CN1389379A - Package and/or applicating device for cosmetic and care product, and preparation method for fiber thereof - Google Patents
Package and/or applicating device for cosmetic and care product, and preparation method for fiber thereof Download PDFInfo
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- CN1389379A CN1389379A CN02122482.XA CN02122482A CN1389379A CN 1389379 A CN1389379 A CN 1389379A CN 02122482 A CN02122482 A CN 02122482A CN 1389379 A CN1389379 A CN 1389379A
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/023—Bristles with at least a core and at least a partial sheath
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B13/00—Brushes with driven brush bodies or carriers
- A46B13/001—Cylindrical or annular brush bodies
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
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- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
- A46B2200/1046—Brush used for applying cosmetics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
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- Brushes (AREA)
- Cosmetics (AREA)
- Coating Apparatus (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Closures For Containers (AREA)
Abstract
本发明涉及一种用于化妆品或护理品的包装和/或涂布装置,该装置具有含有微粒的纤维,所述的微粒能够吸收液体或者在液体溶液中的化合物,或者可溶于液体中。
The invention relates to a packaging and/or application device for cosmetic or care products having fibers containing particles capable of absorbing a liquid or a compound in a liquid solution or soluble in a liquid.
Description
技术领域technical field
本发明涉及将一种物质,尤其是将化妆品或护理品涂布在皮肤上、头发上或者手指或脚趾指甲上。该化妆品是一种熟知的产品,如限定在1993年6月14日的Counsel的Directive 93/95/CEE上。The present invention relates to the application of a substance, in particular a cosmetic or care product, to the skin, hair or finger or toe nails. The cosmetic product is a known product as defined in Directive 93/95/CEE of Counsel of 14.06.1993.
本发明尤其涉及用于涂布物质或者物质中的填料的纤维。In particular the invention relates to fibers for coating substances or fillers in substances.
背景技术Background technique
需要一种纤维,尤其是用于构成刷子或植绒的纤维,该纤维能够吸收相对较大量的物质,例如以便使涂布器能够连续使用很长时间。There is a need for fibers, in particular for the construction of brushes or flocks, which are capable of absorbing relatively large quantities of substances, for example in order to enable applicators to be used continuously for long periods of time.
也需要一种用于睫毛油刷子的硬毛,该硬毛能够抓住眼睫毛,例如以便能清除睫毛表面的物质或者使睫毛弯曲。There is also a need for a bristle for a mascara brush that is able to grip the eyelashes, for example, so that they can remove material from the surface of the eyelashes or bend them.
还需要改进化妆品或护理品的保存。There is also a need to improve the preservation of cosmetic or care products.
还需要能够通过纤维来产生涂布化妆品或护理品的新状态,这适于产生新的化妆效果。There is also a need to be able to create new states of coated cosmetic or care products with fibers, which are suitable for producing new cosmetic effects.
最后,需要能降低化妆品或护理品在涂布器上的变干速度,尤其是当该涂布器并不快速地重新插入到它的容器内或者需要在密封帽体下保持在潮湿条件中时。Finally, there is a need to be able to reduce the drying rate of cosmetic or care products on the applicator, especially when the applicator is not quickly reinserted into its container or needs to be kept in a humid condition under the sealed cap .
发明内容Contents of the invention
本发明的目的尤其是为了满足所有这些要求或这些要求的一部分。The aim of the invention is in particular to fulfill all or some of these requirements.
本发明通过一种用于化妆品或护理品的包装和/或涂布装置来实现该目的,该装置的特征在于:它包括含有微粒的纤维,该微粒能够吸收液体或在液体溶液中的化合物,或者能溶解于液体中。The invention achieves this object by a packaging and/or application device for cosmetic or care products, characterized in that it comprises fibers containing microparticles capable of absorbing liquids or compounds in liquid solutions, Or can be dissolved in liquid.
在本发明中,术语“纤维”用于表示任意普通的细长体,例如用于构成睫毛油刷的硬毛、植绒覆层中的硬毛、油刷中的硬毛,尤其是用于涂指甲油或用于抹粉,或者实际上是用于构成填料的纤维,该填料包含在用于涂布在眼睫毛上的物质,例如以便拉长眼睫毛。该纤维可以为相对柔性,或者实际上可弹性变形,他们可以由合成材料制成。In the present invention, the term "fiber" is used to denote any ordinary elongated body, such as bristles used to make up mascara brushes, bristles in flocked coatings, bristles in oil brushes, especially for Nail varnish or powder, or indeed the fibers used to make up the filler contained in the substance intended to be applied to the eyelashes, for example in order to lengthen them. The fibers may be relatively flexible, or indeed elastically deformable, and they may be made of synthetic material.
上述液体可以是美容化妆可接受的,例如,可以涂布到人体的水或油或含水的乙醇或油溶液,但不受所列举的限制。The above-mentioned liquids may be cosmetically acceptable, for example, water or oil or aqueous ethanol or oil solutions that can be applied to the human body, but are not limited to those listed.
该液体可以是含在涂布的产品中。The liquid may be contained in the coated product.
因此,本发明的目的是用于涂布产品的装置,该装置包括:Therefore, the object of the present invention is a device for coating a product comprising:
用于涂布产品的许多纤维,其特征在于:至少一种纤维包括多个成形的微粒,至少其中一种能够吸收下列之一的:A plurality of fibers for use in coated products, characterized in that at least one fiber comprises a plurality of shaped particles, at least one of which is capable of absorbing one of the following:
具有重量等于微粒的重量的液体的量;和an amount of liquid having a weight equal to the weight of the particle; and
液体溶液中的化合物;和compounds in liquid solutions; and
溶解于液体。所述多个微粒可以没有棉花。dissolve in liquid. The plurality of particles can be free of cotton.
至少一种所述纤维可以有基本恒定的横截面,例如通过由一种或多种热塑性材料和/或弹性体材料挤出或共挤出而形成。该纤维可以由两种合成材料共挤出而成,其中一种合成材料例如填充有上述微粒。该微粒可以至少在纤维的至少一部分的表面上,并可以仅在表面上或可以选择散布在整个塑性材料中。At least one of said fibers may have a substantially constant cross-section, for example formed by extrusion or coextrusion from one or more thermoplastic and/or elastomeric materials. The fibers can be coextruded from two synthetic materials, one of which is filled, for example, with the above-mentioned particles. The particles may be at least on the surface of at least a portion of the fibers, and may be only on the surface or optionally dispersed throughout the plastic material.
在一个特殊实施例中,该微粒适于在与将进行涂布的物质接触时增大容积,例如它们能够在与包含于将涂布的物质内的溶剂接触时膨胀,所述溶剂例如可以是水。这样的容积增大可以起到在纤维表面上产生表面凹凸不平的作用,该凹凸不平可以形成用于保持物质的区域,这在该纤维用于涂布目的和浸在装有供给的化妆品或护理品的容器中时很有利。In a particular embodiment, the particles are adapted to increase in volume when in contact with the substance to be coated, for example they are capable of swelling when in contact with a solvent contained in the substance to be coated, such as water. Such volume increase can act to create surface asperities on the surface of the fiber which can form areas for holding substances, which is useful when the fiber is used for coating purposes and impregnated with a supplied cosmetic or care product. It is advantageous when in the container of the product.
使用能够吸收液体和可以在与液体接触时膨胀,或者在与液体接触时溶解的微粒可以起到在用于涂布化妆品或护理品的纤维上产生特殊锚固区域的作用,尤其是由于该微粒对于包含于物质中的亲水性或亲脂性化合物的亲和性。因此,物质可以更好地附着在该纤维上,涂布器可以带有更大量的物质。The use of microparticles that absorb liquids and can swell on contact with liquids, or dissolve on contact with liquids, can serve to create specific anchoring areas on fibers used to coat cosmetic or care products, especially since the microparticles are The affinity of a hydrophilic or lipophilic compound contained in a substance. Thus, the substance can be better attached to the fibers and the applicator can carry a larger quantity of substance.
存在适于吸收液体和可以选择适于在与该液体接触时膨胀的微粒还可以用于延迟在纤维表面上的化妆品或护理品的变干,因为当包含于化妆品或护理品中的溶剂例如水蒸发时,已经吸收有所述液体的这些微粒再将该液体释放到在该纤维周围的物质中。使在涂布器表面上的物质的变干延迟很有利,因为它不仅能使该涂布器使用更长时间,而且当它不使用并且没有浸在该物质中时,能够延迟它的变干,例如当它仅通过保护帽保护时。The presence of microparticles adapted to absorb liquids and optionally to swell when in contact with such liquids can also be used to delay drying of cosmetic or care products on the surface of the fibers, since when solvents such as water contained in cosmetic or care products Upon evaporation, the particles which have absorbed the liquid then release the liquid into the material surrounding the fiber. Delaying the drying of the substance on the surface of the applicator is advantageous because it not only enables the applicator to be used for a longer period of time, but also delays its drying when it is not in use and not immersed in the substance , for example when it is only protected by a protective cap.
微粒例如当干时是晶状,当与含在被涂布产品中的液体接触时可以是变软。The microparticles, which are for example crystalline when dry, may soften when in contact with a liquid contained in the coated product.
这样在吸收液体后使得纤维更为柔软。通过选择微粒的特性和加入的量,使得纤维具有所希望的柔软性。This makes the fibers softer after absorbing liquid. By selecting the nature of the particles and the amount added, the fiber has the desired softness.
微粒可以吸收至少其重量的液体,例如水。The microparticles can absorb at least their weight in liquid, such as water.
对于可以使微粒在与将涂布的物质接触时,尤其是在与水接触时体积增大的材料,可以如下面所述,但是该例举并不是作为限制:在有水或液体时膨胀的聚合物;有超级吸收性的网状聚丙烯酸酯,该网状聚丙烯酸酯在水中有很高的膨胀系数;聚乙烯醇;羧基乙烯基聚合物;由纤维素派生的半合成物;淀粉;生物胶;生物糖类;scelro-葡聚糖;酪素;植物胶例如藻酸盐、凝胶、gelanes、黄原胶(Xanthan);合成锂皂石;硅石,尤其是胶状硅石;以及它们的混合物。Materials that can cause the particles to increase in volume when in contact with the substance to be coated, especially water, can be as follows, but this example is not meant to be limiting: Swelling in the presence of water or liquids Polymers; superabsorbent reticulated polyacrylates with a high coefficient of expansion in water; polyvinyl alcohol; carboxyvinyl polymers; semi-synthetics derived from cellulose; starch; Biogum; biosaccharides; scelro-dextran; casein; vegetable gums such as alginates, gelatins, gelanes, xanthan gum (Xanthan); synthetic hectorite; silica, especially colloidal silica; and the like mixture.
超级吸收材料至少可吸收二倍,十倍,五十倍或一百倍其重量的液体,例如可以使用聚丙烯酸酯。Superabsorbent materials can absorb at least two, ten, fifty or one hundred times their weight in liquid, for example polyacrylates can be used.
在膨胀之前,该微粒的颗粒大小例如可以在0.1微米(μm)至300μm的范围内,或者在5微米(μm)至200μm的范围内,或者在10微米(μm)至150μm的范围内。Prior to expansion, the microparticles may have a particle size, for example, in the range of 0.1 micrometer (μm) to 300 μm, or in the range of 5 micrometer (μm) to 200 μm, or in the range of 10 micrometer (μm) to 150 μm.
这些微粒的颗粒大小将随着膨胀后所希望的粗糙度的变化来进行选择。The particle size of these particles will be selected as a function of the desired roughness after expansion.
相对于膨胀之前的纤维的总重量,所述微粒的干重重量浓度可以在0至20%范围内,优选是小于或等于6%。The dry weight concentration of the microparticles may range from 0 to 20%, preferably less than or equal to 6%, relative to the total weight of the fiber before expansion.
为了制造纤维,所用材料可以选择为在与将涂布的物质接触时能膨胀,例如能够使体积相对增大15%。For the manufacture of the fibers, the material used may be chosen to expand, for example to enable a relative increase in volume of 15% when in contact with the substance to be coated.
用于制造至少一种纤维的塑性材料可以从下面例举中选择:聚酰胺;聚对苯二甲酸乙二醇酯(PET);醋酸酯、聚乙烯(PE);聚丙烯(PP);聚氯乙烯(PVC);酰胺聚酯(amide block polyester);增塑Rilsan;弹性体,尤其是聚酯弹性体、PE弹性体、硅氧烷弹性体、腈弹性体;以及这些材料的混合物。The plastic material used to make at least one fiber can be selected from the following examples: polyamide; polyethylene terephthalate (PET); acetate, polyethylene (PE); polypropylene (PP); Vinyl chloride (PVC); amide block polyesters; plasticized Rilsan® ; elastomers, especially polyester elastomers, PE elastomers, silicone elastomers, nitrile elastomers; and mixtures of these materials.
在一个特殊实施例中,至少一种纤维包括适于在与液体例如水接触时可溶解的微粒。该微粒可以是水溶性或脂溶性的。该微粒的溶解使得纤维上呈现表面粗糙性,优选是甚至使该纤维多孔。这些微粒的初始颗粒大小可以在0.1μm至300μm的范围内。In a particular embodiment, at least one of the fibers comprises particles adapted to be soluble on contact with a liquid, such as water. The microparticles can be water-soluble or fat-soluble. The dissolution of the particles renders surface roughness on the fibers, preferably even making the fibers porous. The primary particle size of these microparticles may range from 0.1 μm to 300 μm.
至少一种纤维可以包括适于吸收液体例如水,同时膨胀或不膨胀的微粒。使用该微粒的优点是,它能够将一种或多种化合物送入纤维中,例如为了使它有杀死生物的特性,尤其是灭菌特性。尤其是,该纤维可以含有适于吸收液体溶液中,尤其是水溶液中的保养性物质的微粒。At least one of the fibers may comprise particles adapted to absorb liquids, such as water, with or without swelling. The advantage of using the microparticles is that it enables the delivery of one or more compounds into the fiber, for example in order to impart biocidal properties, especially bactericidal properties. In particular, the fibers may contain microparticles suitable for absorbing maintenance substances in liquid solutions, especially aqueous solutions.
适于吸收液体溶液中的液体或化合物的微粒的浓度可以是,在纤维与所述液体接触之前,相对于纤维的总重量,该微粒的重量百分比可以在0至20%的范围内,或者在0至6%的范围内。The concentration of microparticles suitable for absorbing liquids or compounds in liquid solutions may be in the range of 0 to 20% by weight relative to the total weight of the fibers before the fibers come into contact with said liquid, or within 0 to 6% range.
该纤维可以有很多种横截面,例如它的横截面形状可以选择如下:圆形对称或不对称;圆形;实心或空心的方形;盘状,也可选择有槽;实心或空心的三角形;实心或空心的星形;U形;V形;I形;T形:Z形;--形;+-形;肾状形;有三个分支;空心;或者这些形状的组合。该纤维可以扭绞。The fiber can have many cross-sections, for example, its cross-sectional shape can be selected as follows: circular symmetry or asymmetry; circle; solid or hollow square; Solid or hollow star; U-shaped; V-shaped; I-shaped; T-shaped: Z-shaped; ---shaped; +-shaped; kidney-shaped; three-branched; hollow; or a combination of these shapes. The fibers can be twisted.
采用本发明的纤维的包装和涂布装置可以选择包括擦拭件。Packaging and coating equipment employing the fibers of the present invention may optionally include a wiper.
本发明的纤维可以属于适于吸收物质的涂布器,如上所述。The fibers of the invention may belong to applicators suitable for absorbing substances, as described above.
该涂布器可以是睫毛油刷,该刷子的至少一种硬毛由本发明的纤维构成。The applicator may be a mascara brush, the at least one bristle of which brush consists of a fiber according to the invention.
如上所述,存在能够吸收液体和/或在与液体接触时膨胀或者可溶于液体中的微粒,可以使刷子的硬毛有一定程度的粗糙度或多孔性,从而促进睫毛油的粘附和延迟它的变干。尤其是当该微粒适于产生膜时,该微粒也可以在眼睫毛表面上沉积一层膜,从而提高眼睫毛的稳定性或外观,或者有利于该涂布器的滑动。As mentioned above, the presence of particles that absorb liquid and/or swell when in contact with liquid or are soluble in liquid can impart a degree of roughness or porosity to the bristles of the brush, thereby promoting mascara adhesion and Delay it from drying out. Especially when the microparticles are adapted to produce a film, the microparticles can also deposit a film on the surface of the eyelashes, thereby improving the stability or appearance of the eyelashes, or facilitating the sliding of the applicator.
在一种变化形式中,也可选择,涂布器由油刷型涂布器构成,该刷子的至少一种硬毛由一种所述纤维构成。In a variant, also optionally, the applicator is constituted by an oil brush type applicator, at least one bristle of which brush consists of one of said fibers.
该包装和/或涂布装置可以有植绒覆层,在该植绒覆层中,至少一种硬毛由一种所述纤维构成。该植绒覆层可以覆盖从下面选定的一个组件的至少一部分:梳子的齿;刷子的硬毛;擦拭器;泡沫材料;海绵;选择性穿孔膜;刚性或柔性尾端件,尤其是弹性体尾端件;纺织纤维;以及无纺纤维。The packaging and/or coating device can have a flocked covering in which at least one bristle is formed from one of the fibers described. The flocked covering may cover at least a part of a component selected from the following: teeth of a comb; bristles of a brush; wiper; foam; sponge; optionally perforated membrane; rigid or flexible end piece, especially elastic body end pieces; woven fibers; and nonwoven fibers.
纤维的直径例如可以在0.5μm至500μm的范围内,或者在50μm至500μm范围内,这取决于它的用途,且该纤维的长度例如可以在0.5mm至50mm的范围内。The diameter of the fiber may for example be in the range of 0.5 μm to 500 μm, or 50 μm to 500 μm, depending on its use, and the length of the fiber may be in the range of 0.5 mm to 50 mm, for example.
也可选择,该纤维可以构成化妆品或护理品中的填料,尤其是睫毛油,这时,该纤维有助于拉长眼睫毛。在纤维中包括在与液体接触时吸收液体和/或膨胀的微粒,这将例如有利于使纤维保持在眼睫毛上。Alternatively, the fibers can constitute fillers in cosmetic or care products, especially mascara, in which case the fibers help to elongate the eyelashes. Including particles in the fibers that absorb liquid and/or swell upon contact with liquid will, for example, facilitate retention of the fibers on the eyelashes.
还优选是,该纤维中包括已磁化或可磁化的微粒。It is also preferred that the fibers include magnetized or magnetizable particles.
已磁化或可磁化的微粒可以引入已经含有能够在与液体接触时吸收液体或膨胀,或者可溶于液体中的微粒的纤维,或者在一个变化形式中,包装和/或涂布装置可以只有含有磁性微粒的某些纤维,而其它纤维含有能够在与液体接触时吸收液体或膨胀,或者可溶于液体中的微粒。该磁性微粒可以是由树脂涂覆的微粒,例如氰基丙烯酸酯,或者它们可以由沉积在非磁性介质上的磁性材料形成,该非磁性介质例如为玻璃微珠或木纤维。Magnetized or magnetisable particles may be incorporated into fibers already containing particles capable of absorbing or swelling upon contact with a liquid, or soluble in a liquid, or in a variant, the packaging and/or coating device may contain only Certain fibers of magnetic particles, while others contain particles that absorb liquids or swell when in contact with liquids, or are soluble in liquids. The magnetic particles may be resin coated particles, such as cyanoacrylate, or they may be formed of magnetic material deposited on a non-magnetic medium, such as glass beads or wood fibers.
纤维有磁性可以有利于物质的吸取,并可以改进它向护理表面的涂布,或者可以产生新颖的化妆效果。The magnetic properties of the fibers can facilitate the uptake of substances and improve their application to care surfaces, or can create novel cosmetic effects.
该磁性还可以通过促进微循环来促进活性剂的渗透。This magnetism can also facilitate the penetration of active agents by promoting microcirculation.
纤维可以是静止的或者是运动的。Fibers can be stationary or moving.
纤维可以包括多个微粒,该微粒可以没有粘土,和没有硅石。Fibers may include a plurality of particles, which may be clay-free, and silica-free.
至少一种纤维基本上是没有锥度的。At least one fiber is substantially untapered.
本发明还提供了一种制造适用于上述包装和/或涂布装置中的纤维的方法,其特征在于有如下步骤:The present invention also provides a method for manufacturing fibers suitable for use in the above-mentioned packaging and/or coating device, characterized in that the steps are as follows:
挤出或共挤出含有微粒的塑性材料纤维,该微粒能够吸收液体或者在液体溶液中的化合物,或者可溶于液体中;以及extruding or coextruding fibers of plastic material containing microparticles capable of absorbing liquids or compounds in liquid solutions, or soluble in liquids; and
使该纤维与所述液体接触。The fibers are brought into contact with the liquid.
在该方法的特定实施方式中,使用适于在与所述液体接触时膨胀的微粒,且微粒的颗粒大小选择为使纤维在所述微粒膨胀后有预定的粗糙度。In a particular embodiment of the method, microparticles adapted to swell upon contact with said liquid are used, and the particle size of the microparticles is chosen such that the fibers have a predetermined roughness after swelling of said microparticles.
在还一特定实施方式中,当微粒能够吸收液体溶液中的保养物质,该纤维与所述液体接触,并使得该纤维填充有保养物质。所述液体可以用于冷却离开挤出机的纤维。In yet another particular embodiment, when the microparticles are capable of absorbing a maintenance substance in a liquid solution, the fibers are brought into contact with said liquid and cause the fibers to be filled with the maintenance substance. The liquid can be used to cool the fibers exiting the extruder.
本发明还提供了适用于刷子中的硬毛的纤维,或者作为用于化妆品或护理用品的包装和/或涂布装置中的植绒的纤维,该纤维的特征在于:它除了合成材料外,还包括能够吸收液体或者在液体溶液中的化合物的微粒,或者可溶于液体中的微粒。The invention also provides fibers suitable for use as bristles in brushes, or as flocked fibers in packaging and/or application devices for cosmetic or care products, which fibers are characterized in that, in addition to synthetic materials, Also included are microparticles capable of absorbing liquids or compounds in liquid solutions, or microparticles that are soluble in liquids.
本发明还提供了通过上述方法获得的多孔或粗糙纤维,尤其是用于涂布产品装置的纤维,该纤维包括:The present invention also provides porous or coarse fibers obtained by the above method, especially fibers for coating product devices, comprising:
合成材料;和synthetic materials; and
与合成材料相关的多个微粒,该成形的多个微粒至少其中一种能吸收下列之一的:Particles associated with synthetic materials, the shaped plurality of particles being capable of absorbing at least one of:
液体和liquid and
液体溶液中的化合物,并溶于液体中。A compound in a liquid solution and dissolves in a liquid.
其中的多个粒子能够吸收至少等于其重量的液体的量。A plurality of particles therein are capable of absorbing an amount of liquid at least equal to their weight.
附图说明Description of drawings
通过阅读下面对非限定实施例的详细说明并参考附图(该附图为本说明书的一整体部分),可以了解本发明的其它特征和优点,在所有附图中,为了附图清楚,各组件的相对比例可能失真。附图中:Other characteristics and advantages of the present invention can be understood by reading the following detailed description of non-limiting embodiments and referring to the accompanying drawings, which form an integral part of this specification, in all drawings, for the sake of clarity of the drawings, The relative proportions of the various components may be distorted. In the attached picture:
图1A和1B是表示包含有适于在液体中膨胀的微粒的纤维的轴向示意剖视图;Figures 1A and 1B are schematic axial cross-sectional views showing fibers comprising particles adapted to expand in a liquid;
图2A和2B是表示包括可溶于液体中的微粒的纤维的轴向示意剖视图;Figures 2A and 2B are schematic axial cross-sectional views showing fibers comprising microparticles soluble in a liquid;
图3表示了在纤维表面上形成的凝胶;Figure 3 shows the gel formed on the fiber surface;
图4表示了微粒仅在纤维表面上的实施例;Figure 4 shows an embodiment where the particles are only on the fiber surface;
图5A至7是分别于图1A至3类似的视图,表示包括磁性微粒的纤维;Figures 5A to 7 are views similar to Figures 1A to 3, respectively, showing fibers comprising magnetic particles;
图8A至8C是表示磁性微粒在纤维内分布的不同实例的示意横剖图;8A to 8C are schematic cross-sectional views showing different examples of distribution of magnetic particles in fibers;
图9A至9R是表示纤维的各种可能截面的示意横剖图;Figures 9A to 9R are schematic cross-sectional views showing various possible cross-sections of fibers;
图10表示纤维通过挤出制造;Figure 10 shows the manufacture of fibers by extrusion;
图11表示该纤维在挤出后磁化;Figure 11 shows that the fiber is magnetized after extrusion;
图12至26表示包装和/或涂布装置的各种实例;Figures 12 to 26 represent various examples of packaging and/or coating devices;
图27表示用可磁化纤维制成的硬毛在由磁体产生的磁场线作用下在植绒中的定向;Figure 27 represents the orientation in flocking of bristles made of magnetisable fibers under the action of magnetic field lines produced by a magnet;
图28A和28B表示在磁相互作用的影响下刷子硬毛的偏转;Figures 28A and 28B illustrate the deflection of brush bristles under the influence of magnetic interactions;
图29A和29B表示在磁相互作用的影响下油刷硬毛的偏转;Figures 29A and 29B show deflection of oil brush bristles under the influence of magnetic interaction;
图30表示包括涂布组件的涂布器,该涂布组件在不使用时装于保护帽中;Figure 30 shows an applicator including an applicator assembly housed in a protective cap when not in use;
图31表示涂布的磁性微粒;以及Figure 31 shows coated magnetic particles; and
图32表示通过使磁性物质沉积在非磁性体上而形成的磁性微粒。Fig. 32 shows magnetic fine particles formed by depositing a magnetic substance on a non-magnetic body.
具体实施方式 Detailed ways
图1A至9R表示了本发明的纤维,该纤维适用于例如如图12至26中任意一个所示的包装和/或涂布装置。Figures 1A to 9R illustrate fibers of the present invention suitable for use in packaging and/or coating devices such as those shown in any of Figures 12 to 26.
在所述实例中,纤维通过挤出包含微粒填料的热塑性材料11而制成,该微粒能够吸收液体或在液体溶液中的化合物,或者能溶解于液体中,可以选择同时使该微粒填料有磁性。In the example described, the fibers are produced by extruding
图1A表示了在纤维与液体例如水接触之前,包含微粒30化合物的填料的纤维,该微粒30的化合物能够在水中膨胀,而图1B表示了该相同纤维在与液体接触之后的情况。Figure 1A shows a fiber comprising a filler of
在所示实例中,纤维是实心的,并有圆形横截面,但是它也可以有其它截面,如后面所述。In the example shown, the fiber is solid and has a circular cross-section, but it may also have other cross-sections, as will be described later.
例如,该纤维通过如图10所示的装置制造,该装置包括一挤出机20和一冷却液槽21,纤维在离开挤出机后浸没在该槽内。For example, the fibers are produced by means of an apparatus as shown in Figure 10, which comprises an extruder 20 and a coolant tank 21 in which the fibers are submerged after leaving the extruder.
微粒30的膨胀用于在纤维的表面形成起伏效果,通过利用该起伏效果,纤维尤其能吸收更大量的物质,或者在该纤维例如用作睫毛油刷的硬毛时能更好地抓住眼睫毛。The swelling of the
微粒30也能够用于将一种或多种物质吸收到纤维内,该物质例如为具有美容或皮肤活性作用的保护剂或试剂。The
尤其是,用于冷却离开挤出机的纤维的槽21可以包括溶解于槽液中的一种或多种化合物,例如保护剂,所述化合物在纤维浸入该槽21中时由微粒30吸收。这样,离开槽21的纤维填充有由包含于纤维中的微粒30所吸取的化合物。这些化合物例如在与化妆品或护理品接触时再逐渐释放,以便改进它们的保存。该纤维可以在离开槽21后进行脱水。In particular, the tank 21 for cooling the fibers leaving the extruder may comprise one or more compounds dissolved in the tank liquid, such as protective agents, which are absorbed by the
也可选择,除了可选择有微粒30外,纤维还可以包含微粒40,该微粒40可溶于液体中,例如槽21的用于冷却离开挤出机的纤维的水。这些微粒40例如可以由可溶于所用液体中的盐、糖构成,或者当该液体为水时由凝胶构成。图2A表示了包含在溶解之前的该微粒40的纤维,即例如该纤维刚离开挤出机20,而图2B表示了相同纤维在经过槽21之后的情况。可以看见,在纤维表面上的可溶微粒40由槽21中的液体溶解,从而使纤维表面产生粗糙性,甚至可以使该纤维多孔。该粗糙性或多孔性例如可以用于增加纤维能吸收的物质的量。所获得的粗糙性或多孔性的大小取决于微粒40的初始颗粒大小。当纤维离开槽21时,只需要使部分微粒40溶解,这样,微粒在与在其表面上的化妆品或护理品接触时继续溶解。微粒40可以由一种或多种具有化妆或护肤效果的物质构成。在这种情况下,微粒40在与化妆品或护理品接触时的溶解可以伴随着将所述物质释放到护理表面上。优选是,纤维可以受到振动,以便于或使得在表面上的微粒40离开。Alternatively, in addition to the
也可选择,微粒40由并不溶于槽21的水中的材料制成,且该材料只逐渐溶解于与该纤维接触的化妆品或护理品中。Alternatively, the
还可以将微粒50引入纤维中,该纤维适于在与液体接触时形成凝胶,从而在纤维表面上形成一层凝胶51,如图3所示。这样一层凝胶51例如能够改变纤维对于与其接触的化妆品或护理用品的亲和性。该凝胶还可以沉积在护理表面上,例如眼睫毛上,从而提高其稳定性和外观,或者提高涂布器与其接触的滑动性。It is also possible to introduce
采用能吸收液体,尤其是水的微粒还有这样的优点,即当由该微粒吸收的液体能够逐渐释放,以便补偿包含于成分中的溶剂的蒸发时,能够延迟化妆品或护理成分在纤维表面上的变干。The use of particles capable of absorbing liquids, especially water, also has the advantage that cosmetic or care ingredients can be delayed on the surface of the fibers when the liquid absorbed by the particles can be gradually released in order to compensate for the evaporation of the solvent contained in the ingredients. of dry out.
使用微粒30、40或50还可以起到在用于物质的纤维表面上产生特别的锚固区域的作用,例如由于所用微粒对于物质中所包含的亲脂性或亲水性化合物的亲和性。该物质可以是水/油乳化液,该纤维可以仅吸收水或仅吸收油,或者更通常是它们以选定方式吸收物质中的一种化合物。The use of
优选是,微粒30、40或50可以只存在于纤维表面上,如图4所示。Preferably, the
例如,微粒30、40或50的初始颗粒大小在范围1μm至300μm之间,或者在5μm至200μm之间,或者在10μm至150μm之间。微粒30、40或50的浓度可以是当干燥时为0至20%重量范围,或者为0至6%重量范围。For example, the primary particle size of the
该纤维还可以包括磁性微粒12,该磁性微粒12以基本均匀的方式分散在塑性材料11内。The fibers may also comprise
也可选择,磁性材料12可以通过合适方法仅沉积在纤维表面,例如通过如图8A所示的涂覆层,或者它们可以限定在纤维内部,如图8B所示。还可以由中心核14代替磁性微粒,如图8C所示。Alternatively, the
例如,磁性微粒的重量浓度在0.2%至30%的范围内。For example, the weight concentration of magnetic particles is in the range of 0.2% to 30%.
优选是,所用的磁性材料从以下例举中选择:软磁性材料;硬磁性材料;铁氧体,尤其是基于锌、镍或锰的铁氧体;稀土;硫酸钡;硅合金;钴铁,尤其是带有钼填料;以及这些材料的混合物。磁性微粒12可以通过使磁性物质破碎或通过将磁性物质M沉积在非磁性体C上而制成,例如如图31所示的微型小珠或木纤维。也可选择,该磁性微粒可以包括磁性核M和非磁性的外层R,例如一层树脂,尤其是氰基丙烯酸酯,如图32所示。Preferably, the magnetic material used is selected from the following examples: soft magnetic materials; hard magnetic materials; ferrites, especially ferrites based on zinc, nickel or manganese; rare earths; barium sulfate; silicon alloys; Especially with molybdenum fillers; and mixtures of these materials. The
图5A和5B表示了一种纤维,该纤维与图1A和1B中的纤维不同,在其内部有磁性微粒12。Figures 5A and 5B show a fiber which, unlike the fiber in Figures 1A and 1B, has
图6A和6B所示的纤维与图2A和2B中的纤维不同,其中具有磁性微粒12。The fiber shown in Figures 6A and 6B is different from the fiber in Figures 2A and 2B in that it has
图7表示了图3的纤维有在它的整个体积中散布的磁性微粒12。Figure 7 shows the fiber of Figure 3 with
纤维的横截面除了实心圆形外还可以有非常多的变化,如下面参考图9A至9R所述。Fiber cross-sections can vary widely beyond solid circular, as described below with reference to Figures 9A through 9R.
纤维可以挤出成有扁平截面,如图9A所示,或者有十字形截面,如图9B所示,或者有具有三个分支的星形形状的截面,如图9C所示。纤维可以有空心截面,如图9D所示,或者是有毛细槽的实心截面,如图9E所示。该纤维还可以有U形截面,如图9F所示;I形截面,如图9H所示;T形截面,如图9I所示;V形截面,如图9J所示,Z形截面,如图9K所示,或者上述特定形状的组合,例如如图9G所示,图9B和9C中的形状的组合。图9L表示了空心、方形截面的纤维;图9M表示了实心、方形截面的纤维;图9N表示了空心、星形截面的纤维;图9P表示了空心、三角形截面的纤维;图9Q表示了截面形成有周边槽的纤维;图9R表示肾状形截面的纤维。Fibers can be extruded to have a flat cross-section, as shown in Figure 9A, or a cruciform cross-section, as shown in Figure 9B, or a star-shaped cross-section with three branches, as shown in Figure 9C. The fibers can have a hollow cross-section, as shown in Figure 9D, or a solid cross-section with capillary grooves, as shown in Figure 9E. The fiber can also have a U-shaped cross-section, as shown in Figure 9F; an I-shaped cross-section, as shown in Figure 9H; a T-shaped cross-section, as shown in Figure 9I; a V-shaped cross-section, as shown in Figure 9J, and a Z-shaped cross-section, such as As shown in FIG. 9K, or a combination of the above-mentioned specific shapes, for example, as shown in FIG. 9G, a combination of shapes in FIGS. 9B and 9C. Figure 9L shows fibers with a hollow, square cross-section; Figure 9M shows fibers with a solid, square cross-section; Figure 9N shows fibers with a hollow, star-shaped cross-section; Figure 9P shows fibers with a hollow, triangular cross-section; Fibers formed with peripheral grooves; Figure 9R shows fibers with kidney-shaped cross-sections.
当纤维包含磁性微粒时,该纤维可以暴露于磁场中,以便进行磁化,例如为了使纤维磁化成具有预定的极性。这可以在纤维离开槽21时进行,例如通过磁化装置60,如图11所示。优选是,纤维的磁化还可以在纤维装入包装和/或涂布装置之后,通过将磁场加在该装置上或加在一批这样的装置上而进行。纤维的磁化仅仅是为了当它们在包装和/或涂布装置内布置就位时,能够通过限制纤维聚集在一起的危险而使制造更容易。When the fiber contains magnetic particles, the fiber may be exposed to a magnetic field in order to be magnetized, for example in order to magnetize the fiber to a predetermined polarity. This can be done as the fibers leave slot 21, for example by means of magnetization 60, as shown in FIG. Preferably, the magnetization of the fibers is also carried out after the fibers have been loaded into the packaging and/or coating device by applying a magnetic field to the device or to a batch of such devices. The magnetization of the fibers is only to enable easier manufacture by limiting the risk of the fibers clumping together when they are arranged in place within the packaging and/or coating device.
该纤维可以用于多种涂布器和包装装置,如后面所述。The fiber can be used in a variety of applicators and packaging devices, as described below.
图12表示了一种包装和涂布器装置100,该包装和涂布装置100包括:一容器101,该容器101容纳用于涂布的物质P,例如睫毛油;还有一涂布器102。该容器101有擦拭件106,在一个未示出的变化形式中,该擦拭件106可以由绒覆盖。涂布器102包括一个杆103,该杆103在一端有一个手柄104,该手柄104也构成用于封闭该容器101的密封帽,该杆在其另一端有一刷子105。该刷子包括由扭绞的金属丝制成的芯,该芯再装有由上述纤维构成的硬毛,该纤维可以选择包括磁性微粒。FIG. 12 shows a packaging and
当纤维包括磁性微粒时,可以使该刷子的磁极定向成例如沿该杆103的轴线或垂直于该杆103的轴线。该扭绞的芯可以由非磁性材料例如非磁性的不锈钢制成,或者在一种变化形式中,它可以由具有磁性的材料制成。这样,该芯与该硬毛相互磁作用。该刷子105的硬毛可以磁化,这样,刷子硬毛的磁化强度作用在相邻硬毛上,硬毛之间的磁相互作用例如起到使硬毛合适定位的作用。根据刷子磁极的方向,对硬毛定向的作用可以改变。例如,图28A和28B表示了当磁场横向延伸时对刷子的硬毛的侧向偏转作用。也可选择,在将物质涂布在眼睫毛上时单独使用硬毛,以便将有益的磁场施加在眼睫毛或脸的一部分上,例如眼皮上。由刷子的硬毛施加的磁场易于随时变化,尤其是当刷子的结构改变时,例如当涂布器抽出或当涂布物质时。物质P可以有磁性,例如它可以含有可磁化或已磁化的微粒。当物质P有磁性时,也有磁性的刷子硬毛可以增强该刷子吸取物质的能力,例如通过物质和刷子硬毛之间的磁性吸引力。也可选择,物质可以含有具有磁性的纤维或薄片,而涂布器可以与这些薄片磁相互作用,以便使它们在涂布时以特定方向对齐,从而例如有利于涂布器的滑动。When the fibers comprise magnetic particles, the magnetic poles of the brush can be oriented eg along the axis of the
图13表示了用于包装和涂布指甲油的装置110,该装置包括一容器111和一涂布器112,该涂布器包括一杆113,该杆113在其一端有手柄组件114,该手柄组件114也构成用于封闭该容器的帽体,该杆113在其另一端有油刷115,该油刷115包括相对紧密地捆在一起的硬毛束。该硬毛利用本发明的纤维制成,且它们可以选择有磁性,该磁性可以用于在使用时使刷子115的硬毛形成预定方向,从而使刷子115更易于吸取物质或作用在护理表面上。当在刷子的硬毛之间有磁相互作用时,根据各硬毛的磁场极性,该磁相互作用可以有利于将硬毛聚束在一起,或者相反,使它们张开。例如,图29A和29B非常概略地表示了硬毛由于它们之间的磁相互作用而张开的效果。物质P可以选择为有其自身的磁性。Figure 13 has shown the
图14表示了一种包装和涂布装置120,该包装和涂布装置120包括一容器121,该容器121装有物质P,例如液体口红,该装置120还有一涂布器122,该涂布器122包括一杆123,该杆123在一端有帽体124,用于封闭容器121和作为手柄,且在该杆的另一端有一涂布器尾端件124,该涂布器尾端件124由采用本发明纤维制成的植绒覆盖,该纤维可以选择有磁性。该装置120还有由泡沫材料块125构成的擦拭件。该泡沫材料块也可选择有磁性。特别是,该泡沫材料块125可以通过在其中包含磁性微粒而磁化到一定程度。擦试件的磁化例如可以在抽出涂布器122时磁化在尾端件124上的植绒。Fig. 14 has shown a kind of packaging and
图15表示了用于包装和涂布物质P的装置130,该物质P尤其是液体口红,该装置包括一尾端件131,该尾端件由利用本发明的纤维制成的植绒132覆盖,该纤维可以选择有磁性。Figure 15 shows a
图16表示了用于抹粉的油刷140,该刷子的硬毛由本发明的纤维制成,该纤维可以选择有磁性。Figure 16 shows an
图17表示了涂布器150,该涂布器150包括一泡沫材料151,该泡沫材料151的表面由利用本发明的纤维制成的植绒152覆盖,该纤维可以选择有磁性。该涂布器例如可以用于将胭脂(blush)涂在皮肤上。Figure 17 shows an
图18A表示了一种液体口红涂布器160,该液体口红涂布器160包括一个植绒弹性体的尾端件161,图18B表示了眼线膏160’,该眼线膏160’同样包括一个植绒弹性体的尾端件161’。在这两种情况中,用于植绒的硬毛由本发明的纤维制成,该纤维可以选择有磁性。Fig. 18 A has shown a kind of
本发明的纤维还可以用于对粉扑170植绒,如图19所示,或者对卸妆海绵180植绒,如图20所示。The fibers of the present invention can also be used to flock a powder puff 170 as shown in FIG. 19 , or a makeup remover sponge 180 as shown in FIG. 20 .
植绒覆层还可以延伸到固定在泡沫材料块192上的膜191上,该情况的涂布器190如图21所示。The flocked coating may also extend onto a membrane 191 secured to a block of foam material 192 , in which case an applicator 190 is shown in FIG. 21 .
还可以在圆盘200或小毛巾中采用本发明的纤维,该纤维可以选择有磁性,该圆盘200或小毛巾包括至少一层201包含所述纤维的无纺纤维或纺织纤维,如图22所示。It is also possible to use the fibers of the present invention in a disc 200 or towelette, which may optionally be magnetic, and which comprises at least one layer 201 of nonwoven or woven fibers comprising said fibers, as shown in Figure 22 shown.
图23表示了向眼睫毛涂布物质的梳子210,该梳子有植绒的齿211。植绒的硬毛可以由本发明的纤维制成,该纤维可以选择有磁性。Figure 23 shows a comb 210 having flocked teeth 211 for applying a substance to the eyelashes. The flocked bristles can be made from fibers according to the invention, which fibers can optionally be magnetic.
除了纤维有磁性外,该涂布器还可以选择包括一个或多个单件的磁体。In addition to the fibers being magnetic, the applicator may optionally include one or more single-piece magnets.
例如,图24表示了一种涂布器220,该涂布器220包括手柄221,该手柄上固定有磁体222。该磁体由泡沫材料块223覆盖,而该泡沫材料块自身在其外部由植绒224覆盖,该植绒由具有磁性的纤维构成。磁体222的存在受到植绒224的硬毛受到磁场作用。尤其是,基本垂直于底部介质连接的植绒的硬毛沿磁场线M延伸,如图27所示。该硬毛将直立在涂布器组件的表面上,或者根据它们相对于磁体222的位置而沿其它方向伸出,从而使该涂布器可以吸收更大量的物质或使得该涂布器的涂布更柔和。此外,当物质是将与涂布器接触的粉时,且当涂布器有磁性时,粉的微粒将沉积在涂布器上,尤其是在它的纤维上,从而减小了该粉四处吹散和引起打喷嚏的危险。For example, Figure 24 shows an applicator 220 that includes a handle 221 with a magnet 222 secured thereto. The magnet is covered by a block of foam material 223 which itself is covered on the outside by a flock 224 consisting of magnetic fibers. The presence of magnets 222 is effected by the bristles of flocking 224 being subjected to a magnetic field. In particular, the flocked bristles of the bottom dielectric connection extend along the magnetic field lines M substantially perpendicularly, as shown in FIG. 27 . The bristles will stand upright on the surface of the applicator assembly, or protrude in other directions depending on their position relative to the magnet 222, allowing the applicator to absorb a larger amount of material or allowing the applicator to absorb a larger amount of material. Cloth is softer. Furthermore, when the substance is a powder that will come into contact with the applicator, and when the applicator is magnetic, particles of the powder will be deposited on the applicator, especially on its fibers, thereby reducing the chances of the powder spreading. Blowing and sneezing hazard.
在图25所示的装置230中,物质装于柔性袋231中,泵232装在该柔性袋顶上。涂布器包括一泡沫材料234,该泡沫材料234的表面由植绒235覆盖,且该泡沫材料234固定在帽体236上。磁体237装于泡沫材料234内,并安装在帽体236上。植绒235的硬毛利用本发明的纤维制成,该纤维有磁性,且该硬毛受到磁体237的磁场的影响,如前面实施例所述。In the device 230 shown in Figure 25, the substance is contained in a flexible bag 231 and a pump 232 is mounted on top of the flexible bag. The applicator includes a foam material 234 , the surface of the foam material 234 is covered by flocking 235 , and the foam material 234 is fixed on the cap body 236 . Magnet 237 is encased in foam material 234 and mounted on cap 236 . The bristles of the flock 235 are made using the fibers of the present invention, the fibers are magnetic, and the bristles are affected by the magnetic field of the magnet 237, as described in the previous embodiments.
图30表示了涂布器280的一部分,该涂布器280包括一个有植绒的尾端件282,该尾端件282在不使用时装于帽体281内。通过采用含有吸水或在有水时膨胀的试剂的纤维,能够使它在帽体内保持潮湿,从而延迟该尾端件的变干,该尾端件也可以由其它涂布器组件代替,例如刷子。Figure 30 shows a portion of
自然,本发明并不局限于上述实施例。Naturally, the present invention is not limited to the above-described embodiments.
尤其是,在涂布器和装于容器内的物质之间有一网屏240,如图26所示。这时,物质P可以含有磁性微粒241,且涂布器可以有磁性,例如该涂布器由具有植绒覆层的尾端件构成,该植绒覆层由有磁性的本发明纤维构成。该尾端件242可以吸附包含于物质中的磁性微粒241。通过合适选择网屏240的孔径,可以保证由该尾端件242吸引的磁性微粒241不能通过该网屏240,但是起到使物质P朝着尾端件242运动的作用,从而提高该尾端件242吸收该物质的能力。在一种变化形式中,物质P自身有磁性,例如含有涂覆磁性微粒,且该物质P能够通过网屏240的孔。In particular, there is a
该纤维可以仅在其长度的一部分上磁化。The fiber may be magnetized only over part of its length.
上述包装和涂布装置可以包括磁性纤维,且混合有非磁性纤维,该纤维填充有化合物微粒,该化合物微粒能吸收液体和/或适于在与液体接触时膨胀,或者能够在与液体接触时溶解,该液体例如可以是水。The packaging and coating devices described above may comprise magnetic fibers mixed with non-magnetic fibers filled with microparticles of a compound capable of absorbing liquid and/or adapted to swell when in contact with a liquid, or capable of To dissolve, the liquid may be, for example, water.
Claims (40)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0107308A FR2825246B1 (en) | 2001-06-05 | 2001-06-05 | PACKAGING AND/OR APPLICATION DEVICE COMPRISING FIBERS COMPRISING PARTICLES CAPABLE OF ABSORBING A LIQUID OR A COMPOUND IN SOLUTION IN THIS LIQUID OR OF DISSOLVING IN A LIQUID |
| FR0107308 | 2001-06-05 |
Publications (2)
| Publication Number | Publication Date |
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| CN1389379A true CN1389379A (en) | 2003-01-08 |
| CN1246197C CN1246197C (en) | 2006-03-22 |
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| CN02122482.XA Expired - Fee Related CN1246197C (en) | 2001-06-05 | 2002-06-05 | Package and/or applicating device for cosmetic and care product, and preparation method for fiber thereof |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20020182409A1 (en) |
| EP (1) | EP1264562A1 (en) |
| JP (2) | JP2003125846A (en) |
| CN (1) | CN1246197C (en) |
| BR (1) | BR0202112A (en) |
| CA (1) | CA2389556C (en) |
| FR (1) | FR2825246B1 (en) |
| MX (1) | MXPA02005565A (en) |
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| US5349972A (en) * | 1992-12-18 | 1994-09-27 | The Procter & Gamble Company | Dual wiper mascara package having residual chamber with bypass channel |
| US5386278A (en) * | 1993-02-22 | 1995-01-31 | Canon Kabushiki Kaisha | Cleaning fiber, cleaning brush and image forming apparatus using the same |
| DE4306214A1 (en) * | 1993-02-27 | 1994-09-01 | Geka Brush Georg Karl Gmbh | Brush with bristles fixed between twisted wire sections |
| US5466724A (en) * | 1993-06-01 | 1995-11-14 | Variseal Corporation | Adhesive composition for a wound dressing |
| DE4325071C2 (en) * | 1993-07-19 | 1995-08-10 | Lancaster Group Ag | Preparation for circulation promotion |
| US5536263A (en) * | 1994-03-30 | 1996-07-16 | Lectec Corporation | Non-occulusive adhesive patch for applying medication to the skin |
| US5567072A (en) * | 1995-06-07 | 1996-10-22 | Risdon Corporation | Mascara applicator having slotted bristles |
| US5762432A (en) * | 1995-06-07 | 1998-06-09 | Risdon Corporation | Mascara applicator having slotted bristles |
| DE19534368A1 (en) * | 1995-09-15 | 1997-03-20 | Pedex & Co Gmbh | Bristles with a surface structure and process for their manufacture |
| FR2752695B1 (en) * | 1996-09-02 | 1998-10-16 | Oreal | POWDER APPLICATOR AND METHOD FOR MANUFACTURING THE APPLICATOR |
| US5987691A (en) * | 1997-01-06 | 1999-11-23 | Colgate-Palmotive Company | Toothbrush bristles containing microfilaments |
| FR2759872B1 (en) * | 1997-02-21 | 1999-03-26 | Oreal | CONDITIONING AND APPLICATION SET FOR A KERATIN FIBER MAKEUP PRODUCT |
| US5935596A (en) * | 1997-03-20 | 1999-08-10 | Chesebrough-Pond's Usa Co. | Delivery of skin benefit agents via adhesive strips |
| DE19715478A1 (en) * | 1997-04-10 | 1998-10-15 | Lancaster Group Gmbh | Cosmetic and dermatological agent based on hard magnetic particles |
| US6342298B1 (en) * | 1997-11-19 | 2002-01-29 | Basf Aktiengesellschaft | Multicomponent superabsorbent fibers |
| US6072101A (en) * | 1997-11-19 | 2000-06-06 | Amcol International Corporation | Multicomponent superabsorbent gel particles |
| US6269514B1 (en) * | 1998-06-05 | 2001-08-07 | Du Pont | Monofilament bristle assemblies and methods of making brushes using same |
| US20010003600A1 (en) * | 1998-07-10 | 2001-06-14 | Gordon G. Guay | Method of manufacturing a textured toothbrush bristle |
| US6174600B1 (en) * | 1998-11-05 | 2001-01-16 | Speciality Filaments, Inc. | Bristles employing particulates and brushes including same |
| FR2786376B1 (en) * | 1998-11-27 | 2001-10-26 | Oreal | NAIL VARNISH BRUSH AND NAIL VARNISH APPLICATION SET PROVIDED WITH SUCH A BRUSH |
| US6311359B1 (en) * | 1999-05-25 | 2001-11-06 | E.I. Du Pont De Nemours And Company | Tapered brush bristles with clay or silica additive and brushes made therefrom |
| FR2796528B1 (en) * | 1999-07-21 | 2001-09-21 | Oreal | DEVICE FOR CONDITIONING AND APPLYING A PRODUCT TO EYELASHES OR EYEBROWS |
| FR2800586B1 (en) * | 1999-11-10 | 2001-12-07 | Oreal | APPLICATOR OF A LIQUID, PASTY OR POWDERY PRODUCT COMPRISING PARTICLE-LOADED HAIRS, APPLICATION ASSEMBLY THUS EQUIPPED, USE OF THE ASSEMBLY AND METHOD OF MANUFACTURING SUCH HAIRS |
| DE10010572A1 (en) * | 2000-03-03 | 2001-09-06 | Coronet Werke Gmbh | Thermoplastic (e.g. tooth) brush has regions containing surface-diffusing (especially silver) antimicrobial substance and regions guaranteeing required bending and recovery properties |
| US6946413B2 (en) * | 2000-12-29 | 2005-09-20 | Kimberly-Clark Worldwide, Inc. | Composite material with cloth-like feel |
-
2001
- 2001-06-05 FR FR0107308A patent/FR2825246B1/en not_active Expired - Fee Related
-
2002
- 2002-06-04 CA CA002389556A patent/CA2389556C/en not_active Expired - Fee Related
- 2002-06-04 EP EP02291370A patent/EP1264562A1/en not_active Withdrawn
- 2002-06-05 BR BR0202112-9A patent/BR0202112A/en not_active Application Discontinuation
- 2002-06-05 CN CN02122482.XA patent/CN1246197C/en not_active Expired - Fee Related
- 2002-06-05 US US10/161,726 patent/US20020182409A1/en not_active Abandoned
- 2002-06-05 MX MXPA02005565A patent/MXPA02005565A/en active IP Right Grant
- 2002-06-05 JP JP2002164585A patent/JP2003125846A/en active Pending
-
2006
- 2006-05-08 JP JP2006129499A patent/JP2006271983A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102905576A (en) * | 2010-03-29 | 2013-01-30 | 欧莱雅 | Device for the application of fibers to human keratinous fibers |
| CN102905576B (en) * | 2010-03-29 | 2016-09-21 | 欧莱雅 | For the device that fiber is applied on human keratin fiber |
| CN108013579A (en) * | 2016-11-03 | 2018-05-11 | 可喜爱商务有限公司 | Skin care appliance |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003125846A (en) | 2003-05-07 |
| US20020182409A1 (en) | 2002-12-05 |
| MXPA02005565A (en) | 2004-07-16 |
| CA2389556A1 (en) | 2002-12-05 |
| EP1264562A1 (en) | 2002-12-11 |
| BR0202112A (en) | 2003-05-20 |
| FR2825246A1 (en) | 2002-12-06 |
| FR2825246B1 (en) | 2004-06-04 |
| JP2006271983A (en) | 2006-10-12 |
| CA2389556C (en) | 2008-09-30 |
| CN1246197C (en) | 2006-03-22 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
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Granted publication date: 20060322 |