CN1311036C - Artistic powder paint of mottle effect - Google Patents
Artistic powder paint of mottle effect Download PDFInfo
- Publication number
- CN1311036C CN1311036C CNB2004100411645A CN200410041164A CN1311036C CN 1311036 C CN1311036 C CN 1311036C CN B2004100411645 A CNB2004100411645 A CN B2004100411645A CN 200410041164 A CN200410041164 A CN 200410041164A CN 1311036 C CN1311036 C CN 1311036C
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- CN
- China
- Prior art keywords
- pigment
- effect
- agent
- speckle
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000000694 effects Effects 0.000 title claims abstract description 27
- 239000000843 powder Substances 0.000 title claims abstract description 19
- 239000003973 paint Substances 0.000 title abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000000945 filler Substances 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims description 27
- 238000000576 coating method Methods 0.000 claims description 27
- 239000000049 pigment Substances 0.000 claims description 23
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 5
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 4
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 3
- 239000003822 epoxy resin Substances 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 2
- 239000001023 inorganic pigment Substances 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims description 2
- 239000012860 organic pigment Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 229910002012 Aerosil® Inorganic materials 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 5
- 238000007580 dry-mixing Methods 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000002574 poison Substances 0.000 abstract 1
- 231100000614 poison Toxicity 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 230000004075 alteration Effects 0.000 description 5
- 230000035939 shock Effects 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 238000005187 foaming Methods 0.000 description 3
- 230000009972 noncorrosive effect Effects 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 241000909859 Attacus atlas Species 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009503 electrostatic coating Methods 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- -1 flow promotor Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention discloses artistic powder paint with mottle effects. The present invention uses resin, a solidifying system, a degasser, a flow auxiliary agent, paint, a filler, a mottle agent, effect paint, a powdery flow accelerating agent and an effect paint orientation auxiliary agent as raw materials. Firstly, the first five raw materials are made into base materials. Then, other materials are added in the base materials, and finished paint is made by dry mixing and sieving. The present invention has the advantages of no poison, no pollution, favorable effect and reasonable price.
Description
Technical field
The present invention relates to a kind of fine arts type powder coating of speckle effect, belong to the powder coating technical field of electrostatic coating.
Background technology
Fine arts type coating is one of coating R﹠D direction, and fine arts type coating mainly contains kinds such as sand wrinkle, tangerine line, mallear stria, sludge ice, flash of light at present.The coating that uses pearly-lustre, metallic equivalent to answer pigment to make is subjected to liking of people day by day with the good surface appearance decorative effect, therefore paint class fine arts type coating obtained development rapidly, but the environmental pollution, the coating machine performance that constantly exist are low and problem such as integrated construction cost height, accelerated the paces that the technician develops relevant powder coating, fine arts type powder coating more obtained people's favor with outstanding outward appearance visual sense, outstanding concavo-convex sense of touch, excellent physical and mechanical performance.
Summary of the invention
The purpose of this invention is to provide that a kind of coating physical and mechanical properties excellence, speckle concave-convex effect are outstanding, constant product quality, the good fine arts type powder coating of workability.
The present invention realizes with following technical scheme: it is made by following weight percentages: resin and cure system 60-90% thereof, air release agent 0.1-0.5%, flow promotor 2-3%, pigment 2.5-9%, filler 0-25%, speckle agent 0.3-2%, effect pigment 0.2-5%, powder flow improver additive 0.1-0.2%, the directed auxiliary agent 0.01-0.2% of effect pigment.
The usage percentage of each raw material is that the contriver draws on a large amount of experimental basis, all has good effect in above-mentioned amount ranges.
Resin among the present invention and cure system are pure epoxy resin and curative system thereof, also can be epoxy/polyester mixing system, pure polyester/TGIC system, urethane and cure system thereof, acrylic resin and cure system thereof.
Air release agent among the present invention is a micro mist wax.
Flow promotor among the present invention is W-1.
Pigment among the present invention is for being all kinds of organic or inorganic pigment.
Filler among the present invention is a ultra-fine barium sulfate.
Speckle agent among the present invention is the acrylic resin polymkeric substance, particle diameter 10-100 μ m.
Effect pigment among the present invention is that pearly-lustre, metallic equivalent are answered pigment, particle diameter 1-60 μ m.
Flow improver additive among the present invention is gas phase SiO
2Or aluminum oxide C.
The directed auxiliary agent of effect pigment among the present invention is a cellulose acetate-butyrate.
The preparation method of coating of the present invention is: with resin and cure system thereof, air release agent, flow promotor, pigment, filler is that raw material is made base-material, then speckle agent, effect pigment, powder flow promotor, the directed auxiliary agent of effect pigment are joined in the base-material, mix by doing again, sieve and make finished product coating.
The invention has the beneficial effects as follows:
Powder coating of the present invention adopts the electrostatic spraying constructional method to act on all kinds of metal bases after the surperficial pre-treatment, fully solidifies through 200 ℃, naturally cools to room temperature, behind the placement 24h, measures coating performance, its coat-thickness 80-100 μ m.Its salient features characterizes as follows:
Coat-thickness is measured with the two probe thickness testers of 600B type that German BYK company produces, artificial accelerated aging test is measured by the Q-UV artificial accelerated aging test instrument that U.S. ATLAS company produces, aberration is surveyed tinting system with the ALTAIR company computer and is measured, sticking power is measured by GB/T 9286-1998 regulation, and shock strength is measured by GB/T 1732-1993 regulation.Its test result is: every index all reaches or is better than existing national standard or industry standard.Practical application shows, constant product quality between the fine arts type powder coating of this speckle effect batch, and the appearance of coat decorative effect is good, concave-convex sense outstanding, powder construction quality excellence, weathering resistance are good.
Production of the present invention and using method are simple, and be nontoxic, pollution-free, the abundant and low price in starting material source.
Embodiment
Further illustrate the solution of the present invention and effect below in conjunction with embodiment.
Embodiment 1
Raw material consumption (wt%)
Epoxy/polyester resin system 60
Air release agent 0.24
W-1 2
Carbon black 2.5
Ultra-fine barium sulfate 18.4
Speckle agent 0.7
Pearly pigment 4
Gas phase SiO
20.1
Directed auxiliary agent 0.06
The fine arts type powder coating of the speckle effect of making by above-mentioned prescription.0 grade of its coating adhesion, shock strength 50cm, aberration Δ E≤1 between batch.
Embodiment 2
Raw material consumption (wt%)
Polyester/TGIC system 90
Air release agent 0.4
W-1 2.8
Carbon black 2.8
Speckle agent 0.5
Pearly pigment 3.3
Gas phase SiO
20.1
Directed auxiliary agent 0.1
The fine arts type powder coating of the speckle effect of making by above-mentioned prescription.0 grade of its coating adhesion, shock strength 50cm, aberration Δ E≤1 between batch, artificial accelerated aging time 〉=500h, exposure to weather(ing) 12 months is non-foaming, non-corrosive, do not ftracture, do not peel off.
Embodiment 3
Raw material consumption (wt%)
Urethane resin system 72
Air release agent 0.2
W-1 2
Phthalein viridescent 6.7
Ultra-fine barium sulfate 17
Speckle agent 1.5
Metallic pigment 0.45
Al
2O
3C 0.1
Directed auxiliary agent 0.05
The fine arts type powder coating of the speckle effect of making by above-mentioned prescription.0 grade of its coating adhesion, shock strength 50cm, aberration Δ E≤1 between batch, artificial accelerated aging time 〉=500h, exposure to weather(ing) 12 months is non-foaming, non-corrosive, do not ftracture, do not peel off.
Embodiment 4
Raw material consumption (wt%)
Pure epoxy system 76
Air release agent 0.4
W-1 2
Goth black 6# 2.2
Ultra-fine barium sulfate 12
Speckle agent 2
Metallic pigment 5
Gas phase SiO
20.2
Directed auxiliary agent 0.2
The fine arts type powder coating of the speckle effect of making by above-mentioned prescription.0 grade of its coating adhesion, shock strength 80cm, aberration Δ E≤1 between batch, exposure to weather(ing) 12 months is non-foaming, non-corrosive, do not ftracture, do not peel off.
Claims (1)
1. the fine arts type powder coating of a speckle effect is characterized in that it is made by following raw materials by weight percent:
Resin and cure system 60-90%, air release agent 0.1-0.5%, flow promotor 2-3%, pigment 2.5-9%, filler 0-25%, speckle agent 0.3-2%, effect pigment 0.2-5%, powder flow improver additive 0.1-0.2%, the directed auxiliary agent 0.01-0.2% of effect pigment;
Described resin and cure system are pure epoxy resin and curative system or epoxy/polyester mixing system or pure polyester/TGIC system or urethane and cure system or acrylic resin and cure system thereof;
Described air release agent is a micro mist wax;
Described flow promotor is W-1;
Described pigment is all kinds of conventional organic or inorganic pigment;
Described filler is a ultra-fine barium sulfate;
Described speckle agent is the acrylic resin polymkeric substance, particle diameter 10-100 μ m;
Described effect pigment is pearly pigment, metallic pigment, particle diameter 1-60 μ m;
The flow improver additive that is set forth in is aerosil or aluminum oxide C;
The directed auxiliary agent of described effect pigment is a cellulose acetate-butyrate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100411645A CN1311036C (en) | 2004-07-02 | 2004-07-02 | Artistic powder paint of mottle effect |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100411645A CN1311036C (en) | 2004-07-02 | 2004-07-02 | Artistic powder paint of mottle effect |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1715348A CN1715348A (en) | 2006-01-04 |
| CN1311036C true CN1311036C (en) | 2007-04-18 |
Family
ID=35821521
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100411645A Expired - Fee Related CN1311036C (en) | 2004-07-02 | 2004-07-02 | Artistic powder paint of mottle effect |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1311036C (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101157816B (en) * | 2007-11-12 | 2012-04-25 | 徐州正菱涂装有限公司 | Indoor decorative metal powder coating |
| CN102206460B (en) * | 2011-02-28 | 2012-09-26 | 浙江吉利汽车研究院有限公司 | Flower and bird grain powder paint for automobile body finish and preparation method thereof |
| CN102153900A (en) * | 2011-05-27 | 2011-08-17 | 常州市飞扬粉末涂料有限公司 | Moire effect metal art powder coating and preparation method thereof |
| CN102408812B (en) * | 2011-10-08 | 2016-02-10 | 天津翔盛粉末涂料有限公司 | A kind of artistic-type crack powder paint and preparation method thereof |
| JP6092267B2 (en) * | 2012-03-14 | 2017-03-08 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ | Use of the solvent-type pigment paste for producing a solvent-type pigment paste containing a metal pigment and a solvent-type coating agent that imparts an effect |
| CN104194577A (en) * | 2014-09-05 | 2014-12-10 | 晁兵 | Speckle powder coating and preparation method thereof |
| CN105111899B (en) * | 2015-09-28 | 2017-07-28 | 湖南湘江涂料集团有限公司 | A kind of outdoor TEXTURE POWDER COATING and its production method with metal-like |
| CN105602419B (en) * | 2016-02-22 | 2017-11-17 | 福建万安实业有限公司 | A kind of art-type powder coatings of marbled effect and preparation method thereof |
| CN105936790A (en) * | 2016-05-26 | 2016-09-14 | 广西梧州龙鱼漆业有限公司 | Hammer paint |
| CN106590338A (en) * | 2016-12-12 | 2017-04-26 | 墨宝股份有限公司 | Art-type powder coating with stripe effect and preparing method of art-type powder coating |
| CN107057539A (en) * | 2017-04-26 | 2017-08-18 | 安徽联硕实业有限公司 | Polyester powder coating for electromagnetic wire and preparation method thereof |
| CN106928814A (en) * | 2017-04-26 | 2017-07-07 | 安徽联硕实业有限公司 | A kind of powdery paints for electromagnetic wire and preparation method thereof |
| CN106905823A (en) * | 2017-04-26 | 2017-06-30 | 安徽联硕实业有限公司 | Insulation electrostatic powder coating for electromagnetic wire and preparation method thereof |
| CN111218191A (en) * | 2020-03-02 | 2020-06-02 | 佛山市顺德区千之彩实业有限公司 | Metal powder coating and preparation process thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5288770A (en) * | 1990-01-20 | 1994-02-22 | Kansai Paint Co., Ltd. | Resin composition for cationically electrodepositable paint comprising alicyclic epoxy resins and emulsion polymerized, finely divided gelled polymers |
| CN1144245A (en) * | 1995-04-17 | 1997-03-05 | 廖龙 | Acrylic hammer decorative paint |
| CN1144241A (en) * | 1995-04-17 | 1997-03-05 | 廖龙 | Special rust-proof aesthetical paint for rusted steel |
| US6491973B1 (en) * | 1997-09-30 | 2002-12-10 | Dupont Performance Coatings Gmbh & Co. Kg | Powder coating composition, process for the production and use thereof |
-
2004
- 2004-07-02 CN CNB2004100411645A patent/CN1311036C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5288770A (en) * | 1990-01-20 | 1994-02-22 | Kansai Paint Co., Ltd. | Resin composition for cationically electrodepositable paint comprising alicyclic epoxy resins and emulsion polymerized, finely divided gelled polymers |
| CN1144245A (en) * | 1995-04-17 | 1997-03-05 | 廖龙 | Acrylic hammer decorative paint |
| CN1144241A (en) * | 1995-04-17 | 1997-03-05 | 廖龙 | Special rust-proof aesthetical paint for rusted steel |
| US6491973B1 (en) * | 1997-09-30 | 2002-12-10 | Dupont Performance Coatings Gmbh & Co. Kg | Powder coating composition, process for the production and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1715348A (en) | 2006-01-04 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Granted publication date: 20070418 Termination date: 20130702 |