CN1328475C - Tunnel waterproofing method - Google Patents
Tunnel waterproofing method Download PDFInfo
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- CN1328475C CN1328475C CNB018140092A CN01814009A CN1328475C CN 1328475 C CN1328475 C CN 1328475C CN B018140092 A CNB018140092 A CN B018140092A CN 01814009 A CN01814009 A CN 01814009A CN 1328475 C CN1328475 C CN 1328475C
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D11/00—Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
- E21D11/38—Waterproofing; Heat insulating; Soundproofing; Electric insulating
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D11/00—Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
- E21D11/38—Waterproofing; Heat insulating; Soundproofing; Electric insulating
- E21D11/383—Waterproofing; Heat insulating; Soundproofing; Electric insulating by applying waterproof flexible sheets; Means for fixing the sheets to the tunnel or cavity wall
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D11/00—Lining tunnels, galleries or other underground cavities, e.g. large underground chambers; Linings therefor; Making such linings in situ, e.g. by assembling
- E21D11/04—Lining with building materials
- E21D11/10—Lining with building materials with concrete cast in situ; Shuttering also lost shutterings, e.g. made of blocks, of metal plates or other equipment adapted therefor
- E21D11/105—Transport or application of concrete specially adapted for the lining of tunnels or galleries ; Backfilling the space between main building element and the surrounding rock, e.g. with concrete
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- General Life Sciences & Earth Sciences (AREA)
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- Lining And Supports For Tunnels (AREA)
- Excavating Of Shafts Or Tunnels (AREA)
Abstract
Description
技术领域technical field
本发明涉及用于隧道防水的方法。本发明中,浆料、灰泥和混凝土用作表示水泥混凝土的通用术语。The invention relates to a method for waterproofing tunnels. In the present invention, slurry, mortar, and concrete are used as general terms representing cement concrete.
背景技术Background technique
目前在日本主要的隧道构造方法是NATM方法。NATM构造方法是这样的一种方法,其中,通过在隧道挖掘之后直接喷涂灰泥或混凝土的方式涂覆第一涂层以防止在挖洞区域内岩石落下和漏水。之后,涂覆第二混凝土涂层以便于通过保持隧道强度来稳定隧道。此时,设置防水薄片用于防水和用作在第一混凝土涂层和第二混凝土涂层之间的隔层,从而可防止水漏入隧道内,并且可防止由于第二混凝土涂层粘附在土墩上引起的裂纹,或防止由于该土墩的迁移引起的裂纹。最近,可通过隧道钻孔机进行隧道挖掘(TBM构造方法),并且设置防水薄片用于同样的防水目的。Currently, the main tunnel construction method in Japan is the NATM method. The NATM construction method is a method in which a first coat is applied by spraying plaster or concrete directly after tunnel excavation to prevent rock fall and water leakage in the excavated area. Afterwards, a second concrete coat is applied in order to stabilize the tunnel by maintaining its strength. At this time, a waterproof sheet is provided for waterproofing and as an interlayer between the first concrete coat and the second concrete coat, so that water can be prevented from leaking into the tunnel, and adhesion due to the second concrete coat can be prevented. To induce cracks in a mound, or to prevent cracks due to migration of that mound. Recently, tunnel excavation can be performed by a tunnel boring machine (TBM construction method), and a waterproof sheet is provided for the same waterproofing purpose.
另外,由于薄片的宽度窄,如1-2米,存在这样的问题,即当防水薄片端部被彼此叠置并通过焊接连接时,要求更大劳动强度及更费事,并且是不经济的。In addition, since the width of the sheet is narrow, such as 1-2 meters, there is a problem that when the ends of the waterproof sheet are stacked on each other and connected by welding, it requires more labor and labor and is not economical.
还存在这样的问题,即由于防水薄片被不良焊接部分功能性损坏,以及隧道挖洞表面的不规则性,使防水薄片和第二混凝土涂层之间引起渗水,从而不能得到防水能力。There is also a problem that water seepage is caused between the waterproof sheet and the second concrete coating due to functional damage of the waterproof sheet by poorly welded parts, and irregularities in the surface of the tunnel excavation, so that waterproofing ability cannot be obtained.
发明内容Contents of the invention
当为了防止防水薄片的损坏而增加防水薄片的厚度时,存在这样的问题,即防水薄片端部的焊接变得困难,并且增加了防水薄片的质量,结果是实际实施特性变得更不好。When the thickness of the waterproof sheet is increased in order to prevent the damage of the waterproof sheet, there is a problem that welding of the ends of the waterproof sheet becomes difficult and the mass of the waterproof sheet is increased, with the result that practical characteristics become worse.
本发明人对上述问题进行了各种研究。结果是,他们发现了隧道防水构造方法而完善了本发明,其中在设置第二涂覆水泥混凝土层之前,将对第二涂覆水泥混凝土层具有粘附性的防水薄片设置在第一喷涂水泥混凝土层表面上,并且,其中通过使防水薄片与第二涂覆水泥混凝土层成为一个整体,防止了由于不良焊接位置和防水薄片端部的损坏而引起的在防水薄片和第二涂覆混凝土层之间的水渗漏,甚至在第二涂覆水泥混凝土层中产生裂纹时可防止漏水,并且可大大提高防水能力。The present inventors conducted various studies on the above-mentioned problems. As a result, they found a tunnel waterproofing construction method and perfected the present invention, in which a waterproof sheet having adhesion to the second coating cement concrete layer is placed on the first spray cement concrete layer before setting the second coating cement concrete layer. on the surface of the concrete layer, and wherein, by making the waterproof sheet integral with the second coated cement concrete layer, damage to the waterproof sheet and the second coated concrete layer due to poor welding positions and damage to the ends of the waterproof sheet is prevented. Water leakage in between, even when cracks occur in the second coated cement concrete layer, can prevent water leakage, and can greatly improve the waterproof ability.
本发明特别提供了一种隧道防水方法,其特征在于,将第一水泥混凝土层喷涂到隧道洞穴表面,通过粘附非织造织物、纤维材料或不规则形状物薄片将防水隔离层设置到所述第一水泥混凝土层表面上,将一防水薄膜设置到所述防水隔离层上,该防水薄膜具有一塑料或橡胶薄片和一层用于粘附涂覆在所述防水薄膜上的第二涂覆水泥混凝土层的粘附层,并且将第二涂覆水泥混凝土层喷涂到所述防水薄膜上,从而得到所述防水隧道。The present invention particularly provides a method for tunnel waterproofing, characterized in that the first cement concrete layer is sprayed onto the surface of the tunnel cavity, and the waterproof isolation layer is set on the surface by adhering non-woven fabrics, fiber materials or irregular-shaped thin sheets. On the surface of the first cement concrete layer, a waterproof membrane is arranged on the waterproof isolation layer, the waterproof membrane has a plastic or rubber sheet and a second coating for adhesion coating on the waterproof membrane an adhesive layer of the cement concrete layer, and a second coated cement concrete layer is sprayed onto the waterproof membrane, thereby obtaining the waterproof tunnel.
本发明的实施方式Embodiments of the present invention
下面我们将详细描述本发明。Hereinafter we will describe the present invention in detail.
本发明是一种构造方法,其中通过喷涂将防水薄片和隧道形成一个整体,优选将速干水泥混凝土喷涂到挖洞的隧道表面,之后设置和第二涂覆水泥混凝土层具有粘附性的防水薄片。该防水薄片可以随动调节由于第二涂覆水泥混凝土层和土墩在完成后的干燥和收缩引起的水泥混凝土的裂纹。通过将水泥混凝土和防水薄片形成一个整体,即使防水薄片产生损坏,也仅仅在被损坏的位置处产生和水的接触。由于此原因,只要在防水薄片损坏区域的第二涂覆混凝土中的裂纹不发展,就不会发生漏水。因此,大大减少了漏水并且可得到优良的防水能力。此外,由于水在防水薄片和第二涂覆水泥混凝土层之间的水渗漏,作为一个整体的隧道的防水能力的损伤,和第二涂覆水泥混凝土层中的裂纹,当使用传统的防水薄片时也不会发生漏水。另外,由于和第二涂覆水泥混凝土层形成一个整体的防水薄片具有良好的随动调节(follow-up)能力,并且即使在隧道本身产生裂纹时也不会产生损坏,从而防止了漏水,因此与传统的防水构造方法相比,在很大程度上提高了防水能力。The present invention is a construction method in which the waterproof sheet and the tunnel are integrally formed by spraying, preferably quick-drying cement concrete is sprayed onto the surface of the dug tunnel, after which a waterproofing sheet with adhesion to the second coated cement concrete layer is provided. Flakes. The waterproof sheet can adjust accordingly to the cracking of the cement concrete caused by the drying and shrinkage of the second coated cement concrete layer and the mound after completion. By integrating the cement concrete and the waterproof sheet, even if the waterproof sheet is damaged, contact with water occurs only at the damaged position. For this reason, as long as cracks in the second coating concrete in the damaged area of the waterproof sheet do not develop, water leakage does not occur. Therefore, water leakage is greatly reduced and excellent waterproofing ability can be obtained. In addition, due to water seepage between the waterproof sheet and the second coated cement concrete layer, damage to the waterproof ability of the tunnel as a whole, and cracks in the second coated cement concrete layer, when using conventional waterproofing Leakage does not occur when flakes. In addition, since the waterproof sheet integrally formed with the second coating cement concrete layer has good follow-up ability and does not cause damage even when the tunnel itself cracks, thereby preventing water leakage, Compared with the traditional waterproof construction method, the waterproof ability is greatly improved.
和第二涂覆水泥混凝土层具有粘附性的防水薄片的例子包括不交联的橡胶薄片,如异戊二烯橡胶和天然橡胶。Examples of the waterproof sheet having adhesion to the second coated cement concrete layer include non-crosslinked rubber sheets such as isoprene rubber and natural rubber.
和第二涂覆水泥混凝土层具有粘附性的防水薄片还可包含抗氧化剂、紫外线辐射吸收剂和胶粘剂。The waterproof sheet having adhesion to the second coated cement concrete layer may further contain an antioxidant, an ultraviolet radiation absorber, and an adhesive.
在本发明中,如果第二涂覆水泥混凝土层已经以土墩为界,从增加与第二涂覆水泥混凝土层的绝缘效果出发,希望将和第二水泥混凝土层具有粘附性的层和聚合物薄片层压。当使用和第二涂覆水泥混凝土层具有粘附性的一层防水薄片和与聚合物薄片层压的多层防水薄片,它们被设置成使第一喷涂水泥混凝土层表面侧和聚合物薄片接触,并且第二涂覆水泥混凝土层被设置到和第二涂覆水泥混凝土层具有粘附性的防水薄片表面侧。In the present invention, if the second coating cement concrete layer has been bounded by the mound, from increasing the insulating effect with the second coating cement concrete layer, it is hoped that the layer having adhesion with the second cement concrete layer and Polymer sheet lamination. When using a one-layer waterproof sheet having adhesiveness to the second coated cement concrete layer and a multi-layer waterproof sheet laminated with the polymer sheet, they are arranged so that the surface side of the first sprayed cement concrete layer is in contact with the polymer sheet , and the second coated cement concrete layer is provided to the surface side of the waterproof sheet having adhesion to the second coated cement concrete layer.
聚合物薄片材料的例子可包括高密度聚乙烯、低密度聚乙烯、乙烯-乙酸乙烯共聚物(EVA)和聚丙烯。在这些材料中,从绝缘效果、强度、裂纹随动调节能力和价格出发,优选使用高密度聚乙烯。Examples of polymer sheet materials may include high density polyethylene, low density polyethylene, ethylene vinyl acetate (EVA), and polypropylene. Among these materials, high-density polyethylene is preferably used in terms of insulating effect, strength, crack follow-up ability, and price.
在本发明中,为了提高绝缘效果,减少这些存在大量地下水的位置处的水压和增加防水效果,在设置和第二涂覆水泥混凝土层具有粘附性的防水薄片之前可形成隔离水传导层。防水隔离层的例子可包括通过喷涂纤维物质而形成的多个层,该纤维物质如例如聚酯纤维和聚丙烯的纤维浆状非织造织物和薄片或不规则形状物。In the present invention, in order to improve the insulating effect, reduce the water pressure at these locations where a large amount of groundwater exists and increase the waterproofing effect, an insulating water-conducting layer can be formed before setting a waterproof sheet with adhesion to the second coating cement concrete layer . Examples of waterproof barriers may include layers formed by spraying fibrous substances such as fibrous pulp non-woven fabrics and sheets or irregularities such as polyester fibers and polypropylene.
可以在隧道的基床部使用防水构造方法,该防水构造方法在防止基床部分漏水方面显示了很高效率。It is possible to use a waterproof construction method in the bed portion of the tunnel, which shows high efficiency in preventing water leakage of the bed portion.
对于将防水薄片、非织造织物和不规则形状物固定到第一喷涂水泥混凝土层表面上的方法没有特殊的限制,并且可以使用粘附剂和铆钉。There is no particular limitation on the method of fixing the waterproof sheet, non-woven fabric and irregularities to the surface of the first sprayed cement concrete layer, and adhesives and rivets may be used.
在已经以这种方式设置了和第二涂覆水泥混凝土层具有粘附性的防水薄片之后,可涂覆第二涂覆水泥混凝土层并完成该构造。After the waterproof sheet having adhesion to the second applied cementitious concrete layer has been provided in this manner, the second applied cementitious concrete layer can be applied and the construction completed.
例子example
下面我们将以例子为基础说明本发明。In the following we will illustrate the present invention on the basis of examples.
例1example 1
制造一U形模拟隧道,其具有4m的开口,3.5m的高度和3m的长度。假定在模拟隧道中隧道土墩表面是不规则的,并且以合适的间隔设置15个宽度为15cm、高度为20cm、长度为20cm的混凝土块,以形成不规则表面。A U-shaped mock tunnel was fabricated with an opening of 4m, a height of 3.5m and a length of 3m. It is assumed that the tunnel mound surface is irregular in the simulated tunnel, and 15 concrete blocks having a width of 15 cm, a height of 20 cm, and a length of 20 cm are arranged at appropriate intervals to form the irregular surface.
将速干灰泥作为第一喷涂灰泥层并且喷涂,以使该速干灰泥达到10cm厚。The quick-drying plaster was used as the first spray plaster layer and sprayed so that the quick-drying stucco was 10 cm thick.
在喷涂之后,通过铆钉将和第二涂覆混凝土层具有粘附性的多层防水薄片(由美国Grace Construction Products公司制造,牌号为Preprufe300;一双层薄片包括两层,一层对混凝土具有粘附性,一个是聚乙烯层;2.7mm厚)固定到第一喷涂灰泥层表面上。之后,将第二涂覆混凝土层涂覆到30cm厚。为了模拟多层防水薄片的损坏,在其一部分中制出切口。After spraying, the multi-layer waterproof sheet (manufactured by Grace Construction Products Company of the United States, brand name Preprufe300; a double-layer sheet includes two layers, which is adhesive to the concrete layer) is attached to the second coating concrete layer by rivets. Adhesive, one layer of polyethylene; 2.7 mm thick) fixed to the surface of the first spray plaster layer. Afterwards, a second layer of coated concrete was applied to a thickness of 30 cm. In order to simulate damage to a multi-layer waterproofing sheet, a cut is made in a part of it.
在形成第二涂覆混凝土层28天之后,通过钻孔切出一测试样本,并检查其与混凝土的粘附性。第二涂覆混凝土层和防水薄片处于良好接触并成为一个整体。第二涂覆混凝土层和防水薄片的剥离强度大于0.9N/mm。28 days after the formation of the second coated concrete layer, a test sample was cut out by drilling and checked for adhesion to concrete. The second coated concrete layer and the waterproofing sheet are in good contact and become a whole. The peel strength of the second coated concrete layer and the waterproof sheet is greater than 0.9 N/mm.
在切口区域中和第二涂覆混凝土层的一体性还保持得很好,混凝土的切口是小于2mm的线性轮廓形状。在第一喷涂混凝土和多层防水薄片之间的沟槽中施加60m的静态水压。但是,水不会进入多层防水薄片和第二涂覆混凝土层之间的沟槽中,显示出良好的防水能力。Integrality with the second applied concrete layer was also maintained well in the area of the cutout, the cutout of the concrete being in the shape of a linear profile of less than 2 mm. Apply a static water pressure of 60m in the trench between the first sprayed concrete and the multi-layer waterproof sheet. However, water does not enter the groove between the multi-layer waterproof sheet and the second coated concrete layer, showing good waterproof ability.
由于使用的多层防水薄片具有粘附性,仅通过将多层防水薄片的端部彼此叠置,可以令人满意地使多层防水薄片彼此粘接。由于这个原因,其施工能力极好,并可得到叠置部分的粘接强度为1.7N/mm这个理想值。Since the multilayer waterproof sheets used have adhesive properties, the multilayer waterproof sheets can be satisfactorily bonded to each other only by overlapping the end portions of the multilayer waterproof sheets. For this reason, its workability is excellent, and an ideal value of 1.7 N/mm in the bonding strength of the superimposed portion can be obtained.
为了模拟隧道中的裂纹,对第二涂覆混凝土层施加压力并制造裂纹。在多层防水薄片中没有发现异常。To simulate cracks in a tunnel, the second coated concrete layer is stressed and cracked. No abnormalities were found in the multi-layer waterproofing sheet.
下面是各种物理特性的测试方法。The following are test methods for various physical properties.
与混凝土的粘附强度:根据ASTM D 903(90度剥离强度)。叠置部分的粘附强度:根据ASTM D 1876(在叠置多层防水薄片的情况中的确定)。Adhesion strength to concrete: According to ASTM D 903 (90 degree peel strength). Adhesion strength of superimposed parts: according to ASTM D 1876 (determination in case of superimposed multi-layer waterproof sheets).
例2Example 2
执行和例1中同样的程序,所不同的是所使用的和第二涂覆混凝土层具有粘附性的多层防水薄片是牌号为“Santacker Sheet”的产品(异戊二烯橡胶防水薄片,有内衬的非织造织物产品,由HayakawaRubber公司制造)。Execute the same procedure as Example 1, except that the multi-layer waterproof sheet that is used and the second coating concrete layer has adhesion is the product of "Santacker Sheet" (isoprene rubber waterproof sheet, Lined nonwoven fabric product, manufactured by HayakawaRubber Corporation).
在形成第二涂覆混凝土层28天之后,通过钻孔切出一测试样本,并检查其与混凝土的粘附性。第二涂覆混凝土和防水薄片处于良好接触并成为一个整体。28 days after the formation of the second coated concrete layer, a test sample was cut out by drilling and checked for adhesion to concrete. The second coated concrete and the waterproofing sheet are in good contact and become a whole.
但是,将多层防水薄片的端部连接起来比例1中要困难,并且可使用性也有点困难。However, it is difficult to join the ends of the multi-layer waterproof sheet in scale 1, and workability is also a little difficult.
对比例1Comparative example 1
执行和例1中同样的程序,所不同的是使用由EVA制成的防水薄片(其与第二涂覆混凝土层没有粘附性)来代替和第二涂覆混凝土层具有粘附性的多层防水薄片。The same procedure as in Example 1 was carried out, except that a waterproof sheet made of EVA (which had no adhesion to the second coated concrete layer) was used instead of a multilayer sheet having adhesion to the second coated concrete layer. layer of waterproof sheet.
当在第一喷涂混凝土层和多层防水薄片之间的沟槽中施加相当于30m静态水压的压力,从其中假定有损坏的裂纹可发现,大量水进入多层防水薄片和第二涂覆混凝土层之间的沟槽中,并且没有达到防水薄片的性能。When a pressure equivalent to 30 m of static water pressure is applied to the trench between the first sprayed concrete layer and the multi-layer waterproof sheet, a large amount of water enters the multi-layer waterproof sheet and the second coating can be found from cracks where damage is assumed. In the trench between the concrete layers, and did not achieve the performance of the waterproof sheet.
发明效果Invention effect
通过使用本发明的和第二涂覆水泥混凝土层具有粘附性的防水薄片使第二涂覆水泥混凝土层和防水薄片形成一个整体,即使防水薄片的一部分有损坏,水也不会进入防水薄片和第二涂覆混凝土层之间的沟槽中,确保具有良好的防水能力。By using the waterproof sheet having adhesiveness with the second coated cement concrete layer of the present invention so that the second coated cement concrete layer and the waterproof sheet are integrally formed, even if a part of the waterproof sheet is damaged, water does not enter the waterproof sheet In the trench between the second coat of concrete and the second coat of concrete, ensure good water resistance.
此外,本发明防水薄片的裂纹随动调节能力良好,即使第二涂覆水泥混凝土层中的裂纹扩展,防水薄片也不会损坏,确保具有良好的防水能力。即使在任意偶然情况下裂纹宽度很大并且防水薄片发生损坏,由于防水薄片的其它部分和第二涂覆水泥混凝土层为一个整体,水也不会渗漏进入防水薄片和第二涂覆混凝土层之间的沟槽中;因此,工业上的用处极大。In addition, the waterproof sheet of the present invention has a good ability to follow the cracks, even if the cracks in the second coated cement concrete layer expand, the waterproof sheet will not be damaged, ensuring good waterproof ability. Even if the crack width is large and the waterproof sheet is damaged by any chance, since the other parts of the waterproof sheet and the second coated cement concrete layer are integrated, water will not seep into the waterproof sheet and the second coated concrete layer In the trench between; therefore, the industry is of great use.
Claims (9)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP175769/00 | 2000-06-12 | ||
| JP175769/2000 | 2000-06-12 | ||
| JP2000175769A JP2001355398A (en) | 2000-06-12 | 2000-06-12 | Tunnel waterproofing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1524159A CN1524159A (en) | 2004-08-25 |
| CN1328475C true CN1328475C (en) | 2007-07-25 |
Family
ID=18677597
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018140092A Expired - Lifetime CN1328475C (en) | 2000-06-12 | 2001-06-05 | Tunnel waterproofing method |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1290312B1 (en) |
| JP (1) | JP2001355398A (en) |
| KR (1) | KR100783985B1 (en) |
| CN (1) | CN1328475C (en) |
| AT (1) | ATE336641T1 (en) |
| AU (2) | AU6819601A (en) |
| CA (1) | CA2411273C (en) |
| DE (1) | DE60122322T2 (en) |
| ES (1) | ES2269425T3 (en) |
| WO (1) | WO2001096709A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100516464C (en) * | 2006-06-02 | 2009-07-22 | 四川省交通厅公路规划勘察设计研究院 | Tunnel support structure |
| CN101614129B (en) * | 2009-08-10 | 2011-07-27 | 招商局重庆交通科研设计院有限公司 | Construction method of tunnel waterproof and water drainage system |
| DE102014112159A1 (en) * | 2014-08-26 | 2016-03-03 | Köster Bauchemie AG | Process for producing water-sealed surfaces from cement-based materials |
| CN113309109B (en) * | 2021-05-26 | 2022-07-15 | 广西壮族自治区地质环境监测站 | Construction method for quickly blocking water and reinforcing near pit wall of deep foundation pit in loose soil layer |
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- 2001-06-05 AU AU6819601A patent/AU6819601A/en active Pending
- 2001-06-05 AT AT01946109T patent/ATE336641T1/en not_active IP Right Cessation
- 2001-06-05 WO PCT/US2001/018239 patent/WO2001096709A1/en not_active Ceased
- 2001-06-05 ES ES01946109T patent/ES2269425T3/en not_active Expired - Lifetime
- 2001-06-05 AU AU2001268196A patent/AU2001268196B8/en not_active Expired
- 2001-06-05 DE DE60122322T patent/DE60122322T2/en not_active Expired - Lifetime
- 2001-06-05 KR KR1020027016943A patent/KR100783985B1/en not_active Expired - Lifetime
- 2001-06-05 CN CNB018140092A patent/CN1328475C/en not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| CA2411273A1 (en) | 2001-12-20 |
| KR100783985B1 (en) | 2007-12-11 |
| DE60122322D1 (en) | 2006-09-28 |
| HK1050560A1 (en) | 2003-06-27 |
| DE60122322T2 (en) | 2007-09-13 |
| WO2001096709A1 (en) | 2001-12-20 |
| AU6819601A (en) | 2001-12-24 |
| AU2001268196B2 (en) | 2005-11-03 |
| AU2001268196B8 (en) | 2005-12-22 |
| KR20030014710A (en) | 2003-02-19 |
| EP1290312B1 (en) | 2006-08-16 |
| CN1524159A (en) | 2004-08-25 |
| EP1290312A4 (en) | 2005-05-04 |
| ATE336641T1 (en) | 2006-09-15 |
| JP2001355398A (en) | 2001-12-26 |
| CA2411273C (en) | 2009-02-03 |
| EP1290312A1 (en) | 2003-03-12 |
| ES2269425T3 (en) | 2007-04-01 |
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Effective date of registration: 20160606 Address after: Massachusetts, USA Patentee after: GCP Application Technology Co., Ltd. Address before: American Maryland Patentee before: W. R. Grace & Co. |
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