[go: up one dir, main page]

CN1554609A - Cement clinker calcining cycle pre-calcination process and device - Google Patents

Cement clinker calcining cycle pre-calcination process and device Download PDF

Info

Publication number
CN1554609A
CN1554609A CNA2003101041710A CN200310104171A CN1554609A CN 1554609 A CN1554609 A CN 1554609A CN A2003101041710 A CNA2003101041710 A CN A2003101041710A CN 200310104171 A CN200310104171 A CN 200310104171A CN 1554609 A CN1554609 A CN 1554609A
Authority
CN
China
Prior art keywords
furnace
regulating valve
cyclone
kiln
calcination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2003101041710A
Other languages
Chinese (zh)
Inventor
李建锡
余苏
马保国
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunming University of Science and Technology
Original Assignee
Kunming University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kunming University of Science and Technology filed Critical Kunming University of Science and Technology
Priority to CNA2003101041710A priority Critical patent/CN1554609A/en
Publication of CN1554609A publication Critical patent/CN1554609A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/434Preheating with addition of fuel, e.g. calcining

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crucibles And Fluidized-Bed Furnaces (AREA)

Abstract

本发明涉及一种水泥熟料煅烧循环预烧工艺及装置,分解炉体下方与预烧炉相连、上侧部连旋风筒,旋风筒下部由下料管分别与预烧炉及窑入口相连,三次风管通过三次风量调节阀分别与分解炉体及预烧炉相连,上级旋风筒通过生料管分别与分解炉体及预烧炉相连。该工艺综合预分解窑与流化床工艺的优点,使回转窑中传热量最大的过程在预烧炉中完成,同时,保留少量回转窑用于高温反应带的烧成,可使产量提高50%以上,氮氧化物和硫化物有害气体大幅下降,对煤的适应性广,燃烧效率高。

The invention relates to a cement clinker calcination cycle pre-calcination process and device. The lower part of the calciner body is connected to the pre-calcination furnace, and the upper side is connected to the cyclone cylinder. The tertiary air duct is respectively connected with the calciner body and the pre-burning furnace through the tertiary air volume regulating valve, and the upper cyclone is respectively connected with the calciner body and the pre-calciner through the raw material pipe. This process integrates the advantages of precalcining kiln and fluidized bed process, so that the process with the largest heat transfer in the rotary kiln is completed in the pre-firing furnace. At the same time, a small amount of rotary kiln is reserved for firing in the high-temperature reaction zone, which can increase the output by 50% %, the harmful gases of nitrogen oxides and sulfides are greatly reduced, the adaptability to coal is wide, and the combustion efficiency is high.

Description

水泥熟料煅烧循环预烧工艺及装置Cement clinker calcining cycle pre-calcination process and device

所属技术领域Technical field

本发明涉及一种水泥熟料煅烧循环预烧工艺及装置。The invention relates to a cement clinker calcining cycle pre-calcination process and device.

背景技术Background technique

现行预分解水泥煅烧技术,已将水泥熟料煅烧过程中吸热量最大的碳酸钙分解过程90%放在窑外气固悬浮式分解炉中进行,因而产量高、效率较高。但是,仍有部分碳酸钙以及物料的升温过程在回转窑中完成。研究表明,在预分解的回转窑中,850~1100℃温度区仍然占据回转窑接近一半的空间,在此区间内,集中了90%的回转窑热交换量。然而,由于此区间内回转窑气固温差很低,热辐射能力较弱,对流换热又因物料与气流接触面积小而效率极低,因而回转窑中仍存在传热需求量很大与传热效率极低的矛盾。针对这一问题,日本学者提出以高传热率的流化床煅烧技术完全取代回转窑煅烧的方案,并通过了200t/d级的中试试验研究。但实践证明,流化床煅烧存在均匀性、稳定性差的问题,烧成系统难于控制,1450℃熟料烧成温度下粘结堵塞严重,因而难于大规模应用。从理论上讲,水泥熟料煅烧在高温区(1100~1450℃)内存在大量放热的固相反应,实际所需换热量极小,流化床的使用在此区间并无实际的意义。The current pre-decomposition cement calcination technology has put 90% of the calcium carbonate decomposition process with the largest heat absorption in the cement clinker calcination process in the gas-solid suspension decomposition furnace outside the kiln, so the output is high and the efficiency is high. However, there are still some calcium carbonate and the heating process of materials are completed in the rotary kiln. Studies have shown that in the precalcined rotary kiln, the temperature range of 850-1100°C still occupies nearly half of the space of the rotary kiln, and in this range, 90% of the heat exchange capacity of the rotary kiln is concentrated. However, due to the low temperature difference between gas and solid in the rotary kiln in this range, the weak heat radiation capability, and the extremely low efficiency of convective heat transfer due to the small contact area between the material and the air flow, there is still a large heat transfer demand and heat transfer in the rotary kiln. The paradox of extremely low thermal efficiency. In response to this problem, Japanese scholars proposed a solution to completely replace rotary kiln calcination with fluidized bed calcination technology with high heat transfer rate, and passed the 200t/d level pilot test research. However, practice has proved that fluidized bed calcination has the problems of poor uniformity and stability, the calcination system is difficult to control, and the clinker sintering temperature of 1450 ° C is seriously clogged and clogged, so it is difficult to apply on a large scale. Theoretically speaking, cement clinker calcination has a large amount of exothermic solid-phase reaction in the high-temperature zone (1100-1450°C), and the actual heat exchange required is extremely small, so the use of fluidized bed has no practical significance in this range. .

发明内容Contents of the invention

本发明的目的是提供一种水泥熟料煅烧循环预烧工艺及装置,是在现行新型干法水泥新技术(即预分解技术)的基础上,进一步提高其效率、产量、质量以及生态环保性能的技术,对煤的适应性广,燃烧效率高。The purpose of the present invention is to provide a cement clinker calcination cycle pre-calcination process and device, which is to further improve its efficiency, output, quality and ecological environmental protection performance on the basis of the current new dry process cement technology (ie pre-decomposition technology) Advanced technology, wide adaptability to coal, high combustion efficiency.

本发明的目的是这样实现的:这种水泥熟料煅烧循环预烧装置,分解炉体下方与预烧炉相连,分解炉体上侧部连旋风筒,旋风筒下部有调节阀通过下料管分别与预烧炉及窑入口相连,三次风管通过三次风量调节阀分别与分解炉体及预烧炉相连,预烧炉下方连窑尾烟室,窑尾烟室连窑,上级旋风筒下部有生料调节阀通过生料管分别与分解炉体及预烧炉相连。The object of the present invention is achieved in this way: in this cement clinker calcining cycle pre-calcination device, the lower part of the decomposition furnace body is connected with the pre-calcination furnace, the upper side of the decomposition furnace body is connected with the cyclone, and the lower part of the cyclone has a regulating valve through the feeding pipe. They are respectively connected to the pre-burning furnace and the entrance of the kiln. The three air ducts are respectively connected to the calciner body and the pre-burning furnace through the three air volume regulating valves. A raw material regulating valve is connected with the decomposition furnace body and the pre-burning furnace respectively through the raw material pipe.

一种水泥熟料煅烧循环预烧工艺,设有三种调节阀,已预分解生料调节阀、热生料调节阀和三次风量调节阀,煤粉从预烧炉底部的喷煤管喂入,与窑尾烟气混合,升温至900℃~1000℃,在预烧炉4中煤粉与部分三次风混合燃烧,对来自旋风筒的生料进一步煅烧,完全分解;在预烧炉中生料经高温预烧后,部分生料因烧结成粒,直接从窑尾喷口入窑中,其余生料则随气流及部分未燃煤粉一块进入分解炉中,在分解炉中煤粉与其余三次风混合全部燃烧,同时与上级旋风筒来的生料混合,完成预分解过程;而后生料通过旋风筒气固分离,并经调节阀喂入窑及预烧炉中,形成循环。A cement clinker calcination cycle pre-burning process, equipped with three kinds of regulating valves, the pre-decomposed raw meal regulating valve, the hot raw meal regulating valve and the third air volume regulating valve, the coal powder is fed from the coal injection pipe at the bottom of the pre-calcination furnace, Mix with kiln tail flue gas, raise the temperature to 900°C~1000°C, and combust the pulverized coal and part of the tertiary air in the pre-calcination furnace 4, and further calcinate and completely decompose the raw meal from the cyclone; the raw meal in the pre-calcination furnace After pre-burning at high temperature, part of the raw material is sintered into granules, and enters the kiln directly from the nozzle at the end of the kiln, and the rest of the raw material enters the calciner together with the airflow and some unburned coal powder. In the calciner, the coal powder is combined with the remaining three The air is mixed and burned completely, and at the same time mixed with the raw meal from the upper cyclone to complete the pre-decomposition process; then the raw meal is separated from gas and solid by the cyclone, and fed into the kiln and pre-burning furnace through the regulating valve to form a cycle.

本发明具有以下效果:综合预分解窑与流化床工艺的优点,在回转窑与分解炉之间增设强化预烧炉,使回转窑中传热量最大的过程在预烧炉中完成,同时,保留少量回转窑用于高温反应带的烧成,从而实现既有流化床高效的效果,又避免了流化床难于规模生产的两全效果;产量可提高50%以上,氮氧化物和硫化物有害气体大幅下降,对煤的适应性广,燃烧效率高。The present invention has the following effects: combining the advantages of the precalcining kiln and the fluidized bed process, an intensified pre-sintering furnace is added between the rotary kiln and the calcining furnace, so that the process of the largest heat transfer in the rotary kiln is completed in the pre-sintering furnace, and at the same time, Reserve a small amount of rotary kiln for firing in the high-temperature reaction zone, so as to achieve the high-efficiency effect of the fluidized bed and avoid the two-dimensional effect that the fluidized bed is difficult to produce on a large scale; the output can be increased by more than 50%, and the nitrogen oxides and vulcanization Harmful gases are greatly reduced, the adaptability to coal is wide, and the combustion efficiency is high.

附图说明Description of drawings

图1是本发明的装置的结构示意图。Fig. 1 is a schematic structural view of the device of the present invention.

具体实施方式Detailed ways

图1中,分解炉体9下方与预烧炉4相连,分解炉体9上侧部连旋风筒11,旋风筒11下部有已预分解生料调节阀8通过下料管6分别与预烧炉4及窑1入口相连,三次风管5通过三次风量调节阀13分别与分解炉体9及预烧炉4相连,预烧炉4下方连喷口2,喷口2上部设有喷煤管3、下部连窑1,上级旋风筒12下部有热生料调节阀10通过生料管7分别与分解炉体9及预烧炉4相连。In Fig. 1, the lower part of the calciner body 9 is connected with the pre-burning furnace 4, the upper side of the calciner body 9 is connected with the cyclone 11, and the lower part of the cyclone 11 has a pre-decomposed raw meal regulating valve 8 respectively connected to the pre-calcined furnace through the feeding pipe 6. The furnace 4 is connected to the entrance of the kiln 1, and the tertiary air pipe 5 is respectively connected to the calciner body 9 and the pre-burning furnace 4 through the tertiary air volume regulating valve 13. The lower part is connected to the kiln 1, and the lower part of the upper cyclone 12 has a hot raw material regulating valve 10, which is connected to the calciner body 9 and the pre-burning furnace 4 through the raw material pipe 7 respectively.

在本工艺中设有三种调节阀,已预分解生料调节阀8、热生料调节阀10和三次风量调节阀13,以适应不同的煅烧情况。煤粉从预烧炉4底部的喷煤管3喂入,与窑尾烟气混合,在未燃或少量燃烧状态下升温至900℃~1000℃,在预烧炉4中煤粉与部分三次风混合燃烧,使来自旋风筒11的生料进一步煅烧,完全分解。为防止预烧炉4内温度过高,另设一来自热生料调节阀10的生料管7引入部分生料,以控制其中温度不超过1100℃。在预烧炉4中生料经高温预烧后,有部分生料因烧结成粒,直接从窑尾喷口2入窑1,其余生料则随气流及部分未燃煤粉一块进入分解炉9中,在分解炉9中煤粉与其余三次风混合全部燃烧,同时与上级旋风筒12来的生料混合,完成预分解过程。而后生料通过旋风筒11气固分离,并经调节阀8喂入窑1及预烧炉4中,形成循环。当入预烧炉4的生料部分量较大时,烧结成粒直接入窑的生料量就会增加,从而使物料的进出量达到平衡。In this process, there are three regulating valves, pre-decomposed raw meal regulating valve 8, hot raw meal regulating valve 10 and tertiary air volume regulating valve 13, to adapt to different calcination conditions. The pulverized coal is fed from the coal injection pipe 3 at the bottom of the pre-combustion furnace 4, mixed with the flue gas at the kiln tail, and the temperature is raised to 900 ° C ~ 1000 ° C in the state of unburned or a small amount of combustion. The mixed combustion of wind makes the raw material from the cyclone 11 further calcined and completely decomposed. In order to prevent the temperature in the calciner 4 from being too high, a raw meal pipe 7 from a hot raw meal regulating valve 10 is provided to introduce part of the raw meal to control the temperature within 1100°C. After the raw meal is pre-fired at high temperature in the pre-burning furnace 4, some of the raw meal is sintered and granulated, and enters the kiln 1 directly from the kiln tail nozzle 2, and the rest of the raw meal enters the calciner 9 together with the air flow and some unburned coal powder. In the calciner 9, the pulverized coal is mixed with the rest of the tertiary air and burned completely, and simultaneously mixed with the raw material from the upper cyclone 12 to complete the pre-decomposition process. Then the raw meal is separated from the gas and solid by the cyclone 11, and fed into the kiln 1 and the pre-burning furnace 4 through the regulating valve 8 to form a cycle. When the amount of raw material entering the pre-burning furnace 4 is large, the amount of raw material sintered into granules and directly fed into the kiln will increase, so that the amount of material entering and leaving reaches a balance.

Claims (3)

1、一种水泥熟料煅烧循环预烧装置,其特征在于:分解炉体9下方与预烧炉4相连,分解炉体9上侧部连旋风筒11,旋风筒11下部有已预分解生料调节阀8通过下料管6分别与预烧炉4及窑1入口相连,三次风管5通过三次风量调节阀13分别与分解炉体9及预烧炉4相连,预烧炉4下方连喷口2,喷口2下部连窑1,上级旋风筒12下部有热生料调节阀10通过生料管7分别与分解炉体9及预烧炉4相连。1. A cement clinker calcining cycle pre-burning device, characterized in that: the lower part of the calciner body 9 is connected to the pre-calcined furnace 4, the upper side of the calciner body 9 is connected to the cyclone 11, and the lower part of the cyclone 11 has pre-decomposed raw materials. The material regulating valve 8 is connected to the pre-burning furnace 4 and the entrance of the kiln 1 respectively through the feeding pipe 6, and the tertiary air pipe 5 is respectively connected to the calciner body 9 and the pre-calcining furnace 4 through the tertiary air volume regulating valve 13, and the lower part of the pre-burning furnace 4 is connected. The nozzle 2, the lower part of the nozzle 2 is connected to the kiln 1, and the lower part of the superior cyclone 12 has a hot raw material regulating valve 10, which is connected to the calciner body 9 and the pre-burning furnace 4 through the raw material pipe 7 respectively. 2、一种水泥熟料煅烧循环预烧工艺,其特征在于:设有三种调节阀,已预分解生料调节阀8、热生料调节阀10、三次风量调节阀13,煤粉从预烧炉4底部的喷煤管3喂入,与窑尾烟气混合,升温至900℃~1000℃,在预烧炉4中煤粉与部分三次风混合燃烧,对来自旋风筒11的生料进一步煅烧,完全分解;在预烧炉4中生料经高温预烧后,部分生料因烧结成粒,直接从窑尾喷口2入窑1,其余生料则随气流及部分未燃煤粉一块进入分解炉9中,在分解炉9中煤粉与其余三次风混合全部燃烧,同时与上级旋风筒12来的生料混合,完成预分解过程;而后生料通过旋风筒11气固分离,并经调节阀8喂入窑1及预烧炉4中,形成循环。2. A cement clinker calcination cycle pre-burning process, characterized in that: there are three kinds of regulating valves, the pre-decomposed raw meal regulating valve 8, the hot raw meal regulating valve 10, the third air volume regulating valve 13, and the pulverized coal from the pre-burning The coal injection pipe 3 at the bottom of the furnace 4 feeds, mixes with the kiln tail flue gas, and heats up to 900°C-1000°C. In the pre-burning furnace 4, the coal powder and part of the tertiary air are mixed and burned, and the raw meal from the cyclone 11 is further processed. Calcination, complete decomposition; after the raw material is pre-calcined at high temperature in the pre-calcination furnace 4, part of the raw material is sintered into granules, and directly enters the kiln 1 from the nozzle 2 at the kiln tail, and the rest of the raw material is mixed with the air flow and part of the unburned coal powder. Enter the calciner 9, where the pulverized coal is mixed with the rest of the tertiary air and burned completely, and at the same time mixed with the raw meal from the upper cyclone 12 to complete the pre-decomposition process; then the raw meal is separated from gas to solid by the cyclone 11, and It is fed into the kiln 1 and the pre-fired furnace 4 through the regulating valve 8 to form a cycle. 3、按权利要求2是述的水泥熟料煅烧循环预烧工艺,其特征在于:煤粉从预烧炉4底部的喷煤管3喂入应在未燃或少量燃烧状态下升温至900℃~1000℃,在旋风筒12处另设一来自热生料调节阀10的生料管7引入部分生料,以控制其中温度不超过1100℃。3. According to claim 2, the cement clinker calcination cycle pre-combustion process is characterized in that: the pulverized coal is fed from the coal injection pipe 3 at the bottom of the pre-combustion furnace 4 and the temperature should be raised to 900°C in an unburned or a small amount of combustion state ~1000°C, another raw meal pipe 7 from the hot raw meal regulating valve 10 is set at the cyclone 12 to introduce part of the raw meal, so as to control the temperature not to exceed 1100°C.
CNA2003101041710A 2003-12-26 2003-12-26 Cement clinker calcining cycle pre-calcination process and device Pending CN1554609A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA2003101041710A CN1554609A (en) 2003-12-26 2003-12-26 Cement clinker calcining cycle pre-calcination process and device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNA2003101041710A CN1554609A (en) 2003-12-26 2003-12-26 Cement clinker calcining cycle pre-calcination process and device

Publications (1)

Publication Number Publication Date
CN1554609A true CN1554609A (en) 2004-12-15

Family

ID=34333476

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2003101041710A Pending CN1554609A (en) 2003-12-26 2003-12-26 Cement clinker calcining cycle pre-calcination process and device

Country Status (1)

Country Link
CN (1) CN1554609A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101346319B (en) * 2006-06-28 2013-03-27 太平洋水泥株式会社 Cement burning device and drying method for organic waste with high water content
CN101844879B (en) * 2010-02-04 2013-09-04 南京创能电力科技开发有限公司 Device for producing sulfuric acid and cement by decomposing and calcining gypsum
CN104773967A (en) * 2014-04-22 2015-07-15 罗方跃 Cement clinker calcining method
CN108518998A (en) * 2018-05-24 2018-09-11 天津金隅振兴环保科技有限公司 The system and its technique of cement kiln, stove separation pyrolyzing disposition cyanide polluted soil
CN114644472A (en) * 2020-12-17 2022-06-21 中国科学院工程热物理研究所 Cement material processing device and cement material processing method
CN114644470A (en) * 2020-12-17 2022-06-21 中国科学院工程热物理研究所 Cement material processing device and cement material processing method

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101346319B (en) * 2006-06-28 2013-03-27 太平洋水泥株式会社 Cement burning device and drying method for organic waste with high water content
CN101844879B (en) * 2010-02-04 2013-09-04 南京创能电力科技开发有限公司 Device for producing sulfuric acid and cement by decomposing and calcining gypsum
CN104773967A (en) * 2014-04-22 2015-07-15 罗方跃 Cement clinker calcining method
CN108518998A (en) * 2018-05-24 2018-09-11 天津金隅振兴环保科技有限公司 The system and its technique of cement kiln, stove separation pyrolyzing disposition cyanide polluted soil
CN108518998B (en) * 2018-05-24 2024-05-24 天津金隅振兴环保科技有限公司 Cement kiln and furnace separation pyrolysis treatment system and process for cyanide contaminated soil
CN114644472A (en) * 2020-12-17 2022-06-21 中国科学院工程热物理研究所 Cement material processing device and cement material processing method
CN114644470A (en) * 2020-12-17 2022-06-21 中国科学院工程热物理研究所 Cement material processing device and cement material processing method
CN114644470B (en) * 2020-12-17 2023-10-03 中国科学院工程热物理研究所 Cement material processing device and cement material processing method
CN114644472B (en) * 2020-12-17 2023-10-03 中国科学院工程热物理研究所 Cement material handling device and cement material handling method

Similar Documents

Publication Publication Date Title
CN102875036B (en) Heat storage type lime rotary kiln
WO2011009321A1 (en) Predecomposition kiln tail system used outside of cement kiln for processing raw materials with combustible substances
CN203144295U (en) Heat accumulating type dividing-wall heating rotary lime kiln
CN103922625A (en) System for drying and decomposing wet acetylene sludge and firing cement clinker by using wet acetylene sludge as calcium raw material
CN101348341A (en) Manufacturing method for producing construction gypsum from boiler tail gas
CN105152141B (en) A kind of gypsum relieving haperacidity thermal technology and device
CN113028827A (en) Operation method of spodumene calcination conversion device
CN102992661A (en) Beam type heat storage lime kiln
CN203007146U (en) Beam type heat accumulation lime kiln
CN115340304A (en) Device and method for producing light-burned magnesium oxide through decomposition outside five-stage suspension preheating kiln
CN203782044U (en) System for drying and decomposing wet carbide slag as calcium raw material to sinter cement clinker
CN110220386A (en) A kind of kaolin powder pre-heating system and kaolin powder calcination system and method for calcinating comprising it
CN1554609A (en) Cement clinker calcining cycle pre-calcination process and device
ES3007511T3 (en) Device and method for manufacturing cement clinker and calcined clay
CN214792497U (en) Spodumene calcining and converting device
CN203478938U (en) Rotary kiln apparatus with energy recovery equipment
CN103588399A (en) Cement predecomposition kiln
CN104496207A (en) Heat accumulating type lime rotary kiln
WO2025066048A1 (en) Treatment method and system for suspension calcination of clay
CN103332873B (en) Parallel-flow heat accumulating type lime rotary kiln
CN205023854U (en) Gypsum relieving haperacidity thermal technology device
CN110862272A (en) A device and method for preparing composite activator clinker using semi-dry desulfurization ash and application of the clinker
CN114644469B (en) Cement material processing device and cement material processing method
CN109970370B (en) A device and production process for preparing pure calcium aluminate cement using preheater kiln technology
CN114644468B (en) Cement material processing device and cement material processing method

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication