m 2 /g. RynkowskiJ.et al., (Appl.Catal.A: Gen., 2000, 203:335-348) prepared Ce-Ti composite oxides with Ce/Ti molar ratios of 2:8 and 5:5, and found that pretreatment Under different conditions, different compounds are formed. When the Ce/Ti molar ratio is 2:8, the crystallization begins after calcination at 600°C, and CeO 2 and TiO 2 phases and unknown compounds appear when calcination at 800°C; The Ce 4 Ti 9 O 24 phase appeared respectively; the samples calcined at 700°C showed rutile diffraction peaks by XRD; when the Ce/Ti molar ratio was 5:5, when the calcining temperature was lower than 400°C, only CeO 2 phase; when the calcination temperature is higher than 600℃, unknown compounds appeared; the sample calcined at 400℃ was reduced to Ce 2 Ti 2 O 7 phase by H 2 at 900℃. XPS detection shows that the Ce content in the surface layer is higher than that in the bulk phase; when the Ti/Ce molar ratio is 8:2, Ti/Ce=1.4-1.7 in the surface layer; when the Ti/Ce molar ratio is 5:5, the surface layer Middle Ti/Ce=0.4-0.44, even 0.28.
发明内容Contents of the invention
本发明的目的是提供一种化学分子式为CeTi2O6铈钛固溶体及其制备方法，制备所得的CeTi2O6固溶体与单一的CeO2相比具有更高的稳定性、氧化-还原性及良好的低温活性，特别适用于脱除NOx和脱SOx催化剂的载体。The object of the present invention is to provide a kind of chemical molecular formula is CeTi 2 O 6 cerium titanium solid solution and preparation method thereof, the prepared CeTi 2 O 6 solid solution has higher stability, oxidation-reduction and Good low-temperature activity, especially suitable for the carrier of NO x and SO x catalysts.
本发明提供的CeTi2O6固溶体，所述组分铈钛比为Ce＝x(x＝0.1-1.0)，Ti＝1-x(摩尔比)，通过考察Ce/Ti摩尔比x＝0.-1.0的变化，发现Ce∶Ti＝0.3∶0.7(摩尔比)是一较好的组成。The CeTi 2 O 6 solid solution provided by the present invention, said component cerium-titanium ratio is Ce=x (x=0.1-1.0), Ti=1-x (molar ratio), by examining Ce/Ti molar ratio x=0. -1.0 variation, Ce:Ti=0.3:0.7 (molar ratio) was found to be a better composition.
本发明提供的一种CeTi2O6固溶体及其制备方法是以硝酸铈(Ce(NO3)3·6H2O)和四氯化碳(TiCl4)溶液的前驱体为原料，以合适的配比均匀混合(CexTi1-xO2，其中x＝0.1-1.0)，以60滴/分钟的滴加速度将铈钛原料液滴加到浓氨水中，同时快速搅拌，使其沉淀完全(pH值＝10.0-11.0)，室温陈化24h，离心洗涤，洗去Cl-(用硝酸银溶液检验无Cl-存在)，真空冷冻干燥12-14h(干燥时间视粉体的干燥情况而定)，置于50℃的烘箱中干燥24h，转入马弗炉中500℃焙烧2h，得CeO2-TiO2粉体。将CeO2-TiO2粉体分别以650、750和800℃焙烧2h。A CeTi 2 O 6 solid solution provided by the present invention and its preparation method are based on the precursor of cerium nitrate (Ce(NO 3 ) 3 6H 2 O) and carbon tetrachloride (TiCl 4 ) solution as raw materials, and a suitable Mix evenly ( Cex Ti 1-x O 2 , where x=0.1-1.0), add the cerium-titanium raw material dropwise to the concentrated ammonia water at a rate of 60 drops/min, and stir rapidly at the same time to make the precipitation complete (pH value = 10.0-11.0), aging at room temperature for 24 hours, centrifugal washing, washing away Cl - (use silver nitrate solution to check that no Cl - exists), vacuum freeze drying for 12-14 hours (drying time depends on the drying condition of the powder) ), dried in an oven at 50°C for 24h, and transferred to a muffle furnace for calcination at 500°C for 2h to obtain CeO 2 -TiO 2 powder. The CeO 2 -TiO 2 powders were fired at 650, 750 and 800°C for 2h, respectively.
CeO2-TiO2粉体经650℃焙烧2h后，当x＝0.1时，XRD能检测到CeTi2O6相和少量的金红石相；x＝0.2时，仍有隐约可见的CeTi2O6相和金红石相；x＝0.3时，主要以无定形状态存在；x＝0.4-1.0时，则为单一的CeO2相；CeO2-TiO2粉体经750℃焙烧2h后，CeTi2O6已大部分晶化；当焙烧温度达到800℃时，CeTi2O6的晶化过程已趋于完成。After the CeO 2 -TiO 2 powder is calcined at 650℃ for 2 hours, when x=0.1, XRD can detect CeTi 2 O 6 phase and a small amount of rutile phase; when x=0.2, there is still faintly visible CeTi 2 O 6 phase and rutile phase; when x=0.3, it mainly exists in an amorphous state; when x=0.4-1.0, it is a single CeO 2 phase; after the CeO 2 -TiO 2 powder is roasted at 750°C for 2 hours, CeTi 2 O 6 has Most of them are crystallized; when the calcination temperature reaches 800℃, the crystallization process of CeTi 2 O 6 tends to be completed.
本发明工艺过程简单，但每一步需经严格控制，制备所得的Ce0.3Ti0.7O2复合氧化物经氮气的吸-脱附实验发现其比表面积在不同温度焙烧的条件下分别为207.37m2/g(500℃焙烧2h)；58.78m2/g(650℃焙烧2h)；50.26m2/g(750℃焙烧2h)和44.66m2/g(800℃焙烧2h)。且该吸-脱附等温线类型属于BDDT分类中的第VI类，孔径分布属介孔结构材料。XRD测定结果显示在2θ 25.9°、26.7°和27.4°处能检测到CeTi2O6固溶体的特征衍射峰。XPS测定结果显示Ce3d3/2为882.86(eV)，Ti2P3/2为458.7(eV)，Ols lattice为529.5(eV)，Ce/Ti＝1.248，u/Itotal＝0.269(Ce4+/Ce3+的比值决定了u的强度与总强度Itotal的比值。Ce3+增多时u/I total比值下降，u’+v’/Itotal值上升)。在Ce0.3Ti0.7O2复合氧化物中，Ce3+占表面Ce总量的17.8％。制得的固溶体比表面积也较大(800℃焙烧2h后其比表面积为44.66m2/g)，The process of the present invention is simple, but each step needs to be strictly controlled, and the prepared Ce 0.3 Ti 0.7 O 2 composite oxide is found to have a specific surface area of 207.37m 2 under the conditions of roasting at different temperatures through nitrogen adsorption-desorption experiments /g (calcined at 500°C for 2h); 58.78m 2 /g (calcined at 650°C for 2h); 50.26m 2 /g (calcined at 750°C for 2h) and 44.66m 2 /g (calcined at 800°C for 2h). And the adsorption-desorption isotherm type belongs to the VI category in the BDDT classification, and the pore size distribution belongs to the mesoporous structure material. The XRD results show that the characteristic diffraction peaks of CeTi 2 O 6 solid solution can be detected at 2θ 25.9°, 26.7° and 27.4°. XPS measurement results show that Ce 3d3/2 is 882.86 (eV), Ti 2P3/2 is 458.7 (eV), O ls lattice is 529.5 (eV), Ce/Ti=1.248, u/I total ＝0.269 (Ce 4+ The ratio of /Ce 3+ determines the ratio of the intensity of u to the total intensity I total . When Ce 3+ increases, the ratio of u/I total decreases, and the value of u'+v'/I total increases). In the Ce 0.3 Ti 0.7 O 2 composite oxide, Ce 3+ accounts for 17.8% of the total surface Ce. The specific surface area of the prepared solid solution is also large (the specific surface area is 44.66m 2 /g after calcination at 800°C for 2 hours),
具体实施方式Detailed ways
实施例1：Example 1:
CeTi2O6固溶体及其制备方法，其步骤为：CeTi 2 O 6 solid solution and preparation method thereof, the steps are:
(1)CeTi2O6固溶体，其化学分子式为CeTi2O6。它是以硝酸铈(Ce(NO3)3·6H2O)和四氯化钛(TiCl4)溶液的前驱体为原料，以合适的配比均匀混合(CexTi1-xO2，其中x＝0.1-1.0)，再按Ce∶Ti的比例，Ce＝x(x＝0.3)，Ti＝1-x(0.7)的摩尔比计算及量取相应的硝酸铈(Ce(NO3)3·6H2O)和四氯化碳(TiCl4)量，使其均匀混合。(1) CeTi 2 O 6 solid solution, its chemical formula is CeTi 2 O 6 . It is based on the precursor of cerium nitrate (Ce(NO 3 ) 3 6H 2 O) and titanium tetrachloride (TiCl 4 ) solution as raw materials, uniformly mixed in a suitable ratio ( Cex Ti 1-x O 2 , where x=0.1-1.0), then according to the ratio of Ce:Ti, Ce=x(x=0.3), Ti=1-x(0.7) molar ratio to calculate and measure the corresponding cerium nitrate (Ce(NO 3 ) 3 ·6H 2 O) and carbon tetrachloride (TiCl 4 ) to mix them evenly.
(2)在250ml烧杯中加入40ml浓氨水，然后将上述混合均匀的铈钛原料液转入分液漏斗中，以一定的速度将铈钛原料液滴加到浓氨水中，同时快速搅拌，使其沉淀完全(pH值＝10.0-11.0)，室温陈化24h，离心洗涤，洗去Cl-(用硝酸银溶液检验无Cl-存在)，用真空冷冻干燥12-14h(干燥时间视粉体的干燥情况而定)，再置于50℃的烘箱中干燥24h，转入马弗炉中500℃焙烧2h，得CeO2-TiO2粉体。将CeO2-TiO2粉体分别以650、750和800℃焙烧2h。(2) Add 40ml of concentrated ammonia water into a 250ml beaker, then transfer the uniformly mixed cerium-titanium raw material solution into a separatory funnel, drop the cerium-titanium raw material solution into the concentrated ammonia water at a certain speed, and stir rapidly at the same time to make Its precipitation is complete (pH value = 10.0-11.0), aged at room temperature for 24 hours, centrifuged and washed to remove Cl - (check that there is no Cl - with silver nitrate solution), and vacuum freeze-dry for 12-14 hours (drying time depends on the size of the powder) (depending on the drying conditions), and then dried in an oven at 50°C for 24 hours, and transferred to a muffle furnace for calcination at 500°C for 2 hours to obtain CeO 2 -TiO 2 powder. The CeO 2 -TiO 2 powders were fired at 650, 750 and 800°C for 2h, respectively.
(3)CeO2-TiO2粉体经650℃焙烧2h后，当x＝0.1时，XRD能检测到CeTi2O6相和少量的金红石相；x＝0.2时，仍有隐约可见的CeTi2O6相和金红石相；x＝0.3时，主要以无定形状态存在；x＝0.4-1.0时，则为单一的CeO2相；CeO2-TiO2粉体经750℃焙烧2h后，CeTi2O6已大部分晶化；当焙烧温度达到800℃时，CeTi2O6的晶化过程已趋于完成。(3) After CeO 2 -TiO 2 powder is calcined at 650℃ for 2 hours, when x=0.1, XRD can detect CeTi 2 O 6 phase and a small amount of rutile phase; when x=0.2, CeTi 2 is still faintly visible O 6 phase and rutile phase; when x=0.3, it mainly exists in an amorphous state; when x=0.4-1.0, it is a single CeO 2 phase; after CeO 2 -TiO 2 powder is calcined at 750℃ for 2 hours, CeTi 2 Most of O 6 has been crystallized; when the calcination temperature reaches 800℃, the crystallization process of CeTi 2 O 6 tends to be completed.
实施例2：Example 2:
(1)CeTi2O6固溶体，其化学分子式为CeTi2O6。它是以硝酸铈(Ce(NO3)3·6H2O)和四氯化钛(TiCl4)溶液的前驱体为原料，以合适的配比均匀混合(CexTi1-xO2，其中x＝0.1-1.0)，再按Ce∶Ti的比例，Ce＝x(x＝0.3)，Ti＝1-x(0.7)的摩尔比计算及量取浓度为0.5mol/L的硝酸铈(Ce(NO3)3·6H2O)溶液30ml，及浓度为0.333mol/L的四氯化碳(TiCl4)溶液105ml，使其均匀混合。(1) CeTi 2 O 6 solid solution, its chemical formula is CeTi 2 O 6 . It is based on the precursor of cerium nitrate (Ce(NO 3 ) 3 6H 2 O) and titanium tetrachloride (TiCl 4 ) solution as raw materials, uniformly mixed in a suitable ratio ( Cex Ti 1-x O 2 , Wherein x=0.1-1.0), then by the ratio of Ce: Ti, Ce=x (x=0.3), the molar ratio calculation of Ti=1-x (0.7) and measuring concentration are the cerium nitrate ( 30 ml of Ce(NO 3 ) 3 ·6H 2 O) solution and 105 ml of carbon tetrachloride (TiCl 4 ) solution with a concentration of 0.333 mol/L were uniformly mixed.
(2)在250ml烧杯中加入40ml浓氨水，然后将上述混合均匀的铈钛原料液转入分液漏斗中，以60滴/分钟的滴加速度将铈钛原料液滴加到浓氨水中，同时快速搅拌，使其沉淀完全(pH值＝10.0-11.0)，室温陈化24h，离心洗涤，洗去Cl-(用硝酸银溶液检验无Cl-存在)，用真空冷冻干燥12-14h(干燥时间视粉体的干燥情况而定)，再置于50℃的烘箱中干燥24h，转入马弗炉中500℃焙烧2h，得CeO2-TiO2粉体。将CeO2-TiO2粉体分别以650、750和800℃焙烧2h。(2) Add 40ml of concentrated ammonia water in a 250ml beaker, then transfer the above-mentioned homogeneously mixed cerium-titanium raw material solution into a separatory funnel, add the cerium-titanium raw material solution dropwise to the concentrated ammoniacal water at a rate of 60 drops/min, and simultaneously Stir rapidly to make the precipitation complete (pH value = 10.0-11.0), age at room temperature for 24 hours, centrifuge and wash, wash away Cl - (use silver nitrate solution to check that there is no Cl - present), and freeze-dry in vacuum for 12-14 hours (drying time (depending on the drying condition of the powder), then place it in an oven at 50°C for 24 hours, and transfer it to a muffle furnace for calcination at 500°C for 2 hours to obtain CeO 2 -TiO 2 powder. The CeO 2 -TiO 2 powders were fired at 650, 750 and 800°C for 2h, respectively.
(3)CeO2-TiO2粉体经650℃焙烧2h后，当x＝0.1时，XRD能检测到CeTi2O6相和少量的金红石相；x＝0.2时，仍有隐约可见的CeTi2O6相和金红石相；x＝0.3时，主要以无定形状态存在；x＝0.-1.0时，则为单一的CeO2相；CeO2-TiO2粉体经750℃焙烧2h后，CeTi2O6已大部分晶化；当焙烧温度达到800℃时，CeTi2O6的晶化过程已趋于完成。(3) After CeO 2 -TiO 2 powder is calcined at 650℃ for 2 hours, when x=0.1, XRD can detect CeTi 2 O 6 phase and a small amount of rutile phase; when x=0.2, CeTi 2 is still faintly visible O 6 phase and rutile phase; when x=0.3, it mainly exists in an amorphous state; when x=0.-1.0, it is a single CeO 2 phase; after CeO 2 -TiO 2 powder is calcined at 750°C for 2 hours, CeTi Most of the 2 O 6 has been crystallized; when the calcination temperature reaches 800℃, the crystallization process of CeTi 2 O 6 has tended to be completed.
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Cited By (9)
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| WO2007093837A1 (en) * | 2006-02-13 | 2007-08-23 | Council Of Scientific And Industrial Research | Monoclinic ceti2o6 thin film and a sol-gel process for the preparation thereof |
| CN101543775B (en) * | 2008-03-28 | 2011-07-20 | 中国科学院大连化学物理研究所 | A VOx/CeO2/TiO2 composite oxide and its preparation and application |
| CN102527386A (en) * | 2010-12-16 | 2012-07-04 | 株式会社丰田中央研究所 | Co oxidation catalyst and waste gas purification method employing the same |
| CN105688888A (en) * | 2016-01-14 | 2016-06-22 | 济南大学 | High-performance vanadium, cerium and titanium composite oxide catalyst for flue gas denitration and preparation method thereof |
| CN105727926A (en) * | 2016-03-21 | 2016-07-06 | 济南大学 | High-performance cerium titanium loaded zirconium oxide catalyst for flue gas denitrification and preparation method thereof |
| CN105771955A (en) * | 2016-04-14 | 2016-07-20 | 江门市科恒实业股份有限公司 | Preparation method of ceria-zirconia solid solution |
| WO2019096335A1 (en) * | 2017-11-20 | 2019-05-23 | 首凯汽车零部件（江苏）有限公司 | Composite thermistor material, and preparation method therefor and application thereof |
| CN111215085A (en) * | 2018-11-23 | 2020-06-02 | 中国科学院大连化学物理研究所 | Two-step solar thermochemical energy storage non-noble metal catalyst and preparation and application thereof |
| CN113264694A (en) * | 2021-06-11 | 2021-08-17 | 杭州杭钢三江矿业有限公司 | Environment-friendly and energy-saving lime sintering process |
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2003
- 2003-07-08 CN CN 03141571 patent/CN1246078C/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2007093837A1 (en) * | 2006-02-13 | 2007-08-23 | Council Of Scientific And Industrial Research | Monoclinic ceti2o6 thin film and a sol-gel process for the preparation thereof |
| JP2009526724A (en) * | 2006-02-13 | 2009-07-23 | カウンシル・オブ・サイエンティフィック・アンド・インダストリアル・リサーチ | Monoclinic CeTi2O6 thin film and manufacturing method thereof by sol-gel method |
| ES2327205A1 (en) * | 2006-02-13 | 2009-10-26 | Council Of Scientific And Industrial Research | Monoclinic ceti2o6 thin film and a sol-gel process for the preparation thereof |
| ES2327205B1 (en) * | 2006-02-13 | 2010-07-23 | Council Of Scientific And Industrial Research | FINE FILM OF CETI206 MONOCLINICO AND A SOL-GEL PROCESS FOR PREPARATION. |
| CN101400822B (en) * | 2006-02-13 | 2011-06-01 | 科学工业研究委员会 | Monoclinic CeTi2O6 thin film and the sol-gel method used to prepare the monoclinic CeTi2O6 thin film |
| CN101543775B (en) * | 2008-03-28 | 2011-07-20 | 中国科学院大连化学物理研究所 | A VOx/CeO2/TiO2 composite oxide and its preparation and application |
| CN102527386A (en) * | 2010-12-16 | 2012-07-04 | 株式会社丰田中央研究所 | Co oxidation catalyst and waste gas purification method employing the same |
| CN102527386B (en) * | 2010-12-16 | 2015-03-11 | 株式会社丰田中央研究所 | Co oxidation catalyst and waste gas purification method employing the same |
| CN105688888A (en) * | 2016-01-14 | 2016-06-22 | 济南大学 | High-performance vanadium, cerium and titanium composite oxide catalyst for flue gas denitration and preparation method thereof |
| CN105727926A (en) * | 2016-03-21 | 2016-07-06 | 济南大学 | High-performance cerium titanium loaded zirconium oxide catalyst for flue gas denitrification and preparation method thereof |
| CN105771955A (en) * | 2016-04-14 | 2016-07-20 | 江门市科恒实业股份有限公司 | Preparation method of ceria-zirconia solid solution |
| WO2019096335A1 (en) * | 2017-11-20 | 2019-05-23 | 首凯汽车零部件（江苏）有限公司 | Composite thermistor material, and preparation method therefor and application thereof |
| GB2582185A (en) * | 2017-11-20 | 2020-09-16 | Sook Automotive Components (Jiangsu) Co Ltd | Composite thermistor material, and preparation method therefor and application thereof |
| GB2582185B (en) * | 2017-11-20 | 2021-03-24 | Sook Automotive Components Jiangsu Co Ltd | High Temperature Negative Temperature Coefficient Thermistor Material and Preparation Method Thereof |
| CN111215085A (en) * | 2018-11-23 | 2020-06-02 | 中国科学院大连化学物理研究所 | Two-step solar thermochemical energy storage non-noble metal catalyst and preparation and application thereof |
| CN111215085B (en) * | 2018-11-23 | 2023-02-03 | 中国科学院大连化学物理研究所 | Two-step solar thermochemical energy storage non-noble metal catalyst and its preparation and application |
| CN113264694A (en) * | 2021-06-11 | 2021-08-17 | 杭州杭钢三江矿业有限公司 | Environment-friendly and energy-saving lime sintering process |
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