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CN1226366C - Water-resistant corrosion-resistant paint or water-resistant factice produced by using industrial organic waste as raw material - Google Patents

Water-resistant corrosion-resistant paint or water-resistant factice produced by using industrial organic waste as raw material Download PDF

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CN1226366C
CN1226366C CN 03112863 CN03112863A CN1226366C CN 1226366 C CN1226366 C CN 1226366C CN 03112863 CN03112863 CN 03112863 CN 03112863 A CN03112863 A CN 03112863A CN 1226366 C CN1226366 C CN 1226366C
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organic waste
component
mixed solvent
sbs
resin
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CN 03112863
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CN1434089A (en
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刘晓亚
陈明清
奚冬雷
熊万斌
杨成
倪忠斌
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Jiangnan University
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Jiangnan University
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Abstract

以工业有机废料为原料生产的耐水防腐涂料或建筑防水油膏及制备方法，涉及对半固粘胶状有机废料综合利用技术领域。本发明所述两种产品都是以工业有机废料作为主要原料，耐水防腐涂料组分中包含工业有机废料、改性树脂、SBS胶料、混合溶剂、助剂、填料以及固化剂复配而成的一种单组分或双组分的树脂改性仿沥青涂料；建筑防水油膏组分中主要包含工业有机废料、聚氯乙烯树脂和SBS胶料，是以SBS胶料改性的建筑防水油膏。产品耐水、防腐性能强，生产工艺流程简单，达到废物利用、变废为宝、减少污染、保护环境的目的。The invention relates to a water-resistant and anti-corrosion coating or building waterproof ointment produced by using industrial organic waste as a raw material and a preparation method thereof, and relates to the technical field of comprehensive utilization of semi-solid colloidal organic waste. The two products described in the present invention use industrial organic waste as the main raw material, and the components of the water-resistant and anti-corrosion coating include industrial organic waste, modified resin, SBS glue, mixed solvent, auxiliary agent, filler and curing agent. A one-component or two-component resin-modified asphalt-like coating; the building waterproof ointment mainly includes industrial organic waste, polyvinyl chloride resin and SBS glue, and is a building waterproofing material modified with SBS glue ointment. The product has strong water resistance and anti-corrosion performance, and the production process is simple, so as to achieve the purpose of waste utilization, turning waste into treasure, reducing pollution and protecting the environment.

Description

With industrial organic waste materials is water-fast protective system or the buildings waterproof ointment and the preparation method of raw material production
Technical field
With industrial organic waste materials is water-fast protective system or the buildings waterproof ointment and the preparation method of raw material production.The present invention relates to half-and-half consolidate the technical field of viscose glue shape organic waste materials comprehensive treating process.
Background technology
Environmental pollution is China's Economic development, one of problem that social progress faced.Environmental pollution not only destroys the eubiosis, has wasted the resource and the energy, and serious harm mankind itself's healthy and existence, also can hinder further developing of industrial and agricultural production simultaneously.Domestic improvement to waste gas, waste water, urban refuse pollution is at present comparatively paid attention to, but industrial solid castoff is then paid attention to dealing with improperly inadequately, causes secondary pollution, and the harm environment should cause the attention of relevant department to this.
Along with the raising of Economic development and living standards of the people, industrial solid castoff can sharply increase, and China's expectation will reach 9.8 * 10 in 2003 8Ton.Industrial solid castoff is the final state of all contaminations, many pollutant components have concentrated, these pollutant components can discharge again again when condition changes and enter in atmosphere, water body, the soil, thereby its harm has potentiality and chronicity, and its harm to human environment mainly shows appropriation of land, contaminated soil, water body and atmosphere and influences aspects such as environmental health.
Commonly used the having of method of disposal to industrial solid castoff: landfill, burning ashing and sea disposal, but its significant disadvantages and limitation are respectively arranged.
Partly viscose glue shape organic waste materials is maximum in the industrial solid castoff, a modal class admittedly, is partly sticking admittedly jelly as the organic useless tar that produces in the chemical industry.Just produce a large amount of half viscose glue shape organic waste materials admittedly in the vanillin food grade,1000.000000ine mesh production process, be the viscose glue shape under the normal temperature, the pitch shape that is in a liquid state more than 30 ℃, toughness belongs to semisolid waste.Present treatment process is stacking, landfill or open incineration, not only contaminate environment but also waste resource and manpower.
Though be that the epoxide coal bituminous protective system of base-material and polyvinyl chloride buildings waterproof ointment have been promoted in China and used with coal tar, be that the building materials comprehensive utilization of raw material does not appear in the newspapers with industrial organic waste materials.Through consulting lot of documents and trust is looked into newly.Do not see the report that relevant integrated conduct method is arranged both at home and abroad.
Summary of the invention
(1) technical problem that will solve
The invention provides a kind of is water-fast protective system or the buildings waterproof ointment and the preparation method of raw material production with industrial organic waste materials, to reach utilization of waste material, to reduce the purpose of polluting, turning waste into wealth.
(2) technical scheme
With industrial organic waste materials is the water-fast protective system of raw material production, be the imitative bituminous composition of resin modified of a kind of single component or two-pack, comprise industrial organic waste materials, modified resin, SBS sizing material, mixed solvent, filler, auxiliary agent in the component, add or do not add solidifying agent.First component in single component or the two-pack, its component and content (weight %) are:
Industry organic waste materials 20-40%
Modified resin 20-40%
SBS sizing material 1-5%
Mixed solvent 20-40%
Filler 5-25%
Auxiliary agent 1%
The industry organic waste materials can be vanillin food grade,1000.000000ine mesh processing waste or organic useless tar, they mainly are that some are similar to bituminous tarry or thick Chemical Manufacture byproduct or scrap rubber, be but that some contain the lower molecular weight of a small amount of reactive functionality or the organism of higher molecular weight, the existence of active group can make the functional group in organic waste materials and the modified resin react, reach the curing purpose, improve paint film property.
Modified resin can be resin or corresponding plastic waste such as Resins, epoxy, resol, urethane, polystyrene, rosin.Various resins have the various functional groups that can participate in reaction respectively.
The mashed prod that the SBS sizing material is made up of SBS and mixed solvent.SBS is divinyl and cinnamic segmented copolymer, is the divinyl segment in the middle of the long chain molecule, and two ends are vinylbenzene segments, and it ℃ still keeps flexibility at low temperature-73.Cross-linked rubber shape feature is arranged at normal temperatures, and its low-temperature performance is very good, is the toughner under a kind of low temperature, and rebound performance is obviously improved.
SBS sizing material size of content in coating directly influence performances such as the waterproof of paint film, water-fast, anticorrosion, high temperature resistant, sticking power, snappiness, can pass through its consumption of adjustment, and reach some optimum performances.
Mixed solvent is to be mixed by toluene, dimethylbenzene, pimelinketone, isopropylcarbinol, acetates and 200# industrial naptha.
Filler is iron oxide red, Yun Tie, remodeling aluminum phosphate, talcum powder, titanium dioxide, lightweight CaCO 3, the mixture of some materials in antirust filler such as ultra-fine barium sulfate, glass flake and the physique filler.Filler adds fashionable, must be uniformly dispersed.What of amount of filler can be adjusted performances such as film forming water-fast, the anticorrosion and resistance to impact shock of institute.
Second component in the two-pack, it is curing component, its composition adds the mixed solvent dilution by solidifying agent and forms, mixed solvent also is to be mixed by toluene, dimethylbenzene, pimelinketone, isopropylcarbinol, acetates and 200# industrial naptha, and solidifying agent can be the solid oily serial solidifying agent of amine, polymeric amide series solidifying agent, amine curing agent, amine affixture etc.
Above-mentioned is that the preparation method of the water-fast protective system of raw material is formed by industrial organic waste materials, modified resin, SBS sizing material, mixed solvent, filler, additive compound with industrial organic waste materials, if with bicomponent system then prepare second component curing component again and be used.
To industrial organic waste materials, for example vanillin food grade,1000.000000ine mesh organic waste materials or other organic thickness waste material carry out composition analysis earlier, to determine the kind and the consumption of used modified resin.
The organic waste materials pre-treatment: slow heating and melting organic waste materials in reactor, filter and remove impurity and volatile low-molecular-weight organic matter.Pretreated waste chemistry stable in properties, it is at aspect excellent performances such as humidity, water resistance and resistances to chemical attack.
First component preparation (heat refining) in single component or the two-pack:
By proportioning, in mixed solvent, under stirring, heated condition, add pretreated organic waste materials, modified resin, SBS sizing material, make its abundant melting mixing, filtration, cooling, treat to cool off fully the back and add filler and auxiliary agent.Modulation viscosity, and grinding reaches certain fineness.
The preparation of second component (curing component)
It is formulated that curing component of the present invention adds mixed solvent by solidifying agent.Used solidifying agent is looked the difference of used modified resin and can be adjusted, and takes by weighing a certain amount of solidifying agent in a container, adds the mixed solvent that 1-5 doubly measures, and does not stop to stir, and solidifying agent is dissolved in the mixed solvent fully, and being uniformly dispersed gets final product.
With industrial organic waste materials is the polyvinyl chloride buildings waterproof ointment of raw material, comprises industrial organic waste materials in its component, polyvinyl chloride (PVC) RESINS, SBS sizing material, softening agent, stablizer and filler, and its component and content (weight %) are:
Industry organic waste materials 40-60%
Polyvinyl chloride (PVC) RESINS 3-4%
SBS sizing material 0-12%
Softening agent 6%
Stablizer 0.5%
Filler 20-50%
Used industrial organic waste materials, SBS sizing material, filler are with above-mentioned identical.Used polyvinyl chloride (PVC) RESINS, softening agent, stablizer " polyvinyl chloride building joint material People's Republic of China (PRC) specialized standard " together are described identical.
With industrial organic waste materials is that the preparation method of the polyvinyl chloride buildings waterproof ointment of raw material is earlier to industrial organic waste materials pre-treatment: slow heating and melting organic waste materials in reactor, filter and remove impurity and volatile low-molecular-weight organic matter.Sneak into SBS sizing material, polyvinyl chloride (PVC) RESINS, softening agent, stablizer, filler etc. successively by proportioning under heated and stirred again, stir after 0.5-1 hour, packing gets finished product modified polyvinyl chloride buildings waterproof ointment.
(3) beneficial effect
The present invention fully utilizes the viscose glue shape waste material of partly consolidating that produces in vanillin food grade,1000.000000ine mesh and other chemical process, prepares a kind of water-fast protective system or buildings waterproof ointment that is formed by organic waste materials, modified resin, solvent, filler, additive compound.
Organic waste materials is to be the viscosity jelly under maximum in the chemical process, modal, the normal temperature.Adopt the method for stacking, landfill, open incineration to handle at present, both contaminate environment was wasted resource and manpower again.The present invention utilizes organic waste materials to make main raw material and makes a kind of water-fast protective system or buildings waterproof ointment, thereby reaches the cost that reduces product, the purpose of utilization of waste material.Simultaneously the preparation method of this product be that cost is low, technology simple possible, operational path that the water-fast preservative property of product are strong.Can turn waste into wealth, reduce pollution, protection environment.The present invention has significantly comprehensive social benefit and economic benefit.
Embodiment
Embodiment 1
A kind of water-fast protective system is formulated by organic waste materials 20.0%, Resins, epoxy 30.0%, SBS sizing material 2.0%, filler 25%, auxiliary agent 1%, mixed solvent 22.0%.
Embodiment 2
A kind of water-fast protective system is formulated by resol 28%, organic waste materials 26.0%, SBS sizing material 2.0%, filler 15%, mixed solvent 28.0%, auxiliary agent 1%.
Embodiment 3
A kind of water-fast protective system is formulated by urethane resin 30.0%, organic waste materials 25.0%, SBS sizing material 3.0%, filler 12.0%, mixed solvent 29.0%, auxiliary agent 1%.
Embodiment 4
A kind of water-fast protective system is formulated by Resins, epoxy 28.0%, organic waste materials 25.0%, SBS sizing material 2.0%, glass flake 10.0%, fine particle calcium carbonate 5%, auxiliary agent 1%, mixed solvent 29.0%.
Embodiment 5
A kind of modified polyvinyl chloride buildings waterproof ointment is formulated by organic waste materials 40%, polyvinyl chloride (PVC) RESINS 3%, SBS sizing material 12%, softening agent 6%, stablizer 0.5% and filler 38.5%.
Embodiment 6
A kind of modified polyvinyl chloride buildings waterproof ointment, formulated by organic waste materials 50%, polyvinyl chloride (PVC) RESINS 4%, SBS sizing material 10%, softening agent 6%, stablizer 0.5% and filler 29.5%.
Embodiment 7
A kind of modified polyvinyl chloride buildings waterproof ointment, formulated by organic waste materials 60%, polyvinyl chloride (PVC) RESINS 4%, SBS sizing material 8%, softening agent 6%, stablizer 0.5% and filler 21.5%.

Claims (4)

1.一种耐水防腐涂料，其特征是为单组分或双组分的树脂改性仿沥青涂料，组分中包含工业有机废料、改性树脂、SBS胶料、混合溶剂、填料、助剂、加或不加固化剂；1. A water-resistant and anti-corrosion coating is characterized in that it is a single-component or two-component resin-modified imitative asphalt coating, including industrial organic waste, modified resin, SBS sizing material, mixed solvent, filler, auxiliary agent in the component , with or without curing agent; 单组分或双组分中的甲组分，其组分和重量％为：The first component in single-component or two-component, its component and weight % are: 工业有机废料           20-40％Industrial organic waste 20-40% 改性树脂               20-40％Modified resin 20-40% SBS胶料                1-5％SBS rubber compound 1-5% 混合溶剂               20-40％Mixed solvent 20-40% 填料                   5-25％Filler 5-25% 助剂                   1％Auxiliary 1% 工业有机废料是香兰素生产废料或其他来源的有机废焦油；Industrial organic waste is vanillin production waste or organic waste tar from other sources; 改性树脂是环氧树脂、酚醛树脂、聚氨酯、聚苯乙烯、松香树脂或相应的废塑料；The modified resin is epoxy resin, phenolic resin, polyurethane, polystyrene, rosin resin or corresponding waste plastics; 混合溶剂是由甲苯、二甲苯、环己酮、异丁醇、醋酸酯类及200#溶剂汽油混合而成；The mixed solvent is a mixture of toluene, xylene, cyclohexanone, isobutanol, acetate and 200# solvent gasoline; SBS胶料是由SBS和混合溶剂组成的糊状物；SBS glue is a paste composed of SBS and mixed solvent; 填料是铁红、云铁、改型磷酸铝、滑石粉、钛白粉、轻质CaCO3、超细硫酸钡、玻璃鳞片中一些物料的混合物；The filler is a mixture of iron red, cloud iron, modified aluminum phosphate, talcum powder, titanium dioxide, light CaCO 3 , ultrafine barium sulfate, and glass flakes; 乙组分，其组成由固化剂加混合溶剂稀释而成，混合溶剂也是由甲苯、二甲苯、环己酮、异丁醇、醋酸酯类及200#溶剂汽油混合而成，固化剂是胺类固化剂。Component B is formed by diluting curing agent and mixed solvent. The mixed solvent is also mixed with toluene, xylene, cyclohexanone, isobutanol, acetate and 200# solvent gasoline. The curing agent is amine Hardener. 2.根据权利要求1所述的耐水防腐涂料的制备方法，其特征是由工业有机废料、改性树脂、SBS胶料、混合溶剂、填料、助剂复配而成，如采用双组分体系，则再配制乙组分固化组分配合使用；2. The preparation method of the water-resistant and anti-corrosion coating according to claim 1 is characterized in that it is compounded by industrial organic waste, modified resin, SBS sizing material, mixed solvent, filler and auxiliary agent, such as adopting a two-component system , then prepare the curing component of component B for use together; 有机废料预处理：在反应釜内缓慢加热熔融有机废料，过滤，以去除杂质和易挥发低分子量有机物；Organic waste pretreatment: Slowly heat and melt organic waste in the reactor, and filter to remove impurities and volatile low-molecular-weight organics; 单组分或双组分中的甲组分配制：Formulation of Group A in one or two components: 按配比，在混合溶剂中，在搅拌、加热状态下加入预处理过的有机废料、改性树脂、SBS胶料，使其充分熔融混合、过滤、冷却，待完全冷却后加入填料和助剂，调制粘度，并研磨达到一定的细度；According to the proportion, in the mixed solvent, add the pretreated organic waste, modified resin, and SBS rubber under the state of stirring and heating, make it fully melt and mix, filter, cool, and add fillers and additives after complete cooling. Modulate the viscosity and grind to a certain fineness; 双组分中的乙组分的配制：The preparation of B component in two components: 由固化剂加混合溶剂配制而成。It is prepared by curing agent and mixed solvent. 3.一种建筑防水油膏，其特征是组分中包含工业有机废料，聚氯乙烯树脂、SBS胶料、增塑剂、稳定剂和填料，其组分和重量％为：3. A building waterproof ointment is characterized in that the components include industrial organic waste, polyvinyl chloride resin, SBS sizing material, plasticizer, stabilizer and filler, and its components and weight % are: 工业有机废料              40-60％Industrial organic waste 40-60% 聚氯乙烯树脂              3-4％PVC resin 3-4% SBS胶料                   0-12％SBS rubber compound 0-12% 增塑剂                    6％Plasticizer 6% 稳定剂                    0.5％Stabilizer 0.5% 填料                      20-50％Filler 20-50% 工业有机废料是香兰素生产废料或其他来源的有机废焦油；Industrial organic waste is vanillin production waste or organic waste tar from other sources; SBS胶料是由SBS和混合溶剂组成的糊状物；SBS glue is a paste composed of SBS and mixed solvent; 混合溶剂是由甲苯、二甲苯、环己酮、异丁醇、醋酸酯类及200#溶剂汽油混合而成。The mixed solvent is a mixture of toluene, xylene, cyclohexanone, isobutanol, acetate and 200# solvent gasoline. 4.根据权利要求3所述的建筑防水油膏的制备方法，其特征是先对工业有机废料预处理：在反应釜内缓慢加热熔融有机废料，过滤去除杂质和易挥发低分子量有机物，再按配比在加热搅拌下依次混入SBS胶料、聚氯乙烯树脂、增塑剂、稳定剂、填料，搅拌0.5-1小时后，包装，得成品改性聚氯乙烯建筑防水油膏。4. The preparation method of building waterproof ointment according to claim 3 is characterized in that first industrial organic waste is pretreated: slowly heating and melting the organic waste in the reactor, filtering to remove impurities and volatile low-molecular-weight organic matter, and then according to the formula SBS rubber material, polyvinyl chloride resin, plasticizer, stabilizer, and filler are mixed in sequence under heating and stirring, and after stirring for 0.5-1 hour, packaging is performed to obtain a finished modified polyvinyl chloride building waterproof ointment.
CN 03112863 2003-02-19 2003-02-19 Water-resistant corrosion-resistant paint or water-resistant factice produced by using industrial organic waste as raw material Expired - Fee Related CN1226366C (en)

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CN101613533B (en) * 2008-06-28 2011-09-07 西北师范大学 Polymer chemically-modified asphalt composition capable of being stably stored at high temperature and preparation method thereof
CN101735677A (en) * 2008-11-18 2010-06-16 王广武 Anti-corrosive paint filled with hot melting material and preparation method thereof
CN102108234A (en) * 2010-12-22 2011-06-29 白铁林 Colourful environmental-friendly synthesized polymer waterproof paint
CN102120916B (en) * 2011-01-18 2013-07-31 白晓斌 Macromolecular colored road surface anti-skid coating
CN103059586A (en) * 2011-10-24 2013-04-24 洛阳骏腾能源科技有限公司 Preparation method of waterproof cream from biological tar
CN103059577A (en) * 2011-10-24 2013-04-24 洛阳骏腾能源科技有限公司 Preparation method of waterproof cream from biological tar
CN102585659A (en) * 2012-02-20 2012-07-18 丁响亮 Epoxy terrace coating
CN102876173B (en) * 2012-09-26 2014-07-23 苏州汾湖电梯有限公司 Waterproof anticorrosive coating for elevator
CN103602207B (en) * 2013-09-18 2016-08-17 兰州陇嘉化工科技有限公司 A kind of lacquer type organic coating utilizing waste plastic bottle to prepare and preparation method thereof
CN103740253A (en) * 2013-12-25 2014-04-23 苏州市邦成电子科技有限公司 High-adhesive-force metal coating and preparation method thereof

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