CN1321060C - Preparation method for zinc borate - Google Patents
Preparation method for zinc borate Download PDFInfo
- Publication number
- CN1321060C CN1321060C CNB2004100609228A CN200410060922A CN1321060C CN 1321060 C CN1321060 C CN 1321060C CN B2004100609228 A CNB2004100609228 A CN B2004100609228A CN 200410060922 A CN200410060922 A CN 200410060922A CN 1321060 C CN1321060 C CN 1321060C
- Authority
- CN
- China
- Prior art keywords
- zinc borate
- water
- preparation
- product
- zinc oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011787 zinc oxide Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 4
- 239000004327 boric acid Substances 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 4
- 230000029052 metamorphosis Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 4
- 239000003814 drug Substances 0.000 abstract description 3
- 239000003063 flame retardant Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 229960002645 boric acid Drugs 0.000 abstract 3
- 235000010338 boric acid Nutrition 0.000 abstract 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 description 8
- 238000000518 rheometry Methods 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 2
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 2
- 229940007718 zinc hydroxide Drugs 0.000 description 2
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Abstract
The present invention discloses a preparation method for zinc borate. In the method, boracic acid and zinc oxide are uniformly mixed firstly; then, the zinc oxide and the boracic acid are poured into a reaction container, water is added to the reaction container, and the boracic acid, the zinc oxide and the water are stirred and prepared into the rheologic state; the reaction container is closed, and the temperature of the reaction container is constant for some time at a certain temperature; after the container is cooled to the room temperature, a product is taken out to be dried. The preparation method for zinc borate of the present invention has the advantages of simple technology and no need of filtration or water washing after the reaction; the product is used for a flame retardant material and can also be used in daily chemical industry, biological medicine, etc.
Description
Technical field
The invention belongs to technical field of inorganic material, more specifically relate to a kind of preparation method of zinc borate, this product is used for fire retardant material, also can be used for fields such as daily-use chemical industry, biological medicine.
Background technology
According to bibliographical information, the existing method for preparing zinc borate mainly contains following several: be raw material with borax and zinc sulfate 1,, stir synthetic zinc borate in heated in water solution.Owing to two kinds of by products are arranged in this method reaction process, make separation circuit numerous and diverse [USP 3,649,172]; 2, be that raw material synthesizes zinc borate with zinc hydroxide and boric acid.This method needs on-site preparation zinc hydroxide [GB 1,348,900]; 3, be raw material with zinc oxide and boric acid, heated in water solution stir synthetic zinc borate [Zou Xuhua. the study on the synthesis [J] of BACN zinc borate (2335). use chemical industry, 2001,30 (2): 32～33].This method need add excessive boric acid in proportioning, with method 1 the same filtration, the water washing process of needing equally, although mother liquor can reuse, but the problem that exists boron loss and water to discharge.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of zinc borate.This method technological process simply, neither needs to filter, and does not also need water washing process, the reaction yield height.Products obtained therefrom purity height, there is not by product.
In order to realize that the technical measures that purpose of the present invention is taked are:
A kind of method for preparing zinc borate: 1) zinc oxide and boric acid (mol ratio is 1: 3) are mixed; 2) pour in the reaction vessel, add a certain amount of water (amount of water be zinc oxide and boric acid total mass 0.01%～60%), stir and be mixed with rheology attitude (the rheology attitude is non-ly consolidated non-liquid state for what is made up of zinc oxide, boric acid and water); 3) reaction vessel is airtight, and under 60～100 ℃ of temperature constant temperature 6～12 hours, reaction vessel is an encloses container; 4) treat that container is chilled to 20～30 ℃ of room temperatures after, take out product, 120～140 ℃ of oven dry down, promptly obtain the zinc borate product.5) preparation process does not need to filter, do not need washing.
Compared with prior art, the beneficial effect that adopts technical scheme of the present invention and reached:
Preparation method's technological process of the present invention is simple, does not need filtration, water washing process, and the reaction yield height is near 100%.Production process is accomplished zero release, is particularly suitable for industrial production.This product is used for fire retardant material, also can be used for fields such as daily-use chemical industry, biological medicine.
Embodiment
Example 1: take by weighing 3.24 gram zinc oxide and 7.24 gram boric acid respectively, after the mixing, add 6.00g water, be modulated into the rheology attitude, change in the encloses container in 80 ℃ of reactions 12 hours, be chilled to room temperature after, take out reaction product, directly oven dry obtains needed zinc borate product.
Example 2: take by weighing 1.62 gram zinc oxide and 3.71 gram boric acid respectively, after the mixing, add 0.05g water, be modulated into the rheology attitude, change in the encloses container in 100 ℃ of reactions 6 hours, be chilled to room temperature after, take out reaction product, directly oven dry obtains needed zinc borate product.
Example 3: take by weighing 3.24 gram zinc oxide and 7.24 gram boric acid respectively, after the mixing, add 6.00g water, be modulated into the rheology attitude, change in the non-encloses container in 80 ℃ of reactions 12 hours, be chilled to room temperature after, take out reaction product, directly oven dry can not get needed zinc borate product.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100609228A CN1321060C (en) | 2004-09-30 | 2004-09-30 | Preparation method for zinc borate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100609228A CN1321060C (en) | 2004-09-30 | 2004-09-30 | Preparation method for zinc borate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1603237A CN1603237A (en) | 2005-04-06 |
| CN1321060C true CN1321060C (en) | 2007-06-13 |
Family
ID=34666342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100609228A Expired - Fee Related CN1321060C (en) | 2004-09-30 | 2004-09-30 | Preparation method for zinc borate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1321060C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1789135B (en) * | 2005-12-12 | 2011-01-26 | 中国科学院青海盐湖研究所 | Hydrothermal method for preparation of shape-controllable low-hydrate zinc borate powder |
| CN100398441C (en) * | 2006-07-07 | 2008-07-02 | 上海安亿纳米材料有限公司 | Method of preparing nano-zinc borate |
| CN106219565A (en) * | 2016-07-25 | 2016-12-14 | 淄博五维实业有限公司 | The preparation method of three hydrate zinc borates |
| CN108147421B (en) * | 2016-12-05 | 2021-08-06 | 辽宁首钢硼铁有限责任公司 | Preparation method of zinc borate |
| CN110564037A (en) * | 2019-08-30 | 2019-12-13 | 浙江润阳新材料科技股份有限公司 | Preparation of flame-retardant smoke-inhibiting irradiation crosslinked polyethylene for automotive interior |
| CN113773671A (en) * | 2021-10-13 | 2021-12-10 | 赣州启源新材料有限公司 | Preparation method of high-dispersity nano flaky zinc borate powder |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3549316A (en) * | 1967-06-26 | 1970-12-22 | United States Borax Chem | Zinc borate of low hydration and method for preparing same |
| CN1072655A (en) * | 1991-11-22 | 1993-06-02 | 美国博克斯化学有限公司 | Zinc borate |
| SU1834846A3 (en) * | 1991-05-16 | 1993-08-15 | Tobapищectbo C Oгpahичehhoй Otbetctbehhoctью "Эkoxиmmaш" | Metal borates process |
| TR199901134A2 (en) * | 1999-05-21 | 2002-01-21 | Öztürk Fahretti̇n | 3.5 moles. crystalline aqueous zincborate production. |
| CN1364142A (en) * | 2000-01-11 | 2002-08-14 | 水泽化学工业株式会社 | Zinc borate, its preparation method and its use |
-
2004
- 2004-09-30 CN CNB2004100609228A patent/CN1321060C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3549316A (en) * | 1967-06-26 | 1970-12-22 | United States Borax Chem | Zinc borate of low hydration and method for preparing same |
| SU1834846A3 (en) * | 1991-05-16 | 1993-08-15 | Tobapищectbo C Oгpahичehhoй Otbetctbehhoctью "Эkoxиmmaш" | Metal borates process |
| CN1072655A (en) * | 1991-11-22 | 1993-06-02 | 美国博克斯化学有限公司 | Zinc borate |
| TR199901134A2 (en) * | 1999-05-21 | 2002-01-21 | Öztürk Fahretti̇n | 3.5 moles. crystalline aqueous zincborate production. |
| CN1364142A (en) * | 2000-01-11 | 2002-08-14 | 水泽化学工业株式会社 | Zinc borate, its preparation method and its use |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1603237A (en) | 2005-04-06 |
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Granted publication date: 20070613 Termination date: 20110930 |