CN1303034C - Quick repairing polymer cement base material and its preparing method - Google Patents
Quick repairing polymer cement base material and its preparing method Download PDFInfo
- Publication number
- CN1303034C CN1303034C CNB03129104XA CN03129104A CN1303034C CN 1303034 C CN1303034 C CN 1303034C CN B03129104X A CNB03129104X A CN B03129104XA CN 03129104 A CN03129104 A CN 03129104A CN 1303034 C CN1303034 C CN 1303034C
- Authority
- CN
- China
- Prior art keywords
- cement
- quartz sand
- sodium carbonate
- latex powder
- bentonite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000463 material Substances 0.000 title claims abstract description 24
- 239000011414 polymer cement Substances 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 26
- 230000008439 repair process Effects 0.000 claims abstract description 26
- 239000004568 cement Substances 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 20
- 239000004816 latex Substances 0.000 claims abstract description 16
- 229920000126 latex Polymers 0.000 claims abstract description 16
- 239000011398 Portland cement Substances 0.000 claims abstract description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 13
- 239000006004 Quartz sand Substances 0.000 claims description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000000440 bentonite Substances 0.000 claims description 12
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 12
- 229940092782 bentonite Drugs 0.000 claims description 10
- 229910000278 bentonite Inorganic materials 0.000 claims description 10
- 239000003638 chemical reducing agent Substances 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 2
- 229940080314 sodium bentonite Drugs 0.000 claims description 2
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 12
- 239000003292 glue Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 6
- 230000002787 reinforcement Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 229920005646 polycarboxylate Polymers 0.000 description 2
- GCNLRNBDDUYJMP-UHFFFAOYSA-M sodium;2-methylnaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(C)=CC=C21 GCNLRNBDDUYJMP-UHFFFAOYSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
本发明为一种水工、建筑工程用的聚合物水泥基快速修补材料。具体由硅酸盐水泥、高铝水泥、再分散乳胶粉、高效减水胶、碳酸钠等材料按一定重量配比组成。本修补材料粘结强度高,施工适应性广,尤其能适合于潮湿基面上施工。The invention relates to a polymer cement-based rapid repair material for hydraulic engineering and construction engineering. Specifically, it is composed of Portland cement, high alumina cement, redispersed latex powder, high-efficiency water-reducing glue, sodium carbonate and other materials in a certain weight ratio. The repairing material has high bonding strength and wide construction adaptability, and is especially suitable for construction on wet base surfaces.
Description
技术领域technical field
本发明涉及一种水工、建筑工程用聚合物水泥基快速修补材料及其制备方法。具体地讲涉及一种水工、建筑、桥梁、隧道等工程中具有修补、加固、防渗等作用的粉状高性能聚合物水泥基快速修补材料及其制备。The invention relates to a polymer cement-based rapid repair material for hydraulic engineering and construction engineering and a preparation method thereof. Specifically, it relates to a powdery high-performance polymer cement-based rapid repair material with the functions of repair, reinforcement and anti-seepage in hydraulic engineering, construction, bridges, tunnels and other projects and its preparation.
背景技术Background technique
混凝土结构因其脆性大的弱点,在工程应用中往往不可避免产生开裂。混凝土结构因开裂导致混凝土结构水密性下降、渗漏,影响工程的使用寿命,甚至无法正常使用。这是建筑界普遍存在的问题。混凝土结构中裂缝的产生主要有两大类原因,一类由变形引起,包括因温度湿度变化、收缩、膨胀、不均匀沉陷等原因;另一类是外荷载(动、静荷载)直接应力引起的裂缝。在水工、道路、桥梁等工程中混凝土结构受损后,需要进行快速修补。从混凝土结构产生开裂的原因与环境条件分析,开发新型高性能修补材料具有重要意义。Due to its high brittleness, concrete structures often crack inevitably in engineering applications. The watertightness of the concrete structure decreases and leaks due to cracking, which affects the service life of the project and even cannot be used normally. This is a common problem in the construction industry. There are two main reasons for cracks in concrete structures. One is caused by deformation, including temperature and humidity changes, shrinkage, expansion, uneven subsidence, etc.; the other is caused by direct stress of external loads (dynamic and static loads). cracks. After the concrete structure is damaged in hydraulic engineering, roads, bridges and other projects, it needs to be quickly repaired. From the analysis of the causes of cracking in concrete structures and environmental conditions, it is of great significance to develop new high-performance repair materials.
常规的无机修补材料如普通硅酸盐水泥等,虽然具有良好的耐久性,但其脆性大,体积不稳定、易开裂、粘结强度低,不适应快速修补是个不争的事实,使其应用范围受到限制。有机聚合物在无机水泥中的使用大大扩展了水泥的应用范围,聚合物改性水泥基修补材料具有优良的柔性、强度与耐久性。但目前广泛使用的聚合物乳液改性水泥基修补材料,是双组分施工材料,在实际储存、运输、施工应用中受到很多限制,尤其,无法在潮湿环境或水下进行修补。开发研制一种具有刚柔相济,既有较高的强度、一定伸长率,又可在潮湿基面上施工等特点的永久性聚合物水泥基快速修补材料十分必要,而且应是无毒、无污染,符合可持续发展的产品。Conventional inorganic repair materials such as ordinary Portland cement, etc., have good durability, but they are brittle, unstable in size, easy to crack, and low in bonding strength. It is an indisputable fact that they are not suitable for rapid repair. restricted. The use of organic polymers in inorganic cement has greatly expanded the application range of cement, and polymer modified cement-based repair materials have excellent flexibility, strength and durability. However, the currently widely used polymer emulsion modified cement-based repair materials are two-component construction materials, which are subject to many restrictions in actual storage, transportation, and construction applications. In particular, they cannot be repaired in wet environments or underwater. It is necessary to develop a permanent polymer cement-based rapid repair material with the characteristics of rigidity and softness, high strength, certain elongation, and construction on wet base surfaces, and it should be non-toxic and non-polluting , in line with sustainable development products.
发明内容Contents of the invention
本发明的目的在于提供一种具有修补、加固、防渗作用、粘结强度高、施工适应性广的粉状高性能聚合物水泥基快速修补材料。The purpose of the present invention is to provide a powdery high-performance polymer cement-based rapid repair material with repairing, reinforcing and anti-seepage functions, high bonding strength and wide construction adaptability.
本发明提出的聚合物水泥基快速修补材料,是由无机粉料与聚合物乳胶粉复合而成的单组份材料,具体由硅酸盐水泥、高铝水泥、再分散乳胶粉、减水剂、碳酸钠、膨润土、石英砂组成。各组分的重量配比如下:The polymer cement-based rapid repair material proposed by the present invention is a single-component material composed of inorganic powder and polymer latex powder, specifically composed of Portland cement, high alumina cement, redispersed latex powder, and water reducing agent. , sodium carbonate, bentonite, quartz sand. The weight ratio of each component is as follows:
硅酸盐水泥 100Portland cement 100
高铝水泥 10-50High alumina cement 10-50
再分散乳胶粉 5-25Redispersed latex powder 5-25
减水剂 0.5-3Water reducing agent 0.5-3
碳酸钠 0-10Sodium carbonate 0-10
膨润土 5-25Bentonite 5-25
1.25mm-2.5mm石英砂 20-1001.25mm-2.5mm quartz sand 20-100
小于1.25mm石英砂 30-150。Less than 1.25mm quartz sand 30-150.
各组分较佳配比为:The optimal proportioning ratio of each component is:
硅酸盐水泥 100Portland cement 100
高铝水泥 20-30High alumina cement 20-30
再分散乳胶粉 10-20Redispersed latex powder 10-20
减水剂 0.5-1.5Water reducing agent 0.5-1.5
碳酸钠 0-5Sodium carbonate 0-5
膨润土 10-20Bentonite 10-20
1.25mm-2.5mm石英砂 30-701.25mm-2.5mm quartz sand 30-70
小于1.25mm石英砂 40-90。Less than 1.25mm quartz sand 40-90.
本发明中,所用的减水剂可以是聚羧酸盐、甲基萘磺酸钠缩合物、氨基磺酸等。In the present invention, the water reducing agent used may be polycarboxylate, sodium methylnaphthalene sulfonate condensate, sulfamic acid and the like.
本发明是无机粉料与聚合物乳胶粉复合而成的单组分快速修补材料。无机粉料与水拌和后迅速水化,快速凝结硬化。而分散在浆体中的聚合物乳胶粉,在无机粉料的快速水化产生的热量下也吸附在水泥及其水化产物和其它填料的表面,且随着水分的消耗和蒸发,聚合物颗粒之间慢慢地靠拢而相互凝聚在一起,进一步固化即形成连续的网状结构,使得修补材料具有良好的柔韧性与力学性能。它既有高的粘结强度,又有广的施工适应性,尤其能适合于潮湿基面上施工。The invention is a one-component rapid repair material compounded by inorganic powder and polymer latex powder. After the inorganic powder is mixed with water, it hydrates rapidly and coagulates and hardens rapidly. The polymer latex powder dispersed in the slurry is also adsorbed on the surface of cement and its hydration products and other fillers under the heat generated by the rapid hydration of the inorganic powder, and with the consumption and evaporation of water, the polymer The particles slowly move closer to each other and coagulate together, and further solidify to form a continuous network structure, which makes the repair material have good flexibility and mechanical properties. It not only has high bonding strength, but also has wide construction adaptability, especially suitable for construction on wet base surface.
本发明的制备方法是:水泥选用52.5强度等级的硅酸盐水泥,高铝水泥选用62.5强度等级以上的水泥。各组分的自由水分含量控制在0.5%以下。The preparation method of the present invention is as follows: the cement is made of Portland cement with a strength grade of 52.5, and the high-alumina cement is selected with a strength grade of 62.5 or above. The free moisture content of each component is controlled below 0.5%.
按配方比例称取各种原材料,在搅拌机中依次加入石英砂、硅酸盐水泥、高铝水泥、再分散乳胶粉、减水剂、碳酸钠、膨润土,充分搅拌均匀,形成产品。Weigh various raw materials according to the proportion of the formula, add quartz sand, Portland cement, high alumina cement, redispersed latex powder, water reducing agent, sodium carbonate, bentonite into the mixer in sequence, and mix well to form a product.
本发明的优点在于:The advantages of the present invention are:
(1)凝结时间快,并且凝结时间可以根据需要进行适当调整,可适合于各类工程的快速修补和加固;(1) The setting time is fast, and the setting time can be adjusted appropriately according to the needs, which is suitable for rapid repair and reinforcement of various projects;
(2)具有高早强、韧性、良好的变形能力和高耐久性;(2) It has high early strength, toughness, good deformation ability and high durability;
(3)与各种基体粘结力很强,与普通水泥砂浆相比,粘结强度大幅度提高;(3) Strong bonding force with various substrates, compared with ordinary cement mortar, the bonding strength is greatly improved;
(4)具有良好的物理力学性能,其抗折强度、粘结强度、极限拉伸值大幅度提高,低吸水率、高渗透防水性能;(4) It has good physical and mechanical properties, its flexural strength, bond strength, ultimate tensile value are greatly improved, low water absorption, high permeability and waterproof performance;
(5)可在潮湿环境中施工,施工操作简便灵活;(5) It can be constructed in a humid environment, and the construction operation is simple and flexible;
(6)产品无毒、无味,对人体无害,不污染环境,属于环保型快速修补材料。(6) The product is non-toxic, tasteless, harmless to the human body, does not pollute the environment, and is an environmentally friendly quick repair material.
具体实施方式Detailed ways
聚合物水泥基快速修补材料,由硅酸盐水泥、高铝水泥、再分散乳胶粉、减水剂、碳酸钠、膨润土、石英砂组成。根据应用的环境条件,通过调整发明的配方,可以获得所需要的性能。The polymer cement-based rapid repair material is composed of Portland cement, high alumina cement, redispersed latex powder, water reducer, sodium carbonate, bentonite, and quartz sand. According to the environmental conditions of the application, the required performance can be obtained by adjusting the invented formula.
实施例1Example 1
硅酸盐水泥 100Portland cement 100
高铝水泥 30High alumina cement 30
再分散乳胶粉 10Redispersed latex powder 10
聚羧酸盐 2Polycarboxylate 2
碳酸钠 1Sodium carbonate 1
膨润土 10Bentonite 10
1.25mm-2.5mm石英砂 201.25mm-2.5mm quartz sand 20
小于1.25mm石英砂 30。Less than 1.25mm quartz sand 30.
上述组分按前述工艺制备得快速修补材料,流动性大、凝结时间适中、强度高的特点,可灌入一定宽度的裂缝,适合于大面积修补和加固工程。The above-mentioned components are prepared according to the above-mentioned process to prepare a rapid repair material, which has the characteristics of large fluidity, moderate setting time and high strength. It can be poured into cracks of a certain width, and is suitable for large-area repair and reinforcement projects.
实施例2Example 2
硅酸盐水泥 100Portland cement 100
高铝水泥 20High alumina cement 20
再分散乳胶粉 15Redispersed latex powder 15
甲基萘磺酸钠缩合物 1.5Sodium methylnaphthalene sulfonate condensate 1.5
碳酸钠 0Sodium carbonate 0
膨润土 8Bentonite 8
1.25mm-2.5mm石英砂 801.25mm-2.5mm quartz sand 80
小于1.25mm石英砂 120。Less than 1.25mm quartz sand 120.
上述组份按前述工艺制备得的快速修补材料,具有超高强、粘结强度高、流动性大、凝结时间适中的特点,适合于各种修补和加固工程。The rapid repair material prepared from the above components according to the aforementioned process has the characteristics of super high strength, high bonding strength, high fluidity and moderate setting time, and is suitable for various repair and reinforcement projects.
实施例3Example 3
硅酸盐水泥 100Portland cement 100
高铝水泥 40High alumina cement 40
再分散乳胶粉 12Redispersed latex powder 12
氨基磺酸盐 1.0Sulfamate 1.0
碳酸钠 4Sodium carbonate 4
膨润土 10Bentonite 10
1.25mm-2.5mm石英砂 501.25mm-2.5mm quartz sand 50
小于1.25mm石英砂 80。Less than 1.25mm quartz sand 80.
上述组份按前述工艺制备得的快速修补材料,具有凝结时间短、粘结强度高、强度高等性能,适合于特种抢修、加固工程。The rapid repair material prepared from the above components according to the aforementioned process has the properties of short setting time, high bonding strength and high strength, and is suitable for special emergency repair and reinforcement projects.
Claims (3)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB03129104XA CN1303034C (en) | 2003-06-05 | 2003-06-05 | Quick repairing polymer cement base material and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB03129104XA CN1303034C (en) | 2003-06-05 | 2003-06-05 | Quick repairing polymer cement base material and its preparing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1458114A CN1458114A (en) | 2003-11-26 |
| CN1303034C true CN1303034C (en) | 2007-03-07 |
Family
ID=29430492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB03129104XA Expired - Fee Related CN1303034C (en) | 2003-06-05 | 2003-06-05 | Quick repairing polymer cement base material and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1303034C (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1315753C (en) * | 2004-02-26 | 2007-05-16 | 同济大学 | Material for pointing joint ceramic tile, marble |
| CN1326797C (en) * | 2004-03-04 | 2007-07-18 | 同济大学 | Cement-base material for repairing crack of bridge |
| CN1303033C (en) * | 2004-03-04 | 2007-03-07 | 同济大学 | Material of cement-base for covering surface of bridge |
| US7607483B2 (en) | 2004-04-19 | 2009-10-27 | Halliburton Energy Services, Inc. | Sealant compositions comprising colloidally stabilized latex and methods of using the same |
| US7488705B2 (en) | 2004-12-08 | 2009-02-10 | Halliburton Energy Services, Inc. | Oilwell sealant compositions comprising alkali swellable latex |
| US20070111901A1 (en) | 2005-11-11 | 2007-05-17 | Reddy B R | Method of servicing a wellbore with a sealant composition comprising solid latex |
| CN101096303B (en) * | 2006-06-30 | 2011-09-21 | 富春控股集团有限公司 | Rapid repair materials for road construction and construction |
| CN101456717B (en) * | 2007-12-14 | 2013-01-09 | 袁航 | Non-toxic, environmental friendly, anti-corrosive, water proof, anti-seepage and wearable reinforcement material and preparation method thereof |
| CN101817662B (en) * | 2010-03-09 | 2012-06-06 | 申爱琴 | DBB concrete pavement crack repair material |
| CN102249629A (en) * | 2011-06-10 | 2011-11-23 | 上海三瑞高分子材料有限公司 | Acrylate emulsion modified cement-base repair mortar |
| CN102531503A (en) * | 2011-12-23 | 2012-07-04 | 广东工业大学 | High-viscosity cement mortar and manufacturing method thereof |
| CN106007594A (en) * | 2016-05-30 | 2016-10-12 | 江苏名和集团有限公司 | Super early-strength repairing material for cement concrete |
| CN107032711B (en) * | 2016-11-14 | 2019-01-29 | 张文凯 | Natural marble crack repair method |
| CN111892360B (en) * | 2020-06-16 | 2022-06-21 | 中油佳汇(广东)防水股份有限公司 | Modified asphalt waterproof coiled material coated with water-absorbing powder and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1305972A (en) * | 2001-02-23 | 2001-08-01 | 重庆大学 | External insulating mortar and its preparing process |
| CN1388188A (en) * | 2002-06-10 | 2003-01-01 | 杨汤群 | Cement-based polymer paint powder |
| CN1433994A (en) * | 2003-01-17 | 2003-08-06 | 王寿元 | Later-modified cement and use thereof |
-
2003
- 2003-06-05 CN CNB03129104XA patent/CN1303034C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1305972A (en) * | 2001-02-23 | 2001-08-01 | 重庆大学 | External insulating mortar and its preparing process |
| CN1388188A (en) * | 2002-06-10 | 2003-01-01 | 杨汤群 | Cement-based polymer paint powder |
| CN1433994A (en) * | 2003-01-17 | 2003-08-06 | 王寿元 | Later-modified cement and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1458114A (en) | 2003-11-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111533517B (en) | Rapid repair mortar for high-speed railway concrete track slab and preparation method thereof | |
| CN112341123B (en) | A kind of tile adhesive that resists seawater corrosion and its production method | |
| CN114751706B (en) | Concrete crack repairing material based on nano material and preparation method thereof | |
| CN1303034C (en) | Quick repairing polymer cement base material and its preparing method | |
| CN103803918A (en) | Porcelain powder waste mixed cement-based tiny-expansion crack repairing mortar and using method thereof | |
| CN102503318B (en) | High bending strength cement-based grouting material | |
| KR101608015B1 (en) | Method of repairing and reinforcing cross section of concrete structure using fast hardening mortar | |
| CN103896527A (en) | Lightweight high-strength cement based composite material | |
| KR101809485B1 (en) | Ultra rapid harding,high early strength waterproof and mothproof mortar composition | |
| CN1612847A (en) | Additive for dewaterable slurry | |
| CN101698590B (en) | Repairing material for concrete and preparation method thereof | |
| CN101580369A (en) | Fiber reinforced high-strength mortar used for concrete structure repair | |
| CN1844026A (en) | A novel masonry cement | |
| CN102690092A (en) | Low-temperature rice hull ash doped cement-base shrinkage-free grouting material and using method thereof | |
| CN1559970A (en) | A cement-based bridge deck crack repair material | |
| CN107935506A (en) | A kind of anticorrosive concrete and preparation method thereof | |
| CN1546416A (en) | A kind of polymer cement-based self-leveling material and preparation method thereof | |
| CN112930329A (en) | Alkali-activated dry-mixed repair mortar with low shrinkage | |
| CN1587180A (en) | High performance cement base self leveling material | |
| CN108328977B (en) | a concrete repair material | |
| CN111018437B (en) | Ultrahigh-toughness waste brick-concrete regeneration mixture and preparation method and application thereof | |
| CN1559968A (en) | Concrete crack grouting repair material | |
| CN107602013B (en) | Bentonite cement-based composite material and preparation method thereof | |
| CN114044663B (en) | Low-shrinkage early-strength sleeve grouting material and preparation method and application thereof | |
| CN1931772A (en) | No-baking and no-steaming environment protection solid fly ash-cinder brick |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070307 |