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CN1235530C - Product applicator particularly cosmetic applicator and method for producing said applicator - Google Patents

Product applicator particularly cosmetic applicator and method for producing said applicator Download PDF

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CN1235530C
CN1235530C CN03143835.0A CN03143835A CN1235530C CN 1235530 C CN1235530 C CN 1235530C CN 03143835 A CN03143835 A CN 03143835A CN 1235530 C CN1235530 C CN 1235530C
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fiber
sweep
curvature
product
applicator
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CN1473528A (en
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G·罗塞莱特
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LOreal SA
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    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0238Bristles with non-round cross-section
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B9/00Arrangements of the bristles in the brush body
    • A46B9/02Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups
    • A46B9/021Position or arrangement of bristles in relation to surface of the brush body, e.g. inclined, in rows, in groups arranged like in cosmetics brushes, e.g. mascara, nail polish, eye shadow
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B2200/00Brushes characterized by their functions, uses or applications
    • A46B2200/10For human or animal care
    • A46B2200/1046Brush used for applying cosmetics
    • A46B2200/1053Cosmetics applicator specifically for mascara
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles

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  • Coating Apparatus (AREA)
  • Cosmetics (AREA)
  • Closures For Containers (AREA)

Abstract

本发明涉及一种用于涂敷产品的装置(1),尤其是一种用于涂敷化妆和/或护理产品的装置,其中包括一种具有至少一个自由端的多个聚合物纤维的布置形式,所述纤维被安装固定在一个支撑件(3)上并且至少在一些情况下具有弯曲部分,该弯曲部分从支撑件到它(或它们的)自由端连续延伸,该弯曲部分有一个小于45毫米的平均曲率半径,所述弯曲部分相对于彼此被自由定向。

Figure 03143835

The invention relates to a device (1) for applying products, in particular cosmetic and/or care products, comprising an arrangement of polymer fibers having at least one free end , said fibers are mounted on a support (3) and have, at least in some cases, a bend extending continuously from the support to its (or their) free end, the bend having a length less than 45 mm mean radius of curvature, the curved parts are freely oriented relative to each other.

Figure 03143835

Description

产品涂敷装置器、 其生产方法和组合装置Product application device, its production method and combined device

技术领域technical field

本发明涉及一种用于涂敷产品,尤其是化妆品产品和/或尤其是化妆和/或护理用品的装置。该产品是将被涂敷于皮肤或指甲,或者角质纤维,尤其是头发、睫毛或眉毛上的。The invention relates to a device for applying a product, especially a cosmetic product and/or especially a make-up and/or care product. The product is to be applied to the skin or nails, or to keratinous fibers, especially hair, eyelashes or eyebrows.

背景技术Background technique

在化妆品领域,化妆师一直在寻求一种新的效果。In the field of cosmetics, makeup artists are always looking for a new effect.

在睫毛油的领域特别如此,寻求获得能美化身体或更具自然效果的,可以增强弯曲性或伸展性或者这些不同的基本特性的混合效果的化妆品。This is particularly the case in the field of mascaras, cosmetic products that enhance the curl or extension or a mixture of these different basic properties are sought to beautify the body or have a more natural effect.

寻求新的涂敷器具的发展方向由具有新的成分的化妆品的外观决定,因为它们的流变能力不能由传统的涂敷器来实现。The direction of development in the search for new applicators is dictated by the appearance of cosmetic products with new ingredients, since their rheology cannot be achieved by conventional applicators.

因此,专利文献都是这样的专利,它们所公开的装置的目的是产生新的化妆效果或能够涂敷于具有特殊流变能力成分的化妆品。The patent documents are therefore patents which disclose devices aimed at producing new cosmetic effects or able to be applied to cosmetics with ingredients of special rheological power.

作为例子,在这样一些专利中描述的装置可以从以下几方面来彼此区分开:它们的涂敷件(通常是纤维)的密度和/或形状;它们的纵断面或横断面形状;支撑部分和/或涂敷件中天然材料的组成状态;全部或部分涂敷器所承受的处理方式,或者可以从整个包装和涂敷器组合装置中任何其它构件来区分,其中涂敷器装置仅有一个组成部分(例如擦拭器)。As examples, the devices described in such patents can be distinguished from one another in the following respects: the density and/or shape of their applicator members (usually fibers); their longitudinal or cross-sectional shape; and/or the state of composition of the natural materials in the applicator; the manner in which all or part of the applicator has been subjected to, or can be distinguished from any other component of the entire package and applicator assembly, where the applicator device has only one Components (such as wipers).

因此,更特殊的,法国专利申请A 2 668 905描述了一种制成睫毛刷的方法,其包括,当刷被扭转和修剪成想要的外形后,加热纤维的尖端使它们融化,并且由于聚合物材料挨近在一起,因此在纤维的尖端形成小球形的膨大部。经过这些处理纤维基本上仍然是直的。Thus, more specifically, French patent application A 2 668 905 describes a method of making a mascara brush which involves, after the brush has been twisted and trimmed into the desired shape, heating the tips of the fibers to melt them, and due to The polymeric material is close together, thus forming a small spherical swelling at the tip of the fiber. After these treatments the fibers are still substantially straight.

另举一个例子,美国专利申请A 5 161 554描述了一种扭转刷型的睫毛刷,在沿纵轴线方向纤维部分的断面是不同的。纤维是锯齿形的或波浪形的。结果就是纤维具有由一个方向向另一个方向交替变化的曲率,在每次曲率改变时,曲率半径在一个最大半径和最小半径之间变化。As another example, US patent application A 5 161 554 describes a mascara brush of the twisted brush type, in which the section of the fiber portion along the longitudinal axis is different. Fibers are zigzag or wavy. The result is that the fiber has a curvature that alternates from one direction to the other, with the radius of curvature changing between a maximum radius and a minimum radius at each curvature change.

本申请中描述了一定数目的操作方式,尤其在纤维挤压成型过程中或挤压成型后,给出它们一个需要的外形。A number of manipulations are described in this application, especially during or after extrusion of the fibers, to give them a desired shape.

处理过后的纤维被以传统方式布置为纤维层,将该纤维层插入到一定长度U形金属线的两分支之间。然后两分支相对于彼此扭转,使纤维成一个多圈螺旋型的布置形式。The treated fibers are arranged in a conventional manner in a fiber layer which is inserted between two branches of a length of U-shaped metal wire. The two branches are then twisted relative to each other, causing the fibers to form a multi-turn helical arrangement.

根据经验,人们知道:From experience, people know that:

i)当在挤压纤维的过程中产生变形时,由于挤压过程本身,必要的会产生一个大的最小弯曲,并且i) when deformation occurs during extrusion of the fibers, a large minimum bend is necessary due to the extrusion process itself, and

ii)当变形是在挤压后处理的结果时,它们同样有一个大的最小弯曲,如果没有该变曲,在用自动方式操作把它们以层的方式放进一定长度U型金属线的两分支之间,然后使该一定长度的金属线的两分支扭转时会产生大的问题。ii) When the deformation is the result of post-extrusion processing, they also have a large minimum bend, and if there is no such deformation, they are placed in layers in two layers of a certain length of U-shaped wire in an automatic manner. Between the branches and then twisting the two branches of the length of wire creates a big problem.

我们也知道对于睫毛刷是通过模制产生的。模具被设计成涂敷器部件的自由端,该部件通常讲是直的,终止于一个叉形或钩型部分。由于这些末端部分通过模制得到,它们相对的方向是被事先决定的。结果从化妆的观点来看是令人失望的。而且,为了每一种需要类型的化妆都需要一个模具。We also know that for mascara brushes are produced by moulding. The die is designed as the free end of the applicator part, which is generally straight, terminating in a fork or hook-shaped portion. Since these end portions are obtained by moulding, their relative orientation is predetermined. The results were disappointing from a cosmetic point of view. Also, a mold is required for each required type of makeup.

我们也知道,对于睫毛刷,纤维的自由端会被碾或磨而被分成多股。一个弯曲形状的纤维部分可以由这种纯机械处理来产生。然而这些弯曲的部分,严格地定位在纤维的末端。而且,把曲率半径降低到50毫米以下是很难的。We also know that for mascara brushes, the free ends of the fibers are milled or ground to separate them into strands. A curved shape of the fiber section can be produced by this purely mechanical treatment. These curved sections, however, are strictly positioned at the ends of the fibers. Also, it is difficult to reduce the radius of curvature below 50mm.

用这种曲率半径,对于涉及的化妆效果,结果是不大显而易见的。With such radii of curvature, the results are less noticeable with respect to the cosmetic effects involved.

发明内容Contents of the invention

因此,本申请的一个目的是提供一种涂敷器装置,尤其是一种用于涂敷化妆和/或护理产品的涂敷器装置,以解决上述讨论过的关于现有设备中的所有或一部分问题。It is therefore an object of the present application to provide an applicator device, in particular an applicator device for applying cosmetic and/or care products, which solves all or all of the above-discussed problems with existing devices. Part of the problem.

特别的,本发明的一个目的是提供一种用于涂敷化妆和/或护理产品的装置,其从达到一定化妆效果的角度讲表现了一个可供选择的解决办法,或者达到一个可行的与传统的方式不同的化妆效果。In particular, it is an object of the present invention to provide a device for applying cosmetic and/or care products, which represents an alternative solution from the point of view of achieving a certain cosmetic effect, or achieves a feasible and Different makeup effects in the traditional way.

本发明的另一个目的就是提供一个用起来经济的装置。Another object of the invention is to provide a device which is economical to use.

本发明的另一个目的是提供一种生产涂敷器的方法,特别是一种生产用于护理和/或化妆产品上的涂敷器的方法,其可以简单而经济的在一个工业设备上实现。Another object of the present invention is to provide a method for producing applicators, in particular for producing applicators for care and/or cosmetic products, which can be carried out simply and economically on an industrial plant .

其他的目的从接下来的细节描述可以很显然的得知。Other purposes will be apparent from the detailed description that follows.

根据本发明,这些目的可以通过提供一种用于涂敷产品的装置来实现,尤其是一种涂敷化妆和/或护理产品的装置,其中包括具有至少一个自由端的聚合物纤维的布置形式,所述的纤维被装配和固定到一个支撑件上,并且,该纤维在至少一些情况下包括至少一个弯曲部分,所述纤维:According to the invention, these objects are achieved by providing a device for applying a product, in particular a cosmetic and/or care product, comprising an arrangement of polymer fibers having at least one free end, said fibers are assembled and secured to a support and, in at least some cases, include at least one bend, said fibers:

i)从支撑部到一个(或它们的)自由端连续延伸,并且i) extend continuously from the support to one (or their) free end, and

ii)平均曲率半径小于45毫米,所述弯曲相对于彼此是自由定向的。“连续”的意思是指在支撑部和自由端之间的弯曲方向没有反转。ii) the average radius of curvature is less than 45 mm, and the curvatures are freely oriented relative to each other. By "continuous" is meant that there is no reversal in the direction of bending between the support and the free end.

这种弯曲可以通过给全部或部分的涂敷器装置加热到适当的温度而更好的得到,该温度高于聚合体形成所述需要被弯曲的纤维的玻璃转化温度,低于所述聚合体在半结晶状聚合体的情况下的熔点温度。This bending can be better obtained by heating all or part of the applicator assembly to a temperature above the glass transition temperature of the polymer forming the fiber that needs to be bent, and below the temperature of the polymer The melting point temperature in the case of a semi-crystalline polymer.

加热的过程被调节以适合于纤维的材料和直径以得到需要的曲率,并且不引起任何材料连接在一起的情况,与前面描述的法国专利申请A 2 688 905中提到的那样,能够产生纤维实质性地缩短,并且改变它们的横断面,尤其是在端部。The heating process is adjusted to the material and diameter of the fibers to obtain the desired curvature and does not cause any material bonding together, as mentioned in the aforementioned French patent application A 2 688 905, capable of producing fibers Substantially shorten and change their cross-section, especially at the ends.

在大约45毫米的限值以上的效果,尤其是化妆效果,可能没有被充分地考虑,特别是当涂敷产品的流变能力发生变化时。Effects above the limit of about 45 mm, especially cosmetic effects, may not be adequately considered, especially when the rheology of the applied product changes.

纤维的大曲率,甚至假定纤维的密度很高,尤其是对于这种扭转型的睫毛刷的每一匝,可以使在两个连续匝之间的空隙充分地减小并且产生混合效果,因此阻止妆容被溅污。The large curvature of the fibers, even assuming a high fiber density, especially for each turn of this twisted mascara brush, allows the gap between two successive turns to be sufficiently reduced and the mixing effect to occur, thus preventing Makeup was splattered.

实际上,通过纤维的曲率半径与例如纤维的密度,它们的直径,它们的断面形状,或者刷的形状等其他参数协力,可以将妆容由非常自然变得浓重和/或多少得到一定程度的延长或弯曲的涂敷效果。In fact, through the combination of the radius of curvature of the fibers and other parameters such as the density of the fibers, their diameter, their cross-sectional shape, or the shape of the brush, the makeup can be changed from very natural to thick and/or somewhat extended or curved coating effect.

由于相当可观的弯曲,在涂敷器打算用于化妆的情况下,得到与传统型的涂敷器化妆的类型相比较新的化妆类型也是可能的,而且这样做时化妆品的成分是同样的。Due to the considerable curvature, it is also possible, in case the applicator is intended for makeup, to obtain a new type of makeup compared to the type of applicator makeup of the traditional type, and in doing so the composition of the cosmetic is the same.

在用涂敷器涂敷指甲油或者指甲护理成分时,涂敷器成型为漆刷的形式,纤维的弯曲有助于使它们彼此之间隔开一定的距离,因此提高在漆刷纤维间保持的产品的量。由于这个事实,刷一次所携带的量会更多。When applying nail polish or nail care ingredients with an applicator shaped like a paintbrush, the curvature of the fibers helps to keep them at a distance from each other, thus improving the retention between the paintbrush fibers. amount of product. Due to this fact, the amount carried in one swipe will be more.

而且,由于在这种漆刷的纤维簇的特殊结构,在指甲上会形成有班驳的效果。Moreover, due to the special structure of the fiber clusters in this paint brush, a mottled effect is formed on the nails.

所述纤维优选从支撑部到相应的自由端基本上连续弯曲。所说的“基本上连续”是在曲率的变化的围绕平均数在至多15%的范围内变化,优选的围绕所述平均数在至多10%的范围内变化。The fibers are preferably bent substantially continuously from the support to the respective free end. By "substantially continuous" is meant that the variation in curvature varies within a range of at most 15% around the mean, preferably up to 10% around said mean.

根据本发明,涂敷器可以被成形为刷毛基本上彼此平行的布置形式,并且,模仿牙刷的形式,与一个所述支撑部的轴线垂直延伸。这些涂敷器通常与一个预先以固体块形式存在的产品结合使用,固体块在使用前必须先被弄潮湿。According to the invention, the applicator may be shaped in an arrangement of bristles substantially parallel to each other and, imitating the form of a toothbrush, extending perpendicularly to the axis of one of said supports. These applicators are usually combined with a product that comes pre-existing in a solid block that must be moistened before use.

弯曲部分的平均曲率半径优选在2毫米和40毫米之间。最好在2和30毫米之间。更适宜的,是小于20毫米大于3毫米。更加适宜的,曲率半径在3毫米和10毫米之间。The average radius of curvature of the curved portion is preferably between 2 mm and 40 mm. Preferably between 2 and 30 mm. More suitably, it is less than 20 mm and greater than 3 mm. More suitably, the radius of curvature is between 3 mm and 10 mm.

所述纤维有利的是由热塑性塑料材料制成,并且尤其是由聚酰胺,或由热塑性弹性体制成。热塑性材料可以完全是非晶体的或是半结晶的。The fibers are advantageously made of a thermoplastic material, and especially of polyamide, or of a thermoplastic elastomer. Thermoplastic materials can be entirely amorphous or semi-crystalline.

通过举例提到了例如市场上卖的商标为聚酰胺纤维(Tynex)的聚酰胺6s。By way of example, polyamide 6s such as that commercially available under the trade mark Polyamide Fiber (Tynex(R)) is mentioned.

纤维的直径可在0.06毫米到0.35毫米之间,优选在0.10毫米和0.25毫米之间的。The diameter of the fibers may be between 0.06 mm and 0.35 mm, preferably between 0.10 mm and 0.25 mm.

在一个优选实施例中,涂敷器包括一完全直的纤维或者部分直的纤维。In a preferred embodiment, the applicator comprises a completely straight fiber or a partially straight fiber.

可选择地,它包括具有第一平均曲率半径的第一组弯曲部分和具有与第一组曲率半径不同的曲率半径的第二组弯曲部分。Optionally, it includes a first set of curved portions having a first average radius of curvature and a second set of curved portions having a different radius of curvature than the first set of radii of curvature.

第一和第二组的不同的曲率半径是使用形成于不同材料并且尤其具有不同的玻璃转化温度的第一型和第二型的纤维的结果。The different radii of curvature of the first and second sets are the result of using fibers of the first and second type formed from different materials and having, inter alia, different glass transition temperatures.

然而,这些不同可以等同地由形成于同一材料的纤维得到。如果这样猜想,则有许多可能存在:However, these differences can equally be obtained with fibers formed from the same material. If you guess like this, there are many possibilities:

i)根据温度或加热的时间长短,形成的两组弯曲部分的热处理条件是不同的,或者i) The heat treatment conditions of the two sets of curved parts formed are different according to the temperature or the length of heating, or

ii)形成第一组弯曲部分的纤维的直径和/或形状不同于用于形成第二组弯曲部分的纤维的直径和/或形状。ii) The diameter and/or shape of the fibers forming the first set of bends is different from the diameter and/or shape of the fibers used to form the second set of bends.

因此,可以单独或混合使用,实心或中空的刷毛,或者圆形,三角形的,细长形的或C形断面或四叶苜蓿形的(四叶状的)断面的刷毛。也可以用其他的形状的。Thus, solid or hollow bristles, or bristles of round, triangular, elongated or C-section or cloverleaf (four-leaved) section, can be used alone or in admixture. Other shapes can also be used.

当不同弯曲部分组的被彼此混合时,弯曲部分帮助产生特殊涂敷的效果,尤其是当涉及化妆品时。当它们彼此分开时,也可以用于需要处理的区域的不同区段。When different groups of bends are mixed with each other, the bends help to create a special application effect, especially when it comes to cosmetics. When they are separated from each other, they can also be used in different sections of the area to be treated.

支持部分有利的是由一个由两股形成的被扭转的轴芯形成,尤其是彼此相对扭转的金属线,纤维被固定在两个弯曲的股之间并且相对于扭转轴芯放射状延伸,装置是用于来把产品涂敷到角质纤维,尤其是睫毛或眉毛上的。The support part is advantageously formed by a twisted core formed by two strands, in particular metal wires twisted relative to each other, the fibers being fixed between the two bent strands and extending radially relative to the twisted core, the means being Used to apply products to keratinous fibers, especially eyelashes or eyebrows.

对于符合优选实施例的涂敷器,每根纤维基本上都在其中心处被扭转轴芯夹持在适当位置,该纤维包括两部分,这两部分都从支撑处向其相应的自由端延伸。从这样的涂敷器中可以看出:For applicators in accordance with the preferred embodiments, each fiber is held in place substantially at its center by a twisted mandrel, the fiber comprising two parts extending from the support to its respective free end . From such an applicator it can be seen that:

i)两部分的纤维都被弯曲并且具有不同或相同的曲率;或i) the fibers of both parts are bent and have different or the same curvature; or

ii)纤维的一部分被弯曲并且另一部分是直的,或者可能的是,ii) One part of the fiber is bent and the other part is straight, or possibly,

iii)纤维的两部分都是直的,混合了类别i)和ii)或者两者之一。iii) Both parts of the fiber are straight, mixing categories i) and ii) or both.

纤维优选被布置成螺旋形式,每一匝的纤维数目在5和80之间并且尤其是在10和45之间。纤维的螺旋型布置可能较容易看得出或较不容易看得出,或者完全看不出来,涂敷器的表面随纤维弯曲的程度而改变。The fibers are preferably arranged in a helical form, the number of fibers per turn being between 5 and 80 and in particular between 10 and 45. The helical arrangement of the fibers may be more or less visible, or not at all, and the surface of the applicator varies with the degree of bending of the fibers.

涂敷器装置的断面可以是圆形的,或者多边形的,尤其是三角形,四方形或者五边形的。也可以设想是其它形状的。The cross-section of the applicator device may be circular, or polygonal, especially triangular, square or pentagonal. Other shapes are also conceivable.

被扭转的轴芯可以是直的或是弯曲的。The twisted mandrel can be straight or curved.

扭转的轴芯有多个圈,当在竖直位置侧视刷子时这些圈是由左至右上升的。在这种情况下,刷子被称作“逆时针弯曲”。The twisted mandrel has turns that rise from left to right when looking at the brush sideways in the vertical position. In this case, the brush is said to be "curved counterclockwise".

可选择地,在竖直位置侧视时,扭转轴芯可以有由右至左上升的多个圈。这种情况下,刷子被称作“顺时针弯曲”。Alternatively, the torsion axis may have multiple turns rising from right to left when viewed sideways in a vertical position. In this case, the brush is said to be "clockwise bent".

在涂敷器有多组不同曲率的弯曲部分时,所述弯曲会在支撑处彼此混合。When the applicator has multiple sets of bends of different curvature, the bends will blend with each other at the support.

可选择地,不同的弯曲部分的组可以被放在支撑部分的不同点。Alternatively, different sets of curved portions may be placed at different points on the support portion.

在这种情况下,弯曲部分的第一和第二组可沿支撑部分的纵向轴线被置换。In this case, the first and second sets of curved portions may be displaced along the longitudinal axis of the support portion.

可选择地,它们可以绕着扭转轴芯有角度的被置换。Alternatively, they may be angularly displaced about the torsion axis.

根据本发明的另一个方面,还提供了一种生产用于涂敷产品的装置的方法,并且尤其是一种生产用于涂敷化妆和/或护理产品的装置的方法,其中包括以下步骤:According to another aspect of the invention there is also provided a method of producing a device for applying a product, and in particular a method of producing a device for applying a cosmetic and/or care product, comprising the following steps:

i)在一个支撑部上固定布置一些聚合物纤维,并且i) a fixed arrangement of polymer fibers on a support, and

ii)把纤维固定到支撑部上,至少将一些纤维暴露于一个比形成聚合物材料的玻璃转化温度高的温度,并且暴露一段时间,这样:ii) securing the fibers to the support by exposing at least some of the fibers to a temperature higher than the glass transition temperature of the forming polymer material for a period of time such that:

a)所述纤维有至少一个弯曲部分,并且a) said fiber has at least one curved portion, and

b)所述纤维的长度基本上不改变。b) The length of the fibers does not substantially change.

在半结晶材料的情况下,纤维被加热到一个完全比形成它们的材料的熔点低的温度。In the case of semi-crystalline materials, the fibers are heated to a temperature well below the melting point of the material from which they are formed.

所述纤维的加热可以通过对流方式完成,并且尤其是浸入在一个加热液体中,或者通过与热空气接触,或者通过辐射,尤其是红外线辐射来辐射。The heating of the fibers can be accomplished by convection, and in particular by immersion in a heating liquid, or by contact with hot air, or by radiation, especially infrared radiation.

加热优选通过把纤维浸入到加热到大约100摄氏度的热水中。这样的温度证明对聚酰胺6纤维是合适的,它们的玻璃转化温度在50和60摄氏度之间并且它们的熔点大约是185摄氏度。The heating is preferably by immersing the fibers in hot water heated to about 100 degrees Celsius. Such temperatures have proven suitable for polyamide 6 fibers, whose glass transition temperature is between 50 and 60 degrees Celsius and whose melting point is about 185 degrees Celsius.

纤维被浸入在所述的液体中4到25秒中的时间长度并且最好是7到15秒。The fibers are immersed in said liquid for a period of time ranging from 4 to 25 seconds and preferably 7 to 15 seconds.

仅仅是一些提示,即一个扭转的刷包括直径是0.13毫米的聚酰胺6纤维,最大曲率在100摄氏度的热水中放8秒后得到。Just a few hints that a twisted brush comprising polyamide 6 fibers with a diameter of 0.13 mm, the maximum curvature is obtained after 8 seconds in hot water at 100°C.

根据另一个方面,发明目的旨在包装和涂敷一种产品,特别是一种化妆品的组合装置,其中包括According to another aspect, the object of the invention is the packaging and application of a product, in particular a cosmetic assembly comprising

a)一个容器,容纳被涂敷的产品,和a) a container containing the product to be applied, and

b)根据本发明的一个涂敷器装置。b) An applicator device according to the invention.

包装和应用组合装置可包括一个擦拭件,至少在涂敷器从容器中被拔出时可以通过该擦拭件,以使在待计量的纤维上或之间保持一定的量产品。The packaging and application combination may include a wiper which may pass through at least the applicator when it is withdrawn from the container so as to maintain a certain amount of product on or between the fibers to be metered.

附图说明Description of drawings

除了以上细节方面的规定,本发明还包括一些其他的涉及到将在下面对照附图进行描述的,非限制的实施例的规定,其中:In addition to the above detailed provisions, the invention also includes some other provisions related to the non-limiting embodiments described below with reference to the accompanying drawings, in which:

附图1表示一个本发明所述的现有技术的扭转刷型涂敷器。Figure 1 shows a prior art twisted brush applicator according to the present invention.

附图2图示了一个根据本发明第一个实施例的一个涂敷器。Figure 2 illustrates an applicator according to a first embodiment of the invention.

附图3A到3C,图示了图2中的涂敷器装置不同位置的断面。Figures 3A to 3C illustrate cross-sections of the applicator device of Figure 2 in different positions.

附图4A到4F表示了根据本发明可能被用在涂敷器上的纤维的不同位置的横截面。Figures 4A to 4F show cross-sections at different locations of fibers that may be used on an applicator according to the present invention.

附图5图示了根据本发明第二实施例的一个涂敷器。Figure 5 illustrates an applicator according to a second embodiment of the invention.

附图6图示了根据本发明第三实施例的一个涂敷器。Figure 6 illustrates an applicator according to a third embodiment of the present invention.

附图7图示了根据本发明第四实施例的一个涂敷器。Figure 7 illustrates an applicator according to a fourth embodiment of the present invention.

附图8图示了根据发明第五实施例的一个涂敷器。Figure 8 illustrates an applicator according to a fifth embodiment of the invention.

附图9图示了根据发明第六实施例的一个涂敷器。Figure 9 illustrates an applicator according to a sixth embodiment of the invention.

附图10图示了一种包装和应用本发明所述的涂敷器的组合装置。Figure 10 illustrates a combination for packaging and applying the applicator of the present invention.

附图11图示了根据本发明的一个实施例的生产方法的不同阶段。Figure 11 illustrates the different stages of a production method according to an embodiment of the invention.

具体实施方式Detailed ways

附图1显示传统型的刷型的刷50,通常用于对眼睫毛和眉毛的化妆。Figure 1 shows a brush 50 of the conventional type, typically used for eyelash and eyebrow makeup.

刷50包括一个扭转轴芯51,该轴芯51是由一定长度的金属丝弯曲成U型并扭转而成的,在扭转之前,将金属丝的两分支之间插入一层刷毛52。相应于扭转运动,刷毛52形成由一系列之间有较大或较小距离间隔的多匝刷毛构成的螺旋构型。刷毛52从支撑件向外放射状延伸,并且完全是直伸的或至少有一个大的曲率半径(大于60毫米)。The brush 50 includes a twisted core 51 formed by bending a length of wire into a U shape and twisting, before twisting, a layer of bristles 52 is inserted between two branches of the wire. In response to the twisting motion, the bristles 52 form a helical configuration consisting of a series of turns of bristles separated by a greater or lesser distance therebetween. The bristles 52 extend radially outward from the support member and are either completely straight or at least have a large radius of curvature (greater than 60 mm).

扭转轴芯部分51无刷毛的部分被安装入杆53上。杆53的与刷50反方向的末端通常连接到一个构件(未示出),该部分形成一个夹紧刷50的元件和一个把柄和刷联合在一起并封闭起来的元件。The bristle-free portion of the torsion shaft portion 51 is fitted into the rod 53 . The end of the rod 53 facing away from the brush 50 is usually connected to a member (not shown) which forms an element which grips the brush 50 and an element which holds and closes the brush together.

附图2表示了一个和图1中的刷同一类型的但是是根据本发明的刷1。Figure 2 shows a brush 1 of the same type as that in Figure 1 but according to the invention.

在本实施例中,也正象图1中50显示的同样的方式,当将刷1竖直时由侧面看时由于扭转轴芯3的圈是由左至右上升的,所以刷1是“逆时针扭转”型的。In the present embodiment, also just as the same mode that 50 shows among Fig. 1, when the brush 1 is vertically viewed from the side, because the circle of the torsion shaft core 3 rises from left to right, so the brush 1 is " Anti-clockwise twist" type.

与如图1中所示的刷相同的方式,扭转轴芯3的无刷毛部分被装在杆4的末端。刷扭转轴芯3是直的并且沿与杆4的轴线相应的轴线X延伸。In the same manner as the brush shown in FIG. 1 , the bristle-free part of the torsion core 3 is fitted at the end of the rod 4 . The brush torsion axis 3 is straight and extends along an axis X corresponding to the axis of the rod 4 .

该刷的刷毛2,与上图中所示的刷毛52不同,是沿它们的整个长度弯曲的。The bristles 2 of this brush, unlike the bristles 52 shown in the previous figure, are curved along their entire length.

用一个轮廓投影仪放大10倍后测得的刷毛的平均曲率,约为3到10毫米之间。使用的轮廓投影仪是HAUSER公司出售的商号为H562的轮廓投影仪。The average curvature of the bristles measured at 10x magnification with a profile projector is between 3 and 10 mm. The contour projector used is a contour projector sold by the company HAUSER (R) under the trade designation H562.

尽管纤维的弯曲相对于彼此都是自由定向的,但已指出,在优选实施例中,对纤维的热处理使纤维从支撑端到自由端的曲率基本上为定值。Although the bends of the fibers are freely oriented relative to each other, it has been pointed out that, in a preferred embodiment, the heat treatment of the fibers renders the curvature of the fibers substantially constant from the supporting end to the free end.

以下参考附图11进行说明,附图11图示了生产图2中所示类型的刷1的主要步骤。The following description will be made with reference to FIG. 11 , which illustrates the main steps in the production of a brush 1 of the type shown in FIG. 2 .

在第一步200中,刷毛以层的形式被插入到一定长度的金属线的两分支之间,然后金属线的两个分支被扭转。结果是形成一个直径大约15毫米的圆柱形的洗瓶刷201。In a first step 200, the bristles are inserted in layers between two branches of a length of wire, and then the two branches of the wire are twisted. The result is a cylindrical bottle brush 201 with a diameter of approximately 15 mm.

修剪洗瓶刷201(步骤202)使其成截头圆锥体的的外形以符合理想的应用。结果刷203的直径,在它的较宽的一端为大约7到8毫米。刷203的刷毛基本上保持竖直。The bottle brush 201 is trimmed (step 202) to a frusto-conical shape to fit the desired application. The diameter of the resulting brush 203, at its wider end, is about 7 to 8 mm. The bristles of the brush 203 remain substantially vertical.

在下一个步骤204中,刷203被浸入到100摄氏度的水中大约8秒钟。In the next step 204, the brush 203 is immersed in water at 100 degrees Celsius for about 8 seconds.

结果是导致了聚合物材料被成形,该成形引起纤维完全地弯曲,弯曲的平均半径约为3到10毫米之间。The result is that the polymeric material is shaped which causes the fibers to be completely bent with an average radius of between about 3 and 10 mm.

刷1通过上述过程被生产出来,其具有多匝刷毛,由于它的刷毛2的自由定向的曲率混合的结果,该刷的多匝刷毛没有明显的迹象。The brush 1 is produced by the process described above with multiple turns of bristles which show no visible signs as a result of the freely oriented curvature mixing of its bristles 2 .

在一个特殊的实施例中,刷毛的断面是圆形的。它们的直径约是0.13毫米,它们由聚酰胺6制成。In a particular embodiment, the cross-section of the bristles is circular. Their diameter is about 0.13 mm and they are made of polyamide 6.

刷的每一个圈有23到25根刷毛。Each circle of the brush has 23 to 25 bristles.

通过刷1的垂直于轴线X的断面,如在图3A中表示的那样,形状是圆形的。A section through the brush 1 perpendicular to the axis X, as shown in FIG. 3A , is circular in shape.

在图3B中显示了变化的形式,刷1的断面是四方形的。In a variant shown in Figure 3B, the brush 1 is square in cross-section.

另一个变化形式显示于图3C中,刷1的断面部分是三角形的。Another variant is shown in Figure 3C, where the brush 1 is triangular in cross-section.

刷毛2的断面可是各种不同形状的。The cross section of bristle 2 can be various shapes.

在图4A中刷毛2的断面是实心和圆形的。The cross-section of the bristle 2 in Fig. 4A is solid and circular.

在图4B中刷毛2的断面形状是四叶苜蓿形的。The cross-sectional shape of the bristle 2 in FIG. 4B is a four-leaf clover shape.

在图4C中刷毛2的断面形状是三角形的。The cross-sectional shape of the bristle 2 in FIG. 4C is triangular.

在图4D中刷毛2的断面形状是米粒状的。The cross-sectional shape of the bristles 2 in FIG. 4D is rice grain-like.

在图4E中刷毛2是中空的并且断面是环形的。In Fig. 4E the bristles 2 are hollow and circular in cross section.

在图4F中刷毛2的断面形状是C形的。The sectional shape of the bristle 2 in FIG. 4F is C-shaped.

刷1包括仅具有一种断面形状的刷毛2,或者具有不同断面形状的刷毛的混合体。The brush 1 comprises bristles 2 with only one cross-sectional shape, or a mixture of bristles with different cross-sectional shapes.

在图5中所示的变化中,刷1仅仅在扭转轴芯2的一侧并且是同一侧进行了如图11的步骤204中的热处理。In the variant shown in FIG. 5 , the brush 1 is heat treated as in step 204 of FIG. 11 only on one side of the twisted mandrel 2 and on the same side.

结果是刷1,在绕轴芯3延续180度的范围的部分5上,是直的刷毛,在其余的部分6上,有弯曲的刷毛2。部分5和6每个都沿刷1的全部长度延伸。The result is a brush 1 with straight bristles on a portion 5 extending 180° around the core 3 and curved bristles 2 on the remaining portion 6 . Sections 5 and 6 each extend along the full length of brush 1 .

部分5被用来给睫毛涂敷产品。部分6用来分开睫毛。Section 5 is used to apply product to the eyelashes. Part 6 is used to separate the eyelashes.

在显示在图6中的变化中,仅仅在刷1背离杆4的一端的前半部分被图11中的步骤204热处理了。In the variant shown in FIG. 6 , only the front half of the end of the brush 1 facing away from the rod 4 is heat treated in step 204 in FIG. 11 .

结果,在沿刷1基本以一半长度延续的第一轴部分5上,具有直的刷毛2。在另一轴部分6上的刷毛2是弯曲的。As a result, there are straight bristles 2 on the first shaft portion 5 which continues along the brush 1 for substantially half its length. The bristles 2 on the other shaft part 6 are curved.

和在前面描述的实施例中一样,部分5被用来给睫毛涂敷产品。部分6用来分开睫毛。As in the previously described embodiments, section 5 is used to apply product to the eyelashes. Part 6 is used to separate the eyelashes.

显示在图7中的刷1的变化与显示在图2中的刷是不同的,在图7中扭转轴芯3是弯曲的,该曲度基本上相应于沿着眼睑上睫毛位置的浅。The variation of the brush 1 shown in FIG. 7 differs from the brush shown in FIG. 2 in that in FIG. 7 the torsion axis 3 is curved, the curvature substantially corresponding to the shallowness along the upper eyelashes of the eyelid.

图8中显示的变化不同于显示在图2中的刷,在图8中是“顺时针扭转刷”型,当刷1在一个垂直位置侧视时,扭转轴芯3的圈是由右至左上升的。The variation shown in Fig. 8 is different from the brush shown in Fig. 2, in Fig. 8 it is a "clockwise twisted brush" type, when the brush 1 is viewed from the side in a vertical position, the circle of the twisted shaft core 3 is from right to left rising.

再一次得到的化妆类型与用在图2中显示的刷得到的类型是不同的。Again the type of makeup obtained is different from that obtained with the brush shown in FIG. 2 .

在图9中显示的实施例中,涂敷装置81配置成漆刷的形式以给指甲提供光泽面。它包括一簇被夹进到有轴线X的杆83的端部的刷毛82。刷毛82朝向基本上平行于轴X(与轴线X的角度小于45度)In the embodiment shown in Figure 9, the application device 81 is configured in the form of a paintbrush to provide a glossy finish to the nail. It comprises a tuft of bristles 82 clamped into the end of a rod 83 having axis X. The bristles 82 are oriented substantially parallel to the axis X (at an angle of less than 45 degrees to the axis X)

杆83的背离这簇刷毛82末端连接有一个构件84,其形成用来握持漆刷81的元件用来把和刷相连接的容器密封起来的元件。The end of the rod 83 facing away from the tuft of bristles 82 is connected to a member 84 forming an element for holding the paint brush 81 and an element for sealing the container connected to the brush.

漆刷81的刷毛82的曲率可与前面图中描述过的睫毛刷的刷毛的曲率制得的方法一样,仅仅通过把漆刷81浸入在100摄氏度的水中10秒左右就可以了。The curvature of the bristles 82 of the paint brush 81 can be made the same as the curvature of the bristles of the mascara brushes described in previous figures, just by immersing the paint brush 81 in water at 100 degrees Celsius for about 10 seconds.

由于刷毛82的曲率,和刷毛是直的时相比,漆刷可以保持住更多的产品。刷一次后所持续的时间也相应地被延长了。Due to the curvature of the bristles 82, the paint brush can hold more product than if the bristles were straight. The duration of brushing once has also been extended accordingly.

在图10显示了一个装有如图2到8中所示类型的涂敷装置1的包装和应用组件100。组件100包括一个容器101,该容器用于容纳化妆品例如睫毛油;和一个涂敷器110。该涂敷器110包括一个涂敷装置1,该涂敷装置是扭转刷型并被装到一个具有轴线X的杆4的一端,杆4的另一端被固定到一个手柄元件7上,该手柄元件7形成一个帽以密封容器101。容器101包括一个在这种情况下形成于一个圆柱形套筒并终止于一个挠性环形缘107的一端的擦拭件106。在涂敷器110被安装进容器101时,整个涂敷装置1被放置在擦拭件环形缘107和容器的端壁之间。其他类型的擦拭件也可以被使用,例如一块开孔或半开孔泡沫材料,一个狭槽或通道轴向穿过该材料,该狭槽和通道限定缘在无压力状态下大体上彼此接触。In FIG. 10 there is shown a packaging and application assembly 100 incorporating an application device 1 of the type shown in FIGS. 2 to 8 . Assembly 100 includes a container 101 for containing cosmetics such as mascara; and an applicator 110 . The applicator 110 comprises an applicator device 1 which is of the twisted brush type and is fitted to one end of a rod 4 having an axis X, the other end of which is fixed to a handle element 7 which Element 7 forms a cap to seal container 101 . The container 101 comprises a wiper 106 formed in this case in a cylindrical sleeve and terminating at one end of a flexible annular rim 107 . When the applicator 110 is installed in the container 101, the entire applicator device 1 is placed between the wiper ring rim 107 and the end wall of the container. Other types of wipers may also be used, such as a piece of open or semi-open cell foam material through which a slot or channel passes axially, the slot and channel-defining rim being substantially in contact with each other in the unpressurized state.

为了使用涂敷器,使用者旋松由手柄件7形成的帽并从容器101中取出涂敷器110。当这样做后,涂敷装置1通过擦拭件106以调整齿上或刷毛上的产品用量。涂敷器被拔出的方向基本与轴线X垂直。使用后,使用者经再次使涂敷装置1穿过擦拭件106而使涂敷器重新放置回容器中。To use the applicator, the user unscrews the cap formed by the handle member 7 and removes the applicator 110 from the container 101 . When this is done, the applicator 1 passes the wiper 106 to adjust the amount of product applied to the teeth or bristles. The direction in which the applicator is pulled is substantially perpendicular to the axis X. After use, the user repositions the applicator back into the container by passing the applicator device 1 through the wiper 106 again.

在以上详细的描述中,参考了本发明的优选实施例。可清楚地知道在下面的权利要求书的保护范围中可做另外的改变而不超出本发明的范围。In the foregoing detailed description, reference has been made to preferred embodiments of the invention. It is clear that further changes can be made within the scope of protection of the following claims without departing from the scope of the invention.

Claims (42)

1. one kind is used to apply product, cosmetic or the nursing device (1 with product, 81), comprising having at least one free-ended polymer fiber (2,82) arrangement form, described fiber is mounted and is fixed on a support member (3,83) the last and described fiber of at least a portion has at least one sweep, this sweep
I) from the support section to the free end, extend continuously; And
Ii) mean radius of curvature is less than 45 millimeters,
Described sweep is relative to each other free directed.
2. according to the device described in the claim 1, it is characterized in that described sweep has constant curvature from support section to corresponding free end.
3. according to the device (1,81) described in claim 1 or 2, the mean radius of curvature that it is characterized in that described sweep is between 2 millimeters and 40 millimeters.
4. according to the device described in the claim 3 (1,81), the mean radius of curvature that it is characterized in that described sweep is between 2 millimeters and 30 millimeters.
5. device according to claim 4 (1,81), the mean radius of curvature that it is characterized in that described sweep is between 3 meters and 20 millimeters.
6. device according to claim 5 (1,81), the mean radius of curvature that it is characterized in that described sweep is between 3 millimeters and 10 millimeters.
7. according to any one described device (1,81) in the claim 1 to 5, it is characterized in that described fiber is to be made by thermoplastic.
8. device according to claim 7 (1,81) is characterized in that described thermoplastic polymer or thermoplastic elastomer (TPE).
9. according to any one described device (1,81) in the claim 1 to 5, the diameter that it is characterized in that fiber is between 0.06 millimeter and 0.35 millimeter.
10. device according to claim 9 (1,81), the diameter that it is characterized in that fiber is between 0.10 millimeter and 0.25 millimeter.
11., it is characterized in that described device comprises first group of (6) sweep and one second group (5) sweep according to any one described device (1,81) in the claim 1 to 5, the fiber of this second group of sweep or part fiber are straight.
12. according to any one described device (1 in the aforementioned claim 1 to 5,81), it is characterized in that described device comprises first group of sweep with one first mean radius of curvature, with second group of sweep with a second curvature radius different with first curvature radius.
13. device according to claim 11 (1,81), the fiber that it is characterized in that forming first and second sweeps is formed by same material not.
14. device according to claim 13 (1,81) is characterized in that the fiber of forming first and second sweeps made by the different materials with different glass transition temperatures.
15. device according to claim 11 (1,81) is characterized in that the fiber of forming first and second sweeps is formed by commaterial.
16., it is characterized in that fiber (2) is directed transverse to the longitudinal axis X of support member according to any one described device in the claim 1 to 5.
17. device (1 according to claim 16,81), it is characterized in that support member is to be made of the torsional axis core (3) that two strands form, two strands relative to each other reverse, fiber (2) is fixed between two strands of lines that reverse and with respect to torsional axis core (3) and becomes radial extension, and this device is used for being cutin fiber coating application product.
18. device according to claim 17 (1,81) is characterized in that this device is used for being eyelashes and eyebrow coating application product.
19. device according to claim 17 (1,81) is characterized in that described two strands are metal wire.
20. device according to claim 17 (1,81) is characterized in that fiber (2) is arranged to spiral helicine form, the fibre number of every circle is between 5 to 80.
21. device according to claim 20 (1,81), the fibre number that it is characterized in that every circle is between 10 to 45.
22. device according to claim 17 (1,81), the section that it is characterized in that applying device (1) are circle or polygonal.
23. device according to claim 17 (1,81) is characterized in that the section of applying device (1) is a triangle, square or pentagon.
24. device according to claim 17 (1,81) is characterized in that torsional axis core (3) is straight.
25. device according to claim 17 (1,81) is characterized in that torsional axis core (3) is crooked.
26. device according to claim 17 (1,81) is characterized in that torsional axis core (3) is made up of a plurality of circles that rise from left to right when the described device (1) seen from the side in the upright position.
27. device according to claim 17 (1,81) is characterized in that torsional axis core (3) is made up of a plurality of circles that rise from right to left when the described device (1) seen from the side in the upright position.
28. device according to claim 17 (1,81), the sweep that it is characterized in that forming first group mixes with the bend phase-splitting that forms second group on support member.
29. device according to claim 17 (1,81) is characterized in that first and second groups sweep (5,6) is separated.
30. device according to claim 29 (1,81) is characterized in that first and second groups sweep (5,6) can be replaced along the longitudinal axis of support member.
31. device according to claim 29 (1,81) is characterized in that first and second groups sweep (5,6) can be replaced angularly around the axle core that reverses.
32., it is characterized in that fiber (82) is directed along the direction parallel with the longitudinal axis X of support member according to any one described device (1,81) in the claim 1 to 5.
33. a production is used to apply the method for the device (1,81) of product, cosmetic or care product, comprising following steps:
I) with on a plurality of polymer fibers (2,82) fixed and arranged to a support member (8,83), and
After ii) fiber being fixed to support member, at least some fibre (2,82) is exposed to than a period of time in the taller temperature of the glass transition temperature of the polymeric material that forms fiber, like this
A) described fiber (2,82) has at least one sweep, and described sweep has mean radius of curvature less than 45 millimeters, and
B) length of described fiber (2,82) does not change.
34., it is characterized in that realizing by convection type in the heating of described fiber (2,82) according to the method described in the claim 33.
35., it is characterized in that the heating at described fiber (2,82) is by being immersed in a kind of heated liquid, perhaps contacting with hot-air, perhaps realizing by radiation according to the method described in the claim 33.
36., it is characterized in that the heating at described fiber (2,82) is to realize by infrared radiation according to the method described in the claim 33.
37. according to any one described method in the claim 33 to 36, it is characterized in that heating is that mode by fiber is immersed in the hot water realizes that the temperature of this hot water is 100 degrees centigrade.
38., it is characterized in that fiber (2,82) was immersed in the described hot water 4 to 25 seconds according to the described method of claim 37.
39., it is characterized in that fiber (2,82) was immersed in the described hot water 7 to 15 seconds according to the described method of claim 37.
40. pack and apply the composite set (100) of a kind of product or cosmetics, it comprises:
A) hold the container (101) of coated product, and
B) according to any one described applying device (1,81) in the claim 1 to 5.
41. composite set according to claim 29 (100) is characterized in that product is cosmetic and/or the care product that is used for cutin fiber.
42. composite set according to claim 29 (100) is characterized in that cutin fiber is eyelashes or eyebrow.
CN03143835.0A 2002-06-20 2003-06-19 Product applicator particularly cosmetic applicator and method for producing said applicator Expired - Fee Related CN1235530C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR02/07640 2002-06-20
FR0207640A FR2841108B1 (en) 2002-06-20 2002-06-20 PRODUCT APPLICATOR, ESPECIALLY COSMETIC, AND METHOD FOR MANUFACTURING SUCH AN APPLICATOR

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CN1473528A CN1473528A (en) 2004-02-11
CN1235530C true CN1235530C (en) 2006-01-11

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JP (1) JP4296394B2 (en)
CN (1) CN1235530C (en)
AT (1) ATE374543T1 (en)
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DE (1) DE60316626T2 (en)
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FR (1) FR2841108B1 (en)

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Publication number Priority date Publication date Assignee Title
FR2853528B1 (en) * 2003-04-11 2008-08-29 Oreal COSMETIC COMPOSITION COMPRISING AN AMORPHOUS FILMOGENIC POLYMER AND HAVING A PARTICULAR THERMAL PROFILE
US7996947B2 (en) 2005-06-15 2011-08-16 L'oreal Brush and a packaging and applicator device including such a brush
FR2887130B1 (en) * 2005-06-15 2007-08-24 Oreal BRUSH AND DEVICE FOR PACKAGING AND APPLICATION COMPRISING SUCH A BRUSH.
JP2009201818A (en) * 2008-02-28 2009-09-10 Tokyo Parts Kk Liquid applicator
US20090276973A1 (en) * 2008-05-06 2009-11-12 Herve Bouix Cosmetic Applicator Assembly
EP2533665A1 (en) * 2010-02-13 2012-12-19 The Procter & Gamble Company Package for applying a personal care product
US8308383B2 (en) * 2010-03-26 2012-11-13 Elc Management, Llc Heated mascara applicator and suitable compositions
CN102669930A (en) * 2011-03-17 2012-09-19 苏州洽兴塑胶有限公司 Novel lash curler

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DE4022890A1 (en) 1990-07-18 1992-01-23 Geka Brush Georg Karl Gmbh BRUSH, ESPECIALLY MASCARA BRUSH
FR2668905B1 (en) 1990-11-13 1993-02-12 Oreal BRUSH FOR THE APPLICATION OF A COSMETIC PRODUCT IN PARTICULAR TO EYELASHES OR HAIR, AND METHOD FOR OBTAINING SUCH A BRUSH.
FR2687055B1 (en) * 1992-02-11 1994-04-29 Oreal BRUSH FOR APPLYING NAIL VARNISH OR THE LIKE.
FR2717057B1 (en) * 1994-03-14 1996-04-12 Oreal Nail varnish brush and set of nail varnish application provided with such a brush.
DE19615098A1 (en) * 1996-04-17 1997-10-23 Coronet Werke Gmbh Brush for gum massage and tooth cleaning and method for producing the bristles of such a brush

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DE60316626T2 (en) 2008-07-17
DE60316626D1 (en) 2007-11-15
BR0302237A (en) 2004-09-08
JP2004024871A (en) 2004-01-29
CN1473528A (en) 2004-02-11
FR2841108A1 (en) 2003-12-26
ES2294249T3 (en) 2008-04-01
EP1374723A1 (en) 2004-01-02
FR2841108B1 (en) 2004-07-30
JP4296394B2 (en) 2009-07-15
ATE374543T1 (en) 2007-10-15

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