CN1322078C - Inorganic powder texture coating, and its applying method - Google Patents
Inorganic powder texture coating, and its applying method Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及一种建筑涂料,特别是涉及一种可用于建筑物内外墙面的无机干粉质感涂料。The invention relates to an architectural coating, in particular to an inorganic dry powder texture coating which can be used on the inner and outer walls of buildings.
技术背景technical background
目前的建筑涂料,大部分是以合成树脂为主要成膜物质的有机涂料,合成树脂的原料主要来自石油,而石油是一种不可再生资源,随着社会的发展,石油作为一种主要能源以及重要的化工原料,由于大量开采已面临枯竭,以致供应日益紧张,出现石油危机。并且有机涂料的制造和施工的过程中都会使用一定量的有机溶剂,这些有机溶剂也是来自石油,而这些有机溶剂在涂料的生产和施工过程中会直接排放在大气中,这样既造成了资源的大量浪费,又会造成对环境和人体直接或间接的危害。无机涂料是以无机物为主要成膜物质,其主要成膜物质的来源为天然矿石、金属氧化物等,这些原料地球上储量丰富、易得,并且无机涂料多数以水为分散介质,成膜物质本身无毒,施工后不存在有机溶剂之类的挥发物,完全符合现代社会所要求的环保和可持续发展的要求。特别是无机干粉状的涂料,生产简便,不需要分散介质,避免了有机溶剂挥发到大气中造成污染,消除了涂料在生产、运输、贮存和施工过程中对人体健康的危害和可能产生的火灾等危险。Most of the current architectural coatings are organic coatings with synthetic resin as the main film-forming substance. The raw material of synthetic resin mainly comes from petroleum, and petroleum is a non-renewable resource. With the development of society, petroleum as a major energy source and Important chemical raw materials are facing depletion due to massive exploitation, resulting in increasingly tight supply and an oil crisis. Moreover, a certain amount of organic solvents will be used in the process of manufacturing and construction of organic coatings. These organic solvents also come from petroleum, and these organic solvents will be directly discharged into the atmosphere during the production and construction of coatings, which will not only cause resources. A large amount of waste will cause direct or indirect harm to the environment and human body. Inorganic coatings use inorganic substances as the main film-forming substances. The main sources of film-forming substances are natural ores, metal oxides, etc. These raw materials are abundant and easy to obtain on the earth, and most of the inorganic coatings use water as the dispersion medium. The substance itself is non-toxic, and there is no volatile matter such as organic solvents after construction, which fully meets the requirements of environmental protection and sustainable development required by modern society. In particular, inorganic dry powder coatings are easy to produce and do not require a dispersion medium, which avoids the pollution caused by the volatilization of organic solvents into the atmosphere, and eliminates the harm and possible damage to human health during the production, transportation, storage and construction of coatings. fire hazard.
有机涂料要达到一定的装饰效果,对基材平整度要求高,需要多次施工,涂层通常存在附着力较差,容易起泡、开裂、耐久性差等缺陷,且虽然色彩丰富,但表面效果以平面为主,很难做成各种立体或纹理效果。而无机涂料与多孔性无机底材有良好的结合性能,形成的涂层能透气、耐候性好、硬度高,具有良好的物化性能。In order to achieve a certain decorative effect, organic coatings have high requirements on the flatness of the substrate and require multiple constructions. The coating usually has defects such as poor adhesion, easy foaming, cracking, and poor durability. Although the color is rich, the surface effect It is mainly flat, and it is difficult to make various three-dimensional or texture effects. The inorganic coating has good bonding performance with the porous inorganic substrate, and the formed coating is breathable, has good weather resistance, high hardness, and has good physical and chemical properties.
发明内容Contents of the invention
为了避免有机涂料中溶剂对环境及人体健康带来危害,实现社会的可持续发展,节约能源,弥补有机涂料装饰性的单一化,本发明的目的是提供一种无机干粉质感涂料,其不含有机溶剂,可更好的保护墙面,使装饰效果多样化,施工简便,可满足日趋严格的环保要求及个性化的应用需求。In order to prevent solvents in organic coatings from harming the environment and human health, realize sustainable social development, save energy, and make up for the simplification of organic coatings, the purpose of the present invention is to provide an inorganic dry powder texture coating that does not contain Organic solvent can better protect the wall surface, make the decoration effect more diversified, and the construction is simple, which can meet the increasingly stringent environmental protection requirements and individual application requirements.
本发明的主要技术方案是如下:Main technical scheme of the present invention is as follows:
无机干粉质感涂料的组成为(重量百分比):水泥20~40%,可再分散乳胶粉2~8%,增稠剂0.1~0.5%,抗裂剂0.1~0.5%,彩砂30~60%,填料5~20%。The composition of the inorganic dry powder texture paint is (percentage by weight): 20-40% of cement, 2-8% of redispersible latex powder, 0.1-0.5% of thickener, 0.1-0.5% of anti-cracking agent, and 30-60% of colored sand , 5-20% filler.
本发明还可以按需要加入憎水剂,其重量百分比0.0~1.5%,也可以按需要加入无机颜料,其重量百分比0~3.0%。In the present invention, water-repellent agent can also be added as required, its weight percentage is 0.0-1.5%, and inorganic pigment can also be added as required, its weight percentage is 0-3.0%.
本发明的无机干粉质感涂料主要由无机材料水泥、彩砂、填料为主,再辅以可分散乳胶粉和多种添加剂。以水泥为主要粘结料,水泥为425号的白色硅酸盐水泥或425号的白色硅酸盐水泥与强度等级为42.5R的普通硅酸盐水泥的任意比例混合,施工应用在水泥基材上得到多孔性涂层,与基材逐渐形成同质层,牢固地粘结在一起。可再分散乳胶粉由醋酸乙烯酯与叔碳酸乙烯酯、乙烯、丙烯酸酯中的任意一种或一种以上反应生成的共聚物,经过喷雾干燥得到的乳液粉末,它具有良好的可再分散性,与水接触时重新分散成乳液,并且其化学性能与初始乳液完全相同,能提高材料的粘结力、内聚力,降低材料的吸水性、降低材料的弹性模量,增强材料的抗折强度、抗冲性、耐磨性和耐久性,提高材料的施工性能,一般在干混预拌砂浆中添加可再分散乳胶粉,可以改善砂浆的多种性能。增稠剂包括羟乙基甲基纤维素、羟丙基甲基纤维素等,加入增稠剂能使无机干粉质感涂料的保水性能和施工性能得到提高。抗裂剂包括木质纤维或人造纤维,其长度在长度0.02~5毫米、直径在1~100微米之间,增强漆膜的抗开裂性。所选用的憎水剂为有机硅类粉末和硬脂酸锌等。彩砂为天然彩砂和人工彩砂,由20~40目、40~80目、80~120目等不同粒径根据装饰性要求级配而成,能提供色彩和立体效果。颜料为无机干粉颜料。填料包括200~400目的石英粉或重质碳酸钙或硅灰石粉或滑石粉等,既填充空隙又可以降低成本。The inorganic dry powder texture paint of the present invention is mainly composed of inorganic materials such as cement, colored sand, and fillers, supplemented by dispersible latex powder and various additives. With cement as the main binder, the cement is white Portland cement No. 425 or white Portland cement No. 425 mixed with ordinary Portland cement with a strength grade of 42.5R in any proportion. The construction is applied to the cement substrate. A porous coating is obtained on the substrate, which gradually forms a homogeneous layer with the substrate and is firmly bonded together. Redispersible latex powder is a copolymer formed by the reaction of vinyl acetate and any one or more of vinyl tertiary carbonate, ethylene, and acrylate, and the emulsion powder obtained by spray drying has good redispersibility , when in contact with water, it redisperses into an emulsion, and its chemical properties are exactly the same as the initial emulsion, which can improve the cohesive force and cohesion of the material, reduce the water absorption of the material, reduce the elastic modulus of the material, and enhance the flexural strength of the material. Impact resistance, wear resistance and durability, improve the construction performance of the material, generally add redispersible latex powder to the dry-mixed ready-mixed mortar, which can improve various properties of the mortar. The thickener includes hydroxyethyl methylcellulose, hydroxypropyl methylcellulose, etc. Adding the thickener can improve the water retention and construction performance of the inorganic dry powder texture coating. The anti-cracking agent includes wood fiber or artificial fiber, the length of which is 0.02-5 mm in length and 1-100 microns in diameter, which enhances the cracking resistance of the paint film. The selected water-repellent is organic silicon powder and zinc stearate. Colored sand is natural colored sand and artificial colored sand, which are graded according to decorative requirements by 20-40 mesh, 40-80 mesh, 80-120 mesh, etc., and can provide color and three-dimensional effects. The pigment is an inorganic dry powder pigment. Fillers include 200-400 mesh quartz powder or heavy calcium carbonate or wollastonite powder or talcum powder, etc., which can not only fill the gap but also reduce the cost.
该涂料的生产工艺过程是:将各种原料按比例投入搅拌机中,混合均匀后即可包装入库。The production process of the coating is as follows: put various raw materials into the mixer in proportion, and after mixing evenly, they can be packaged and put into storage.
无机干粉质感涂料对合格的基材要求为平整、坚实、洁净,表面无油污、浮尘、疏松颗粒以及无霉菌、苔藻、油污等污染物。施工时先将无机干粉质感涂料按比例:涂料∶水<重量比>=100∶20~40调配,搅拌均匀,调节施工粘度,然后按需要用拉毛滚筒、压花滚筒、特殊滚筒、批刀、喷枪、刷子等施工工具中的一种或一种以上的工具,用辊涂、喷涂、批刮、刷涂等其中的任意一种或一种以上的施工方法,可得到不同造型的涂层,具有良好的装饰效果,特殊滚筒是指根据墙面造型设计成相应形状的滚筒。Inorganic dry powder texture coatings require qualified substrates to be flat, solid, and clean, with no oil, floating dust, loose particles, and no mold, moss, oil, and other pollutants on the surface. During construction, first mix the inorganic dry powder texture paint according to the ratio: paint: water <weight ratio>=100:20~40, stir evenly, adjust the construction viscosity, and then use napping rollers, embossing rollers, special rollers, trowels, One or more of the construction tools such as spray guns and brushes can be used to obtain coatings of different shapes by using any one or more of the construction methods such as roller coating, spray coating, batch scraping, brush coating, etc. It has a good decorative effect, and the special roller refers to a roller designed into a corresponding shape according to the shape of the wall.
该涂料与一般的涂料相比,具有以下特点:Compared with ordinary paints, this paint has the following characteristics:
1、低VOC,环保;所采用原料都是干粉状,大部分都是易得的无机材料,涂料中的VOC几乎为零,对人体和环境无不良的影响。1. Low VOC, environmental protection; the raw materials used are dry powder, most of which are easily available inorganic materials, the VOC in the coating is almost zero, and has no adverse effects on the human body and the environment.
2、施工容易、简便;可直接在合格的基材上施工,不需要底漆,可用各种施工工具施工。2. The construction is easy and convenient; it can be directly constructed on qualified substrates without primer, and can be constructed with various construction tools.
3、质感独特、装饰性强;各种不同的施工工具和施工方法可以获得各种不同的表面效果,有很高的装饰性,可以满足个性化的要求。3. Unique texture and strong decoration; various construction tools and construction methods can obtain various surface effects, which are highly decorative and can meet individual requirements.
4、耐水、透气、不起泡、不龟裂;无机粘结料、不同粒径级配的彩砂、填料等形成的涂层具有多孔性,使涂层具有良好的透气性、耐水性,不会起泡,各种添加剂的加入使涂层有一定的韧性不易产生龟裂。4. Water-resistant, breathable, non-foaming, and non-cracking; the coating formed by inorganic binders, colored sand with different particle size distributions, fillers, etc. is porous, which makes the coating have good air permeability and water resistance. It will not foam, and the addition of various additives makes the coating have a certain toughness and is not easy to crack.
5、色彩丰富自然、耐久性好;无机材料性质稳定,具有很好的耐候性,彩砂和无机颜料等可使涂层色彩自然,颜色丰富。5. The color is rich and natural, and the durability is good; the inorganic material is stable and has good weather resistance, colored sand and inorganic pigments can make the coating color natural and rich.
具体实施方式Detailed ways
实施例1Example 1
本实施例的组成及重量百分比为:425号白水泥20.0%,可再分散乳胶粉8.0%,羟丙基甲基纤维素0.2%,憎水剂有机硅粉未0.3%,木质纤维0.5%,80~120目彩砂56.0%,325目石英粉15.0%。The composition and percentage by weight of the present embodiment are: 20.0% of No. 425 white cement, 8.0% of redispersible latex powder, 0.2% of hydroxypropyl methylcellulose, 0.3% of water-repellent organic silicon powder, 0.5% of wood fiber, 56.0% of 80-120 mesh colored sand, 15.0% of 325 mesh quartz powder.
用实施例1所得的无机干粉质感涂料∶水=100∶30~35(重量比)开料;先批刮一遍,4小时后用拉毛滚筒辊涂一遍,养护七天,可获得有质感强烈、装饰性极高的有拉毛效果的涂层。Use the inorganic dry powder texture paint that embodiment 1 gains: water=100: 30~35 (weight ratio) cutting; First batch scrape once, after 4 hours, use nap roller roller to coat again, curing seven days, can obtain texture strong, decorative Highly resistant, napped coating.
实施例2Example 2
本实施例的组成及重量百分比为:425号白水泥28.0%,可再分散乳胶粉6.5%,羟丙基甲基纤维素0.35%,憎水剂有机硅粉未0.25%,木质纤维0.4%,无机颜料氧化铁红0.1%,80~120目彩砂54.55%,325目石英粉10.0%。The composition and percentage by weight of the present embodiment are: 28.0% of No. 425 white cement, 6.5% of redispersible latex powder, 0.35% of hydroxypropyl methylcellulose, 0.25% of water-repellent organic silicon powder, 0.4% of wood fiber, Inorganic pigment iron oxide red 0.1%, 80-120 mesh colored sand 54.55%, 325 mesh quartz powder 10.0%.
用实施例2所得的无机干粉质感涂料∶水=100∶25~30(重量比)开料;批刮二遍,养护七天,可获得有质感强烈、装饰极高的仿真石效果的涂层。With the inorganic dry powder texture paint that embodiment 2 gains: water=100: 25~30 (weight ratio) cutting; Batch scraping twice, curing seven days, can obtain the coating that has strong texture, highly decorated artificial stone effect.
实施例3Example 3
本实施例的组成及重量百分比为:425号白水泥35.0%,可再分散乳胶粉4.0%,羟乙基甲基纤维素0.3%,憎水剂0.4%,木质纤维0.2%,无机颜料氧化铁黄0.2%,40~80目彩砂5%,80~120目彩砂46.9%,325目石英粉8.0%。The composition and weight percent of this embodiment are: No. 425 white cement 35.0%, redispersible latex powder 4.0%, hydroxyethyl methylcellulose 0.3%, water repellent 0.4%, wood fiber 0.2%, inorganic pigment iron oxide Yellow 0.2%, 40-80 mesh colored sand 5%, 80-120 mesh colored sand 46.9%, 325 mesh quartz powder 8.0%.
用实施例3所得的无机干粉质感涂料∶水=100∶25~30(重量比)开料;直接用压纹滚筒辊涂一遍,养护七天,可获得有质感强烈、装饰极高的带有特殊纹理效果的涂层。Use the inorganic dry powder texture coating obtained in Example 3: water=100:25~30 (weight ratio) to cut the material; directly use the embossing roller to coat it once, and maintain it for seven days to obtain a strong texture and a very high decoration with special texture. Textured effect coating.
实施例4Example 4
本实施例的组成及重量百分比为:425号白水泥36.0%,42.5R普通硅酸盐水泥4%,可再分散乳胶粉2.0%,羟丙基甲基纤维素0.1%,憎水剂有机硅粉未0.2%木质纤维0.5%,20~40目彩砂2.0%,40~80目彩砂7.0%,80~120目彩砂43.2%,325目石英粉5.0%。The composition and weight percent of this embodiment are: 36.0% of No. 425 white cement, 4% of 42.5R ordinary Portland cement, 2.0% of redispersible latex powder, 0.1% of hydroxypropyl methylcellulose, and water-repellent organic silicon Powder 0.2% wood fiber 0.5%, 20-40 mesh colored sand 2.0%, 40-80 mesh colored sand 7.0%, 80-120 mesh colored sand 43.2%, 325 mesh quartz powder 5.0%.
用实施例4所得的无机干粉质感涂料∶水=100∶20~25(重量比)开料;直接用光身辊滚辊涂一遍,养护七天,可获得有质感强烈、装饰极高有仿树皮效果的涂层。Use the inorganic dry powder texture coating obtained in Example 4: water=100:20~25 (weight ratio) to cut the material; directly apply it once with a bare roller, and maintain it for seven days to obtain a strong texture, high decoration and imitation tree. Leather effect coating.
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| CN102276232B (en) * | 2011-05-31 | 2013-03-20 | 王天补 | Novel waterproof dry powder coating |
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