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CN1303034C - Quick repairing polymer cement base material and its preparing method - Google Patents

Quick repairing polymer cement base material and its preparing method Download PDF

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Publication number
CN1303034C
CN1303034C CNB03129104XA CN03129104A CN1303034C CN 1303034 C CN1303034 C CN 1303034C CN B03129104X A CNB03129104X A CN B03129104XA CN 03129104 A CN03129104 A CN 03129104A CN 1303034 C CN1303034 C CN 1303034C
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cement
quartz sand
sodium carbonate
latex powder
bentonite
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CN1458114A (en
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蒋正武
孙振平
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Tongji University
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Tongji University
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Abstract

本发明为一种水工、建筑工程用的聚合物水泥基快速修补材料。具体由硅酸盐水泥、高铝水泥、再分散乳胶粉、高效减水胶、碳酸钠等材料按一定重量配比组成。本修补材料粘结强度高,施工适应性广,尤其能适合于潮湿基面上施工。The invention relates to a polymer cement-based rapid repair material for hydraulic engineering and construction engineering. Specifically, it is composed of Portland cement, high alumina cement, redispersed latex powder, high-efficiency water-reducing glue, sodium carbonate and other materials in a certain weight ratio. The repairing material has high bonding strength and wide construction adaptability, and is especially suitable for construction on wet base surfaces.

Description

聚合物水泥基快速修补材料及其制备方法Polymer cement-based rapid repair material and preparation method thereof

技术领域technical field

本发明涉及一种水工、建筑工程用聚合物水泥基快速修补材料及其制备方法。具体地讲涉及一种水工、建筑、桥梁、隧道等工程中具有修补、加固、防渗等作用的粉状高性能聚合物水泥基快速修补材料及其制备。The invention relates to a polymer cement-based rapid repair material for hydraulic engineering and construction engineering and a preparation method thereof. Specifically, it relates to a powdery high-performance polymer cement-based rapid repair material with the functions of repair, reinforcement and anti-seepage in hydraulic engineering, construction, bridges, tunnels and other projects and its preparation.

背景技术Background technique

混凝土结构因其脆性大的弱点,在工程应用中往往不可避免产生开裂。混凝土结构因开裂导致混凝土结构水密性下降、渗漏,影响工程的使用寿命,甚至无法正常使用。这是建筑界普遍存在的问题。混凝土结构中裂缝的产生主要有两大类原因,一类由变形引起,包括因温度湿度变化、收缩、膨胀、不均匀沉陷等原因;另一类是外荷载(动、静荷载)直接应力引起的裂缝。在水工、道路、桥梁等工程中混凝土结构受损后,需要进行快速修补。从混凝土结构产生开裂的原因与环境条件分析,开发新型高性能修补材料具有重要意义。Due to its high brittleness, concrete structures often crack inevitably in engineering applications. The watertightness of the concrete structure decreases and leaks due to cracking, which affects the service life of the project and even cannot be used normally. This is a common problem in the construction industry. There are two main reasons for cracks in concrete structures. One is caused by deformation, including temperature and humidity changes, shrinkage, expansion, uneven subsidence, etc.; the other is caused by direct stress of external loads (dynamic and static loads). cracks. After the concrete structure is damaged in hydraulic engineering, roads, bridges and other projects, it needs to be quickly repaired. From the analysis of the causes of cracking in concrete structures and environmental conditions, it is of great significance to develop new high-performance repair materials.

常规的无机修补材料如普通硅酸盐水泥等,虽然具有良好的耐久性,但其脆性大,体积不稳定、易开裂、粘结强度低,不适应快速修补是个不争的事实,使其应用范围受到限制。有机聚合物在无机水泥中的使用大大扩展了水泥的应用范围,聚合物改性水泥基修补材料具有优良的柔性、强度与耐久性。但目前广泛使用的聚合物乳液改性水泥基修补材料,是双组分施工材料,在实际储存、运输、施工应用中受到很多限制,尤其,无法在潮湿环境或水下进行修补。开发研制一种具有刚柔相济,既有较高的强度、一定伸长率,又可在潮湿基面上施工等特点的永久性聚合物水泥基快速修补材料十分必要,而且应是无毒、无污染,符合可持续发展的产品。Conventional inorganic repair materials such as ordinary Portland cement, etc., have good durability, but they are brittle, unstable in size, easy to crack, and low in bonding strength. It is an indisputable fact that they are not suitable for rapid repair. restricted. The use of organic polymers in inorganic cement has greatly expanded the application range of cement, and polymer modified cement-based repair materials have excellent flexibility, strength and durability. However, the currently widely used polymer emulsion modified cement-based repair materials are two-component construction materials, which are subject to many restrictions in actual storage, transportation, and construction applications. In particular, they cannot be repaired in wet environments or underwater. It is necessary to develop a permanent polymer cement-based rapid repair material with the characteristics of rigidity and softness, high strength, certain elongation, and construction on wet base surfaces, and it should be non-toxic and non-polluting , in line with sustainable development products.

发明内容Contents of the invention

本发明的目的在于提供一种具有修补、加固、防渗作用、粘结强度高、施工适应性广的粉状高性能聚合物水泥基快速修补材料。The purpose of the present invention is to provide a powdery high-performance polymer cement-based rapid repair material with repairing, reinforcing and anti-seepage functions, high bonding strength and wide construction adaptability.

本发明提出的聚合物水泥基快速修补材料,是由无机粉料与聚合物乳胶粉复合而成的单组份材料,具体由硅酸盐水泥、高铝水泥、再分散乳胶粉、减水剂、碳酸钠、膨润土、石英砂组成。各组分的重量配比如下:The polymer cement-based rapid repair material proposed by the present invention is a single-component material composed of inorganic powder and polymer latex powder, specifically composed of Portland cement, high alumina cement, redispersed latex powder, and water reducing agent. , sodium carbonate, bentonite, quartz sand. The weight ratio of each component is as follows:

硅酸盐水泥                  100Portland cement 100

高铝水泥                    10-50High alumina cement 10-50

再分散乳胶粉                5-25Redispersed latex powder 5-25

减水剂                      0.5-3Water reducing agent 0.5-3

碳酸钠                      0-10Sodium carbonate 0-10

膨润土                      5-25Bentonite 5-25

1.25mm-2.5mm石英砂          20-1001.25mm-2.5mm quartz sand 20-100

小于1.25mm石英砂            30-150。Less than 1.25mm quartz sand 30-150.

各组分较佳配比为:The optimal proportioning ratio of each component is:

硅酸盐水泥                  100Portland cement 100

高铝水泥                    20-30High alumina cement 20-30

再分散乳胶粉                10-20Redispersed latex powder 10-20

减水剂                      0.5-1.5Water reducing agent 0.5-1.5

碳酸钠                      0-5Sodium carbonate 0-5

膨润土                      10-20Bentonite 10-20

1.25mm-2.5mm石英砂          30-701.25mm-2.5mm quartz sand 30-70

小于1.25mm石英砂            40-90。Less than 1.25mm quartz sand 40-90.

本发明中,所用的减水剂可以是聚羧酸盐、甲基萘磺酸钠缩合物、氨基磺酸等。In the present invention, the water reducing agent used may be polycarboxylate, sodium methylnaphthalene sulfonate condensate, sulfamic acid and the like.

本发明是无机粉料与聚合物乳胶粉复合而成的单组分快速修补材料。无机粉料与水拌和后迅速水化,快速凝结硬化。而分散在浆体中的聚合物乳胶粉,在无机粉料的快速水化产生的热量下也吸附在水泥及其水化产物和其它填料的表面,且随着水分的消耗和蒸发,聚合物颗粒之间慢慢地靠拢而相互凝聚在一起,进一步固化即形成连续的网状结构,使得修补材料具有良好的柔韧性与力学性能。它既有高的粘结强度,又有广的施工适应性,尤其能适合于潮湿基面上施工。The invention is a one-component rapid repair material compounded by inorganic powder and polymer latex powder. After the inorganic powder is mixed with water, it hydrates rapidly and coagulates and hardens rapidly. The polymer latex powder dispersed in the slurry is also adsorbed on the surface of cement and its hydration products and other fillers under the heat generated by the rapid hydration of the inorganic powder, and with the consumption and evaporation of water, the polymer The particles slowly move closer to each other and coagulate together, and further solidify to form a continuous network structure, which makes the repair material have good flexibility and mechanical properties. It not only has high bonding strength, but also has wide construction adaptability, especially suitable for construction on wet base surface.

本发明的制备方法是:水泥选用52.5强度等级的硅酸盐水泥,高铝水泥选用62.5强度等级以上的水泥。各组分的自由水分含量控制在0.5%以下。The preparation method of the present invention is as follows: the cement is made of Portland cement with a strength grade of 52.5, and the high-alumina cement is selected with a strength grade of 62.5 or above. The free moisture content of each component is controlled below 0.5%.

按配方比例称取各种原材料,在搅拌机中依次加入石英砂、硅酸盐水泥、高铝水泥、再分散乳胶粉、减水剂、碳酸钠、膨润土,充分搅拌均匀,形成产品。Weigh various raw materials according to the proportion of the formula, add quartz sand, Portland cement, high alumina cement, redispersed latex powder, water reducing agent, sodium carbonate, bentonite into the mixer in sequence, and mix well to form a product.

本发明的优点在于:The advantages of the present invention are:

(1)凝结时间快,并且凝结时间可以根据需要进行适当调整,可适合于各类工程的快速修补和加固;(1) The setting time is fast, and the setting time can be adjusted appropriately according to the needs, which is suitable for rapid repair and reinforcement of various projects;

(2)具有高早强、韧性、良好的变形能力和高耐久性;(2) It has high early strength, toughness, good deformation ability and high durability;

(3)与各种基体粘结力很强,与普通水泥砂浆相比,粘结强度大幅度提高;(3) Strong bonding force with various substrates, compared with ordinary cement mortar, the bonding strength is greatly improved;

(4)具有良好的物理力学性能,其抗折强度、粘结强度、极限拉伸值大幅度提高,低吸水率、高渗透防水性能;(4) It has good physical and mechanical properties, its flexural strength, bond strength, ultimate tensile value are greatly improved, low water absorption, high permeability and waterproof performance;

(5)可在潮湿环境中施工,施工操作简便灵活;(5) It can be constructed in a humid environment, and the construction operation is simple and flexible;

(6)产品无毒、无味,对人体无害,不污染环境,属于环保型快速修补材料。(6) The product is non-toxic, tasteless, harmless to the human body, does not pollute the environment, and is an environmentally friendly quick repair material.

具体实施方式Detailed ways

聚合物水泥基快速修补材料,由硅酸盐水泥、高铝水泥、再分散乳胶粉、减水剂、碳酸钠、膨润土、石英砂组成。根据应用的环境条件,通过调整发明的配方,可以获得所需要的性能。The polymer cement-based rapid repair material is composed of Portland cement, high alumina cement, redispersed latex powder, water reducer, sodium carbonate, bentonite, and quartz sand. According to the environmental conditions of the application, the required performance can be obtained by adjusting the invented formula.

实施例1Example 1

硅酸盐水泥          100Portland cement 100

高铝水泥            30High alumina cement 30

再分散乳胶粉        10Redispersed latex powder 10

聚羧酸盐            2Polycarboxylate 2

碳酸钠              1Sodium carbonate 1

膨润土              10Bentonite 10

1.25mm-2.5mm石英砂  201.25mm-2.5mm quartz sand 20

小于1.25mm石英砂    30。Less than 1.25mm quartz sand 30.

上述组分按前述工艺制备得快速修补材料,流动性大、凝结时间适中、强度高的特点,可灌入一定宽度的裂缝,适合于大面积修补和加固工程。The above-mentioned components are prepared according to the above-mentioned process to prepare a rapid repair material, which has the characteristics of large fluidity, moderate setting time and high strength. It can be poured into cracks of a certain width, and is suitable for large-area repair and reinforcement projects.

实施例2Example 2

硅酸盐水泥          100Portland cement 100

高铝水泥            20High alumina cement 20

再分散乳胶粉        15Redispersed latex powder 15

甲基萘磺酸钠缩合物  1.5Sodium methylnaphthalene sulfonate condensate 1.5

碳酸钠              0Sodium carbonate 0

膨润土              8Bentonite 8

1.25mm-2.5mm石英砂  801.25mm-2.5mm quartz sand 80

小于1.25mm石英砂    120。Less than 1.25mm quartz sand 120.

上述组份按前述工艺制备得的快速修补材料,具有超高强、粘结强度高、流动性大、凝结时间适中的特点,适合于各种修补和加固工程。The rapid repair material prepared from the above components according to the aforementioned process has the characteristics of super high strength, high bonding strength, high fluidity and moderate setting time, and is suitable for various repair and reinforcement projects.

实施例3Example 3

硅酸盐水泥          100Portland cement 100

高铝水泥            40High alumina cement 40

再分散乳胶粉        12Redispersed latex powder 12

氨基磺酸盐          1.0Sulfamate 1.0

碳酸钠              4Sodium carbonate 4

膨润土              10Bentonite 10

1.25mm-2.5mm石英砂  501.25mm-2.5mm quartz sand 50

小于1.25mm石英砂    80。Less than 1.25mm quartz sand 80.

上述组份按前述工艺制备得的快速修补材料,具有凝结时间短、粘结强度高、强度高等性能,适合于特种抢修、加固工程。The rapid repair material prepared from the above components according to the aforementioned process has the properties of short setting time, high bonding strength and high strength, and is suitable for special emergency repair and reinforcement projects.

Claims (3)

1、一种聚合物水泥基快速修补材料,其特征在于由硅酸盐水泥、高铝水泥、再分散乳胶粉、减水剂、碳酸钠、膨润土、石英砂组成,各组分的重量配比如下:1. A polymer cement-based rapid repair material is characterized in that it is composed of Portland cement, high alumina cement, redispersed latex powder, water reducer, sodium carbonate, bentonite, and quartz sand. The weight ratio of each component is as follows: Down: 硅酸盐水泥                100Portland cement 100 高铝水泥                  10-50High alumina cement 10-50 再分散乳胶粉              5-25Redispersed latex powder 5-25 减水剂                    0.5-3Water reducing agent 0.5-3 碳酸钠                    0-10Sodium carbonate 0-10 膨润土                    5-25Bentonite 5-25 1.25mm-2.5mm石英砂        20-1001.25mm-2.5mm quartz sand 20-100 小于1.25mm石英砂          30-150。Less than 1.25mm quartz sand 30-150. 2、根据权利要求1所述的聚合物水泥基快速修补材料,其特征在于各组分的重量配比如下:2. The polymer cement-based quick repair material according to claim 1, characterized in that the weight ratio of each component is as follows: 硅酸盐水泥                100Portland cement 100 高铝水泥                  20-30High alumina cement 20-30 再分散乳胶粉              10-20Redisperse latex powder 10-20 减水剂                    0.5-1.5Water reducing agent 0.5-1.5 碳酸钠                    0-5Sodium carbonate 0-5 膨润土                    10-20Bentonite 10-20 1.25mm-2.5mm石英砂        30-701.25mm-2.5mm quartz sand 30-70 小于1.25mm石英砂          40-90。Less than 1.25mm quartz sand 40-90. 3、一种如权利要求1所述的聚合物水泥基快速修补材料的制备方法,其特征在于按配方比例称取各种原材料,在搅拌机中依次加入石英砂、硅酸盐水泥、高铝水泥、再分散乳胶粉、减水剂、碳酸钠、膨润土,充分搅拌均匀,形成产品。3. A method for preparing polymer cement-based rapid repair materials as claimed in claim 1, characterized in that various raw materials are weighed according to the formula ratio, and quartz sand, Portland cement, and high alumina cement are sequentially added to the mixer , Redisperse latex powder, water reducer, sodium carbonate, bentonite, fully stir evenly to form a product.
CNB03129104XA 2003-06-05 2003-06-05 Quick repairing polymer cement base material and its preparing method Expired - Fee Related CN1303034C (en)

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Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1315753C (en) * 2004-02-26 2007-05-16 同济大学 Material for pointing joint ceramic tile, marble
CN1326797C (en) * 2004-03-04 2007-07-18 同济大学 Cement-base material for repairing crack of bridge
CN1303033C (en) * 2004-03-04 2007-03-07 同济大学 Material of cement-base for covering surface of bridge
US7607483B2 (en) 2004-04-19 2009-10-27 Halliburton Energy Services, Inc. Sealant compositions comprising colloidally stabilized latex and methods of using the same
US7488705B2 (en) 2004-12-08 2009-02-10 Halliburton Energy Services, Inc. Oilwell sealant compositions comprising alkali swellable latex
US20070111901A1 (en) 2005-11-11 2007-05-17 Reddy B R Method of servicing a wellbore with a sealant composition comprising solid latex
CN101096303B (en) * 2006-06-30 2011-09-21 富春控股集团有限公司 Rapid repair materials for road construction and construction
CN101456717B (en) * 2007-12-14 2013-01-09 袁航 Non-toxic, environmental friendly, anti-corrosive, water proof, anti-seepage and wearable reinforcement material and preparation method thereof
CN101817662B (en) * 2010-03-09 2012-06-06 申爱琴 DBB concrete pavement crack repair material
CN102249629A (en) * 2011-06-10 2011-11-23 上海三瑞高分子材料有限公司 Acrylate emulsion modified cement-base repair mortar
CN102531503A (en) * 2011-12-23 2012-07-04 广东工业大学 High-viscosity cement mortar and manufacturing method thereof
CN106007594A (en) * 2016-05-30 2016-10-12 江苏名和集团有限公司 Super early-strength repairing material for cement concrete
CN107032711B (en) * 2016-11-14 2019-01-29 张文凯 Natural marble crack repair method
CN111892360B (en) * 2020-06-16 2022-06-21 中油佳汇(广东)防水股份有限公司 Modified asphalt waterproof coiled material coated with water-absorbing powder and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1305972A (en) * 2001-02-23 2001-08-01 重庆大学 External insulating mortar and its preparing process
CN1388188A (en) * 2002-06-10 2003-01-01 杨汤群 Cement-based polymer paint powder
CN1433994A (en) * 2003-01-17 2003-08-06 王寿元 Later-modified cement and use thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1305972A (en) * 2001-02-23 2001-08-01 重庆大学 External insulating mortar and its preparing process
CN1388188A (en) * 2002-06-10 2003-01-01 杨汤群 Cement-based polymer paint powder
CN1433994A (en) * 2003-01-17 2003-08-06 王寿元 Later-modified cement and use thereof

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