CN1302930C - Ink jetting head assembly and production method thereof - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及一种喷墨头组件及其制造方法,尤其涉及一种降低制造成本的喷墨头组件及其制造方法。The invention relates to an ink-jet head assembly and a manufacturing method thereof, in particular to an ink-jet head assembly with reduced manufacturing cost and a manufacturing method thereof.
背景技术Background technique
喷墨头组件为喷墨打印机的关键零组件,以目前喷墨头的封装结构而言,其组装过程多半先将喷孔片和喷墨头芯片先行制作完成,接着将感光型的接着剂平铺于芯片上,以光刻的方式在此接着剂上形成储墨室与供应墨水的流道,再将喷孔片和芯片以接着剂来进行对位贴合,最后把卷带式自动封装片的引脚(Lead)以高温及外加压力的方式,对准贴合在芯片的电性讯号接点(Pads)上,以提供芯片对外的电性连接。The inkjet head assembly is the key component of the inkjet printer. In terms of the current packaging structure of the inkjet head, most of the assembly process first completes the orifice sheet and the inkjet head chip, and then puts the photosensitive adhesive on the surface. Lay it on the chip, form the ink storage chamber and the flow channel for supplying ink on the adhesive by photolithography, and then use the adhesive to carry out alignment and bonding of the orifice sheet and the chip, and finally wrap the tape and roll automatically The pins (Lead) of the chip are aligned and attached to the electrical signal contacts (Pads) of the chip by means of high temperature and external pressure, so as to provide the external electrical connection of the chip.
其中,喷墨头芯片的讯号接点是以内引脚方式对位热压,使其与基板的导线接脚结合。需使用半导体技术的内引脚接合(ILB,Inner Lead Bonding)设备,在封装时先使喷墨芯片的讯号接点与基板的导线接脚作精确对位;再以热熔加压方式将导线接脚熔接于讯号接点,并在熔接区域填充底胶以增加可靠度。由于此工艺的精密度相当高且相当困难,其工艺条件容易影响到组件的封装结构的质量。另外,现有技术所使用的喷孔片,是以电铸的方式制成,在制作之前,需要精密的调整电镀液的配方,经过长时间的调整校正,才可以获得较好的电铸质量,因此,以此方法所获得批量制造的喷孔片,其喷孔的尺寸与圆度、喷孔片的厚度均匀性,都难以精准的控制。同时金属喷孔片与喷墨芯片的接合强度,会因为受到储墨室内的墨水侵蚀,附着力随时间持续降低,进而造成局部的脱离(delamination)现象。Wherein, the signal contacts of the inkjet head chip are aligned and hot-pressed in the form of inner pins, so that they are combined with the wire pins of the substrate. Inner Lead Bonding (ILB, Inner Lead Bonding) equipment using semiconductor technology is required. During packaging, the signal contacts of the inkjet chip and the wire pins of the substrate are firstly aligned; then the wires are bonded by hot melt pressure. The feet are welded to the signal contacts, and the welded area is filled with primer to increase reliability. Due to the high precision and difficulty of this process, its process conditions are likely to affect the quality of the packaging structure of the component. In addition, the orifice sheet used in the prior art is made by electroforming. Before making it, it is necessary to precisely adjust the formula of the electroplating solution. After a long period of adjustment and correction, better electroforming quality can be obtained. Therefore, it is difficult to precisely control the size and roundness of the orifice holes and the thickness uniformity of the orifice sheets obtained by this method. At the same time, the bonding strength between the metal orifice sheet and the inkjet chip will be eroded by the ink in the ink storage chamber, and the adhesion will continue to decrease over time, thereby causing local delamination.
另外,也可以激光穿孔的方式在卷带式自动封装片上制作喷孔,请参考美国第5305015号专利,其整体制作工艺为在卷带式自动封装片的基材上先形成传动孔,再以电铸或贴铜箔的方式制造出讯号传输的导线,之后再聚焦激光以蚀刻出喷孔。经过清理的程序,最后再与芯片以热压的方式结合,完成喷墨头芯片的封装。然而此专利方法须以激光逐一制作喷孔,使制造过程速度缓慢,并且在制造过程中会产生高热容易导致喷孔周围产生变形。此外如欲产生不同尺寸的喷孔,需要使用不同透镜来聚焦激光,会造成制造时间与成本的增加,而在激光制程中在其喷孔周围所产生的碎屑也不容易去除。In addition, laser perforation can also be used to make nozzle holes on the tape-and-reel automatic packaging sheet. Please refer to US Patent No. 5,305,015. The wires for signal transmission are produced by electroforming or pasting copper foil, and then the focused laser is used to etch the nozzle holes. After the cleaning procedure, it is finally combined with the chip by hot pressing to complete the packaging of the inkjet head chip. However, in this patented method, the nozzle holes must be produced one by one by laser, which makes the manufacturing process slow, and high heat will be generated during the manufacturing process, which will easily lead to deformation around the nozzle holes. In addition, if you want to produce nozzle holes of different sizes, you need to use different lenses to focus the laser, which will increase the manufacturing time and cost, and the debris generated around the nozzle holes during the laser process is not easy to remove.
发明内容Contents of the invention
本发明所要解决的技术问题在于提供一种喷墨头组件及其制造方法,直接将储墨室、喷孔以及对芯片的电性连接引脚整合至单一组件,并且通过整体性的制造工艺来加以制造完成。The technical problem to be solved by the present invention is to provide an inkjet head assembly and its manufacturing method, which directly integrates the ink storage chamber, the nozzle hole, and the electrical connection pins to the chip into a single assembly, and through an integral manufacturing process To be manufactured.
为了实现上述目的,本发明提供了一种喷墨头组件的制造方法,其步骤包含:In order to achieve the above object, the present invention provides a method for manufacturing an inkjet head assembly, the steps of which include:
提供一基材(substrate);providing a substrate;
在所述基材表面形成一牺牲层(sacrificial layer);forming a sacrificial layer on the surface of the substrate;
在所述牺牲层表面形成一金属导电线路;forming a metal conductive line on the surface of the sacrificial layer;
在所述金属导电线路表面形成一第一感光性聚合物层;forming a first photosensitive polymer layer on the surface of the metal conductive circuit;
以光刻法(photolithography)在所述第一感光性聚合物层形成一个以上的喷孔及一个以上的通孔,所述喷孔提供流体通过,所述通孔用以露出该金属导电线路的一引脚端;Forming more than one spray hole and more than one through hole in the first photosensitive polymer layer by photolithography, the spray hole provides fluid passage, and the through hole is used to expose the metal conductive circuit a pin terminal;
具有一个以上储墨室的一流体结构的步骤,所述储墨室对应并连接于所述喷孔;及the step of having a fluid structure with more than one ink storage chamber corresponding to and connected to the nozzle hole; and
去除所述牺牲层,使所述感光性聚合物层与其所附着的所述金属导电线路脱离所述基材。The sacrificial layer is removed to separate the photosensitive polymer layer and the metal conductive lines attached thereto from the substrate.
上述的喷墨头组件的制造方法,其特点在于,在所述牺牲层上方形成一金属导电线路的步骤,是以电铸(electroforming)的方法形成所述金属导电线路。The above-mentioned manufacturing method of the inkjet head assembly is characterized in that the step of forming a metal conductive circuit on the sacrificial layer is to form the metal conductive circuit by electroforming.
上述的喷墨头组件的制造方法,其特点在于,所述牺牲层由非金属材料所形成,并在所述牺牲层上方形成一金属导电线路的步骤之前,还包含一在所述牺牲层表面形成一电铸种子层(seed layer)的步骤。The method for manufacturing the above-mentioned inkjet head assembly is characterized in that the sacrificial layer is formed of non-metallic material, and before the step of forming a metal conductive circuit on the sacrificial layer, it also includes a A step of forming an electroformed seed layer.
上述的喷墨头组件的制造方法,其特点在于,在所述牺牲层上方形成一金属导电线路的步骤,是先在所述牺牲层上方形成一金属层,再配合光刻法蚀刻所述金属层以形成所述金属导电线路。The above-mentioned manufacturing method of the inkjet head assembly is characterized in that the step of forming a metal conductive circuit above the sacrificial layer is to first form a metal layer above the sacrificial layer, and then cooperate with photolithography to etch the metal. layer to form the metal conductive lines.
上述的喷墨头组件的制造方法,其特点在于,所述形成具有一个以上储墨室的一流体结构的步骤,是在所述第一感光性聚合物层表面形成一第二感光性聚合物层,并以光刻法形成所述流体结构。The above-mentioned manufacturing method of the inkjet head assembly is characterized in that the step of forming a fluid structure having more than one ink storage chamber is to form a second photosensitive polymer on the surface of the first photosensitive polymer layer layer, and form the fluid structure by photolithography.
上述的喷墨头组件的制造方法,其特点在于,还包含一在所述金属导电线路表面形成一保护层的步骤。The above-mentioned manufacturing method of the inkjet head assembly is characterized in that it further includes a step of forming a protective layer on the surface of the metal conductive circuit.
上述的喷墨头组件的制造方法,其特点在于,所述牺牲层由金属材料所形成。The method for manufacturing the above-mentioned inkjet head assembly is characterized in that the sacrificial layer is formed of a metal material.
本发明还提供一种喷墨头组件,其包含:The present invention also provides an inkjet head assembly comprising:
一感光性聚合物层基材,其具有一个以上的喷孔以提供流体通过,所述喷孔以光刻法形成;A photosensitive polymer layer substrate, which has more than one orifice to provide fluid passage, and the orifice is formed by photolithography;
一金属导电线路,设于所述感光性聚合物层基材表面,所述金属导电线路具有一前端与一引脚端,所述前端用来接收外部讯号,所述引脚端则用以提供与一芯片的电性连接,所述引脚端外露于所述感光性聚合物层基材;及A metal conductive circuit is arranged on the surface of the photosensitive polymer layer substrate, the metal conductive circuit has a front end and a pin end, the front end is used to receive external signals, and the pin end is used to provide an electrical connection to a chip, the pin ends being exposed on the photopolymer layer substrate; and
一流体结构,其结合于所述感光性聚合物层基材,所述流体结构具有一个以上的储墨室,所述储墨室对应并连接于所述喷孔。A fluid structure, which is combined with the base material of the photosensitive polymer layer, the fluid structure has more than one ink storage chamber, and the ink storage chamber corresponds to and connects with the nozzle hole.
上述的喷墨头组件,其特点在于,所述流体结构还包含一个以上的流道,所述流道用以提供墨水至所述储墨室。The above-mentioned inkjet head assembly is characterized in that the fluid structure further includes more than one flow channel, and the flow channel is used to supply ink to the ink storage chamber.
上述的喷墨头组件,其特点在于,还包含一在所述金属导电线路表面形成一保护层The above-mentioned inkjet head assembly is characterized in that it also includes a protective layer formed on the surface of the metal conductive circuit
以下结合附图和具体实施例对本发明进行详细描述,但不作为对本发明的限定。The present invention will be described in detail below in conjunction with the accompanying drawings and specific embodiments, but not as a limitation of the present invention.
附图说明Description of drawings
图1~图7为本发明第一实施例的制作流程图;及1 to 7 are the production flow charts of the first embodiment of the present invention; and
图8~图11为本发明第二实施例的制作流程图。8 to 11 are the production flowcharts of the second embodiment of the present invention.
具体实施方式Detailed ways
本发明所揭露的喷墨头组件及其制造方法,可以混合利用曝光、显影和电铸等方式,制作出整合性的喷墨头组件。The inkjet head assembly disclosed in the present invention and its manufacturing method can be combined with exposure, development and electroforming to produce an integrated inkjet head assembly.
请参考图1至图7,其为本发明第一实施例的制作流程图。Please refer to FIG. 1 to FIG. 7 , which are the production flowcharts of the first embodiment of the present invention.
如图1所示,首先,在基材100的表面沉积金属牺牲层110。所谓牺牲层即结构制作时使其他层分开的材料。As shown in FIG. 1 , firstly, a metal
如图2所示,然后在牺牲层110表面制出光阻层(photoresist)120。As shown in FIG. 2 , a photoresist layer (photoresist) 120 is formed on the surface of the
如图3所示,以电铸方式在金属牺牲层110上方的光阻层120的间隙中形成金属导电线路130。As shown in FIG. 3 , a metal
如图4所示,在金属导电线路130上方涂布一感光性聚合物层140,并以光刻法制出喷孔及露出金属导电线路引脚端的通孔,以作为金属导电线路130对外的电性连接处。光罩200分为透光与不透光区域,不透光区域可以阻隔光线通过,透光区域则提供光线通过,照射于感旋光性聚合物层140的部分区域使其产生链接。以适当的光源通过光罩200对感旋光性聚合物层140加以曝光之后,即制出喷孔及露出金属导电线路引脚端的通孔。As shown in Figure 4, a
接着,如图5所示,显影感光性聚合物层140的曝光图案,以形成喷孔及露出金属导电线路引脚端的通孔。Next, as shown in FIG. 5 , the exposure pattern of the
如图6所示,去除金属牺牲层110和电铸金属时所使用的光阻层,使金属导电线路130及感光性聚合物层140脱离基材100形成具有喷孔的软性电路板,以上述的方法,即可迅速地制作出喷墨头芯片所需封装的组件,该组件包含数个喷孔与金属导电线路,可以取代原先的喷孔片与卷带式自动封装片。As shown in Figure 6, the photoresist layer used when removing the metal
以及,如图7所示,也可在去除电铸金属时所使用的光阻层之前,将软性电路板翻转过来,利用光刻法在金属导电线路130的表面形成保护层150,再在显影保护层150图案的同时去除电铸金属时所使用的光阻层。And, as shown in FIG. 7 , before removing the photoresist layer used for electroforming metal, the flexible circuit board can be turned over, and the
其中,本发明第一实施例的金属牺牲层也可使用其它材质的牺牲层来取代,但在以电铸方式形成金属导电线路时,需预先在牺牲层的表面形成金属种子层(seed layer),以利于后续的电铸制程。或者也可直接使用光刻法来制作金属导电线路,先沉积金属层在牺牲层表面,再进行光阻涂布、曝光、显影和蚀刻等步骤来形成金属导电线路。Wherein, the metal sacrificial layer in the first embodiment of the present invention can also be replaced by a sacrificial layer of other materials, but when forming a metal conductive circuit by electroforming, a metal seed layer (seed layer) needs to be formed on the surface of the sacrificial layer in advance. , to facilitate the subsequent electroforming process. Alternatively, photolithography can be used directly to fabricate metal conductive lines. Firstly, a metal layer is deposited on the surface of the sacrificial layer, and then steps such as photoresist coating, exposure, development and etching are performed to form metal conductive lines.
另外,本发明还包含将储墨室以及流道整合于具有喷孔的软性电路板结构。In addition, the present invention also includes integrating the ink storage chamber and the flow channel into the structure of the flexible circuit board with spray holes.
请参考图8至图11,其为本发明第二实施例的制作流程图。Please refer to FIG. 8 to FIG. 11 , which are the production flowcharts of the second embodiment of the present invention.
首先其步骤如同第一实施例的图1至图4,首先,在基材的表面沉积金属牺牲层之后;在牺牲层表面制造出光阻层;再以电铸方式在金属牺牲层上方形成金属导电线路。并在金属导电线路上方涂布一第一感光性聚合物层,以适当的光源通过光罩对第一感旋光性聚合物层加以曝光之后,即制造出喷孔及露出金属导电线路引脚端的通孔。First, the steps are the same as those shown in Figures 1 to 4 of the first embodiment. First, after depositing a metal sacrificial layer on the surface of the substrate; a photoresist layer is produced on the surface of the sacrificial layer; line. And coating a first photosensitive polymer layer on the metal conductive circuit, after exposing the first photosensitive polymer layer through a photomask with a suitable light source, the nozzle holes and the pin ends of the exposed metal conductive circuit are produced. through hole.
然后,如图8所示,再在制造完成的第一感旋光性聚合物层140表面形成第二感光性聚合物层141,并利用适当的光罩200曝光第二层感光性聚合物层141以制造出储墨室和流道等流体结构。Then, as shown in FIG. 8 , form a second
接着,如图9所示,显影第二感光性聚合物层141与第一感光性聚合物层140的曝光图案,以形成喷孔、露出金属导电线路引脚端的通孔、储墨室和流道等流体结构。Next, as shown in FIG. 9, the exposure patterns of the second
如图10所示,去除金属牺牲层110和电铸金属时所使用的光阻层,使金属导电线路130、第一感光性聚合物层140及第二感光性聚合物层141皆脱离基材100以形成具有喷孔、储墨室和流道的软性电路板。As shown in FIG. 10 , the metal
以及,如图11所示,也可在去除电铸金属时所使用的光阻层之前,将软性电路板翻转过来,利用光刻法在金属导电线路130的表面形成保护层151,再在显影保护层151图案时,一起去除电铸金属时所使用的光阻层,保护层151形成于金属导电线路130附着第一感光性聚合物层140的表面之外的另一表面。And, as shown in FIG. 11 , before removing the photoresist layer used in electroforming metal, the flexible circuit board can be turned over, and a
本发明是通过光刻技术来制作喷孔,其圆度及厚度皆可随意控制,并且圆度及厚度的质量都远优于传统技术,仅需改变光罩就可以做出不规则的喷孔。将喷孔与储墨室整合在软性电路板以形成单一组件,可以有效降低成本,不需额外制造喷孔片与在芯片上形成储墨室,同时,软性电路板的基材、喷孔、储墨室可在同一个制作平台上,使用同样的制造方法,快速且精准的完成。The invention uses photolithography technology to make the nozzle hole, and its roundness and thickness can be controlled at will, and the quality of the roundness and thickness is far superior to the traditional technology, and the irregular nozzle hole can be made only by changing the photomask . Integrating the orifice and the ink storage chamber in the flexible circuit board to form a single component can effectively reduce the cost, and there is no need to additionally manufacture the orifice sheet and form the ink storage chamber on the chip. At the same time, the substrate of the flexible circuit board, the inkjet Holes and ink storage chambers can be quickly and accurately completed on the same manufacturing platform and using the same manufacturing method.
当然,本发明还可有其它多种实施例,在不背离本发明精神及其实质的情况下,器件的结构可以经过进一步的改进,但这些相应的改变都应属于本发明所附的权利要求的保护范围。Of course, the present invention can also have other various embodiments, and the structure of the device can be further improved without departing from the spirit and essence of the present invention, but these corresponding changes should all belong to the appended claims of the present invention scope of protection.
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| US10821729B2 (en) | 2013-02-28 | 2020-11-03 | Hewlett-Packard Development Company, L.P. | Transfer molded fluid flow structure |
| EP2961612B1 (en) | 2013-02-28 | 2019-08-07 | Hewlett-Packard Development Company, L.P. | Molding a fluid flow structure |
| CN107901609B (en) | 2013-02-28 | 2020-08-28 | 惠普发展公司,有限责任合伙企业 | Fluid flow structure and printhead |
| CN105189122B (en) | 2013-03-20 | 2017-05-10 | 惠普发展公司,有限责任合伙企业 | Molded die slivers with exposed front and back surfaces |
| TWI572494B (en) * | 2013-07-29 | 2017-03-01 | 惠普發展公司有限責任合夥企業 | Fluid flow structure and method of manufacturing fluid passage in fluid flow structure |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04120791A (en) * | 1990-09-12 | 1992-04-21 | Hitachi Chem Co Ltd | Manufacture of multilayer printer circuit board |
| JPH0537128A (en) * | 1991-07-30 | 1993-02-12 | Casio Comput Co Ltd | Wiring board manufacturing method |
| US5305015A (en) * | 1990-08-16 | 1994-04-19 | Hewlett-Packard Company | Laser ablated nozzle member for inkjet printhead |
-
2003
- 2003-09-10 CN CNB03156769XA patent/CN1302930C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5305015A (en) * | 1990-08-16 | 1994-04-19 | Hewlett-Packard Company | Laser ablated nozzle member for inkjet printhead |
| JPH04120791A (en) * | 1990-09-12 | 1992-04-21 | Hitachi Chem Co Ltd | Manufacture of multilayer printer circuit board |
| JPH0537128A (en) * | 1991-07-30 | 1993-02-12 | Casio Comput Co Ltd | Wiring board manufacturing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1593924A (en) | 2005-03-16 |
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