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CN1331780C - Integrative bioreactor for treating refuse leachate - Google Patents

Integrative bioreactor for treating refuse leachate Download PDF

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CN1331780C
CN1331780C CNB2004100888067A CN200410088806A CN1331780C CN 1331780 C CN1331780 C CN 1331780C CN B2004100888067 A CNB2004100888067 A CN B2004100888067A CN 200410088806 A CN200410088806 A CN 200410088806A CN 1331780 C CN1331780 C CN 1331780C
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CN1769211A (en
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梁祝
刘俊新
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GUIZHOU ACADEMY OF ENVIRONMENTAL SCIENCE AND DESIGNING
Research Center for Eco Environmental Sciences of CAS
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Abstract

本发明是一种处理垃圾渗滤液的一体化生物反应器,涉及环保技术。本发明由两个生物反应区和一个调节区组成,每个生物反应区内均填充生物填料,形成好氧区和厌氧区。在好氧区内,有机物被好氧异养菌降解为无机碳,并控制氨氮的硝化过程在亚硝化阶段,将50%的氨氮氧化为亚硝酸盐,好氧区的出水在调节区中与pH调节剂混合均匀后,进入厌氧区。在厌氧区,厌氧氨氧化菌以氨氮为电子供体还原亚硝酸盐,以亚硝酸盐为电子受体来氧化氨氮,将氨氮和亚硝态氮转变成氮气,部分有机物被其它厌氧微生物吸收或降解。本发明可在垃圾渗滤液低碳氮比的水质条件下完成氨氮和有机物的去除,调节垃圾渗滤液水质和水量的冲击负荷,运行高效稳定。

The invention relates to an integrated bioreactor for treating landfill leachate, which relates to the technology of environmental protection. The invention is composed of two biological reaction areas and a regulating area, and each biological reaction area is filled with biological filler to form an aerobic area and an anaerobic area. In the aerobic zone, organic matter is degraded into inorganic carbon by aerobic heterotrophic bacteria, and the nitrification process of ammonia nitrogen is controlled. In the nitrification stage, 50% of ammonia nitrogen is oxidized to nitrite, and the effluent from the aerobic zone is mixed with After the pH regulator is mixed evenly, it enters the anaerobic zone. In the anaerobic zone, anammox bacteria use ammonia nitrogen as the electron donor to reduce nitrite, use nitrite as the electron acceptor to oxidize ammonia nitrogen, convert ammonia nitrogen and nitrite nitrogen into nitrogen, and some organic matter is anaerobic. microbial uptake or degradation. The invention can complete the removal of ammonia nitrogen and organic matter under the water quality condition of low carbon-to-nitrogen ratio of landfill leachate, adjust the impact load of water quality and water quantity of landfill leachate, and operate efficiently and stably.

Description

一种处理垃圾渗滤液的一体化生物反应器An integrated bioreactor for treating landfill leachate

技术领域technical field

本发明涉及环保技术领域,涉及一体化生物反应器,特别是一种处理垃圾渗滤液的生物反应器。The invention relates to the technical field of environmental protection, and relates to an integrated bioreactor, in particular to a bioreactor for treating landfill leachate.

背景技术Background technique

垃圾渗滤液是一种危害较大、处理难度较大的高浓度氨氮废水。它含有多种污染物质,主要的水质特征:氨氮浓度高,且碳氮(C/N)的比例失调;BOD5/CODcr比值变化大,水质和水量的时间和地域变化性。目前国内外处理渗滤液的主要技术有生物处理和物化处理,物化处理技术虽有较好的处理效果,但成本昂贵,能耗大,易产生二次污染,生物处理技术由于具有经济简便等优点而被普遍采用。Landfill leachate is a kind of high-concentration ammonia-nitrogen wastewater that is harmful and difficult to treat. It contains a variety of pollutants, the main water quality characteristics: high concentration of ammonia nitrogen, and the imbalance of carbon and nitrogen (C/N) ratio; BOD 5 /CODcr ratio changes greatly, and the temporal and regional variability of water quality and water quantity. At present, the main technologies for treating leachate at home and abroad include biological treatment and physical and chemical treatment. Although physical and chemical treatment technology has a good treatment effect, it is expensive, energy-consuming, and prone to secondary pollution. Biological treatment technology has the advantages of economy and simplicity. And is generally adopted.

传统的生物脱氮包括生物好氧硝化和反硝化两个步骤,工艺流程如图5所示。污水输进反硝化池处理后,进入完全硝化池处理,完全硝化池出来的混合液,一部分回流入反硝化池二次处理,一部分进入二沉池沉淀,底层泥由下方输出,一部分回流入反硝化池二次处理,一部分排出,上层合格水由上方排出。Traditional biological denitrification includes two steps of biological aerobic nitrification and denitrification, and the process flow is shown in Figure 5. After the sewage is input into the denitrification tank for treatment, it enters the complete nitrification tank for treatment. Part of the mixed liquor from the complete nitrification tank flows back into the denitrification tank for secondary treatment, and part of it enters the secondary sedimentation tank for sedimentation. Secondary treatment in the nitrification tank, part of which is discharged, and the qualified water in the upper layer is discharged from the top.

该技术处理垃圾渗滤液,存在以下主要问题:This technology treats landfill leachate, and there are the following main problems:

(1)能耗大,1g氨氮完全硝化需耗氧4.57g。(1) High energy consumption, 4.57g of oxygen is required for complete nitrification of 1g of ammonia nitrogen.

(2)反硝化过程需要足够的有机碳源作为电子供体才能保证脱氮率。而对于高氨氮、低碳氮比(C/N)的垃圾渗滤液,难以有效地反硝化,使脱氮效率较低,而外加碳源不仅增加处理成本,还易造成二次污染(2) The denitrification process requires sufficient organic carbon sources as electron donors to ensure the denitrification rate. For landfill leachate with high ammonia nitrogen and low carbon-to-nitrogen ratio (C/N), it is difficult to effectively denitrify, resulting in low denitrification efficiency, and the addition of carbon sources not only increases the treatment cost, but also easily causes secondary pollution

(3)工艺流程复杂,污泥回流和混合液回流增加动力费用。(3) The technological process is complicated, and the return flow of sludge and mixed liquid increases the power cost.

垃圾渗滤液具有水质和水量的时间和地域变化性,目前的生物处理设施和反应装置不能很好地调节水质和水量的负荷冲击,存在运行不稳定,处理效率低等主要缺点。Landfill leachate has time and geographical variability of water quality and water quantity. The current biological treatment facilities and reaction devices cannot well adjust the load impact of water quality and water quantity, and have major shortcomings such as unstable operation and low treatment efficiency.

发明内容Contents of the invention

本发明的目的在于,克服现有处理设施面临的问题,将亚硝化与厌氧氨氧化技术相结合,提出一种能稳定、高效处理垃圾渗滤液的一体化生物反应器。The purpose of the present invention is to overcome the problems faced by existing treatment facilities, combine nitrification and anaerobic ammonia oxidation technology, and propose an integrated bioreactor capable of stably and efficiently treating landfill leachate.

为达到上述目的,本发明的技术解决方案是提供一种处理垃圾渗滤液的一体化生物反应器,为封闭的容器,由好氧生物反应区、厌氧生物反应区和调节区三部分组成,每个生物反应区内均有部分区域填充生物填料,并分别在好氧和厌氧条件下运行,调节区位于好氧区和厌氧区之间;In order to achieve the above object, the technical solution of the present invention is to provide an integrated bioreactor for treating landfill leachate, which is a closed container and consists of three parts: an aerobic biological reaction zone, an anaerobic biological reaction zone and a regulation zone. Part of each biological reaction zone is filled with biological fillers, and operates under aerobic and anaerobic conditions respectively, and the regulating zone is located between the aerobic zone and the anaerobic zone;

好氧生物反应区和厌氧生物反应区容腔内的上部、中部结构相同,在两区容腔内,上部上方各水平设有一横向支架,横向支架两端与侧壁固接,中部各设有三相分离器,三相分离器由中心筒和倒锥台构成,中心筒为倒T型,上端圆筒与支架中部固接,下端为喇叭口,中心筒喇叭口下方水平设置倒锥台,倒锥台的四周缘与容腔内壁固接,三相分离器下方各设有球型填料;The upper and middle structures of the aerobic bioreaction zone and the anaerobic bioreaction zone are the same. In the cavity of the two zones, a horizontal support is provided horizontally above the upper part. There is a three-phase separator. The three-phase separator is composed of a central cylinder and an inverted cone. The central cylinder is an inverted T shape. The upper cylinder is fixed to the middle of the bracket. The lower end is a bell mouth. The surrounding edges of the inverted cone are fixed to the inner wall of the cavity, and spherical fillers are installed under the three-phase separators;

厌氧生物反应区容腔内的上部侧壁设有出水管;An outlet pipe is provided on the upper side wall of the chamber of the anaerobic biological reaction zone;

好氧生物反应区和厌氧生物反应区的顶部都设有水封盖,其中心上侧固接有气体排出管,两气体排出管的另一端接气体处理设备;The top of the aerobic biological reaction area and the anaerobic biological reaction area are equipped with water seals, and the upper side of the center is fixed with a gas discharge pipe, and the other ends of the two gas discharge pipes are connected to gas treatment equipment;

好氧生物反应区容腔内下部上方水平设有污水进水管,污水进水管下方水平设有曝气板,曝气板上有多个孔,其四周缘与容腔内壁固接,其下方侧壁设有进气管;There is a sewage inlet pipe horizontally above the lower part of the chamber in the aerobic biological reaction zone, and an aeration plate is arranged horizontally below the sewage water inlet pipe. The wall is provided with an air intake pipe;

厌氧生物反应区容腔内下部上方水平设有布水板,布水板上有多个布水孔,其四周缘与容腔内壁固接,其下方水平设有加热管,加热管从侧壁穿出后与加热设备相连;There is a water distribution plate horizontally above the lower part of the chamber in the anaerobic biological reaction zone. There are multiple water distribution holes on the water distribution board. The surrounding edges are fixed to the inner wall of the chamber. After the wall passes through, it is connected to the heating equipment;

好氧生物反应区与调节区相邻的侧壁上方有出水口,将好氧生物反应区和调节区连通;There is a water outlet above the side wall adjacent to the aerobic bioreaction area and the adjustment area, which connects the aerobic bioreaction area and the adjustment area;

厌氧生物反应区与调节区相邻的侧壁下方有进水口,将厌氧生物反应区和调节区连通;There is a water inlet below the side wall adjacent to the anaerobic biological reaction zone and the regulating zone, which connects the anaerobic biological reaction zone and the regulating zone;

调节区的容腔顶端设有加药管,加药管外端与加药设备相通。A dosing pipe is provided at the top of the chamber in the regulating area, and the outer end of the dosing pipe communicates with the dosing equipment.

所述的一体化生物反应器,其所述好氧生物反应区的外侧壁上还设有插口,插口上安装溶解氧监测计电极;In the integrated bioreactor, a socket is also provided on the outer wall of the aerobic bioreaction zone, and a dissolved oxygen monitor electrode is installed on the socket;

厌氧生物反应区的外侧壁上,上方的出水管与反应器好氧区的污水进水管相通,在出水管与污水进水管连通的管路上设有回流泵,下方设有pH和温度监测计、氧化还原电位监测计;On the outer wall of the anaerobic biological reaction zone, the upper outlet pipe communicates with the sewage inlet pipe in the aerobic zone of the reactor, a return pump is installed on the pipeline connecting the outlet pipe and the sewage inlet pipe, and a pH and temperature monitor is installed below , redox potential monitor;

调节区的容腔内,设有布水装置。A water distribution device is provided in the cavity of the regulating area.

所述的一体化生物反应器,其所述加热管为多个,汇入一根总管,总管从侧壁穿出后与加热设备相连。In the integrated bioreactor, there are a plurality of heating pipes, which merge into a main pipe, and the main pipe passes through the side wall and is connected with the heating equipment.

所述的一体化生物反应器,其所述布水装置,由出水槽和配水管组成,配水管又分为配水干管、配水支管;布水装置有三种结构。In the integrated bioreactor, the water distribution device is composed of a water outlet tank and a water distribution pipe, and the water distribution pipe is further divided into a water distribution main pipe and a water distribution branch pipe; the water distribution device has three structures.

所述的一体化生物反应器,其所述布水装置的三种结构,第一种是在调节区的容腔内中部,于好氧生物反应区出水口的下方,水平设一出水槽,出水槽底面上有多个孔,孔顺反应器对角线方向或径向排列,孔下方垂直固接有配水支管,配水支管的长度,依反应器对角线或直径的一端向另一端逐渐加长;In the integrated bioreactor, the three structures of the water distribution device, the first one is to set a water outlet horizontally in the middle of the cavity of the adjustment area, below the water outlet of the aerobic bioreaction area, There are multiple holes on the bottom surface of the water outlet tank, the holes are arranged along the diagonal or radial direction of the reactor, and the water distribution branch pipe is fixed vertically under the hole, and the length of the water distribution branch pipe gradually increases from one end to the other end according to the diagonal line or diameter of the reactor. lengthened;

第二种是在调节区的容腔内中部,于好氧生物反应区出水口的下方,水平设一出水槽,出水槽底面上有多个孔,孔排列成一行,孔下方垂直固接有配水干管,配水干管在竖直方向上等距水平设置多个配水支管;The second is to set a water outlet horizontally in the middle of the chamber of the adjustment area below the water outlet of the aerobic biological reaction area. There are a plurality of holes on the bottom surface of the water outlet. The main water distribution pipe, the main water distribution pipe is equidistantly arranged in the vertical direction with multiple water distribution branch pipes horizontally;

第三种是由数个第二种布水装置组合而成。The third type is composed of several second water distribution devices.

所述的一体化生物反应器,其所述第二种布水装置中的配水支管,其两端向上翘起。In the integrated bioreactor, the two ends of the branch water distribution pipe in the second water distribution device are tilted upward.

所述的一体化生物反应器,其所述调节区的布水装置,可根据不同需要,选用不同的结构;当设计水量大,反应器容积大时,选用第一种或第三种布水装置;好氧反应区出水侧壁宽小于1~1.5米时,选择第二种布水装置;布水装置中的配水管可根据实际水量相应增加。In the integrated bioreactor, the water distribution device in the adjustment area can be of different structures according to different needs; when the design water volume is large and the reactor volume is large, the first or third water distribution device can be selected. device; when the outlet side wall width of the aerobic reaction zone is less than 1 to 1.5 meters, choose the second water distribution device; the water distribution pipe in the water distribution device can be increased according to the actual water volume.

所述的一体化生物反应器,其所述回流泵,构成回流系统,部分厌氧生物反应区的出水回流至反应器进水处,与垃圾渗滤液混合进入好氧反应区,以降低高浓度污染物的负荷冲击,回流量视垃圾渗滤液中污染物浓度而定,当进水中氨氮浓度低于1000mg/L时,回流停止。In the integrated bioreactor, the reflux pump constitutes a reflux system, and part of the effluent from the anaerobic biological reaction zone flows back to the water inlet of the reactor, and is mixed with landfill leachate into the aerobic reaction zone to reduce the high concentration The load impact of pollutants, the return flow depends on the concentration of pollutants in the landfill leachate. When the concentration of ammonia nitrogen in the influent is lower than 1000mg/L, the return flow stops.

所述的一体化生物反应器,其特征是:The integrated bioreactor is characterized in that:

所述的好氧生物反应区内,降解有机物的微生物和亚硝化菌附着生长在生物填料上,有机物被好氧异养菌降解为无机碳,控制氨氮的硝化过程在亚硝化阶段,并保持50%~55%的氨氮氧化为亚硝酸盐;In the aerobic biological reaction zone, microorganisms and nitrosating bacteria that degrade organic matter attach and grow on the biological filler, organic matter is degraded into inorganic carbon by aerobic heterotrophic bacteria, and the nitrification process of ammonia nitrogen is controlled in the nitrification stage, and the 50 %~55% of ammonia nitrogen is oxidized to nitrite;

所述的厌氧生物反应区内,培养厌氧氨氧化菌附着生长在填料上,厌氧氨氧化菌以氨氮为电子供体来还原亚硝酸盐,以亚硝酸盐为电子受体来氧化氨氮,将氨氮和亚硝态氮转变成氮气,部分有机物被其它厌氧微生物吸收或降解;In the anaerobic biological reaction zone, the cultured anammox bacteria attach and grow on the filler, and the anammox bacteria use ammonia nitrogen as an electron donor to reduce nitrite, and use nitrite as an electron acceptor to oxidize ammonia nitrogen , convert ammonia nitrogen and nitrite nitrogen into nitrogen, and some organic matter is absorbed or degraded by other anaerobic microorganisms;

调节区的布水装置,可调节水质,使好氧生物反应区不同时段的出水在预混合区中充分混合,同时调节水的pH值以保证水质的稳定和使厌氧反应区在最佳状况。The water distribution device in the adjustment area can adjust the water quality, so that the effluent from the aerobic biological reaction area in different periods can be fully mixed in the pre-mixing area, and at the same time adjust the pH value of the water to ensure the stability of the water quality and make the anaerobic reaction area in the best condition .

本发明中的处理垃圾渗滤液的一体化反应器具有以下优点:The integrated reactor for treating landfill leachate in the present invention has the following advantages:

(1)微生物相多样化,能存活世代时间较长的微生物。(1) Microorganisms are diverse and can survive for a long time.

(2)脱氮效率高,无需投加有机碳源。(2) The denitrification efficiency is high, and there is no need to add organic carbon sources.

(3)工艺流程简单,无需污泥回流,能耗低,无需单独设置沉淀池,运行简便。(3) The process flow is simple, no need for sludge reflux, low energy consumption, no need to set up a separate sedimentation tank, and the operation is simple.

(4)运行稳定,耐水质、水量的负荷冲击(4) Stable operation, resistant to load impact of water quality and water quantity

(5)工艺布置紧凑,占地少,基建投资省。(5) The process layout is compact, the land occupation is small, and the infrastructure investment is low.

(6)反应器封闭运行,产生的气体集中收集排出,保证处理场地的环境卫生。(6) The reactor is closed and operated, and the gas generated is collected and discharged in a centralized manner to ensure the environmental sanitation of the treatment site.

附图说明Description of drawings

图1本发明的一种处理垃圾渗滤液的一体化生物反应器结构图。Fig. 1 is a structural diagram of an integrated bioreactor for treating landfill leachate according to the present invention.

图2本发明的布水装置23A示意图。Fig. 2 is a schematic diagram of a water distribution device 23A of the present invention.

图3本发明的布水装置23B示意图。Fig. 3 is a schematic diagram of the water distribution device 23B of the present invention.

图4本发明的布水装置23C示意图。Fig. 4 is a schematic diagram of a water distribution device 23C of the present invention.

图5传统的生物脱氮工艺流程图。Figure 5. Traditional biological denitrification process flow chart.

具体实施方式Detailed ways

如图1所示,为本发明的一种处理垃圾渗滤液的一体化生物反应器结构图。一体化生物反应器为封闭的容器,由两个生物反应区和一个调节区组成,三个区域在封闭的整体容器内相互连通,每个生物反应区内均填充生物填料,形成好氧区1和厌氧区3,调节区2位于好氧区1和厌氧区3之间。As shown in FIG. 1 , it is a structural diagram of an integrated bioreactor for treating landfill leachate according to the present invention. The integrated bioreactor is a closed container, which consists of two biological reaction areas and one adjustment area. The three areas are connected to each other in the closed overall container. Each biological reaction area is filled with biological fillers to form an aerobic area 1 and anaerobic zone 3, conditioning zone 2 is located between aerobic zone 1 and anaerobic zone 3.

好氧生物反应区1和厌氧生物反应区3容腔内的上部、中部结构相同,但好氧生物反应区1的构成部件小于厌氧生物反应区3的构成部件。在两区容腔内,上部上方各水平设有一横向支架17、17a,横向支架17、17a两端与侧壁固接,中部各设有三相分离器,三相分离器由中心筒16、16a和倒锥台8、8a构成,中心筒16、16a为倒T型,上端圆筒与支架17、17a中部固接,下端为喇叭口,喇叭口的水平侧角为60°,中心筒16、16a喇叭口下方水平设置倒锥台8、8a,倒锥台8、8a的四周缘与容腔内壁固接,倒锥台8、8a底面与侧面夹角为120°,三相分离器下方各设有球型填料7、7a;厌氧生物反应区3容腔内的上部侧壁设有出水管22。The upper and middle structures of the aerobic bioreaction zone 1 and the anaerobic bioreaction zone 3 are the same, but the components of the aerobic bioreaction zone 1 are smaller than those of the anaerobic bioreaction zone 3 . In the chambers of the two regions, a horizontal bracket 17, 17a is arranged horizontally above the upper part. Constituted with inverted cones 8, 8a, the central cylinder 16, 16a is an inverted T shape, the upper cylinder is fixedly connected to the middle part of the bracket 17, 17a, the lower end is a bell mouth, and the horizontal side angle of the bell mouth is 60 °, the central cylinder 16, 16a Inverted cones 8, 8a are arranged horizontally below the bell mouth, the surrounding edges of the inverted cones 8, 8a are fixedly connected to the inner wall of the cavity, the angle between the bottom surface and the side of the inverted cones 8, 8a is 120°, and each of the three-phase separators below Spherical fillers 7, 7a are provided; an outlet pipe 22 is provided on the upper side wall of the cavity of the anaerobic biological reaction zone 3 .

好氧生物反应区1和厌氧生物反应区3的顶部都设有水封盖10、10a,其中心上侧固接有气体排出管20,气体排出管20的另一端接气体处理设备。The tops of the aerobic biological reaction zone 1 and the anaerobic biological reaction zone 3 are provided with water seals 10, 10a, and a gas discharge pipe 20 is fixedly connected to the upper side of the center, and the other end of the gas discharge pipe 20 is connected to gas treatment equipment.

好氧生物反应区1和厌氧生物反应区3容腔内的下部结构不同。好氧生物反应区1容腔内下部上方水平设有污水进水管4,污水进水管4下方水平设有曝气板5,曝气板5上有多个孔,其四周缘与容腔内壁固接,其下方侧壁设有进气管21。The lower structures in the cavities of the aerobic biological reaction zone 1 and the anaerobic biological reaction zone 3 are different. In the aerobic biological reaction zone 1, a sewage water inlet pipe 4 is horizontally arranged above the lower part of the chamber, and an aeration plate 5 is horizontally arranged below the sewage water inlet pipe 4. Then, the lower side wall is provided with an air intake pipe 21.

厌氧生物反应区3容腔内下部上方水平设有布水板13,布水板13上有多个布水孔,其四周缘与容腔内壁固接,其下方水平设有多个加热管19,多个加热管19汇入一根总管,总管从侧壁穿出后与加热设备相连。In the anaerobic biological reaction zone 3, there is a water distribution plate 13 horizontally above the lower part of the cavity, and there are multiple water distribution holes on the water distribution plate 13. 19. A plurality of heating pipes 19 merge into a main pipe, and the main pipe passes through the side wall and is connected with the heating equipment.

好氧生物反应区1与调节区2相邻的侧壁上方有出水口9,将好氧生物反应区1和调节区2连通。There is a water outlet 9 above the side wall adjacent to the aerobic bioreaction zone 1 and the regulation zone 2, which connects the aerobic bioreaction zone 1 and the regulation zone 2.

厌氧生物反应区3与调节区2相邻的侧壁下方有进水口12,将厌氧生物反应区3和调节区2连通。There is a water inlet 12 under the side wall adjacent to the anaerobic biological reaction zone 3 and the regulating zone 2, which connects the anaerobic biological reaction zone 3 and the regulating zone 2.

好氧生物反应区1的外侧壁上还设有插口6,插口6上安装溶解氧监测计(DO)电极。The outer wall of the aerobic biological reaction zone 1 is also provided with a socket 6, and a dissolved oxygen monitor (DO) electrode is installed on the socket 6.

厌氧生物反应区3的外侧壁上,上方的出水管22与反应器好氧区1的污水进水管4相通,在出水管22与污水进水管4连通的管路上设有回流泵18,下方设有pH和温度监测计14、氧化还原电位(ORP)监测计15。On the outer wall of the anaerobic biological reaction zone 3, the outlet pipe 22 above communicates with the sewage inlet pipe 4 of the aerobic zone 1 of the reactor. A pH and temperature monitor 14 and an oxidation-reduction potential (ORP) monitor 15 are provided.

调节区2的容腔顶端设有加药管11,加药管11外端与加药设备相通。A dosing tube 11 is provided at the top of the cavity of the regulating area 2, and the outer end of the dosing tube 11 communicates with the dosing equipment.

调节区2的容腔内,设有布水装置23,布水装置23由出水槽231和配水管组成,配水管又分为配水干管232、配水支管233。布水装置23有三种结构:布水装置23A、布水装置23B和布水装置23C。In the cavity of the adjustment area 2, a water distribution device 23 is provided. The water distribution device 23 is composed of a water outlet tank 231 and a water distribution pipe. The water distribution pipe is further divided into a water distribution main pipe 232 and a water distribution branch pipe 233. The water distribution device 23 has three structures: a water distribution device 23A, a water distribution device 23B and a water distribution device 23C.

如图2所示,为布水装置23A,是在调节区2的容腔内中部,于好氧生物反应区1出水口9的下方,水平设一出水槽231,出水槽231底面上有多个孔,孔顺反应器对角线方向(或径向)排列,孔下方垂直固接有配水支管233,配水支管233的长度,依反应器对角线(或直径)的一端向另一端逐渐加长。As shown in Figure 2, it is a water distribution device 23A, which is in the middle of the cavity of the conditioning area 2, below the water outlet 9 of the aerobic bioreaction area 1, and a water outlet 231 is horizontally arranged. The holes are arranged along the diagonal direction (or radial direction) of the reactor, and a water distribution branch pipe 233 is vertically fixed below the hole. lengthened.

如图4所示,为布水装置23C,是在调节区2的容腔内中部,于好氧生物反应区1出水口9的下方,水平设一出水槽231,出水槽231底面上有多个孔,孔排列成一行,孔下方垂直固接有配水干管232,配水干管232在竖直方向上等距水平设置多个配水支管233,配水支管233两端向上翘起。As shown in Figure 4, it is a water distribution device 23C, which is in the middle of the cavity of the adjustment area 2, below the water outlet 9 of the aerobic biological reaction area 1, and a water outlet 231 is horizontally arranged, and there are many water outlets on the bottom of the water outlet 231. The holes are arranged in a row, and the bottom of the hole is vertically fixed with a main water distribution pipe 232, and the main water distribution pipe 232 is provided with a plurality of water distribution branch pipes 233 equidistantly in the vertical direction, and the two ends of the water distribution branch pipe 233 are upturned.

如图3所示,为布水装置23B,布水装置23B是由数个布水装置23C组合而成。As shown in FIG. 3 , it is a water distribution device 23B, and the water distribution device 23B is composed of several water distribution devices 23C.

布水装置23可根据不同需要,选用不同的布水装置。当设计水量大,反应器容积大时,需选用布水装置23A和23B,好氧反应区1出水侧壁宽小于1~1.5米时,选择布水装置23C;布水装置23A和23B中的配水管可根据实际水量相应增加;布水装置23A的配水支管233按照反应器对角线进行排列,以达到均匀布水的目的。The water distribution device 23 can select different water distribution devices according to different needs. When the design water volume is large and the volume of the reactor is large, the water distribution devices 23A and 23B should be selected. When the outlet side wall width of the aerobic reaction zone 1 is less than 1-1.5 meters, the water distribution device 23C should be selected; the water distribution devices 23A and 23B The water distribution pipes can be increased correspondingly according to the actual water volume; the water distribution branch pipes 233 of the water distribution device 23A are arranged according to the diagonal of the reactor, so as to achieve the purpose of uniform water distribution.

反应器中的好氧反应区1和厌氧反应区3均采用上向流固定床生物膜反应器结构,下层安装球型填料7、7a。反应器的顶部安装水封盖10、10a,使反应器中的气味不外逸,产生的各种气体集中收集后处理外排,保证处理场地的环境卫生。Both the aerobic reaction zone 1 and the anaerobic reaction zone 3 in the reactor adopt an upward-flowing fixed-bed biofilm reactor structure, and spherical fillers 7 and 7a are installed in the lower layer. Water seals 10, 10a are installed on the top of the reactor to keep the smell in the reactor from escaping, and the various gases produced are collected and treated for discharge to ensure the sanitation of the treatment site.

垃圾渗滤液由底部流入好氧生物反应区1,通过布水管4向反应区均匀布水,由供气设施通过曝气装置5向反应器供气,提供生物好氧反应所需的氧气,运行过程中,在插口6上安装溶解氧监测计(DO)电极,监测反应区内的溶解氧,根据不同的进水水质和水量,即不同的进水污染物负荷调节曝气量,达到控制亚硝化的目的。废水与填料7上生长的生物膜接触,渗滤液中的部分氨氮(NH4-N)被氧化为亚硝酸盐氮(NO2-N),大部分易生物降解的有机物被好氧异养菌降解为无机碳,生物降解后的废水和悬浮污泥的混合液经过三相分离器8后,气体主要收集在上部中心筒16中,向上经气体排出管20排放,污泥絮凝、沉淀,澄清水从出水口9流出,进入调节区2,通过布水装置23使不同时段的出水充分混合均匀后,经厌氧生物反应区3下方进水口12自动流进厌氧生物反应区3,废水自下而上通过布水板13流动,在厌氧条件下,填料7a上生长的微生物进行生物代谢,厌氧氨氧化菌以氨氮(NH4-N)为电子供体来还原亚硝酸盐,以亚硝酸盐(NO2-N)为电子受体来氧化氨氮(NH4-N),将氨氮和亚硝态氮转变成氮气(N2),部分有机物被其它厌氧微生物吸收或降解。生物降解后的废水通过三相分离器8a对气、水和泥的分离后,上清液外排,出水通过水封保证空气不进入反应器中。厌氧反应区3上安装有pH和温度监测计14、氧化还原电位(ORP)监测计15的在线控制接口,运行中,反应区中废水的pH低于8,在线控制系统中的加药泵启动,将碱剂经加药管11泵入调节区2,与好氧区1的出水充分混合均匀后,由下方进水口12自动流进厌氧区3,调节厌氧区3中的pH达到运行要求,保障厌氧氨氧化生物反应的正常进行;由于厌氧氨氧化生物反应对温度的要求,厌氧区3底部安装加热管19,在环境温度降低时,对反应器中的废水进行加热。厌氧区3的出水管22与反应器好氧区2的污水进水管4相连,当垃圾渗滤液的水质改变,污染物浓度大大增加时,使用回流泵18将反应器的出水回流与垃圾渗滤液混合稀释后进入好氧区1,以降低进水污染物负荷,减少对反应器的冲击,保障反应器的稳定运行。The landfill leachate flows into the aerobic biological reaction zone 1 from the bottom, distributes water evenly to the reaction zone through the water distribution pipe 4, and supplies gas to the reactor through the aeration device 5 from the gas supply facility to provide the oxygen required for the biological aerobic reaction, and run During the process, a dissolved oxygen monitor (DO) electrode is installed on the socket 6 to monitor the dissolved oxygen in the reaction zone, and adjust the aeration rate according to different influent water quality and water volume, that is, different influent pollutant loads, so as to control sub- purpose of nitrification. The waste water is in contact with the biofilm grown on the filler 7, part of the ammonia nitrogen (NH 4 -N) in the leachate is oxidized to nitrite nitrogen (NO 2 -N), and most of the easily biodegradable organic matter is destroyed by aerobic heterotrophic bacteria Degraded into inorganic carbon, the mixed liquid of biodegraded wastewater and suspended sludge passes through the three-phase separator 8, the gas is mainly collected in the upper central cylinder 16, and discharged upward through the gas discharge pipe 20, and the sludge is flocculated, precipitated, and clarified The water flows out from the water outlet 9 and enters the adjustment area 2. After the water outlets in different periods are fully mixed and uniform through the water distribution device 23, the water automatically flows into the anaerobic biological reaction area 3 through the water inlet 12 below the anaerobic biological reaction area 3, and the waste water automatically flows into the anaerobic biological reaction area 3. Flow through the water distribution plate 13 from bottom to top. Under anaerobic conditions, the microorganisms grown on the filler 7a perform biological metabolism, and the anammox bacteria use ammonia nitrogen (NH 4 —N) as the electron donor to reduce nitrite, thereby Nitrite (NO 2 -N) is an electron acceptor to oxidize ammonia nitrogen (NH 4 -N), convert ammonia nitrogen and nitrite nitrogen into nitrogen (N 2 ), and some organic matter is absorbed or degraded by other anaerobic microorganisms. After the biodegraded waste water is separated from gas, water and mud by the three-phase separator 8a, the supernatant is discharged, and the effluent is passed through a water seal to ensure that air does not enter the reactor. The online control interface of pH and temperature monitor 14, oxidation-reduction potential (ORP) monitor 15 is installed on the anaerobic reaction area 3, in operation, the pH of wastewater in the reaction area is lower than 8, and the dosing pump in the online control system Start, pump the alkali agent into the adjustment area 2 through the dosing pipe 11, and after fully mixing with the effluent from the aerobic area 1, it will automatically flow into the anaerobic area 3 from the lower water inlet 12, and adjust the pH in the anaerobic area 3 to reach Operation requirements to ensure the normal progress of the anammox biological reaction; due to the temperature requirements of the anammox biological reaction, a heating pipe 19 is installed at the bottom of the anaerobic zone 3 to heat the wastewater in the reactor when the ambient temperature drops . The outlet pipe 22 of the anaerobic zone 3 is connected to the sewage inlet pipe 4 of the aerobic zone 2 of the reactor. When the water quality of the landfill leachate changes and the concentration of pollutants increases greatly, the reflux pump 18 is used to return the outlet water of the reactor to the garbage seepage. The filtrate enters the aerobic zone 1 after being mixed and diluted to reduce the load of influent pollutants, reduce the impact on the reactor, and ensure the stable operation of the reactor.

反应器的顶部安装水封盖10和10a,生物反应产生的气体由反应器顶部收集后,经气体排出管20送至处理设备排出。Water seals 10 and 10a are installed on the top of the reactor, and the gas generated by the biological reaction is collected from the top of the reactor and sent to the processing equipment through the gas discharge pipe 20 for discharge.

本发明中反应器采用的处理技术原理是:将垃圾渗滤液中约50%的氨氮氧化为亚硝酸盐氮,即硝化过程仅进行到亚硝化阶段,同时去除大部分易生物降解的有机物;微生物在厌氧条件下,以剩余的50%氨氮作为电子供体,以亚硝酸盐氮作为电子受体,将氨氮和亚硝态氮转化为氮气。The principle of the treatment technology adopted by the reactor in the present invention is: oxidize about 50% of the ammonia nitrogen in the landfill leachate to nitrite nitrogen, that is, the nitrification process only proceeds to the nitrosation stage, and removes most of the easily biodegradable organic matter at the same time; Under anaerobic conditions, use the remaining 50% ammonia nitrogen as the electron donor and nitrite nitrogen as the electron acceptor to convert ammonia nitrogen and nitrite nitrogen into nitrogen gas.

本发明的处理技术具有以下优点:The processing technique of the present invention has the following advantages:

(1)硝化反应只进行到亚硝化阶段,且只需约50%的氨氮氧化为亚硝酸盐氮,节省能耗62.5%。。(1) The nitrification reaction only proceeds to the nitrosation stage, and only about 50% of ammonia nitrogen is oxidized to nitrite nitrogen, saving energy consumption by 62.5%. .

(2)节省100%反硝化有机碳源。(2) Save 100% denitrification organic carbon source.

实施例1Example 1

请参见附图1。Please refer to attached picture 1.

以垃圾渗滤液作为处理废水。整个工艺流程连续稳定运行近四个月,反应器的处理效果如下:Landfill leachate is used as wastewater treatment. The entire technological process has been running continuously and stably for nearly four months, and the treatment effect of the reactor is as follows:

氨氮(NH4-N)的进水浓度:1282.9mg/L,出水浓度:108.6mg/L,去除率:91.5%;TN的进水浓度:1424.6mg/L,出水浓度:260.1mg/L,去除率:81.6%;CODcr的进水浓度:1035.5mg/L,出水浓度:279mg/L,去除率:73%。Influent concentration of ammonia nitrogen (NH 4 -N): 1282.9mg/L, effluent concentration: 108.6mg/L, removal rate: 91.5%; TN influent concentration: 1424.6mg/L, effluent concentration: 260.1mg/L, Removal rate: 81.6%; CODcr influent concentration: 1035.5mg/L, effluent concentration: 279mg/L, removal rate: 73%.

Claims (9)

1. the integrated bioreactor of a treating refuse percolate, container for sealing, form by aerobe reaction zone, anaerobe reaction zone and regulatory region three parts, subregion filled biomass filler is all arranged in each bio-reaction zone, and under aerobic and anaerobic condition, move respectively, regulatory region is between aerobic zone and anaerobic zone; It is characterized in that:
Top, central structure in aerobe reaction zone and the anaerobe reaction zone cavity volume are identical, in two district's cavity volumes, each level of top, top is provided with a horizontal support, horizontal support two ends and sidewall are affixed, the middle part respectively is provided with triphase separator, triphase separator is made of central tube and inversed taper platform, central tube is an inverted T shape, upper end cylinder and mid-stent are affixed, the lower end is a hydraucone, central tube hydraucone lower horizontal is provided with inversed taper platform, and edge and cavity volume inwall are affixed around the inversed taper platform, and the triphase separator below respectively is provided with the ball-type filler;
Upper portion side wall in the anaerobe reaction zone cavity volume is provided with rising pipe;
The top of aerobe reaction zone and anaerobe reaction zone all is provided with manhole cover, and wherein side is connected with gas outlet pipe in the heart, another termination gas processing device of two gas outlet pipes;
The bottom upper horizontal is provided with sewage water inlet pipe in the aerobe reaction zone cavity volume, and the sewage water inlet pipe lower horizontal is provided with aeration board, and a plurality of holes are arranged on the aeration board, and edge and cavity volume inwall are affixed around it, and its lower sidewalls is provided with inlet pipe;
The bottom upper horizontal is provided with water distribution board in the anaerobe reaction zone cavity volume, and a plurality of water distributing pores are arranged on the water distribution board, and edge and cavity volume inwall are affixed around it, and its lower horizontal is provided with heating tube, and heating tube passes the back from sidewall and links to each other with heating installation;
There is water outlet the sidewall top that aerobe reaction zone and regulatory region are adjacent, and aerobe reaction zone and regulatory region are communicated with;
There is water-in the sidewall below that anaerobe reaction zone and regulatory region are adjacent, and anaerobe reaction zone and regulatory region are communicated with;
The top of regulatory region is provided with chemical feed pipe, and the chemical feed pipe outer end communicates with medicine machine.
2. integrated bioreactor as claimed in claim 1 is characterized in that: also be provided with socket on the outer side wall of described aerobe reaction zone, dissolved oxygen monitoring meter electrode is installed on the socket;
On the outer side wall of anaerobe reaction zone, the rising pipe of top communicates with the sewage water inlet pipe of reactor aerobic zone, is provided with reflux pump on rising pipe and pipeline that sewage water inlet pipe is communicated with, and the below is provided with pH and temperature monitoring meter, redox potential monitoring meter;
In the cavity volume of regulatory region, be provided with water-distributing device.
3. integrated bioreactor as claimed in claim 1 is characterized in that: described heating tube is a plurality of, imports a house steward, and house steward passes the back from sidewall and links to each other with heating installation.
4. integrated bioreactor as claimed in claim 2 is characterized in that: described water-distributing device, to form by effluent trough and water distributing pipe, and water distributing pipe is divided into distributing main, range pipe again; Water-distributing device has three kinds of structures.
5. integrated bioreactor as claimed in claim 4, it is characterized in that: three kinds of structures of described water-distributing device, first kind is middle part in the cavity volume of regulatory region, in the below of aerobe reaction zone water outlet, level is established an effluent trough, and a plurality of holes are arranged on the effluent trough bottom surface, hole cistron device diagonal or radial array, hole below vertically is connected with range pipe, and the length of range pipe extends to the other end gradually according to an end of reactor diagonal lines or diameter;
Second kind is middle part in the cavity volume of regulatory region, and in the below of aerobe reaction zone water outlet, level is established an effluent trough, a plurality of holes are arranged on the effluent trough bottom surface, the hole is arranged in delegation, and the below, hole vertically is connected with distributing main, and the distributing main in the vertical direction equidistantly is horizontally disposed with a plurality of range pipes;
The third is to be combined by several second kind of water-distributing device.
6. integrated bioreactor as claimed in claim 5 is characterized in that: the range pipe in described second kind of water-distributing device, its two ends are upturned.
7. integrated bioreactor as claimed in claim 5 is characterized in that: the water-distributing device of described regulatory region, can select different structures for use according to different needs; When designed water is big, when reactor volume is big, select first kind or the third water-distributing device for use; Aerobic reactor zone water outlet sidewall is wide during less than 1~1.5 meter, selects second kind of water-distributing device; Water distributing pipe in the water-distributing device can be according to the corresponding increase of actual amount of water.
8. integrated bioreactor as claimed in claim 2, it is characterized in that: described reflux pump, constitute return-flow system, the effluent recycling of part anaerobe reaction zone is to reactor water inlet place, be mixed into aerobic reactor zone with percolate, to reduce the load impact of high density pollution thing, quantity of reflux is decided on Pollutant levels in the percolate, when ammonia nitrogen concentration was lower than 1000mg/L in the water inlet, backflow stopped.
9. as claim 1,2,3,4,5,6 or 7 described integrated bioreactors, it is characterized in that:
In the described aerobe reaction zone, the microorganism of degradation of organic substances and nitrococcus apposition growth are on biologic packing material, organism is degraded to inorganic carbon by aerobic heterotrophic bacterium, and the nitrifying process of control ammonia nitrogen is in the nitrosification stage, and keeps 50%~55% ammonia nitrogen to be oxidized to nitrite;
In the described anaerobe reaction zone, cultivate the anaerobic ammonia oxidizing bacteria apposition growth on filler, anaerobic ammonia oxidizing bacteria is that electron donor reduces nitrite with the ammonia nitrogen, with the nitrite is that electron acceptor(EA) comes the oxidation ammonia nitrogen, ammonia nitrogen and nitrite nitrogen are transformed into nitrogen, and partial organic substances is absorbed by other anaerobion or degrades;
The water-distributing device of regulatory region, adjustable water saving matter makes aerobe reaction zone water outlet thorough mixing in the pre-mixing district of different periods, and the pH value of regulating water simultaneously is to guarantee the stable of water quality and to make the anaerobic reaction district at optimum.
CNB2004100888067A 2004-11-04 2004-11-04 Integrative bioreactor for treating refuse leachate Expired - Fee Related CN1331780C (en)

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