CN1391447A - Shoe linings for the shoe industry - Google Patents
Shoe linings for the shoe industry Download PDFInfo
- Publication number
- CN1391447A CN1391447A CN00816037A CN00816037A CN1391447A CN 1391447 A CN1391447 A CN 1391447A CN 00816037 A CN00816037 A CN 00816037A CN 00816037 A CN00816037 A CN 00816037A CN 1391447 A CN1391447 A CN 1391447A
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- CN
- China
- Prior art keywords
- continuous monofilament
- footwear liner
- multicomponent
- shoe
- multicomponent continuous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/016—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the fineness
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B23/00—Uppers; Boot legs; Stiffeners; Other single parts of footwear
- A43B23/07—Linings therefor
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
- D04H3/011—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/10—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically
- D04H3/11—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between yarns or filaments made mechanically by fluid jet
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Woven Fabrics (AREA)
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
Description
技术领域technical field
本发明涉及一种用于制鞋业的鞋内衬以及一种制造该鞋内衬的方法。The present invention relates to a shoe lining for the shoe industry and a method of manufacturing the shoe lining.
背景技术Background technique
在制鞋业中应用一些用于对鞋的里边部分加衬的耐磨材料即所谓的鞋内衬。这些材料一方面应能有助于将脚汗形成的湿气向外传送,另一方面它们应能将脚的展开运动在鞋皮革上产生的力分布在大的范围上,以便这样来避免形成皱褶以及与此相关连的快速的穿坏。In the footwear industry some wear-resistant materials are used for lining the inner part of the shoe, so-called shoe linings. On the one hand, these materials should help to transport the moisture formed by foot sweat outwards, on the other hand, they should be able to distribute the forces generated by the foot's spreading movement on the shoe leather over a large area, so as to avoid forming Wrinkles and the associated rapid wear and tear.
为达此目的,迄今使用了热结合的和轧花砑光的聚酰胺无纺布、有纺织物外观和柔软手感的起毛的或梳理的针织物、起毛的织物、以聚氨基甲酸乙酯凝结物为基的合成皮革或天然原材料裂变皮革。For this purpose, thermally bonded and calendered polyamide nonwovens, raised or carded knitted fabrics, raised fabrics, coagulated with polyurethane Material-based synthetic leather or natural raw material fission leather.
发明内容Contents of the invention
本发明的任务是,提供一种用于制鞋业的鞋内衬,该鞋内衬在80~170g/m2的单位面积重量情况下在长和宽方向上均具有大于7N的抗撕裂和连续撕裂强度。The task of the present invention is to provide a shoe liner for the shoe industry, which has a tear resistance greater than 7N in the length and width directions at a weight per unit area of 80-170g/ m2 . and continuous tear strength.
本发明的另一任务是,提供一种特别用于制造这样一种鞋内衬的方法。A further object of the invention is to provide a method in particular for producing such a shoe lining.
根据本发明,这一任务是通过这样一种鞋内衬来解决的,它具有一个80~170g/m2的单位面积重量以及在长和宽方向上均大于7N的抗连续撕裂强度,其中该鞋内衬由热熔喷丝的、气动拉伸并直接排列成一纤维网的具有1.5~5dtex(分特克斯)纤度的多成分连续单丝组成,且该多成分连续单丝在经一预固化之后其中至少80%被分裂和固化成具有0.1~0.8dtex纤度的微连续单丝。该鞋内衬具有在较小的单位面积重量下高的抗拉性和耐磨性。对本发明所述的鞋内衬来说,由于是连续单位,因此还不需要贴边且不会出现纤维松散,从而也避免了接缝处的加厚以及由此可能产生的压力部位。According to the invention, this task is solved by such a kind of shoe inner liner, and it has a weight per unit area of 80~170g/m 2 and in length and width direction all greater than 7N continuous tear resistance, wherein The shoe lining is composed of multi-component continuous monofilaments with a fineness of 1.5-5 dtex (decentex) that are hot-melt-spun, pneumatically stretched and directly arranged into a fiber web, and the multi-component continuous monofilaments are passed through a After pre-curing, at least 80% of them are split and solidified into micro-continuous monofilaments with a denier of 0.1-0.8 dtex. The shoe inner liner has high tensile resistance and abrasion resistance with a small weight per unit area. For the shoe inner lining of the present invention, because it is a continuous unit, there is no need for welt and no fiber loosening, thereby also avoiding the thickening of the seam and the pressure part that may be generated thereby.
该鞋内衬优选地为这样一种内衬,其中的无纺布由热熔喷丝的、气动拉伸并直接排列成一纤维网的具有2~3dtex纤度的多成分连续单丝组成,且该多成分连续单丝可能情况下在经一预固化之后其中至少80%被分裂和固化成具有0.1~0.5dtex纤度的微连续单丝。该鞋内衬在其纤维网中具有一种各向同性的单丝分布。因此在裁剪鞋内衬时无需考虑机器的剪裁方向。The shoe inner liner is preferably such an inner liner, wherein the non-woven fabric is composed of hot-melt-spun, pneumatically stretched and directly arranged into a fiber web with multi-component continuous monofilaments with a fineness of 2 to 3 dtex, and the The multicomponent continuous monofilaments, possibly after a precure, at least 80% of them are split and solidified into microcontinuous monofilaments with a titer of 0.1 to 0.5 dtex. The shoe liner has an isotropic monofilament distribution in its fiber web. Therefore, it is not necessary to take into account the cutting direction of the machine when cutting the shoe lining.
该鞋内衬优选地为这样一种内衬,其中该多成分连续单丝为两种不相容的聚合物、尤其是一种聚酯(PES)和一种聚酰胺(PA)组成的双成分连续单丝。多成分连续单丝因此具有一种很好的抗折裂性以及一种很有利的强度与单位面积重量比。The shoe liner is preferably a liner in which the multicomponent continuous monofilament is a bilayer of two incompatible polymers, especially a polyester (PES) and a polyamide (PA). Constituent continuous monofilament. The multicomponent continuous monofilament thus has a very good resistance to breakage and a very favorable ratio of strength to weight per unit area.
该鞋内衬优选地为这样一种内衬,其中该多成分连续单丝具有一种橙子式的或者也称作为“馅饼”式的多扇形结构的截面,其中这些扇形交替地各自包含两不相容聚合物之中的一种。除了这种多成分连续单丝的橙子式多扇形结构外,也可在多成分连续单丝中采取一种不相容聚合物的“肩并肩”(S/S)或扇形配置方式,该配置方式优选地被用来制造鬈曲单丝。多成分连续单丝中不相容聚合物的这种扇形配置形式证明是能够十分好地被分裂的。该鞋内衬具有一个很有利的单位面积重量与绝缘性能比,这样尤其通过如起毛那样的后续处理工序便可制造出柔软和保暖的鞋内衬。The shoe liner is preferably a liner in which the multicomponent continuous monofilament has a cross-section of an orange or also called "pie" multi-segment structure, wherein the sectors alternately contain two One of the incompatible polymers. In addition to this orange multi-sector configuration of multicomponent continuous monofilaments, a "side-by-side" (S/S) or fan-shaped configuration of incompatible polymers in multicomponent continuous monofilaments is also possible. mode is preferably used to manufacture curly monofilaments. This fan-shaped arrangement of incompatible polymers in multicomponent continuous monofilaments proved to be very well splittable. The shoe liner has a very favorable ratio of weight per unit area to insulating properties, so that a soft and warm shoe liner can be produced, in particular through subsequent processing steps such as raising.
该鞋内衬优选地为这样一种内衬,其中由多成分连续单丝形成的无纺布被预砑光来进行预固化。该材料因此具有一种很好的厚度均匀性。The shoe innerliner is preferably an innerliner in which the nonwoven fabric formed from multicomponent continuous monofilaments is pre-calendered for pre-curing. The material thus has a very good thickness uniformity.
此外,作为鞋内衬优选地使用一种具有一纺织物外观和一耐磨表面的材料,该材料经高压水射流处理被保持在一个具有一定结构的和/或开口网眼的筛网基底上。In addition, a material with a textile appearance and a wear-resistant surface is preferably used as the shoe inner lining, which is held on a structured and/or open-mesh mesh substrate by high-pressure water jetting.
尤其优选的还有一种鞋内衬,其中构成为多成分连续单丝的不相容聚合物中的至少一种包含一种添加剂,例如颜料、恒久作用的抗静电剂和/或能影响亲水或疏水性质的添加剂,其添加剂量最多达15%的重量比。该鞋内衬为此在有关其耐晒性、带静电性倾向、脚汗的传送性以及湿气积聚性等方面均会产生积极的影响作用。此外,颜料添加到纺料中有助于制造出深度的和耐磨的颜色。Particularly preferred is also a shoe lining in which at least one of the incompatible polymers constituted as multicomponent continuous monofilaments contains an additive, such as a pigment, a permanent-acting antistatic agent and/or capable of affecting hydrophilicity. or additives of hydrophobic nature in amounts up to 15% by weight. For this purpose, the shoe lining has a positive influence with respect to its light fastness, tendency towards static charging, transport of perspiration and moisture accumulation. In addition, pigments are added to textiles to help create deep and wearable colours.
尤其优选的还有一种鞋内衬,其中多成分连续单丝是未被鬈曲的,因为这样由于能够很好地分裂成微连续单丝因而能保证织物的手感。Particularly preferred is also a shoe lining in which the multicomponent continuous monofilaments are not curled, since this ensures the hand of the fabric due to good splitting into micro-continuous monofilaments.
该鞋内衬优选地是这样一种内衬,其中两面中的一面被提供有一种热熔粘接剂涂敷层。这样一种材料尤其适用于用自动化机器的进一步处理。The shoe liner is preferably a liner in which one of the two sides is provided with a hot-melt adhesive coating. Such a material is especially suitable for further processing with automated machines.
根据本发明的用于制造该鞋内衬的方法步骤为:从熔液中喷纺多成分连续单丝,对其进行气动拉伸并直接排列成一纤维网,可能情况下经预砑光或针缝来进行预固化,且该无纺布用高压水射流来固化并同时被分裂成纤度为0.1~0.8dtex、优选地纤度为0.1~0.5dtex的微连续单丝。这样所得的产品其强度承载能力十分均匀,因为产品中具有一种广泛的各向同性纤丝分布。产品并不易于脱层且具有高弹性模量值和抗撕裂及连续撕裂性。此外,根据本发明的鞋内衬还具有很好的湿气传送性,这一性质在水蒸汽的传送和对湿鞋的干燥方面十分有利于提供鞋的舒适性。The steps of the method according to the invention for the manufacture of the shoe lining are: blow spinning multicomponent continuous monofilaments from a melt, pneumatically stretching them and arranging them directly into a web, possibly precalendered or needled The non-woven fabric is solidified by high-pressure water jets and simultaneously split into micro-continuous monofilaments with a fineness of 0.1-0.8 dtex, preferably a fineness of 0.1-0.5 dtex. The strength bearing capacity of the resulting product is very uniform due to a broad isotropic distribution of fibrils in the product. The product is not prone to delamination and has high elastic modulus values and resistance to tearing and continuous tearing. In addition, the shoe inner liner according to the present invention also has good moisture transport properties, which are very beneficial for providing shoe comfort in terms of water vapor transport and drying of wet shoes.
本方法的另一具有优点的实施例在于:多成分连续单丝的固化和分裂是这样来进行的:可能情况下被预固化了的无纺布每一面至少一次用高压水射流来加以冲击。多成分连续单丝的这种型式的固化和分裂能得到具有光滑表面的十分致密的无纺布。A further advantageous embodiment of the method consists in that the solidification and splitting of the multicomponent continuous filaments is carried out in such a way that the possibly precured nonwoven is impacted at least once per side with a high-pressure water jet. This type of solidification and splitting of the multicomponent continuous filaments results in a very dense nonwoven with a smooth surface.
最后的高压水射流处理优选地是在一个网眼宽度为5~50目的筛网基底上进行的。由此将衬底进一步固化,使之变得更耐磨并具有一种织物的外观。The final high-pressure water jet treatment is preferably carried out on a screen substrate with a mesh width of 5-50 mesh. This further cures the substrate, making it more wear resistant and having a textile appearance.
该浸渍的材料优选地还要经受诸如上色、滚光、抛光和/或预缩等后续处理。通过这些措施可更进一步改善所得材料的表面特性和手感。The impregnated material is preferably also subjected to subsequent treatments such as colouring, tumbling, polishing and/or shrinking. By means of these measures the surface properties and the hand feel of the resulting material can be further improved.
具体实施例specific embodiment
从一种PES-PA双成分连续单丝中制造一种具有110g/m2单位面积重量的单丝纱并对其两面交替地进行压力最高为280bar的水射流处理。这里水射流共在四个处理步骤上进行,其中第四个步骤是在一个20目的筛网基底上进行的。由此则产生一种具有一定结构的和/或成孔的表面,且该鞋内衬具有一种纺织品外观和柔软的手感。经该水射流后同时将输出单丝分裂成纤度小于0.2dtex的微单丝。由此产生的鞋内衬再经过喷射着色处理且可不考虑裁剪机器的走向而被加以应用。这样所得的鞋内衬具有下表所给出的强度参数,且十分适合于给定的应用目的。
Claims (13)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19960063.5 | 1999-12-13 | ||
| DE19960063A DE19960063C2 (en) | 1999-12-13 | 1999-12-13 | Lining for the shoe industry |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005100920692A Division CN1803042A (en) | 1999-12-13 | 2000-10-06 | Manufacturing of a lining for use in the footwear industry |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1391447A true CN1391447A (en) | 2003-01-15 |
Family
ID=7932474
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005100920692A Pending CN1803042A (en) | 1999-12-13 | 2000-10-06 | Manufacturing of a lining for use in the footwear industry |
| CN00816037A Pending CN1391447A (en) | 1999-12-13 | 2000-10-06 | Shoe linings for the shoe industry |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005100920692A Pending CN1803042A (en) | 1999-12-13 | 2000-10-06 | Manufacturing of a lining for use in the footwear industry |
Country Status (23)
| Country | Link |
|---|---|
| EP (1) | EP1237433B1 (en) |
| JP (1) | JP2003518965A (en) |
| KR (1) | KR20020070315A (en) |
| CN (2) | CN1803042A (en) |
| AT (1) | ATE271794T1 (en) |
| AU (1) | AU7915500A (en) |
| BG (1) | BG106820A (en) |
| BR (1) | BR0016318A (en) |
| CA (1) | CA2394700A1 (en) |
| CZ (1) | CZ20021937A3 (en) |
| DE (2) | DE19960063C2 (en) |
| ES (1) | ES2225234T3 (en) |
| HR (1) | HRP20020368A2 (en) |
| HU (1) | HUP0203530A2 (en) |
| MA (1) | MA25689A1 (en) |
| MX (1) | MXPA02004804A (en) |
| PL (1) | PL356845A1 (en) |
| RU (1) | RU2002119057A (en) |
| SK (1) | SK8282002A3 (en) |
| TR (1) | TR200201541T2 (en) |
| WO (1) | WO2001043575A1 (en) |
| YU (1) | YU34502A (en) |
| ZA (1) | ZA200204509B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101686896B1 (en) * | 2016-08-31 | 2016-12-15 | 허민수 | Shoes |
| KR102282838B1 (en) | 2021-05-17 | 2021-07-29 | (주)마이라텍스 | A method of manufacturing lining fabric for industrial materials using wool blended yarn, and fabric manufactured therefrom |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0090397B1 (en) * | 1982-03-31 | 1990-01-24 | Toray Industries, Inc. | Ultrafine fiber entangled sheet and method of producing the same |
| FR2546536B1 (en) * | 1983-05-25 | 1985-08-16 | Rhone Poulenc Fibres | PROCESS FOR THE TREATMENT OF NONWOVEN TABLECLOTHS AND PRODUCT OBTAINED |
| DE29602475U1 (en) * | 1996-02-13 | 1996-04-18 | Spielau, Paul, Dipl.-Chem. Dr., 53844 Troisdorf | Diffusion-open roofing membrane |
| FR2749860B1 (en) * | 1996-06-17 | 1998-08-28 | Freudenberg Spunweb Sa | NON WOVEN TABLECLOTH FORMED OF VERY THIN CONTINUOUS FILAMENTS |
| GB9626636D0 (en) * | 1996-12-21 | 1997-02-12 | British United Shoe Machinery | Lining material |
| JPH10212624A (en) * | 1997-01-27 | 1998-08-11 | Nippon Ester Co Ltd | Splittable conjugated fiber |
| DE19947870C1 (en) * | 1999-10-05 | 2001-05-10 | Freudenberg Carl Fa | Heel lining for the shoe industry |
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1999
- 1999-12-13 DE DE19960063A patent/DE19960063C2/en not_active Expired - Fee Related
-
2000
- 2000-10-06 HU HU0203530A patent/HUP0203530A2/en unknown
- 2000-10-06 AU AU79155/00A patent/AU7915500A/en not_active Abandoned
- 2000-10-06 KR KR1020027007381A patent/KR20020070315A/en not_active Abandoned
- 2000-10-06 CN CNA2005100920692A patent/CN1803042A/en active Pending
- 2000-10-06 AT AT00969441T patent/ATE271794T1/en not_active IP Right Cessation
- 2000-10-06 CA CA002394700A patent/CA2394700A1/en not_active Abandoned
- 2000-10-06 JP JP2001544522A patent/JP2003518965A/en active Pending
- 2000-10-06 HR HR20020368A patent/HRP20020368A2/en not_active Application Discontinuation
- 2000-10-06 RU RU2002119057/12A patent/RU2002119057A/en not_active Application Discontinuation
- 2000-10-06 YU YU34502A patent/YU34502A/en unknown
- 2000-10-06 MX MXPA02004804A patent/MXPA02004804A/en not_active Application Discontinuation
- 2000-10-06 SK SK828-2002A patent/SK8282002A3/en unknown
- 2000-10-06 TR TR2002/01541T patent/TR200201541T2/en unknown
- 2000-10-06 CZ CZ20021937A patent/CZ20021937A3/en unknown
- 2000-10-06 ES ES00969441T patent/ES2225234T3/en not_active Expired - Lifetime
- 2000-10-06 PL PL00356845A patent/PL356845A1/en unknown
- 2000-10-06 BR BR0016318-0A patent/BR0016318A/en not_active IP Right Cessation
- 2000-10-06 CN CN00816037A patent/CN1391447A/en active Pending
- 2000-10-06 DE DE50007231T patent/DE50007231D1/en not_active Expired - Fee Related
- 2000-10-06 EP EP00969441A patent/EP1237433B1/en not_active Expired - Lifetime
- 2000-10-06 WO PCT/EP2000/009805 patent/WO2001043575A1/en not_active Ceased
-
2002
- 2002-05-02 MA MA26623A patent/MA25689A1/en unknown
- 2002-06-05 ZA ZA200204509A patent/ZA200204509B/en unknown
- 2002-06-13 BG BG106820A patent/BG106820A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE50007231D1 (en) | 2004-09-02 |
| RU2002119057A (en) | 2004-01-10 |
| DE19960063C2 (en) | 2002-03-14 |
| YU34502A (en) | 2004-12-31 |
| HRP20020368A2 (en) | 2004-02-29 |
| KR20020070315A (en) | 2002-09-05 |
| MXPA02004804A (en) | 2003-10-14 |
| ZA200204509B (en) | 2004-01-28 |
| JP2003518965A (en) | 2003-06-17 |
| BG106820A (en) | 2003-01-31 |
| SK8282002A3 (en) | 2002-11-06 |
| EP1237433B1 (en) | 2004-07-28 |
| PL356845A1 (en) | 2004-07-12 |
| EP1237433A1 (en) | 2002-09-11 |
| CA2394700A1 (en) | 2001-06-21 |
| MA25689A1 (en) | 2003-04-01 |
| CZ20021937A3 (en) | 2002-08-14 |
| TR200201541T2 (en) | 2002-10-21 |
| WO2001043575A1 (en) | 2001-06-21 |
| HUP0203530A2 (en) | 2008-01-28 |
| BR0016318A (en) | 2002-08-20 |
| DE19960063A1 (en) | 2001-06-28 |
| AU7915500A (en) | 2001-06-25 |
| ES2225234T3 (en) | 2005-03-16 |
| ATE271794T1 (en) | 2004-08-15 |
| CN1803042A (en) | 2006-07-19 |
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