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CN1377742A - Process for harmless treating life refuse resource - Google Patents

Process for harmless treating life refuse resource Download PDF

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Publication number
CN1377742A
CN1377742A CN02117946A CN02117946A CN1377742A CN 1377742 A CN1377742 A CN 1377742A CN 02117946 A CN02117946 A CN 02117946A CN 02117946 A CN02117946 A CN 02117946A CN 1377742 A CN1377742 A CN 1377742A
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China
Prior art keywords
comprehensive
harmless
composting
heat
rubbish
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CN02117946A
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Chinese (zh)
Inventor
张蕊
张顺福
张卷昆
于迪
于凤册
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Individual
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Individual
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Priority to CN02117946A priority Critical patent/CN1377742A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

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  • Processing Of Solid Wastes (AREA)

Abstract

The present invention provides a harmlessly domestic refuse treating process capable of utilizing the refuse resource completely. The technological process includes sorting, comprehensive treatment, stoving, magnetic selecting, crushing, producing fertilizer and building material, and recovering harmful material. Through digestion of domestic refuse at certain temperature and pressure, the organic matters inside refuse may be decomposed in 3-4 hr. The process can eliminate the pollution of harmful matters in refuse to environment while converting refuse into fertilizer and building material.

Description

Process for harmless treating life refuse resource
Technical field
The present invention relates to a kind of domestic rubbish disposal technology, belong to the treatment process technical field of solid waste.
Background technology
Along with the develop rapidly of world economy, the mankind also are on the rise to environment damage.Wherein environmental pollution is one of major reason of environmental degradation.Environmental pollution mainly shows the influence to environment such as sewage, obnoxious flavour, solid waste.And the domestic refuse of how handling in the solid waste is the difficult problem that generally acknowledge in the whole world, and for this reason, national governments all drop into a large amount of man power and materials to some extent and study and solve.At present, the method for domestic rubbish disposal mainly comprises three kinds of burnings, landfill, compost, and concerning China, landfill accounts for more than 70%, secondly is that During High-Temperature Composting accounts for more than 20%, burns only to account for seldom.Landfill is a kind of traditional trash processing way of primary, it can cause serious secondary pollution inevitably, comprise atmosphere, soil, ground and body of groundwater, various biotic pollution, taken a large amount of soils simultaneously, a lot of cities, the whole nation all are among the encirclement of rubbish.In order to change this situation, the Chinese government has taked many measures, comprise introducing external advanced refuse treatment plant, but because therefore the composition complexity of China's domestic refuse also exists many problems in processing.At first the calorific value of China's rubbish is lower, as has a large amount of gourd, fruit and vegetables etc., therefore contains a large amount of moisture, need consume a large amount of energy during burning, and cost is too high, so be unsuitable for burning disposal; Secondly material letter sortings such as the inorganics in the rubbish, organism, poisonous metal are difficult, and inorganic content is big when making compost, and fertilizer quality is poor behind the compost; Have, need artificial broken bag, letter sorting when letter sorting, efficient is low, labour intensity is big, also can polluted air.The problems referred to above all make present rubbish processing to be harmless cause difficulty.
Chinese patent CN1270991A discloses a kind of garbage treating process and equipment used thereof.Its technological process is: the refuse treatment jar is connected with the mixed gas reaction jar, and the mixed gas reaction jar also is connected with gas cooler, connects the coal gas hold-up vessel through water filter, refining plant.Chinese patent CN1259502A discloses a kind of domestic garbage comprehensive treatment technology and complete set equipment, and it is made up of the wet grinding machine of the modular fermentation cabin of the size separation equipment of pre-treatment, fermentative processing, aftertreatment and hot method granulating equipment of rotary drum and the air-bleed system equipment of producing organic compositing fertilizer.Chinese patent CN1068251C discloses a kind of innoxious, resource utilization, easily sorting, no remaining garbage treating process, it adopts pyrolytic technique, domestic waste is placed in the special encloses container, under certain pressure and temperature condition, it is carried out the chemical catalysis reaction, eliminate objectionable impurities and peculiar smell, make complicated refuse classification technology become simple, the organism after the pyrolysis is made bio-fertilizer, inorganics system building materials.The common drawback of the method that above-mentioned patent adopts is to contain washy problem and need all to add that fuel burns or drying and dewatering in order to solve rubbish in the part for the treatment of refuse, therefore consumes a large amount of energy.Aforesaid method is also unsatisfactory in the comprehensive utilization of rubbish in addition.
Summary of the invention
Technical problem to be solved by this invention provides a kind ofly can carry out the garbage treating process that harmless is handled and utilized cmpletely to rubbish, also can save a large amount of energy in treating processes.
Problem to be solved by this invention is realized by following technical scheme:
A kind of process for harmless treating life refuse resource, its technical process comprise clean operation of comprehensive sorting operation-comprehensive treating process operation-baking operation-magnetic look operation-pulverizing process-composting operation and product operation and heat and nuisance recovery process;
Described comprehensive sorting operation is that flammable organism is sub-elected, and useful plastics, harmful plastics and metal, battery etc. are sorted out, and all the other most of rubbish are sent to the comprehensive treating process operation;
The rubbish of described comprehensive treating process operation after with comprehensive sorting is handled under the vapor action of certain temperature, pressure, and s main working parameters is: pressure 3-10kg/cm 2, 130 ℃-200 ℃ of temperature were feeded 30-40 minute, and boiling 2-5 hour, discharging 0.8-1.5kg/cm 2The solution that oozes after the processing is delivered to composting operation composting, and screen overflow send the clean operation of heat to do to burn thermal source, and screen underflow send baking operation;
The clean operation of described heat is that the flammable organism that comprehensive sorting operation is sub-elected, the screen overflow and the screen overflow in the pulverizing process of comprehensive treating process operation send roasting kiln to burn, the heat energy of its generation uses the broken operation of combustion residue powder feeding for comprehensive treating process operation and baking operation;
Described baking operation is that employed thermal source is provided by the clean operation of heat with the oven dry of the screen underflow of comprehensive treating process operation, baking operation adopt wet scrubber to the dust-laden, the sulfurous gas desulfurization that produce, take off dirt, take off qualified discharge behind the cigarette.
Described magnetic look operation is to remove iron in the material of oven dry, non-ferrous metal, stainless steel, battery etc., and it is delivered to nuisance recovery process and metal recovery department, and all the other most of materials are delivered to pulverizing process.
The raw material of described pulverizing process is material and the hot combustion residue of operation only that magnetic look operation is sent here, pulverizes the back screen overflow and send heat operation burning only, and screen underflow is the raw material of composting and product, and screen underflow is a 60-100 order powder, moisture 8%-10%.
Above-mentioned process for harmless treating life refuse resource, the sepage that the liquid that the granulation of described composting operation is used is discharged as the comprehensive treating process operation, harmless rubbish under the sieve of the solid material that uses as pulverizing process, sal epsom that the purification part is discharged and magnesium chloride, magnesium oxide account for the 5-10% of fertilizer component as binding agent.
Above-mentioned process for harmless treating life refuse resource, the raw material of described product operation is the harmless rubbish of inorganics under the sieve of pulverizing process, add known binding agent, aggregate, properties-correcting agent such as water-resisting agent, anti reversed halogen agent, be compressed to plate, watt, brick etc., binding agent is a magnesium cement, accounts for the 40-60% of raw material gross weight.
Above-mentioned process for harmless treating life refuse resource after in the described magnetic look operation metal, battery etc. being removed, is crushed to plastics about diameter 10mm, adding additives not, and directly to heat is 180 ℃-260 ℃ to the progressive die tool, be forced into 800kg/cm 2-1500kg/cm 2, be hot pressed into sheet material.
The present invention has realized the harmless of domestic refuse is handled and recycling.Adopted the novel process of rubbish being carried out boiling under certain temperature and pressure in the present invention, but it can make in the domestic refuse composting organism at 3-4 hour with regard to the become thoroughly decomposed degree of hydrolyzable to the compost requirement.Substantially exceed the required 7-20 of biological fermentation days that adopt usually both at home and abroad, and external advanced enterprise 3 angel's rubbish meet the requirements of the level of rotten degree.The present invention can effectively eliminate the pollution of objectionable impurities to environment, also the rubbish after handling can be made fertilizer or is made material of construction etc.Investment and floor space are little, and the processing cycle is short, and running cost is low.
Fig. 1 is a process flow sheet of the present invention.
Embodiment
The present invention is a kind of process for harmless treating life refuse resource, its main technique flow process comprises comprehensive sorting operation, comprehensive treating process operation, baking operation, magnetic look operation, pulverizing process, composting operation and product operation, also has clean operation of heat and nuisance recovery process.Narrate respectively according to the order of technical process below:
1. comprehensive sorting operation.Rubbish carries out sorting at this, and big part organism send the clean operation of heat to burn after picking as carton, bamboo basket, straw bag, summer sleeping mat, timber, branch etc.; The harmless organism of fritter, as bamboo and wood, mould, paper, fabric etc. send the clean operation of heat to burn; During sorting, profile and color according to the domestic refuse of on conveyor, moving, the harmful separating plastics such as benzene, chlorine that contain are wherein gone out, dioxin contamination in burning away the refuse with minimizing, rest part enters following comprehensive treating process operation, this part rubbish is the 85-95% of charging total amount, looks the variation of different component of refuse and difference.
2. comprehensive treating process operation.After rubbish and modifying agent enter treater, under the steam of certain temperature, pressure, rubbish is carried out disinfection, sterilizes, deodorizes, dewaters, takes off ten effects such as benzene, degraded, separation, decrement, broken bag, sepage processing, make rubbish harmless, minimizing, the treatment facility of domestic and international any domestic refuse does not reach this level as yet so far.Comprehensive treatment equipment in this operation can use disclosed garbage decomposition jar in 99235230.4 patents.
It is the exclusive special process of the present invention that high temperature, the high pressure steam that the present invention adopts carried out boiling to rubbish, but it can make in the domestic refuse composting organism at 3-4 hour with regard to the become thoroughly decomposed degree of hydrolyzable to the compost requirement.And the biological fermentation that adopts usually both at home and abroad needs 7-20 days, even the longer time just can reach requirement.According to the pertinent data introduction, advanced foreign technology can meet the requirements of rotten degree with 3 angel's rubbish, and this also substantially exceeds the time required for the present invention.
The s main working parameters of this technology is: pressure 3-10kg/cm 2, 130 ℃-200 ℃ of temperature were feeded 30-40 minute, and boiling 3-4 hour, discharging 0.8-1.5kg/cm.That comprehensive treatment equipment in this technology has is vertical, horizontal, continous way, discontinuous work are several, is selected voluntarily by the user.
The resultant of this technological process comprises solution, screen overflow and screen underflow three parts.Solution is discharged by treater, send the liquid fertilizer pool post precipitation, send the composting workshop again, does the fertile granulation of solid and uses.The solid part dispensing drying machine drying that is settled out is to certain humidity, through magnetic look, pulverizing process, composting operation batching composting.The moisture 15-20% of screen overflow is mainly plastics, wooden bamboo, fabric (woven bag, clothing, towel) footwear, glass etc. and send the clean operation of heat to burn to make thermal source, discharge send after bits are pulverized the product operation make brick, watt, plate and so on.Screen underflow is mainly used in composting (accounting for rubbish total amount 40-50%), sends into baking operation, and this moment, water content was about 25-30%.
3. baking operation.Baking operation provides hot gas by the clean operation of heat, and raw material is from above-mentioned screen underflow and liquid fertilizer throw out.Baking operation adopt wet scrubber to the dust-laden, the sulphur gas sweetening that produce, take off dirt, take off qualified discharge behind the cigarette.The waste liquid of sulfur acid magnesium send the product operation to make binding agent and uses, and the waste liquid that contains calcium sulfite can be used for doing gypsum.Entering magnetic look operation after all the other most of composting raw material dryings handles.
4. magnetic look operation.Remove the iron in the composting raw material, discriminated unions such as non-ferrous metal copper, aluminium, zinc (battery), stainless steel are separated.The metal of telling is sent into the export trade of metal storehouse, and battery send the nuisance treating part, the broken operation of all the other composting raw material powder feedings.
5. pulverizing process.Raw material is material and the hot surplus slag of operation only that magnetic look operation is sent here, simultaneously hard (stone, cement block), soft (bamboo and wood, plastics), rubber mass is sent into pulverizer, and this pulverizer can adopt the disclosed structure of ZL99235104.9.Feed size is less than diameter 60-80mm, can pulverize to reach 200 orders, and is adjustable, and general 60-100 order gets final product.After the pulverizing, screen overflow send the clean operation of heat to burn, and screen underflow is the raw material of composting and product, and screen underflow is a 60-100 order powder, moisture 8%-12%.
6. hot clean operation.This part comprises thermal source and purification.The organism that sorting part and comprehensive treating process operation pick (bamboo and wood, mould, knit, paper etc.), screen overflow are delivered to the thermal source burning, be a kind of mode that rubbish is handled on the one hand, provide a large amount of heat energy behind these substance combustions on the other hand, be used for steam being provided and providing hot gas and generating, to be sparing in the use of coal to dryer to the comprehensive treating process operation.This is the important content that the present invention fully utilizes, and is different from burning process in other refuse treatment, has saved a large amount of energy than other scheme.Purify to adopt the special corrosion resistant of usefulness of development newly, the glass reinforced plastic wet cleaner that temperature-resistant material is made, make nitride in the flue gas, sulfide, muriate, Dioxins, dust etc. drop to Schwellenwert, meet or exceed national standard.Wherein: take off SO 2Reach more than 80%; Take off HCL 〉=95%; Dedusting<80mg/Nm; Take off Dioxins<1ng/Nm.
7. composting operation.The screen underflow of above-mentioned pulverizing process is the composting raw material, and screen underflow is a 60-100 order powder, moisture 8%-12%.Purify the sal epsom of part discharge and the magnesium chloride of interpolation, the binding agent in the magnesium oxide as fertilizer sources, elemental chlorine, magnesium, sulphur are the composition in the fertilizer, both can make fertilizer reach the bonding purpose, easily are hydrolyzed again, use for plant.Sal epsom, magnesium chloride, magnesium oxide account for the 3%-8% of fertilizer component as binding agent.The harmless liquid fertilizer that the sepage that the liquid that the composting granulation is used is discharged for the comprehensive treating process operation forms.The composting process is by computer batching, mixing, granulation, oven dry, screening, packing.
8. product operation.The screen underflow of above-mentioned pulverizing process is an inorganics product raw material, adds magnesium cement and makes binding agent, accounts for the 40%-60% of weight ratio, adds other known aggregate, properties-correcting agent again, can make different shapes, performance plate, watt, brick etc.
Also can after the metal in the plastics, battery etc. are removed, plastics be crushed to about diameter 10mm adding additives not, directly heat 210 ℃, pressurization 1200kg/cm of progressive die tool 2, make sheet material.When making sheet material, not adding additives and directly extrusion forming also be peculiar technology of the present invention.
9. nuisance recovery process.
Battery reclaims technology: broken skin-recovery zinc-scrubbing-blowdown is up to standard.
Chlorine, benzene reclaim technology: (containing chlorobenzene plastics+filler)-thermal degradation-system paint raw materials.

Claims (4)

1. process for harmless treating life refuse resource is characterized in that: its technical process comprises clean operation of comprehensive sorting operation-comprehensive treating process operation-baking operation-magnetic look operation-pulverizing process-composting operation and product operation and heat and nuisance recovery process;
Described comprehensive sorting operation is that flammable organism is sub-elected, and useful plastics, harmful plastics and metal, battery etc. are sorted out, and all the other most of rubbish are sent to the comprehensive treating process operation;
The rubbish of described comprehensive treating process operation after with comprehensive sorting is handled under the vapor action of certain temperature, pressure, and s main working parameters is: pressure 3-10kg/cm 2, 130 ℃-200 ℃ of temperature were feeded 30-40 minute, and boiling 2-5 hour, discharging 0.8-1.5kg/cm 2The solution that oozes after the processing is delivered to composting operation composting, and screen overflow send the clean operation of heat to do to burn thermal source, and screen underflow send baking operation;
The clean operation of described heat is that the flammable organism that comprehensive sorting operation is sub-elected, the screen overflow and the screen overflow in the pulverizing process of comprehensive treating process operation send roasting kiln to burn, the heat energy of its generation uses the broken operation of combustion residue powder feeding for comprehensive treating process operation and baking operation;
Described baking operation is that employed thermal source is provided by the clean operation of heat with the oven dry of the screen underflow of comprehensive treating process operation, baking operation adopt wet scrubber to the dust-laden, the sulfurous gas desulfurization that produce, take off dirt, take off qualified discharge behind the cigarette.
Described magnetic look operation is to remove iron in the material of oven dry, non-ferrous metal, stainless steel, battery etc., and it is delivered to nuisance recovery process and metal recovery department, and all the other most of materials are delivered to pulverizing process.
The raw material of described pulverizing process is material and the hot combustion residue of operation only that magnetic look operation is sent here, pulverizes the back screen overflow and send heat operation burning only, and screen underflow is the raw material of composting and product, and screen underflow is a 60-100 order powder, moisture 8%-10%.
2. process for harmless treating life refuse resource according to claim 1, it is characterized in that, the sepage that the liquid that the granulation of described composting operation is used is discharged as the comprehensive treating process operation, harmless rubbish under the sieve of the solid material that uses as pulverizing process, sal epsom that the purification part is discharged and magnesium chloride, magnesium oxide account for the 5-10% of fertilizer component as binding agent.
3. process for harmless treating life refuse resource according to claim 1 and 2, it is characterized in that: the raw material of described product operation is a harmless rubbish under the sieve of pulverizing process, add binding agent, aggregate, properties-correcting agent, be compressed to plate, watt, brick, binding agent is a magnesium cement, accounts for the 40-60% of weight.
4. process for harmless treating life refuse resource according to claim 1 and 2, it is characterized in that, after in the described magnetic look operation metal in the plastics, battery etc. being removed, plastics are crushed to diameter 10mm, directly to heat is 180 ℃-260 ℃ to the progressive die tool, be forced into 800kg/cm 2-1500kg/cm 2, be hot pressed into sheet material.
CN02117946A 2002-05-27 2002-05-27 Process for harmless treating life refuse resource Pending CN1377742A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101949543A (en) * 2010-09-17 2011-01-19 杨长银 Household garbage treatment system
CN102226108A (en) * 2011-05-04 2011-10-26 杨长银 System for converting domestic garbage and solid waste into combustible gas
CN102607032A (en) * 2012-03-07 2012-07-25 陈震 System and method for winter refuse wet-steaming and fermentation for household refuse fired power plants
CN102632068A (en) * 2011-02-15 2012-08-15 杭州布鲁斯凯环境科技有限公司 Mechanization, biologicalization and transportation integrated treatment process of domestic garbage
CN102773247A (en) * 2012-07-20 2012-11-14 谢鸣燕 System and method for making bricks by utilizing domestic garbage
CN101508603B (en) * 2009-04-10 2013-07-31 北京绿创大气科技有限公司 High-speed composting process and apparatus
CN103286114A (en) * 2013-03-29 2013-09-11 高翁斌 An ecological resource recycling process for garbage from farmers markets and kitchens
CN105032891A (en) * 2015-07-09 2015-11-11 大连惠川环保科技有限公司 Pyrolysis energy conversion method for fully recycling of household garbage
CN107971321A (en) * 2017-10-12 2018-05-01 镇江市中运城市环境治理股份有限公司 A kind of household-garbage processing process
CN108941148A (en) * 2018-05-15 2018-12-07 黄解放 A kind of Waste sorting recycle utilizes method
CN109704863A (en) * 2019-02-18 2019-05-03 湖北三宁化工股份有限公司 A kind of bulky grain sulfur-containing nitrogen fertilizer and preparation method thereof

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101508603B (en) * 2009-04-10 2013-07-31 北京绿创大气科技有限公司 High-speed composting process and apparatus
CN101949543A (en) * 2010-09-17 2011-01-19 杨长银 Household garbage treatment system
CN102632068A (en) * 2011-02-15 2012-08-15 杭州布鲁斯凯环境科技有限公司 Mechanization, biologicalization and transportation integrated treatment process of domestic garbage
CN102226108A (en) * 2011-05-04 2011-10-26 杨长银 System for converting domestic garbage and solid waste into combustible gas
CN102226108B (en) * 2011-05-04 2013-10-09 杨长银 System for converting domestic garbage and solid waste into combustible gas
CN102607032A (en) * 2012-03-07 2012-07-25 陈震 System and method for winter refuse wet-steaming and fermentation for household refuse fired power plants
CN102773247A (en) * 2012-07-20 2012-11-14 谢鸣燕 System and method for making bricks by utilizing domestic garbage
CN103286114A (en) * 2013-03-29 2013-09-11 高翁斌 An ecological resource recycling process for garbage from farmers markets and kitchens
CN105032891A (en) * 2015-07-09 2015-11-11 大连惠川环保科技有限公司 Pyrolysis energy conversion method for fully recycling of household garbage
CN107971321A (en) * 2017-10-12 2018-05-01 镇江市中运城市环境治理股份有限公司 A kind of household-garbage processing process
CN108941148A (en) * 2018-05-15 2018-12-07 黄解放 A kind of Waste sorting recycle utilizes method
CN109704863A (en) * 2019-02-18 2019-05-03 湖北三宁化工股份有限公司 A kind of bulky grain sulfur-containing nitrogen fertilizer and preparation method thereof

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