CN1560158A - Water silicon bubber emulsion for coating glass fibre cloth - Google Patents
Water silicon bubber emulsion for coating glass fibre cloth Download PDFInfo
- Publication number
- CN1560158A CN1560158A CNA2004100141472A CN200410014147A CN1560158A CN 1560158 A CN1560158 A CN 1560158A CN A2004100141472 A CNA2004100141472 A CN A2004100141472A CN 200410014147 A CN200410014147 A CN 200410014147A CN 1560158 A CN1560158 A CN 1560158A
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- CN
- China
- Prior art keywords
- silicon rubber
- glass fiber
- agent
- water
- coated glass
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003365 glass fiber Substances 0.000 title claims abstract description 17
- 239000000839 emulsion Substances 0.000 title claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 21
- 239000004744 fabric Substances 0.000 title claims description 16
- 239000011248 coating agent Substances 0.000 title abstract description 15
- 238000000576 coating method Methods 0.000 title abstract description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title 1
- 229910052710 silicon Inorganic materials 0.000 title 1
- 239000010703 silicon Substances 0.000 title 1
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 48
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- -1 polysiloxane silicon Polymers 0.000 claims abstract description 13
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 12
- 229920001971 elastomer Polymers 0.000 claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 4
- 239000003960 organic solvent Substances 0.000 claims abstract description 4
- 239000002270 dispersing agent Substances 0.000 claims abstract description 3
- 239000000945 filler Substances 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 239000004945 silicone rubber Substances 0.000 claims description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- HIHIPCDUFKZOSL-UHFFFAOYSA-N ethenyl(methyl)silicon Chemical compound C[Si]C=C HIHIPCDUFKZOSL-UHFFFAOYSA-N 0.000 claims description 4
- NOKUWSXLHXMAOM-UHFFFAOYSA-N hydroxy(phenyl)silicon Chemical compound O[Si]C1=CC=CC=C1 NOKUWSXLHXMAOM-UHFFFAOYSA-N 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 239000004848 polyfunctional curative Substances 0.000 claims description 2
- 229920000126 latex Polymers 0.000 abstract description 5
- 239000004816 latex Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- 239000007822 coupling agent Substances 0.000 abstract description 2
- 239000008235 industrial water Substances 0.000 abstract 2
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000009775 high-speed stirring Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 239000012454 non-polar solvent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- JCYPECIVGRXBMO-UHFFFAOYSA-N 4-(dimethylamino)azobenzene Chemical compound C1=CC(N(C)C)=CC=C1N=NC1=CC=CC=C1 JCYPECIVGRXBMO-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention is a water-borne silicon rubber latex for coating glass fiber cloths, relating the composition of water-borne silicon rubber latex and especially relating to that of the water-borne silicon rubber latex for coating glass fiber cloths. It includes linear polysiloxane silicon rubber, molecular weight 500,000-800,000, nonionic surfactant, nonionic soaking dispersing agent and organic solvent gasoline, and its characteristic: it is also added with silence coupling agent, curing agent, gas-phase white carbon as fillings and industrial water. By weight percent, silicon rubber 8-10%, emulsifying agent 1-3, dispersing agen 1-2%, gasoline 20-26%, silane coupling agent 1-2%, curing agent 2-5%, fillings 3-6% and industrial water 46-64%. The made latex has strong adhesion to the glass fiber cloths, thick coating, and high strength. It eliminates hidden trouble in production safety and reduces the pollution to the around environment and has good economic and social benefits.
Description
Technical field
Coated glass fiber cloth use silicon rubber emulsion relates to the composition of water silicon rubber emulsion, relates in particular to the composition of coated glass fiber cloth with the silicon rubber emulsion.
Background technology
The silicon rubber emulsion is one of coating material of glasscloth.Glasscloth coating silicon rubber goods have good use properties, and for example its heatproof, resistance to chemical attack, breaking tenacity, tear strength are high, now extensively apply to building, and the electric insulation pipeline flexible connects, fields such as chemical anticorrosion and sealing.
The silicon rubber molecule is to form major key with-Si-O-key, and this bond dissociation energy is very big.Traditional silicon rubber emulsion is formulated with the non-polar solvent dissolving.These non-polar solvent great majority are poisonous, inflammable substance.Gasoline for example, toluene, dimethylbenzene, vinyl acetate etc., contaminate environment not only influences the healthy of operating worker, but also has dangerous production hidden danger in actual use.
A kind of preparation of water silicon rubber emulsion is disclosed in the CN1053619 patent, but its emulsion solid content is lower, coating is thin, intensity is low, only be applicable to the coating of paper glazing and thin-film material, be not suitable for coated glass fiber cloth, the subject matter of existence be the silicon rubber emulsion coating to the glasscloth poor adhesive force, breaking tenacity is low.
Summary of the invention
The objective of the invention is to: at the characteristic of glasscloth, a kind of prescription of coated glass fiber cloth use silicon rubber emulsion is proposed, it mainly is that solvent makes with water, can reduce the pollution to surrounding environment greatly, and improves performances such as the sticking power of coated glass fiber cloth and intensity simultaneously.
Technical solution of the present invention is as follows: it comprises that molecular weight is the linear polysiloxane silicon rubber of 50-80 ten thousand, nonionic surface active agent, non-ionic type infiltrative type dispersion agent and organic solvent gasoline, it is characterized in that: it also is added with silane coupling agent, solidifying agent, gas-phase silica is filler and service water, calculate by weight percentage, the silicon rubber consumption is 8-10%, the emulsifying agent consumption is 1-3%, dispersant dosage is 1-2%, the gasoline consumption is 20-26%, the silane coupling agent consumption is 1-2%, hardener dose is 2-5%, amount of filler is 3-6%, and the service water consumption is 46-64%.
Silane coupling agent contains alpha-functional group, and it mainly acts on is that silicon rubber can be combined with base cloth better, and it can form covalent linkage with the reaction of fiberglass surfacing silanol groups.Simultaneously form hydrogen bond between coupling agent and the fiberglass surfacing, under the situation that has water to exist, when the inflexible polymkeric substance was done relative movement, the bonded hydrogen bond was promptly destroyed, and newly formed hydrogen bond with contiguous OH basic weight again simultaneously at once.The prestress that the interface exists that so both relaxed is not given birth to sticking simultaneously again.Alpha-functional group also has the solidification value that reduces coating, increases the resistance to elevated temperatures of coating, increases the intensity of coating and the ability that the high temperature resistance high velocity air washes away, and the corrosion-resistanting waterproofing performance of raising coating etc.
The described solidifying agent of this patent is one of following material: 1) organo-peroxide; 2) family's azo-compound.Wherein commonly used is organo-peroxide.When silicon rubber solidified with organo-peroxide, superoxide was undertaken by free radical reaction between two activatory methyl or vinyl the curing of silicon rubber.
The adding of described gas-phase silica filler has reinforcing effect to silicon rubber.Used gas-phase silica finer particles, its specific surface area is big more, and then reinforcing effect is good more, but processing property is just poor more.Otherwise the thicker specific surface areas of its particle are also little, and reinforcing effect is just poor, but processing property will be quite a lot of.It mainly is because 1. rubber are adsorbed by filler grain that white carbon black has reinforcing effect to silicon rubber, and filler grain adsorpting polymerization thing makes the rubber molecule segment directly be fixed near the of filler grain or directed or be detained by the filler aggregate along filling surface.2. rubber combines with filler grain, and filler grain combines with polymer segment and produces effectively the crosslinked and polymkeric substance filler grain that tangled.In addition, gas-phase silica also has thickening power, and gas-phase silica is with after water contacts, and the variation of concentration just takes place its surface hydroxyl, and it is constant wherein to isolate hydroxyl, and adjacent hydroxyl can increase gradually.This is because white carbon black has the Si-O-Si key, and these keys can absorb water to open and form more adjacent hydroxyl.
The consumption of used service water is up to 46-64%, and water is innoxious solvent.
Described molecular weight is that the linear polysiloxane silicon rubber of 50-80 ten thousand is one of following material: 1) dimethyl silicone rubber; 2) methyl vinyl silicone rubber; 3) phenyl siloxane rubber.
Described nonionic surface active agent is an alkylphenol polyoxyethylene, and the HLB value is between 8-15.The HLB value of tensio-active agent directly influences the character and the application of water-soluble silicon rubber latex.Practice and the tensio-active agent effect of theoretical proof HLB value between 8-15 relatively are fit to oil-in-water emulsifiers.
It is C that described non-ionic type soaks into dispersion agent
12-18The high fatty alcohol Soxylat A 25-7.This class surface type agent alive mainly is to be used to reduce surface tension and to improve wetting agent.
The coated glass fiber cloth use silicon rubber emulsion that adopts the present invention program to make, equipment is simple, and is easy to make, the emulsifying power height.This silicon rubber emulsion is to the glasscloth strong adhesion, thick coating, intensity height.Owing to use a large amount of water to be solvent; only use a spot of organic solvent,, both improved workman's labour protection condition so significantly reduced toxic and harmful; eliminated production safety hidden danger and alleviated pollution again, had good economic benefit and a social benefit surrounding environment.
Embodiment
Embodiment 1:
Component consumption (weight)
Methyl vinyl silicone rubber 9%
120# gasoline 24%
Alkylphenol polyoxyethylene 2%
Benzoyl peroxide 3%
Gas-phase silica 3%
Fatty alcohol-polyoxyethylene ether (C
12-15) 1.5%
Silane coupling agent 1.5%
Service water 56%
Example 1 compound method is as follows:
1) the mixing methyl vinyl silicone rubber GF-141 of commercially available solid is cut into bulk, size joins 24Kg120# gasoline then for 1cm * 1cm * 1cm 9Kg that weighs puts into container, carries out obtaining oil-soluble organo-silicone rubber after the high-speed stirring with high speed agitator.
2) the molten type silicon rubber of oil was left standstill 10 minutes, in this container, add 2Kg alkylphenol polyoxyethylene OP-10,3Kg benzoyl peroxide, 3Kg gas-phase silica A-200,1.5kg fatty alcohol-polyoxyethylene ether AEO-9,1.5Kg silane coupling agent Nanjing University-42 then according to this, carried out stirring at low speed 0.5-1 hour with agitator.
3) add 56Kg service water restir at last and made silicon rubber emulsion stable, even, oil-in-water-type in 30 minutes.
Embodiment 2:
Component consumption (weight)
Dimethyl silicone rubber 8%
120# gasoline 22%
Alkylphenol polyoxyethylene 2%
4-dimethylaminoazobenzene 3%
Gas-phase silica 4%
Fatty alcohol-polyoxyethylene ether (C
12-15) 1.5%
Silane coupling agent 1.5%
Service water 58%
Example 2 compound methods are as follows:
1) the mixing dimethyl silicone rubber 201 of commercially available solid is cut into bulk, size joins 22Kg120# gasoline then for 1cm * 1cm * 1cm 8Kg that weighs puts into container, carries out obtaining oil-soluble organo-silicone rubber after the high-speed stirring with high speed agitator.
2) the molten type silicon rubber of oil was left standstill 10 minutes, in this container, add 2Kg alkylphenol polyoxyethylene OP-10,3Kg4-dimethylaminoazobenzene, 4Kg gas-phase silica A--200,1.5kg fatty alcohol-polyoxyethylene ether AEO-9,1.5Kg silane coupling agent Nanjing University-42 then according to this, carried out stirring at low speed 0.5-1 hour with agitator.
3) add 58Kg service water restir at last and made silicon rubber emulsion stable, even, oil-in-water-type in 30 minutes.
Embodiment 3:
Component consumption (weight)
Phenyl siloxane rubber 10%
120# gasoline 26%
Alkylphenol polyoxyethylene 3%
Organo-peroxide 5%
Gas-phase silica 5%
Fatty alcohol-polyoxyethylene ether 2%
Silane coupling agent 2%
Service water 47%
Example 3 compound methods are as follows:
1) the mixing phenyl siloxane rubber 120--1 of commercially available solid is cut into bulk, size joins 26Kg120# gasoline then for 1cm * 1cm * 1cm 10Kg that weighs puts into container, carries out obtaining oil-soluble organo-silicone rubber after the high-speed stirring with high speed agitator.
2) the molten type silicon rubber of oil was left standstill 10 minutes, in this container, add 2Kg alkylphenol polyoxyethylene OP-10,5Kg benzoyl peroxide, 5Kg gas-phase silica A-200,2kg fatty alcohol-polyoxyethylene ether AEO-9,2Kg silane coupling agent Nanjing University-42 then according to this, carried out stirring at low speed 0.5-1 hour with agitator.
3) add 47Kg service water restir at last and made silicon rubber emulsion stable, even, oil-in-water-type in 30 minutes.
Emulsion coating thickness with above-mentioned preparation is that the prepared silica gel cloth performance of 0.23mm glasscloth is as follows:
| Sequence number | Project | Assay | Standard value |
| ????1 | Use temperature (℃) | ????-70-250 | ??…… |
| ????2 | Thickness (mm) | ????0.30 | ??0.32±0.03 |
| ????3 | Mass area ratio (g/m 2) | ????408 | ??440±40 |
| ????4 | Warp-wise ultimate strength (N/25mm) | ????957 | ??≥900 |
| ????5 | Broadwise ultimate strength (N/25mm) | ????810 | ??≥700 |
| ????6 | Width (cm) | ????101.3 | ??100-103 |
| ????7 | Combustible content (%) | ????43.5 | ??≥30 |
| ????8 | Piecing strength (N/25mm) | ????786 | ??--- |
| ????9 | Warp-wise is torn brute force (N/60mm) | ????89 | ??--- |
| ????10 | Broadwise is torn brute force (N/60mm) | ????97 | ??--- |
Claims (6)
1. coated glass fiber cloth use silicon rubber emulsion, it comprises that molecular weight is the linear polysiloxane silicon rubber of 50-80 ten thousand, nonionic surface active agent, non-ionic type infiltrative type dispersion agent and organic solvent gasoline, it is characterized in that: it also is added with silane coupling agent, solidifying agent, filler and service water, calculate by weight percentage, the silicon rubber consumption is 8-10%, the emulsifying agent consumption is 1-3%, dispersant dosage is 1-2%, the gasoline consumption is 20-26%, the silane coupling agent consumption is 1-2%, hardener dose is 2-5%, and amount of filler is 3-6%, and the service water consumption is 46-64%.
2. coated glass fiber cloth use silicon rubber emulsion according to claim 1 is characterized in that described solidifying agent is one of following material: 1) organo-peroxide; 2) family's azo-compound.
3. coated glass fiber cloth use silicon rubber emulsion according to claim 1, it is characterized in that: described filler is a gas-phase silica, its granularity is 7nm-12nm.
4. coated glass fiber cloth use silicon rubber emulsion according to claim 1 is characterized in that: described molecular weight is that the linear polysiloxane silicon rubber of 50-80 ten thousand is one of following material: 1) dimethyl silicone rubber; 2) methyl vinyl silicone rubber; 3) phenyl siloxane rubber.
5. coated glass fiber cloth use silicon rubber emulsion according to claim 1, it is characterized in that: described nonionic surface active agent is an alkylphenol polyoxyethylene, and the HLB value is between 8-15.
6. coated glass fiber cloth use silicon rubber emulsion according to claim 1 is characterized in that: it is C that described non-ionic type soaks into dispersion agent
12-15The high fatty alcohol Soxylat A 25-7.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2004100141472A CN1560158A (en) | 2004-02-24 | 2004-02-24 | Water silicon bubber emulsion for coating glass fibre cloth |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2004100141472A CN1560158A (en) | 2004-02-24 | 2004-02-24 | Water silicon bubber emulsion for coating glass fibre cloth |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1560158A true CN1560158A (en) | 2005-01-05 |
Family
ID=34440219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2004100141472A Pending CN1560158A (en) | 2004-02-24 | 2004-02-24 | Water silicon bubber emulsion for coating glass fibre cloth |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1560158A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605620A (en) * | 2012-03-09 | 2012-07-25 | 南京彤天科技实业有限责任公司 | Method for preparing film material by coating polyvinylidene fluoride on glass fiber cloth |
| CN103570255A (en) * | 2012-08-07 | 2014-02-12 | 重庆国际复合材料有限公司 | Glass fiber infiltrating agent composition as well as preparation method and application thereof |
| CN106881778A (en) * | 2017-03-21 | 2017-06-23 | 常州龙途新材料科技有限公司 | A kind of preparation method of continuous glass-fiber rubber prepreg |
| CN109021581A (en) * | 2018-07-16 | 2018-12-18 | 江苏省苏安能节能建材科技有限公司 | A kind of Water-based silicone rubber can porcelain flexible clay facing tile and its preparation and application |
| CN110098371A (en) * | 2018-01-29 | 2019-08-06 | 株式会社Lg化学 | Secondary battery and top insulator for secondary battery |
| CN110870091A (en) * | 2018-01-29 | 2020-03-06 | 株式会社Lg化学 | Top insulator for secondary battery and method of making the same |
| CN110862555A (en) * | 2019-12-03 | 2020-03-06 | 中国化工株洲橡胶研究设计院有限公司 | High-temperature silicone rubber emulsion and preparation method and application thereof |
| KR20200142069A (en) * | 2018-04-16 | 2020-12-21 | 써튼티드 엘엘씨 | Silicone coated mineral wool insulation and its manufacturing and use method |
-
2004
- 2004-02-24 CN CNA2004100141472A patent/CN1560158A/en active Pending
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102605620A (en) * | 2012-03-09 | 2012-07-25 | 南京彤天科技实业有限责任公司 | Method for preparing film material by coating polyvinylidene fluoride on glass fiber cloth |
| CN103570255A (en) * | 2012-08-07 | 2014-02-12 | 重庆国际复合材料有限公司 | Glass fiber infiltrating agent composition as well as preparation method and application thereof |
| CN103570255B (en) * | 2012-08-07 | 2016-08-10 | 重庆国际复合材料有限公司 | A kind of glass fiber infiltration agent composition, preparation method and application |
| CN106881778A (en) * | 2017-03-21 | 2017-06-23 | 常州龙途新材料科技有限公司 | A kind of preparation method of continuous glass-fiber rubber prepreg |
| EP3644392A4 (en) * | 2018-01-29 | 2020-11-25 | Lg Chem, Ltd. | BATTERY AND INSULATION PLATE FOR BATTERY |
| CN110098371A (en) * | 2018-01-29 | 2019-08-06 | 株式会社Lg化学 | Secondary battery and top insulator for secondary battery |
| CN110870091A (en) * | 2018-01-29 | 2020-03-06 | 株式会社Lg化学 | Top insulator for secondary battery and method of making the same |
| US12334571B2 (en) | 2018-01-29 | 2025-06-17 | Lg Energy Solution, Ltd. | Top insulator for secondary battery and method for manufacturing the same |
| CN110098371B (en) * | 2018-01-29 | 2020-08-14 | 株式会社Lg化学 | Secondary battery and top insulator for secondary battery |
| EP3644393A4 (en) * | 2018-01-29 | 2020-10-21 | Lg Chem, Ltd. | INSULATION PLATE FOR RECHARGEABLE BATTERY AND METHOD OF MANUFACTURING IT |
| US11552358B2 (en) | 2018-01-29 | 2023-01-10 | Lg Energy Solution, Ltd. | Top insulator for secondary battery and method for manufacturing the same |
| US11532846B2 (en) | 2018-01-29 | 2022-12-20 | Lg Energy Solution, Ltd. | Secondary battery and top insulator for secondary battery |
| JP7096908B2 (en) | 2018-04-16 | 2022-07-06 | サートゥンティード エルエルシー | Silicone coated mineral wool insulation materials, as well as how to make and use them |
| JP2021529713A (en) * | 2018-04-16 | 2021-11-04 | サートゥンティード エルエルシー | Silicone coated mineral wool insulation materials, and how to make and use them |
| KR20200142069A (en) * | 2018-04-16 | 2020-12-21 | 써튼티드 엘엘씨 | Silicone coated mineral wool insulation and its manufacturing and use method |
| KR102546149B1 (en) | 2018-04-16 | 2023-06-22 | 써튼티드 엘엘씨 | Silicone-coated mineral wool insulation and method of manufacturing and using the same |
| US11746192B2 (en) * | 2018-04-16 | 2023-09-05 | Certainteed Llc | Silicone-coated mineral wool insulation materials and methods for making and using them |
| US20240067778A1 (en) * | 2018-04-16 | 2024-02-29 | Certainteed Llc | Silicone-coated mineral wool insulation materials and methods for making and using them |
| US12391803B2 (en) * | 2018-04-16 | 2025-08-19 | Certainteed Llc | Silicone-coated mineral wool insulation materials and methods for making and using them |
| CN109021581A (en) * | 2018-07-16 | 2018-12-18 | 江苏省苏安能节能建材科技有限公司 | A kind of Water-based silicone rubber can porcelain flexible clay facing tile and its preparation and application |
| CN110862555B (en) * | 2019-12-03 | 2022-08-12 | 中国化工株洲橡胶研究设计院有限公司 | A kind of high temperature silicone rubber emulsion and its preparation method and application |
| CN110862555A (en) * | 2019-12-03 | 2020-03-06 | 中国化工株洲橡胶研究设计院有限公司 | High-temperature silicone rubber emulsion and preparation method and application thereof |
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