CN1361186A - Nanometer acrylic acid microemulsion, water-thinned heat reflecting and isolating paint and their production process - Google Patents
Nanometer acrylic acid microemulsion, water-thinned heat reflecting and isolating paint and their production process Download PDFInfo
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- CN1361186A CN1361186A CN 02109969 CN02109969A CN1361186A CN 1361186 A CN1361186 A CN 1361186A CN 02109969 CN02109969 CN 02109969 CN 02109969 A CN02109969 A CN 02109969A CN 1361186 A CN1361186 A CN 1361186A
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- Prior art keywords
- water
- heat reflecting
- solvent
- acrylic acid
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- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 239000003973 paint Substances 0.000 title claims abstract description 41
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 35
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 19
- 239000000049 pigment Substances 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 11
- 230000008569 process Effects 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims description 38
- 239000003795 chemical substances by application Substances 0.000 claims description 36
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 28
- 239000003999 initiator Substances 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 22
- 239000000178 monomer Substances 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 18
- 230000003750 conditioning effect Effects 0.000 claims description 17
- 230000008719 thickening Effects 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 15
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 14
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 13
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 13
- 238000009413 insulation Methods 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 9
- 239000011521 glass Substances 0.000 claims description 9
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 6
- -1 process white Chemical compound 0.000 claims description 6
- 229920000570 polyether Polymers 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 4
- 244000025254 Cannabis sativa Species 0.000 claims description 3
- 239000003518 caustics Substances 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 238000005304 joining Methods 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 239000002562 thickening agent Substances 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 229910052741 iridium Inorganic materials 0.000 claims description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 2
- 239000004005 microsphere Substances 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims description 2
- 229910052703 rhodium Inorganic materials 0.000 claims description 2
- 239000010948 rhodium Substances 0.000 claims description 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 abstract description 9
- 239000002253 acid Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 description 34
- 239000011248 coating agent Substances 0.000 description 32
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 21
- 239000006185 dispersion Substances 0.000 description 12
- 239000004342 Benzoyl peroxide Substances 0.000 description 8
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- 235000019400 benzoyl peroxide Nutrition 0.000 description 8
- 238000003912 environmental pollution Methods 0.000 description 6
- NECRQCBKTGZNMH-UHFFFAOYSA-N 3,5-dimethylhex-1-yn-3-ol Chemical compound CC(C)CC(C)(O)C#C NECRQCBKTGZNMH-UHFFFAOYSA-N 0.000 description 5
- 239000013530 defoamer Substances 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 235000013980 iron oxide Nutrition 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- UEEJHVSXFDXPFK-UHFFFAOYSA-O N-dimethylethanolamine Chemical compound C[NH+](C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-O 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- HVCNXQOWACZAFN-UHFFFAOYSA-N 4-ethylmorpholine Chemical compound CCN1CCOCC1 HVCNXQOWACZAFN-UHFFFAOYSA-N 0.000 description 1
- JRLTTZUODKEYDH-UHFFFAOYSA-N 8-methylquinoline Chemical group C1=CN=C2C(C)=CC=CC2=C1 JRLTTZUODKEYDH-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- GPXJNWSHGFTCBW-UHFFFAOYSA-N Indium phosphide Chemical compound [In]#P GPXJNWSHGFTCBW-UHFFFAOYSA-N 0.000 description 1
- 101100412856 Mus musculus Rhod gene Proteins 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- HEQBUZNAOJCRSL-UHFFFAOYSA-N iron(ii) chromite Chemical compound [O-2].[O-2].[O-2].[Cr+3].[Fe+3] HEQBUZNAOJCRSL-UHFFFAOYSA-N 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention is one kind of nano acrylic acid microemulsion, water-thinned heart reflecting and isolating paint with the nano acrylic acid microemulsion and their prodcution process. The present invention aims at solving the technological problems of available paint, which contains great amount of organic solvent to pollute environment and has poor heat reflecting and isoalting performance. The water-thinned heat reflecting and isolating paint consists of nano acrlic acid microemulsion, conventional acrylic acid emulsion, pigment, filler, infrared ray reflector, assistant, pH regulator, densifier and softened water. The paint contains no organic solvent and has excellent heat reflecting and isolating performance.
Description
Technical field:
The water-thinned heat reflecting and isolating paint that the present invention relates to a kind of nanometer acrylic acid microemulsion and adopt nanometer acrylic acid microemulsion to make, and the manufacture method of nanometer acrylic acid microemulsion and water-thinned heat reflecting and isolating paint.
Background technology:
Traditional coating mostly is solvent-borne type, and contained organic solvent in use also will add organic solvent diluting sometimes generally greater than 30%.These solvents evaporate in construction process in the atmosphere, and not only the health of human body to the constructor works the mischief, and pollutes the environment, and cause the hidden danger of fire in addition.Along with countries in the world environmental requirement increasingly stringent, development environment protection type coating is the trend of the times material with replace solvents type coating.The particularly dark coating of common coating can absorb the infrared rays in the sunlight mostly, is converted into heat energy, causes that the coating temperature raises, and heat continues inwardly to be conducted by ground by being coated with the course ground again, causes the temperature in indoor or the container to raise.For addressing this problem, people develop heat reflection coatings in recent years, compare with common coating, and this coating can reflect or the scattering infrared rays morely, and has heat-blocking action, obviously reduces the body surface temperature.Be used for building wall and roof and have effect cool in summer and warm in winter, can reduce the air-conditioning expense.Be used for oil refining and chemical plant basin and can significantly reduce temperature in the basin, improve security.Existing heat reflection coatings major part is solvent based coating or is the water dilution type coating of base-material with water dilution type resin that the former contains more organic solvent, and the latter contains pure ethers solubility promoter.For example Japanese Patent JP98-120946 discloses a kind of infrared reflection coating of outward appearance dark color, is to combine with metal oxide-type black pigment, indium phosphide, flake aluminum, fluoro-resin, polysulfone resin, and its infrared reflectance is 31%, and weathering resistance is fabulous.This coating shortcoming is that base-material is a solvent type resin, and problem of environmental pollution is arranged, and its infrared reflectance is also not ideal enough.German patent DE 19501114 discloses a kind of infrared reflection coating, be to be base-material with water dilution type acrylic resin, with pigment such as titanium dioxide, chrome black, iron oxide reds, filler such as talcum powder, mica powder is formed, being applied to the coating that forms dried film thickness 45 μ m on the white primer, is ultrared reflectivity＞50% of 1200-2000nm to wavelength.This coating shortcoming is that the mixed solution with propylene glycol and water is a thinner, still has problem of environmental pollution.External existing report about the research of water-thinned heat reflecting coating, but coating package stability, application property, coating heat reflection and effect of heat insulation are still undesirable, do not reach industrialization phase.
Summary of the invention:
The technical problem to be solved in the present invention is: existing coating can cause environmental pollution because of containing a large amount of organic solvents, and heat reflection and heat-proof quality are poor.
For solving existing coating because of containing the technical problem that a large amount of organic solvents can cause environmental pollution, the present invention by the following technical solutions: nanometer acrylic acid microemulsion, its special character is: its raw material contains:
The raw material weight ratio
Methyl methacrylate 30-70
Butyl acrylate 20-60
And/or butyl methacrylate 0-30
And/or methacrylic acid 0-4
And/or vinylformic acid 0-4
And/or MALEIC ANHYDRIDE 0-2
Initiator 1-3
PH conditioning agent 3-7
Solvent 20-30
Softening water 100-150.
Butyl methacrylate, methacrylic acid, vinylformic acid, MALEIC ANHYDRIDE are four kinds of selectivity raw materials, but must contain more than one.Initiator can adopt benzoyl peroxide, and solvent can adopt propyl carbinol.In the final nanometer acrylic acid microemulsion that generates, solvent should be deviate from, make it not contain solvent substantially.
Nanometer acrylic acid microemulsion of the present invention can be used alone as the preparation rust-inhibiting paint, also can mix use with conventional ACRYLIC EMULSION, and as coating for internal and external wall, hard floor paint etc., it can improve compactness, weathering resistance, sticking power, anti-fouling performance etc.Because it is deviate from solvent, do not pollute the environment in the use, can not produce disaster hidden-trouble.
Can cause environmental pollution for solving existing coating because of containing a large amount of organic solvents, and the technical problem of heat reflection and heat-proof quality difference, the present invention is by the following technical solutions: contain the water-thinned heat reflecting and isolating paint of aforesaid propylene acid nanometer micro-emulsion, its special character is: its raw material contains:
The raw material weight ratio
Nanometer acrylic acid microemulsion 15-25
Conventional ACRYLIC EMULSION 15-25
Pigment 1-20
Filler 5-20
Infrared reflection agent 0.1-1
Cenosphere 1-10
Auxiliary agent 0.5-2.5
PH conditioning agent 0.1-0.5
Thickening material 0.2-1.5
Softening water 20-40.
Above-mentioned conventional ACRYLIC EMULSION can be selected commercially available vinylformic acid building emulsion for use, for example the B-96 emulsion of east-Rhom and Hass, AC-261 emulsion.The particle size range of cenosphere is 1-100m.
Cenosphere of the present invention comprises that hollow ceramic microspheres, hollow glass micropearl and power plant float one or more in the pearl.
A kind of byproduct that produces in the cinder that pearl is the power station floats in power plant.
Hollow glass micropearl of the present invention is to be that raw material makes with the low boron glass of degree of hydrolysis.
Pigment of the present invention comprises that iron oxide black, red iron oxide, iron oxide yellow, titanium dioxide, phthalein green grass or young crops are red, in phthalocyanine blue and the organic yellow one or more.
Require selected pigment low or infrared reflectance is high to the infrared ray absorption rate.
Filler of the present invention comprises one or more in light calcium carbonate, process white, talcum powder and the mica powder.
Infrared reflection agent of the present invention is the nano-scale oxide micro mist of nanometer titanium dioxide micropowder and/or noble ruthenium, rhodium, iridium.
Thickening material of the present invention is polyethers and/or caustic solubility ACRYLIC EMULSION class associative thickener.
Auxiliary agent comprises dispersion agent, wetting agent, flow agent, defoamer, mould inhibitor, sanitas.Wherein selecting for use because of pigment property of dispersion agent decided, for mineral dyes such as titanium dioxide, red iron oxides, can adopt sodium, ammonium, the amine salt of alkenyl monomer and unsaturated carboxylic acid and lipin polymer thereof, for example: 5040,5027 dispersion agents of Henkel KGaA company, the T-731 dispersion agent of U.S. Rhom and Hass, consumption is the 0.5-2% of amount of pigment; For pigment dyestuffs such as phthalocyanine blues, can select high-molecular block copolymer for use with close pigment group, the EFKA-4550 of the Byk184 of for example German Bi Ke company or Dutch EFKA company, consumption is the 5-20% of amount of pigment; Wetting agent is selected polyether-modified alkynol for use, and as SURFYNOL GA, the SURFYNOL TG of U.S. aerochemistry company, consumption is the 0.1-0.3% of coating content; Flow agent can be selected silane or fluorine-carbon modified polyethers for use, the Byk348,307 of for example German Bi Ke company, the EFKA-3570 of Dutch EFKA company; Defoamer is selected organic silicon modified by polyether for use, for example SN313 of Henkel KGaA company, NXZ, NDW, and the BYK 024 of Bi Ke company, consumption are the 0.01-0.1% of coating content; Sanitas can be the KATHONLXE of east-Rhom and Hass, and consumption is the 0.1-0.3% of coating content; Mould inhibitor can be the SKANE M-8 of east-Rhom and Hass, the BCM mould inhibitor of Xuzhou insecticide factory, and consumption is the 0.1-0.5% of coating content.The PH conditioning agent is a volatile alkali, for example: ammoniacal liquor, 2-amino-1-propyl alcohol, N-methylmorpholine, N-ethylmorpholine, triethylamine, N, N dimethylethanolamine.Thickening material is polyethers or caustic solubility ACRYLIC EMULSION class associative thickener, the TT935 thickening material of Beijing Orient-Rhom and Hass for example, the Rh-278 thickening material of U.S. Wei Lesi company.Softening water is deionized water or distilled water, the total amount＜100ppm of water-soluble substances wherein, specific conductivity＜20 μ s/cm.
The present invention makes the method for aforesaid propylene acid nanometer micro-emulsion, and its special character is: may further comprise the steps:
A. add first part of mixture that mixes unsaturated monomer, solvent and initiator in No. 1 reaction vessel, stir, logical nitrogen is warmed up to 80-110 ℃, insulation 1.5-2h; Wherein first part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, methacrylic acid, vinylformic acid, and their weight part is followed successively by: (10-20), (6-20), (0-10), (0-1), (0-1); The weight part of solvent and initiator is followed successively by: (6-10), (0.3-1);
B. second part of mixture that mixes unsaturated monomer, solvent and initiator evenly is added dropwise in No. 1 reaction vessel, the dropping time is 0.5-1h, at 80-110 ℃ of insulation 1-1.5h; Wherein second part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, methacrylic acid, vinylformic acid, and their weight part is followed successively by: (10-20), (6-20), (0-10), (0-1), (0-1); The weight part of solvent and initiator is followed successively by: (6-10), (0.3-1);
C. the 3rd part of mixture that mixes unsaturated monomer, solvent and initiator evenly is added dropwise in No. 1 reaction vessel, the dropping time is 0.5-1h, at 80-110 ℃ of insulation 1.5-2h; Wherein the 3rd part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, methacrylic acid, vinylformic acid, MALEIC ANHYDRIDE, and their weight part is followed successively by: (10-30), (8-20), (0-10), (0-2), (0-2), (0-2); The weight part of solvent and initiator is followed successively by: (8-10), (0.4-1);
D. PH conditioning agent and softening water are joined in No. 2 reaction vessels, stir, the material in No. 1 reaction vessel is transferred in No. 2 reaction vessels stirring and emulsifying 1-2h; Wherein: the weight part of PH conditioning agent and softening water is followed successively by: (3-7), (100-150);
E. the material that obtains among the step D is vacuumized solvent, and filter, the filtering larger particles obtains nanometer acrylic acid microemulsion.
Weight part in the above-mentioned steps all refers to weight part shared in the raw material total amount.In step e, solvent is deviate from, in final product nanometer acrylic acid microemulsion, do not contained solvent substantially.The vacuum tightness that vacuumizes in the step e generally can be 500-700mmHg, and filtration can adopt the 100-150 mesh filter screen to filter, and preferably adopts 120 mesh filter screens.The main component of the nanometer acrylic acid microemulsion that obtains in the step e is an acrylic copolymer, and the number-average molecular weight of this acrylic copolymer is 20000-100000, number average particle size in the 10-100nm scope greater than 95%.
The present invention makes the method for above-mentioned water-thinned heat reflecting and isolating paint, and its special character is: may further comprise the steps:
F. in joining the slurry container, add softening water, auxiliary agent, infrared reflection agent and nanometer acrylic acid microemulsion, stir;
G. add pigment and filler in the compound that in step F, obtains, stir;
H. obtain mill base below the compound that obtains among the step G being ground to fineness 30 μ m;
I. in the paint container, add mill base, cenosphere and conventional ACRYLIC EMULSION, stir;
J. add thickening material in the compound that in step I, obtains, stir;
K. add the PH conditioning agent in the compound that in step J, obtains, regulate pH value to 8-10;
L. the compound that obtains in the step K is filtered, the filtering larger particles obtains water-thinned heat reflecting and isolating paint.
Can adopt the adjustable high-speed dispersion machine to stir among step F, G, I, the J, can adopt ball mill or sand mill to grind among the step H, can adopt the 60-100 mesh filter screen to filter among the step L, preferably adopt 80 mesh filter screens.
Compare with existing solvent-based thermal reflective coating with common coating, the present invention has following advantage: 1. heat reflection and heat-proof quality excellence.Owing to contain infrared reflection agent and cenosphere in the water-thinned heat reflecting and isolating paint of the present invention, the former infrared rays in can reflection ray, the latter's surface can reflection ray, intermediary is hollow can be heat insulation, make water-thinned heat reflecting and isolating paint of the present invention can reflect the solar thermal energy of 50-80%, significantly reduce in the container or room temp.2. safe and convenient to use.Nanometer acrylic acid microemulsion of the present invention and water-thinned heat reflecting and isolating paint are medium with water, do not contain organic solvent and solubility promoter, can not cause environmental pollution, have improved construction environment, have avoided disaster hidden-trouble.3. good decorative property.The base-material of water-thinned heat reflecting and isolating paint of the present invention is conventional ACRYLIC EMULSION and nanometer acrylic acid microemulsion of the present invention, and latter's latex particle size is little, can fill the former emulsion particle gap, obtains the coating of uniform and smooth, high-decoration.4. paint film good combination property.Because in water-thinned heat reflecting and isolating paint of the present invention, conventional ACRYLIC EMULSION and nanometer acrylic acid microemulsion of the present invention are reasonably combined, the film forming densification, paint film adhesion, mechanical property, water tolerance, alkali resistance, weathering resistance are all good.
Every technical indicator of water-thinned heat reflecting and isolating paint of the present invention has has all met or exceeded solvent-based thermal reflective coating level, can replace the solvent-based thermal reflective coating fully, verified this coating is at buildings roof and interior exterior wall, petroleum chemical plant basin, pipeline, surface reflection of facility such as train, boats and ships and isolated solar heat, reducing the internal temperature aspect has good practical function.Substitute common protective coating or solvent-based thermal reflective heat-insulation paint with water-thinned heat reflecting and isolating paint of the present invention, can save energy, the protection environment is obtained huge social benefit and considerable economic.
Embodiment:
Below most preferred embodiment of the present invention is described in detail.
Embodiment 1 to 6:
As shown in table 1, embodiment 1 to 6 is respectively the proportioning raw materials of six kinds of nanometer acrylic acid microemulsions.
Table 1:
| Step | Raw material | Embodiment (g) | |||||
| 1 | ?2 | ?3 | ?4 | ?5 | ?6 | ||
| ????A | Methacrylic acid | 8 | ?8 | ?8 | ?8 | ?8 | ?8 |
| Methyl methacrylate | 100 | ?150 | ?150 | ?100 | ?200 | ?200 | |
| Butyl acrylate | 150 | ?150 | ?100 | ?200 | ?200 | ?100 | |
| Butyl methacrylate | 150 | ?100 | ?150 | ?100 | ?0 | ?100 | |
| Benzoyl peroxide | 1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | ?1.0 | |
| Propyl carbinol | 7 | ?7 | ?7 | ?7 | ?7 | ?7 | |
| ????B | Methacrylic acid | 12 | ?12 | ?12 | ?12 | ?12 | ?12 |
| Methyl methacrylate | 80 | ?110 | ?110 | ?75 | ?150 | ?150 | |
| Butyl acrylate | 110 | ?110 | ?80 | ?150 | ?150 | ?75 | |
| Butyl methacrylate | 110 | ?80 | ?110 | ?75 | ?0 | ?75 | |
| Benzoyl peroxide | 0.5 | ?0.5 | ?0.5 | ?0.5 | ?0.5 | ?0.5 | |
| Propyl carbinol | 8 | ?8 | ?8 | ?8 | ?8 | ?8 | |
| ????C | Methacrylic acid | 20 | ?10 | ?0 | ?0 | ?10 | ?15 |
| Vinylformic acid | 0 | ?0 | ?20 | ?10 | ?10 | ?0 | |
| MALEIC ANHYDRIDE | 0 | ?10 | ?0 | ?10 | ?0 | ?20 | |
| Methyl methacrylate | 80 | ?110 | ?110 | ?75 | ?150 | ?150 | |
| Butyl acrylate | 110 | ?110 | ?80 | ?150 | ?150 | ?75 | |
| Butyl methacrylate | 110 | ?80 | ?110 | ?75 | ?0 | ?75 | |
| Benzoyl peroxide | 0.5 | ?0.5 | ?0.5 | ?0.5 | ?0.5 | ?0.5 | |
| Propyl carbinol | 10 | ?10 | ?10 | ?10 | ?10 | ?10 | |
| ????D | Triethylamine | 3 | ?4 | ?5 | ?3 | ?4 | ?5 |
| 2-amino-1-propyl alcohol | 3 | ?2 | ?1 | ?0 | ?0 | ?0 | |
| N, the N dimethylethanolamine | 0 | ?0 | ?0 | ?3 | ?2 | ?1 | |
| Softening water | 150 | ?130 | ?110 | ?150 | ?130 | ?110 |
Benzoyl peroxide is an initiator in the table 1, and propyl carbinol is a solvent, triethylamine, 2-amino-1-propyl alcohol and N, and the N dimethylethanolamine is the PH conditioning agent.
The manufacture method of the nanometer acrylic acid microemulsion of the foregoing description 1 to 6 is that example is described as follows with the manufacture method of embodiment 4 only:
The manufacture method of the nanometer acrylic acid microemulsion of embodiment 4 may further comprise the steps:
A. add first part of mixture that mixes unsaturated monomer, solvent and initiator in No. 1 reaction vessel, stir, logical nitrogen is warmed up to 80-110 ℃, insulation 1.5-2h; Wherein first part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, methacrylic acid, and their weight (g) is followed successively by: 100,200,100,8; Solvent adopts propyl carbinol, and weight is 7g, and initiator adopts benzoyl peroxide, and weight is 1.0g;
B. second part of mixture that mixes unsaturated monomer, solvent and initiator evenly is added dropwise in No. 1 reaction vessel, the dropping time is 0.5-1h, at 80-110 ℃ of insulation 1-1.5h; Wherein second part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, methacrylic acid, and their weight (g) is followed successively by: 75,150,75,12; Solvent adopts propyl carbinol, and weight is 8g, and initiator adopts benzoyl peroxide, and weight is 0.5g;
C. the 3rd part of mixture that mixes unsaturated monomer, solvent and initiator evenly is added dropwise in No. 1 reaction vessel, the dropping time is 0.5-1h, at 80-110 ℃ of insulation 1.5-2h; Wherein the 3rd part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, vinylformic acid, MALEIC ANHYDRIDE, and their weight (g) is followed successively by: 75,150,75,10,10; Solvent adopts propyl carbinol, and weight is 10g, and initiator adopts benzoyl peroxide, and weight is 0.5g;
D. PH conditioning agent and softening water are joined in No. 2 reaction vessels, stir, the material in No. 1 reaction vessel is transferred in No. 2 reaction vessels stirring and emulsifying 1-2h; Wherein: the PH conditioning agent adopts triethylamine and N, the N dimethylethanolamine, and their weight all is 3g, the weight of softening water is 150g;
E. the material that obtains among the step D is vacuumized solvent, the vacuum tightness that vacuumizes is 500-700mmHg, and with 120 order copper strainer filterings, the filtering larger particles obtains nanometer acrylic acid microemulsion.
The performance of six kinds of nanometer acrylic acid microemulsions of the foregoing description 1 to 6 sees Table 2.
Table 2:
| Project | Embodiment | |||||
| ??1 | ??2 | ??3 | ??4 | ??5 | ??6 | |
| Self-emulsifying | Excellent | Very | Excellent | Very | Excellent | Very |
| Thermostability | Excellent | Very | Excellent | Very | Excellent | Very |
| Mechanical stability | Excellent | Very | Excellent | Very | Excellent | Very |
| Mill efficiency | Very | Excellent | Very | Excellent | Very | Excellent |
| The paint film water tolerance, h | ??120 | ??168 | ??96 | ??120 | ??96 | ??168 |
Embodiment 7 to 15:
As shown in table 3, embodiment 7 to 15 is respectively the proportioning raw materials of nine kinds of water-thinned heat reflecting and isolating paints.
Table 3:
| Raw material | Embodiment (g) | ||||||||
| ????7 | ????8 | ????9 | ????10 | ????11 | ????12 | ????13 | ????14 | ????15 | |
| Softening water | ????215 | ????250 | ????250 | ????205 | ????200 | ????215 | ????210 | ????215 | ????200 |
| SURFYNOL?GA | ????2.0 | ????1.5 | ????1.5 | ????1.0 | ????2.0 | ????1.5 | ????2.0 | ????2.0 | ????1.5 |
| Dispersion agent 5040 | ????1.5 | ????2 | ????1.5 | ????2 | ????2 | ????2 | ????2 | ????1.5 | ????1.5 |
| Dispersant B yk184 | ????2 | ????2 | ????0 | ????0.5 | ????3 | ????0.5 | ????1 | ????0 | ????2 |
| Defoamer NXZ | ????0.3 | ????0.1 | ????0.2 | ????0.2 | ????0.3 | ????0.1 | ????0.2 | ????0.3 | ????0.1 |
| KATHON?LXE | ????2 | ????1.5 | ????1 | ????1.5 | ????1.5 | ????2 | ????1 | ????1 | ????1 |
| SKANE?M-8 | ????1 | ????2 | ????3 | ????2 | ????1 | ????0 | ????1 | ????1 | ????1 |
| The BCM mould inhibitor | ????0 | ????0 | ????0 | ????1 | ????2 | ????3 | ????2 | ????2 | ????2 |
| Triethylamine | ????3 | ????2 | ????2 | ????5 | ????5 | ????3 | ????2 | ????2 | ????5 |
| Titanium dioxide | ????150 | ????150 | ????150 | ????150 | ????150 | ????50 | ????100 | ????150 | ????0 |
| Red iron oxide | ????1.5 | ????0 | ????0 | ????1.5 | ????0 | ????0 | ????0 | ????0 | ????0 |
| Iron oxide yellow | ????0 | ????1.5 | ????1.5 | ????0 | ????0 | ????0 | ????0 | ????0 | ????0 |
| Organic yellow | ????0 | ????0 | ????0.5 | ????0 | ????0 | ????30 | ????15 | ????6 | ????30 |
| Phthalein green grass or young crops is red | ????0 | ????0 | ????0 | ????0.5 | ????0 | ????10 | ????5 | ????2 | ????10 |
| Phthalocyanine blue | ????0 | ????0 | ????0 | ????0 | ????0.1 | ????10 | ????5 | ????2 | ????10 |
| The infrared reflection agent | ????0.2 | ????0.4 | ????0.6 | ????0.8 | ????0.8 | ????1.0 | ????0.8 | ????0.6 | ????1.0 |
| Hollow glass micropearl | ????5 | ????7 | ????10 | ????0 | ????0 | ????0 | ????2 | ????3 | ????5 |
| Pearl floats in power plant | ????0 | ????0 | ????0 | ????6 | ????8 | ????10 | ????3 | ????4 | ????5 |
| Process white | ????150 | ????150 | ????150 | ????150 | ????150 | ????270 | ????220 | ????180 | ????350 |
| The micronized talc powder | ????120 | ????120 | ????120 | ????120 | ????120 | ????100 | ????100 | ????100 | ????100 |
| Self-control 1 #Emulsion | ????150 | ????00 | ????0 | ????0 | ????150 | ????0 | ????0 | ????0 | ????650 |
| Self-control 2 #Emulsion | ????0 | ????150 | ????0 | ????0 | ????0 | ????150 | ????0 | ????0 | ????0 |
| Self-control 4 #Emulsion | ????0 | ????0 | ????175 | ????0 | ????0 | ????0 | ????175 | ????0 | ????0 |
| Self-control 6 #Emulsion | ????0 | ????0 | ????0 | ????200 | ????0 | ????0 | ????0 | ????200 | ????250 |
| The B-96 emulsion | ????150 | ????150 | ????175 | ????200 | ????0 | ????0 | ????0 | ????0 | ????150 |
| The AC-261 emulsion | ????0 | ????0 | ????0 | ????0 | ????150 | ????150 | ????175 | ????200 | ????100 |
| The TT-935 thickening material | ????10 | ????8 | ????6 | ????0 | ????0 | ????0 | ????7 | ????6 | ????5 |
| The Rh-278 thickening material | ????0 | ????0 | ????0 | ????10 | ????8 | ????6 | ????3 | ????2 | ????1 |
SURFYNOL GA in the table 3, dispersion agent 5040, dispersant B yk184, defoamer NXZ, KATHON LXE, SKANE M-8 and BCM mould inhibitor are auxiliary agent; Triethylamine is the PH conditioning agent; The blue or green red and phthalocyanine blue of titanium dioxide, red iron oxide, iron oxide yellow, organic yellow, phthalein is a pigment; It is cenosphere that pearl floats in hollow glass micropearl and power plant; Process white and micronized talc powder are filler; Self-control 1
#Emulsion, self-control 2
#Emulsion, self-control 4
#Emulsion and self-control 6
#Emulsion is respectively the nanometer acrylic acid microemulsion of making according to the composition of raw materials of the foregoing description 1, embodiment 2, embodiment 4 and embodiment 6; B-96 emulsion and AC-261 emulsion are conventional ACRYLIC EMULSION; TT-935 thickening material and Rh-278 thickening material are thickening material.
The manufacture method of the water-thinned heat reflecting and isolating paint of the foregoing description 7 to 15 is that example is described as follows with the manufacture method of embodiment 7 only:
The manufacture method of the water-thinned heat reflecting and isolating paint of embodiment 7 may further comprise the steps:
F. in joining the slurry container, add softening water, auxiliary agent, infrared reflection agent and nanometer acrylic acid microemulsion, stir with the adjustable high-speed dispersion machine; Softening water 215g wherein, auxiliary agent comprises SURFYNOL GA, dispersion agent 5040, dispersant B yk184, defoamer NXZ, KATHONLXE, SKANE M-8, be respectively 2.0g, 1.5g, 2g, 0.3g, 2g, 1g, infrared reflection agent 0.2g, the nanometer acrylic acid microemulsion 150g that the composition of raw materials of employing embodiment 1 is made;
G. add pigment and filler in the compound that in step F, obtains, stir with the adjustable high-speed dispersion machine; Wherein pigment comprises titanium dioxide, red iron oxide, is respectively 150g, 1.5g, and filler comprises process white and micronized talc powder, is respectively 150g, 120g;
H. the compound that obtains among the step G is obtained mill base with ball mill grinding to fineness 30 μ m;
I. in the paint container, add mill base, cenosphere and the conventional ACRYLIC EMULSION that obtains among the step H, stir with the adjustable high-speed dispersion machine; Cenosphere adopts hollow glass micropearl, and weight is 5g, and conventional ACRYLIC EMULSION adopts the B-96 emulsion, and weight is 150g;
J. add thickening material in the compound that in step I, obtains, stir with the adjustable high-speed dispersion machine; Thickening material adopts the TT-935 thickening material, and weight is 10g;
K. add the PH conditioning agent in the compound that in step J, obtains, regulate pH value to 8-10; The PH conditioning agent adopts triethylamine, and weight is 3g;
L. the compound that obtains in the step K is adopted 80 order copper strainer filterings, the filtering larger particles obtains water-thinned heat reflecting and isolating paint.
The performance of nine kinds of water-thinned heat reflecting and isolating paints of the foregoing description 7 to 15 sees Table 4.
Table 4:
| Project | Embodiment | |||||||||
| 7 | ??8 | ??9 | ??10 | ?11 | ??12 | ??13 | ??14 | ??15 | ||
| Appearance of coat | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified | Qualified | |
| Viscosity, s,＞ | 30 | ??30 | ??30 | ??30 | ?30 | ??30 | ??30 | ??30 | ??30 | |
| Time of drying | Surface drying, h | 2 | ??2 | ??2 | ??2 | ?2 | ??2 | ??2 | ??2 | ??2 |
| Do solid work h | 24 | ??24 | ??24 | ??24 | ?24 | ??24 | ??24 | ??24 | ??24 | |
| Sticking power, level | 1 | ??1 | ??1 | ??1 | ?1 | ??1 | ??1 | ??1 | ??1 | |
| Shock-resistant, Kg.cm | 40 | ??40 | ??40 | ??40 | ?40 | ??40 | ??40 | ??40 | ??40 | |
| Snappiness, mm | 2 | ??2 | ??2 | ??2 | ?2 | ??2 | ??2 | ??2 | ??2 | |
| Water-fast, 96h | By | By | By | By | By | By | By | By | By | |
| The solar heat reflection rate, % | 73 | ??71 | ??71 | ??72 | ?59 | ??63 | ??65 | ??69 | ??56 | |
| Freeze-thawing resistant, cycle number | 5 | ??5 | ??5 | ??5 | ?5 | ??5 | ??5 | ??5 | ??5 | |
Claims (10)
1. nanometer acrylic acid microemulsion, it is characterized in that: its raw material contains:
The raw material weight ratio
Methyl methacrylate 30-70
Butyl acrylate 20-60
And/or butyl methacrylate 0-30
And/or methacrylic acid 0-4
And/or vinylformic acid 0-4
And/or MALEIC ANHYDRIDE 0-2
Initiator 1-3
PH conditioning agent 3-7
Solvent 20-30
Softening water 100-150.
2. contain the water-thinned heat reflecting and isolating paint of the described nanometer acrylic acid microemulsion of claim 1, it is characterized in that: its raw material contains:
The raw material weight ratio
Nanometer acrylic acid microemulsion 15-25
Conventional ACRYLIC EMULSION 15-25
Pigment 1-20
Filler 5-20
Infrared reflection agent 0.1-1
Cenosphere 1-10
Auxiliary agent 0.5-2.5
PH conditioning agent 0.1-0.5
Thickening material 0.2-1.5
Softening water 20-40.
3. water-thinned heat reflecting and isolating paint according to claim 2 is characterized in that: cenosphere comprises that hollow ceramic microspheres, hollow glass micropearl and power plant float one or more in the pearl.
4. water-thinned heat reflecting and isolating paint according to claim 3 is characterized in that: hollow glass micropearl is to be that raw material makes with the low boron glass of degree of hydrolysis.
5. water-thinned heat reflecting and isolating paint according to claim 2 is characterized in that: pigment comprises that iron oxide black, red iron oxide, iron oxide yellow, titanium dioxide, phthalein green grass or young crops are red, in phthalocyanine blue and the organic yellow one or more.
6. water-thinned heat reflecting and isolating paint according to claim 2 is characterized in that: filler comprises one or more in light calcium carbonate, process white, talcum powder and the mica powder.
7. water-thinned heat reflecting and isolating paint according to claim 2 is characterized in that: the infrared reflection agent is the nano-scale oxide micro mist of nanometer titanium dioxide micropowder and/or noble ruthenium, rhodium, iridium.
8. water-thinned heat reflecting and isolating paint according to claim 2 is characterized in that: thickening material is polyethers and/or caustic solubility ACRYLIC EMULSION class associative thickener.
9. make the method for the described nanometer acrylic acid microemulsion of claim 1, it is characterized in that: may further comprise the steps:
A. add first part of mixture that mixes unsaturated monomer, solvent and initiator in No. 1 reaction vessel, stir, logical nitrogen is warmed up to 80-110 ℃, insulation 1.5-2h; Wherein first part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, methacrylic acid, vinylformic acid, and their weight part is followed successively by: (10-20), (6-20), (0-10), (0-1), (0-1); The weight part of solvent and initiator is followed successively by: (6-10), (0.3-1);
B. second part of mixture that mixes unsaturated monomer, solvent and initiator evenly is added dropwise in No. 1 reaction vessel, the dropping time is 0.5-1h, at 80-110 ℃ of insulation 1-1.5h; Wherein second part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, methacrylic acid, vinylformic acid, and their weight part is followed successively by: (10-20), (6-20), (0-10), (0-1), (0-1); The weight part of solvent and initiator is followed successively by: (6-10), (0.3-1);
C. the 3rd part of mixture that mixes unsaturated monomer, solvent and initiator evenly is added dropwise in No. 1 reaction vessel, the dropping time is 0.5-1h, at 80-110 ℃ of insulation 1.5-2h; Wherein the 3rd part of unsaturated monomer comprises methyl methacrylate, butyl acrylate, butyl methacrylate, methacrylic acid, vinylformic acid, MALEIC ANHYDRIDE, and their weight part is followed successively by: (10-30), (8-20), (0-10), (0-2), (0-2), (0-2); The weight part of solvent and initiator is followed successively by: (8-10), (0.4-1);
D. PH conditioning agent and softening water are joined in No. 2 reaction vessels, stir, the material in No. 1 reaction vessel is transferred in No. 2 reaction vessels stirring and emulsifying 1-2h; Wherein: the weight part of PH conditioning agent and softening water is followed successively by: (3-7), (100-150);
E. the material that obtains among the step D is vacuumized solvent, and filter, the filtering larger particles obtains nanometer acrylic acid microemulsion.
10. make the method for the described water-thinned heat reflecting and isolating paint of claim 2, it is characterized in that: may further comprise the steps:
F. in joining the slurry container, add softening water, auxiliary agent, infrared reflection agent and nanometer acrylic acid microemulsion, stir;
G. add pigment and filler in the compound that in step F, obtains, stir;
H. obtain mill base below the compound that obtains among the step G being ground to fineness 30 μ m;
I. in the paint container, add mill base, cenosphere and conventional ACRYLIC EMULSION, stir;
J. add thickening material in the compound that in step I, obtains, stir;
K. add the PH conditioning agent in the compound that in step J, obtains, regulate pH value to 8-10;
L. the compound that obtains in the step K is filtered, the filtering larger particles obtains water-thinned heat reflecting and isolating paint.
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