CN1378262A - Manufacturing method of dynamic random access memory capacitor - Google Patents
Manufacturing method of dynamic random access memory capacitor Download PDFInfo
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本发明是关于一种半导体制程,特别是关于一种深次微米(deepsub-micron),动态随机存储器(Dynamic Random Access Memory,DRAM)电容器(capacitor)的制造方法。The present invention relates to a semiconductor manufacturing process, in particular to a deep sub-micron (deepsub-micron), dynamic random access memory (Dynamic Random Access Memory, DRAM) capacitor (capacitor) manufacturing method.
动态随机存储器是一种广泛应用的集成电路组件,尤其在信息电子业中更居不可或缺的地位。而随着产业发展,对于更高容量的动态随机存储器的需求也随之增加,相关业界无不努力研发以满足高容量密度的要求,并在组件缩小化的同时如何保持其原有性质,此为业内人士共同面临的问题之一。DRAM is a widely used integrated circuit component, especially in the information electronics industry is more indispensable. With the development of the industry, the demand for higher-capacity DRAMs has also increased. The related industries have been working hard to meet the requirements of high-capacity density, and how to maintain their original properties while reducing the size of components. One of the common problems faced by people in the industry.
公知堆栈式动态随机存储器(stack DRAM)存储单元数组一般至少需要包括定义主动区(active area,AA),定义字符线(word line,WL),定义自动对准接触窗(self-aligned contact,SAC),定义位线接触窗(bitline contact,BC),定义位线(bit line,BL)以及节点接触窗(node contact,CN)等6道光罩始能完成。图1是公知堆栈式位线上电容器(capacitorover bit line,COB)动态随机存储器的剖面图,是利用隔离结构102在基底100上定义主动区104,包括字符线106、位线108以及电容器110等,其中位线108与电容器110分别以自动对准接触窗112以及节点接触窗114与基底100电性连接,至于字符线、位线108以及电容器110的间则有介电材料116绝缘。Known stack type dynamic random access memory (stack DRAM) storage cell array generally needs to comprise definition active area (active area, AA) at least, definition word line (word line, WL), definition self-aligned contact window (self-aligned contact, SAC) ), defining the bitline contact (BC), defining the bitline (BL) and the node contact (CN) and other six masks can be completed. 1 is a cross-sectional view of a known stacked capacitor over bit line (COB) DRAM, which uses an isolation structure 102 to define an active region 104 on a substrate 100, including word lines 106, bit lines 108, and capacitors 110. , wherein the bit line 108 and the capacitor 110 are electrically connected to the substrate 100 through the self-alignment contact 112 and the node contact 114 respectively, and the word line, the bit line 108 and the capacitor 110 are insulated by a dielectric material 116 .
上述的六道光罩中包括了一道定义主动区104的岛状光罩(islandpattern),二道包括定义字符线106以及位线的线光罩(line/spacepattern),与三道包括自动对准接触窗112、位线接触窗,以及节点接触窗114的接触洞光罩(contact hole pattern)。随着动态随机存储器芯片尺寸设计规则(design rule)的缩小,接触窗的尺寸也需随之缩小,对于目前的微影制程而言,将是一项极大的挑战。The above-mentioned six masks include an island pattern defining the active area 104, two including a line/space pattern defining the word lines 106 and bit lines, and three including an automatic alignment contact contact hole pattern for the window 112, the bit line contact window, and the node contact window 114. With the shrinking of the DRAM chip design rule, the size of the contact window needs to be reduced accordingly, which will be a great challenge for the current lithography process.
此外,在不同光罩之间的重叠与对准的情况,在组件尺寸缩小的情况下也变得越发地困难,而此将会限制堆栈式形成动态随机存储器的制程窗口(process window)。In addition, the overlap and alignment between different masks becomes more and more difficult as the device size shrinks, which will limit the process window of the stacked DRAM.
有鉴于此,本发明提供一种动态随机存储器电容器的制造方法,以改善制程窗口以及重叠范围(overlay margin)。In view of this, the present invention provides a method for manufacturing a DRAM capacitor to improve the process window and overlay margin.
本发明提供一种动态随机存储器电容器的制造方法,是在基底上定义主动区后,在基底上形成复数条平行排列的字符线,接着,在字符线间,预定形成位线接触窗与节点接触窗的位置形成第一插塞与第二插塞,而其余的字符线间则填入绝缘材料。之后,在第一插塞上形成一位线接触窗,随后在基底上形成复数条平行排列,且与字符线垂直相交的位线,其中位线经由位线接触窗与第一插塞以及基底电性连接,而位线与位线之间电性绝缘,且位线上覆盖有一硬材料层。最后在第二插塞上形成节点接触窗。The invention provides a method for manufacturing a DRAM capacitor. After defining the active area on the substrate, a plurality of word lines arranged in parallel are formed on the substrate, and then, between the word lines, a bit line contact window is predetermined to be formed to contact the nodes. The position of the window forms the first plug and the second plug, and insulating material is filled between the rest of the word lines. After that, a bit line contact window is formed on the first plug, and then a plurality of bit lines arranged in parallel and perpendicular to the word line are formed on the substrate, wherein the bit line is connected to the first plug and the substrate through the bit line contact window. The bit lines are electrically connected, and the bit lines are electrically insulated, and the bit lines are covered with a hard material layer. Finally, a node contact window is formed on the second plug.
本发明再提供一种动态随机存储器电容器的制造方法,是在基底上定义主动区后,在基底上形成复数条互相平行排列的字符线,而字符线与字符线之间以一间隙隔开。接着,在间隙中填入第一绝缘层,定义第一绝缘层,形成作为位线接触窗的第一自动对准接触窗开口与作为节点接触窗一第二自动对准接触窗开口。之后,在第一与第二自动对准接触窗开口中填入导电材料,形成第一自动对准接触窗与第二自动对准接触窗。接着在字符线上形成第二绝缘层,并定义第二绝缘层,形成一位线接触窗开口。接着,在位线接触窗开口中填入导电材料,形成一位线接触窗,使位线接触窗可经由第一自动对准接触窗与基底电性连接。随后,在第二绝缘层上形成介电层,并定义介电层,而形成复数条与字符线垂直且互相平行排列的沟道。续在沟道中填入导电材料,形成位线,其中位线的一上表面低于介电层,且位线经由位线接触窗与第一自动对准接触窗电性连接。接着,在位线上形成硬材料层,并将沟道填满。续定义介电层与第二绝缘层,形成一节点接触窗开口,并在节点接触窗开口中填入导电材料,形成一节点接触窗,其中节点接触窗经由第二自动对准接触窗与基底电性连接。The present invention further provides a manufacturing method of the DRAM capacitor. After defining the active area on the substrate, a plurality of word lines arranged parallel to each other are formed on the substrate, and the word lines are separated by a gap. Next, filling the first insulating layer in the gap, defining the first insulating layer, forming a first self-aligned contact window opening as a bit line contact window and a second self-aligned contact window opening as a node contact window. Afterwards, filling the openings of the first and second self-alignment contact windows with conductive material to form the first self-alignment contact window and the second self-alignment contact window. Next, a second insulating layer is formed on the word line, and the second insulating layer is defined to form a bit line contact window opening. Next, filling the opening of the bit line contact window with conductive material to form the bit line contact window, so that the bit line contact window can be electrically connected to the substrate through the first self-aligned contact window. Subsequently, a dielectric layer is formed on the second insulating layer, and the dielectric layer is defined to form a plurality of channels perpendicular to the word lines and parallel to each other. Then fill the trench with conductive material to form a bit line, wherein an upper surface of the bit line is lower than the dielectric layer, and the bit line is electrically connected to the first self-aligned contact window through the bit line contact window. Next, a hard material layer is formed on the bit line and the trench is filled. Continue to define the dielectric layer and the second insulating layer, form a node contact window opening, and fill the conductive material in the node contact window opening to form a node contact window, wherein the node contact window is connected to the substrate via the second self-aligning contact window electrical connection.
本发明形成的自动对准接触窗与节点接触窗均利用自动对准制程进行,可增加制程窗口,改善重叠范围。Both the self-alignment contact window and the node contact window formed by the present invention are carried out by the self-alignment process, which can increase the process window and improve the overlapping range.
为让本发明的上述目的、特征和优点能更明显易懂,特举一较佳实施例,并配合所附图,作详细说明如下:In order to make the above-mentioned purposes, features and advantages of the present invention more obvious and understandable, a preferred embodiment is specifically cited, and in conjunction with the accompanying drawings, the detailed description is as follows:
图面说明:Graphic description:
图1是一种公知堆栈式位线上电容器的动态随机存储器的剖面图;Fig. 1 is a sectional view of a known stacked DRAM of capacitors on bit lines;
图2A-2I是根据本发明较佳实施例的动态随机存储器电容器的布局;2A-2I are layouts of DRAM capacitors according to a preferred embodiment of the present invention;
图3A-3I是根据图2A-2I3-3线切面的制造流程剖面图;3A-3I is a cross-sectional view of the manufacturing process according to the line section of FIG. 2A-2I3-3;
图4A-4I是根据图2A-2I4-4线切面的制造流程剖面图;4A-4I is a cross-sectional view of the manufacturing process according to the line section of FIG. 2A-2I4-4;
图5是定义自动对准接触窗的光阻图案;Figure 5 is a photoresist pattern defining a self-aligning contact window;
图6A-6D是图2G6-6线的部分切面的制造流程;以及Figures 6A-6D are the manufacturing process of a partial section of line 6-6 in Figure 2G; and
图7-9是图2I7-7、8-8、与9-9线切面的剖面图。Fig. 7-9 is a cross-sectional view of Fig. 2I7-7, 8-8, and 9-9.
附图标记说明:Explanation of reference signs:
100、200 基底 102、202 隔离结构100, 200
104、204 主动区 106、206 字符线104, 204
108、230 位线 110 电容器108, 230 bit line 110 capacitor
112 自动对准接触窗 114 节点接触窗112 Automatic Alignment Contact Window 114 Node Contact Window
116 介电材料 208 导电层116
210 覆绝缘层 212 硬材料间隙壁210
214 间隙 216、224 绝缘层214
218 不连续式T型岛状光阻图案218 Discontinuous T-shaped island photoresist pattern
218a 连续式自动对准接触窗光阻图案218a Continuous automatic alignment contact window photoresist pattern
220a、220b第一插塞、第二插塞220a, 220b first plug, second plug
226 位线接触窗开 228 位线接触窗226 bit line contact window open 228 bit line contact window
232 介电层 234、234a沟道232
236 硬材料层236 hard material layers
238 线形节点接触窗开口光阻图案238 Linear node contact window opening photoresist pattern
240 节点接触窗开 242 节点接触窗240 Node contact window open 242 Node contact window
请同时参照图2A,图3A与图4A,在基底200上形成隔离结构202,以定义形成包括场效应晶体管(field effect transistor,FET)与电容器等组件的主动区(active area,AA)204,主动区204的定义是选择在符合设计尺寸(design rule)的条件下,具有最大微影制程窗口。其中,隔离结构202例如为浅沟道隔离(STI),其可以任何公知技术形成。Please refer to FIG. 2A, FIG. 3A and FIG. 4A at the same time, an
接着,在基底200上形成互相平行排列的字符线206。字符线206的形成例如先在基底200形成栅极氧化物层(未绘出),再于栅极氧化物层上依序形成导电层208与覆绝缘层(cap insulation layer)210,之后利用微影蚀刻制程定义覆绝缘层210、导电层206与栅极氧化物层,并在导电层208侧壁形成硬材料间隙壁212,而形成如图3A与图4A所示的字符线206,字符线206与字符线206之间具有间隙214隔开。Next,
其中,导电层208作为场效应晶体管中的栅极,可以是掺杂的复晶硅,或是其它导电材质制成,而覆绝缘层210与硬材料间隙壁212则以氮化硅较佳。场效应晶体管的源/漏极区(未绘出)则形成在字符线206侧边的基底200。字符线206的微影蚀刻定义制程是利用直线且等宽的光阻图案进行,因此可提供最大的制程窗口以符合制程与电性的需求。Wherein, the
请同时参照图2B、图3B与图4B,在字符线206与字符线206之间的间隙214(图3A、图4A)填入绝缘层216。绝缘层216的形成是先在基底200上形成绝缘材料,例如以化学气相沉积法(CVD)沉积氧化物,覆盖字符线206并延伸至字符线206表面,之后,再以覆绝缘层210为终点,以化学机械研磨法(CMP)平坦化绝缘材料,直至暴露出覆绝缘层210的上表面为止。Please refer to FIG. 2B , FIG. 3B and FIG. 4B at the same time, the gap 214 ( FIG. 3A , FIG. 4A ) between the word lines 206 and 206 is filled with an insulating
请参照图2C、图3C与图4C,接着,利用光阻218定义绝缘层216,而去除在预定形成自动对准接触窗(self-aligned contact,SAC)位置上的绝缘层216,形成第一自动对准接触窗开口220a与第二自动对准接触窗开口220b,其中,第一自动对准接触窗开口220a是用作以后形成位线接触窗之用,而第二自动对准接触窗开口220b是用作以后形成节点接触窗之用。之后,再去除光阻218。Please refer to FIG. 2C, FIG. 3C and FIG. 4C, and then, utilize a
自动对准接触窗开口220a、220b的形成可利用如图2C所绘示的不连续式的T形岛状光阻图案(T-shape island PR pattern)218为光罩,覆盖部分的字符线206与绝缘层216,在作为覆绝缘层210与硬材料间隙壁212的氮化硅层与作为绝缘层216的氧化物具有高蚀刻选择比(etching selectivity)的条件下,蚀刻预定位置的绝缘层216,而形成自动对准接触窗开口220a、220b,暴露出基底200。使用T形岛状光阻图案218为光罩,可使定义自动对准接触窗开口220a、220b的制程窗口变大。The formation of the self-aligning
此外,定义自动对准接触窗开口220a、220b的光罩也可选用如图5所示的光阻图案218a,它是连续式的光阻图案,光阻图案218a的剖面同样如图3C的光阻218a所示,覆盖住部分的字符线206与绝缘层216,而可通过光阻218a去除预定形成自动对准接触窗开口220a、220b位置的绝缘层216。之后,再去除光阻218。In addition, the photomask defining the self-aligning
请同时参照图2D、图3D与图4D,在第一自动对准接触窗开口220a与第二自动对准接触窗开口220b中填入导电材料,形成第一插塞222a与第二插塞222b,其中,第一插塞222a作为后续形成的位线接触窗与基底200电性连接的第一自动对准接触窗,而第二插塞222b作为节点接触窗与基底200电性连接的第二自动对准接触窗。插塞222a、222b的形成是先在字符线206上形成导电材料,例如以化学气相沉积法形成复晶硅或钨金属等,之后,再以覆绝缘层210为研磨终点,使用化学机械研磨法将覆绝缘层210表面的导电材料研磨去除。Please refer to FIG. 2D, FIG. 3D and FIG. 4D at the same time, fill the conductive material in the first self-alignment
请同时参照图2E、图3E与图4E,在字符线206、第一插塞222a与第二插塞222b上形成一绝缘层224,之后再利用微影蚀刻法定义绝缘层224,蚀刻而去除部分绝缘层224,在第一插塞222a上形成一位线接触窗开口(bit line contact hole,CB hole)226,暴露出第一插塞。其中,绝缘层224例如以化学气相沉积法形成薄氧化物层,而在作为覆绝缘层210的氮化物与作为绝缘层224的氧化物具有较大的蚀刻选择比之下,蚀刻绝缘层224的步骤可停留在覆绝缘层210上,而不致破坏字符线206。Please refer to FIG. 2E, FIG. 3E and FIG. 4E at the same time, an insulating
请参照图2F、图3F与图4F,在绝缘层224上形成导电材料,例如以化学气相沉积法形成复晶硅或钨金属等,填入位线接触窗开口222a中,并延伸至绝缘层224表面。之后,再利用化学机械研磨法研磨导电材料,将绝缘层224上的导电材料去除,而在第一插塞222a上形成位线接触窗228。其中,位线接触窗228通过第一插塞222a与基底200电性连接。Referring to FIG. 2F, FIG. 3F and FIG. 4F, a conductive material is formed on the insulating
请参照图2G、图3G、图4G以及图6A-6D,其中图6A-6D是图2G6-6线的部分切面的制造流程。接着,在基底200上形成互相平行排列的位线230。位线230形成是先在绝缘层224与位线接触窗228上形成一毯覆式介电层232,覆盖整个晶圆,例如以化学气相沉积法形成氧化物层。之后,再于介电层232上覆盖线形位线光阻图案(BLline space pattern),利用线形位线光阻图案为罩幕,以微影蚀刻制程定义介电层232,而在介电层232中形成与字符线垂直相交,互相平行排列且深度与介电层232厚度同高的沟道234,如图6A所示,其中沟道234需经过位线接触窗228,而在沟道234中暴露出位线接触窗228表面。Please refer to FIG. 2G , FIG. 3G , FIG. 4G , and FIGS. 6A-6D , wherein FIGS. 6A-6D are part of the manufacturing process of the sectional plane along line 6-6 in FIG. 2G . Next,
接着,在沟道234中形成位线230,它是先在沟道234中填入导电材料,例如以化学气相沉积法沉积钨金属,导电材料填满沟道234并延伸至介电层232表面。续进行回蚀沟道234中导电材料的步骤,回蚀刻除了将介电层232表面的导电材料去除外,将沟道234中的导电材料回蚀至一深度,使沟道234中的下半部具有导电材料,而形成如图6B所示的位线230,位线230通过位线接触窗228与第一插塞222a与基底200电性连接。其中,位线230的表面需低于介电层232表面,而位线230与介电层232之间更可具有阻障层(barrier layer)增加导电材料与氧化物的间的附着力。之后,再对介电层232进行等向性蚀刻(isotropic etching)步骤,使得位线230以上的沟道234开口扩大,而形成一碗状开口234a。请参照图6D,续在沟道234中填入硬材料层236,例如为氮化硅层,硬材料层236可以化学气相沉积法形成,在填满沟道234之后并延伸至介电层232表面,之后再以介电层232作为研磨终点,利用化学机械研磨法将介电层232表面的硬材料层去除,而形成如图3G以及图6D所示,不高于介电层232表面的硬材料层236。扩大的开口234a使得填入的硬材料层236具有较大的表面积,因此当后续形成节点接触窗开口时,可避免破坏底下的位线230。Next, the
请参照图2H、图3H与图4H,在介电层232与硬材料层236上形成如图2H所示的线形节点接触窗开口光阻图案(space node contactpattern,space CN pattern)238,覆盖在第一插塞222a上的介电层232与硬材料层236,至少需暴露出预定形成节点接触窗的位置。接着,以线形节点接触窗开口光阻图案238为罩幕,对介电层232与绝缘层224进行蚀刻,而形成节点接触窗开口240,暴露出第二插塞222b。在定义节点接触窗开口240的步骤中,由于位线230上有硬材料层236覆盖,因此在蚀刻步骤进行时,硬材料层236与介电层232的高蚀刻选择比可使得硬材料层236阻挡蚀刻剂的侵蚀,故可仅蚀刻暴露出的介电层232,而使节点接触窗开口240可自动对准在第二插塞222b上。随后去除光阻238。Referring to FIG. 2H, FIG. 3H and FIG. 4H, a linear node contact window opening photoresist pattern (space node contact pattern, space CN pattern) 238 as shown in FIG. 2H is formed on the
接着,请参照图2I,图3I与图4I以及图7、图8与图9,其中图7、图8与图9分别是图2I线7-7、线8-8、与线9-9的剖面图。在节点接触窗开口240中填入导电材料,例如为复晶硅或钨金属,填满节点接触窗开口240并延伸至介电层232表面,随后再利用化学机械研磨法去除介电层232表面多余的导电材料,而形成如图4I所示的节点接触窗242,其中节点接触窗242经由第二插塞222b与基底电性连接。从图9所可明显看出,硬材料层236因扩大的碗状开口234a(图6C)相对于位线230而言具有较大的表面积,故在定义节点接触窗242时,可避免破坏到硬材料层236下方的位线230。Next, please refer to FIG. 2I, FIG. 3I and FIG. 4I and FIG. 7, FIG. 8 and FIG. 9, wherein FIG. 7, FIG. 8 and FIG. sectional view. Fill the node contact window opening 240 with a conductive material, such as polysilicon or tungsten metal, fill the node contact window opening 240 and extend to the surface of the
至此完成存储单元数组,后续可以任何公知制程进行电容的制作,例如柱状电容、冠状电容等。So far, the memory cell array is completed, and any known process can be used to fabricate capacitors, such as columnar capacitors, crown capacitors, and the like.
此外,本发明的较佳实施例使用了在形成自动对准接触窗222a、222b与节点接触窗242时均利用自动对准接触窗的制程,故可增加制程窗口,并改善重叠范围。In addition, the preferred embodiment of the present invention uses a process that utilizes self-aligned contacts when forming the self-aligned
再者,本发明的较佳实施例中,利用不连续T形岛状光罩图案218定义自动对准接触窗,再加上定义位线与节点接触窗时均使用线状/间隔状的光罩图案,因此更能增加制程窗口。Furthermore, in the preferred embodiment of the present invention, the discontinuous T-shaped island-shaped
虽然本发明已以一较佳实施例阐明如上,然其并非用以限定本发明,任何熟习此技术者,在不脱离本发明的精神和范围内,当可作各种更动与润饰,因此本发明的保护范围当以权利要求书范围所界定为准。Although the present invention has been illustrated above with a preferred embodiment, it is not intended to limit the present invention. Any skilled person can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore The scope of protection of the present invention should be defined by the scope of claims.
Claims (28)
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101378064B (en) * | 2007-08-31 | 2010-09-08 | 台湾积体电路制造股份有限公司 | Dynamic random access memory unit and its manufacturing method |
| CN101740572B (en) * | 2008-11-25 | 2012-02-01 | 台湾积体电路制造股份有限公司 | memory element |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101378064B (en) * | 2007-08-31 | 2010-09-08 | 台湾积体电路制造股份有限公司 | Dynamic random access memory unit and its manufacturing method |
| CN101740572B (en) * | 2008-11-25 | 2012-02-01 | 台湾积体电路制造股份有限公司 | memory element |
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