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CN1378264A - A Self-Aligning Contact Method with Sacrificial Packed Columns - Google Patents

A Self-Aligning Contact Method with Sacrificial Packed Columns Download PDF

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CN1378264A
CN1378264A CN 01110194 CN01110194A CN1378264A CN 1378264 A CN1378264 A CN 1378264A CN 01110194 CN01110194 CN 01110194 CN 01110194 A CN01110194 A CN 01110194A CN 1378264 A CN1378264 A CN 1378264A
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layer
insulating
sacrificial
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wire
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CN1153273C (en
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刘豪杰
蔡泓祥
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Winbond Electronics Corp
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Abstract

The invention provides a self-aligned contact process method with a sacrificial type filling column, which can not damage other isolation layers when a self-aligned contact step is carried out, thereby influencing the isolation effect and generating leakage current. In addition, the thickness of the insulating layer formed by the method and covering the conducting wire can be reduced, thereby reducing the aspect ratio and obtaining better gap insulating layer filling.

Description

一种具有牺牲型填充柱的自行对准接触方法A Self-Aligning Contact Method with Sacrificial Packed Columns

本发明是关于一种自行对准接触的方法,特别是有关于一种具有牺牲型填充柱的自行对准接触的工艺方法。The invention relates to a method for self-alignment contact, in particular to a process method for self-alignment contact with sacrificial filled columns.

半导体集成电路的制作是极其复杂的过程,目的在于将特定电路所需的各种电子组件和线路,缩小制作在一小面积基底上。其中,各个组件必须藉由适当的内连导线(interconnect)来作电性连接,方得以发挥所期望的功能。一般所谓集成电路的金属化工艺(metallization),除了制作各层导线图之外,并藉助介层窗(contact/via)构造,作为组件接触区与导线之间,或是多层导线之间联系的信道。深亚微米工艺技术的发展更突显出某些特定半导体制造技术的重要性,如蚀刻平板印刷工艺(lithography process)和干式蚀刻等工艺。高精密型曝光仪器和高感光材料的发展已使光阻层上的亚微米影像可以容易地获得,再者,先进的干式蚀刻的设备与技术应用于超大规模集成电路芯片制造上亦使光阻层上的亚微米影像可以精确地描摹到被蚀刻的材料上。然而,要进一步缩小半导体芯片的尺寸除了上述先进的工艺技术的创新外,亦须研发其它特殊工艺或结构。The manufacture of semiconductor integrated circuits is an extremely complex process, the purpose of which is to reduce and manufacture various electronic components and circuits required for a specific circuit on a small area substrate. Wherein, each component must be electrically connected by an appropriate interconnection wire (interconnect) in order to perform the desired function. Generally, the so-called metallization process of integrated circuits, in addition to making the wiring diagrams of each layer, also uses the contact/via structure as a connection between the contact area of the component and the wires, or between multi-layer wires. Channel. The development of deep submicron process technology highlights the importance of some specific semiconductor manufacturing technologies, such as etching lithography process (lithography process) and dry etching. The development of high-precision exposure equipment and high-photosensitive materials has made it easy to obtain submicron images on the photoresist layer. Furthermore, the application of advanced dry etching equipment and technology to the manufacture of VLSI chips has also made light Submicron images on resist layers can be traced precisely onto the material being etched. However, in order to further reduce the size of the semiconductor chip, in addition to the innovation of the above-mentioned advanced process technology, other special processes or structures must be developed.

自行对准接触工艺,因其可缩减蚀刻平板印刷工艺的步骤,并且可以缩小半导体内组件尺寸,从而缩小芯片的尺寸,它被广泛的应用在深亚微米工艺中。目前,由于集成电路的加工朝向ULSI发展,因此内部的电路密度愈来愈增加,随着集成电路的积集度日益增加,现今自行对准接触工艺尚有些技术障碍有待突破。以下将简述传统的自行对准接触工艺及其技术上的不足。The self-aligned contact process is widely used in the deep submicron process because it can reduce the steps of the etching lithography process and reduce the size of components in the semiconductor, thereby reducing the size of the chip. At present, since the processing of integrated circuits is developing towards ULSI, the internal circuit density is increasing. With the increasing integration of integrated circuits, there are still some technical obstacles to be overcome in the current self-alignment contact process. The traditional self-aligned contact process and its technical shortcomings will be briefly described below.

首先,请参见第1A图,其显示在基底2的表面上,形成一由氧化硅衬底层4、多晶硅层6和硅化钨层8所组成的导线结构,及在导线结构上形成氮化硅上盖层10和于氮化硅上盖层及导线结构两侧侧壁形成氮化硅间隔层12。其次,请参见第1B图,其显示在导线结构上全面性形成一介电层(氧化硅层)再施行蚀刻平板印刷和蚀刻程序,以定义此介电层而形成如图所示的介电层14及介于此介电层间的接触窗16。接着,请参见第1C图,全面性形成一导电层18,其填满接触窗16而与半导体基底20电性连接,再以化学机械研磨此导电层18,使露出介电层14,而使导电层18形成被绝缘隔离的接触插塞。First, please refer to Fig. 1A, which shows that on the surface of the substrate 2, a wiring structure composed of a silicon oxide substrate layer 4, a polysilicon layer 6 and a tungsten silicide layer 8 is formed, and a silicon nitride layer is formed on the wiring structure. The capping layer 10 and the silicon nitride spacer layer 12 are formed on the silicon nitride capping layer and the sidewalls on both sides of the wiring structure. Next, please refer to FIG. 1B, which shows that a dielectric layer (silicon oxide layer) is formed on the entire wiring structure, and then etching lithography and etching procedures are performed to define this dielectric layer to form a dielectric layer as shown in the figure. layer 14 and contacts 16 between the dielectric layers. Next, referring to FIG. 1C, a conductive layer 18 is formed completely, which fills the contact hole 16 and is electrically connected to the semiconductor substrate 20, and then the conductive layer 18 is chemically mechanically polished to expose the dielectric layer 14, so that The conductive layer 18 forms contact plugs that are isolated by insulation.

当上述传统的自行对准接触工艺形成接触窗16步骤,而施行蚀刻平板印刷和蚀刻氧化硅介电层时,若采用非等向性反应离子蚀刻使用CHF3作为蚀刻剂时,必需使氧化硅层与氮化硅层的被蚀刻速率的比率为20比1以上,以免损伤到氮化硅上盖层10和氮化硅间隔层12,而目前之制造技术尚无法达到此项目标。第2A图显示理想的自行对准接触工艺进行非等向性反应离子蚀刻所形成接触窗16,而第2B图显示进行非等向性反应离子蚀刻后,实际形成的接触窗16,由图中可见氮化硅上盖层10和氮化硅间隔层12已受到蚀刻的损失,而若是损坏太严重,将影响到绝缘及隔离效果,造成导线结构与接触插塞短路。When the above-mentioned traditional self-aligned contact process forms the contact window 16 step, and when performing etching lithography and etching the silicon oxide dielectric layer, if anisotropic reactive ion etching is used and CHF 3 is used as an etchant, it is necessary to make silicon oxide The ratio of the etched rate of the silicon nitride layer to the silicon nitride layer is more than 20 to 1 to avoid damage to the silicon nitride capping layer 10 and the silicon nitride spacer layer 12, which cannot be achieved by the current manufacturing technology. FIG. 2A shows the contact window 16 formed by anisotropic reactive ion etching in an ideal self-aligned contact process, and FIG. 2B shows the contact window 16 actually formed after performing anisotropic reactive ion etching. It can be seen that the silicon nitride capping layer 10 and the silicon nitride spacer layer 12 have been etched. If the damage is too severe, the insulation and isolation effects will be affected, resulting in a short circuit between the wire structure and the contact plug.

以上的缺点使得组件要再缩小尺度显得困难的多,尤其是在深亚微米处理中,只允许更小尺寸的线宽及高深宽比,而若要大幅改善反应离子蚀刻的高选择比目前还要困难,因此若无新的工艺技术突破,将使得产品合格率难以提升,且无法达到经济规模的量产。The above shortcomings make it much more difficult to scale down components, especially in deep sub-micron processing, which only allows smaller line widths and high aspect ratios, and it is still difficult to greatly improve the high selectivity ratio of reactive ion etching. It is difficult, so if there is no breakthrough in new process technology, it will be difficult to improve the product qualification rate, and it will not be possible to achieve mass production on an economical scale.

本发明的目的在于提供一种具有牺牲型填充柱的自行对准接触工艺方法,该方法于实施自行对准接触步骤时不会损害到其它隔离层,而影响隔离效果使得漏电流产生。The purpose of the present invention is to provide a self-aligned contact process method with sacrificial filled columns, which will not damage other isolation layers during the self-aligned contact step, but will affect the isolation effect and cause leakage current.

本发明另一目的在于提供一种具有牺牲型填充柱的自行对准接触工艺方法,该方法无需在反应离子蚀刻工艺中使用高氧化硅对于氮化硅选择比的蚀刻剂来达成自行对准接触步骤。Another object of the present invention is to provide a self-aligned contact process method with sacrificial filled pillars, which does not need to use an etchant with a high selectivity ratio of silicon oxide to silicon nitride in the reactive ion etching process to achieve self-aligned contact step.

本发明尚有另一目的在于提供一种具有牺牲型填充柱自行对准接触工艺方法,该方法采用的绝缘材料可大幅减低导线层间的寄生电容。Still another object of the present invention is to provide a self-aligned contact process method with sacrificial filled pillars. The insulating material used in the method can greatly reduce the parasitic capacitance between wire layers.

简单说,本发明揭露一种具有牺牲型填充柱的自行对准接触方法,首先,提供一半导体基底,在基底上依序形成由氧化硅衬底层、多晶硅层和硅化钨层所组成之导线结构,之后,于导线结构上形成一绝缘上盖层,接着定义出导线结构图。接着,于绝缘上盖层及导线结构两侧侧壁形成一导线绝缘间隔层。其次,顺应性形成一绝缘衬垫层以覆盖导线绝缘间隔层和导线结构表面。其次,全面性形成一牺牲层再施行蚀刻干板印刷和蚀刻程序,定义此牺牲层以形成牺牲型填充柱及介于此牺牲型填充柱间的开口。接着,全面性形成一不同于绝缘衬垫层材料的绝缘层以填满该牺牲型填充柱间的开口。然后,研磨此绝缘层,使露出该牺牲型填充柱的上表面。再者,去除此牺牲型填充柱而形成一接触窗开口。其次,经由接触窗开口利用非等向性反应离子蚀刻工艺去除覆盖于半导体基底上而介于该导线绝缘间隔层间的绝缘衬垫层。最后,全面性形成一导电层填满该接触窗开口而与半导体基底电性连接,再研磨此导电层,使露出绝缘层,而使导电层形成被绝缘隔离的接触插塞。In short, the present invention discloses a self-aligned contact method with sacrificial filled columns. First, a semiconductor substrate is provided, and a wiring structure composed of a silicon oxide substrate layer, a polysilicon layer and a tungsten silicide layer is sequentially formed on the substrate. , and then, forming an insulating upper cover layer on the wire structure, and then defining the wire structure diagram. Next, a wire insulating spacer layer is formed on the insulating upper cover layer and the sidewalls on both sides of the wire structure. Secondly, an insulating liner layer is conformally formed to cover the wire insulating spacer layer and the surface of the wire structure. Secondly, a sacrificial layer is formed on the whole, and then etching dry printing and etching procedures are performed to define the sacrificial layer to form sacrificial filling pillars and openings between the sacrificial filling pillars. Next, an insulating layer different from the material of the insulating liner layer is formed to fill the openings between the sacrificial filling columns. Then, the insulating layer is ground to expose the upper surface of the sacrificial filling column. Furthermore, the sacrificial filled column is removed to form a contact window opening. Secondly, an anisotropic reactive ion etching process is used to remove the insulating liner layer covering the semiconductor substrate and interposed between the wire insulating spacers through the opening of the contact window. Finally, a conductive layer is formed to fill the opening of the contact window and electrically connected to the semiconductor substrate, and then the conductive layer is ground to expose the insulating layer, so that the conductive layer forms a contact plug isolated by insulation.

综上所述,本发明所提供了一种具有牺牲型填充柱的自行对准接触方法,该方法于实施自行对准接触工艺步骤时不会损害到其它隔离层,进而影响隔离效果使得漏电流产生,且此方法无需在反应离子蚀刻方法中使用高氧化硅对于氮化硅选择比的蚀刻剂来达成自行对准接触,此外,本方法所形成覆盖在导线上的绝缘上盖层的厚度可缩减,从而缩小纵宽比,获得较佳的间隙绝缘层填充,本方法采用的绝缘材料可大幅减低导线层间的寄生电容。To sum up, the present invention provides a self-aligned contact method with sacrificial filled columns, which will not damage other isolation layers when implementing the self-aligned contact process steps, thereby affecting the isolation effect and causing leakage current produced, and this method does not need to use an etchant with a high selectivity ratio of silicon oxide to silicon nitride in the reactive ion etching method to achieve self-aligned contacts. In addition, the thickness of the insulating capping layer formed on the wires formed by this method can be Therefore, the aspect ratio is reduced, and better filling of the gap insulating layer is obtained. The insulating material used in this method can greatly reduce the parasitic capacitance between the wire layers.

为了让本发明之上述和其它目的、特征、及优点能更明显易懂,下文特举出较佳实施例,并配合附图,作详细说明如下:In order to make the above-mentioned and other purposes, features, and advantages of the present invention more obvious and understandable, the preferred embodiments are specially cited below, and in conjunction with the accompanying drawings, the detailed description is as follows:

第1A至1C图为公知技术的自行对准接触工艺的制造流程剖面图。1A to 1C are cross-sectional views of the manufacturing process of the self-aligned contact process in the prior art.

第2A图显示理想的自行对准接触工艺所形成的接触窗的剖面图。FIG. 2A shows a cross-sectional view of a contact window formed by an ideal self-aligned contact process.

第2B图显示进行非等向性反应离子蚀刻后,实际形成的接触窗的剖面图。FIG. 2B shows a cross-sectional view of the actually formed contact window after performing anisotropic reactive ion etching.

第3A至3F图为根据本发明实施例1的具有牺牲型填充柱的自行对准接触工艺的制造流程剖面图。3A to 3F are cross-sectional views of the manufacturing process of the self-aligned contact process with sacrificial filled pillars according to Embodiment 1 of the present invention.

第4A至4F图为根据本发明实施例2的具有牺牲型填充柱的自行对准接触工艺的制造流程剖面图。4A to 4F are cross-sectional views of the manufacturing process of the self-aligned contact process with sacrificial filled pillars according to Embodiment 2 of the present invention.

第5A至5F图为根据本发明实施例3的具有牺牲型填充柱的自行对准接触工艺的制造流程剖面图。5A to 5F are cross-sectional views of the manufacturing process of the self-aligned contact process with sacrificial filled pillars according to Embodiment 3 of the present invention.

符号说明Symbol Description

20、40、60~半导体基底;22、42、62~氧化硅衬底层;24、44、64~多晶硅层;26、46、66~硅化钨层;28、48、68绝缘上盖层;30、52~绝缘间隔层;32、50~绝缘衬垫层;70~第一绝缘衬垫层;72~第二绝缘衬垫层;34、54、74~牺牲型填充柱;36、56、76~开口;37、57、77~接触窗开口;38、58、78~绝缘层;39、59、79~导电层。20, 40, 60 ~ semiconductor substrate; 22, 42, 62 ~ silicon oxide substrate layer; 24, 44, 64 ~ polysilicon layer; 26, 46, 66 ~ tungsten silicide layer; 28, 48, 68 insulating upper cover layer; 30 , 52~ insulating spacer layer; 32, 50~ insulating liner layer; 70~ first insulating liner layer; 72~ second insulating liner layer; 34, 54, 74~ sacrificial filled column; 36, 56, 76 ~ opening; 37, 57, 77 ~ contact window opening; 38, 58, 78 ~ insulating layer; 39, 59, 79 ~ conductive layer.

实施例1Example 1

本实施例为参照第3A至3F图,说明根据本发明改进方法的一个较佳实施例。首先,如第3A图所示,提供一半导体基底20,例如是一硅晶片,其上可以形成任何所需的半导体组件,例如是晶体管组件,此处为了简化起见,仅以一平整的基底20表示之。在基底20的表面上,依序形成由一氧化硅衬底层22、一多晶硅层24和一硅化钨层26所组成的导线结构,例如先利用一热氧化工艺形成一薄氧化硅衬底层22,然后以一等离子体增强化学气相沉积(PECVD)成形一多晶硅层24和一硅化钨层26,之后,于导线结构上形成一绝缘上盖层28,例如以一等离子体(plasma)增强化学气相沉积(PECVD)或低压化学气相沉积(LPCVD)成形一厚度为200至2500之二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。接着,实行蚀刻平板印刷和蚀刻程序,定义出如图所示的氧化硅衬底层22、多晶硅层24、硅化钨层26和绝缘上盖层28所组成的导线结构图。接着,于绝缘上盖层及导线结构两侧侧壁形成一导线绝缘间隔层30,亦以一等离子体增强化学气相沉积(PECVD)或低压化学气相沉积(LPCVD)成形一厚度为100至600之二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。再回蚀刻(etching-back)此薄膜层形成一绝缘间隔层30。其次,顺应性形成一绝缘衬垫层32以覆盖导线绝缘间隔层和导线结构表面,亦以等离子体增强化学气相沉积(PECVD)或低压化学气相沉积(LPCVD)成形一厚度为100至400之二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。This embodiment illustrates a preferred embodiment of the improved method according to the present invention with reference to Figures 3A to 3F. First, as shown in FIG. 3A, a semiconductor substrate 20 is provided, such as a silicon wafer, on which any required semiconductor components, such as transistor components, can be formed. Here, for the sake of simplicity, only a flat substrate 20 is used. express it. On the surface of the substrate 20, a wiring structure composed of a silicon oxide substrate layer 22, a polysilicon layer 24 and a tungsten silicide layer 26 is sequentially formed, for example, a thin silicon oxide substrate layer 22 is first formed by a thermal oxidation process, Then form a polysilicon layer 24 and a tungsten silicide layer 26 with a plasma enhanced chemical vapor deposition (PECVD), after that, form an insulating upper cap layer 28 on the wire structure, for example, with a plasma (plasma) enhanced chemical vapor deposition (PECVD) or low-pressure chemical vapor deposition (LPCVD) to form a silicon dioxide layer, silicon nitride layer, silicon oxynitride layer, aluminum oxide layer or silicon carbide layer with a thickness of 200 to 2500 Å. Next, implement etching lithography and etching procedures to define the wire structure diagram composed of silicon oxide substrate layer 22 , polysilicon layer 24 , tungsten silicide layer 26 and insulating upper cover layer 28 as shown in the figure. Next, form a wire insulation spacer layer 30 on the insulating upper cover layer and the side walls on both sides of the wire structure, and form a thickness of 100 to 600 Å by plasma enhanced chemical vapor deposition (PECVD) or low pressure chemical vapor deposition (LPCVD). Silicon dioxide layer, silicon nitride layer, silicon oxynitride layer, aluminum oxide layer or silicon carbide layer. Etching-back the film layer to form an insulating spacer layer 30 . Next, an insulating liner layer 32 is conformably formed to cover the wire insulating spacer layer and the surface of the wire structure, and a thickness of 100 to 400 Å is also formed by plasma enhanced chemical vapor deposition (PECVD) or low pressure chemical vapor deposition (LPCVD). A silicon dioxide layer, a silicon nitride layer, a silicon oxynitride layer, an aluminum oxide layer or a silicon carbide layer.

其次,请参见第3B图,全面性形成一牺牲层再施行蚀刻平板印刷和蚀刻程序,定义此牺牲层以形成牺牲型填充柱34及介于此牺牲型填充柱间的开口36。此牺牲层可为一多晶硅层,由于之前已形成绝缘间隔层30及绝缘衬垫层32,所以可以防止蚀刻此多晶硅层时产生残留物而造成电性短路。Next, referring to FIG. 3B , a sacrificial layer is fully formed and then etched lithography and etching procedures are performed to define the sacrificial layer to form sacrificial filled pillars 34 and openings 36 between the sacrificial filled pillars. The sacrificial layer can be a polysilicon layer. Since the insulating spacer layer 30 and the insulating liner layer 32 have been formed before, it can prevent electrical short circuit caused by residues generated during etching the polysilicon layer.

接着,请参见第3C图,全面形成一不同于绝缘衬垫层材料的绝缘层以填满该牺牲型填充柱间的开口36,例如以一等离子体增强化学气相沉积(PECVD)成形一厚度5000至8000的氧化物层。Next, referring to FIG. 3C, an insulating layer different from the material of the insulating liner layer is formed to fill the opening 36 between the sacrificial filling columns, for example, a plasma enhanced chemical vapor deposition (PECVD) is used to form a thickness of 5000 to 8000 Å oxide layer.

然后,利用平坦化工艺,如化学机械研磨,研磨此绝缘层,使露出该牺牲型填充柱的上表面,形成如图所示的绝缘层38的图案,例如调整工艺参数中的转盘速度,下压力,研磨垫类型和研磨剂种类以控制工艺中的移除率,均匀性和选择性,磨除此绝缘层的上部。Then, use a planarization process, such as chemical mechanical polishing, to polish the insulating layer, so that the upper surface of the sacrificial filled column is exposed, and the pattern of the insulating layer 38 as shown in the figure is formed. For example, the speed of the turntable in the process parameters is adjusted. Pressure, pad type and abrasive type to control the removal rate, uniformity and selectivity in the process, abrading the upper part of this insulating layer.

再者,请参见第3D图,利用等向性干蚀刻工艺或等向性湿蚀刻工艺对牺牲型填充柱进行回蚀刻以去除此牺牲型填充柱而形成一接触窗开口37。Furthermore, referring to FIG. 3D , an isotropic dry etching process or an isotropic wet etching process is used to etch back the sacrificial filling column to remove the sacrificial filling column to form a contact window opening 37 .

其次,请参见第3E图,经由接触窗开口37利用非等向性反应离子蚀刻制程以去除覆盖于半导体基底上而介于该导线绝缘间隔层间的绝缘衬垫层。Next, please refer to FIG. 3E , anisotropic reactive ion etching process is used through the contact opening 37 to remove the insulating liner layer covering the semiconductor substrate and interposed between the wire insulating spacers.

最后,请参见第3F图,全面形成一导电层39,填满该接触窗开口37而与半导体基底20电性连接,再以化学机械研磨此导电层39,使露出绝缘层38,而使导电层39形成被绝缘隔离之接触插塞,其中,此导电层是溅镀多晶硅层或钨层。Finally, referring to FIG. 3F, a conductive layer 39 is formed on the entire surface, fills the contact opening 37 and is electrically connected to the semiconductor substrate 20, and then chemically mechanically polishes the conductive layer 39 to expose the insulating layer 38 and make the conductive layer 39 conductive. Layer 39 forms contact plugs isolated by insulation, wherein the conductive layer is a sputtered polysilicon layer or a tungsten layer.

实施例2Example 2

本实施例为参照第4A至4F图,说明根据本发明改进方法的另一较佳实施例。首先,如第4A图所示,在半导体基底40的表面上,依序形成由一氧化硅衬底层42、一多晶硅层44和一硅化钨层46所组成的导线结构,例如先利用一热氧化步骤形成一薄氧化硅衬底层42,然后以一等离子体增强化学气相沉积(PECVD)成形一多晶硅层44和一硅化钨层46,之后,于导线结构上形成一绝缘上盖层48,例如以一等离子体增强化学气相沉积(PECVD)或低压化学气相沉积(LPCVD)成形一厚度为200至2500的二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。接着,实行蚀刻平板印刷和蚀刻程序,定义出如图所示的氧化硅衬底层42、多晶硅层44、硅化钨层46和绝缘上盖层48所组成的导线结构图。接着,顺应性形成一绝缘衬垫层50以覆盖导线结构表面,亦以等离子体增强化学气相沉积(PECVD)或低压化学气相沉积(LPCVD)成形一厚度为100至400的二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。其次,于覆盖导线结构的绝缘衬垫层两侧侧壁形成一导线绝缘间隔层52,亦以等离子体增强化学气相沉积(PECVD)或低压化学气相沉积(LPCVD)成形一厚度为100至600的二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。再回蚀刻(etching-back)此薄膜层形成一绝缘间隔层52。This embodiment illustrates another preferred embodiment of the improved method according to the present invention with reference to FIGS. 4A to 4F. First, as shown in FIG. 4A, on the surface of the semiconductor substrate 40, a wiring structure composed of a silicon oxide substrate layer 42, a polysilicon layer 44 and a tungsten silicide layer 46 is sequentially formed, for example, using a thermal oxidation The steps form a thin silicon oxide substrate layer 42, then form a polysilicon layer 44 and a tungsten silicide layer 46 with a plasma enhanced chemical vapor deposition (PECVD), and then form an insulating upper cap layer 48 on the wire structure, for example, with A plasma enhanced chemical vapor deposition (PECVD) or low pressure chemical vapor deposition (LPCVD) forms a silicon dioxide layer, silicon nitride layer, silicon oxynitride layer, aluminum oxide layer or silicon carbide layer with a thickness of 200 to 2500 Å. Next, implement etching lithography and etching procedures to define the wire structure diagram composed of silicon oxide substrate layer 42 , polysilicon layer 44 , tungsten silicide layer 46 and insulating upper cover layer 48 as shown in the figure. Next, conformally form an insulating liner layer 50 to cover the surface of the wire structure, and form a silicon dioxide layer with a thickness of 100 to 400 Å by plasma enhanced chemical vapor deposition (PECVD) or low pressure chemical vapor deposition (LPCVD), A silicon nitride layer, a silicon oxynitride layer, an aluminum oxide layer or a silicon carbide layer. Next, a wire insulating spacer layer 52 is formed on both sides of the insulating liner layer covering the wire structure, and a thickness of 100 to 600 Å is also formed by plasma enhanced chemical vapor deposition (PECVD) or low pressure chemical vapor deposition (LPCVD). Silicon dioxide layer, silicon nitride layer, silicon oxynitride layer, aluminum oxide layer or silicon carbide layer. Etching-back the film layer to form an insulating spacer layer 52 .

其次,请参见第4B图,全面形成一牺牲层再施行蚀刻平板印刷和蚀刻程序,定义此牺牲层以形成牺牲型填充柱54及介于此牺牲型填充柱间的开口56。此牺牲层可为一多晶硅层,由于之前已形成绝缘间隔层50及绝缘衬垫层52,所以可以防止蚀刻此多晶硅层时产生残留物而造成电性短路。Next, referring to FIG. 4B , a sacrificial layer is fully formed and then etched lithography and etching procedures are performed to define the sacrificial layer to form sacrificial filled pillars 54 and openings 56 between the sacrificial filled pillars. The sacrificial layer can be a polysilicon layer. Since the insulating spacer layer 50 and the insulating liner layer 52 have been formed before, it can prevent electrical short circuit caused by residues generated during etching the polysilicon layer.

接着,请参见第4C图,全面形成一不同于绝缘衬垫层材料的绝缘层以填满该牺牲型填充柱间的开口56,例如以一等离子体增强化学气相沉积(PECVD)成形一厚度5000至8000的氧化物层。Next, referring to FIG. 4C, an insulating layer different from the material of the insulating liner layer is formed to fill the opening 56 between the sacrificial filling columns, for example, a thickness of 5000 is formed by plasma enhanced chemical vapor deposition (PECVD). to 8000 Å oxide layer.

然后,利用平坦化工艺,如化学机械研磨,研磨此绝缘层,使露出该牺牲型填充柱的上表面,形成如图所示的绝缘层58的图案,例如调整工艺参数中的转盘速度,下压力,研磨垫类型和研磨剂种类以控制工艺中的移除率,均匀性和选择性,磨除此绝缘层的上部。Then, use a planarization process, such as chemical mechanical polishing, to polish the insulating layer, so that the upper surface of the sacrificial filled column is exposed, and the pattern of the insulating layer 58 as shown in the figure is formed. Pressure, pad type and abrasive type to control the removal rate, uniformity and selectivity in the process, abrading the upper part of this insulating layer.

再者,请参见第4D图,利用等向性干蚀刻工艺或等向性湿蚀刻工艺对牺牲型填充柱进行回蚀刻以去除此牺牲型填充柱而形成一接触窗开口57。Furthermore, referring to FIG. 4D , an isotropic dry etching process or an isotropic wet etching process is used to etch back the sacrificial filling column to remove the sacrificial filling column to form a contact window opening 57 .

其次,请参见第4E图,经由接触窗开口57利用非等向性反应离子蚀刻工艺以去除覆盖于半导体基底之上而介于该导线绝缘间隔层间的绝缘衬垫层。Next, referring to FIG. 4E , anisotropic reactive ion etching process is used through the contact opening 57 to remove the insulating liner layer covering the semiconductor substrate and interposed between the wire insulating spacers.

最后,请参见第4F图,全面性形成一导电层59,其穿过绝缘层58而与半导体基底40电性连接,再以化学机械研磨此导电层59,使露出绝缘层58,而使导电层59形成被绝缘隔离的接触插塞,其中,此导电层是溅镀多晶硅层或钨层。Finally, referring to FIG. 4F, a conductive layer 59 is formed comprehensively, which passes through the insulating layer 58 and is electrically connected to the semiconductor substrate 40, and then the conductive layer 59 is chemically mechanically polished to expose the insulating layer 58 and make the conductive layer 59 conductive. Layer 59 forms contact plugs that are isolated by insulation, wherein the conductive layer is a sputtered polysilicon layer or a tungsten layer.

实施例3Example 3

本实施例为参照第5A至5F图,说明根据本发明改进方法的另一较佳实施例。首先,如第5A图所示,在半导体基底60的表面上,依序形成由一氧化硅衬底层62、一多晶硅层64和一硅化钨层66所组成的导线结构,例如先利用一热氧化步骤形成一薄氧化硅衬底层62,然后以一等离子体增强化学气相沉积(PECVD)成形一多晶硅层64和一硅化钨层66,之后,于导线结构上形成一绝缘上盖层68,例如以等离子体增强化学气相沉积(PECVD)或低压化学气相沉积(LPCVD)成形一厚度为200至2500的二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。接着,施行蚀刻平板印刷和蚀刻程序,定义出如图所示的氧化硅衬底层62、多晶硅层64、硅化钨层66和绝缘上盖层68所组成的导线结构图。接着,顺应性形成一第一绝缘衬垫层70及一第二绝缘衬垫层72以覆盖导线结构表面,亦以一等离子体增强化学气相沉积(PECVD)或低压化学气相沉积(LPCVD)成形一厚度为100至600的氮化硅层70及一厚度为100至600的氧化物层72。This embodiment illustrates another preferred embodiment of the improved method according to the present invention with reference to Figures 5A to 5F. First, as shown in FIG. 5A, on the surface of the semiconductor substrate 60, a wiring structure composed of a silicon oxide substrate layer 62, a polysilicon layer 64 and a tungsten silicide layer 66 is sequentially formed, for example, using a thermal oxidation The step is to form a thin silicon oxide substrate layer 62, then form a polysilicon layer 64 and a tungsten silicide layer 66 by a plasma enhanced chemical vapor deposition (PECVD), and then form an insulating upper cap layer 68 on the wiring structure, for example with Plasma enhanced chemical vapor deposition (PECVD) or low pressure chemical vapor deposition (LPCVD) forms a silicon dioxide layer, silicon nitride layer, silicon oxynitride layer, aluminum oxide layer or silicon carbide layer with a thickness of 200 to 2500 Å. Next, implement etching lithography and etching procedures to define the wire structure diagram composed of silicon oxide substrate layer 62 , polysilicon layer 64 , tungsten silicide layer 66 and insulating upper cap layer 68 as shown in the figure. Next, a first insulating liner layer 70 and a second insulating liner layer 72 are conformally formed to cover the surface of the wire structure, and a plasma-enhanced chemical vapor deposition (PECVD) or low-pressure chemical vapor deposition (LPCVD) is also used to form a A silicon nitride layer 70 having a thickness of 100 to 600 Å and an oxide layer 72 having a thickness of 100 to 600 Å.

其次,请参见第5B图,全面性形成一牺牲层再施行蚀刻平板印刷和蚀刻程序,定义此牺牲层以形成牺牲型填充柱74及介于此牺牲型填充柱间的开口76。此牺牲层可为一多晶硅层,由于之前已形成绝缘间隔层70及绝缘衬垫层72,所以可以防止蚀刻此多晶硅层时产生残留物而造成电性短路。Next, referring to FIG. 5B , a sacrificial layer is fully formed and then etched lithography and etching procedures are performed to define the sacrificial layer to form sacrificial filled pillars 74 and openings 76 between the sacrificial filled pillars. The sacrificial layer can be a polysilicon layer. Since the insulating spacer layer 70 and the insulating liner layer 72 have been formed before, it can prevent electrical short circuit caused by residues generated during etching the polysilicon layer.

接着,请参见第5C图,全面性形成一不同于绝缘衬垫层材料的绝缘层以填满该牺牲型填充柱间的开口76,例如以一等离子体增强化学气相沉积(PECVD)成形一厚度5000至8000的氧化物层。Next, referring to FIG. 5C, an insulating layer different from the material of the insulating liner layer is formed comprehensively to fill the opening 76 between the sacrificial filling columns, for example, a plasma-enhanced chemical vapor deposition (PECVD) is used to form a thickness 5000 to 8000 Å oxide layer.

然后,利用平坦化工艺,如化学机械研磨,研磨此绝缘层,使露出该牺牲型填充柱的上表面,形成如图所示的绝缘层78的图案,例如调整工艺参数中的转盘速度,下压力,研磨垫类型和研磨剂种类以控制工艺中的移除率,均匀性和选择性,磨除此绝缘层之上部。Then, use a planarization process, such as chemical mechanical polishing, to grind the insulating layer, so that the upper surface of the sacrificial filled column is exposed, and the pattern of the insulating layer 78 as shown in the figure is formed, for example, the speed of the turntable in the process parameters is adjusted, and the following Pressure, pad type and abrasive type to control the removal rate, uniformity and selectivity in the process, abrading the upper part of this insulating layer.

再者,请参见第5D图,利用等向性干蚀刻工艺或等向性湿蚀刻工艺对牺牲型填充柱进行回蚀刻以去除此牺牲型填充柱而形成一接触窗开口77。Furthermore, referring to FIG. 5D , the sacrificial filling column is etched back by an isotropic dry etching process or an isotropic wet etching process to remove the sacrificial filling column to form a contact window opening 77 .

其次,请参见第5E图,经由接触窗开口77利用非等向性反应离子蚀刻工艺以去除覆盖于半导体基底之上而介于该导线绝缘间隔层间的绝缘衬垫层。Next, referring to FIG. 5E , anisotropic reactive ion etching process is used through the contact opening 77 to remove the insulating liner layer covering the semiconductor substrate and interposed between the wire insulating spacers.

最后,请参见第5F图,全面性形成一导电层79,其穿过绝缘层78而与半导体基底60电性连接,再以化学机械研磨此导电层79,使露出绝缘层78,而使导电层79形成被绝缘隔离的接触插塞,其中,此导电层是溅镀多晶硅层或钨层。Finally, referring to FIG. 5F, a conductive layer 79 is formed comprehensively, which passes through the insulating layer 78 and is electrically connected to the semiconductor substrate 60, and then the conductive layer 79 is chemically mechanically polished to expose the insulating layer 78 and make the conductive layer 79 electrically conductive. Layer 79 forms contact plugs that are isolated by insulation, wherein the conductive layer is a sputtered polysilicon layer or a tungsten layer.

本发明虽然已以较佳实施例披露如上,然而并非用以限定本发明,任何熟知本领域技术者,在不脱离本发明之精神和范围内,当可作更动与润饰,因此本发明的保护范围应视后附的权利要求范围并参考说明书以及附图所界定者为准。Although the present invention has been disclosed above with preferred embodiments, it is not intended to limit the present invention. Any person skilled in the art can make changes and modifications without departing from the spirit and scope of the present invention. Therefore, the present invention The scope of protection should be determined by the scope of the appended claims and with reference to the specification and drawings.

Claims (20)

1.一种具有牺牲型填充柱的自行对准接触工艺方法,适用于一半导体基底,该方法包括下列步骤:1. A self-aligned contact process method with sacrificial filled columns is applicable to a semiconductor substrate, the method comprising the following steps: (a)于该半导体基底上形成一导线结构;(a) forming a wire structure on the semiconductor substrate; (b)于该导线结构上形成一绝缘上盖层;(b) forming an insulating capping layer on the lead structure; (c)于该绝缘上盖层及导线结构两侧侧壁形成一导线绝缘间隔层;(c) forming a wire insulating spacer layer on the insulating upper cover layer and the side walls on both sides of the wire structure; (d)形成一绝缘衬垫层以覆盖该导线绝缘间隔层和该导线结构表面;(d) forming an insulating liner layer to cover the wire insulating spacer layer and the surface of the wire structure; (e)形成一牺牲层,并定义该牺牲层以形成牺牲型填充柱及介于该牺牲型填充柱间的开口;(e) forming a sacrificial layer and defining the sacrificial layer to form sacrificial packed posts and openings between the sacrificial packed posts; (f)形成一不同于该绝缘衬垫层材料的绝缘层以填满该牺牲型填充柱间的开口;(f) forming an insulating layer different from the material of the insulating liner layer to fill the opening between the sacrificial filling columns; (g)去除该牺牲型填充柱而形成一接触窗开口;(g) removing the sacrificial filled column to form a contact opening; (h)经由该接触窗开口去除覆盖于该半导体基底上而介于该导线绝缘间隔层间的该绝缘衬垫层;及(h) removing the insulating liner layer covering the semiconductor substrate and interposed between the wire insulating spacers through the contact window opening; and (i)形成一导电层填满该接触窗开口且与该半导体基底电性连接。(i) forming a conductive layer to fill the opening of the contact window and electrically connect with the semiconductor substrate. 2.如权利要求1所述的方法,其特征在于,该步骤(a)中的导线结构是由氧化硅衬底层、多晶硅层和硅化钨层所组成。2. The method according to claim 1, wherein the wire structure in the step (a) is composed of a silicon oxide substrate layer, a polysilicon layer and a tungsten silicide layer. 3.权利要求1所述的方法,其特征在于,该绝缘上盖层、该导线绝缘间隔层及该绝缘衬垫层是为二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。3. The method according to claim 1, characterized in that, the insulating upper cover layer, the wire insulating spacer layer and the insulating liner layer are silicon dioxide layer, silicon nitride layer, silicon oxynitride layer, aluminum oxide layer or SiC layer. 4.权利要求1所述的方法,其特征在于,该步骤(f)还包括用化学机械研磨该绝缘层,使露出该牺牲型填充柱之上表面。4. The method of claim 1, wherein the step (f) further comprises chemical mechanical polishing the insulating layer to expose the upper surface of the sacrificial filled pillar. 5.权利要求1所述的方法,其特征在于,该步骤(g)中之去除该牺牲型填充柱,利用等向性干蚀刻工艺或等向性湿蚀刻工艺对该牺牲型填充柱进行回蚀刻。5. The method according to claim 1, characterized in that, in removing the sacrificial filled column in the step (g), the sacrificial filled column is regenerated by an isotropic dry etching process or an isotropic wet etching process. etch. 6.权利要求1所述的方法,其特征在于,该步骤(h)中去除覆盖于该半导体基底之上而介于该导线绝缘间隔层间的绝缘衬垫层是利用非等向性反应离子蚀刻工艺完成。6. The method according to claim 1, characterized in that, in the step (h), removing the insulating liner layer covered on the semiconductor substrate and interposed between the wire insulating spacers is to utilize anisotropic reactive ions The etching process is complete. 7.权利要求1所述的方法,其特征在于,该步骤(i)中的导电层是为多晶硅层或钨层,并采用化学机械研磨该导电层,使露出该绝缘层,而使该导电层形成被绝缘隔离的接触插塞。7. The method according to claim 1, characterized in that, the conductive layer in the step (i) is a polysilicon layer or a tungsten layer, and chemical mechanical grinding is used to polish the conductive layer to expose the insulating layer and make the conductive layer The layers form contact plugs that are isolated by insulation. 8.一种具有牺牲型填充柱的自行对准接触工艺方法,适用于一半导体基底,该方法包括下列步骤:8. A self-aligned contact process method with sacrificial filled columns, suitable for a semiconductor substrate, the method comprising the following steps: (a)于该半导体基底上形成一导线结构;(a) forming a wire structure on the semiconductor substrate; (b)于该导线结构上形成一绝缘上盖层;(b) forming an insulating capping layer on the lead structure; (c)形成一绝缘衬垫层以覆盖该导线结构表面;(c) forming an insulating liner layer to cover the surface of the wire structure; (d)于覆盖该导线结构之该绝缘衬垫层两侧侧壁形成一导线绝缘间隔层;(d) forming a wire insulating spacer layer on the side walls of both sides of the insulating liner layer covering the wire structure; (e)形成一牺牲层,并定义该牺牲层以形成牺牲型填充柱及介于该牺牲型填充柱间的开口;(e) forming a sacrificial layer and defining the sacrificial layer to form sacrificial packed posts and openings between the sacrificial packed posts; (f)形成一不同于该绝缘衬垫层材料的绝缘层以填满该牺牲型填充柱间的开口;(f) forming an insulating layer different from the material of the insulating liner layer to fill the opening between the sacrificial filling columns; (g)去除该牺牲型填充柱而形成一接触窗开口;(g) removing the sacrificial filled column to form a contact opening; (h)经由该接触窗开口去除覆盖于该半导体基底之上而介于该导线绝缘间隔层间的所述的绝缘衬垫层;及(h) removing the insulating liner layer covering the semiconductor substrate and interposed between the wire insulating spacers through the contact window opening; and (i)形成一导电层填满该接触窗开口且与该半导体基底电性连接。(i) forming a conductive layer to fill the opening of the contact window and electrically connect with the semiconductor substrate. 9.权利要求8所述的方法,其特征在于,该步骤(a)中的导线结构是由氧化硅衬底层、多晶硅层和硅化钨层所组成。9. The method according to claim 8, characterized in that the wire structure in the step (a) is composed of a silicon oxide substrate layer, a polysilicon layer and a tungsten silicide layer. 10.权利要求8所述的方法,其特征在于,该绝缘上盖层、该导线绝缘间隔层及该绝缘衬垫层是为二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。10. The method according to claim 8, characterized in that, the insulating upper cover layer, the wire insulating spacer layer and the insulating liner layer are silicon dioxide layer, silicon nitride layer, silicon oxynitride layer, aluminum oxide layer or SiC layer. 11.权利要求8所述的方法,其特征在于,该步骤(f)还包括采用化学机械研磨该绝缘层,使露出该牺牲型填充柱的上表面。11 . The method of claim 8 , wherein the step (f) further comprises chemical mechanical polishing the insulating layer to expose the upper surface of the sacrificial filled pillar. 12 . 12.权利要求8所述的方法,其特征在于,该步骤(g)中的去除该牺牲型填充柱,是利用等向性干蚀刻工艺或等向性湿蚀刻工艺对该牺牲型填充柱进行回蚀刻。12. The method according to claim 8, characterized in that, removing the sacrificial filled column in the step (g) is to use an isotropic dry etching process or an isotropic wet etching process to carry out the sacrificial filled column etch back. 13.权利要求8所述的方法,其特征在于,该步骤(h)中的去除覆盖于该半导体基底之上而介于该导线绝缘间隔层间的该绝缘衬垫层系利用非等向性反应离子蚀刻工艺完成。13. The method according to claim 8, characterized in that, the removal of the insulating liner layer covering the semiconductor substrate and interposed between the wire insulating spacers in the step (h) utilizes anisotropy The reactive ion etching process is completed. 14.权利要求8所述的方法,其特征在于,该步骤(i)中的导电层是多晶硅层或钨层,并采用化学机械研磨该导电层,使露出该绝缘层,而使该导电层形成被绝缘隔离的接触插塞。14. The method according to claim 8, characterized in that, the conductive layer in the step (i) is a polysilicon layer or a tungsten layer, and the conductive layer is chemically mechanically ground to expose the insulating layer, so that the conductive layer Contact plugs isolated by insulation are formed. 15.一种具有牺牲型填充柱的自行对准接触工艺方法,适用于一半导体基底,该方法包括下列步骤:15. A self-aligned contact process method with sacrificial filled columns, suitable for a semiconductor substrate, the method comprising the following steps: (a)于该半导体基底上形成一导线结构;(a) forming a wire structure on the semiconductor substrate; (b)于该导线结构上形成一绝缘上盖层;(b) forming an insulating capping layer on the lead structure; (c)形成一第一绝缘衬垫层以覆盖该导线结构表面;(c) forming a first insulating liner layer to cover the surface of the wire structure; (d)形成一第二绝缘衬垫层以覆盖该第一绝缘衬垫层;(d) forming a second insulating liner layer to cover the first insulating liner layer; (e)形成一牺牲层,并定义该牺牲层以形成牺牲型填充柱及介于该牺牲型填充柱间的开口;(e) forming a sacrificial layer and defining the sacrificial layer to form sacrificial packed posts and openings between the sacrificial packed posts; (f)形成一不同于该第一绝缘衬垫层材料之绝缘层以填满该牺牲型填充柱间的开口;(f) forming an insulating layer different from the material of the first insulating liner layer to fill the openings between the sacrificial filling columns; (g)去除该牺牲型填充柱而形成一接触窗开口;(g) removing the sacrificial filled column to form a contact opening; (h)经由该接触窗开口去除覆盖于该半导体基底之上而介于该导线结构间的第一绝缘衬垫层、第二绝缘衬垫层;及(h) removing the first insulating liner layer and the second insulating liner layer covering the semiconductor substrate and interposed between the wire structures through the contact window opening; and (i)形成一导电层填满该接触窗开口且与该半导体基底电性连接。(i) forming a conductive layer to fill the opening of the contact window and electrically connect with the semiconductor substrate. 16.如申请专利范围第15项所述之方法,其中,该绝缘上盖层、该导线绝缘间隔层及该绝缘衬垫层是为二氧化硅层、氮化硅层、氮氧化硅层、氧化铝层或碳化硅层。16. The method as described in item 15 of the scope of patent application, wherein the insulating upper cover layer, the wire insulating spacer layer and the insulating liner layer are silicon dioxide layer, silicon nitride layer, silicon oxynitride layer, Aluminum oxide layer or silicon carbide layer. 17.如申请专利范围第15项所述之方法,其中,该步骤(f)还包括采用化学机械研磨该绝缘层,使露出该牺牲型填充柱之上表面。17. The method as described in claim 15, wherein the step (f) further includes chemical mechanical polishing of the insulating layer to expose the upper surface of the sacrificial filled pillar. 18.如申请专利范围第15项所述之方法,其中,该步骤(g)中的去除该牺牲型填充柱,是利用等向性干蚀刻工艺或等向性湿蚀刻工艺对该牺牲型填充柱进行回蚀刻。18. The method as described in item 15 of the scope of patent application, wherein the removal of the sacrificial filling column in the step (g) is to use an isotropic dry etching process or an isotropic wet etching process to fill the sacrificial type The pillars are etched back. 19.如申请专利范围第15项所述之方法,其中,该步骤(h)中的去除覆盖于该半导体基底之上,而介于该导线绝缘间隔层间的该绝缘衬垫层是利用非等向性反应离子蚀刻工艺完成。19. The method as described in item 15 of the claimed scope of patents, wherein the removal in the step (h) is covered on the semiconductor substrate, and the insulating liner layer between the insulating spacer layers of the wires is made of non- The isotropic reactive ion etching process is completed. 20.如申请专利范围第15项所述之方法,其中,该步骤(i)中的导电层是为多晶硅层或钨层,并采用化学机械研磨该导电层,使露出该绝缘层,而使该导电层形成被绝缘隔离的接触插塞。20. The method as described in item 15 of the scope of patent application, wherein the conductive layer in the step (i) is a polysilicon layer or a tungsten layer, and chemical mechanical grinding is used to polish the conductive layer to expose the insulating layer, so that The conductive layer forms contact plugs that are isolated by insulation.
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