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CN1473949A - Aluminium alloy foil and its producing method - Google Patents

Aluminium alloy foil and its producing method Download PDF

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Publication number
CN1473949A
CN1473949A CNA031322131A CN03132213A CN1473949A CN 1473949 A CN1473949 A CN 1473949A CN A031322131 A CNA031322131 A CN A031322131A CN 03132213 A CN03132213 A CN 03132213A CN 1473949 A CN1473949 A CN 1473949A
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temperature
mentioned
rolling
ingot blank
thick
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Inventor
沈健生
李振芳
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Priority to CNA031322131A priority Critical patent/CN1473949A/en
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Abstract

The present invention discloses a kind of aluminum alloy foil for heat exchanger of air conditioner, cooler, heater unit, radiator, etc. in automobile and its production process. The aluminum alloy foil is produced with Al, Fe, Si, Mn, Zn, Cu, Mg, Zr and Ti, and through smelting, casting, homogenizing, cutting, milling, heating, rolling, annealing, finish rolling and other steps. The aluminum alloy foil thus produced has no deformation, subsidence and collapse.

Description

A kind of alloy foil and production method thereof
(1) technical field
The present invention relates to a kind of aluminium foil and production method thereof.Specifically, be interchanger such as motorcar air conditioner, charge air cooler, warm-air drier and water tank alloy foil and production methods thereof.
(2) background technology
At present, employed alloy foil on the interchanger such as motorcar air conditioner, charge air cooler, warm-air drier and water tank mainly is 3003 or the 3A21 aluminium foil.The former is made by raw materials such as silicon, iron, copper and manganese, and the latter is made by raw materials such as silicon, iron, copper, manganese and titaniums.Because these two kinds of aluminium foils do not have the anodic protection effect, can increase the spot corrosion of aluminium foil when soldering.Therefore, the aluminium foil of these two kinds of trades mark when soldering, all be easy to generate the distortion and subside.
Because the fusing point of these two kinds of trade mark aluminium foils is all very low, and fusing point one is low, its recrystallization temperature is just low again.So, the distortion in the time of also can making soldering strengthens.
On the other hand, manganic compound is the key that improves solidus temperature, and 3003 and two kinds of trade mark aluminium foils of 3A21 in the content of manganese all lower.The content one of manganese is low, and solidus temperature is just low.Therefore, the solidus temperature of these two kinds of trade mark aluminium foils is all lower.The situation of also easily subsiding during soldering.
Though can overcome the distortion of above-mentioned two kinds of aluminium foils and subside the raising that increase thickness can bring user's production cost again by increasing thickness.All more than 0.15mm, under the pursuit of most current cost target, moreover the thickness of aluminium foil just develops towards more and more thinner direction the aluminum foil thickness of above-mentioned two kinds of trades mark.Therefore, above-mentioned two kinds of trade mark aluminium foils are inapplicable.
In addition, in traditional aluminium foil production method, be after being rolled down to finished product thickness, just carry out anneal, can make fibrous crystal grain return near round shape crystal grain.So, when soldering, the silicon of soldering place easily is diffused into the inside of aluminium foil base material, and then aluminium foil is formed melt erosion and be out of shape.Therefore, the reviewing phenomenon often appears.
(3) summary of the invention
The purpose of this invention is to provide a kind of alloy foil.This alloy foil can not be out of shape and subside during soldering.
Another object of the present invention provides a kind of production method of alloy foil.The alloy foil of Sheng Chaning the reviewing phenomenon can not occur during soldering in this way.
Above-mentioned purpose of the present invention is realized by following technical solution:
Alloy foil of the present invention, make by the raw material of following parts by weight:
0.4~0.8 part of iron; 0.6~1.0 part of silicon; 1.4~1.7 parts in manganese; 1.3~1.6 parts on zinc; 0.01~0.05 part of copper; 0.01~0.05 part in magnesium; 0.05~0.15 part of zirconium; 0.03~0.15 part of titanium.
Produce the method for above-mentioned alloy foil, may further comprise the steps successively:
(1) melting
Iron, silicon, manganese, zinc, copper, magnesium, zirconium and titanium are put into the flame reverberatory furnace, and be heated to 750~770 ℃, make these raw material fusings; Afterwards, add degasifier, carry out refining; Said degasifier is according to Repone K: the ratio of sodium-chlor=1: 1 and making;
(2) casting
Under 680~700 ℃ temperature, above-mentioned molten metal is cast as ingot blank with 65~90mm/ minute speed;
(3) homogenizing is handled
It is 580~600 ℃ electric furnace that above-mentioned ingot blank is put into temperature, and constant temperature kept 25~28 hours, carries out homogenizing and handles;
(4) sawing with mill face
The ingot blank of handling through homogenizing is carried out sawing, and saw removes its head, tail; Then, two big face is carried out milling, eliminate defective with milling machine;
(5) heat treated
To put into process furnace through sawing and the ingot blank that mills face, under 480~520 ℃ temperature, keep 10~12 hours;
(6) hot rolling
Is that 480~520 ℃ ingot blank carries out hot rolling with milling train to temperature, is rolled into the thin plate that thickness is 6.5~7mm;
(7) middle temperature rolling
Being lower than under 220 ℃ the temperature, above-mentioned sheet rolling is become the thick thin plate of 3~3.5mm;
(8) cold roughing.
At normal temperatures, above-mentioned 3~3.5mm is thick sheet rolling becomes the thick thin plate of 1.8~2.0mm;
(9) roll in cold
At normal temperatures, sheet rolling that above-mentioned 1.8~2.0mm is thick becomes the aluminium foil of 0.18~0.2mm;
(10) anneal
It is 410~430 ℃ electric furnace that the aluminium foil of above-mentioned 0.18~0.2mm is put into temperature, and constant temperature kept 10~14 hours, carried out anneal;
(11) cold finish rolling
To become 0.1~0.12mm thick through the aluminum foil rolling that anneal is crossed with finishing mill, be alloy foil of the present invention.
Adopt such scheme, have the following advantages:
Because contain zinc in the alloy foil prescription of the present invention, zincification has 2 effects: the one, the corrosion potential of alloy foil is reduced, zincification is many more, and current potential descends many more, and the foil of zincification is preferentially corroded as anode, thus the protective medium passage; The 2nd, can reduce the passive film intensity of alloy foil, it is peeled off easily and become general corrosion, thus the purpose that reaches distortion when suppressing spot corrosion and then prevention soldering and subside.
Owing to contain pick in the present invention's prescription,, add the recrystallization temperature that pick can be improved alloy foil again because of the fusing point of pick is high especially.So, also can play the effect that increases welding strength indirectly.Thereby the distortion when having avoided soldering.
Because suitably heightened the content of silicon in the prescription of the present invention, flowability improves when making soldering, has increased clearance filling capability and has made the welding zone homogeneous microstructure fine and closely woven, thereby improved brazing quality.
Owing to improved the content of manganese in the prescription of the present invention, its objective is in order to increase the calorize manganic compound.This compound can obviously improve the solidus temperature of alloy foil, thereby has increased the hot strength of alloy foil, the reviewing when having prevented soldering.
In addition, in production method, carry out cold finish rolling after the employing annealing, adopt the ideal working modulus, the suitable elongation of control crystal grain can stop scolder to its internal divergence when soldering, to guarantee enough solidus temperatures.Also played anti-purpose of subsiding.
(4) embodiment
Below in conjunction with embodiment the present invention is described in further detail:
First embodiment
Choose 0.4 part iron, 0.8 part silicon, 1.7 parts manganese, 1.5 parts zinc, 0.01 part copper, 0.03 part magnesium, 0.10 part zirconium and 0.15 part titanium earlier, stand-by.
Then, carry out melting
Iron, silicon, manganese, zinc, copper, magnesium, zirconium and titanium are put into the flame reverberatory furnace, and be heated to 750 ℃, make these raw material fusings; Afterwards, add degasifier, carry out refining; Said degasifier is according to Repone K: the ratio of sodium-chlor=1: 1 and making.
Afterwards, cast
Under 700 ℃ temperature, above-mentioned molten metal is cast as ingot blank with 80mm/ minute speed.
Afterwards, carrying out homogenizing handles
It is 580 ℃ electric furnace that above-mentioned ingot blank is put into temperature, and constant temperature kept 28 hours, carries out homogenizing and handles.
Afterwards, carry out sawing and mill face
The ingot blank of handling through homogenizing is carried out sawing, and saw removes its head, tail; Then, two big face is carried out milling, eliminate defective with milling machine.
Afterwards, carry out heat treated
To put into process furnace through sawing and the ingot blank that mills face, under 500 ℃ temperature, keep 10 hours.
Afterwards, carry out hot rolling
Is that 500 ℃ ingot blank carries out hot rolling with milling train to temperature, is rolled into the thin plate that thickness is 6.5mm.
Afterwards, carry out middle temperature rolling
Being lower than under 220 ℃ the temperature, above-mentioned sheet rolling is become the thick thin plate of 3mm.
Afterwards, carry out cold roughing.
At normal temperatures, above-mentioned 3mm is thick sheet rolling becomes the thick thin plate of 1.8mm.
Afterwards, carry out rolling in cold
At normal temperatures, sheet rolling that above-mentioned 1.8mm is thick becomes the aluminium foil of 0.18mm.
Again, carry out anneal
It is 410 ℃ electric furnace that the aluminium foil of above-mentioned 0.18mm is put into temperature, and constant temperature kept 10 hours, carried out anneal.
At last, carry out cold finish rolling
To become 0.1mm thick through the aluminum foil rolling that anneal is crossed with finishing mill, promptly obtain alloy foil of the present invention.
Second embodiment
Choose 0.6 part iron, 1.0 parts silicon, 1.5 parts manganese, 1.3 parts zinc, 0.03 part copper, 0.05 part magnesium, 0.15 part zirconium and 0.04 part titanium earlier, stand-by.
Then, carry out melting
Iron, silicon, manganese, zinc, copper, magnesium, zirconium and titanium are put into the flame reverberatory furnace, and be heated to 760 ℃, make these raw material fusings; Afterwards, add degasifier, carry out refining; Said degasifier is according to Repone K: the ratio of sodium-chlor=1: 1 and making.
Afterwards, cast
Under 680 ℃ temperature, above-mentioned molten metal is cast as ingot blank with 90mm/ minute speed.
Afterwards, carrying out homogenizing handles
It is 590 ℃ electric furnace that above-mentioned ingot blank is put into temperature, and constant temperature kept 26 hours, carries out homogenizing and handles.
Afterwards, carry out sawing and mill face
The ingot blank of handling through homogenizing is carried out sawing, and saw removes its head, tail; Then, two big face is carried out milling, eliminate defective with milling machine.
Afterwards, carry out heat treated
To put into process furnace through sawing and the ingot blank that mills face, under 480 ℃ temperature, keep 11 hours.
Afterwards, carry out hot rolling
Is that 480 ℃ ingot blank carries out hot rolling with milling train to temperature, is rolled into the thin plate that thickness is 6.8mm.
Afterwards, carry out middle temperature rolling
Being lower than under 220 ℃ the temperature, above-mentioned sheet rolling is become the thick thin plate of 3.3mm.
Afterwards, carry out cold roughing.
At normal temperatures, above-mentioned 3.3mm is thick sheet rolling becomes the thick thin plate of 1.9mm.
Afterwards, carry out rolling in cold
At normal temperatures, sheet rolling that above-mentioned 1.9mm is thick becomes the aluminium foil of 0.19mm.
Again, carry out anneal
It is 420 ℃ electric furnace that the aluminium foil of above-mentioned 0.19mm is put into temperature, and constant temperature kept 12 hours, carried out anneal.
At last, carry out cold finish rolling
To become 0.11mm thick through the aluminum foil rolling that anneal is crossed with finishing mill, promptly obtain alloy foil of the present invention.
The 3rd embodiment
Choose 0.8 part iron, 0.6 part silicon, 1.4 parts manganese, 1.6 parts zinc, 0.05 part copper, 0.01 part magnesium, 0.05 part zirconium and 0.03 part titanium earlier, stand-by.
Then, carry out melting
Iron, silicon, manganese, zinc, copper, magnesium, zirconium and titanium are put into the flame reverberatory furnace, and be heated to 770 ℃, make these raw material fusings; Afterwards, add degasifier, carry out refining; Said degasifier is according to Repone K: the ratio of sodium-chlor=1: 1 and making.
Afterwards, cast
Under 690 ℃ temperature, above-mentioned molten metal is cast as ingot blank with 70mm/ minute speed.
Afterwards, carrying out homogenizing handles
It is 600 ℃ electric furnace that above-mentioned ingot blank is put into temperature, and constant temperature kept 25 hours, carries out homogenizing and handles.
Afterwards, carry out sawing and mill face
The ingot blank of handling through homogenizing is carried out sawing, and saw removes its head, tail; Then, two big face is carried out milling, eliminate defective with milling machine.
Afterwards, carry out heat treated
To put into process furnace through sawing and the ingot blank that mills face, under 520 ℃ temperature, keep 12 hours.
Afterwards, carry out hot rolling
Is that 520 ℃ ingot blank carries out hot rolling with milling train to temperature, is rolled into the thin plate that thickness is 7mm.
Afterwards, carry out middle temperature rolling
Being lower than under 220 ℃ the temperature, above-mentioned sheet rolling is become the thick thin plate of 3.5mm.
Afterwards, carry out cold roughing.
At normal temperatures, above-mentioned 3.5mm is thick sheet rolling becomes the thick thin plate of 2.0mm.
Afterwards, carry out rolling in cold
At normal temperatures, sheet rolling that above-mentioned 2.0mm is thick becomes the aluminium foil of 0.20mm.
Again, carry out anneal
It is 430 ℃ electric furnace that the aluminium foil of above-mentioned 0.20mm is put into temperature, and constant temperature kept 14 hours, carried out anneal.
At last, carry out cold finish rolling
To become 0.12mm thick through the aluminum foil rolling that anneal is crossed with finishing mill, promptly obtain alloy foil of the present invention.

Claims (2)

1. alloy foil is characterized in that being made by the raw material of following parts by weight:
0.4~0.8 part of iron; 0.6~1.0 part of silicon; 1.4~1.7 parts in manganese; 1.3~1.6 parts on zinc; 0.01~0.05 part of copper; 0.01~0.05 part in magnesium; 0.05~0.15 part of zirconium; 0.03~0.15 part of titanium.
2. produce the method for above-mentioned alloy foil, it is characterized in that may further comprise the steps successively:
(1) melting
Iron, silicon, manganese, zinc, copper, magnesium, zirconium and titanium are put into the flame reverberatory furnace, and be heated to 750~770 ℃, make these raw material fusings; Afterwards, add degasifier, carry out refining; Said degasifier is according to Repone K: the ratio of sodium-chlor=1: 1 and making;
(2) casting
Under 680~700 ℃ temperature, above-mentioned molten metal is cast as ingot blank with 65~90mm/ minute speed;
(3) homogenizing is handled
It is 580~600 ℃ electric furnace that above-mentioned ingot blank is put into temperature, and constant temperature kept 25~28 hours, carries out homogenizing and handles;
(4) sawing with mill face
The ingot blank of handling through homogenizing is carried out sawing, and saw removes its head, tail; Then, two big face is carried out milling, eliminate defective with milling machine;
(5) heat treated
To put into process furnace through sawing and the ingot blank that mills face, under 480~520 ℃ temperature, keep 10~12 hours;
(6) hot rolling
Is that 480~520 ℃ ingot blank carries out hot rolling with milling train to temperature, is rolled into the thin plate that thickness is 6.5~7mm;
(7) middle temperature rolling
Being lower than under 220 ℃ the temperature, above-mentioned sheet rolling is become the thick thin plate of 3~3.5mm;
(8) cold roughing.
At normal temperatures, above-mentioned 3~3.5mm is thick sheet rolling becomes the thick thin plate of 1.8~2.0mm;
(9) roll in cold
At normal temperatures, sheet rolling that above-mentioned 1.8~2.0mm is thick becomes the aluminium foil of 0.18~0.2mm;
(10) anneal
It is 410~430 ℃ electric furnace that the aluminium foil of above-mentioned 0.18~0.2mm is put into temperature, and constant temperature kept 10~14 hours, carried out anneal;
(11) cold finish rolling
To become 0.1~0.12mm thick through the aluminum foil rolling that anneal is crossed with finishing mill, be alloy foil of the present invention.
CNA031322131A 2003-07-29 2003-07-29 Aluminium alloy foil and its producing method Pending CN1473949A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Publications (1)

Publication Number Publication Date
CN1473949A true CN1473949A (en) 2004-02-11

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Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100410405C (en) * 2006-07-04 2008-08-13 江苏常铝铝业股份有限公司 Aluminium alloy foil for founding and rolling automotive heat radiator fin billet and manufacturing method thereof
CN100507045C (en) * 2006-07-04 2009-07-01 江苏常铝铝业股份有限公司 Aluminum foil for hot rolling blank auto radiator fin and its production method
CN101798645A (en) * 2010-04-17 2010-08-11 上海交通大学 Aluminum alloy for heat exchanger fins and preparation method thereof
CN101818287A (en) * 2010-04-22 2010-09-01 江阴博威合金材料有限公司 Universal aluminium alloy air-conditioner foil and manufacturing method thereof
CN101182611B (en) * 2007-12-11 2010-10-13 乳源东阳光精箔有限公司 A kind of aluminum substrate for printing plate and its manufacturing method
CN101712117B (en) * 2008-10-06 2011-11-09 程拥军 Process for manufacturing light and thin aluminium alloy sheet materials
CN102337428A (en) * 2010-07-20 2012-02-01 东洋铝株式会社 Aluminum alloy foil and manufacture method thereof, aluminum alloy foil container, and food package body
CN102721316A (en) * 2012-06-19 2012-10-10 银邦金属复合材料股份有限公司 A kind of aluminum alloy radiator fin material
CN102732755A (en) * 2012-06-19 2012-10-17 银邦金属复合材料股份有限公司 Aluminum alloy material for processing automobile water tank radiator water pipe
CN101898200B (en) * 2009-12-16 2012-11-14 安徽工业大学 Direct rolling method of zinc ingots
CN103212574A (en) * 2013-04-15 2013-07-24 东北大学 Method for preparing aluminium alloy compound foil by compounding cold rolling and warm rolling
CN103402756A (en) * 2011-02-15 2013-11-20 联邦-莫古尔威斯巴登股份有限公司 Method for producing a lead-free, plated aluminium plain bearing
CN104550235A (en) * 2014-12-24 2015-04-29 镇江鼎胜铝业股份有限公司 Method for preparing PCB (Printed Circuit Board) aluminum foils by using cast-rolled slabs
CN105088021A (en) * 2015-08-14 2015-11-25 招商局铝业(重庆)有限公司 3003 hard-anodized aluminum alloy of black pot, and manufacturing method of 3003 hard-anodized aluminum alloy
CN106048479A (en) * 2016-08-16 2016-10-26 安徽天祥空调科技有限公司 Air conditioning radiator aluminum foil annealing process
CN107723524A (en) * 2017-11-10 2018-02-23 安徽华中天力铝业有限公司 A kind of 8150 electrolytic aluminium liquid Alloy Foils and its production technology
CN116043143A (en) * 2023-01-09 2023-05-02 江苏中基新能源科技集团有限公司 A kind of aluminum foil produced by cast-rolled slab and preparation method thereof

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100507045C (en) * 2006-07-04 2009-07-01 江苏常铝铝业股份有限公司 Aluminum foil for hot rolling blank auto radiator fin and its production method
CN100410405C (en) * 2006-07-04 2008-08-13 江苏常铝铝业股份有限公司 Aluminium alloy foil for founding and rolling automotive heat radiator fin billet and manufacturing method thereof
CN101182611B (en) * 2007-12-11 2010-10-13 乳源东阳光精箔有限公司 A kind of aluminum substrate for printing plate and its manufacturing method
CN101712117B (en) * 2008-10-06 2011-11-09 程拥军 Process for manufacturing light and thin aluminium alloy sheet materials
CN101898200B (en) * 2009-12-16 2012-11-14 安徽工业大学 Direct rolling method of zinc ingots
CN101798645A (en) * 2010-04-17 2010-08-11 上海交通大学 Aluminum alloy for heat exchanger fins and preparation method thereof
CN101798645B (en) * 2010-04-17 2012-01-04 上海交通大学 Aluminum alloy for heat exchanger fins and preparation method thereof
CN101818287A (en) * 2010-04-22 2010-09-01 江阴博威合金材料有限公司 Universal aluminium alloy air-conditioner foil and manufacturing method thereof
CN101818287B (en) * 2010-04-22 2011-12-28 江阴博威合金材料有限公司 Universal aluminium alloy air-conditioner foil and manufacturing method thereof
CN102337428A (en) * 2010-07-20 2012-02-01 东洋铝株式会社 Aluminum alloy foil and manufacture method thereof, aluminum alloy foil container, and food package body
CN103402756A (en) * 2011-02-15 2013-11-20 联邦-莫古尔威斯巴登股份有限公司 Method for producing a lead-free, plated aluminium plain bearing
CN103402756B (en) * 2011-02-15 2016-04-20 联邦-莫古尔威斯巴登股份有限公司 Manufacture the method for unleaded sliding bearing of aluminizing
CN102732755A (en) * 2012-06-19 2012-10-17 银邦金属复合材料股份有限公司 Aluminum alloy material for processing automobile water tank radiator water pipe
CN105333763A (en) * 2012-06-19 2016-02-17 银邦金属复合材料股份有限公司 Aluminium alloy radiator fin material
CN102721316A (en) * 2012-06-19 2012-10-10 银邦金属复合材料股份有限公司 A kind of aluminum alloy radiator fin material
CN103212574A (en) * 2013-04-15 2013-07-24 东北大学 Method for preparing aluminium alloy compound foil by compounding cold rolling and warm rolling
CN104550235A (en) * 2014-12-24 2015-04-29 镇江鼎胜铝业股份有限公司 Method for preparing PCB (Printed Circuit Board) aluminum foils by using cast-rolled slabs
CN105088021A (en) * 2015-08-14 2015-11-25 招商局铝业(重庆)有限公司 3003 hard-anodized aluminum alloy of black pot, and manufacturing method of 3003 hard-anodized aluminum alloy
CN106048479A (en) * 2016-08-16 2016-10-26 安徽天祥空调科技有限公司 Air conditioning radiator aluminum foil annealing process
CN107723524A (en) * 2017-11-10 2018-02-23 安徽华中天力铝业有限公司 A kind of 8150 electrolytic aluminium liquid Alloy Foils and its production technology
CN116043143A (en) * 2023-01-09 2023-05-02 江苏中基新能源科技集团有限公司 A kind of aluminum foil produced by cast-rolled slab and preparation method thereof

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