CN1449660A - Acetofenate solvent-free emalsible concentrate - Google Patents
Acetofenate solvent-free emalsible concentrate Download PDFInfo
- Publication number
- CN1449660A CN1449660A CN 03111562 CN03111562A CN1449660A CN 1449660 A CN1449660 A CN 1449660A CN 03111562 CN03111562 CN 03111562 CN 03111562 A CN03111562 A CN 03111562A CN 1449660 A CN1449660 A CN 1449660A
- Authority
- CN
- China
- Prior art keywords
- acetochlor
- solvent
- free
- missible oil
- emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- FSGNOVKGEXRRHD-UHFFFAOYSA-N [2,2,2-trichloro-1-(3,4-dichlorophenyl)ethyl] acetate Chemical compound CC(=O)OC(C(Cl)(Cl)Cl)C1=CC=C(Cl)C(Cl)=C1 FSGNOVKGEXRRHD-UHFFFAOYSA-N 0.000 title 1
- 239000012141 concentrate Substances 0.000 title 1
- VTNQPKFIQCLBDU-UHFFFAOYSA-N Acetochlor Chemical compound CCOCN(C(=O)CCl)C1=C(C)C=CC=C1CC VTNQPKFIQCLBDU-UHFFFAOYSA-N 0.000 claims abstract description 79
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 23
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000004480 active ingredient Substances 0.000 claims description 22
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 claims description 14
- -1 polyoxyethylene nonylphenol Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- 239000003814 drug Substances 0.000 abstract description 7
- 230000001988 toxicity Effects 0.000 abstract description 4
- 231100000419 toxicity Toxicity 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 241001465754 Metazoa Species 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000004495 emulsifiable concentrate Substances 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 244000068988 Glycine max Species 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 231100000572 poisoning Toxicity 0.000 description 2
- 230000000607 poisoning effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241001060350 Acalypha Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 208000018380 Chemical injury Diseases 0.000 description 1
- 240000006122 Chenopodium album Species 0.000 description 1
- 235000009344 Chenopodium album Nutrition 0.000 description 1
- 241000233838 Commelina Species 0.000 description 1
- 244000058871 Echinochloa crus-galli Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000292697 Polygonum aviculare Species 0.000 description 1
- 235000006386 Polygonum aviculare Nutrition 0.000 description 1
- 240000003461 Setaria viridis Species 0.000 description 1
- 235000002248 Setaria viridis Nutrition 0.000 description 1
- 235000010086 Setaria viridis var. viridis Nutrition 0.000 description 1
- 240000008866 Ziziphus nummularia Species 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention is formed from acetochlor and emulsifier, the mass percentage content of the acetochlor effective component in the acetochlar raw medicine is 95.0-100, its emulsifier is formed from calcium dodecylbenzenesulfonate and nouylphenol polyethenoxy ether, their mass ratio is 1:1-1.4 and the dose of the emulsifier is 5-12% of total mass of acetochlar solventless emulsifiable concentrate. Said invention is tow in toxicity, safe for production, transportation, storage and application, can reduce toxicity to crops, people and animals, and can reduce environmental pollution, does not produce insecticide burn and its inserticidal effect is good.
Description
Technical field: the present invention relates to a kind of agricultural chemicals.
Background technology: existing missible oil is that pesticide original medicine ratio in accordance with regulations is dissolved in the organic solvent, the oily liquids of the homogeneous phase transparent that adds a certain amount of agricultural chemicals emulsifier special again and make, contain more organic solvent in traditional missible oil, because organic solvent belongs to inflammable thing, producing, firing accident all very easily takes place in transportation and the keeping, and organic solvent has the medicament of promotion to the crop epidermis, zoodermic osmosis, so it has increased the chance of medicament to chemical injury of crops and person poultry poisoning, and a large amount of organic solvents constantly is dispersed into natural world, can cause environmental pollution, influence natural, ecological.
Summary of the invention: the present invention overcomes the defective that the organic solvent existence is caused in traditional missible oil, thereby provide a kind of solvent-free missible oil of Acetochlor of not dosing any organic solvent, it is made up of acetochlor tc and emulsifier, the quality percentage composition of Acetochlor active ingredient is 95.0～100 in the acetochlor tc, described emulsifier is made up of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether, the mass ratio of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1～1.4, and the consumption of described emulsifier accounts for 5～12% of the solvent-free missible oil gross mass of Acetochlor.The present invention is the preparation that acetochlor tc and emulsifier are directly mixed, and does not wherein dose any organic solvent, and its toxicity is low, and production, storing and safe in utilization alleviate the toxicity to crop and people and animals, reduces the pollution to environment; Its good drug efficacy does not produce poisoning, increase yield significantly; And its technology is simple, and is easy and simple to handle, and the materials kind is few, has good value for applications.
Embodiment one: in the present embodiment, the adopted name of acetochlor tc: Acetochlor; Chemical name: 2 '-ethyl-6 '-methyl-N-(ethoxymethyl)-2-chloro acetanilide; Chemical structural formula:
Empirical formula: C
14H
20CINO
2Relative molecular mass: 269.77 (by international relative atomic masses in 1989); Physicochemical property: this product is blue to purple grease, ρ 1.1358g/cm
3(20 ℃) can ignore under the vapour pressure room temperature; Solvability (25 ℃): 223mg/l in the water; Stability: the EC preparation stabilization phase is (room temperature) more than 2 years.
Present embodiment is made up of acetochlor tc and emulsifier, the quality percentage composition of Acetochlor active ingredient is 95.0～100 in the acetochlor tc, described emulsifier is made up of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether, the mass ratio of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1～1.4, and the consumption of described emulsifier accounts for 5～12% of the solvent-free missible oil gross mass of Acetochlor.
During making, mix as emulsifier calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether standby according to the above ratio earlier; Then, acetochlor tc and the emulsifier that mixes are calculated inventory according to the above ratio, accurately drop in the preparation still metering back again, stirs sample analysis after a hour, puts into lautertuns after qualified to filter, and storing material after filtering gets final product in basin.
Embodiment two: in the present embodiment in the acetochlor tc quality percentage composition of Acetochlor active ingredient be 95.5～96.5.
Embodiment three: in the present embodiment in the acetochlor tc quality percentage composition of Acetochlor active ingredient be 97.0～98.0.
Embodiment four: in the present embodiment in the acetochlor tc quality percentage composition of Acetochlor active ingredient be 98.5～99.5.
Embodiment five: the mass ratio of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1.05～1.1 in the present embodiment.
Embodiment six: the mass ratio of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1.15～1.2 in the present embodiment.
Embodiment seven: the mass ratio of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1.25～1.3 in the present embodiment.
Embodiment eight: the consumption of emulsifier accounts for 5.5～7% of the solvent-free missible oil gross mass of Acetochlor in the present embodiment.
Embodiment nine: the consumption of emulsifier accounts for 7.5～9% of the solvent-free missible oil gross mass of Acetochlor in the present embodiment
Embodiment ten: the consumption of emulsifier accounts for 9.5～11% of the solvent-free missible oil gross mass of Acetochlor in the present embodiment.
Embodiment 11: in the present embodiment, the quality volume content of the Acetochlor active ingredient when 20 spend in every liter of missible oil is 948～1017g.
Embodiment 12: in the present embodiment, the quality volume content of the Acetochlor active ingredient when 20 spend in every liter of missible oil is 950～980g.
Embodiment 13: in the present embodiment, the quality volume content of the Acetochlor active ingredient when 20 spend in every liter of missible oil is 985～995g.
Embodiment 14: in the present embodiment, the quality volume content of the Acetochlor active ingredient when 20 spend in every liter of missible oil is 996～1015g.
Embodiment 15: in the present embodiment, Acetochlor active ingredient accounts for 85.0～91.0% of the solvent-free missible oil gross mass of Acetochlor.
Embodiment 16: in the present embodiment, Acetochlor active ingredient accounts for 85.5～86.5% of the solvent-free missible oil gross mass of Acetochlor.
Embodiment 17: in the present embodiment, Acetochlor active ingredient accounts for 87.0～87.5% of the solvent-free missible oil gross mass of Acetochlor.
Embodiment 18: in the present embodiment, Acetochlor active ingredient accounts for 88.0～90.0% of the solvent-free missible oil gross mass of Acetochlor.
Embodiment 19: in the present embodiment, the quality volume content of the Acetochlor active ingredient when 20 spend in every liter of missible oil is 1000g.
Embodiment 20: Acetochlor active ingredient accounts for 90% of the solvent-free missible oil gross mass of Acetochlor in the present embodiment.
Embodiment 21: the consumption of emulsifier accounts for 8% of the solvent-free missible oil gross mass of Acetochlor in the present embodiment.
Embodiment 22: the mass ratio of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1～1.2 in the present embodiment.
The main performance index that the present invention can reach sees the following form:
| Project name | Index | |
| Outward appearance | Brown or purple homogeneous phase transparent liquid does not have visible suspension and precipitation. | |
| Acetochlor content | % (m/m) | 85.0～91.0 |
| G/L (20 ℃) | 948～1017 | |
| Moisture, %≤ | 0.4 | |
| The pH value scope | 5.0～9.0 | |
| Stability of emulsion (diluting 200 times) | Qualified | |
| Low-temperature stability ※ | Qualified | |
| Heat storage stability ※ | Qualified | |
| Annotate: when ※ was ordinary production, per at least season check once | ||
The effect of preventing and kill off soybean weeds that product of the present invention had sees the following form:
| Handle medicament, dosage (commodity amount) ml/mu | Total preventive effect | The barnyard grass grass | Green foxtail | Acalypha copperleaf | Lamb's-quarters | Dayflower | Knotweed | Water sour jujube pin | |
| Embodiment 1 | ????135 | ????94.1 | ????100 | ????95 | ????88 | ??86 | ????98 | ??87 | ????78 |
| Embodiment 2 | ????135 | ????93.9 | ????98 | ????96 | ????90 | ??82 | ????98 | ??90 | ????81 |
| 50% acetochlor ec | ????250 | ????85.8 | ????93 | ????86 | ????80 | ??80 | ????88 | ??75 | ????72 |
| 90% acetochlor ec | ????140 | ????89.0 | ????95 | ????92 | ????84 | ??83 | ????87 | ??83 | ????75 |
| Dispenser (strain/m not 2) | ????302 | ????84 | ????77 | ????24 | ??28 | ????52 | ??22 | ????15 | |
Product of the present invention sees the following form to the influence of soybean fertility output:
| Dispenser period | Handle medicament, dosage (commodity amount) ml/mu | Plant height (cm) | 100-grain weight (g) | Output (kg/mu) | Rate of growth (%) |
| Broadcast the preceding closed soil of back seedling | Embodiment 1 135 | ????72.2 | ????19.3 | ????304.3 | ????66.7 |
| Embodiment 2 135 | ????71.8 | ????19.6 | ????300.9 | ????64.8 | |
| 50% acetochlor ec 250 | ????67.1 | ????16.5 | ????243.1 | ????33.1 | |
| 90% acetochlor ec 140 | ????69.4 | ????17.8 | ????276.5 | ????51.4 | |
| Contrast | Not dispenser (intertillage) | ????71.2 | ????16.3 | ????182.6 |
Claims (13)
1, the solvent-free missible oil of a kind of Acetochlor, it is characterized in that it is made up of acetochlor tc and emulsifier, the quality percentage composition of Acetochlor active ingredient is 95.0～100 in the acetochlor tc, described emulsifier is made up of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether, the mass ratio of calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1～1: 1.4, and the consumption of described emulsifier accounts for 5～12% of the solvent-free missible oil gross mass of Acetochlor.
2, the solvent-free missible oil of Acetochlor according to claim 1 is characterized in that described acetochlor tc active ingredient quality accounts for 85.5%～87.0% of the solvent-free missible oil gross mass of Acetochlor.
3, the solvent-free missible oil of Acetochlor according to claim 1 is characterized in that described acetochlor tc active ingredient quality accounts for 87.5%～89.5% of the solvent-free missible oil gross mass of Acetochlor.
4, the solvent-free missible oil of Acetochlor according to claim 1 is characterized in that described acetochlor tc active ingredient quality accounts for 89.6%～90.5% of the solvent-free missible oil gross mass of Acetochlor.
2, the solvent-free missible oil of Acetochlor according to claim 1, the quality percentage composition that it is characterized in that Acetochlor active ingredient in the described acetochlor tc is 95.5～96.5.
3, the solvent-free missible oil of Acetochlor according to claim 1, the quality percentage composition that it is characterized in that Acetochlor active ingredient in the described acetochlor tc is 97.0～98.0.
4, the solvent-free missible oil of Acetochlor according to claim 1, the quality percentage composition that it is characterized in that Acetochlor active ingredient in the described acetochlor tc is 98.5～99.5.
5, the solvent-free missible oil of Acetochlor according to claim 1, the mass ratio that it is characterized in that described calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1.05～1.1.
6, the solvent-free missible oil of Acetochlor according to claim 1, the mass ratio that it is characterized in that described calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1.15～1.2.
7, the solvent-free missible oil of Acetochlor according to claim 1, the mass ratio that it is characterized in that described calcium dodecyl benzene sulfonate and polyoxyethylene nonylphenol ether is 1: 1.25～1.3.
8, the solvent-free missible oil of Acetochlor according to claim 1 is characterized in that the consumption of described emulsifier accounts for 5.5～7% of the solvent-free missible oil gross mass of Acetochlor.
9, the solvent-free missible oil of Acetochlor according to claim 1 is characterized in that the consumption of described emulsifier accounts for 7.5～9% of the solvent-free missible oil gross mass of Acetochlor.
10, the solvent-free missible oil of Acetochlor according to claim 1 is characterized in that the consumption of described emulsifier accounts for 9.5～11% of the solvent-free missible oil gross mass of Acetochlor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03111562 CN1449660A (en) | 2003-04-25 | 2003-04-25 | Acetofenate solvent-free emalsible concentrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03111562 CN1449660A (en) | 2003-04-25 | 2003-04-25 | Acetofenate solvent-free emalsible concentrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1449660A true CN1449660A (en) | 2003-10-22 |
Family
ID=28683967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03111562 Pending CN1449660A (en) | 2003-04-25 | 2003-04-25 | Acetofenate solvent-free emalsible concentrate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1449660A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070191230A1 (en) * | 2006-02-15 | 2007-08-16 | Pompeo Michael P | Emulsifier system and pesticidal formulations containing the emulsifier system |
| CN102428917A (en) * | 2011-11-23 | 2012-05-02 | 西南大学 | Acetochlor nanoemulsion and preparation method thereof |
| WO2015014767A1 (en) * | 2013-07-31 | 2015-02-05 | Akzo Nobel Chemicals International B.V. | Solvent free liquid alkylbenzene sulfonate composition and its use in agrochemical formulations |
-
2003
- 2003-04-25 CN CN 03111562 patent/CN1449660A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070191230A1 (en) * | 2006-02-15 | 2007-08-16 | Pompeo Michael P | Emulsifier system and pesticidal formulations containing the emulsifier system |
| US9072294B2 (en) * | 2006-02-15 | 2015-07-07 | Cognis Ip Management Gmbh | Emulsifier system and pesticidal formulations containing the emulsifier system |
| CN102428917A (en) * | 2011-11-23 | 2012-05-02 | 西南大学 | Acetochlor nanoemulsion and preparation method thereof |
| WO2015014767A1 (en) * | 2013-07-31 | 2015-02-05 | Akzo Nobel Chemicals International B.V. | Solvent free liquid alkylbenzene sulfonate composition and its use in agrochemical formulations |
| CN105377030A (en) * | 2013-07-31 | 2016-03-02 | 阿克佐诺贝尔化学国际公司 | Solvent free liquid alkylbenzene sulfonate composition and its use in agrochemical formulations |
| CN105377030B (en) * | 2013-07-31 | 2018-01-19 | 阿克佐诺贝尔化学国际公司 | Solvent-free liquid alkyl benzene sulfonate composition and its purposes in agrochemical formulation |
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