CN1322563C - Laser annealing device for preparing polysilicon film layer and method for forming polysilicon film layer - Google Patents
Laser annealing device for preparing polysilicon film layer and method for forming polysilicon film layer Download PDFInfo
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- 229910021420 polycrystalline silicon Inorganic materials 0.000 title claims abstract description 35
- 238000005224 laser annealing Methods 0.000 title claims abstract description 23
- 238000000034 method Methods 0.000 title claims description 33
- 229920005591 polysilicon Polymers 0.000 title description 20
- 229910021417 amorphous silicon Inorganic materials 0.000 claims abstract description 39
- 239000000758 substrate Substances 0.000 claims abstract description 33
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- 238000010276 construction Methods 0.000 claims 3
- 238000005499 laser crystallization Methods 0.000 claims 3
- 230000001678 irradiating effect Effects 0.000 abstract description 2
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- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
技术领域technical field
本发明有关于一种用以制备多晶硅膜层的激光退火装置,且特别是有关于一种利用连续式侧向固化法(sequential lateral solidification;SLS)进行低温多晶硅的工序(low temperature poly silicon process;LTPS process)所使用的激光退火装置。The present invention relates to a laser annealing device for preparing a polysilicon film, and in particular to a low temperature polysilicon process (low temperature polysilicon process) using a sequential lateral solidification (SLS) method; LTPS process) used in the laser annealing device.
背景技术Background technique
薄膜晶体管为有源数组型平面显示器常用的有源组件(activeelement),通常用来驱动有源式液晶显示器(active matrix type liquidcrystal display)、有源式有机电激发光显示器(active matrix typeorganic light-emitting display)等装置。薄膜晶体管中的半导体硅薄膜一般可区分为多晶硅(poly-silicon)薄膜以及非晶硅(amorphoussilicon,a-Si:H)薄膜。Thin film transistors are active elements commonly used in active matrix type flat panel displays, and are usually used to drive active matrix type liquid crystal displays, active matrix type organic light-emitting displays (active matrix type organic light-emitting display) and other devices. Semiconductor silicon films in thin film transistors can generally be classified into polysilicon (poly-silicon) films and amorphous silicon (a-Si:H) films.
非晶硅薄膜虽然具备低工序温度、因可用气相沉积法来制备而适合大量生产、工序技术较成熟因而良率也较高等优点,但由于多晶硅的导电特性佳、使用多晶硅膜的薄膜晶体管具有较高的场效迁移率使晶体管可应用在高操作速度的电路中、驱动电路的积集度较佳等特性,再加上低温多晶硅工序的开发,已渐取代非晶硅薄膜。Although amorphous silicon thin film has the advantages of low process temperature, suitable for mass production because it can be prepared by vapor deposition method, mature process technology and high yield rate, etc., due to the good electrical conductivity of polysilicon, thin film transistors using polysilicon film have relatively high performance. High field effect mobility enables transistors to be used in circuits with high operating speeds, and the integration of drive circuits is better. Coupled with the development of low-temperature polysilicon processes, it has gradually replaced amorphous silicon films.
常见的多晶硅薄膜的制造方法大致有三种,第一种是利用沉积步骤直接沉积形成,第二种是先形成非晶硅薄膜后利用热能使其结晶成多晶硅薄膜,第三种是先形成非晶硅薄膜后利用激光使其结晶成多晶硅薄膜。然而上述的方法有下列的缺点,第一种方法的缺点是必须沉积足够厚才能形成大晶粒的多晶硅膜,而且,其表面均匀度差,所需的工序温度亦高达600度。第二种方法虽然可以制造出厚度薄且均匀的多晶硅薄膜,然而其结晶步骤所需的温度高达600度,热预算高,且所需的时间长,会影响产率。第三种方法的工序温度低,传统以准分子激光退火(excimer laserannealing;ELA)的方式使非晶硅转换为多晶硅,不过其扫描速度只有0.2mm/sec,能量仅370mJ/cm2,不仅产率低,受限于能量的大小,结晶情况常仅发生于表面,而无法达到使整层非晶硅再结晶成多晶硅的目的。使用扫描速度快(30mm/sec)且激光能量高(600mJ/cm2)的连续式侧向固化(SLS)激光退火处理使非晶硅转成多晶硅,可以解决上述的问题。但是,由于非晶硅薄膜沉积在玻璃基板边缘上的厚度并不均一,如图1所示,其绘示传统于玻璃基板10的缓冲层12上沉积形成的非晶硅层14的示意图,通常在玻璃基板10边缘区域A的非晶硅层14会较中间区域(即主要区域)C薄,当激光打在非晶硅薄膜14较薄处,即边缘区域A,会容易因激光而受到毁损。然而,此区域通常是后段工序要作对位的对准标记放置处,因此容易造成后段工序的中断。There are roughly three common manufacturing methods for polysilicon thin films. The first is to form by direct deposition using deposition steps. The second is to form an amorphous silicon thin film first and then use thermal energy to crystallize it into a polysilicon thin film. The third is to form an amorphous silicon thin film first. The silicon film is then crystallized into a polysilicon film using a laser. However, the above method has the following disadvantages. The disadvantage of the first method is that the polysilicon film must be deposited thick enough to form a large grain, and its surface uniformity is poor, and the required process temperature is as high as 600 degrees. Although the second method can produce a thin and uniform polysilicon film, the temperature required for the crystallization step is as high as 600 degrees, the thermal budget is high, and the required time is long, which will affect the yield. The process temperature of the third method is low. Excimer laser annealing (ELA) is traditionally used to convert amorphous silicon into polysilicon. However, the scanning speed is only 0.2mm/sec and the energy is only 370mJ/cm 2 . The rate is low, limited by the size of the energy, the crystallization usually only occurs on the surface, and the purpose of recrystallizing the entire layer of amorphous silicon into polysilicon cannot be achieved. Using continuous lateral solidification (SLS) laser annealing with fast scanning speed (30mm/sec) and high laser energy (600mJ/cm 2 ) to convert amorphous silicon into polysilicon can solve the above problems. However, since the thickness of the amorphous silicon thin film deposited on the edge of the glass substrate is not uniform, as shown in FIG. The
就连续式侧向固化(SLS)激光退火处理而言,由于SLS激光机台的扫描速度(scan rate)高达30mm/sec,因此必须要有一段距离做加速,亦即必须要从玻璃以外就开始照射。As for the continuous lateral solidification (SLS) laser annealing process, since the scan rate of the SLS laser machine is as high as 30mm/sec, there must be a certain distance for acceleration, that is, it must start from outside the glass irradiated.
为避免边缘区域A因激光而受到毁损的问题,现行线束激光(line beamlaser)都是从非晶硅薄膜14均匀处,即主要区域C,开始照射。而由于连续式侧向固化(SLS)激光退火处理必须要从玻璃以外就开始照射,因此把机台中控制激光放射的快门(shutter)开启点设在薄膜沉积均匀处,以避免位于基板边缘区域A的非晶硅薄膜14受损。如图1所示,设定快门开启点为D和E,但快门完全开启点为d和e,因此会有一区段的非晶硅薄膜14所受的激光能量不均匀,反而减少了可用来制作面板的区域。In order to avoid the problem that the edge area A is damaged by laser light, the current line beam laser (line beam laser) starts to irradiate from the uniform part of the
发明内容Contents of the invention
有鉴于此,本发明的目的在于提供一种在不会影响可用来制作面板的区域面积下,可以解决基板边缘区域的非晶硅层在经激光退火时受到损害的激光退火装置。In view of this, the object of the present invention is to provide a laser annealing device that can solve the damage of the amorphous silicon layer in the edge region of the substrate during laser annealing without affecting the area that can be used to make panels.
为达上述目的,本发明提出一种用以制备多晶硅膜层的激光退火装置,此种激光退火装置包括一遮蔽结构,当对非晶硅系膜层进行激光退火以形成多晶硅膜层时,遮蔽结构会抵挡基板边缘区域的激光,以避免激光完全照射到基板边缘区域的非晶硅膜层。因此,对应到基板边缘区域的激光束会被遮蔽结构完全挡住或者是部分穿透。In order to achieve the above object, the present invention proposes a laser annealing device for preparing a polysilicon film layer. This laser annealing device includes a shielding structure. The structure will resist the laser light in the edge area of the substrate, so as to prevent the laser light from fully irradiating the amorphous silicon film layer in the edge area of the substrate. Therefore, the laser beam corresponding to the edge region of the substrate will be completely blocked or partially penetrated by the shielding structure.
附图说明Description of drawings
图1为传统于玻璃基板的缓冲层上沉积形成的非晶硅层的示意图。FIG. 1 is a schematic diagram of an amorphous silicon layer conventionally deposited on a buffer layer of a glass substrate.
图2为本发明用于连续式侧向固化法(SLS)的激光退火装置的示意图。FIG. 2 is a schematic diagram of a laser annealing device for continuous lateral solidification (SLS) according to the present invention.
图3为图2中的工序反应室的放大图,其中遮蔽结构是由支撑结构、旋转装置和挡板所组成。Fig. 3 is an enlarged view of the process reaction chamber in Fig. 2, wherein the shielding structure is composed of a supporting structure, a rotating device and a baffle.
图4为图3的遮蔽结构的一实施例的平面图。FIG. 4 is a plan view of an embodiment of the shielding structure of FIG. 3 .
图5为图3的遮蔽结构的另一实施例的平面图。FIG. 5 is a plan view of another embodiment of the shielding structure of FIG. 3 .
图6为挡板旋转至可便于基板进行进出的位置的示意图。FIG. 6 is a schematic diagram of the baffle being rotated to a position that facilitates the entry and exit of the substrate.
图7为本发明另一较佳实施例的一种工序反应室的结构示意图,其中遮蔽结构是由挡板和伸缩装置所组成。Fig. 7 is a structural schematic diagram of a process reaction chamber according to another preferred embodiment of the present invention, wherein the shielding structure is composed of a baffle plate and a telescopic device.
图8为挡板收缩至可便于基板进行进出的位置的示意图。FIG. 8 is a schematic diagram showing that the baffle shrinks to a position where it is convenient for the substrate to enter and exit.
图号说明Description of figure number
玻璃基板:10 缓冲层:12Glass substrate: 10 Buffer layer: 12
非晶硅层:14、17 边缘区域:AAmorphous silicon layer: 14, 17 Edge area: A
主要区域:C 快门开启点:D、EMain area: C Shutter opening point: D, E
快门完全开启点:d、eShutter fully open point: d, e
激光:22 激光源:10Lasers: 22 Laser sources: 10
衰减器:11 光束均匀器:12Attenuator: 11 Beam Homogenizer: 12
视野镜:13 罩幕:14Vision Mirror: 13 Shroud: 14
物镜:15 序反应室:20Objective lens: 15 Sequence reaction chamber: 20
转移平台:16 基板:18Transfer platform: 16 Substrate: 18
遮蔽结构:21 19-1、19-2、19-3:反射镜Shading structure: 21 19-1, 19-2, 19-3: Reflector
支撑结构:21b 旋转装置:21cSupport structure: 21b Rotation device: 21c
挡板:21a 支撑板:21b1 Bezel: 21a Support plate: 21b 1
支撑架:21b2 伸缩装置:21dSupport frame: 21b 2 telescopic device: 21d
具体实施方式Detailed ways
为了避免高能量高扫描速度的激光对边缘区域的非晶硅膜层造成毁损,因此,本发明提供一种改良的激光退火装置,以避免激光照射到基板边缘区域的非晶硅膜层,而对此区域较薄的非晶硅膜层造成伤害。In order to avoid damage to the amorphous silicon film layer in the edge region by the laser with high energy and high scanning speed, the present invention provides an improved laser annealing device to avoid laser irradiation on the amorphous silicon film layer in the edge region of the substrate, and Damage to the thinner amorphous silicon film in this area.
当由连续式侧向固化法(SLS)使非晶硅膜再结晶时,激光束会先被定义出预定的形状,并以此激光对非晶硅膜进行持续的照射。图2为用于连续式侧向固化法(SLS)的激光退火装置。When the amorphous silicon film is recrystallized by continuous lateral solidification (SLS), the laser beam is first defined into a predetermined shape, and the amorphous silicon film is continuously irradiated with the laser beam. Figure 2 is a laser annealing device for continuous lateral solidification (SLS).
对再结晶非晶硅膜而言,未定义的初始激光22会自激光源10放射出来,并会通过衰减器(attenuator)11、光束均匀器(homogenizer)12和视野镜(field lens),由此聚集激光束22并控制激光束22的能量。For the recrystallized amorphous silicon film, the undefined
接下来,激光束22会由通过罩幕(mask)14而定义出预定的形状。当定义后的激光束22通过物镜(object lens)15后,激光束22会照射在工序反应室20内转移平台16上的基板18的非晶硅膜17,使其转换成多晶硅膜,对应于基板18边缘区域的激光会被遮蔽结构21挡住,或经遮蔽结构21而使此区域的激光束部份穿透。图中标号19-1、19-2、19-3指反射镜,用以控制激光束22的路径。Next, the
图2中的工序反应室的结构为本发明一较佳实施例,图3为此部份结构的放大图。The structure of the process reaction chamber in FIG. 2 is a preferred embodiment of the present invention, and FIG. 3 is an enlarged view of a part of the structure.
遮蔽结构21例如是由支撑结构21b、旋转装置21c和挡板21a所组成,其中支撑结构21b例如图4中的支撑板21b1,或是图5中的支撑架21b2,固定于转移平台16上,用以支撑挡板21a,而挡板21a可由旋转装置21c固定于支撑结构21b上,并做旋转,以利于基板18的进出。图6为挡板21a旋转至可便于基板18进行进出的位置的示意图。The shielding
图7为本发明另一较佳实施例的一种工序反应室的结构示意图,遮蔽结构21例如是由挡板21a和伸缩装置21d所组成,伸缩装置21d例如固定于工序反应室壁面,用以支撑伸缩装置21d和挡板21a,而挡板21a可由伸缩装置21d控制挡板21a的位置,图8为挡板21a收缩至可便于基板18进行进出的位置的示意图。7 is a schematic structural view of a process reaction chamber in another preferred embodiment of the present invention. The shielding
基板18可为玻璃基板,上述的非晶硅膜层17亦可为其它材质的非晶硅膜层,同样可由上述的方法,使非晶硅膜层转为多晶硅膜层。通常,在非晶硅膜层17和基板18之间还包括设置一层缓冲层(未绘示),其材质可为氮化硅。The
上述的挡板21a的材质选择可以反射或吸收激光束的材质,以使激光束可被完全挡住或者是部份穿透,其材质例如是金属材质(如铬、铝、银等)。The above-mentioned
本发明由改良激光退火装置,使激光束不会直接照射到基板边缘区域处厚度较薄的非晶硅层,以避免高能量的激光照射会使边缘区域的非晶硅层受损。The invention improves the laser annealing device so that the laser beam does not directly irradiate the thinner amorphous silicon layer at the edge region of the substrate, so as to avoid damage to the amorphous silicon layer at the edge region due to high-energy laser irradiation.
本发明由挡板的设计,使高扫描速度高能量的激光照射可以避开对边缘区域的直接照射,因此不会减少可用来制作面板的区域。In the present invention, the design of the baffle allows the high-scanning-speed and high-energy laser irradiation to avoid direct irradiation to the edge area, thus not reducing the area that can be used to make panels.
虽然本发明已以较佳实施例揭露如上,然其并非用以限定本发明,任何熟习此技艺者,在不脱离本发明的精神和范围内,当可作些许的更动与润饰,因此本发明的保护范围当视后附的申请专利范围所界定者为准。Although the present invention has been disclosed above with preferred embodiments, it is not intended to limit the present invention. Anyone skilled in the art can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, this The scope of protection of the invention shall be defined by the scope of the appended patent application.
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| CN112670206A (en) * | 2020-12-21 | 2021-04-16 | 上海华力集成电路制造有限公司 | Laser annealing equipment for improving wafer fragment and application method thereof |
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| JPH05304106A (en) * | 1992-04-28 | 1993-11-16 | Sony Corp | Excimer laser annealer |
| JP2000135578A (en) * | 1998-10-27 | 2000-05-16 | Sumitomo Heavy Ind Ltd | Laser irradiation device |
| US6071796A (en) * | 1998-10-30 | 2000-06-06 | Sharp Laboratories Of America, Inc. | Method of controlling oxygen incorporation during crystallization of silicon film by excimer laser anneal in air ambient |
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| CN1641844A (en) | 2005-07-20 |
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