CN1444234A - Preparation method of glass fibre fabric conductive material - Google Patents
Preparation method of glass fibre fabric conductive material Download PDFInfo
- Publication number
- CN1444234A CN1444234A CN03112158A CN03112158A CN1444234A CN 1444234 A CN1444234 A CN 1444234A CN 03112158 A CN03112158 A CN 03112158A CN 03112158 A CN03112158 A CN 03112158A CN 1444234 A CN1444234 A CN 1444234A
- Authority
- CN
- China
- Prior art keywords
- glass fabric
- preparation
- glass
- conducting material
- electric conducting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 29
- 239000003365 glass fiber Substances 0.000 title claims abstract description 14
- 239000004020 conductor Substances 0.000 title claims description 10
- 238000002360 preparation method Methods 0.000 title claims description 9
- 239000000463 material Substances 0.000 claims abstract description 18
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 15
- 229910052802 copper Inorganic materials 0.000 claims abstract description 13
- 239000011159 matrix material Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 7
- 229910052709 silver Inorganic materials 0.000 claims abstract description 3
- 239000011521 glass Substances 0.000 claims description 27
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 26
- 238000007747 plating Methods 0.000 claims description 21
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 11
- 238000009713 electroplating Methods 0.000 claims description 7
- 238000005516 engineering process Methods 0.000 claims description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 238000004544 sputter deposition Methods 0.000 claims description 2
- 238000012216 screening Methods 0.000 abstract description 3
- 238000009434 installation Methods 0.000 abstract description 2
- 230000009970 fire resistant effect Effects 0.000 abstract 1
- 229910000595 mu-metal Inorganic materials 0.000 abstract 1
- 238000001771 vacuum deposition Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000011017 operating method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- -1 150g/m 2 Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/50—Glass production, e.g. reusing waste heat during processing or shaping
- Y02P40/57—Improving the yield, e-g- reduction of reject rates
Landscapes
- Laminated Bodies (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
A method for preparing glass fiber fabric conduction material includes vacuum coating with Ni or Cu, then continuously coated with Ni, Cu, Ag or Mu metal layer on glass fiber cloth, net and felt matrix. This invented material can be retardant, fire resistant, suitable for screening materials of space and military installations or screening materials of electronic and precision instruments.
Description
(1) technical field
The present invention relates to a kind of to insulation, fire-retardant, software glass fabric (containing glass fabric, net, felt) conduction processing, prepare the method for composite conducting material (shielding material), belong to that vacuum is plated, the electroplating technology field.
(2) technical background
Along with science and technology development, the electronic technology product has goed deep into huge numbers of families' life neutralization industry, military, each corner such as space flight, household electrical appliance, mobile phone, the computer office automation, Medical Devices, military applications etc., if there is not electronic technology, no matter in the field of study or industrial circle, can not obtain the achievement of today, because the increase of these equipment, electromagnetic interference is also increasing, and electronic instrument caused distorted signals, error, cause instrument damage, its loss is difficult to estimate, so the exploitation of electromagnetic wave screen fabric (electroconductive glass fibre fabric) is arisen at the historic moment.At present, domestic main employing metal oxide-coated, chemical plating, be coated with technologies such as conducting resinl, not only can not satisfy the requirement of environmental protection and product quality, the chemical plating cost is higher, and more serious pollution arranged, and the easily oxidation of glass fabric surface of general vacuum plating software, and electromagnet shield effect is lower, sheet resistance is higher, only reach generally that 8 Ω/more than the cm, originally the software base material of Shi Yonging all is fibers material and polyurethane, Yi Ran, non-refractory, can not be used for electronics at all, the shielding part of precision instrument and senior shielded enclosure, promptly original traditional handicraft and the raw material of selecting for use can't satisfy the requirement of modern industry.
(3) summary of the invention
The present invention is directed to prior art and use the defective of base material and method, the preparation method of the composite conducting material of a kind of good conductivity, resistance to oxidation, heat-resistant fireproof is provided.
Method of the present invention is included in vacuum nickel plating or copper on glass fabric, net or the felt matrix, the continuous electroplating coat of metal again.
Concrete technical scheme is as follows:
1, matrix: glass fabric, glass fiber mesh or glass mat.
Glass fabric: the thick 0.05mm～0.5mm of cloth, plain weave or twill, 30g/m
2～300g/m
2, glass fiber diameter: 0.008mm～0.06mm.
Glass fiber mesh: mesh is square, hexangle type or round, 30g/m
2～250g/m
2, 80 orders～200 order/inches, filament diameter: 0.04mm～0.08mm, thickness: 0.08mm～0.5mm.
Glass mat: thickness 0.02mm～1mm, 20g/m
2～300g/m
2, filament diameter: 0.006mm～0.028mm.
2, above-mentioned glass fabric, net or felt are plated plating method nickel plating or copper metal, 50 ℃～400 ℃ of temperature, vacuum degree 3 * 10 with vacuum under argon shield
-1Pa～9 * 10
-5Pa, matrix translational speed: 0.5m/ minute～5m/ minute, 0.1g/ square metre of ion sputtering concentration～3g/ square metre.
This moment, the material electric conductivity was R=5 Ω/cm～3 * 10
5Ω/cm.
3, adopt existing plastic electroplating technical matters to plate 2～4 kinds of coats of metal continuously then on above-mentioned material, institute's plating is nickel, copper, silver or golden, and order is not done special qualification.
This moment material surface resistance R=0.013 Ω/cm～3 Ω/cm.
With above-mentioned material flushing, oven dry, clot.
Compared with the prior art the present invention has following excellent results:
One, fire-retardant, high temperature resistant, be suitable for the shielding material and the indoor shielding material of space flight, military installations.
Two, because screening effectiveness height, sheet resistance are low, be suitable for the shielding part of making electronics and precision instrument.
Three, continuous mechanized of the present invention is produced, and human factor reduces, and quality is guaranteed that production efficiency also can significantly improve.
Four, material of the present invention is cheap, has overcome the pollution of prior art chemical plating again, has reduced production cost.
(4) embodiment
The present invention will be further described below in conjunction with embodiment, but be not limited thereto.Embodiment 1: glass fabric nickel plating 1, matrix: plain weave glass fabric, the thick 0.1mm of cloth, 150g/m
2, glass fibre filament diameter: 0.028mm.2, vacuum plating nickel plating under argon shield, is plated plating method nickel plating, temperature 180 ℃, vacuum chamber true temp 8.4 * 10 with vacuum with glass fabric
-5Pa, 1.8 meters/minute of glass fabric translational speeds, sputter nickel plating concentration 1.8g/m
23, adopt existing plastic electroplating technology on above-mentioned material, to plate layer of copper coating and one deck nickel coating continuously then.4, with above-mentioned material flushing, oven dry, clot embodiment 2: glass fiber mesh is silver-plated
Operating procedure such as embodiment 1, different is that matrix is a glass fiber mesh, the glass fiber mesh translational speed is 2m/ minute, the silver-plated 1.5g/m of sputter
2, continuous plating layer of copper coating and one deck silvering.Embodiment 3: copper facing on the glass mat
Operating procedure such as embodiment 1, different is that matrix is a glass mat, the glass mat translational speed is 1.4m/ minute, vacuum plating copper facing 2.2g/m
2, continuous plating one deck nickel coating and one deck silvering.Embodiment 4: as described in embodiment 1, different is:
Matrix is a glass fiber mesh, and mesh is a square, 80g/m
2, 135 order/inches, thickness: 0.06mm.Embodiment 5: as different is as described in the embodiment 1:
Matrix is a glass mat, thickness 0.11mm, 30g/m
2, filament diameter: 0.028mm.
Claims (6)
1. the preparation method of a glass fabric electric conducting material is included in vacuum nickel plating or copper on glass fabric, net or the felt matrix, again the continuous electroplating coat of metal.
2. the preparation method of glass fabric electric conducting material as claimed in claim 1 is characterized in that, glass fabric: the thick 0.05mm～0.5mm of cloth, plain weave or twill, 30g/m
2～300g/m
2, glass fiber diameter: 0.008mm～0.06mm.
3. the preparation method of glass fabric electric conducting material as claimed in claim 1 is characterized in that, glass fiber mesh: mesh is square, hexangle type or round, 30g/m
2～250g/m
2, 80 orders～200 order/inches, filament diameter: 0.04mm～0.08mm, thickness: 0.08mm～0.5mm.
4. the preparation method of glass fabric electric conducting material as claimed in claim 1 is characterized in that, glass mat: thickness 0.02mm～1mm, 20g/m
2～300g/m
2, filament diameter: 0.006mm～0.028mm.
5. the preparation method of glass fabric electric conducting material as claimed in claim 1; it is characterized in that; described vacuum nickel plating or copper are that glass fabric, net, felt are plated plating method nickel plating or copper metal, 50 ℃～400 ℃ of temperature, vacuum degree 3 * 10 with vacuum under argon shield
-1Pa～9 * 10
-5Pa, matrix translational speed: 0.5m/ minute～5m/ minute, ion sputtering concentration 0.1 gram/square metre～3 grams/square metre.
6. the preparation method of glass fabric electric conducting material as claimed in claim 1 is characterized in that, described continuous electroplating is to adopt the plastic electroplating technology to plate 2～4 kinds of coats of metal continuously on above-mentioned material, and institute's plating is nickel, copper, silver or golden.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031121586A CN1207735C (en) | 2003-04-15 | 2003-04-15 | Preparation method of glass fibre fabric conductive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031121586A CN1207735C (en) | 2003-04-15 | 2003-04-15 | Preparation method of glass fibre fabric conductive material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1444234A true CN1444234A (en) | 2003-09-24 |
| CN1207735C CN1207735C (en) | 2005-06-22 |
Family
ID=27814611
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031121586A Expired - Lifetime CN1207735C (en) | 2003-04-15 | 2003-04-15 | Preparation method of glass fibre fabric conductive material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1207735C (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100338301C (en) * | 2005-05-20 | 2007-09-19 | 长沙鑫邦工程新材料技术有限公司 | Preparation method of conductive dacron fabric for electromagnetic wave shielding |
| US7688036B2 (en) | 2006-06-26 | 2010-03-30 | Battelle Energy Alliance, Llc | System and method for storing energy |
| CN102286254A (en) * | 2011-05-06 | 2011-12-21 | 广州方邦电子有限公司 | High-peeling-strength conductive adhesive film with through holes and preparation method thereof |
| CN102421277A (en) * | 2011-08-08 | 2012-04-18 | 深圳昊天龙邦复合材料有限公司 | Shielding material with aromatic synthetic fiber paper as base material |
| CN102650088A (en) * | 2012-05-19 | 2012-08-29 | 扬州锦江有色金属有限公司 | Nuclear radiation shielding alloy lead fiber woven fabric |
| CN102701603A (en) * | 2012-05-29 | 2012-10-03 | 中南大学 | Preparation method for copper/zinc coating on surface of glass fiber |
| CN102729005A (en) * | 2012-05-31 | 2012-10-17 | 何玉忠 | Preparation method and application of metal fiber shielding felt |
| CN102756130A (en) * | 2012-07-11 | 2012-10-31 | 沈阳理工大学 | Preparation method of metal powder |
| CN105808002A (en) * | 2016-03-11 | 2016-07-27 | 上海万寅安全环保科技有限公司 | Wearable support plate |
| CN106993404A (en) * | 2017-05-02 | 2017-07-28 | 卜庆革 | Flexible and lightweight nickel-plated silver glass fiber, cloth and method for high temperature resistance, fire resistance, electromagnetic radiation damage and electromagnetic shielding |
| CN113512873A (en) * | 2021-05-28 | 2021-10-19 | 益阳市菲煌科技有限公司 | Conductive cloth and preparation method thereof |
-
2003
- 2003-04-15 CN CNB031121586A patent/CN1207735C/en not_active Expired - Lifetime
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100338301C (en) * | 2005-05-20 | 2007-09-19 | 长沙鑫邦工程新材料技术有限公司 | Preparation method of conductive dacron fabric for electromagnetic wave shielding |
| US7688036B2 (en) | 2006-06-26 | 2010-03-30 | Battelle Energy Alliance, Llc | System and method for storing energy |
| CN102286254A (en) * | 2011-05-06 | 2011-12-21 | 广州方邦电子有限公司 | High-peeling-strength conductive adhesive film with through holes and preparation method thereof |
| CN102421277B (en) * | 2011-08-08 | 2014-11-12 | 深圳昊天龙邦复合材料有限公司 | Shielding material with aromatic synthetic fibre paper as base material |
| CN102421277A (en) * | 2011-08-08 | 2012-04-18 | 深圳昊天龙邦复合材料有限公司 | Shielding material with aromatic synthetic fiber paper as base material |
| CN102650088A (en) * | 2012-05-19 | 2012-08-29 | 扬州锦江有色金属有限公司 | Nuclear radiation shielding alloy lead fiber woven fabric |
| CN102701603A (en) * | 2012-05-29 | 2012-10-03 | 中南大学 | Preparation method for copper/zinc coating on surface of glass fiber |
| CN102729005A (en) * | 2012-05-31 | 2012-10-17 | 何玉忠 | Preparation method and application of metal fiber shielding felt |
| CN102729005B (en) * | 2012-05-31 | 2014-05-21 | 何玉忠 | Preparation method and application of metal fiber shielding felt |
| CN102756130A (en) * | 2012-07-11 | 2012-10-31 | 沈阳理工大学 | Preparation method of metal powder |
| CN105808002A (en) * | 2016-03-11 | 2016-07-27 | 上海万寅安全环保科技有限公司 | Wearable support plate |
| CN106993404A (en) * | 2017-05-02 | 2017-07-28 | 卜庆革 | Flexible and lightweight nickel-plated silver glass fiber, cloth and method for high temperature resistance, fire resistance, electromagnetic radiation damage and electromagnetic shielding |
| CN113512873A (en) * | 2021-05-28 | 2021-10-19 | 益阳市菲煌科技有限公司 | Conductive cloth and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1207735C (en) | 2005-06-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1207735C (en) | Preparation method of glass fibre fabric conductive material | |
| Jiang et al. | Electromagnetic shielding and corrosion resistance of electroless Ni–P/Cu–Ni multilayer plated polyester fabric | |
| US7105234B2 (en) | Flame retardant corrosive resistant conductive fabric article and method | |
| CN1268803C (en) | Nickel-copper composite metal textile and preparation method thereof | |
| CN201174256Y (en) | Electricity conductive shielding fabric | |
| CN105960155A (en) | Flexible transparent conductive material for electromagnetic shielding window, and preparation method | |
| Zhang et al. | Flexible Ni-Fe-P/PPy@ PI fiber paper-based composites with three-layer structure for 5 G electromagnetic shielding applications | |
| CN1276127C (en) | Silver coating fabric making method | |
| CN105755819B (en) | A kind of fire-type is electromagnetically shielded Antiradiation protection cloth | |
| US20070095567A1 (en) | EMI vent panels including electrically-conductive porous substrates and meshes | |
| CN2640204Y (en) | Omnibearing conductive foamed cotton | |
| CN201160361Y (en) | Conductive fiber cloth for electromagnetic shielding | |
| CN205934535U (en) | Metallization coating screen cloth | |
| CN2848891Y (en) | Weaving machine radiation proof surface material made of yarn containing conductive fiber | |
| CN102421277B (en) | Shielding material with aromatic synthetic fibre paper as base material | |
| CN2720576Y (en) | Electromagnetic shield cloth | |
| CN109371668A (en) | A kind of electromagnetic shielding anti-radiation electric conduction cloth | |
| CN1359110A (en) | Method for preparing composite conductive material | |
| CN203490951U (en) | Shielding filament and screen mesh used for electromagnetic shielding glass | |
| US20030134558A1 (en) | Metallized fiber structure and its manufacturing method | |
| Peng et al. | Polysufonamide/stainless steel woven fabrics: manufacturing techniques, flame retardance and electromagnetic shielding effectiveness | |
| RU2338021C1 (en) | Metallised material ''nanotex'' | |
| CN207854402U (en) | A kind of conductive fabric with function of shielding | |
| CN1443872A (en) | Method for preparing polyester base conductive net fabric | |
| CN207657293U (en) | A kind of ultra-thin electromagnetic screening conductive cloth |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SHANDONG TIANNUO PHOTOELECTRIC MATERIALS CO., LTD Free format text: FORMER OWNER: XIA ZHILIN Effective date: 20040514 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20040514 Address after: High tech Zone Xinyu South Road Ji'nan city Shandong province 250101 first Qilu Software building room 212 Applicant after: Shandong Tiannuo Photoelectric Material Co.,Ltd. Address before: 250013 Shandong Province, Lixia District of Ji'nan city after the green area five 13 Building 2 unit 301 room Applicant before: Xia Zhilin |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Bao Guangming Document name: Notice of conformity |
|
| DD01 | Delivery of document by public notice |
Addressee: Limited by Share Ltd. responsible for collecting Tiannuo photoelectric material Document name: Notification that Application Deemed not to be Proposed |
|
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: Yuxing Road Flyover District of Ji'nan city in Shandong province 250119 New Material Industrial Park No. 517 Patentee after: TIANNUO PHOTOELECTRIC MATERIAL Co.,Ltd. Address before: High tech Zone Xinyu South Road Ji'nan city Shandong province 250101 first Qilu Software building room 212 Patentee before: Shandong Tiannuo Photoelectric Material Co.,Ltd. |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20050622 |