CN1229011C - Protection of plant from cutworms and grub - Google Patents
Protection of plant from cutworms and grub Download PDFInfo
- Publication number
- CN1229011C CN1229011C CN 00132824 CN00132824A CN1229011C CN 1229011 C CN1229011 C CN 1229011C CN 00132824 CN00132824 CN 00132824 CN 00132824 A CN00132824 A CN 00132824A CN 1229011 C CN1229011 C CN 1229011C
- Authority
- CN
- China
- Prior art keywords
- cutworm
- sulphur
- prestige
- melolonthid
- crop
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 241000256259 Noctuidae Species 0.000 title abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 241000238631 Hexapoda Species 0.000 claims abstract description 9
- 239000000575 pesticide Substances 0.000 claims abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 21
- 239000005864 Sulphur Substances 0.000 claims description 21
- 241000289763 Dasygaster padockina Species 0.000 claims description 18
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- 239000011737 fluorine Substances 0.000 claims description 10
- 150000002825 nitriles Chemical class 0.000 claims description 10
- 235000013311 vegetables Nutrition 0.000 claims description 10
- 235000013339 cereals Nutrition 0.000 claims description 9
- 230000009545 invasion Effects 0.000 claims description 9
- 241000218475 Agrotis segetum Species 0.000 claims description 5
- 244000068988 Glycine max Species 0.000 claims description 5
- 235000010469 Glycine max Nutrition 0.000 claims description 5
- 241000254099 Melolontha melolontha Species 0.000 claims description 3
- 235000011293 Brassica napus Nutrition 0.000 claims description 2
- 240000008100 Brassica rapa Species 0.000 claims description 2
- 235000000540 Brassica rapa subsp rapa Nutrition 0.000 claims description 2
- 241001063424 Euxoa tritici Species 0.000 claims description 2
- 241001366032 Melamphaes suborbitalis Species 0.000 claims description 2
- 238000011282 treatment Methods 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 23
- 210000004124 hock Anatomy 0.000 abstract description 2
- 241001586735 Agrotis exclamationis Species 0.000 abstract 1
- 241000130993 Scarabaeus <genus> Species 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 description 10
- 125000001188 haloalkyl group Chemical group 0.000 description 9
- 241001465965 Holotrichia Species 0.000 description 7
- 125000005843 halogen group Chemical group 0.000 description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 6
- 241000218473 Agrotis Species 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 241001585293 Euxoa Species 0.000 description 3
- 241001368048 Agrochola Species 0.000 description 2
- 241000282376 Panthera tigris Species 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000004093 cyano group Chemical group *C#N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000566547 Agrotis ipsilon Species 0.000 description 1
- 241001520019 Holotrichia oblita Species 0.000 description 1
- 241000346653 Holotrichia parallela Species 0.000 description 1
- 206010061217 Infestation Diseases 0.000 description 1
- 241000270322 Lepidosauria Species 0.000 description 1
- 241000254043 Melolonthinae Species 0.000 description 1
- 241001585712 Noctua Species 0.000 description 1
- WTKZEGDFNFYCGP-UHFFFAOYSA-N Pyrazole Chemical class C=1C=NNC=1 WTKZEGDFNFYCGP-UHFFFAOYSA-N 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000484432 Xestia c-nigrum Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 244000038559 crop plants Species 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000001072 heteroaryl group Chemical group 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000013008 thixotropic agent Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pretreatment Of Seeds And Plants (AREA)
Abstract
The present invention provides a method for protecting crops from being attacked or easily attacked by hock gill scarabs which belong to (grubs), or heart and dart moths which belong to insect larvae of (cutworms), or perfect insects. The present invention comprises the following steps that a mixture pesticide of a compound in a formula (I) and tiodicarb is used for processing the seeds or the plumule of the crops, wherein the application amount of the mixture to each kilogram of seeds is 0.2 to 1 grams applied to the compound in the formula (I), and the application amount of the plumule is used to 6 grams; contrarily, the dosage of the compound in the formula (I) for processing the leaves of the plumule is 15 to 60 grams/hectares, and the dosage of the tiodicarb is 200 to 800 grams/hectares; the definition of the compound in the formula (I) is shown in a specification in details.
Description
Technical field
The present invention relates to a kind of protective plant and resist the method for cutworm and grub.
Background technology
People understand insecticide fluorine worm nitrile and the two prestige of sulphur very much.Although these insecticides are generally quite effective, but be difficult to break away from grub (latin name:
Holotrichia spp.Have another name called: chafer) and cutworm (latin name:
Agrotis spp.Have another name called: cut the root noctuid), they attack crop, particularly vegetables, cereal and soybean crops.
Summary of the invention
The purpose of this invention is to provide and be used to the effect that reaches such, in other words, cover crop, i.e. vegetables, cereal and soybean crops are resisted the method for cutworm and grub invasion and attack.
Another object of the present invention is a cover crop, and particularly vegetables, cereal and soybean crops are resisted Latin and be called
AgrotisWith
Holotrichia, the insect infestations that exists especially in China.
A further object of the present invention is a cover crop, particularly vegetables, cereal and soybean crops, the invasion and attack of opposing cutworm and grub, the insect that exists in China especially.
The kind of cutting the root Noctua is included in the pest species that this paper is referred to as cutworm, and it is not of the same race that the definition of tiger side by side also comprises other of this class pest.The kind that hock gill cockchafer belongs to is included in the pest species that this paper is referred to as grub, and it is not of the same race that the definition of grub simultaneously also comprises other of this class pest.
Another object of the present invention is a cover crop; be vegetables and cereal, opposing exists in China especially; be selected from black cutworm (Agrotis ypsilon); white line dart moth of turnip (Agrotis segetum); big cutworm (Agrotistokionis); the black greatly melolonthid (Holotrichiadiomphalta) in dart moth (Agrotis exclamations) and northeast; the black greatly melolonthid (Holotrichia sauteri) in south China; Ao Bulita angle cockchafer (Holotrichia oblita); the dun melolonthid (Holotrichia parallela); the hair yellow ridge head melolonthid (Holotrichia trichophora); the cutworm of the brown melolonthid (Holotrichia titanis) and the invasion and attack of a red-spotted lizard Scarabaeiform.
Another object of the present invention is a cover crop; be vegetables and cereal; resist white edge cutworm (Euxoa oberithuri), Eight characters cutworm (Amathes c-nigrum), the Eight characters ground tiger (Xestiac-nigrum), the insect of taking place in China especially, but also cover the invasion and attack of the insect of other kind.
The method according to this invention can obtain these good effects.
Cover crop is resisted by larva of grub and cutworm and adult invasion and attack or is easy to by the method for its invasion and attack; comprise seed (or seed) or plumule with the described crop of mixture process of formula (I) compound and the two prestige of sulphur; described mixture is the two prestige of sulphur of formula (I) compound and the 1-6 gram/kilogram seed of 0.2-1 gram/kilogram seed for the applied amount of seed, or the applied amount that described mixture is handled for the leaf of plumule is the two prestige of sulphur of formula (I) compound and the 200-800 gram/hectare of 15-60 gram/hectare.For plumule, its implication is the crop plants of also tying without any joint.
Formula (I) compound is a following formula: compound:
Wherein:
R
1Be halogen atom or CN or CS-NH
2Or CO-CH
3,
R
2Be S (O) nR
3Or 4,5-dicyano imidazole-2-base or haloalkyl;
R
3Be alkyl or haloalkyl;
R
4Represent hydrogen atom or halogen atom; Or hydroxyl or NR
5R
6Group, S (O) mR
7, C (O) R
7Or C (O) O-R
7, alkyl, haloalkyl or OR
8Or N=C (R
9) (R
10);
R
5And R
6Represent independently of one another hydrogen atom or alkyl, haloalkyl, C (O) alkyl, alkoxy carbonyl, alkoxyalkyl-C (O)-, S (O) r-CF
3Or R
5And R
6Form by one or two divalent heteroatom the divalent alkyl that separates as oxygen or sulphur together;
R
7Represent alkyl or haloalkyl;
R
8Represent alkyl, haloalkyl or hydrogen atom;
R
9Represent alkyl or hydrogen atom;
R
10Represent phenyl or heteroaryl, they randomly by one or more halogen atoms or OH ,-the O-alkyl ,-S-alkyl, cyano group or alkyl replace;
R
11And R
12Represent hydrogen atom, halogen atom independently of one another, or be CN or NO
2, but preferably H or halogen atom;
R
13Represent halogen atom or haloalkyl, halogenated alkoxy, S (O) qCF
3Or SF
5
M, n, q, r represent 0,1 or 2 integer independently of one another;
X represents trivalent nitrogen atom or C-R
12, three other keys of carbon atom have constituted the part of aromatic ring;
Alkyl in formula (I) definition generally comprises 1-6 carbon atom.R
5And R
6And the nitrogen-atoms that is attached thereto forms 5,6 or 7 yuan ring together.
Preferred formula (I) compound comprises R
1Be CN, and/or R
3Be haloalkyl, and/or R
4Be NH
2, and/or X is CR
12And/or R
11And R
12Be halogen atom independently each other, and/or R
13It is the compound of haloalkyl.
Best formula (I) compound of the present invention is
1-[2,6-Cl
24-CF
3Phenyl] 3-CN 4-[SO-CF
3]
5-NH
2Pyrazoles,
At this called after compd A, it is equivalent to above-mentioned fluorine worm nitrile.
According to method preparation formula (I) compound: WO 87/3781,93/6089,94/21606 or EP 295117,403300,385809,679650 or German patent application 19511269 or United States Patent (USP) 5232940 and 5296938 of following patent application announcement, or any other method that can realize according to the field of chemical synthesis expert prepares.For making product of the present invention become chemical product, the technical staff should possess the ability of consulting in the reference paper that " chemical abstracts " and this paper quotes.Comprise that formula (I) compound can be prepared according to identical prior art or similar prior art with the composition of the two prestige of sulphur.The solid pharmaceutical preparation of the two prestige of formula (I) compound and fluorine worm nitrile or sulphur itself is known.
The two prestige of sulphur are following formula: compounds:
CH
3-S-C(CH
3)＝N-O-C(O)-N(CH
3)-C(O)-O-N＝C(CH
3)-S-CH
3
The weight ratio of the two prestige of formula (I) compound/sulphur advantageously 1/3 to 1/10, preferably 1/6-1/10.
The preparation of the two prestige of the formula of using in the present invention (I) compound and sulphur can be any character, liquid or solid.Itself is known.Mixture can be the concentrate composition of the mixture that has made or the mixture of instant preparation.
Formulations employed advantageously comprises the dispersant of surfactant or wetting agent or material, so that formula (I) compound is being opened up more evenly on the seed or on the cauline leaf.Adhesive or thixotropic agent or thickener also are favourable usually.
Following embodiment is not that it has been set forth the present invention and has demonstrated its enforcement as qualification.
Embodiment
Embodiment 1
Handled in back 10 days being easy to be germinateed by the vegetable crop of the adult of (Agrotis and Holotrichia and Euxoa and Amathes) such as grub and cutworms invasion and attack, this moment, the height of plumule was lower than 10 centimetres.
Mixture with formula (I) compound and the two prestige of sulphur is handled, and the consumption of formula (I) compound is 40 gram/hectares, and the two prestige of sulphur are 250 gram/hectares.
At last, along with vegetable crop grows tall, compare with untreated situation, crop opposing grub of handling and the protective rate of cutworm (adult) reach 90%.
If only handle, observe the improvement of 30-40% protection at least with formula (I) compound or the two prestige of sulphur.
Embodiment 2
Stir 10 kilograms of millets (wheat) seed having to contain in the container of liquid preparation that weight ratio is 1/7.3 fluorine worm nitrile and the two prestige of sulphur.
The seed of dry gained, the content of observing fluorine worm nitrile is 0.3 gram/kg seed, the content of the two prestige of sulphur is 2.2 gram/kg seeds.
Plant these seeds, allow them germinate, plant is correspondingly growing tall.
At last, along with cereal grow tall, compare with untreated situation, the protective rate of (Agrotis and Holotrichia and Euxoa and Amathes) larvas such as crop opposing grub of handling and cutworm reaches 100%.
If only handle, observe the improvement of 30-40% protection at least with formula (I) compound or the two prestige of sulphur.
Claims (7)
1. a protection is belonged to insect larvae or adult invasion and attack by cutworm and grub or is easy to by the method for the crop of its invasion and attack; comprise seed or plumule with the described crop of mixture pesticide treatments of fluorine worm nitrile and the two prestige of sulphur; described mixture is that fluorine worm nitrile applies the 0.2-1 gram for the applied amount of every kilogram of seed; the two prestige of sulphur are the 1-6 gram; perhaps for the leaf of handling plumule; the consumption of fluorine worm nitrile is a 15-60 gram/hectare, and the two prestige of sulphur are 200-800 gram/hectare.
2. according to the described method of aforementioned claim 1, it is characterized in that the insect that protected crop is resisted is present in China.
3. method according to claim 1; it is characterized in that the insect that protected crop is resisted is the black greatly melolonthid in black cutworm, white line dart moth of turnip, big cutworm, dart moth and northeast, the black greatly melolonthid in south China, Ao Buli tower angle cockchafer, the dun melolonthid, the yellow ridge head melolonthid of hair or the brown melolonthid, cutworm, Eight characters cutworm or white edge cutworm.
4. according to aforementioned claim 1 or 3 described methods, it is characterized in that the weight ratio of the two prestige of fluorine worm nitrile/sulphur is 1/3-1/10.
5. according to the described method of aforementioned claim 4, it is characterized in that the weight ratio of the two prestige of fluorine worm nitrile/sulphur is 1/6-1/10.
6. according to aforementioned claim 1 or 3 described methods, it is characterized in that protected crop is vegetables or cereal or soybean.
7. method according to claim 6 is characterized in that, protected crop is vegetables or cereal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00132824 CN1229011C (en) | 2000-11-01 | 2000-11-01 | Protection of plant from cutworms and grub |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00132824 CN1229011C (en) | 2000-11-01 | 2000-11-01 | Protection of plant from cutworms and grub |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1350776A CN1350776A (en) | 2002-05-29 |
| CN1229011C true CN1229011C (en) | 2005-11-30 |
Family
ID=4595418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 00132824 Expired - Fee Related CN1229011C (en) | 2000-11-01 | 2000-11-01 | Protection of plant from cutworms and grub |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1229011C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2067403A1 (en) * | 2007-12-03 | 2009-06-10 | Bayer CropScience AG | Pesticidal compound mixtures comprising ethiprole and specific carbamates |
| CN102972242A (en) * | 2012-12-10 | 2013-03-20 | 甘肃黄羊河集团食品有限公司 | Method for preventing cutworms in film covered crop fields |
-
2000
- 2000-11-01 CN CN 00132824 patent/CN1229011C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1350776A (en) | 2002-05-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20051130 Termination date: 20111101 |