CN1421351A - Method of making hull of fishing boat and yacht with basalt fiber reinforced material - Google Patents
Method of making hull of fishing boat and yacht with basalt fiber reinforced material Download PDFInfo
- Publication number
- CN1421351A CN1421351A CN 01142390 CN01142390A CN1421351A CN 1421351 A CN1421351 A CN 1421351A CN 01142390 CN01142390 CN 01142390 CN 01142390 A CN01142390 A CN 01142390A CN 1421351 A CN1421351 A CN 1421351A
- Authority
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- Prior art keywords
- resin
- basalt fibre
- reinforcing material
- fishing boat
- hull
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- 229920002748 Basalt fiber Polymers 0.000 title claims abstract description 44
- 239000000463 material Substances 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 29
- 239000011347 resin Substances 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000003822 epoxy resin Substances 0.000 claims abstract description 9
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 9
- 239000004744 fabric Substances 0.000 claims abstract description 7
- 238000005507 spraying Methods 0.000 claims abstract description 7
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 5
- 239000012779 reinforcing material Substances 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 238000005516 engineering process Methods 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 229920001225 polyester resin Polymers 0.000 claims description 8
- 239000004645 polyester resin Substances 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- 238000013461 design Methods 0.000 claims description 7
- 238000003475 lamination Methods 0.000 claims description 7
- 239000003086 colorant Substances 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 239000003085 diluting agent Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 239000007791 liquid phase Substances 0.000 claims description 6
- 239000002674 ointment Substances 0.000 claims description 6
- 230000009974 thixotropic effect Effects 0.000 claims description 6
- 230000000977 initiatory effect Effects 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 238000002347 injection Methods 0.000 claims description 4
- 239000007924 injection Substances 0.000 claims description 4
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims description 3
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 claims description 3
- 229920002799 BoPET Polymers 0.000 claims description 3
- XVTCWJZIJJQGAC-UHFFFAOYSA-N C=CC1=CC=CC=C1.[Co].C1(=CC=CC2=CC=CC=C12)C(=O)O Chemical compound C=CC1=CC=CC=C1.[Co].C1(=CC=CC2=CC=CC=C12)C(=O)O XVTCWJZIJJQGAC-UHFFFAOYSA-N 0.000 claims description 3
- 239000005041 Mylar™ Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 229920002301 cellulose acetate Polymers 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 239000000123 paper Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920002545 silicone oil Polymers 0.000 claims description 3
- 238000007598 dipping method Methods 0.000 claims description 2
- 238000005470 impregnation Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000013307 optical fiber Substances 0.000 claims description 2
- 239000012071 phase Substances 0.000 claims description 2
- 238000012805 post-processing Methods 0.000 claims description 2
- 239000003365 glass fiber Substances 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 5
- 239000011152 fibreglass Substances 0.000 description 5
- 239000010959 steel Substances 0.000 description 5
- 239000002657 fibrous material Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 235000013332 fish product Nutrition 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Moulding By Coating Moulds (AREA)
Abstract
The present invention is the method of making hull of fishing boat and yacht with basalt fiber reinforced material. The material used includes twist-less basalt rove or fabric, unsaturated polyester resin or epoxy resin, promoter and other supplementary material. The making process includes spreading the basalt material, spraying resin, curing, demolding and other steps. The basalt fiber has acid and alkali resistance, heat stability, tensile strength and other mechanical performance superior to those of common glass fiber. Making hull of fishing boat and yacht with basalt fiber reinforced material can result in improved performance and lowered cost.
Description
Technical field
The present invention relates to make as reinforcing material the method for fishing boat and yacht hull with basalt fibre.
Background technology
China is a fishery big country, and according to the national first fishing boat reconnaissance information that the Ministry of Agriculture announces calendar year 2001, the overwhelming majority is to be the fishing boat that material is made with timber in China's fishing boat.Constitute from the hull material of fishing for fishing boat, wooden ship quantity accounts for fishes for 86.01% of fishing boat sum; Next is to be the fishing boat that material is made with steel, accounts for 8.93%; In addition, the fishing boat that also has fraction ferro-cement material to make.Glass fibre develops in China in recent years to some extent as the fiberglass fishing boat of reinforcing material manufacturing, accounts for 2.5% of sum.The Ministry of Agriculture of country just proposed to greatly develop fiberglass fishing boat in national agricultural working meeting in 1994, and had put into effect some preferential policies.The fiberglass fishing boat advantage is obvious, but develops unhappyly, and it is a lot of that major cause is that glass fibre valency height causes the fiberglass fishing boat price to exceed wooden fishing vessels, and its utilization is subjected to the restriction of economic condition.Thereby need the development of new material, further improve product quality, cost-cutting.
Through the basalt fibre that fusing draws out, have the nearly all advantage performance of glass fibre with basalt, its resistance to alkalis, resistance to acids, heat stability, tensile strength and mechanical property are all above the simple glass fiber.Except that properties of product, the advantage of basalt fibre is that also its raw MAT'L wide material sources, resource are unlimited, and productive costs is low.Make fishing boat, yacht hull with basalt fibre as reinforcing material, can improve the hull performance, reduce fishing boat, yacht price.Through inquiry, up to the present, yet there are no at home with the patent documentation and relevant publication of basalt fibre, or use aborning as fishing boat, yacht product and the manufacture method thereof of reinforcing material.
Summary of the invention
The purpose of this invention is to provide the method for making fishing boat, yacht hull with basalt fibre as reinforcing material.
Technical scheme of the present invention has two, promptly uses two kinds of production technologies that purpose of the present invention is achieved.
Scheme one, the injection molding technology.
Raw MAT'L: adopt surface treated basalt fibre roving as reinforcing material; Resin adopts unsaturated polyester resin, and initiating agent adopts liquid phase methyl ethyl ketone peroxide or liquid phase cyclohexanone peroxide, and accelerator adopts the naphthoic acid cobalt styrene solution.Mold release adopts film-type, solution-type or ointment class mold release.Auxiliary material comprise curing agent, accelerator, thixotropic compound, diluent, filler, colorant etc.Equipment choosing novel injection equipment.
Its technological process is: use spraying equipment will be added with the resin mixture and the initiating agent mixing jetting of accelerator, carry out gel coat spraying on the mould of mold release scribbling, gel, carry out spray, use kit lamination nip drum eliminating bubble that resin and fiber mix the spray lamination then, curing, the demoulding then.
Scheme two, hand is stuck with paste technology.
Raw-material selection.Select surface treated basalt fibre reinforcing material for use, as: chopped mat, roving, Chopped fiber, roving woven roving, twisting cloth and basalt fibre band.Resin is selected Polyester resin or epoxy resin for use.Auxiliary material comprise curing agent, accelerator, thixotropic compound, diluent, filler, colorant etc.Mold release can be selected film-type mold releases such as glass paper, mylar, polyvinyl chloride film for use, or solution-type mold releases such as perchleroe thylene solution, poly-vinyl alcohol solution, polystyrene solution, cellulose acetate mold release, silaatic and silicone oil, or ointment, paraffin release agent.
Its technological process is: will be added with the resin mixture and the manual lay successively of basalt fibre reinforcing material of curing agent, and scribbling impregnation on the mould of mold release, getting rid of bubble, be laminated to design thickness, then curing molding.
Make the beneficial effect of fishing boat, yacht as reinforcing material with basalt fibre:
The at present overwhelming majority or wooden fishing vessels in China's fishing boat, thereby the annual high-quality timber that consumes of renovating is up to ten thousand stere surplus 200.The China's Forest Resources shortage is if the overcut forest is unfavorable for preserving the ecological environment.The steel that the steel fishing boat uses are perishable, the service expenditure height, and technology is complicated, and period of service is short.Ferrocement boat since from great, loading is few, and performance is affected, adding improves quality be difficult for to guarantee, just is eliminated at present.Fiberglass fishing boat also exists price than problems such as height.Basalt fibre is better than glass fibre on most performances, it is little that it has density, advantages such as good, bright and clean attractive in appearance, the long service life of intensity height, shock resistance, withstanding corrosion, adiathermancy and electrical insulating property, the saving energy, cost are lower are the ideal materials of building medium and small fishing boat and yacht.Basalt fibre density is lower than steel, and the hull mass that basalt fibre is made is light by 20～50% than wooden boat and steel ship, the carrying capacity of corresponding increase ship.Basalt fibre ship smooth surface, can reduce resistance, the saving in power energy of ship navigation.The ship seawater corrosion resistance that basalt fibre is made is not damaged by worms, the easy-maintaining maintenance, and used life can reach more than 50 years, was the several times of wooden boat.The basalt fiber material coefficient of thermal conductivity is low, water absorption rate is little, it is heat insulation fresh-keeping to be beneficial to fish products.Basalt fibre shipbuilding offhand, device therefor is relative with technical ability simple, and tissue is produced easily.Make yacht with basalt fiber material, also can promote the manufacturing development of China's yacht.Have data to show, now the annual value of production of yacht and corollary equipment thereof has formed big ship, marine equipment and the yacht situation of standing like the legs of a tripod basically up to 25,000,000,000 dollars in the world.China is on shipbuilding science and technology such as composite material and Ship Hydrodynamics, theory of structure field and keep up with, and makes that the yacht performance improves and cost reduces with basalt fiber material, and the utilization of new material will strengthen our competitive edge.
The specific embodiment
Make the specific embodiment of fishing boat, yacht hull with the injection molding technology.
Raw MAT'L: employing can be satisfied spray technology performance (cuttability, dispersiveness, dipping etc.), surface treated basalt fibre roving as reinforcing material; Resin adopts unsaturated polyester resin etc., and initiating agent adopts liquid phase methyl ethyl ketone peroxide or liquid phase cyclohexanone peroxide etc., and accelerator adopts naphthoic acid cobalt styrene solution etc.Mold release adopts film-type, solution-type or ointment class mold release etc.Auxiliary material comprise curing agent, accelerator, thixotropic compound, diluent, filler, colorant etc.Equipment choosing novel injection equipment.
Finish product design, and make mould according to designing requirement.On mould, spray gel coat, emitted dose 700～800g/min, gel coat thickness 0.4～0.7mm.Use the optical fiber cutting apparatus of spraying equipment and outfit that roving is cut into fixed length then, make its back that sheds mix mixed with resin by centrifugal inertia and form lamination with the pressure of ejection.Injection pressure is between 0.3～0.5mpa.Hull goods gel is cured to the demoulding behind the demoulding strength.After the demoulding, carry out furnace run, impel resin fully to solidify.The epoxy resin heat treatment temperature in 150 ℃, Polyester resin class heat treatment temperature 120 ℃ with interior, between 50 ℃～80 ℃.At last, assemble with methods such as mechanical connection, splicing, repair, finish hull and make according to designing requirement.
Stick with paste the specific embodiment that technology is made fishing boat, yacht hull with hand.
Finish product design, and according to designing requirement making mould, select film-type mold releases such as glass paper, mylar, polyvinyl chloride film for use, or solution-type mold releases such as perchleroe thylene solution, poly-vinyl alcohol solution, polystyrene solution, cellulose acetate mold release, silaatic and silicone oil, or ointment, paraffin release agent.Select basalt fibre reinforcing materials such as surface treated basalt chopped fiber felt, roving, Chopped fiber, roving woven roving, twisting cloth and basalt fibre band for use according to designing requirement.Resin is selected Polyester resin or epoxy resin for use.Auxiliary material comprise curing agent, accelerator, thixotropic compound, diluent, filler, colorant etc.
The preparation gel coating resin.Add fleut or surperficial felt is made the higher gel coat superficial layer of one deck resin content with resin, thickness is about 0.2～0.4mm.
Paste.Gel coating resin begins gel, promptly pastes.Be coated with one deck resin earlier, lay one deck fiber cloth is got rid of bubble then, and is superimposed layer by layer, to design thickness.The gum content of lamination is between 45%～55%, and the work room temperature is more than 15 ℃, and humidity is not higher than 80%.
Solidify.Its process is divided into gel, curing and heating post-processing three phases.The hull gel is cured to the demoulding behind the demoulding strength.After the demoulding, carry out furnace run, impel resin fully to solidify.The epoxy resin heat treatment temperature in 150 ℃, Polyester resin class heat treatment temperature 120 ℃ with interior, between 50 ℃～80 ℃.At last, assemble with methods such as mechanical connection, splicing, repair, finish hull and make according to designing requirement.
Claims (9)
1, makes the method for fishing boat and yacht hull as reinforcing material with basalt fibre.This method comprises injection molding technology and hand pasting forming technology.It is characterized in that, adopt surface treated basalt fibre roving as reinforcing material, adopt basis materiales such as unsaturated polyester resin, and auxiliary material such as accelerator, use spraying equipment will be added with the resin mixture and the initiating agent mixing jetting of accelerator, carry out gel coat spraying, gel on the mould of mold release scribbling, carry out the spray that resin and fiber mix the spray lamination then, then curing, the demoulding; Perhaps select surface treated basalt fibre reinforcing material for use, as basalt chopped fiber felt, roving, Chopped fiber, roving woven roving, twisting cloth and basalt fibre band etc., select Polyester resin or epoxy resin for use, and other auxiliary material, the resin mixture and the manual lay successively of basalt fibre reinforcing material of curing agent will be added with, scribbling impregnation on the mould of mold release, getting rid of bubble, be laminated to design thickness, then curing molding.
2, according to claim 1 with the method for basalt fibre as reinforcing material manufacturing fishing boat and yacht hull, it is characterized in that adopting and can satisfy spray technology performance (cuttability, dispersiveness, dipping etc.), surface treated basalt fibre roving as reinforcing material; Resin adopts unsaturated polyester resin, and initiating agent adopts liquid phase methyl ethyl ketone peroxide or liquid phase cyclohexanone peroxide, and accelerator adopts the naphthoic acid cobalt styrene solution.Mold release adopts film-type, solution-type or ointment class mold release.Auxiliary material comprise curing agent, accelerator, thixotropic compound, diluent, filler, colorant etc.
3, according to claim 1 with the method for basalt fibre as reinforcing material manufacturing fishing boat and yacht hull, it is characterized in that finishing product design, and make mould according to designing requirement.On mould, spray gel coat, emitted dose 700～800g/min, gel coat thickness 0.4～0.7mm.
4, the method for making fishing boat and yacht hull with basalt fibre as reinforcing material according to claim 1, it is characterized in that using the optical fiber cutting apparatus of spraying equipment and outfit that roving is cut into fixed length, make its back that sheds mix mixed with resin by centrifugal inertia and form lamination with the pressure of ejection.Injection pressure is between 0.3～0.5mpa.
5, according to claim 1ly make the method for fishing boat and yacht hull as reinforcing material, it is characterized in that hull goods gel, be cured to the demoulding behind the demoulding strength with basalt fibre.After the demoulding, carry out furnace run, impel resin fully to solidify.The epoxy resin heat treatment temperature in 150 ℃, Polyester resin class heat treatment temperature 120 ℃ with interior, between 50 ℃～80 ℃.
6, the method for making fishing boat and yacht hull with basalt fibre as reinforcing material according to claim 1, it is characterized in that selecting for use surface treated basalt fibre reinforcing material, as basalt chopped fiber felt, roving, Chopped fiber, roving woven roving, twisting cloth and basalt fibre band.Resin is selected Polyester resin or epoxy resin for use.Auxiliary material comprise curing agent, accelerator, thixotropic compound, diluent, filler, colorant etc.Mold release can be selected film-type mold releases such as glass paper, mylar, polyvinyl chloride film for use, or solution-type mold releases such as perchleroe thylene solution, poly-vinyl alcohol solution, polystyrene solution, cellulose acetate mold release, silaatic and silicone oil, or ointment, paraffin release agent.
7, according to claim 1 with the method for basalt fibre as reinforcing material manufacturing fishing boat and yacht hull, it is characterized in that preparing gel coating resin.Add fleut or surperficial felt is made the higher gel coat superficial layer of one deck resin content with resin, thickness is about 0.2～0.4mm.
8, according to claim 1 with the method for basalt fibre as reinforcing material manufacturing fishing boat and yacht hull, it is characterized in that pasting.Gel coating resin begins gel, promptly pastes.Be coated with one deck resin earlier, lay one deck fiber cloth is got rid of bubble then, and is superimposed layer by layer, to design thickness.The gum content of lamination is between 45%～55%, and the work room temperature is more than 15 ℃, and humidity is not higher than 80%.
9, according to claim 1 with the method for basalt fibre as reinforcing material manufacturing fishing boat and yacht hull, it is characterized in that solidifying.Its process is divided into gel, curing and heating post-processing three phases.The hull gel is cured to the demoulding behind the demoulding strength.After the demoulding, carry out furnace run, impel resin fully to solidify.The epoxy resin heat treatment temperature in 150 ℃, Polyester resin class heat treatment temperature 120 ℃ with interior, between 50 ℃～80 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01142390 CN1421351A (en) | 2001-11-28 | 2001-11-28 | Method of making hull of fishing boat and yacht with basalt fiber reinforced material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01142390 CN1421351A (en) | 2001-11-28 | 2001-11-28 | Method of making hull of fishing boat and yacht with basalt fiber reinforced material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1421351A true CN1421351A (en) | 2003-06-04 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01142390 Pending CN1421351A (en) | 2001-11-28 | 2001-11-28 | Method of making hull of fishing boat and yacht with basalt fiber reinforced material |
Country Status (1)
| Country | Link |
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| CN (1) | CN1421351A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005047403A1 (en) * | 2003-11-13 | 2005-05-26 | Unternehmen Für Spezialfasern Sakrowski e.K. | Biocide-free antifouling coating consisting of a fabric based on basalt fibres |
| CN102002851A (en) * | 2010-11-23 | 2011-04-06 | 哈尔滨工业大学 | PBO (Poly-p-phenylenebenzobisoxazazole) fiber fabric ship with super buoyancy and preparation method thereof |
| CN102922747A (en) * | 2012-10-31 | 2013-02-13 | 重庆海电风能集团有限公司 | Injecting manual pasting mixing and forming technology for glass fiber reinforced plastics chamber cover die of wind turbine |
| EP2729539A1 (en) | 2011-07-04 | 2014-05-14 | Maretex GmbH | Corrosion protection layer |
| CN106985420A (en) * | 2017-03-24 | 2017-07-28 | 常州市金坛奉献橡塑有限公司 | Automobile preprocessor and exhaust insulation solidification coating member production technology |
| CN110328865A (en) * | 2019-07-24 | 2019-10-15 | 中车长春轨道客车股份有限公司 | A kind of moulding process of basalt fibre subway seat |
| CN111844805A (en) * | 2020-07-30 | 2020-10-30 | 宁波耀众模塑科技有限公司 | Carbon fiber reinforced resin matrix composite material for polyurethane foam product |
| CN112194961A (en) * | 2020-08-24 | 2021-01-08 | 艾普科模具材料（上海）有限公司 | Manufacturing method of spraying gel coat and mold |
| CN112743954A (en) * | 2020-12-30 | 2021-05-04 | 朴成浩 | Novel composite material and composite process thereof |
| CN113161875A (en) * | 2021-02-03 | 2021-07-23 | 成来电气科技有限公司 | Wind power generation box type transformer station glass fiber reinforced plastic shell and manufacturing process thereof |
| CN114919245A (en) * | 2022-04-20 | 2022-08-19 | 无锡市鸿声船用玻璃钢有限公司 | Light composite hull material and preparation method thereof |
| CN116587634A (en) * | 2023-05-26 | 2023-08-15 | 四川四众玄武岩纤维技术研发有限公司 | A method for forming a basalt fiber traffic boat |
-
2001
- 2001-11-28 CN CN 01142390 patent/CN1421351A/en active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005047403A1 (en) * | 2003-11-13 | 2005-05-26 | Unternehmen Für Spezialfasern Sakrowski e.K. | Biocide-free antifouling coating consisting of a fabric based on basalt fibres |
| DE10353185A1 (en) * | 2003-11-13 | 2005-06-23 | Unternehmen Für Spezialfasern Sakrowski e.K. | Biocide-free antifouling coating |
| DE10353185B4 (en) * | 2003-11-13 | 2005-11-10 | Unternehmen Für Spezialfasern Sakrowski e.K. | Use of basalt fibers or basalt filaments as a textile fabric for biocide-free antifouling coating for underwater surfaces |
| AU2004289806B2 (en) * | 2003-11-13 | 2007-08-23 | Unternehmen Fur Spezialfasern Sakrowski E.K. | Biocide-free antifouling coating consisting of a fabric based on basalt fibres |
| KR100882829B1 (en) * | 2003-11-13 | 2009-02-10 | 운터네멘 퓌어 슈페치알파저른 자크로브스키 에. 카. | Biocide-free antifouling coating agent of a fabric based on basalt fibres |
| CN100516148C (en) * | 2003-11-13 | 2009-07-22 | 特种纤维企业萨克罗夫斯基公司 | Biocide-free antifouling coating consisting of a fabric based on basalt fibres |
| US7887654B2 (en) | 2003-11-13 | 2011-02-15 | Unternehmen Für Spezialfasern Sakrowski e.K. | Biocide-free anti-fouling coating containing a fabric based on basalt fibers |
| CN102002851A (en) * | 2010-11-23 | 2011-04-06 | 哈尔滨工业大学 | PBO (Poly-p-phenylenebenzobisoxazazole) fiber fabric ship with super buoyancy and preparation method thereof |
| EP2729539B1 (en) * | 2011-07-04 | 2017-09-06 | Mare Solutions GmbH | Corrosion protection layer |
| EP2729539A1 (en) | 2011-07-04 | 2014-05-14 | Maretex GmbH | Corrosion protection layer |
| CN102922747B (en) * | 2012-10-31 | 2015-07-15 | 重庆海电风能集团有限公司 | Injecting manual pasting mixing and forming technology for glass fiber reinforced plastics chamber cover die of wind turbine |
| CN102922747A (en) * | 2012-10-31 | 2013-02-13 | 重庆海电风能集团有限公司 | Injecting manual pasting mixing and forming technology for glass fiber reinforced plastics chamber cover die of wind turbine |
| CN106985420A (en) * | 2017-03-24 | 2017-07-28 | 常州市金坛奉献橡塑有限公司 | Automobile preprocessor and exhaust insulation solidification coating member production technology |
| CN110328865A (en) * | 2019-07-24 | 2019-10-15 | 中车长春轨道客车股份有限公司 | A kind of moulding process of basalt fibre subway seat |
| CN111844805A (en) * | 2020-07-30 | 2020-10-30 | 宁波耀众模塑科技有限公司 | Carbon fiber reinforced resin matrix composite material for polyurethane foam product |
| CN112194961A (en) * | 2020-08-24 | 2021-01-08 | 艾普科模具材料（上海）有限公司 | Manufacturing method of spraying gel coat and mold |
| CN112743954A (en) * | 2020-12-30 | 2021-05-04 | 朴成浩 | Novel composite material and composite process thereof |
| CN113161875A (en) * | 2021-02-03 | 2021-07-23 | 成来电气科技有限公司 | Wind power generation box type transformer station glass fiber reinforced plastic shell and manufacturing process thereof |
| CN114919245A (en) * | 2022-04-20 | 2022-08-19 | 无锡市鸿声船用玻璃钢有限公司 | Light composite hull material and preparation method thereof |
| CN116587634A (en) * | 2023-05-26 | 2023-08-15 | 四川四众玄武岩纤维技术研发有限公司 | A method for forming a basalt fiber traffic boat |
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