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CN1318118A - Apparatus and method for cleaning and refreshing fabrics with supplemental heat source - Google Patents

Apparatus and method for cleaning and refreshing fabrics with supplemental heat source Download PDF

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Publication number
CN1318118A
CN1318118A CN99810880A CN99810880A CN1318118A CN 1318118 A CN1318118 A CN 1318118A CN 99810880 A CN99810880 A CN 99810880A CN 99810880 A CN99810880 A CN 99810880A CN 1318118 A CN1318118 A CN 1318118A
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Prior art keywords
cleaning
fabric
bag
agent
substrate
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Chinese (zh)
Inventor
布鲁斯·艾伯特·耶泽尔
约翰·迈克尔·詹森
马修·爱德华·沃尔彭海因
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Procter and Gamble Ltd
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Procter and Gamble Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F43/00Dry-cleaning apparatus or methods using volatile solvents
    • D06F43/007Dry cleaning methods
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F58/00Domestic laundry dryers
    • D06F58/20General details of domestic laundry dryers 
    • D06F58/203Laundry conditioning arrangements
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F58/00Domestic laundry dryers
    • D06F58/30Drying processes 
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F73/00Apparatus for smoothing or removing creases from garments or other textile articles by formers, cores, stretchers, or internal frames, with the application of heat or steam 
    • D06F73/02Apparatus for smoothing or removing creases from garments or other textile articles by formers, cores, stretchers, or internal frames, with the application of heat or steam  having one or more treatment chambers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F58/00Domestic laundry dryers
    • D06F58/20General details of domestic laundry dryers 
    • D06F58/26Heating arrangements, e.g. gas heating equipment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B40/00Technologies aiming at improving the efficiency of home appliances, e.g. induction cooking or efficient technologies for refrigerators, freezers or dish washers
    • Y02B40/18Technologies aiming at improving the efficiency of home appliances, e.g. induction cooking or efficient technologies for refrigerators, freezers or dish washers using renewables, e.g. solar cooking stoves, furnaces or solar heating

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

处理纺织物的设备含有一个配置了边面板的处理袋,边面板限定处理袋的内室大小并至少可以悬挂一件纺织物品在内室中。一种液态清洗更新剂被放置于这个织物处理袋的内部或者附近,使来自清洗更新剂的蒸汽可以进入处理袋的内室。处理袋是受制于一个辅助热源。优选被动的辅助热源,更好的被动辅助热源是选自下组:阳光辐射、一种颗粒发热剂、和二者的混合物。还提供了使用本发明设备来清洗和更新纺织物品的方法。

Figure 99810880

The apparatus for treating textiles comprises a treatment bag provided with side panels which define the size of the inner chamber of the disposal bag and are capable of suspending at least one textile article in the inner chamber. A liquid cleansing refresher is placed in or near the fabric disposal bag so that vapors from the cleansing refresher can enter the inner chamber of the disposal bag. The disposal bag is subject to an auxiliary heat source. Passive auxiliary heat sources are preferred, more passive auxiliary heat sources are selected from the group consisting of solar radiation, a particulate heat generating agent, and mixtures of the two. Also provided are methods of cleaning and refreshing textile items using the apparatus of the invention.

Figure 99810880

Description

使用配有辅助热源的用来清洗和 更新纺织物的设备和方法Apparatus and method for cleaning and refreshing textiles using an auxiliary heat source

技术领域technical field

本发明是关于一种通过非浸泡方式来清洗和更新纺织物的设备和方法。它使用一个辅助热源,以一个被动热源较为适合。The present invention relates to an apparatus and method for cleaning and refreshing textiles by non-immersion means. It uses an auxiliary heat source, preferably a passive heat source.

发明背景Background of the invention

一些精致的纺织物是不适宜用传统的家庭浸入清洗法来清洗。虽然对当今社会里的许多纺织物来说,家用洗衣机已经可以提供极好的的清洗效果,在某种情况下,它会造成丝绸,亚麻,羊毛和其他一些精致纺织物收缩或其它方面的损伤。消费者一般把他们的精致纺织物拿去‘干洗’。然而,干洗一般都需要把纺织物沉浸在几种碳氢化合物和卤化碳溶剂中,它们要求专门的操作,而且溶剂必须得到回收。结果造成这种方式不适于家庭使用。因此,干洗在传统上是由商店经营的,同家庭清洗方式来比,它是既不方便又费用高。Some delicate textiles are not suitable for cleaning by traditional domestic immersion cleaning methods. While domestic washing machines already provide excellent cleaning results for many textiles in today's society, at some point it can cause silk, linen, wool and some other delicate textiles to shrink or otherwise damage . Consumers generally take their delicate textiles to 'dry cleaning'. However, dry cleaning generally involves immersing textiles in several hydrocarbon and halocarbon solvents, which require specialized operations, and the solvents must be recovered. As a result, this mode is not suitable for home use. Thus, dry cleaning has traditionally been operated by shops and is inconvenient and expensive compared to home cleaning.

人们已经作了许多尝试去提供一种家庭用的干洗系统,它既具家庭浸入方式对织物的清洗和更新又具有干洗方式保护织物的优越性。其中的一种家庭清洗更新衣物系统由一张含有几种液态或胶化的清洗剂的基片和一个塑料袋子组成。衣服和基片一起被放置在袋中,然后被放置于一个传统式滚筒干衣机中翻动。在目前的商业实施方案中,多个含有清洗更新剂的一次性使用型的基片是和一个可多次使用的塑料袋被包装在一起出售的。Many attempts have been made to provide a home dry cleaning system which combines the cleaning and renewal of fabrics by home immersion with the advantages of fabric protection by dry cleaning. One such home cleaning refreshment system consists of a substrate containing several liquid or gelled cleaning agents and a plastic bag. The garment is placed in the bag with the substrate and then tumbled in a conventional tumble dryer. In the current commercial embodiment, a plurality of single-use substrates containing a cleaning refresher are packaged together in a reusable plastic bag for sale.

遗憾的是,这种家庭用方法的设计是在一个传统式干衣机或者与其类似的设备中使用。这类设备不是总容易得到,也常常是不经济的。而且在许多国家里干衣机是不需要的。例如,在许多热带地区,人们不会专门地去拥有干衣机,因为无论在任何季节里把他们的衣物挂在外面的阳光里便会使其干燥。在人们不专门拥有干衣机的世界地区里,那些需要热源设备的产品(像干衣机)是几乎或完全没有价值的。Unfortunately, this home method is designed to be used in a conventional clothes dryer or similar. Such equipment is not always readily available and is often uneconomical. And in many countries clothes dryers are not needed. For example, in many tropical regions, people do not go out of their way to own clothes dryers because hanging their clothes outside in the sun will dry them no matter what the season. In parts of the world where people don't exclusively own clothes dryers, products that require heat source equipment (like clothes dryers) are of little or no value.

因此,需要去发展一种家庭的非浸泡式的清洗更新方法和清洗更新剂,它在不需要一个机械的,电力的或者燃烧的热源的情况下,提供可以接受的清洗。Therefore, there is a need to develop a household non-immersion cleaning refreshment method and cleaning refresher that provides acceptable cleaning without the need for a mechanical, electrical or combustion heat source.

现已无意中发现,在一个家庭用非浸泡清洗更新操作中,与清洗更新剂和织物处理袋一起使用某些热源,像阳光辐射和化学氧化反应,可以有效地清洗和更新纺织物。本发明提供了设备;设备的使用方法;和一些不需要使用机械的,电力的,或者燃烧的热源来清洗和更新纺织物的装置的成套工具。It has now been inadvertently discovered that certain heat sources, such as solar radiation and chemical oxidation reactions, are used in conjunction with a cleaning refresher and a fabric treatment bag to effectively clean and refresh fabrics in a domestic non-immersion cleaning refreshment operation. The present invention provides apparatus; methods of using the apparatus; and kits of means for cleaning and refreshing textiles that do not require the use of mechanical, electrical, or combustion heat sources.

发明概述Summary of the invention

本发明的一方面是提供一些用来处理纺织物的设备,它们包括:An aspect of the present invention is to provide some equipment for processing textiles, they include:

a)一个配置了边面板的处理袋,由边面板限定处理袋的内室大小并至少可以悬挂一件纺织物品在内室中;a) a disposal bag equipped with side panels that define the size of the inner chamber of the disposal bag and allow at least one textile article to be suspended within the inner chamber;

b)一种液态的清洗更新剂;及b) a liquid cleaning and updating agent; and

c)一个被动的热源。c) A passive heat source.

被动的热源最好从下面一组中选择,它们包括:阳光辐射;一种颗粒放热剂和二者的混合。较好的颗粒发热剂是由铁粉,碳,至少一种金属盐和水所组成。The passive heat source is preferably selected from the group consisting of: solar radiation; a particulate exothermic agent and mixtures of the two. A preferred particulate exothermic agent is composed of iron powder, carbon, at least one metal salt and water.

在本发明的一个优选的实施方案中,清洗更新剂是以能释出的方式被吸收在吸附剂载体或基片上的。在本发明的另一方面中,此设备还包含了一个盛有清洗剂的加药装置。In a preferred embodiment of the invention, the cleaning refresher is releasably absorbed on the adsorbent carrier or substrate. In another aspect of the invention, the apparatus further includes a dosing device containing a cleaning agent.

本发明同样提供了一个非浸泡式清洗更新纺织物品的操作方法,其构成步骤如下:The present invention also provides a non-immersion method for cleaning and renewing textile items, the steps of which are as follows:

a)把纺织物品连同清洗更新剂一起放置于织物处理袋的内室中;a) Place the textile items together with the cleaning and updating agent in the inner chamber of the fabric disposal bag;

b)使织物处理袋受热于一个被动热源;b) subjecting the fabric treatment bag to a passive heat source;

c)把织物从处理袋中取出。c) Remove the fabric from the disposal bag.

在以上方法的(b)步骤过程中,最好将蒸汽从织物处理袋中排放出去。在这种操作过程的另一个优点是,织物有正面和反面,此操作进一步由下面的步骤组成:During step (b) of the above method, steam is preferably vented from the fabric treatment bag. Another advantage of this operation is that the fabric has both front and back sides, this operation further consists of the following steps:

a)把药剂瓶中的局部清洗剂涂抹在织物正面的被污染区;a) Apply the topical cleaner in the bottle to the contaminated area on the front of the fabric;

b)在步骤(a)的同时或者紧接它,使用一个助处理器接触纺织物正面被污染处周围;以及b) at the same time as or immediately following step (a), applying a co-processor to the front side of the textile around the contaminated area; and

c)使用一个污渍接受器接触纺织物反面被污染处周围;c) use a stain receiver to touch around the stained area on the reverse side of the textile;

本发明比早期技术的优势就在不需要使用像干衣机等昂贵的机械设备就能使织物得到清洗和更新。此外,当太阳能被作为被动的热源时,消费者不会有能量上的金钱花费。The advantage of the present invention over earlier technologies is that fabrics can be cleaned and renewed without the use of expensive mechanical equipment such as clothes dryers. Furthermore, when solar energy is used as a passive heat source, there is no monetary expenditure on energy for the consumer.

附图简述Brief description of the drawings

虽然本说明书以清楚地限定本发明的权利要求来结束,但参照本发明的详细叙述及附图相信会对本发明的权利要求做出更好的解释,其中Although the description ends with clearly defining the claims of the present invention, it is believed that the claims of the present invention will be better explained with reference to the detailed description and accompanying drawings of the present invention, wherein

图1是本发明的织物处理袋的示意图;Figure 1 is a schematic diagram of a fabric disposal bag of the present invention;

图2是本发明的织物处理袋的示意图,在其中为了一个基片视图而切除了处理袋的一角;Figure 2 is a schematic illustration of the fabric disposal bag of the present invention with a corner of the disposal bag cut away for a substrate view;

图3是本发明的织物处理袋的下半部位的局部示意图,在其中有一个辅助热源被置于一个基片下面;Figure 3 is a partial schematic view of the lower half of the fabric treatment bag of the present invention, in which an auxiliary heat source is placed under a substrate;

图4是本发明的织物处理袋的接近底部的局部示意图,在其中处理袋的一个边面板上安置了一个用来接收基片的口袋;Figure 4 is a partial schematic view near the bottom of a fabric processing bag of the present invention in which a pocket for receiving a substrate is disposed on one side panel of the bag;

图5是本发明的织物处理袋的示意图,在其中边面板是透明的,同时在处理袋的下部分没有安置任何排气口。Figure 5 is a schematic view of the fabric disposal bag of the present invention, in which the side panels are transparent without any vent openings disposed in the lower portion of the disposal bag.

本发明详细说明Detailed Description of the Invention

本发明提供了一种家庭用非浸泡的方式来清洗更新纺织物品的设备,这些设备是利用一个辅助热源,它最好是一个被动的热源。清洗和更新的过程是纺织物品与清洗更新剂一起在一个织物处理袋中完成的。清洗更新剂可以被直接加入处理袋中,例如通过把它倾注入口袋中,喷雾法,或者把它倾注入安置在处理袋中的计量器中。或者也可以通过基片把它加入处理袋,清洗更新剂是以能释出的方式被吸入基片的。The present invention provides an apparatus for cleaning and renewing textile items in the home in a non-immersion manner, using an auxiliary heat source, preferably a passive heat source. The process of cleaning and refreshing is done with the textile items together with cleaning and refreshing agent in a fabric treatment bag. The cleaning refresher can be added directly to the disposal bag, for example by pouring it into a pocket, spraying it, or pouring it into a meter housed in the disposal bag. Alternatively, it can be added to the processing bag through the substrate, the cleaning refresher being drawn into the substrate in a releasable manner.

被动的热源可以被放置于处理袋的里面,外面,或者附近,它引发了清洗更新剂至少部分的蒸发。接着蒸汽与纺织物品混合来清洗和更新纺织物。被蒸发的清洗更新剂连同有异味的化合物和其它的挥发性物质通过处理袋的上部被排放出去。下面将详细描述处理袋,清洗更新剂,被动热源,和在一个家庭非浸泡式清洗和更新操作中使用这些物品的方法。织物处理袋A passive heat source may be placed inside, outside, or near the disposal bag, which induces at least partial evaporation of the cleaning refresher. The steam is then mixed with the textile items to clean and refresh the textiles. The evaporated cleaning refresher, along with odorous compounds and other volatiles, is discharged through the upper portion of the disposal bag. The disposal bag, cleaning refresher, passive heat source, and method of using these items in a home non-immersion cleaning and refreshing operation are described in detail below. fabric disposal bag

图1是本发明的织物处理袋10的示意图,其中处理袋10高度为12,宽度为13,和厚度为14。虽然处理袋10是被显示为一个矩形盒子的外形,但是本发明并不意味着局限于此。其它结构的外形对于本发明也是适用的,例如锥体的,球形的,半球形的,双面服装袋和其它形状。处理袋可以是任何适当的尺寸。处理袋10较适合的尺寸如下:高度12是从大约40厘米至200厘米较佳,从50厘米至150厘米为更佳;宽度13是从大约30厘米至大约100厘米较佳,从大约40厘米至大约80厘米为更佳;厚度14是从大约0厘米至大约100厘米较佳,从大约10厘米至大约80厘米为更佳。FIG. 1 is a schematic illustration of a fabric disposal bag 10 of the present invention, wherein the disposal bag 10 has a height 12 , a width 13 , and a thickness 14 . Although the disposal bag 10 is shown in the shape of a rectangular box, the invention is not meant to be limited thereto. Other structural shapes are also suitable for use with the present invention, such as pyramidal, spherical, hemispherical, double-sided garment bags, and other shapes. The disposal bag can be of any suitable size. The preferred dimensions of the disposal bag 10 are as follows: the height 12 is preferably from about 40 cm to 200 cm, more preferably from 50 cm to 150 cm; the width 13 is preferably from about 30 cm to about 100 cm, preferably from about 40 cm More preferably, the thickness 14 is from about 0 cm to about 100 cm, more preferably from about 10 cm to about 80 cm.

处理袋10是优选由边面板21所构成,由边面板决定一个内室23的范围,可通过入口15进入内室。在处理袋10运作期间,入口15要被掩盖,可以使用被连在边面板21上并附有封条17的入口面板19完成此项工作。那些有经验的专家都会知道用来进入本发明的处理袋的内室23的方法很多,其中一种方法便如图2所示。封条17可以由任何已知的封闭装置构成,例如拉链,胶布,ZIP LOCK_封条,吊钩,环形按钮,例如VELCRO_The processing bag 10 is preferably composed of side panels 21 , which determine the scope of an inner chamber 23 , which can be entered through the entrance 15 . During operation of the disposal bag 10, the inlet 15 is to be concealed. This can be done using the inlet panel 19 attached to the side panel 21 with the seal 17 attached. Those experienced experts will know that there are many ways to enter the inner chamber 23 of the disposal bag of the present invention, one of which is shown in FIG. 2 . The seal 17 can be made of any known closure means, such as zippers, adhesive tape, ZIP LOCK _ seals, hooks, ring buttons, such as VELCRO _ .

处理袋10可以用任何适合的材料来制造,例如塑料,纺织物,金属和它们的类似材料。像聚乙烯和聚丙烯的塑料片材被推荐用作边面板21,顶面板30和底面板36的制造。这种片材可以是坚硬的或者是有弹性的。面板21,30和36可以是透明的,或者选自下面一组里的材料,它们包括:不透明的材料,可阻挡紫外线的材料和二者的混合材料。如图1中所示,在处理袋10有一段高度为18的不透明中段部分27,有一段高度为20的透明下段部分29,和有一段高度为16的透明上部分31。图5表明处理袋100的中段42是透明的。处理袋的剩余部分也是透明的。Disposal bag 10 may be constructed of any suitable material, such as plastic, fabric, metal and the like. Plastic sheets like polyethylene and polypropylene are recommended for the manufacture of side panels 21 , top panel 30 and bottom panel 36 . Such sheets can be rigid or elastic. Panels 21, 30 and 36 may be transparent, or a material selected from the group consisting of: opaque materials, UV blocking materials and combinations of the two. As shown in FIG. 1, the disposal bag 10 has an opaque middle section 27 with a height of 18, a transparent lower section 29 with a height of 20, and a transparent upper section 31 with a height of 16. Figure 5 shows that the central section 42 of the disposal bag 100 is transparent. The remainder of the disposal bag is also transparent.

专业人士都认识到,本质上所有的纺织物在紫外线辐射环境中都会发生一定程度的褪色,但在可见光环境中,褪色程度相对小些。因为在本发明的一个优选实施方案是需要让处理袋受到由紫外线辐射和可见光两者所组成的阳光辐射,所以需有一些防止织物褪色的措施。可以用屏障材料来提供对褪色的保护,例如一种紫外线阻断材料或者一种不透明材料。这里所用的“不透明材料”是指任何材料,例如:织物,塑料,薄金属,涂层,例如防阳膜和涂料,及其它。这些材料会吸收或者反射掉至少50%,好的可达75%,最高的能达到90%的照射在它们上面的紫外线辐射,可见光,或者它们二者。可以用屏障材料来制造整个处理袋或者只是如图1中所示的那部分。专业人士会知道用那些阻断紫外辐射材料,像其中一例是聚萘二甲酸乙二酯,“PEN”。It is recognized by professionals that virtually all textiles will fade to some extent in the presence of ultraviolet radiation, but to a lesser extent in the presence of visible light. Because in a preferred embodiment of the present invention it is necessary to expose the disposal bag to sunlight consisting of both ultraviolet radiation and visible light, some means of preventing fading of the fabric is required. Protection against fading can be provided by a barrier material, such as a UV blocking material or an opaque material. As used herein, "opaque material" means any material such as: fabrics, plastics, thin metals, coatings such as sunscreens and paints, and others. These materials absorb or reflect at least 50%, preferably up to 75%, and up to 90% of the ultraviolet radiation, visible light, or both, that impinges on them. The entire disposal bag or just the portion as shown in FIG. 1 can be made from the barrier material. Professionals will know to use materials that block UV radiation, as one example is polyethylene naphthalate, "PEN".

织物处理袋10自选地包含一个上层骨架框28;一个底部骨架框34和侧面骨架框25。这些骨架框可以相互拆散,或者它们可以是一个整体结构。骨架框28是高度推荐的,但是这些骨架框中的一件或多件是可以不被安装。可以使用刚性的边面板去建造本发明的处理袋,并且可以使用转轴使处理袋可以折叠。The fabric disposal bag 10 optionally includes an upper frame 28 ; a bottom frame 34 and side frames 25 . These skeletal frames can be separated from each other, or they can be an integral structure. Skeleton frames 28 are highly recommended, but one or more of these skeletal frames may not be installed. Rigid side panels can be used to construct the disposal bag of the present invention, and hinges can be used to make the disposal bag collapsible.

如果使用一个骨架框,优选一个以柔韧的可折叠的材料所构成的骨架框。当它被展开时,会构成一个半刚性的三维结构。已有可折叠结构之实例,例如在1991年8月13日授予Norman的美国专利U.S.Patent No.5,038,812中的实例,这个专利在这里以文献形式编入。在一般情况下,像那些在Norman专利中所述的柔韧的可折叠骨架框是由相对坚固但又有足够的柔韧性可以使其被折叠的材料所构成的。一种典型的骨架材料是扁平型弹簧钢,其矩形横切面的宽为1.6毫米和长为76毫米。骨架或者骨架框可以铆合,粘连,或者以别的方式附于处理袋的内部或外部。同样,处理袋材料可以是松散地被挂在骨架或者骨架框的上面或者被骨架或者骨架框扩展开。If a skeleton frame is used, it is preferably constructed of a flexible, foldable material. When unfolded, it forms a semi-rigid three-dimensional structure. Examples of foldable structures exist, such as in U.S. Patent No. 5,038,812, issued to Norman on August 13, 1991, which is hereby incorporated by reference. In general, flexible collapsible carcass frames such as those described in the Norman patent are constructed of materials that are relatively strong but flexible enough to allow them to be folded. A typical frame material is flat spring steel with a rectangular cross-section 1.6 mm wide and 76 mm long. The skeleton or skeleton frame can be riveted, glued, or otherwise attached to the interior or exterior of the disposal bag. Likewise, the bag material may be loosely hung on or spread out from the frame or frame.

现在谈及图3,它是一个处理袋10的下部分29的切面图。它显示了一个覆盖在任选的辅助热源50上面的基片40。基片40是一种把清洗更新药剂提供到处理袋10的内室23中去的优选方法。在这里清洗更新药剂是以能释出的方式被吸入基片的。其它把清洗更新药剂添加入处理袋10中的方法包括:直接加入和为专业人士所熟知的加料装置,还有其它的专业人士所用的方法。任选的辅助热源50可以是像下面描述的由颗粒发热剂构成的热池。另外,辅助热源50也可以是一个受热器,比如一个可以在吸收了阳光辐射后使表面温度升高的深色材料,它通过热量传递使含有清洗更新剂的基片40温度升高。辅助热源50可以是任何适当的尺寸。但是如果辅助热源50的目的是吸收阳光辐射,那么辅助热源50就需要有一个大于基片40的表面积。这样当基片40直接放置于辅助热源50上面时,至少有一部分辅助热源50就会超过基片40的边缘。Turning now to FIG. 3, it is a cutaway view of the lower portion 29 of the disposal bag 10. As shown in FIG. It shows a substrate 40 overlying an optional auxiliary heat source 50 . The substrate 40 is a preferred method of delivering cleaning refreshment agents to the interior chamber 23 of the treatment bag 10. As shown in FIG. Here the cleaning and refreshing agent is drawn into the substrate in a releasable manner. Other methods of adding cleaning and refreshing agents to the treatment bag 10 include: direct addition and feeding devices known to those skilled in the art, and other methods used by those skilled in the art. The optional auxiliary heat source 50 may be a heat pool of particulate exothermic agent as described below. In addition, the auxiliary heat source 50 can also be a heat sink, such as a dark material that can increase the surface temperature after absorbing sunlight radiation, and it can increase the temperature of the substrate 40 containing the cleaning and updating agent through heat transfer. Auxiliary heat source 50 may be of any suitable size. However, if the purpose of the auxiliary heat source 50 is to absorb solar radiation, then the auxiliary heat source 50 needs to have a larger surface area than the substrate 40 . In this way, when the substrate 40 is directly placed on the auxiliary heat source 50 , at least a part of the auxiliary heat source 50 will exceed the edge of the substrate 40 .

现在谈及图4,在本发明的一个优选实施方案中,处理袋10进一步包含了一个用来接收清洗更新剂的口袋54。清洗更新剂可以被直接倒入口袋54,或者更好让清洗更新剂以能释出的方式吸入安置在口袋54中的基片40。口袋54可以在处理袋10的内室23内,或者它可以附在处理袋10的外部,但是口袋54最好是在边面板21上,这样可以增加阳光辐射60对清洗更新剂的照射量。口袋54需要与处理袋10的内室23保持流体联通,这样被蒸发的清洗更新剂才会与悬挂在处理袋中的纺织物品混合在一起。在图4中,口袋54是和一个任选的辅助热源52一起显示的。辅助热源52可以是一种深色材料,当它吸收了阳光辐射时可以使辅助热源52的温度升高,通过热量传递加热含有清洗更新剂的基片40。辅助热源52也可以是一个如下所描述的含有颗粒发热剂的热池。Referring now to FIG. 4, in a preferred embodiment of the present invention, the disposal bag 10 further includes a pocket 54 for receiving cleaning refresher. The cleaning refresher can be poured directly into the pocket 54, or preferably the cleaning refresher is drawn into the substrate 40 disposed in the pocket 54 in a releasable manner. The pocket 54 can be inside the inner chamber 23 of the disposal bag 10, or it can be attached to the outside of the disposal bag 10, but the pocket 54 is preferably on the side panel 21 to increase the exposure of the solar radiation 60 to the cleaning refresher. The pocket 54 needs to be in fluid communication with the inner chamber 23 of the disposal bag 10 so that the evaporated cleaning refresher mixes with the textile items suspended in the disposal bag. In FIG. 4 , the pocket 54 is shown with an optional auxiliary heat source 52 . The auxiliary heat source 52 can be a kind of dark material, when it absorbs the sunlight radiation, the temperature of the auxiliary heat source 52 can be increased, and the substrate 40 containing the cleaning and refreshing agent can be heated by heat transfer. Auxiliary heat source 52 may also be a heat bath containing a particulate exothermic agent as described below.

本发明的处理袋的一项优选实施方案中至少使用了一个排气口,如下所述,这个排气口不需要是一个分离的元件。在图1,图2和图5中显示了上排气口32,同时在图1至图4中显示了下排气口38。排气口32和38被分别地被显示在接近上面板30和底面板36的位置,但是这不代表本发明对此有所限制。排气口可以设置在边面板的任何位置上,并且排气口不必是一个分离的元件。明确的说,处理袋10可以通过入口周围和封条处以自然的泄漏来排气,例如入口15四周的封条17。也可以使用一个全封闭的内室用来专门增强内室的温度或蒸汽浓度。A preferred embodiment of the disposal bag of the present invention utilizes at least one vent, which need not be a separate component, as described below. The upper exhaust port 32 is shown in FIGS. 1 , 2 and 5 , while the lower exhaust port 38 is shown in FIGS. 1-4 . Exhaust ports 32 and 38 are shown proximate to upper panel 30 and bottom panel 36, respectively, but this is not meant to limit the invention thereto. The vent can be located anywhere on the side panel and the vent need not be a separate component. In particular, the disposal bag 10 can be vented through natural leaks around the inlet and seals, such as the seal 17 around the inlet 15 . It is also possible to use a fully enclosed inner chamber to specifically enhance the temperature or steam concentration of the inner chamber.

可以使用任何适当的方法把纺织物品悬挂在处理袋10的内室23中。在图1,2和5中显示了其中的一种方法,在图中提供一条横木10用来悬挂衣架26。在本发明的一个实施方案中,基片40可以被悬挂在处理袋10的内部,例如,把基片40悬垂在衣架26上。如上所述,处理袋10可以在一个刚性的骨架框的支撑下自由站立,或者可以通过悬挂器22使它被挂在某支撑处(图中没有示出)。虽然骨架框一般被优选用来控制和维持内室23的形状和体积的,但是如果在使用悬挂器22把处理袋10悬挂起来使用时,可以不使用任何骨架。The textile items may be suspended within the interior chamber 23 of the disposal bag 10 using any suitable method. One of these methods is shown in Figures 1, 2 and 5, where a rail 10 is provided for hanging a clothes hanger 26. In one embodiment of the present invention, the substrate 40 may be hung inside the disposal bag 10, for example, by hanging the substrate 40 from the hanger 26. As mentioned above, the processing bag 10 can stand freely under the support of a rigid skeleton frame, or it can be hung on a support by the hanger 22 (not shown in the figure). Although the skeleton frame is generally preferred to control and maintain the shape and volume of the inner chamber 23, if the hanger 22 is used to hang the processing bag 10 for use, any skeleton may not be used.

现在谈及图2,它是一个织物处理袋10的示意图,在图中为了更完全的显示基片40而切去了处理袋的一部分边角。可以看到边面板21是与阳光辐射60接触着的。由于阳光辐射60照射到处理袋10上而产生的广为人知的温室效应和辐射热使内室23中的温度上升。温度的升高导致被以能释出的方式吸收在基片40上的清洗更新剂蒸发成蒸汽46。在内室23中温度的升高也导致了另一种众所周知的“烟囱效应”现象。这种烟囱效应导致外界的空气44通过下排气口38被吸入,在那里它与从基片40上蒸发出来的清洗更新剂的蒸汽相混合,一起向上运行穿越内室23,在这个过程中,空气和蒸汽的混合与任何被悬挂在那里的织物像图5中所示的衣物33相混合。接着这些空气/蒸汽混合物48便通过上排气口32被排放到大气中去。空气/蒸汽混合物48典型的包含了来自织物的异味混合物,例如香烟味和其它有可能附在织物上有挥发性的混合物。图5显示的处理袋100除了没有设在底部面板36上的排气口外,其它操作与上面所描述的大致一样。Turning now to FIG. 2, which is a schematic illustration of a fabric disposal bag 10, a portion of the bag has been cut away in order to more fully show the substrate 40. As shown in FIG. It can be seen that the side panels 21 are in contact with the solar radiation 60 . The temperature in the inner chamber 23 is raised by the well-known greenhouse effect and radiant heat due to solar radiation 60 impinging on the processing bag 10 . The increase in temperature causes the cleaning refresher releasably absorbed on the substrate 40 to evaporate as vapor 46 . The increase in temperature in the inner chamber 23 also leads to another phenomenon known as the "chimney effect". This chimney effect causes outside air 44 to be sucked in through the lower exhaust port 38 where it mixes with the vapors of cleaning and refreshing agent evaporated from the substrate 40 and travels up through the inner chamber 23 together, in the process , the mixture of air and steam mixes with any fabric that is hung there like the clothes 33 shown in FIG. 5 . The air/steam mixture 48 is then exhausted through the upper exhaust port 32 to the atmosphere. The air/steam mixture 48 typically contains odorous compounds from the fabric, such as cigarette smoke and other volatile compounds that may be attached to the fabric. The disposal bag 100 shown in FIG. 5 operates substantially as described above except that there is no vent on the bottom panel 36 .

在图2中显示了另一个基片40,它被垂吊在接近处理袋10的上部分31处的衣架26上。正如像这里所描述的,在织物处理清洗过程中可以使用一个或多个基片,它们都是以能释出的方式含有本发明的清洗更新剂的。另外,基片可以被放置在处理袋中实际上任何位置,或者如上面所描述的那样置于处理袋的外部临近处。图2中也显示了一个可供选择的用来进入处理袋10的内室的另一种通道19。Another substrate 40 is shown in FIG. As described herein, one or more substrates may be used in a fabric treatment cleaning process which contain the cleaning refresher of the present invention in releasable form. Additionally, the substrate may be placed in virtually any location within the processing bag, or as described above adjacent to the exterior of the processing bag. Also shown in FIG. 2 is an alternative channel 19 for accessing the inner chamber of the disposal bag 10 .

湍流的空气流穿过像图5中所显示的衣服33类的织物可以改善织物和气体的接触,从而加强了从纺织物品上消除异味的效果。猛烈的气流可以通过任何一种被专业人士所知的方法来实现,在处理袋内室中产生湍流的方法包括:特殊的袋子设计;袋内阻板;以电池,太阳能电池,或者其它可得到的能源作动力源的风扇;或者一个用上面讨论到的烟囱效应中产生出的上升热气流作为动力源的风扇。Turbulent air flow through a fabric like the garment 33 shown in Figure 5 improves the contact between the fabric and the air, thereby enhancing the odor removal effect from the textile item. The violent air flow can be achieved by any method known to those skilled in the art. Methods of creating turbulent flow in the treatment bag chamber include: special bag design; bag internal baffles; batteries, solar cells, or other available or a fan powered by the rising thermals generated by the chimney effect discussed above.

热源heat source

本发明的处理袋普遍需要一个辅助热源,更为适用的热源是被动的。这里‘被动的’是指不通过。机械的,电力的,或者燃烧的方式来提供热量的热源。那些非被动型而又可以被考虑使用于本发明中的辅助热源包括:例如,把一个的传统型头发用的吹风机部分置入处理袋,风筒运转便会在处理袋中产生一个热气流。阳光辐射和发热的化学品特别地被优选为被动热源。建议选用的发热化学品可以来自例如由铁粉,碳,金属盐和水组成的颗粒发热剂。Disposal bags of the present invention generally require an auxiliary heat source, a more suitable heat source being passive. Here 'passive' means not passing. A heat source that provides heat mechanically, electrically, or by combustion. Those non-passive auxiliary heat sources that can be considered for use in the present invention include, for example, a conventional hair dryer partly inserted into the treatment bag, the operation of which creates a hot air flow within the treatment bag. Solar radiation and heat-generating chemicals are particularly preferred as passive heat sources. Suggested exothermic chemicals may come from eg granular exothermic agents consisting of iron powder, carbon, metal salts and water.

在美国专利申请U.S.Patent Application No.08/604,694中描述了由颗粒发热剂构成的热池,此专利申请是在1996年2月21日以Timothy AlanBurkett的名义和HEAT CELL的题名申请的。全部No.08/604,694申请内容是作为参考资料被编入这里。如上所述,图3是一个织物处理袋10下部分29的局部示意图,在那里有一个辅助热源50被放置在基片40的下面。辅助热源50可以是例如一个或者多个在美国专利申请08/604,694中透露的那种热池。一种优选使用的颗粒发热剂是由铁粉,碳,至少一种金属盐和水组成的。下面描述了其中每一种成分的详细细节。Thermal cells composed of particulate exothermic agents are described in U.S. Patent Application No. 08/604,694, filed February 21, 1996 in the name of Timothy Alan Burkett and titled HEAT CELL. The entire contents of Application No. 08/604,694 are incorporated herein by reference. As noted above, FIG. 3 is a partial schematic view of the lower portion 29 of a fabric processing bag 10 where an auxiliary heat source 50 is positioned beneath the substrate 40. As shown in FIG. Auxiliary heat source 50 may be, for example, one or more heat sinks of the type disclosed in US Patent Application Serial No. 08/604,694. A preferred particulate exothermic agent is composed of iron powder, carbon, at least one metal salt and water. Details of each of these ingredients are described below.

铁粉iron powder

铁的放热氧化中用于电化学反应的阳极是铁。合适的铁源包括铸铁粉,还原铁粉,电解铁粉,废铁粉,生铁,熟铁,各种钢,铁合金,和类似物以及这类铁粉的各种处理后的品种。只要它们能与电导水和空气产生热,对于它们的纯度和种类等并没有特别限制。The anode used for the electrochemical reaction in the exothermic oxidation of iron is iron. Suitable iron sources include cast iron fines, reduced iron fines, electrolytic fine iron, scrap iron fines, pig iron, wrought iron, various steels, ferroalloys, and the like and various processed varieties of such iron fines. There are no particular limitations on their purity, kind, etc. as long as they can generate heat with electrically conductive water and air.

本发明中的颗粒放热成份一般含30%到80%重量比的铁粉,优选含50%到70%重量比。The granular exothermic composition in the present invention generally contains 30% to 80% by weight of iron powder, preferably 50% to 70% by weight.

虽然要发生铁的氧化反应需要氧,然而本发明的热池中并不需要一个内置的氧源,因为在制备颗粒放热成份时已将能产生氧的化学物质混入。这并不改变本发明的范围。本发明所用于此目的的氧源包括空气和不同纯度的人工生产氧。在这些氧源中,优选空气,因为它是最方便和廉价。Although oxygen is required for iron oxidation to occur, a built-in source of oxygen is not required in the thermal cell of the present invention because oxygen-generating chemicals are incorporated in the preparation of the particulate exothermic composition. This does not change the scope of the invention. Oxygen sources used in the present invention for this purpose include air and artificially produced oxygen of varying purities. Of these oxygen sources, air is preferred because it is the most convenient and inexpensive.

活性炭和非活性炭Activated and Non-Activated Carbon

铁发热氧化中电化学反应的阴极由活性炭充当。由于活性炭的内部结构高度多孔,这使它具有特别好的保水能力。活性炭不但能很好吸收水而且能吸附由放热成份发出的热所汽化的水蒸气而不使它逃逸。因此它可以充当一个保水材料。甚者,活性炭还可以吸附铁粉氧化后所产生的气味。The cathode of the electrochemical reaction in the exothermic oxidation of iron is acted by activated carbon. Due to the highly porous internal structure of activated charcoal, it has a particularly good water retention capacity. Activated carbon not only absorbs water well but also absorbs water vapor vaporized by the heat emitted by exothermic components without letting it escape. So it can act as a water-retaining material. What's more, activated carbon can also absorb the odor produced by the oxidation of iron powder.

从椰子壳,木材,木炭,煤,骨炭等制备的活性炭是可用的,其它如从动物制品,天然气,油脂和树脂等原料制成的活性炭也适用于本发明的热池。能用的活性炭的种类是没有限制的,但是优选的活性炭应具有很好的保水能力。阴极的功能也可以通过选用非活性炭粉而予以延伸,也就是通过炭的混合而降低成本。因此,上述各种炭也可以混合后用于本发明。Activated carbons made from coconut shells, wood, charcoal, coal, bone char, etc. are useful, as are other sources such as animal products, natural gas, oils and resins, which are also suitable for use in the thermal pools of the present invention. The type of activated carbon that can be used is not limited, but the preferred activated carbon should have a good water retention capacity. The function of the cathode can also be extended by choosing non-activated carbon powder, that is, the cost can be reduced by mixing carbon. Therefore, the various charcoals mentioned above can also be mixed and used in the present invention.

典型的是,活性炭,非活性炭以及它们的混合物在本发明的放热成份中占大约3%到大约25%重量比,优选占大约8%到大约20%,最优选占大约9%到大约15%重量比。Typically, activated carbon, non-activated carbon, and mixtures thereof comprise from about 3% to about 25% by weight of the exothermic ingredients of the present invention, preferably from about 8% to about 20%, most preferably from about 9% to about 15% by weight. %weight ratio.

金属盐metal salt

金属盐是充当活化铁粉表面反应的促进剂。它可以促进铁粉与空气的氧化反应并为放热成份提供导电性以抵御腐蚀反应。可用的金属盐包括多种硫酸盐如硫酸铁,硫酸钾,硫酸钠,硫酸猛,硫酸镁等,多种氯化物如氯化铜,氯化钾,氯化钠,氯化钙,氯化锰,氯化镁和氯化亚铜。同样,碳酸盐,乙酸盐,硝酸盐,亚硝酸盐和其它盐也可以用。The metal salt acts as an accelerator for activating the surface reaction of the iron powder. It facilitates the oxidation reaction of iron powder with air and provides conductivity to the exothermic components to resist corrosion reactions. Available metal salts include various sulfates such as ferric sulfate, potassium sulfate, sodium sulfate, manganese sulfate, magnesium sulfate, etc., various chlorides such as copper chloride, potassium chloride, sodium chloride, calcium chloride, manganese chloride , magnesium chloride and cuprous chloride. Likewise, carbonates, acetates, nitrates, nitrites and other salts can be used.

在这些金属盐中,一些容易潮解的盐如氯化钙,氯化镁等是非常吸湿的,因此这些化合物即使加入小量可以有效抑止水气的逃逸。氯化钠具有较低的溶解度温度依赖性,因而在低温下不会结晶沉淀下来,同时还会提供适当的热。这样就不会发生由于大气中空气的温度变化而引起生热效应的偏离。一般来说,几种合适的碱金属,碱土金属和过渡金属的盐也可以单独或组合后使用以抵御铁的腐蚀反应。Among these metal salts, some easily deliquescent salts such as calcium chloride, magnesium chloride, etc. are very hygroscopic, so even a small amount of these compounds can effectively inhibit the escape of water vapor. Sodium chloride has a low temperature dependence of solubility, so it will not crystallize and precipitate at low temperatures, while providing appropriate heat. In this way, no deviation of the heating effect due to the temperature change of the air in the atmosphere will occur. In general, several suitable salts of alkali metals, alkaline earth metals and transition metals can also be used alone or in combination to resist the corrosion reaction of iron.

本发明中优选的三种金属盐为氯化钠,氯化铜和它们的混合物。The three metal salts preferred in the present invention are sodium chloride, copper chloride and mixtures thereof.

典型的来说,本发明的颗粒放热剂含有大约0.5%到大约10%重量比的金属盐,优选大约1.0%到5%重量比的金属盐。Typically, the particulate exothermic agents of the present invention contain from about 0.5% to about 10% by weight metal salt, preferably from about 1.0% to 5% by weight metal salt.

water

在这里用的水,可以从任何合适的来源得到。对水的纯度,种类等没有特别的限制。典型地来说本发明的颗粒放热剂中含水从大约1%到大约40%重量比,优选从大约10%到大约30%重量比。Water used herein may be obtained from any suitable source. There are no particular restrictions on the purity, kind, etc. of the water. Typically the particulate exothermic agents of the present invention contain from about 1% to about 40% by weight water, preferably from about 10% to about 30% by weight water.

其它组份other components

本发明颗粒放热剂中含有上述组份外还可加入适当的其它组份。In addition to the above-mentioned components, the granular exothermic agent of the present invention may also be added with other appropriate components.

与碳一样其它保水材料也可以吸收反应促进剂的水溶液并可完成向共存的铁粉逐渐供应促进剂和水。可以用的其它保水组份包括:蛭石,多孔硅酸盐,木粉,木末,含有大量绒毛的棉布,棉的短纤维,纸屑,植物类物质,超高吸水可溶胀或水可溶树脂或聚合物,羧甲基纤维素盐,和其它具有大毛细功能和亲水性的多孔材料。Other water-retaining materials like carbon can also absorb the aqueous solution of the reaction accelerator and can accomplish the gradual supply of the accelerator and water to the coexisting iron powder. Other water-retaining ingredients that may be used include: vermiculite, porous silicates, wood flour, wood dust, cotton cloth with a lot of fluff, short fibers of cotton, paper scraps, vegetable matter, superabsorbent swellable or water soluble Resins or polymers, carboxymethylcellulose salts, and other porous materials with large capillary function and hydrophilicity.

典型地来说,本发明的颗粒放热剂中的其他保水材料含量为大约0.1%到30%重量比,优选含量为大约0.5%到20%重量比,最优选含量为大约1%到10%。Typically, the particulate exothermic agents of the present invention comprise from about 0.1% to 30% by weight of other water retaining materials, preferably from about 0.5% to 20% by weight, most preferably from about 1% to 10% .

其他组份中还包括氧化反应加强剂,例如元素铬,锰,或铜含有上述元素的化合物或它们的混合物;氢气抑止剂,例如无机或有机碱化合物或碱的弱酸盐包括:氢氧化钠,氢氧化钾,碳酸氢钠,碳酸钠,氢氧化钙,碳酸钙和丙酸钠;填充料如天然纤维碎片包括木屑,棉毛,和纤维素,合成纤维的碎屑包括:聚酯纤维;泡沫合成树脂,例如泡沫聚苯乙烯和泡沫聚氨酯;无机化合物包括:二氧化硅粉,多孔硅胶,硫酸钠,硫酸钡,氧化铁和氧化铝;抗结饼剂例如磷酸三钙和硅铝酸钠。这样的组份还包括增稠剂例如玉米淀粉,土豆淀粉,羧甲基纤维素,和α-淀粉;表面活性剂例如那些包括在阴离子型,阳离子型,非离子型,两性离子型的一些品种。如果要用的话,优选的表面活性剂是非离子型的,本发明中的颗粒放热剂适当时还可以加其他组份包括增延剂例如硅酸盐,锆和陶瓷。Other components also include oxidation reaction enhancers, such as elemental chromium, manganese, or copper compounds containing the above elements or their mixtures; hydrogen inhibitors, such as inorganic or organic base compounds or weak acid salts of bases include: sodium hydroxide , Potassium Hydroxide, Sodium Bicarbonate, Sodium Carbonate, Calcium Hydroxide, Calcium Carbonate, and Sodium Propionate; fillers such as natural fiber chips including wood chips, cotton wool, and cellulose, synthetic fiber chips including: polyester fibers; foam Synthetic resins such as foamed polystyrene and foamed polyurethane; inorganic compounds including: silica powder, porous silica gel, sodium sulfate, barium sulfate, iron oxide and aluminum oxide; anti-caking agents such as tricalcium phosphate and sodium aluminosilicate. Such components also include thickeners such as corn starch, potato starch, carboxymethylcellulose, and alpha-starch; surfactants such as those included in anionic, cationic, nonionic, and zwitterionic types . The preferred surfactants, if used, are nonionic. The particulate exothermic agents of the present invention may optionally contain other components including extenders such as silicates, zirconium and ceramics.

粒度范围Granularity range

本发明中颗粒放热剂中的粒子中至少有50%重量百分数,更好有70%,再好有80%,最好有90%的平均粒度小于200μm,优选小于150μm。At least 50% by weight of the particles in the granular exothermic agent of the present invention, more preferably 70%, more preferably 80%, and most preferably 90% have an average particle size of less than 200 μm, preferably less than 150 μm.

混合组份方式Mixing method

上述发热剂中各组份可用经典混合技术在隔离空气的状态下进行。合适的混合这些组份的方法在1987年3月17日授于Yasuki等的美国专利U.S.Patent No.4,649,895中详述,这个专利在这里以文献形式编入。颗粒放热药剂可以放在任何合适的容器中,例如这里引用的美国专利U.S.Patent No.4,649,895中所描述的那种。装配好的热池包封在一个不透空气的次级包装中以阻止氧化反应在不应发生时发生。这一点也在美国专利U.S.Patent No.4,649,895中有叙述。另一个方法是可以在热池的通气孔上封上一条不透气和可移走的胶粘带,这样一旦移走胶粘带,空气即可进入热池,激活铁粉的氧化反应。Each component in the above-mentioned exothermic agent can be carried out under the condition of isolating air by classical mixing technology. Suitable methods for mixing these components are described in detail in U.S. Patent No. 4,649,895, issued March 17, 1987 to Yasuki et al., which patent is hereby incorporated by reference. The particulate exothermic agent may be placed in any suitable container, such as that described in U.S. Patent No. 4,649,895, incorporated herein. The assembled thermal cell is enclosed in an airtight secondary packaging to prevent oxidation reactions from occurring when they should not. This is also described in U.S. Patent No. 4,649,895. Another method is to seal an airtight and removable adhesive tape over the vent hole of the hot pool, so that once the adhesive tape is removed, air can enter the hot pool and activate the oxidation reaction of the iron powder.

清洗更新药剂cleaning update potion

清洗更新药剂优选含有水和另一成份,这个成份可以从下列一组物质中挑选。它们包括:表面活性剂,香水,防腐剂,漂白剂,辅助清洗剂,防缩剂,有机溶剂,及其混合物。优选的有机溶剂为乙二醇醚,特别是甲氧基丙氧基丙醇,乙氧基丙氧基丙醇,丙氧基丙氧基丙醇,丁氧基丙氧基丙醇,丁氧基丙醇,乙醇,异丙醇及其混合物。本发明所用织物防缩剂是从下列一组物质中挑选,它们是乙二醇,丙二醇的所有异构体,丁二醇,戊二醇,己二醇,及其混合物。织物防缩剂更优选的可以从下列物质中挑选,它们是新戊二醇,聚乙二醇,1,2-丙二醇,1,3-丁二醇,1-辛醇以及它们的混合物。优选的表面活性剂为非离子型的例如一个乙氧基化的醇或乙氧基化的烷基苯酚。它们在清洗清新剂中所占重量分数可以高到2%。典型的清洗更新剂含水重量分数,至少大约80%,较优选至少大约90%,最优选至少大约为95%。The cleansing refreshment agent preferably contains water and another ingredient which can be selected from the following group of substances. They include: surfactants, perfumes, preservatives, bleaches, cleaning aids, anti-shrinkage agents, organic solvents, and mixtures thereof. Preferred organic solvents are glycol ethers, especially methoxypropoxypropanol, ethoxypropoxypropanol, propoxypropoxypropanol, butoxypropoxypropanol, butoxy propanol, ethanol, isopropanol and mixtures thereof. The fabric antishrink agent used in the present invention is selected from the following group of materials, which are ethylene glycol, all isomers of propylene glycol, butylene glycol, pentylene glycol, hexylene glycol, and mixtures thereof. The fabric anti-shrinkage agent can more preferably be selected from the following materials, which are neopentyl glycol, polyethylene glycol, 1,2-propylene glycol, 1,3-butanediol, 1-octanol and their mixtures. Preferred surfactants are nonionic such as an ethoxylated alcohol or ethoxylated alkylphenol. Their weight fraction in the rinse freshener can be as high as 2%. Typical cleanser refreshers contain at least about 80%, more preferably at least about 90%, and most preferably at least about 95% water by weight.

下面的例子给出这里所用清洗清新剂中各组份的特定范围。一个更详细的清洗更新剂中各组份的含量,其中包括有机溶剂,表面活性剂,香料,防腐剂,漂白剂和辅助清洗剂等。信息可以在1998年8月4日授予You等人的美国专利U.S.Patent No.5,789,368中得到,You等人的专利的全部内容引用于此作为参考。此外,清洗清新剂也在美国专利申请U.S.Patent Application No.08/789,171中叙述,它是以Trinh等名于1997年1月24日提交申请的。Trinh等的申请的全部内容也引用于此作为参考。本发明中所用的防缩剂可在美国专利临时申请号U.S.ProvisionalApplication No.60/__中找到,它的题目为“可减少织物收缩的清洗剂”,它是Strang和Siklosi于1998年8月24日提交申请的。Strang和Siklosi申请的全部内容也引用于此作为参考。The following examples give specific ranges for the components of the rinse and fresheners used herein. A more detailed content of each component in the cleaning and updating agent, including organic solvents, surfactants, fragrances, preservatives, bleaching agents and auxiliary cleaning agents, etc. Information can be found in U.S. Patent No. 5,789,368 issued to You et al. on August 4, 1998, which is incorporated herein by reference in its entirety. In addition, cleaning fresheners are described in U.S. Patent Application No. 08/789,171, filed January 24, 1997 in the name of Trinh et al. The entire contents of the Trinh et al. application are also incorporated herein by reference. The anti-shrinkage agent used in the present invention can be found in U.S. Provisional Application No. 60/___, its title is "cleaning agent that can reduce fabric shrinkage", it was Strang and Siklosi on August 24, 1998 date of submission of the application. The entire contents of the Strang and Siklosi application are also incorporated herein by reference.

基片Substrate

本发明的一个实施方案中清洗更新剂可以在吸附剂基片(以后简称基片)上以能释出的方式吸附着。这个基片以能释出的方式含有清洗更新剂。“能释出的含有”的意思是药剂可以从基片有效地被释放到被玷污的织物上并作为织物清洗更新过程的一部分。这个释出主要通过辅助热源放出的热引起药剂气化而实现的。In one embodiment of the present invention, the cleaning and refreshing agent can be adsorbed on the adsorbent substrate (hereinafter referred to as the substrate) in a releasable manner. This substrate contains the cleaning refresher in releasable form. "Releasably contained" means that the agent can be effectively released from the substrate onto the soiled fabric as part of the fabric cleaning refreshment process. This release is mainly achieved by the vaporization of the medicament caused by the heat released by the auxiliary heat source.

载体或基片可以有各种形状例如粉粒,薄片,碎片等。然而,最好基片的形状为完整的垫或薄片,这样它可以在整个过程中维持它的结构完整性。本发明的基片和薄片在文献中有时称作“载体”或“吸收剂载体薄片”;不言而喻,所有这些称呼是指液体吸收材料,它们可以很方便地用来输运液体。这样的基片在You等的美国专利U.S.Patent No.5,789,368中有详细描述,并在本文中已作了参考引用。本发明中对这些基片的制造不再阐述,因为它们早已在文献中发表。可参阅Viazmensky等的1991年4月23日美国专利U.S.Patent No.5,009,747号和1994年3月8日美国专利U.S.Patent No.5,292,581号,它们在这里作了参考引用。The carrier or substrate can have various shapes such as granules, flakes, chips and the like. However, it is preferred that the substrate is in the form of a complete pad or sheet so that it maintains its structural integrity throughout the process. The substrates and sheets of the present invention are sometimes referred to in the literature as "carriers" or "absorbent carrier sheets"; it is understood that all these designations refer to liquid-absorbent materials which may conveniently be used to transport liquids. Such substrates are described in detail in U.S. Patent No. 5,789,368 to You et al., which is incorporated herein by reference. The manufacture of these substrates is not described in the present invention, since they have already been published in the literature. See U.S. Patent No. 5,009,747, April 23, 1991, and U.S. Patent No. 5,292,581, March 8, 1994, to Viazmensky et al., which are incorporated herein by reference.

基片应包含足够量的清洗更新剂以便有效地实现期望的目的。按不同的应用目的来改变基片和药剂的容量。基片的尺寸大小不应太大以至用户使用时不方便。典型的基片两面加在一起的宏观表面积至少大约在360平方厘米,最好在大约360平方厘米到大约3000平方厘米。例如,一块长方形的基片其X方向的长度为大约10厘米到大约35厘米,其Y方向长度为大约18厘米到大约45厘米。The substrate should contain a sufficient amount of cleaning refresher to be effective for its intended purpose. Change the capacity of the substrate and the medicament according to different application purposes. The size of the substrate should not be so large that it is inconvenient for the user to handle. Typical substrates have a combined macroscopic surface area of at least about 360 square centimeters, preferably from about 360 square centimeters to about 3000 square centimeters. For example, a rectangular substrate may have an X-direction length of about 10 cm to about 35 cm and a Y-direction length of about 18 cm to about 45 cm.

在本发明的一个较好的实施方案中,基片或是一个深色材料,或者覆In a preferred embodiment of the invention, the substrate is either a dark material, or

一个深色材料,例如一个黑色的织物。众所周知,深色材料比较白材料更容易吸热。因此,如果用日光作为辅助热源时,深色材料将吸收更多的热,并更多地使清洗更新剂气化。正如已经讨论过的那样,基片也可以任选使用一个罩单覆盖,这将在下面叙述。A dark material, such as a black fabric. It is well known that dark materials absorb heat more easily than white materials. Therefore, if sunlight is used as an auxiliary heat source, the dark material will absorb more heat and vaporize the cleaning and updating agent more. As already discussed, the substrate can also optionally be covered with a cover sheet, which will be described below.

罩单cover sheet

这里所用罩单与基片不同,相对来说罩单不像基片对清洗更新剂来说不是一个吸收剂。罩单是用憎水纤维制成,它不吸收液体也就不能促进液体输运。但是当对物件施加更大的压力时,可以让液体通过罩单纤维中间的空孔空间。因此在典型用途的条件下,罩单将提供一个物理的障碍来避免使含有清洗清新剂而变潮的基片与要清洗更新的织物直接接触。然而,罩单还是可以将清洗清新剂的蒸汽通过它而转移到织物处理袋中而使织物得以清洗和更新。如果希望的话,罩单上可以设有宏观的通道,棉毛,纤维或土粒可以通过它,这样进一步帮助将物件内的这类杂物予以捕获。The cover sheet used here is different from the substrate in that the cover sheet, unlike the substrate, is relatively not an absorbent for the cleaning and refreshing agent. The cover sheet is made of hydrophobic fibers, which do not absorb fluids and do not facilitate fluid transport. But when more pressure is applied to the object, the liquid can be allowed to pass through the empty space in the middle of the single fiber of the cover. Thus under conditions of typical use, the drapes will provide a physical barrier to prevent direct contact of the substrate dampened with the cleaning freshener from the fabric being refreshed. However, the cover sheet can still transfer the steam of the cleaning freshener through it to the fabric treatment bag so that the fabric can be washed and refreshed. If desired, the cover sheet can be provided with macroscopic channels through which lint, fibers or soil particles can pass, thus further assisting in capturing such debris within the article.

这样的纤维质的罩单最好是耐热的和憎水的。在上面已参考引用的You等的美国专利U.S.Patent No.5,789,368中有详细描述。另外,Wise等在1998年3月11日提交的悬案美国临时专利申请(Co-pending U.S.Provisional application)60/077,556中描述了对本发明罩单的改良。Wise等的全部内容也在这里参考引用。根据生产者的希望,可以将You等有关罩单的技术与Wise等的改进适当结合起来但不脱离本发明的精神和范围。Such fibrous coverings are preferably heat resistant and water repellent. It is described in detail in U.S. Patent No. 5,789,368 to You et al., cited above. Additionally, Wise et al. describe improvements to the cover sheet of the present invention in co-pending U.S. Provisional application 60/077,556, filed March 11, 1998. The entire contents of Wise et al. are also incorporated herein by reference. According to the hope of the producer, the technology related to the cover sheet of You, etc. can be properly combined with the improvement of Wise, etc. without departing from the spirit and scope of the present invention.

局部清洗剂spot cleanser

本方法的使用者可以得到各种局部清洗剂以便用于本发明的任选局部预处理步骤中。这些药剂是被用来在清洗前或清洗后去清除被处理织物上的局部污渍。当然,局部清洗剂必须不伤害被清洗的织物,也就是说在局部清洗时它不会使织物大量脱色,也不会在织物上留下可见的痕斑。因此,本发明的优点在于它提供的局部清洗剂中并不含有会在被清洗的织物上留下可见残留物的材料。这意味着优良的药剂在其配方中需含有最高可能的百分数的挥发物质-水。典型例子是它含水95%,最好97.7%和表面活性剂大约0.1%到0.7%。一个优选的局部清洗剂也将含有少量但有效的清洗溶剂,例如丁氧基丙氧基丙醇(BPP)。它的典型含量大约为1%到大约4%,优选大约2%。A variety of topical cleansers are available to the user of the present method for use in the optional topical pretreatment step of the present invention. These agents are used to remove spot stains from treated fabrics before or after washing. Of course, the spot cleaner must be harmless to the fabric being cleaned, that is to say it does not substantially discolor the fabric or leave visible stains on the fabric when spot cleaning. It is therefore an advantage of the present invention that it provides a spot cleaner which does not contain materials which leave visible residues on the fabrics being cleaned. This means that a good pharmaceutical contains the highest possible percentage of volatile matter - water - in its formulation. Typically it contains 95%, preferably 97.7% water and about 0.1% to 0.7% surfactant. A preferred spot cleaner will also contain a small but effective cleaning solvent such as butoxypropoxypropanol (BPP). Its typical level is from about 1% to about 4%, preferably about 2%.

优选的局部清洗剂在下面例证,在这里参考引用的You等的美国专利U.S.Patent No.5,789,368中有详细描述。另外,在1997年5月20日授于Roetker的美国专利U.S.Patent No.5,630,847中也有叙述。Roetker的专利全部内容在这里引作参考。Preferred topical cleansers are exemplified below and described in detail in U.S. Patent No. 5,789,368 to You et al., incorporated herein by reference. In addition, it is also described in U.S. Patent No. 5,630,847 issued to Roetker on May 20, 1997. The Roetker patent is incorporated herein by reference in its entirety.

助处理器coprocessor

在一个实施方案中,为帮助去除织物上的局部污渍而提供了一个助处理器。本发明的一个优点是局部清洗剂是盛在给药器例如一个瓶中提供的。给药器有一个长尖端,它可以充作助处理器。另外,助处理器可以包含一个吸收剂基材,例如,它可以是一个天然或人造海绵,一个纤维素质吸收片或垫片,或类似物。多个隆起物与这个基材接触并向外延伸。在这里参考引用的You等的美国专利U.S.Patent No.5,789,368中对助处理器给出了几个特例。In one embodiment, a co-processor is provided to aid in the removal of spot stains from fabrics. An advantage of the present invention is that the topical cleanser is provided in a dispenser, such as a bottle. The dispenser has a long tip that acts as a co-processor. Alternatively, the co-processor may comprise an absorbent substrate, which may be, for example, a natural or synthetic sponge, a cellulosic absorbent sheet or pad, or the like. A plurality of bumps contact the substrate and extend outwardly. Several special cases for coprocessors are given in U.S. Patent No. 5,789,368 to You et al., incorporated herein by reference.

吸收剂污渍接受器Absorbent Stain Receiver

一个吸收剂污渍接受器有时简称污渍接受器可以任选性地应用于任选预先局部清洗操作中。这样的污渍接受器可以由任何吸收剂材料制成,只要它们能吸入予局部清洗操作中所用的液态药剂。可丢弃的纸巾,布巾例如BOUNTYTM牌的纸巾,清洁碎布等都可以用。然而在一个较好的情况中污渍接受器特别设计使它能将液态药剂从玷污面积处排走。污渍接受器中的一种好的种类是它含有一个无纺布垫子,例如一个热粘合气铺织物(“TBAL”)。另一种很受欢迎的污渍接受器包含有聚合物泡沫,其中含有一个聚合了的水在油中的乳液,有时称作“poly-HIPE”。聚合物泡沫的制备方面在文献中有广泛的报导。可参阅1993年11月9日出版的DesMarais,Stone,Thompson,Young,LaVon和Dyer的美国专利U.S.Patent No.5,260,345;1996年8月27日出版的DesMarais的美国专利U.S.Patent No.5,550,167以及1997年7月22日出版的DesMarais等的美国专利U.S.Patent No.5,650,222。所有这些都在这里作参考引用。本发明的聚合物泡沫的典型制备条件在1998年3月13日由T.A.DesMarais等提交的共同申请的美国专利U.S.Patent Application Serial No.09/042,418。其标题为“分配水溶液的吸收剂材料”。它的披露在这里作为参考编入。本发明所用聚合物泡沫的制备条件的其他披露在1998年3月13日由T.A.DesMarais等提交的共同申请的美国专利U.S.Provisional PatentApplication Serial No.60/077,955中叙述。它的标题为“耐摩擦聚合物泡沫及由其制成的污渍接受器”。它的披露在这里是作为参考引用的。An absorbent stain catcher, sometimes referred to simply as a stain catcher, may optionally be employed in optional pre-spot cleaning operations. Such stain receivers may be made of any absorbent material provided they are capable of absorbing the liquid medicament used in the spot cleaning operation. Disposable paper towels, cloth towels such as BOUNTY™, cleaning rags, etc. can be used. However in a preferred situation the stain receiver is specifically designed to drain the liquid agent away from the stained area. A good variety of stain catchers consists of a nonwoven pad, such as a thermally bonded airlaid fabric ("TBAL"). Another popular stain catcher consists of a polymeric foam containing a polymerized water-in-oil emulsion, sometimes referred to as "poly-HIPE". The preparation of polymeric foams is widely reported in the literature. See U.S. Patent No. 5,260,345 of DesMarais, Stone, Thompson, Young, LaVon and Dyer published on November 9, 1993; U.S. Patent No. 5,550,167 of DesMarais published on August 27, 1996; U.S. Patent No. 5,650,222 to DesMarais et al., published July 22. All of these are incorporated herein by reference. Typical preparation conditions for the polymeric foams of the present invention are described in co-applied U.S. Patent Application Serial No. 09/042,418, filed March 13, 1998 by T.A. DesMarais et al. Its title is "Absorbent material for distributing aqueous solutions". Its disclosure is incorporated herein by reference. Additional disclosures of conditions for the preparation of polymeric foams useful in the present invention are described in co-applied U.S. Provisional Patent Application Serial No. 60/077,955, filed March 13, 1998 by T.A. DesMarais et al. It's titled "Abrasion-resistant polymer foams and stain receivers made from them." Its disclosure is incorporated herein by reference.

无论这里所述污渍接受器或这里所附文献中所述的污渍接受器都优选含有一个不透液体的背片或基片(backsheet)。这个基片可以是薄层的聚丙烯,聚乙烯和其他相似物。这个基片对污渍接受器所放置的表面提供对局部清洗剂的保护。例如局部清洗操作一般都在一个坚硬的表面,如一个桌面上进行的,污渍接受器是放在桌上的,而被清洗的织物是放在污渍接受器上面的。在织物的玷污面积上放入局部清洗剂以后,它被引入污渍接受器。如果没有基片,局部清洗剂会漏入桌面而可能引起损坏。Either the stain receivers described herein or the stain receivers described in the documents attached hereto preferably comprise a liquid impermeable backsheet or backsheet. This substrate can be a thin layer of polypropylene, polyethylene and the like. This substrate provides protection from spot cleaning agents to the surface on which the stain receiver is placed. For example, spot cleaning operations are generally performed on a hard surface, such as a table top, with the stain catcher placed on the table and the fabric being cleaned placed on the stain catcher. After the spot cleaner is placed on the stained area of the fabric, it is introduced into the stain receiver. Without a substrate, spot cleaners can leak onto the tabletop and possibly cause damage.

基片只是覆盖了吸收剂污渍接受器的一个面,而使另一面暴露给局部清洗剂并接受它,基片可以延伸过接受器的各个边,以便避免局部清洗剂从污渍接受器的边上泄漏出去。然而,如果将基片延伸出污渍接受器的边而到达它的另一面将可减少能接触局部清洗剂的面积。根据这个道理要解决上述问题可以使基片的一部份似翼那样延伸出污渍接受器一个角或多个角。这些翼可以提供进一步的保护来确保局部清洗剂被保留在污渍接受器中,而不至从它的边上泄漏。这样也可以同时使污渍接受器能有最大的吸收剂表面积。The substrate covers only one side of the absorbent stain receiver leaving the other side exposed to and accepting the spot cleaner, the substrate may extend across all sides of the receiver in order to avoid spot cleaner from the sides of the stain receiver leak out. However, if the substrate is extended beyond the edge of the stain receiver to its other side, the area available for contact with the topical cleaner is reduced. According to this principle, the above-mentioned problem can be solved by making a part of the substrate extend like a wing out of one or more corners of the stain receiver. These wings can provide further protection to ensure that the spot cleaner is retained in the stain receiver and does not leak from its sides. This also simultaneously maximizes the absorbent surface area of the stain receiver.

清洗更新的操作方法How to clean and update

清洗更新药剂必须能以蒸气或液体形式进入处理袋,也就是说,只要蒸气可以自由进入处理袋,液态药剂总是处在处理袋外部附近。因此,清洗更新药剂即可直接加入处理袋,例如,直接倒入,喷入,或放入一个能释出的含清洗清新药剂的基片;或放入一个含药剂的透气加料装置。也可以通过上述任何一个方法将清洗更新药剂放到处理袋外部附近,这样,药剂的蒸气可以进入处理袋的内室。要清洗更新的织物可以在任何方便的时候放入处理袋,也即在加入清洗更新药剂以前,中间或之后的时间内。Cleaning and renewing agents must be able to enter the disposal bag in vapor or liquid form, that is, liquid agents are always near the outside of the disposal bag as long as vapor can freely enter the disposal bag. Therefore, the cleaning and refreshing agent can be directly added to the treatment bag, for example, directly poured, sprayed, or put into a base sheet containing the cleaning and refreshing agent that can be released; or put into a breathable feeding device containing the agent. It is also possible to place the cleaning and renewing agent near the outside of the processing bag by any of the above methods, so that the vapor of the agent can enter the inner chamber of the processing bag. The fabric to be cleaned and renewed can be placed in the disposal bag at any convenient time, that is, before, during or after adding the cleaning and refreshing agent.

处理袋中的清洗更新药剂至少是部分气化的,为了提高这个处理袋的温度,可以将处理袋与一个辅助热源接触。可以通过下属方法来完成,例如可以将处理袋放到日光可以照到的地方,也可以将一个或多个热池放入袋内或放在处理袋外部的附近,这样,热池就能加热清洗更新药剂;也可以部份地将一个普通的头发吹风筒放入处理袋内去对袋吹热风;也可以用其他使袋内生温的方法。In order to increase the temperature of the treatment bag in which the cleaning and refreshing agent is at least partially vaporized, the treatment bag can be brought into contact with an auxiliary heat source. This can be accomplished by sub-methods such as placing the bag in a location where it will be exposed to sunlight, or by placing one or more thermal baths inside the bag or near the outside of the bag so that the pools can heat Cleaning and updating agent; also can partly put an ordinary hair dryer into the treatment bag to blow hot air to the bag; also can use other methods to make the inside of the bag warm.

处理袋可以是被悬吊在一个支撑架上,或者它也可以自由立式放置。当采用自由立式放置时,最好不要把它直接放置于地面或者其它可用作为受热器的表面上。例如,使用一个简单的由支架和基底构成的架子来支撑处理袋,使它可以从一些有可能从处理袋下部份吸收热量的表面被架起。The disposal bag can be suspended from a support frame, or it can stand free standing. When using free standing, it is best not to place it directly on the ground or other surface that can be used as a heat sink. For example, using a simple shelf and base to support the bag allows it to be raised from surfaces that would absorb heat from the lower portion of the bag.

辅助热源使处理袋内形成了一个温暖湿润的环境,在这种环境里有异味的化合物以‘蒸汽蒸馏’的方式蒸发,同时使纺织物和污渍润湿。这种润湿的织物可以使以前的褶皱消失,并且不会在之后的干燥步骤至最后的干燥循环过程中产生新的褶皱。在操作过程中,适当选择清洗清新剂的剂量,明确水的用量,更为重要的是适当的袋中排气都会减少织物的褶皱。此外,如果处理袋没有被排气,那么从织物上被蒸发移出的异味物质就可能被再次被存放到织物上。The auxiliary heat source creates a warm, moist environment inside the treatment bag where odorous compounds are 'steam distilled' to evaporate while wetting the fabric and stain. This wetted fabric allows previous wrinkles to disappear and does not create new wrinkles during subsequent drying steps to the final drying cycle. In the process of operation, proper selection of the dosage of cleaning freshener, clear water consumption, and more importantly, proper ventilation in the bag will reduce the wrinkles of the fabric. Furthermore, if the disposal bag is not vented, odorous substances removed by evaporation from the fabric may be re-deposited on the fabric.

更具体地说,这里清洗更新的方法可以以下列方式施行。在不违背本发明的精神和范围的前提下,可以对本方法步骤施行改良。More specifically, the cleaning and updating method here can be implemented in the following manner. Modifications may be made to the method steps without departing from the spirit and scope of the invention.

(ⅰ)如下所述,在织物的局部污渍区域可任选地施行一个预定点方法;(i) a pre-spot method may optionally be applied to the localized stained area of the fabric as described below;

(ⅱ)把全部织物连同清洗更新剂一起放置于织物处理袋中,优选使用一个以能释出的方式含有清洗更新剂的基片。(ii) Place the entire fabric together with the cleaning refresher in a fabric disposal bag, preferably using a substrate containing the cleaning refresher in a releasable manner.

(ⅲ)使处理袋受制于一个辅助热源,以被动式热源较为适宜,而选自下组中的热源更为适宜,它包括:阳光辐射,一种颗粒发热剂,和二者的混合物。(iii) subjecting the bag to an auxiliary heat source, preferably a passive heat source, more suitably a heat source selected from the group consisting of: solar radiation, a particulate exothermic agent, and mixtures of both.

(ⅳ)取出处理袋中的织物。(iv) Take out the fabric in the disposal bag.

处理袋可以在任何适当的时间范围里受制于辅助热源。时间可以是短至10分钟长至全天。例如,当阳光辐射被用作于热源时,只要阳光还在,这个过程就可以被持续地进行。如果使用一个其它的热源时,短一些的时段可能更为适合些。根据使用者的需要,操作这一步骤的时间周期可以长些或短些,取决于像织物的污染程度和类型,污渍的种类,织物的种类,织物的数量,供热量,和一些类似的因素。The treatment bag may be subjected to the auxiliary heat source for any suitable time frame. The time can be as short as 10 minutes or as long as the whole day. For example, when solar radiation is used as a heat source, the process can continue as long as sunlight is present. A shorter period of time may be more suitable if an other heat source is used. The time period for operating this step can be longer or shorter according to the user's needs, depending on things like the degree and type of soiling of the fabric, the type of stain, the type of fabric, the amount of fabric, the heat supply, and some similar factor.

更详细地说,一个预洗步骤可以以下面的方式进行。可以对本方法步骤施行改进,但不脱离本发明的精神和范围。In more detail, a prewash step can be performed in the following manner. Modifications may be made to the method steps without departing from the spirit and scope of the invention.

1.把织物受污染的区域反向放置,并使用这里描述过poly-HIPE或者TBAL污渍接收器与其接触,或者也可以对适当的表面像桌面等使用普通的折叠好的纸巾(例如,白色或者没有印染的为更适合,这样可以避免从纸巾上转移染料。例如BOUNTY_品牌)。整个过程可以在一个盘子中或其他类似物中进行。1. Turn the stained area of the fabric upside down and contact it with a poly-HIPE or TBAL stain catcher as described here, or you can use plain folded paper towels (e.g., white or non-printed for a better fit, this avoids transferring the dye from the paper towel. eg BOUNTY_ brand). The whole thing can be done in a dish or something like that.

2.从一个带有导引药剂的尖嘴的局部清洗剂给药瓶中,把足够的局部清洗剂直接置于污渍上(不需要在织物的污染区域周围形成不必要的饱和),使局部清洗剂在被污染的区域里饱和,大约需要10滴左右,对于较大的污渍可能需要使用更多滴。2. From a spot cleanser dispensing bottle with a pointed tip that guides the dose, place enough spot cleanser directly on the stain (without creating unnecessary saturation around the stained area of the fabric) to make the spot cleanser About 10 drops are needed to saturate the stained area, more may be needed for larger stains.

3.任选的让药剂渗入污渍3至5分钟。3. Optionally allow the agent to soak into the stain for 3 to 5 minutes.

4.任选的加入额外的药剂-大约10滴;对于较大的污渍可能需要使用更多滴。4. Optionally add additional agent - about 10 drops; more drops may be required for larger stains.

5.使用助处理器,像给药瓶瓶尖,把污渍完全洗掉。对于较轻微的污渍,此操作可以持续1至60秒的范围;对于较严重的和顽固的污渍,将需要1至5分钟。5. Use a co-processor, like a medicine bottle tip, to get the stain out completely. For lighter stains, this can range from 1 to 60 seconds; for heavier and stubborn stains, it will take 1 to 5 minutes.

6.任选地,吸去织物上多余的药剂,例如,把织物置于纸巾之间。或者在处理区域里使用一块潮湿的海绵或者其它吸收剂介质洗刷织物来除去多余的药剂。6. Optionally, excess agent is blotted from the fabric, for example, by placing the fabric between paper towels. Alternatively, use a damp sponge or other absorbent medium to scrub the fabric of the treated area to remove excess agent.

下面的例子进一步对本发明加以说明,但不意味对其加以限制。The following examples further illustrate the invention, but are not meant to limit it.

                    实施例1清洗更新药剂Example 1 Cleaning and updating agent

本发明织物处理袋所用的清洗更新剂组成如下:The used cleaning and updating agent of the fabric treatment bag of the present invention is composed as follows:

成份                 重量比(%)Composition Weight Ratio (%)

乳化剂(TWEEN 20)*     0.5Emulsifier (TWEEN 20) * 0.5

芳香剂                 0.5Fragrance 0.5

KATHON_              0.0003 KATHON_0.0003

苯甲酸钠               0.1Sodium Benzoate 0.1

水                     余量*聚氧化乙烯(20)山梨糖醇酐单月桂酸酯可以从ICI Surfactants得到。Water Balance * Polyoxyethylene (20) sorbitan monolaurate is available from ICI Surfactants.

另外,本操作中织物处理袋中较好药剂成份如下:In addition, the preferred ingredients in the fabric treatment bag in this operation are as follows:

成份       重量(%)    范围(重量%)Composition Weight (%) Range (weight %)

水           99.0       95.1-99.9Water 99.0 95.1-99.9

芳香剂       0.5        0.05-1.5Fragrance 0.5 0.05-1.5

表面活性剂*  0.5        0.05-2.0Surfactant* 0.5 0.05-2.0

乙醇或异丙醇 0          任选至4%Ethanol or isopropanol 0 Optional to 4%

溶剂(如BPP)  0          任选至4%Solvent (such as BPP) 0 Optional up to 4%

过氧化氢     0          任选至4%Hydrogen peroxide 0 optional up to 4%

pH范围大约6到大约8pH range from about 6 to about 8

                    实施例2Example 2

含有一种清洗/更新药剂的基片的制备方法Process for the preparation of substrates containing a cleaning/refreshing agent

一个用Dexter Corp生产的HYDRASPUN_材料制成的片状基片,其尺寸为10 1/4英时×14 1/4英时(26厘米×36厘米)。基片的两个面用Reemay厚度为8密尔(0.2毫米)纤维罩单材料的顶层罩和底层罩罩住。罩单(不论顶层罩和底层罩)均用Vertrod_或其他标准热密封设备例如常规的超声密封装置使它与基片粘合,这样使基片的周边的多层结构均粘合在一起。基片周边各边缘的顶层罩和底层罩中间均被胶插入。如上所述,粘合处宽度尽可能小,大约0.25英时(6.4毫米)。A sheet-like substrate made of HYDRASPUN® material from Dexter Corp. has dimensions of 10 1/4 inches by 14 1/4 inches (26 cm by 36 cm). Both sides of the substrate were masked with top and bottom masks of Reemay's 8 mil (0.2 mm) thick fiber mask single material. The cover sheet (whether the top cover or the bottom cover) is bonded to the substrate using a Vertrod® or other standard heat sealing equipment such as a conventional ultrasonic sealer such that the multilayer structure around the perimeter of the substrate is bonded together. Glue is inserted between the top cover and the bottom cover at each edge of the substrate periphery. As mentioned above, the bond width should be as small as possible, about 0.25 inches (6.4 mm).

这样制备的粘合后的复合基片褶叠后放入一个小袋。任何塑料小袋只要不泄漏都合适。例如,可以使用一个食品服务工业常用的那种多层箔的胶合小袋。这样的小袋在工业上是众所周知的,它们用不吸收食物香味的材料制成。这里的配方设计人同样希望所用的小袋不会吸收清洗/更新药剂中的香味。市场上能够买到的多种小袋通常都是可以用的。The bonded composite substrate thus prepared was folded and placed in a pouch. Any plastic sachet will work as long as it doesn't leak. For example, a laminated foil pouch of the type commonly used in the food service industry can be used. Such pouches are well known in the industry and are made of materials that do not absorb food aromas. Here again the formulator wanted to use a sachet that would not absorb the scent of the cleansing/renewing agent. A variety of commercially available sachets are usually available.

将褶叠好的基片/罩单组放入小袋,褶叠方式可以有多种,例如手风琴式褶叠或卷成卷后对褶。褶叠后的尺寸并不重要,只要能很方便放入小袋。Put the folded base sheet/cover sheet into a pouch. There are many ways to fold, such as accordion folds or double folds after being rolled. The folded size doesn't matter as long as it fits easily in the pouch.

将23克清洗/更新药剂倒在基片/罩单上,允许基片吸入这些药剂。在液态药剂放入小袋后,立即封住小袋。贮存备用。Pour 23 grams of cleaning/refreshing agent onto the substrate/mask and allow the substrate to absorb the agent. Seal the sachet immediately after the liquid medicine is placed in the sachet. Store for later use.

                      实施例3Example 3

局部清洗药剂spot cleaner

本发明所用的一个局部清洗药剂,如上所述最好配有一个给药装置和一个TBAL或高冲击聚乙烯(poly-HIPE)泡沫的污迹接收器,可以如下制备:A topical cleansing agent for use in the present invention, preferably equipped with a delivery device as described above and a stain receiver of TBAL or high impact polyethylene (poly-HIPE) foam, can be prepared as follows:

成份             重量%(非离子型)    范围(重量%)Composition Weight % (Non-ionic) Range (Wt%)

过氧化氢              1.000             0-2Hydrogen peroxide 1.000 0-2

氨基三亚甲基膦酸*    0.040             0-0.06Aminotrimethylenephosphonic acid * 0.040 0-0.06

丁氧基丙氧基丙醇(BPP) 2.000             1-6Butoxypropoxypropanol (BPP) 2.000 1-6

Neodol23 6.5          0.250             0-1Neodol23 6.5 0.250 0-1

Kathon防腐剂          0.0003            任选**Kathon Preservative 0.0003 Optional**

水                    96.710            余量Water 96.710 balance

pH目标为7;范围6-8pH target is 7; range 6-8

*过氧化氢的稳定剂 * Stabilizer for hydrogen peroxide

**足够量提供防腐功能。 ** Sufficient amount to provide anti-corrosion function.

在这里作局部清洗步骤中使用的另一个较好的高含水量,低局部清洗药剂残留的局部清洗药剂的配方如下:Another preferred high water content, low spot cleanser residue spot cleanser formulation for use in the spot cleansing step herein is as follows:

成份                    阴离子型药剂%Ingredient Anionic agent%

过氧化氢                    1.000Hydrogen peroxide 1.000

氨基三(亚甲基膦酸)*        0.0400Amino tri(methylene phosphonic acid) * 0.0400

丁氧基丙氧基丙醇(BPP)       2.000Butoxypropoxypropanol (BPP) 2.000

NH4椰子E1S                  0.285NH4 coconut E1S 0.285

十二烷基二甲基胺氧化物      0.031Dodecyldimethylamine oxide 0.031

氯化镁                      0.018Magnesium chloride 0.018

硫酸镁                      0.019Magnesium Sulfate 0.019

助溶剂,香料和其他辅料      0.101Co-solvents, fragrances and other excipients 0.101

Kathon防腐剂                0.0003Kathon preservative 0.0003

水(去离子或蒸馏水)          96.5Water (deionized or distilled water) 96.5

pH目标值                    6.0pH target value 6.0

*过氧化氢的稳定剂 * Stabilizer for hydrogen peroxide

如上所述为了减少破坏染料,含有H2O2的予局部清洗药剂所含的阴离子型或非离子型表面活性剂的重量百分数应比H2O2的量少。较好的是表面活性剂与H2O2的重量比在大约1∶10到大约1∶15,最好为大约1∶4到大约1∶3。To reduce dye damage as stated above, pre-spot cleansers containing H2O2 should contain less anionic or nonionic surfactant by weight percent than the amount of H2O2 . Preferably the weight ratio of surfactant to H2O2 is from about 1:10 to about 1:15, most preferably from about 1:4 to about 1:3 .

另一个在这里予局部清洗步骤中所用高含水量,低残留量的局部清洗药剂的配方如下:Another formulation of the high water content, low residue spot cleanser used in the pre-spot cleansing step here is as follows:

成份                      阴离子型药剂%Ingredient Anionic agent %

丁氧基丙氧基丙醇(BPP)        2.000Butoxypropoxypropanol (BPP) 2.000

NH4椰子E1S                   0.285NH4 coconut E1S 0.285

十二烷基二甲基胺氧化物       0.031Dodecyldimethylamine oxide 0.031

氯化镁                       0.018Magnesium chloride 0.018

硫酸镁                       0.019Magnesium Sulfate 0.019

助溶剂,香料和其他辅料       0.101Co-solvents, fragrances and other excipients 0.101

Kathon防腐剂                 0.0003Kathon preservative 0.0003

水(去离子或蒸馏水)           97.5Water (deionized or distilled water) 97.5

pH目标值                     6.0pH target value 6.0

Claims (14)

1. equipment of handling textiles comprises:
A) fabric treating bag that disposes the limit panel defines the scope of handling the bag inner room by the limit panel, has at least a fabric can be suspended in the inner room;
B) new medicament of a kind of cleaning of liquid state/more; And
C) passive thermal source.
2. equipment as claimed in claim 1, passive thermal source wherein is selected from as next group: solar irradiation, a kind of particle exothermic mixture and the mixture of the two.
3. equipment as claimed in claim 1, cleaning wherein/renewal agent includes water and is selected from down the another kind of material composition of group: surfactant, spices, preservative agent, bleaching agent, auxiliary cleaning agent, anti-piping compound, organic solvent, and their mixture, preferred organic is a glycol ether, and preferred organic solvent is to be selected from down the group material: methoxy propoxy propanol, ethyoxyl propoxyl group propyl alcohol, propoxyl group propoxyl group propyl alcohol, butoxy propoxyl group propyl alcohol, butoxy propyl alcohol, ethanol, isopropyl alcohol and their mixture.
4. equipment as claimed in claim 1, cleaning wherein/renewal agent is to be inhaled in the substrate in the mode that can disengage.
5. equipment as claimed in claim 1 further also comprises a dosing metering device that contains cleaning/renewal agent.
6. equipment as claimed in claim 2, particle exothermic mixture wherein contain iron powder, carbon, at least a slaine and water.
7. equipment as claimed in claim 1, the part of limit panel wherein are to be selected from down the group material: opaque material, can shielding of ultraviolet radiation material and their mixture.
8. equipment as claimed in claim 1, fabric treating bag has wherein further also comprised one the flexible skeleton frame that can fold, when launching, the skeleton frame forms a semirigid three-dimensional structure, the preferred process bag has also further comprised a pocket that is used for receiving cleaning/renewal agent, this pocket will and fabric treating bag inner room between keep fluid communication, more preferably the fabric treating bag further comprises at least one exhaust outlet.
9. cleaning/method for updating of handling the non-steeped formula of textile fabric comprises following each step:
(a) textile fabric is upgraded the inner room that a fabric treating bag is put in agent together with cleaning;
(b) make the fabric treating bag be limited by a passive thermal source;
(c) textiles is taken out from the fabric treating bag.
10. non-steeped formula as claimed in claim 9 is cleaned update method, wherein cleaning/renewal agent is to be inhaled in the substrate in the mode that can disengage, cleaning/renewal agent includes water and another kind of composition, this composition is to be selected from down the group material: surfactant, spices, preservative agent, bleaching agent, auxiliary cleaning agent, anti-piping compound, organic solvent, and their mixture, preferred organic is a glycol ether, and preferred organic solvent is to be selected from down the group material: methoxy propoxy propanol, ethyoxyl propoxyl group propyl alcohol, propoxyl group propoxyl group propyl alcohol, butoxy propoxyl group propyl alcohol, the butoxy propyl alcohol, ethanol, isopropyl alcohol, and their mixture.
11. method as claimed in claim 9, steam wherein are to be discharged out the processing bag in the process that (b) step is carried out.
12. method as claimed in claim 10, wherein textile fabric and substrate are to be suspended in the fabric treating bag.
13. method as claimed in claim 9, wherein the fabric treating bag has further also contained a pocket that is used for receiving cleaning/renewal agent, is keeping fluid communication between it and the fabric treating bag inner room.
14. method as claimed in claim 9, wherein textile fabric has obverse and reverse, and further comprises following each step:
(a) give the poluted region that the medicine bottle local cleaning agent is put on the front of textiles from one;
(b) when step (a) is carried out or and then it, use one to help near the positive contaminated zone of processor contact fabric; And
(c) use one to absorb near the spot recipient contact fabric reverse side poluted region.
CN99810880A 1998-09-28 1999-09-28 Apparatus and method for cleaning and refreshing fabrics with supplemental heat source Pending CN1318118A (en)

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CN101842529B (en) * 2007-10-31 2012-03-28 塞尔焦·扎利奥 Machines for cleaning, washing, drying and ironing clothes and garments
CN110998015A (en) * 2017-08-07 2020-04-10 皇家飞利浦有限公司 Stain removal apparatus using bleaching chemistry and heat generation
CN110998015B (en) * 2017-08-07 2022-10-21 皇家飞利浦有限公司 Equipment for stain removal using bleaching chemical solutions and heat
US12104311B2 (en) 2017-08-07 2024-10-01 Koninklijke Philips N.V. Stain removal device using bleach chemical solution and heat generation

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