CN1481684A - Composite isoproturon-metribuzin herbicide - Google Patents
Composite isoproturon-metribuzin herbicide Download PDFInfo
- Publication number
- CN1481684A CN1481684A CNA031316239A CN03131623A CN1481684A CN 1481684 A CN1481684 A CN 1481684A CN A031316239 A CNA031316239 A CN A031316239A CN 03131623 A CN03131623 A CN 03131623A CN 1481684 A CN1481684 A CN 1481684A
- Authority
- CN
- China
- Prior art keywords
- isoproturon
- herbicide
- percetage
- killer herbicide
- weed killer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004009 herbicide Substances 0.000 title claims abstract description 54
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 35
- 239000005583 Metribuzin Substances 0.000 title abstract 3
- 239000002131 composite material Substances 0.000 title description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002270 dispersing agent Substances 0.000 claims abstract description 14
- 239000000080 wetting agent Substances 0.000 claims abstract description 14
- 229920001285 xanthan gum Polymers 0.000 claims abstract description 8
- 239000003599 detergent Substances 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 51
- RMFGNMMNUZWCRZ-UHFFFAOYSA-N Humulone Natural products CC(C)CC(=O)C1=C(O)C(O)(CC=C(C)C)C(O)=C(CC=C(C)C)C1=O RMFGNMMNUZWCRZ-UHFFFAOYSA-N 0.000 claims description 26
- VMSLCPKYRPDHLN-NRFANRHFSA-N humulone Chemical compound CC(C)CC(=O)C1=C(O)C(CC=C(C)C)=C(O)[C@@](O)(CC=C(C)C)C1=O VMSLCPKYRPDHLN-NRFANRHFSA-N 0.000 claims description 26
- PUIYMUZLKQOUOZ-UHFFFAOYSA-N isoproturon Chemical compound CC(C)C1=CC=C(NC(=O)N(C)C)C=C1 PUIYMUZLKQOUOZ-UHFFFAOYSA-N 0.000 claims description 26
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical class [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 24
- 239000012752 auxiliary agent Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 11
- 239000004480 active ingredient Substances 0.000 claims description 9
- 241000209140 Triticum Species 0.000 abstract description 9
- 235000021307 Triticum Nutrition 0.000 abstract description 9
- 241000196324 Embryophyta Species 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 6
- 240000001592 Amaranthus caudatus Species 0.000 abstract description 2
- 235000009328 Amaranthus caudatus Nutrition 0.000 abstract description 2
- 239000003905 agrochemical Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- FOXFZRUHNHCZPX-UHFFFAOYSA-N metribuzin Chemical compound CSC1=NN=C(C(C)(C)C)C(=O)N1N FOXFZRUHNHCZPX-UHFFFAOYSA-N 0.000 abstract 2
- 235000014820 Galium aparine Nutrition 0.000 abstract 1
- 240000005702 Galium aparine Species 0.000 abstract 1
- 241000219873 Vicia Species 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 229940082509 xanthan gum Drugs 0.000 abstract 1
- 235000010493 xanthan gum Nutrition 0.000 abstract 1
- 239000000230 xanthan gum Substances 0.000 abstract 1
- 239000010902 straw Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000005496 Chlorsulfuron Substances 0.000 description 2
- 240000005979 Hordeum vulgare Species 0.000 description 2
- 235000007340 Hordeum vulgare Nutrition 0.000 description 2
- 239000005584 Metsulfuron-methyl Substances 0.000 description 2
- 208000005374 Poisoning Diseases 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- VJYIFXVZLXQVHO-UHFFFAOYSA-N chlorsulfuron Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)Cl)=N1 VJYIFXVZLXQVHO-UHFFFAOYSA-N 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- RSMUVYRMZCOLBH-UHFFFAOYSA-N metsulfuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=NC(OC)=N1 RSMUVYRMZCOLBH-UHFFFAOYSA-N 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 240000004585 Dactylis glomerata Species 0.000 description 1
- 240000003173 Drymaria cordata Species 0.000 description 1
- 244000299507 Gossypium hirsutum Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000105017 Vicia sativa Species 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 125000004193 piperazinyl group Chemical group 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to agricultural chemical, and is especially herbicide. The herbicide has effective components isoprotuin and metribuzin and consists of isoprotuin 15-70 wt%, metribuzin 1-25 wt%, assistants 8-10 wt% and stuffing the rest. When the herbicide is produced as powder preparation, the assistants include abstergent, dispersant and wetting agent and the stuffing is kaolin. When it is paste, the assistants include dispersant, wetting agent, glycol and xanthan gum and the stuffing is water. Herbicidal test shows that the herbicide has herbicidal effect on both gramineous weeds, such as hard weed, dentes foxtail, etc. and broad leaved weeds, such as cleavers, vetch, etc. It is safe to wheat and has no negative effect on subsequent crop.
Description
Technical field
The present invention relates to a kind of agricultural chemicals, refer in particular to a kind of compound herbicide that isoproturon and piperazine humulone are mixed and made into according to a certain percentage.
Background technology
The application of cornfield herbicidal is more extensive, and kind is also many, as wheat straw spirit etc.Mainly forming of wheat straw spirit by chlorsulfuron and metsulfuron-methyl, the wheat straw spirit has preventive effect preferably to the multiple weeds in the wheatland, broad weed-killing spectrum, but wherein metsulfuron-methyl is relatively poor to the safety of wheat, barley and highland barley careless slightlyly is easy to generate poisoning, though the chlorsulfuron in the wheat straw spirit has drug effect preferably, but after using, in soil the lasting period long, and cumulative function is arranged, cause back stubble rice anisopliae, crops such as corn, rape and cotton seedling suffer poisoning.
Summary of the invention
The object of the present invention is to provide a kind of isoproturon and piperazine humulone complex weedicide,, reduce the harm of weed killer herbicide farmland and succession crop to improve herbicidal effect.
Its main technical schemes is: the active ingredient of this weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 1～25%, isoproturon 15～70%, and auxiliary agent 8～10%, surplus is filler, unit is a percetage by weight.
When producing the weed killer herbicide of pulvis, the composition of auxiliary agent is: detergent 20～40%, and dispersant 30～50%, wetting agent 10～30%, the filler of this moment should adopt kaolin, and unit is a percetage by weight.
When producing the weed killer herbicide of paste, the composition of auxiliary agent is a dispersant 20～40%, wetting agent 10～30%, and ethylene glycol 40～60%, xanthans 1～3% at this moment, should adopt water to do filler, and unit is a percetage by weight.
Xanthans wherein gets by refining in the corn, and its effect is for thickening.Dispersant by naphthalene sulfonic acids and formaldehyde condensation after, get through neutralization.
Wherein, the structural formula of detergent LS is as follows, and its effect is in order to improve the suspensibility of wetting powder.
The structural formula of wetting agent BX is:
Its effect is in order to reduce wetting time.
The structural formula of piperazine humulone is:
The structural formula of isoproturon is:
As a kind of herbicidal composition preferably is piperazine humulone 5～20%, isoproturon 30～55%, and auxiliary agent 8～10%, surplus is filler, unit is a percetage by weight.
This weed killer herbicide shows through the test of pesticide effectiveness, not only grassy weed such as hard grass, amur foxtail etc. are had and remove effect preferably, and broadleaved herb such as clearvers, common vetch, chickweed etc. also there is excellent preventive effect, under normal dosage situation, to wheat growth safety, and this medicament use the back to succession crop without any negative effect.
Embodiment
Embodiment one
The active ingredient of weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 1%, isoproturon 70%, and auxiliary agent 10%, surplus is kaolin, unit is a percetage by weight.
The composition of auxiliary agent is: detergent 20%, and dispersant 50%, wetting agent 30%, unit are percetage by weight.This is the pulvis weed killer herbicide.
Embodiment two
The active ingredient of weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 25%, isoproturon 15%, and auxiliary agent 8%, surplus is kaolin, unit is a percetage by weight.
The composition of auxiliary agent is: detergent 40%, and dispersant 50%, wetting agent 10%, unit are percetage by weight.This is the pulvis weed killer herbicide.
Embodiment three
The active ingredient of weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 15%, isoproturon 45%, and auxiliary agent 9%, surplus is kaolin, unit is a percetage by weight.
The composition of auxiliary agent is: detergent 40%, and dispersant 30%, wetting agent 30%, unit are percetage by weight.This is the pulvis weed killer herbicide.
Embodiment four
The active ingredient of this weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 1%, isoproturon 70%, and auxiliary agent 10%, surplus is filler water, unit is a percetage by weight.
The composition of auxiliary agent is a dispersant 40%, wetting agent 10%, and ethylene glycol 49%, xanthans 1%, unit are percetage by weight.This prescription can be produced the weed killer herbicide of paste.
Embodiment five
The active ingredient of this weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 25%, isoproturon 15%, and auxiliary agent 8～%, surplus is filler water, unit is a percetage by weight.
The composition of auxiliary agent is a dispersant 20%, wetting agent 30%, and ethylene glycol 47%, xanthans 3%, unit are percetage by weight.This prescription can be produced the weed killer herbicide of paste.
Embodiment six
The active ingredient of this weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 15%, isoproturon 50%, and auxiliary agent 9%, surplus is filler water, unit is a percetage by weight.
The composition of auxiliary agent is a dispersant 29%, wetting agent 10%, and ethylene glycol 60%, xanthans 1%, unit are percetage by weight.This prescription can be produced the weed killer herbicide of paste.
Embodiment seven
The active ingredient of this weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 15%, isoproturon 50%, and auxiliary agent 9%, surplus is filler water, unit is a percetage by weight.
The composition of auxiliary agent is a dispersant 38%, wetting agent 20%, and ethylene glycol 40%, xanthans 2%, unit are percetage by weight.This prescription can be produced the weed killer herbicide of paste.
Through indoor cultivation test, test is to the preventive effect of the grassy weed of wheat paddock with to the safety of wheat, and the result shows: the composite dose of co-toxicity coefficient to grassy weed of piperazine humulone and isoproturon all is higher than 100, is notable synergistic.
Claims (5)
1, isoproturon and piperazine humulone complex weedicide, it is characterized in that: the active ingredient of this weed killer herbicide is isoproturon and piperazine humulone, and wherein the piperazine humulone 1～25%, isoproturon 15～70%, auxiliary agent 8～10%, surplus is filler, unit is a percetage by weight.
2, weed killer herbicide according to claim 1 is characterized in that the composition of auxiliary agent is: detergent 20～40%, and dispersant 30～50%, wetting agent 10～30%, unit are percetage by weight.
3, weed killer herbicide according to claim 1 is characterized in that: the composition of auxiliary agent is a dispersant 20～40%, wetting agent 10～30%, and ethylene glycol 40～60%, xanthans 1～3%, unit are percetage by weight.
4, weed killer herbicide according to claim 1 is characterized in that: filler is kaolin or water.
5, weed killer herbicide according to claim 1 is characterized in that: piperazine humulone 5～20%, and isoproturon 30～55%, auxiliary agent 8～10%, surplus is filler, unit is a percetage by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031316239A CN1481684A (en) | 2003-05-28 | 2003-05-28 | Composite isoproturon-metribuzin herbicide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA031316239A CN1481684A (en) | 2003-05-28 | 2003-05-28 | Composite isoproturon-metribuzin herbicide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1481684A true CN1481684A (en) | 2004-03-17 |
Family
ID=34153820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA031316239A Pending CN1481684A (en) | 2003-05-28 | 2003-05-28 | Composite isoproturon-metribuzin herbicide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1481684A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013501739A (en) * | 2009-08-14 | 2013-01-17 | バイエル・クロップサイエンス・アーゲー | High concentration suspension concentrate of metribuzin without aluminum silicate |
| CN105265459A (en) * | 2015-10-28 | 2016-01-27 | 泰安市农业科学研究院 | Weeding composition containing triaziflam and isoproturon |
| CN120753274A (en) * | 2025-08-27 | 2025-10-10 | 山东潍坊润丰化工股份有限公司 | Herbicidal composition and use thereof |
-
2003
- 2003-05-28 CN CNA031316239A patent/CN1481684A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013501739A (en) * | 2009-08-14 | 2013-01-17 | バイエル・クロップサイエンス・アーゲー | High concentration suspension concentrate of metribuzin without aluminum silicate |
| CN105265459A (en) * | 2015-10-28 | 2016-01-27 | 泰安市农业科学研究院 | Weeding composition containing triaziflam and isoproturon |
| CN120753274A (en) * | 2025-08-27 | 2025-10-10 | 山东潍坊润丰化工股份有限公司 | Herbicidal composition and use thereof |
| CN120753274B (en) * | 2025-08-27 | 2025-11-14 | 山东潍坊润丰化工股份有限公司 | Herbicidal Compositions and Their Applications |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |