CN1330460C - Super-coating material for sand paper and production thereof - Google Patents
Super-coating material for sand paper and production thereof Download PDFInfo
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Abstract
本发明砂纸用超涂层材料由甲、乙和丙组分混合配制而成,各组分的重量配比为100∶200~350∶5~70;甲组分由胶粘剂10~35%和溶剂65~90%组成;乙组分由吸热剂25~40%、填料20~30%和溶剂30~55%组成;丙组分为溶剂。砂纸用超涂层材料的制备步骤包括:先按工艺分别制备甲、乙组分,再将其按重量计为100∶200~350混合配制,搅拌均匀,然后按配比加入丙组分混合配制,搅拌均匀即可。本发明具有许多优点,主要有:中温下表干快,低温也可完全表干;便于操作;使用时脱屑、散热、不易堵塞效果好;特别适用于软质材料例如木材、油漆、软金属等材料的干磨和抛光;同时也提高了砂纸的耐磨性能。The supercoating material for sandpaper of the present invention is prepared by mixing components A, B and C, and the weight ratio of each component is 100: 200~350: 5~70; Component A consists of 10~35% of adhesive and solvent 65-90% composition; B component is composed of endothermic agent 25-40%, filler 20-30% and solvent 30-55%; C component is solvent. The preparation steps of the super-coating material for sandpaper include: firstly prepare component A and component B respectively according to the process, then mix and prepare them at a ratio of 100:200 to 350 by weight, stir evenly, and then add component C according to the proportion to mix and prepare, Just mix well. The present invention has many advantages, mainly including: fast surface drying at medium temperature, and complete surface drying at low temperature; easy to operate; good desquamation, heat dissipation, and non-blocking effect during use; especially suitable for soft materials such as wood, paint, soft metal Dry grinding and polishing of other materials; also improves the wear resistance of sandpaper.
Description
技术领域technical field
本发明涉及材料领域,特别是一种砂纸用超涂层材料及其制备方法。The invention relates to the field of materials, in particular to a supercoating material for sandpaper and a preparation method thereof.
背景技术Background technique
在磨料磨具行业,砂纸是一种被广泛使用的打磨工具。不同型号的砂纸具有使用范围广泛、方便,价格低廉等优点。但是,当使用砂纸打磨木材、油漆、软金属等软质材料时,一般的砂纸往往会出现被碎屑堵塞的现象。In the abrasives industry, sandpaper is a widely used grinding tool. Different types of sandpaper have the advantages of wide range of use, convenience, and low price. However, when sanding soft materials such as wood, paint, and soft metals, ordinary sandpaper tends to become clogged with debris.
发明内容Contents of the invention
本发明所要解决的技术问题是:提供一种砂纸用超涂层材料及其制备方法。该超涂层材料具有防堵塞功能,从而能够克服上述现有技术的不足。The technical problem to be solved by the present invention is to provide a super-coating material for sandpaper and a preparation method thereof. The supercoat material has an anti-clogging function, thereby being able to overcome the above-mentioned deficiencies in the prior art.
本发明解决其技术问题所采用的技术方案是:砂纸用超涂层材料由甲、乙和丙组分混合配制而成,各组分的重量配比为100:200~350:5~70;甲组分由胶粘剂10~35%和溶剂65~90%组成;乙组分由吸热剂25~40%、填料20~30%和溶剂30~55%组成;丙组分为溶剂。The technical solution adopted by the present invention to solve the technical problem is: the supercoating material for sandpaper is prepared by mixing components A, B and C, and the weight ratio of each component is 100:200~350:5~70; Component A is composed of 10-35% of adhesive and 65-90% of solvent; component B is composed of 25-40% of endothermic agent, 20-30% of filler and 30-55% of solvent; component C is solvent.
砂纸用超涂层材料的制备步骤包括:The preparation steps of supercoating material for sandpaper comprise:
(1)甲组分的制备:将胶粘剂10~35%和溶剂65~90%,依次倒入反应釜中,并且边倒入边搅拌,混合均匀即可。(1) Preparation of component A: Pour 10-35% of the adhesive and 65-90% of the solvent into the reaction kettle in turn, and stir while pouring, and mix evenly.
(2)乙组分的制备:将吸热剂25~40%、填料20~30%和溶剂30~55%,依次倒入反应釜中,并且边倒入边搅拌,混合均匀即可。(2) Preparation of component B: Pour 25-40% of endothermic agent, 20-30% of filler and 30-55% of solvent into the reaction kettle in sequence, and stir while pouring, and mix evenly.
(3)混合配制:先将制得的甲、乙组分按重量计为100∶200~350混合配制,搅拌均匀,再加入丙组分混合配制,搅拌均匀即得砂纸用超涂层材料。(3) Mixing and preparation: first mix and prepare the obtained A and B components by weight at 100:200~350, stir evenly, then add C component to mix and prepare, and stir evenly to obtain the supercoating material for sandpaper.
上述甲组分中的胶粘剂为:聚乙烯醇、聚乙二醇、环氧树脂、白乳胶、聚醋酸乙烯-乙烯共聚物、聚醋酸乙烯酯、聚醋酸乙烯、聚酰亚胺、聚丙烯酰胺、中性二聚酸聚酰胺树脂、N,N-亚甲基双丙烯酰胺、聚酰胺、丙烯酸甲酯、甲基丙烯酸甲酯和过氧化苯甲酰中的两种,或者两种以上的混合物。The adhesives in the above-mentioned component A are: polyvinyl alcohol, polyethylene glycol, epoxy resin, white latex, polyvinyl acetate-ethylene copolymer, polyvinyl acetate, polyvinyl acetate, polyimide, polyacrylamide , neutral dimer acid polyamide resin, N, N-methylenebisacrylamide, polyamide, two kinds of methyl acrylate, methyl methacrylate and benzoyl peroxide, or a mixture of two or more .
上述乙组分中的填料为:滑石粉、钛白粉、硬脂酸锌、硬脂酸钙、硬脂酸镁、硬脂酸钠、硬脂酸铝、氮化硼、气相二氧化硅、氧化镁、氧化钙、二硫化钼、云母粉、三聚氰胺氰尿酸络合物、硼酸钾、硼酸钠、氟化钙、氟化硼、氯化硼、氯化铬、碘化钙和碘化铅中的一种,或者两种,或者两种以上的混合物。The fillers in the above component B are: talcum powder, titanium dioxide, zinc stearate, calcium stearate, magnesium stearate, sodium stearate, aluminum stearate, boron nitride, fumed silica, oxide Magnesium, calcium oxide, molybdenum disulfide, mica powder, melamine cyanuric acid complex, potassium borate, sodium borate, calcium fluoride, boron fluoride, boron chloride, chromium chloride, calcium iodide, and lead iodide One, or two, or a mixture of two or more.
上述丙组分为溶剂,其加入量按重量计为5~70。The above-mentioned component C is a solvent, and its addition amount is 5-70 by weight.
甲、乙组分中的溶剂和丙组分为:甲醇、乙醇、乙二醇、甲苯、丙酮、溶剂油、苯乙烯和四氯化碳中的一种,或者两种,或者两种以上的混合物。The solvent in the A and B components and the C component are: methanol, ethanol, ethylene glycol, toluene, acetone, solvent naphtha, styrene and carbon tetrachloride, or two, or two or more mixture.
超涂层材料是指在砂纸表面即在碳化硅或棕刚玉砂纸表面加涂的一层特殊的防堵塞材料。用该材料形成的砂纸有别于普通砂纸,其工作原理是利用涂覆的特殊防堵塞材料,在磨削产生大量热能时,使其里面的吸热物质发生相转变,物态由固态转变为液态,从而起到吸收热能、降低工件表面温度的作用;同时吸热物质发生相转变后在砂纸的表面上形成润滑膜,因此也提高了砂纸的耐磨性和磨削效率。The super-coating material refers to a layer of special anti-clogging material coated on the surface of the sandpaper, that is, on the surface of the silicon carbide or brown corundum sandpaper. The sandpaper formed with this material is different from ordinary sandpaper. Its working principle is to use the special anti-clogging material coated. When grinding generates a large amount of heat energy, the heat-absorbing substance in it undergoes phase transformation, and the state of matter changes from solid to Liquid state, thereby absorbing heat energy and reducing the surface temperature of the workpiece; at the same time, the endothermic substance undergoes a phase transition to form a lubricating film on the surface of the sandpaper, thus improving the wear resistance and grinding efficiency of the sandpaper.
本发明提供的砂纸用超涂层材料,由于采用了合适的胶粘剂、吸热剂、填料以及溶剂系统,致使用该材料制成的超涂层砂纸具有许多优点,主要有:中温下表干快,低温也可完全表干;便于操作;使用时脱屑、散热、不易堵塞效果好;特别适用于软质材料例如木材、油漆、软金属等材料的干磨和抛光;同时也提高了砂纸的耐磨性能。The super-coated material for sandpaper provided by the present invention has many advantages due to the adoption of suitable adhesive, heat-absorbing agent, filler and solvent system, and the super-coated sandpaper made of the material has many advantages, mainly including: the surface dries quickly under the middle temperature , can be completely surface-dried at low temperature; easy to operate; good effect of desquamation, heat dissipation, and not easy to clog during use; especially suitable for dry grinding and polishing of soft materials such as wood, paint, soft metal and other materials; at the same time, it also improves the sandpaper. wear resistance.
具体实施方式Detailed ways
本发明是一种砂纸用超涂层材料及其制备方法。The invention relates to a supercoating material for sandpaper and a preparation method thereof.
一.砂纸用超涂层材料1. Supercoating materials for sandpaper
该材料由甲、乙和丙组分混合配制而成,各组分的重量配比为100∶200~350∶5~70。甲组分由胶粘剂10~35%和溶剂65~90%组成。乙组分由吸热剂25~40%、填料20~30%和溶剂30~55%组成。丙组分为溶剂。The material is prepared by mixing components A, B and C, and the weight ratio of each component is 100:200-350:5-70. Component A is composed of 10-35% of adhesive and 65-90% of solvent. Component B is composed of 25-40% endothermic agent, 20-30% filler and 30-55% solvent. Part C is the solvent.
上述甲组分中的胶粘剂为:聚乙烯醇、聚乙二醇、环氧树脂、白乳胶、聚醋酸乙烯-乙烯共聚物、聚醋酸乙烯酯、聚醋酸乙烯、聚酰亚胺、聚丙烯酰胺、中性二聚酸聚酰胺树脂、N,N-亚甲基双丙烯酰胺、聚酰胺、丙烯酸甲酯、甲基丙烯酸甲酯和过氧化苯甲酰中的一种,或者两种,或者两种以上的混合物。The adhesives in the above-mentioned component A are: polyvinyl alcohol, polyethylene glycol, epoxy resin, white latex, polyvinyl acetate-ethylene copolymer, polyvinyl acetate, polyvinyl acetate, polyimide, polyacrylamide , neutral dimer acid polyamide resin, N, N-methylene bisacrylamide, polyamide, methyl acrylate, methyl methacrylate and one of benzoyl peroxide, or two, or both mixture of the above.
上述乙组分中的吸热剂为:硼、白云石、砂子、粘土、铅、碳酸钙、碳化硅、刚玉粉、石榴石和玻璃砂中的一种,或者两种,或者两种以上的混合物。The heat absorbing agent in the above-mentioned component B is: boron, dolomite, sand, clay, lead, calcium carbonate, silicon carbide, corundum powder, garnet and glass sand, or two, or a mixture of two or more .
上述乙组分中的填料为:滑石粉、钛白粉、硬脂酸锌、硬脂酸钙、硬脂酸镁、硬脂酸钠、硬脂酸铝、氮化硼、气相二氧化硅、氧化镁、氧化钙、二硫化钼、云母粉、三聚氰胺氰尿酸络合物、硼酸钾、硼酸钠、氟化钙、氟化硼、氯化硼、氯化铬、碘化钙和碘化铅中的一种,或者两种,或者两种以上的混合物。The fillers in the above component B are: talcum powder, titanium dioxide, zinc stearate, calcium stearate, magnesium stearate, sodium stearate, aluminum stearate, boron nitride, fumed silica, oxide Magnesium, calcium oxide, molybdenum disulfide, mica powder, melamine cyanuric acid complex, potassium borate, sodium borate, calcium fluoride, boron fluoride, boron chloride, chromium chloride, calcium iodide, and lead iodide One, or two, or a mixture of two or more.
上述甲、乙组分中的溶剂和丙组分为:甲醇、乙醇、乙二醇、甲苯、丙酮、溶剂油、苯乙烯和四氯化碳中的一种,或者两种,或者两种以上的混合物。The solvent and component C in the above components A and B are: methanol, ethanol, ethylene glycol, toluene, acetone, solvent naphtha, styrene and carbon tetrachloride, or two, or more than two mixture.
二.砂纸用超涂层材料的制备方法Two. Preparation method of supercoating material for sandpaper
砂纸用超涂层材料由上述的甲、乙和丙组分混合配制而成,其步骤包括:The supercoating material for sandpaper is prepared by mixing the above-mentioned components A, B and C, and the steps include:
(1)甲组分的制备:将胶粘剂10~35%和溶剂65~90%,依次倒入反应釜中,并且边倒入边搅拌,混合均匀即可。(1) Preparation of component A: Pour 10-35% of the adhesive and 65-90% of the solvent into the reaction kettle in turn, and stir while pouring, and mix evenly.
(2)乙组分的制备:将吸热剂25~40%、填料20~30%和溶剂30~55%,依次倒入反应釜中,并且边倒入边搅拌,混合均匀即可。(2) Preparation of component B: Pour 25-40% of endothermic agent, 20-30% of filler and 30-55% of solvent into the reaction kettle in sequence, and stir while pouring, and mix evenly.
(3)混合配制:先将制得的甲、乙组分按重量计为100∶200~350混合配制,搅拌均匀,再加入丙组分按重量计为5~70混合配制,搅拌均匀即得砂纸用超涂层材料。(3) Mixing and preparation: first mix and prepare the prepared A and B components at a ratio of 100:200 to 350 by weight, stir evenly, then add component C to mix and prepare at 5 to 70 by weight, and stir evenly to obtain Supercoated material for sandpaper.
超涂层材料的使用方法:正常使用时,可按甲组分∶乙组分∶丙组分=100∶200~350∶5~70的比例搅拌均匀使用。其中,甲组分∶乙组分∶丙组分=100∶230~320∶15~55为优选值。甲组分由胶粘剂15~25%和溶剂75~85%组成。乙组分由吸热剂25~35%、填料20~30%和溶剂35~55%组成。How to use the super-coating material: during normal use, it can be used by stirring evenly according to the ratio of component A: component B: component C = 100: 200-350: 5-70. Among them, component A:component B:component C=100:230~320:15~55 is the preferred value. Component A is composed of 15-25% of adhesive and 75-85% of solvent. Component B is composed of 25-35% endothermic agent, 20-30% filler and 35-55% solvent.
砂纸用超涂层材料,其在砂纸上的涂覆工艺条件是:60℃的条件下8~12min表面初干,1.8~2.2h后完全固化。如果希望固化时间更长或更短可减增胶粘剂的用量来调节,不会影响固化的强度和其它效果,简捷方便。The super coating material for sandpaper, its coating process conditions on sandpaper are: the surface is initially dry at 60°C for 8-12 minutes, and it is completely cured after 1.8-2.2 hours. If you want the curing time to be longer or shorter, you can adjust it by reducing the amount of adhesive, which will not affect the curing strength and other effects, which is simple and convenient.
下面结合具体实例对本发明作进一步说明。The present invention will be further described below in conjunction with specific examples.
实施例1:将甲组分的聚醋酸乙烯-乙烯20%,乙醇80%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;将乙组分的碳酸钙30%,钛白粉25%,乙醇45%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;然后将甲、乙组分按100∶250的比例混合,搅拌均匀,按配比加入甲苯,调节至适当的粘度即得超涂层材料。Example 1: Add 20% polyvinyl acetate-ethylene and 80% ethanol of component A to the reaction kettle in turn, pour in while stirring to make it mix evenly; add 30% calcium carbonate of component B , titanium dioxide 25%, ethanol 45%, add to the reaction kettle in turn, pour in while stirring to make it mix evenly; then mix A and B components according to the ratio of 100:250, stir evenly, Add toluene and adjust to proper viscosity to get the super coating material.
实施例2:将甲组分的聚醋酸乙烯-乙烯15%,乙醇85%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;将乙组分的碳酸钙35%,钛白粉25%,乙醇40%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;然后将甲、乙组分按100∶250的比例混合,搅拌均匀,按配比加入甲苯,调节至适当的粘度即得超涂层材料。Example 2: Add 15% polyvinyl acetate-ethylene and 85% ethanol of component A to the reaction kettle in turn, pour in while stirring to make it mix evenly; add 35% calcium carbonate of component B , titanium dioxide 25%, ethanol 40%, add to the reaction kettle in turn, pour in while stirring to make it mix evenly; then mix A and B components according to the ratio of 100:250, stir evenly, Add toluene and adjust to proper viscosity to get the super coating material.
实施例3:将甲组分的聚醋酸乙烯-乙烯35%,乙醇65%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;将乙组分的碳酸钙32%,钛白粉23%,乙醇45%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;然后将甲、乙组分按100∶260的比例混合,搅拌均匀,按配比加入甲苯,调节至适当的粘度即得超涂层材料。Example 3: Add 35% polyvinyl acetate-ethylene and 65% ethanol of component A to the reaction kettle in turn, pour in while stirring to make it mix evenly; add 32% calcium carbonate of component B , titanium dioxide 23%, ethanol 45%, add to the reaction kettle in turn, pour in while stirring, make it mix evenly; then mix A and B components according to the ratio of 100:260, stir evenly, Add toluene and adjust to proper viscosity to get the super coating material.
实施例4:将甲组分的聚醋酸乙烯-乙烯22%,乙醇78%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;将乙组分的碳酸钙28%,钛白粉20%,乙醇52%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;然后将甲、乙组分按100∶275的比例混合,搅拌均匀,按配比加入甲苯,调节至适当的粘度即得超涂层材料。Example 4: Add 22% polyvinyl acetate-ethylene and 78% ethanol of component A to the reaction kettle in turn, pour in while stirring to make it mix evenly; add 28% calcium carbonate of component B , titanium dioxide 20%, ethanol 52%, add to the reaction kettle in turn, pour in while stirring to make it mix evenly; then mix A and B components according to the ratio of 100:275, stir evenly, Add toluene and adjust to proper viscosity to get the super coating material.
实施例6:将甲组分的聚醋酸乙烯-乙烯10%,乙醇90%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;将乙组分的碳酸钙40%,钛白粉30%,乙醇30%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;然后将甲、乙组分按100∶200的比例混合,搅拌均匀,按配比加入甲苯,调节至适当的粘度即得超涂层材料。Embodiment 6: Add 10% polyvinyl acetate-ethylene and 90% ethanol of component A to the reaction kettle in turn, pour in while stirring to make it mix evenly; add 40% calcium carbonate of component B , titanium dioxide 30%, ethanol 30%, add to the reaction kettle in turn, pour in while stirring to make it mix evenly; then mix A and B components according to the ratio of 100:200, stir evenly, Add toluene and adjust to proper viscosity to get the super coating material.
实施例7:将甲组分的聚醋酸乙烯~乙烯22%,乙醇78%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;将乙组分的碳酸钙25%,钛白粉20%,乙醇55%,依次加入反应釜中,倒入时边搅拌边倒入,使其混合均匀;然后将甲、乙组分按100∶350的比例混合,搅拌均匀,按配比加入甲苯,调节至适当的粘度即得超涂层材料。Example 7: Add 22% polyvinyl acetate to ethylene and 78% ethanol of component A to the reaction kettle in turn, and pour it while stirring to make it mix evenly; add 25% calcium carbonate of component B , titanium dioxide 20%, and ethanol 55%, are added to the reaction kettle in turn, and poured while stirring to make it evenly mixed; then mix A and B components in a ratio of 100:350, stir evenly, and Add toluene and adjust to proper viscosity to get the super coating material.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CNB2005100181188A CN1330460C (en) | 2005-01-07 | 2005-01-07 | Super-coating material for sand paper and production thereof |
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| CNB2005100181188A CN1330460C (en) | 2005-01-07 | 2005-01-07 | Super-coating material for sand paper and production thereof |
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| CN1644793A CN1644793A (en) | 2005-07-27 |
| CN1330460C true CN1330460C (en) | 2007-08-08 |
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| CNB2005100181188A Expired - Fee Related CN1330460C (en) | 2005-01-07 | 2005-01-07 | Super-coating material for sand paper and production thereof |
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Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103692366B (en) * | 2013-12-13 | 2015-11-18 | 江苏锋芒复合材料科技集团有限公司 | Multiple glue of a kind of super-hydrophobic anti-clogging sand paper and preparation method thereof |
| CN103992681B (en) * | 2014-06-03 | 2017-01-11 | 洛阳惠尔纳米科技有限公司 | Super environment-friendly coating for abrasive paper, abrasive cloth and abrasive belt and preparation method of coating |
| CN105315749A (en) * | 2014-08-05 | 2016-02-10 | 东莞金太阳研磨股份有限公司 | Anti-electrostatic wet-and-dry anti-blockage coating layer and preparation method therefor |
| CN106497161B (en) * | 2016-10-31 | 2019-01-15 | 江苏裕邦车业科技有限公司 | Super coating paste for abrasive band |
| CN106965101B (en) * | 2017-04-06 | 2019-01-08 | 湖北明仁研磨科技股份有限公司 | A kind of sand paper substrate crack-resistance treatment method |
| CN107627226B (en) * | 2017-09-15 | 2019-05-07 | 东莞市中微纳米科技有限公司 | A kind of elasticity concretion abrasive and its preparation method and application |
| CN112847167B (en) * | 2020-12-23 | 2022-07-19 | 苏州远东砂轮有限公司 | Zirconium corundum abrasive belt and manufacturing method thereof |
| CN113183047B (en) * | 2021-04-23 | 2022-09-27 | 韶关威鸣研磨材料有限公司 | Abrasive belt special for plywood and preparation process thereof |
| CN117488558B (en) * | 2023-11-01 | 2024-06-14 | 东莞金太阳研磨股份有限公司 | Preparation method of high-temperature-resistant abrasive cloth coating for metal polishing |
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