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CN1302828C - Apparatus for heat recoverin multigrade flash desalting of sea water - Google Patents

Apparatus for heat recoverin multigrade flash desalting of sea water Download PDF

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Publication number
CN1302828C
CN1302828C CNB2005100428405A CN200510042840A CN1302828C CN 1302828 C CN1302828 C CN 1302828C CN B2005100428405 A CNB2005100428405 A CN B2005100428405A CN 200510042840 A CN200510042840 A CN 200510042840A CN 1302828 C CN1302828 C CN 1302828C
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flash
flash chamber
section
pipeline
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CN1724394A (en
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严俊杰
王金华
邵树峰
刘继平
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Xian Jiaotong University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/124Water desalination
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

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Abstract

回热型多级闪蒸海水淡化装置,包括热排放段循环盐水管道、相互连通的若干组热回收段闪蒸室和热排放段闪蒸室,热排放段循环盐水管道自热排放段闪蒸室的上端穿过,热排放段循环盐水管道的出口与热排放段末级闪蒸室的底端相连通,且上一级热排放段闪蒸室的蒸汽出口与下一级热排放段闪蒸室下端相连通,热排放段末级闪蒸室底部的闪蒸盐水与穿过热回收段闪蒸室上端的设置有冷凝管的热回收段循环盐水管道相连通,热回收段循环盐水管道的管路上还设置有盐水加热器,自热回收段循环盐水管道出来的循环盐水经盐水加热器加热后与热回收段闪蒸室的第一级闪蒸室下部相连通,且上一级热回收段闪蒸室的蒸汽出口通过管路与下一级热回收段闪蒸室下端相连通。

Figure 200510042840

The heat recovery type multi-stage flash seawater desalination device includes circulating brine pipelines in the heat discharge section, several sets of interconnected flash chambers in the heat recovery section and flash chambers in the heat discharge section, and the circulating brine pipeline in the heat discharge section is flashed from the heat discharge section. The upper end of the chamber passes through, the outlet of the circulating brine pipeline in the heat discharge section is connected to the bottom end of the final flash chamber in the heat discharge section, and the steam outlet of the flash chamber in the upper heat discharge section is connected to the flash chamber in the next heat discharge section. The lower end of the steaming chamber is connected, and the flash brine at the bottom of the final flash chamber of the heat discharge section is connected with the circulating brine pipeline of the heat recovery section provided with a condenser through the upper end of the flash chamber of the heat recovery section, and the circulating brine pipeline of the heat recovery section is A brine heater is also installed on the pipeline, and the circulating brine coming out of the circulating brine pipeline in the heat recovery section is heated by the brine heater and then communicated with the lower part of the first-stage flash chamber of the heat recovery section flash chamber, and the upper stage heat recovery The steam outlet of the flash chamber of the first stage is connected with the lower end of the flash chamber of the next heat recovery stage through pipelines.

Figure 200510042840

Description

回热型多级闪蒸海水淡化装置Regeneration type multi-stage flash seawater desalination device

技术领域technical field

本发明属于水、废水、污水或污泥的处理技术领域,具体涉及一种热能多次回收利用的回热型多级闪蒸海水淡化装置。The invention belongs to the technical field of water, waste water, sewage or sludge treatment, and in particular relates to a recuperating type multi-stage flash seawater desalination device for multiple recovery and utilization of heat energy.

背景技术Background technique

多级闪蒸海水淡化系统是使热盐水依次流经若干个压力逐渐降低的闪蒸室,由于此时环境压力低于热盐水的温度所对应的饱和蒸汽压,热盐水急速地部分汽化,产生蒸汽,经冷凝而变成淡水。它具有设备简单可靠、易于大型化、操作弹性大以及可利用低位热能和废热等优点,具有广泛的应用前景。但在实际应用中,由于闪蒸蒸汽释放的潜热全部用来加热本级冷凝管内的循环盐水,因此现有的多级闪蒸海水淡化系统存在装置造水比偏小和各级闪蒸盐水浓度过高的问题。装置造水比偏小,将削弱系统的热经济性;各级闪蒸盐水浓度过高,将加剧系统的腐蚀和结垢,影响系统运行的安全性。The multi-stage flash seawater desalination system is to make the hot brine flow through several flash chambers in which the pressure is gradually reduced. Since the ambient pressure is lower than the saturated vapor pressure corresponding to the temperature of the hot brine, the hot brine is rapidly partially vaporized, resulting in Steam, condensed into fresh water. It has the advantages of simple and reliable equipment, easy large-scale operation, high operating flexibility, and the ability to utilize low-level heat energy and waste heat, etc., and has broad application prospects. However, in practical applications, since the latent heat released by the flash steam is all used to heat the circulating brine in the condensation pipe of the current stage, the existing multi-stage flash seawater desalination system has a relatively small water production ratio and a low concentration of flash brine at each stage. Too high a problem. If the water production ratio of the device is too small, the thermal economy of the system will be weakened; if the concentration of flash brine at each level is too high, the corrosion and scaling of the system will be aggravated, which will affect the safety of system operation.

发明内容Contents of the invention

本发明的目的在于克服上述现有技术的缺点,提供了一种能够提高系统的造水比,降低系统的各级闪蒸盐水浓度,且可以避免由于补充水温度变化导致的造水比下降,从而使系统产水量更加稳定、可靠的回热型多级闪蒸海水淡化装置。The purpose of the present invention is to overcome the shortcomings of the above-mentioned prior art, to provide a system that can increase the water production ratio, reduce the concentration of flash brine at all levels of the system, and avoid the decrease of the water production ratio caused by the temperature change of the supplementary water. Thereby making the water production of the system more stable and reliable regenerative multi-stage flash seawater desalination device.

为达到上述目的,本发明采用的技术方案是:包括热排放段循环盐水管道、以及相互连通的若干组带有冷凝管和淡水槽的热回收段闪蒸室和热排放段闪蒸室,其特点是,热排放段循环盐水管道与凝汽器相连通并自热排放段闪蒸室的上端穿过,热排放段循环盐水管道的出口与热排放段末级闪蒸室的底端相连通,且上一级热排放段闪蒸室的蒸汽出口通过管路与下一级热排放段闪蒸室下端相连通,热排放段末级闪蒸室底部的闪蒸盐水通过盐水循环泵与穿过热回收段闪蒸室上端的设置有冷凝管的热回收段循环盐水管道相连通,热回收段循环盐水管道的管路上还设置有盐水加热器,自热回收段循环盐水管道出来的循环盐水经盐水加热器加热后与热回收段闪蒸室的第一级闪蒸室下部相连通,且上一级热回收段闪蒸室的蒸汽出口通过管路与下一级热回收段闪蒸室下端相连通。In order to achieve the above-mentioned purpose, the technical solution adopted by the present invention is: comprising heat discharge section circulating brine pipeline, and several groups of interconnected heat recovery section flash chambers and heat discharge section flash chambers with condensing pipes and fresh water tanks. The characteristic is that the circulating brine pipeline in the heat discharge section is connected with the condenser and passes through the upper end of the flash chamber in the heat discharge section, and the outlet of the circulating brine pipeline in the heat discharge section is connected with the bottom end of the final flash chamber in the heat discharge section , and the steam outlet of the flash chamber of the upper heat discharge section is connected to the lower end of the flash chamber of the next heat discharge section through a pipeline, and the flash brine at the bottom of the flash chamber of the final stage of the heat discharge section is connected to The upper end of the flash chamber in the superheat recovery section is connected to the circulating brine pipeline in the heat recovery section with a condensing pipe. A brine heater is also installed on the pipeline of the circulating brine pipeline in the heat recovery section. The circulating brine coming out of the circulating brine pipeline in the heat recovery section passes through After the brine heater is heated, it is connected to the lower part of the first-stage flash chamber of the heat recovery section flash chamber, and the steam outlet of the upper-stage heat recovery section flash chamber is connected to the lower end of the next-stage heat recovery section flash chamber through the pipeline. connected.

本发明的另一特点是:淡水槽的出口处还设置有产品水泵;热排放段末级闪蒸室的底端还设置有一与盐水排污泵相连接的盐水排污泵;热回收段闪蒸室及热排放段闪蒸室的下端闪蒸盐水中还设置有面式加热器;热回收段闪蒸室及热排放段闪蒸室内淡水槽的下端还设置有丝网除沬器。Another feature of the present invention is: the outlet of the fresh water tank is also provided with a product water pump; the bottom of the final flash chamber in the heat discharge section is also provided with a brine sewage pump connected with the brine sewage pump; the heat recovery section flash chamber There is also a surface heater in the flash brine at the lower end of the flash chamber of the heat discharge section; a wire mesh defoamer is also provided at the lower end of the fresh water tank in the flash chamber of the heat recovery section and the flash chamber of the heat discharge section.

本发明在现有多级闪蒸海水淡化系统的基础上,将各级闪蒸室中闪蒸出的二次蒸汽的一部分引到下一级闪蒸室中用来加热闪蒸盐水,同时以电厂凝汽器循环海水代替原海水作为系统补充水,从而提高系统的造水比,降低系统的各级闪蒸盐水浓度,且可以避免由于补充水温度变化导致造水比下降的缺点,从而使系统产水量更加稳定、可靠。On the basis of the existing multi-stage flash seawater desalination system, the present invention introduces part of the secondary steam flashed out of the flash chambers of each stage to the next stage flash chamber to heat the flash brine, and at the same time The circulating seawater in the condenser of the power plant replaces the original seawater as the supplementary water of the system, thereby increasing the water production ratio of the system, reducing the flash brine concentration at all levels of the system, and avoiding the disadvantage of the decrease in the water production ratio due to the temperature change of the supplementary water, so that The water production of the system is more stable and reliable.

附图说明Description of drawings

图1是本发明的系统示意图;Fig. 1 is a schematic diagram of the system of the present invention;

图2是本发明闪蒸室的结构示意图。Fig. 2 is a structural schematic diagram of the flash chamber of the present invention.

具体实施方式Detailed ways

下面结合附图对本发明的结构原理和工作原理作进一步详细说明。The structural principle and working principle of the present invention will be further described in detail below in conjunction with the accompanying drawings.

参见图1,2,本发明包括入口与凝汽器11相连接的热排放段循环盐水管道12,热排放段循环盐水管道12自热排放段闪蒸室2的上端穿过,且在热排放段闪蒸室2内的循环盐水管道12上还分别设置有冷凝器3,热排放段循环盐水管道12的出口与热排放段末级闪蒸室2-1的底端相连通,且上一级热排放段闪蒸室2的蒸汽出口通过管路与下一级热排放段闪蒸室2下端相连通,热排放段末级闪蒸室2-1底部的闪蒸盐水通过盐水循环泵6与穿过热回收段闪蒸室1上端的设置有冷凝管3-1的热回收段循环盐水管道13相连通,且在热排放段末级闪蒸室2-1的底端还设置有一与盐水排污泵相连接的盐水排污泵5,热回收段循环盐水管道13的出口管路上还设置有盐水加热器9,自热回收段循环盐水管道13出来的循环盐水经盐水加热器9加热后与热回收段闪蒸室1的第一级闪蒸室下部相连通,热回收段闪蒸室1及热排放段闪蒸室2的下端闪蒸盐水中还设置有面式加热器7,且上一级热回收段闪蒸室1的蒸汽出口通过管路与下一级热回收段闪蒸室的下端相连通,且在各热回收段闪蒸室1与热排放段闪蒸室2内还设置有与产品水泵4相连通的淡水槽10,在淡水槽10的下端还设置有丝网除沫器8。Referring to Fig. 1, 2, the present invention includes the heat discharge section circulation brine pipeline 12 that the inlet is connected with the condenser 11, the heat discharge section circulation brine pipeline 12 passes through the upper end of the heat discharge section flash chamber 2, and in the heat discharge section Condensers 3 are also respectively arranged on the circulating brine pipeline 12 in the section flash chamber 2, and the outlet of the circulating brine pipeline 12 in the heat discharge section is connected with the bottom end of the final stage flash chamber 2-1 in the heat discharge section, and the upper The steam outlet of the flash chamber 2 in the heat discharge section of the first stage is connected to the lower end of the flash chamber 2 of the next heat discharge section through a pipeline, and the flash brine at the bottom of the flash chamber 2-1 in the final stage of the heat discharge section passes through the brine circulation pump 6 It communicates with the circulating brine pipeline 13 of the heat recovery section provided with a condensation pipe 3-1 passing through the upper end of the flash chamber 1 of the heat recovery section, and is also provided with a brine at the bottom of the final flash chamber 2-1 of the heat discharge section. The brine sewage pump 5 connected to the sewage pump is also provided with a brine heater 9 on the outlet pipeline of the circulating brine pipeline 13 in the heat recovery section. The lower part of the first-stage flash chamber of the recovery section flash chamber 1 is connected, and a surface heater 7 is also arranged in the flash brine at the lower end of the heat recovery section flash chamber 1 and the heat discharge section flash chamber 2, and the upper one The steam outlet of the flash chamber 1 of the first-stage heat recovery section is connected to the lower end of the flash chamber of the next heat recovery section through a pipeline, and there are also set in the flash chamber 1 of each heat recovery section and the flash chamber 2 of the heat discharge section There is a fresh water tank 10 communicated with the product water pump 4, and a wire mesh demister 8 is also arranged at the lower end of the fresh water tank 10.

在热排放段闪蒸室2,供热机组凝汽器11的循环海水首先通过热排放段循环盐水管道12经冷凝管3用来冷凝热排放段闪蒸室2里产生的一部分闪蒸蒸汽,同时循环海水被加热,另一部分热排放段闪蒸室2内的闪蒸蒸汽被引到下一级热排放段闪蒸室2中通过面式加热器7换热来加热闪蒸盐水,并冷凝为产品淡水。从热排放段闪蒸室2出来的海水一部分返回大海,另外部分经加酸、加防泡剂后与热排放段末级闪蒸室2-1内的闪蒸盐水混合,经盐水循环泵6送入穿过热回收段闪蒸室1的热回收段循环盐水管道13,依次冷凝各热回收段闪蒸室1内闪蒸出的一部分蒸汽,同样,另一部分闪蒸蒸汽经管道被引到下一级闪蒸室中用来加热闪蒸盐水。循环盐水回收闪蒸蒸汽的部分热量后,进入盐水加热器9,进一步被加热,达到工艺要求的最高温度,然后进入热回收段第一级闪蒸室下部,由于此时其温度大于第一级闪蒸室真空对应的饱和温度,闪蒸盐水开始闪蒸,闪蒸出的蒸汽向上经丝网除沫器8除去盐水滴和泡沫后进入冷凝区冷凝成产品淡水。以后逐级重复上述过程至最末一级,一部分闪蒸盐水被盐水排污泵5排放,产品淡水被产品水泵4送入产品水箱。In the flash chamber 2 of the heat discharge section, the circulating seawater of the condenser 11 of the heat supply unit first passes through the circulating brine pipeline 12 of the heat discharge section through the condenser pipe 3 to condense a part of the flash steam generated in the flash chamber 2 of the heat discharge section, At the same time, the circulating seawater is heated, and another part of the flash steam in the flash chamber 2 of the heat discharge section is led to the flash chamber 2 of the next heat discharge section to exchange heat with the surface heater 7 to heat the flash brine and condense it. Fresh water for the product. Part of the seawater coming out of the flash chamber 2 in the heat discharge section returns to the sea, and the other part is mixed with the flash brine in the final flash chamber 2-1 of the heat discharge section after adding acid and antifoaming agent, and passed through the brine circulation pump 6 It is fed into the circulating brine pipeline 13 of the heat recovery section through the flash chamber 1 of the heat recovery section, and sequentially condenses part of the steam flashed out of the flash chamber 1 of each heat recovery section. Similarly, another part of the flash steam is led to the lower The primary flash chamber is used to heat the flash brine. After the circulating brine recovers part of the heat of the flash steam, it enters the brine heater 9 and is further heated to reach the maximum temperature required by the process, and then enters the lower part of the first-stage flash chamber in the heat recovery section, because its temperature is higher than that of the first-stage At the saturation temperature corresponding to the vacuum in the flash chamber, the flash brine begins to flash, and the flash steam goes upward through the wire mesh demister 8 to remove brine droplets and foam, and then enters the condensation zone to condense into product fresh water. Repeat the above process step by step to the last stage, a part of the flash salt water is discharged by the salt water sewage pump 5, and the product fresh water is sent into the product water tank by the product water pump 4.

本发明将各级闪蒸室中闪蒸出的二次蒸汽的一部分引到下一级闪蒸室中用来加热闪蒸盐水,根据质量、动量、能量守恒原理,装置的造水比明显增大。In the present invention, part of the secondary steam flashed out of the flash chambers of each level is led to the next level of flash chambers to heat flash brine. According to the principle of conservation of mass, momentum and energy, the water production ratio of the device is significantly increased. big.

Claims (5)

1, apparatus for heat recoverin multigrade flash desalting of sea water, comprise heat-discharging section circulating brine pipeline [12], and some groups of heat-recovery section flash chamber [1] and the heat-discharging section flash chambers [2] that have condenser pipe [3] and fresh-water tank [10] that are interconnected, it is characterized in that: heat-discharging section circulating brine pipeline [12] is connected with condenser [11] and passes from the upper end of heat-discharging section flash chamber [2], the outlet of heat-discharging section circulating brine pipeline [12] is connected with the bottom of heat-discharging section final stage flash chamber [2-1], and the steam (vapor) outlet of upper level heat-discharging section flash chamber [2] is connected with next stage heat-discharging section flash chamber [2] lower end by pipeline, the flash distillation salt solution of heat-discharging section final stage flash chamber [2-1] bottom is connected with the heat-recovery section circulating brine pipeline [13] that is provided with condenser pipe [3-1] that passes heat-recovery section flash chamber [1] upper end by salt water circulating pump [6], also be provided with brine heater [9] on the pipeline of heat-recovery section circulating brine pipeline [13], be connected with the first order flash chamber bottom of heat-recovery section flash chamber [1] after brine heater [9] heating from the circulating brine that heat-recovery section circulating brine pipeline [13] comes out, and the steam (vapor) outlet of upper level heat-recovery section flash chamber [1] is connected with next stage heat-recovery section flash chamber [1] lower end by pipeline.
2, apparatus for heat recoverin multigrade flash desalting of sea water according to claim 1 is characterized in that: the exit of said fresh-water tank [10] also is provided with product water pump [4].
3, apparatus for heat recoverin multigrade flash desalting of sea water according to claim 1 is characterized in that: the bottom of said heat-discharging section final stage flash chamber [2-1] also is provided with a salt solution dredge pump [5] that is connected with the salt solution dredge pump.
4, apparatus for heat recoverin multigrade flash desalting of sea water according to claim 1 is characterized in that: also be provided with face formula heater [7] in the lower end flash distillation salt solution of said heat-recovery section flash chamber [1] and heat-discharging section flash chamber [2].
5, apparatus for heat recoverin multigrade flash desalting of sea water according to claim 1 is characterized in that: the lower end of said heat-recovery section flash chamber [1] and the interior fresh-water tank of heat-discharging section flash chamber [2] [10] also is provided with Si Wang Chu Droplets device [8].
CNB2005100428405A 2005-06-23 2005-06-23 Apparatus for heat recoverin multigrade flash desalting of sea water Expired - Fee Related CN1302828C (en)

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