CN1308543C - Method for wet transfer printing digital color image onto fiber fabric of cellulose, and dedicated transfer paper - Google Patents
Method for wet transfer printing digital color image onto fiber fabric of cellulose, and dedicated transfer paper Download PDFInfo
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- CN1308543C CN1308543C CNB2005100412271A CN200510041227A CN1308543C CN 1308543 C CN1308543 C CN 1308543C CN B2005100412271 A CNB2005100412271 A CN B2005100412271A CN 200510041227 A CN200510041227 A CN 200510041227A CN 1308543 C CN1308543 C CN 1308543C
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- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
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- Decoration By Transfer Pictures (AREA)
Abstract
The present invention discloses a method for the wet transfer printing of a digital color image onto a fiber fabric of cellulose, and special transfer printing paper for the method. In the method, a dye is coated by an ink spraying printer in a spraying mode so that a pattern is printed on the transfer printing paper, the part on a fabric, which is to be in transfer printing with the pattern, is wetted by a sodium-bicarbonate water solution and is coated with transfer printing paste, one face on the transfer printing paper, which is printed with the pattern, is pasted on the surface of the fabric to be in transfer printing and is flattened, the transfer printing paste is scalded and dried by an iron or a flat plate type thermal transfer printer after the transfer printing paper is wetted, the fabric is then put in a pressure cooker to be steamed for 8 to 12 min, loose color and glue paste on the pattern of the obtained fabric are finally cleaned off, and then a fiber fabric of cellulose, which is printed with the pattern, is obtained after the fabric is dried. The method has the advantages of little equipment investment, simple technology, high pattern resolution, good hand feeling of dress, good ventilation and high making speed, and can make the pattern on a single fabric; the transfer printing paper realizing the method is composed of three layers, wherein the lower layer is base paper, the intermediate layer is a film-forming adhesive layer, and the upper layer is an aquasol layer.
Description
One, technical field
The present invention relates to a kind of fabrics printing and dyeing method, particularly a kind of on cellulose base fiber fabric the method for wet transfer printing digital color image, the invention still further relates to the dedicated transfer paper that this method adopts.
Two, background technology
At present, generally adopt following several method for printing or transfer printing multicolour pattern on cellulose fibre (cotton fiber) fabric in the dyeing:
1, silk screen print method:
Its print principle is the hole version method of biting, and two kinds of forms of cylinder forme peace wire mark version are arranged.At first pattern design is carved in the certain position of the space of a whole page, form mesh-like pattern, the interior mill base of half tone is extruded from figuratum mesh by bar magnet or doctor during printing, make the textiles under the half tone painted, every edition of the same colour, but chromatography plurality of color, and can use the printing of multiclass mill base, the printing coating of making as water-soluble dye mill base, solvent-borne type organic pigment printing ink, heat-set ink, inorganic pigment or metal mining powder, printing ink etc.Use serigraphy printed color pattern on cotton-spinning fabric, except the color separation Copy Preparation before printing, forme prepares to be needed outside fund and the time input, owing to reasons such as screen cloth self-characteristic and wire mark technology, seal slurries, make method for printing screen be difficult on cotton-spinning fabric, directly starching and print out high-resolution colour picture with the dyestuff seal.
2, thermal transfer printing method:
At present, thermal transfer has following dual mode: (1) gas phase transfer method: select for use the DISPERSE DYES with heat sublimation character to make varicolored water-based printing paste, solvent borne printing ink or ink for ink-jet printer.Method with serigraphy, offset printing or inkjet printing prints out image on transfer paper.During transfer printing, the transfer paper front that is printed on image is attached on the fabric of image to be printed, uses dull and stereotyped heat transfer machine heating and pressurizing on transfer paper then, make dyestuff form gas and transfer to the inner set of fibres for fabrics, form coloured image.But this dyestuff only suits to dye on the polyester fiber kind fabric, as painted on cellulose base fiber fabric, also need add on the cellulose base fiber fabric top layer and is coated with a resin bed or cotton fiber is done grafting, and is expanded, and modifications such as interfacial polymerization are handled.The dye image of transfer printing on cellulose base fiber fabric just has certain fastness; (2) hot melt transfer printing: the hot melt transfer printing has dual mode, first kind is the fusion transfer printing, this kind mode needs the ink dye self of printed images fusible or add hot melt adhesive in printing ink, scribbles on the release liners of silicone oil material printed image on the surface with this printing ink then and makes transfer paper.During transfer printing, the transfer paper that image is arranged is put on the fabric of image to be printed, printing ink faces fabric, uses heat transfer machine heating and pressurizing on transfer paper then, makes printing ink meet heat back fusion, forms the surface that image is bonded in fabric.Second kind is to peel off transfer printing, and peeling off transfer printing has dual mode again, and behind printed image on the release liners, printing one deck white adhesive layer is made the image background to one on image again, and prints additional one deck hot melt adhesive again on glue-line with four colour printing printing ink.During transfer printing, hot melt adhesive layer is placed on the textiles, with heat transfer machine from last to the release liners heating and pressurizing, make the hot melt adhesive fusion that adheres under the image glue-line and stick on the fabric.Treat to throw off release liners after the melten gel cooling.Another kind is peeled off transfer printing, on release liners, scribble the transparent heat cladding resin layer that one deck absorbs water-soluble dye ink (before not having heating transfer), available ink-jet printer is to this paper and coating print image, afterwards transfer paper is placed on the fabric, to the release liners heating and pressurizing, the coating that is printed on image is adhered on the fabric with flatiron or heat transfer machine.Throw off release liners after the glue-line cooling fusion.But when adopting the thermal transfer printing method on COTTON FABRIC, pattern is that seal is attached on the air-locked glue-line of one deck, thus the fabric breathability variation of pattern that made transfer printing.
3, wet quick transfer printing method:
According to " cloth print " (write in the gold and silver river, Beijing Chemical Industry Press in December, 2003 version) book introduction: the wet trans-printing characteristics of fabric are, and are not painted by the distillation of dyestuff, can use various dyestuffs, also are suitable for various fabrics.Its basic principle is that dyestuff, link stuff are made the seal slurry earlier, is printed to transfer printing paper.During trans-printing, earlier that fabric is wetting with suitable dyeing assistant, with promotion dyestuff color development, painted or fixation is under 120 ℃ of-150 ℃ of temperature and 120-150kg/cm
2Trans-printing under the pressure.This just requires used paper substrate heat-resisting, and is withstand voltage or enough wet strengths are arranged, and the finished product decorative pattern is easily imbibition also.It has also experienced its development as a kind of trans-printing means, and ripe evolution process was once prevalent at the time in Japan.Owing to need preliminary treatment before the trans-printing, need set after the printing again, washing, operations such as post processing such as drying, technical process are subjected at that time conditionalities such as scientific and technological level, and whole wet transfer process is complex process not only, and the printing and dyeing effect is also unsatisfactory.Therefore, wet transfer printing does not obtain promoting.
4, digital jet printing method:
This method adopts computer control, directly textiles is carried out digital ink-jet and prints, and finishes the printing of various patterns on fabric, is the scientific and technological focus that current fabric printing process is expanded.Owing to this technology is not have a version mode of printing, therefore shortened the delivery time greatly, saved the preceding spending of seal, and the color fidelity that flower case image presents has been brought up to unprecedented level.But current spray-jet printing machine of selling in the market and supporting with it facility price are high, cause the stamp cost high, promote, popularization and application is slower.In addition, also inconvenience is used for printed color pattern on the personalized ready-made clothes of single-piece.
Three, summary of the invention
1, goal of the invention: it is little to the purpose of this invention is to provide a kind of equipment investment, technology is simply carried out the method for wet transfer printing digital color image to cellulose base fiber fabric, adopt the pattern resolution height of these method printing and dyeing, the dress material gas permeability after dress ornament good hand touch and the printing and dyeing remains unchanged.Another object of the present invention provides a kind of dedicated transfer paper of realizing this method.
2, technical scheme: the method for fabric wet transfer printing digital color image of the present invention may further comprise the steps:
(1) with ink-jet printer spraying dyestuff needed multicolour pattern is printed on the transfer paper; Described transfer paper is formed by three layers, and lower floor is basic paper, but the middle level is the film forming glue adhesion coating, and the upper strata is a water-soluble adhesive layer;
(2), and be coated with last layer transfer printing slurry uniformly with the fractional wettability of sodium bicarbonate aqueous solution with pattern to be transferred on the cellulose base fiber fabric;
(3) one side that is printed on pattern on the described transfer paper of step (1) is attached to cellulose base fiber fabric surface to be transferred, and flattens;
(4) paper to be transferred moistening after, press with flatiron or plat type heat transfer machine and to scald dry transfer printing slurry;
(5) cellulose base fiber fabric with transfer paper was put into the pressure cooker decatize 8-12 minute;
(6) loose colour and the rubber cement on the eccysis gained textile design promptly obtains being printed on the cellulose base fiber fabric of pattern after the drying.
Dyestuff in the step (1) is salt-free REACTIVE DYES; The concentration of the sodium bicarbonate aqueous solution in the step (2) is 3% (weight), and the transfer printing slurry makes for add 4g sodium alginate, 3g sodium bicarbonate, 1g reservehao S and 2g urea in the water of every 100ml.
Realize the transfer paper of described method to wet transfer printing digital color image onto fiber fabric of cellulose, form by three layers that lower floor is basic paper, but the middle level is the film forming glue adhesion coating, the upper strata is a water-soluble adhesive layer.
The basic paper of transfer paper can be glue body paper or art paper; But the film forming glue adhesion coating is made by the insoluble macromolecule polyester thing of water, and the insoluble macromolecule polyester thing of described water is polyvinyl acetate, styrene maleic anhydride copolymer or polyvinyl butyral resin; Water-soluble adhesive layer is made by sodium alginate, and can add 0.3% calcium propionate as preservative agent.
3, beneficial effect: the present invention has the following advantages: (1) uses this method transfer printing digital multicolour pattern on cellulose base fiber fabric, and equipment investment is little, technology is simple, pattern resolution is high, dress ornament good hand touch, good permeability; (2) can be in ready-made clothes or cloth cut-parts direct pattern transferring, can save expense before the seals such as Copy Preparation and plate-making; Dye loss is less, is convenient to pattern-making on the single-piece fabric, thus satisfying personalized pursuit; (3) manufacturing speed is faster; (4) transfer paper of the present invention not only makes the pattern of printing painted, colour fixation is better, also because the hydrosol has been used on the transfer paper upper strata, can compared with prior art have been improved the gas permeability of pattern part on the fabric by eccysis behind the transfer printing good pattern.The present invention is specially adapted to cellulose fibre (cotton) fabric, protein fibre (silk) and polyamide (nylon) fabric.
Four, description of drawings
Accompanying drawing is the structural representation of the transfer paper of the method to wet transfer printing digital color image onto fiber fabric of cellulose of the present invention.
Five, the specific embodiment
Embodiment 1:
After designing pattern on computers, with little piezoelectric type color inkjet printer or wide format printer and use ink-jet printed special active dye ink that multicolour pattern is printed on the wet transfer printing dedicated transfer paper of cotton-spinning fabric; Sodium bicarbonate with 3 percent (sodium bicarbonate) aqueous solution wants the part of pattern transferring to soak and dry to cotton-spinning fabric; Under the cotton fabric hygrometric state, the part blade coating transfer printing of wanting pattern transferring is starched with screen printing forme, again the transfer paper front that is printed on pattern is attached on the cotton fabric of scraping transfer printing slurry, and makes transfer paper and the last fabric side of crossing slurry the two fits tightly with the dull and stereotyped transfer paper that flattens of plate glass or other; Press the boiling hot transfer printing slurry of doing from the transfer paper back side with heat transfer machine after 3 minutes, the heat transfer machine temperature can be set between 80 ℃-90 ℃, cotton fabric and the transfer paper that is printed on pattern are bonded together, and scalding can be at which floor gauze of fabric underlay so that vapor evolution when doing the transfer printing slurry.Then the cotton fabric that is adhering to pattern is put into decatize color development, fixation in 102 ℃-105 ℃ the pressure cooker, steaming time is 10 minutes, also can put into and bake 2-8 minute color development, fixation in the baking oven of 150-180 degree temperature; Take out fabric after the decatize, tear transfer paper, rinsing is loose colour and rubber cement to the greatest extent, dries at last or scalds and do, and has promptly finished whole technical process to cotton fabric transfer printing digital multicolour pattern.
As shown in the figure, the transfer paper of present embodiment is made up of three layers of different materials, and its structure is: upper strata base paper 1 is art paper; But middle level film forming glue adhesion coating 2 insoluble macromolecule polyester thing---the polyvinyl acetate that is water; The upper strata is a water-soluble adhesive layer 3, is made up of sodium alginate, and adds 0.3% calcium propionate as preservative agent.
Embodiment 2:
After designing pattern on computers, with little piezoelectric type color inkjet printer, offset press or adopt the method for screen printed pattern is printed on multicolour pattern on the wet transfer printing dedicated transfer paper on the hydrosol aspect by using reactive dye ink or printing ink.Before the transfer printing, with sodium bicarbonate (sodium bicarbonate) 3%, the aqueous solution of sodium carbonate (soda ash) 2% soaks the part of wanting pattern transferring and dries; Cotton fabric is wanted only be added with on the even blade coating of part of pattern transferring the sodium alginate transfer printing slurry of 3% sodium bicarbonate again with the silk-screen half tone, then a transfer paper front that is printed on pattern is attached on the cotton fabric of scraping the transfer printing slurry, and makes transfer paper and the last fabric side of crossing slurry the two fits tightly with the dull and stereotyped transfer paper that flattens of plate glass or other.Exert pressure from the transfer paper back side and the boiling hot transfer printing slurry of doing with heat transfer machine after 3 minutes, (the heat transfer machine temperature is set between 90 ℃-100 ℃) fully is bonded together cotton fabric and the transfer paper that is printed on pattern.(scalding can be at which floor gauze of fabric underlay so that vapor evolution when doing the transfer printing slurry.Scald and do the transfer paper that tears after transfer printing is starched on the fabric.Cotton fabric is immersed in 1-2 minute fixation in the fixation liquid that is heated to 80 ℃-90 ℃, and the fixation formula of liquid is: with sodium carbonate (soda ash) 150g, sodium chloride (salt) 200g, and NaOH (caustic soda) 16g---add water to 1000ml; Take out fabric after the fixation, wash with water and float most loose colour and rubber cement, scald and do, promptly finish whole technical process cotton fabric transfer printing digital multicolour pattern.
As shown in the figure, the transfer paper of present embodiment is made up of three layers of different materials, and its structure is: upper strata base paper 1 is the glue body paper; But middle level film forming glue adhesion coating 2 insoluble macromolecule polyester thing---the polyvinyl butyral resin that is water; The upper strata is a water-soluble adhesive layer 3, is made up of sodium alginate, and adds 0.3% calcium propionate as preservative agent.
Claims (9)
1, a kind of method to wet transfer printing digital color image onto fiber fabric of cellulose is characterized in that it may further comprise the steps:
(1) with ink-jet printer spraying dyestuff needed multicolour pattern is printed on the transfer paper, described transfer paper is formed by three layers, and lower floor is basic paper (1), but the middle level is film forming glue adhesion coating (2), and the upper strata is water-soluble adhesive layer (3);
(2), and be coated with last layer transfer printing slurry uniformly with the fractional wettability of sodium bicarbonate aqueous solution with pattern to be transferred on the cellulose base fiber fabric;
(3) one side that is printed on pattern on the described transfer paper of step (1) is attached to cellulose base fiber fabric surface to be transferred, and flattens;
(4) paper to be transferred moistening after, press with flatiron or plat type heat transfer machine and to scald dry transfer printing slurry;
(5) cellulose base fiber fabric with transfer paper was put into the pressure cooker decatize 8-12 minute;
(6) loose colour and the rubber cement on the eccysis gained textile design promptly obtains being printed on the cellulose base fiber fabric of pattern after the drying.
2, the method to wet transfer printing digital color image onto fiber fabric of cellulose as claimed in claim 1 is characterized in that: the dyestuff in the described step (1) is salt-free REACTIVE DYES.
3, the method to wet transfer printing digital color image onto fiber fabric of cellulose as claimed in claim 1 is characterized in that: the concentration of the sodium bicarbonate aqueous solution in the described step (2) is 3% (weight).
4, the method to wet transfer printing digital color image onto fiber fabric of cellulose as claimed in claim 1 is characterized in that: the transfer printing slurry in the described step (2) makes for add 4g sodium alginate, 3g sodium bicarbonate, 1g reservehao S and 2g urea in the water of every 100ml.
5, a kind of transfer paper of realizing the described method to wet transfer printing digital color image onto fiber fabric of cellulose of claim 1, it is characterized in that: described transfer paper is formed by three layers, lower floor is basic paper (1), but the middle level is film forming glue adhesion coating (2), and the upper strata is water-soluble adhesive layer (3).
6, transfer paper as claimed in claim 5 is characterized in that: the basic paper (1) of lower floor is glue body paper or art paper.
7, transfer paper as claimed in claim 5 is characterized in that: but the film forming glue adhesion coating (2) in middle level is made by the insoluble macromolecule polyester thing of water.
8, transfer paper as claimed in claim 7 is characterized in that: the insoluble macromolecule polyester thing of described water is polyvinyl acetate, styrene maleic anhydride copolymer or polyvinyl butyral resin.
9, transfer paper as claimed in claim 6 is characterized in that: the water-soluble adhesive layer on upper strata (3) is made by sodium alginate, and adds 0.3% calcium propionate as preservative agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100412271A CN1308543C (en) | 2005-07-28 | 2005-07-28 | Method for wet transfer printing digital color image onto fiber fabric of cellulose, and dedicated transfer paper |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100412271A CN1308543C (en) | 2005-07-28 | 2005-07-28 | Method for wet transfer printing digital color image onto fiber fabric of cellulose, and dedicated transfer paper |
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| Publication Number | Publication Date |
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| CN1727571A CN1727571A (en) | 2006-02-01 |
| CN1308543C true CN1308543C (en) | 2007-04-04 |
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| CNB2005100412271A Expired - Fee Related CN1308543C (en) | 2005-07-28 | 2005-07-28 | Method for wet transfer printing digital color image onto fiber fabric of cellulose, and dedicated transfer paper |
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| TWI481764B (en) * | 2011-11-17 | 2015-04-21 | Newtech Textile Technology Dev Shanghai Co Ltd | Composite coating solvent for cold-transfer printing carrier and application method thereof |
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| JP5899534B2 (en) | 2010-06-24 | 2016-04-06 | ディーエスエム アイピー アセッツ ビー．ブイ． | Waterproof breathable composite material capable of manufacturing articles such as flexible membranes |
| US8802189B1 (en) | 2010-08-03 | 2014-08-12 | Cubic Tech Corporation | System and method for the transfer of color and other physical properties to laminate composite materials and other articles |
| JP2013535587A (en) * | 2010-08-03 | 2013-09-12 | キュービック テック コーポレイション | Transfer of color and other physical properties to laminate materials |
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| US5196030A (en) * | 1987-10-05 | 1993-03-23 | Dansk Transfertryk A/S | Process with no heating for transfer pattern printing of a moist cellulose, wool or silk textile web, and an apparatus as well as a pattern carrier web for use in the process |
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