[go: up one dir, main page]

CN1219858C - Clean alcohol fuel for vehicle - Google Patents

Clean alcohol fuel for vehicle Download PDF

Info

Publication number
CN1219858C
CN1219858C CN 200410048044 CN200410048044A CN1219858C CN 1219858 C CN1219858 C CN 1219858C CN 200410048044 CN200410048044 CN 200410048044 CN 200410048044 A CN200410048044 A CN 200410048044A CN 1219858 C CN1219858 C CN 1219858C
Authority
CN
China
Prior art keywords
fuel
coal tar
ethanol
clean
combustion improver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 200410048044
Other languages
Chinese (zh)
Other versions
CN1583975A (en
Inventor
范守伟
王建业
张君海
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heilongjiang Zhong Dan Institute Of Biotechnology
Original Assignee
JIANYE FUEL CO Ltd HEILONGJIANG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANYE FUEL CO Ltd HEILONGJIANG filed Critical JIANYE FUEL CO Ltd HEILONGJIANG
Priority to CN 200410048044 priority Critical patent/CN1219858C/en
Publication of CN1583975A publication Critical patent/CN1583975A/en
Application granted granted Critical
Publication of CN1219858C publication Critical patent/CN1219858C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Landscapes

  • Liquid Carbonaceous Fuels (AREA)

Abstract

The present invention relates to clean alcohol fuel for vehicles, which is characterized in that the clean alcohol fuel is formed by mixing alcohol, light hydrocarbon, 1<#> coal tar oil, 6<#> solvent oil, tert-butyl alcohol, a combustion improver, detergent dispersant, an anti-corrosive inhibiting agent and a metal deactivating agent in definite proportion. The fuel can improve the alkane producing value of the gasoline, and effectively reduce the exhaust of harmful substances in tail gas, such as compounds of CO, CH and NOx, etc. The fuel has no corrosion to metal, such as aluminium, cast iron, copper and the like, has the advantages of wide composition source, simple production and low manufacture cost, and is protection type clean fuel with wide market prospects.

Description

A kind of vehicle ethanol clean fuel
Technical field
The present invention relates to liquid fuel, more particularly, be a kind of be the vehicle ethanol fuel of main raw material preparation with ethanol and lighter hydrocarbons.
Background technology
From seventies in 20th century for the second time behind the world oil crisis, the research work of methanol gasoline and ethanol petrol all seeking alternative fuel, is carried out in countries in the world.China is along with economy develops fast, and oil consumption increases sharply with the speed in year 13%, and China's net importation oil had reached 4,000 ten thousand tons in 1999, will break through 100,000,000 tons this year.In recent years, the demand of China's refined oil had the rate of increase of scholarly forecast gasoline in 2005 to reach 4.4%, the gasoline consumption reaches 4,300 ten thousand tons, and the increase of automobile amount, make atmospheric pollution even more serious, the clean fuel surrogate of therefore seeking environment-friendly type has become trend of the times.China once carried out methanol gasoline and automotive research exploitation thereof in " six or five ", the enforcement period of the seventh five-year plan, at present some technology is existing breaks through (as number of patent application: 02104311.6, a kind of production technique of ethanol petrol), but some difficult point is also treated further solution, therefore do not obtain practical application (contemporary petrochemical complex as yet, 2003,11 (6): 6-8).
Summary of the invention
The purpose of this invention is to provide that a kind of dynamic performance is good, cost is low, calorific value is high, pollute the ethanol clean fuel of circlet guarantor type.
Main technical schemes of the present invention: ethanol is joined in the lighter hydrocarbons, be aided with fuel dope again, be mixed with required fuel.
The composition of fuel of the present invention and weight percentage thereof:
Ethanol 15-35%, lighter hydrocarbons 20-40%, 1 #Coal tar 10-20%, 6 #Solvent oil 15-35%, trimethyl carbinol 3-5%, combustion improver 02-1.0%, detergent-dispersant additive 0.03-0.08%, anticorrosion inhibitor 0.05-0.1%, metal passivator 0.01-0.06%.
Described lighter hydrocarbons, its fraction scope is 30-205 ℃, is to analyse oil by separating facing of obtaining in the Sweet natural gas of oil field.
Described 1 #Coal tar, its fraction scope is 30-200 ℃, is provided by Harbin Gas Works.
Described 6 #Solvent oil, its fraction scope is 60-90 ℃, is the production of grand celebration Fine Chemical Works.
The described trimethyl carbinol is a solubility promoter, is that rubber plant of Qilu Petroleum Chemical Corporation Institute produces.
Described combustion improver is to be formed by ether, acetone and hydrogen peroxide allotment, and its volumetric mixture ratio is 1: 1: 1.
Described detergent-dispersant additive, its trade mark are T151, the chemical name mono butonediimide, and Lanzhou general petrochemicals factory produces.
Described anticorrosion inhibitor, its trade mark are BR-7903, and chemical name is a fatty acid ester, and petrochemical complex institute in Beijing's provides.
Described metal passivator, its trade mark are T1201, and chemical name is N, N '-two inferior bigcatkin willow-1, and the 2-propylene diamine, Jinzhou Petrochemical Co. produces.
Fuel compound method of the present invention: at normal temperatures and pressures, earlier with lighter hydrocarbons and 1 #Coal tar joins in the container, and mixing adds ethanol, 6 again #Solvent oil, the trimethyl carbinol, combustion improver, detergent-dispersant additive, anticorrosion inhibitor and metal passivator, mixing promptly gets required fuel.
Advantage of the present invention and effect:
(1) ethanol in the fuel of the present invention is a kind of energy, is again a kind of good gasoline quality improving agent, and it can improve the octane value of gasoline, and peace and quiet engine reduces the objectionable impurities in the vehicle exhaust effectively.Show through engine rig test and row test-results, use this engine fuel need not transform, dynamic performance is constant substantially, and exhaust emissions amount CO and CH compound decreased average are more than 30%, oil consumption slightly reduces, but because of containing oxygen in the ethanol, make the gasoline oxygen level increase by 4%, part that can not perfect combustion in the gasoline fully can be burnt, CO reduces by 33% in the tail gas, thereby make the corresponding minimizing of oil consumption, both offset, and overall oil consumption are maintained an equal level or slightly decline.
(2) fuel of the present invention can use separately, also can join non-lead gasoline for car with any ratio and mix use.
(3) preparation method of the present invention is simple, can prepare in non-pressure vessel, so low cost of manufacture, produces, accumulating is very convenient.
(4) fuel element wide material sources of the present invention, described ethanol can make from agricultural-food such as corn, wheat.China is large agricultural country, and the comprehensive productivity of grain is near 500,000,000 tons, can solve the transition problem of farm crop such as grain so effectively, and helping increases and stable farmers' income.
(5) therefore fuel of the present invention do not have corrosion to metal owing to be added with anticorrosion inhibitor; Most elastomeric materials there is not the swelling phenomenon; Fuel of the present invention in addition even if under-45 ℃ low temperature, demixing phenomenon can not occur in 1 year under air-proof condition.
In sum, fuel production of the present invention is simple, low cost of manufacture, and raw material sources are extensive, and the more important thing is and reduced objectionable impurities in the discharging tail gas, be the wide environment-friendly type clean fuels of a kind of market outlook therefore.
Embodiment
Further specify characteristics of the present invention below by specific examples.
Example 1-3
Example 1-3 is a preparation fuel of the present invention.The composition and the content of fuel see Table 1.
Table 1 (unit: kilogram)
Raw material Example 1 Example 2 Example 3
Ethanol 250 ?350 ?150
Lighter hydrocarbons 400 ?200 ?300
L #Coal tar 100 ?200 ?150
6 #Solvent oil 193.2 ?213.2 ?343.2
The trimethyl carbinol 50 ?30 ?50
Combustion improver 5 ?5 ?5
Mono butonediimide 0.6 ?0.6 ?0.6
Fatty acid ester 0.8 ?0.8 ?0.8
N, N '-two inferior salicylidene-1,2-propylene diamine 0.4 ?0.4 ?0.4
The preparation method:
At normal temperatures and pressures, earlier with lighter hydrocarbons and 1 #Coal tar is added in the jar, adds ethanol, the trimethyl carbinol, combustion improver, mono butonediimide, fatty acid ester and N behind the mixing more successively, N '-two inferior salicylidene-1, and 2-propylene diamine, mixing promptly obtain required product.The performance of product is through the 2 (operative norms: GB17930-1999) that the results are shown in Table of product quality supervision and inspection station, Heilongjiang Province test.
Table 2
Analysis project Quality index Analytical results
Anti-knocking property: research octane number (RON) (RON) is not less than anti-knock index (RON+MON) and is not less than ?90 ?85 ?90.7 ?85
Lead content, g/L is not more than ?0.005 Do not detect
Boiling range: 10% vaporization temperature, be not higher than 50% vaporization temperature, be not higher than 90% vaporization temperature, be not higher than final boiling point, be not higher than residual quantity, % (V/V) is not more than ? ?70 ?120 ?190 ?205 ?2 ? ?51 ?67 ?182 ?188 ?1.0
Vapour pressure, Kpa is not more than ?74 ?48.7
Existent gum, mg/100mL is not more than ?5 ?3
Inductive phase, min is not less than ?480 ?480
Sulphur content, % (m/m) is not more than ?0.10 ?0.022
Copper corrosion (50,3h) level is not more than ?1 ?1
Water soluble acid or alkali Do not have Do not have
The doctor test By By
Mechanical impurity and moisture Do not have Do not have
Benzene content, % (V/V) is not more than ?2.5 ?0.29
Aromaticity content, % (V/V) is not more than ?40 ?5.7
Olefin(e) centent, % (V/V) is not more than ?35 ?19.3
Oxygen level, % (m/m) is not more than ?2.7 ?6.76
Iron level, g/L is not more than ?0.01 Less than 0.0005
Manganese content, g/L is not more than ?0.018 Less than 0.0005
Example 4
This example is the road test of fuel of the present invention.
Test unit: national car mass supervision and inspection center
Test basis:
BT/T12543-1990 " automobile acceleration test method "
G/T12544-1990 " automobile max. speed test method "
GB/T12545.1-2001 " passenger car fuel consumption trial "
Interventions Requested:
On same FV7160Ci type car, use fuel of the present invention and No. 93 gasoline to carry out following comparison test: (1) acceleration characteristics; (2) max. speed; (3) constant-speed driving fuel consumption; (4) exhaust contaminant.The Motor Number ATK145498 of test usefulness, odometer reading 16831.7KM.
Test-results sees Table 3.
Table 3
Sequence number Interventions Requested Assay
Environment-protecting clean fuel of the present invention Gasoline Comparing result (%) The contrast conclusion
1 Dynamic property Accelerate to 100km/h required time (s) from 30km/h 4 grades 22.7 ?20.7 -9.7 Increase by 2 (s)
5 grades 28.8 ?27.1 -6.3 Increase by 1.7 (s)
The continuous gear shift that starts to walk accelerates to 100km/h required time (s) 16.6 ?15.6 -6.4 Increase by 1 (s)
2 Max. speed (km/h) 163.2 ?170.0 -4.0 Reduce by 6.8 (km/h)
3 Constant-speed driving fuel consumption (L/100k m) 4 grades 60 km/h 5.6 ?5.4 -3.7 Increase by 0.2 (L/100km)
90 km/h 7.2 ?7.2 0.0 Equate
120 k/mh 9.0 ?9.3 3.2 Reduce by 0.3 (L/100km)
5 grades 60 km/h 5.1 ?4.8 -6.2 Increase by 0.3 (L/100km)
90 km/h 6.6 ?6.2 -6.5 Increase by 0.4 (L/100km)
120 km/h 8.4 ?8.4 0.0 Equate
4 Exhaust contaminant CO(ppm) 204.08 ?257.05 20.6 Reduce by 5297 (ppm)
HC(ppm) 73.26 ?94.40 22.4 Reduce by 21.14 (ppm)
NO x(ppm) 30.54 ?35.20 13.2 Reduce by 4.66 (ppm)
CO(%) 0.43 ?0.42 -2.4 Increase by 0.01 (%)
Comparative test result is as follows:
(1) fuel ratio of the present invention uses the acceleration characteristics and the max. speed of No. 93 gasoline slightly to descend;
(2) the constant-speed driving fuel consumption of fuel of the present invention and No. 93 gasoline is equal substantially;
(3) discharging pollutants of No. 93 gasoline of fuel ratio of the present invention descends to some extent
Example 5
This example is to detect formaldehyde content in the fuel exhaust gas of the present invention.
Measuring unit: product quality supervision and inspection station, Heilongjiang Province.
Test car: black AB7066 Jetta car
Analytical procedure: spectrophotometric colorimetry
Measurement result: fuel formaldehyde content of the present invention is 0.37 μ g/L, is 70 μ g/L and use the formaldehyde content of the vehicle exhaust of gasoline

Claims (1)

1, a kind of vehicle ethanol clean fuel is characterized in that: composition and weight percentage thereof are:
Ethanol 15-35%, lighter hydrocarbons 20-40%, 1 #Coal tar 10-20%, 6 #Solvent oil 15-35%, trimethyl carbinol 3-5%, combustion improver 0.2-1.0%, mono butonediimide 0.03-0.08%, fatty acid ester 0.05-0.1%, N, N '-two inferior salicylidene-1,2-propylene diamine 0.01-0.06% makes by following process: at normal temperatures and pressures, and earlier with lighter hydrocarbons, 1 #Coal tar and 6 #Solvent oil joins in the reactor, adds ethanol, combustion improver, mono butonediimide, fatty acid ester and N, N '-two inferior salicylidene-1 then successively again, the 2-propylene diamine, the spray circulation stirs and promptly gets desired product, and described lighter hydrocarbons fraction scope is 30-205 ℃, and described 1 #The coal tar distillate scope is 30-200 ℃, described 6 #Solvent oil fraction scope is 60-90 ℃, and described combustion improver is to be formed with 1: 1: 1 mixed preparing of volume ratio by ether, acetone and hydrogen peroxide.
CN 200410048044 2004-06-11 2004-06-11 Clean alcohol fuel for vehicle Expired - Fee Related CN1219858C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410048044 CN1219858C (en) 2004-06-11 2004-06-11 Clean alcohol fuel for vehicle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200410048044 CN1219858C (en) 2004-06-11 2004-06-11 Clean alcohol fuel for vehicle

Publications (2)

Publication Number Publication Date
CN1583975A CN1583975A (en) 2005-02-23
CN1219858C true CN1219858C (en) 2005-09-21

Family

ID=34602060

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200410048044 Expired - Fee Related CN1219858C (en) 2004-06-11 2004-06-11 Clean alcohol fuel for vehicle

Country Status (1)

Country Link
CN (1) CN1219858C (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101231225B (en) * 2007-01-24 2012-04-04 通用汽车环球科技运作公司 System and method for determining ethanol content in fuel
CN101544916B (en) * 2008-03-26 2013-08-14 王建业 Automobile-used methanol and ethanol-based clean fuel additive and preparation method thereof

Also Published As

Publication number Publication date
CN1583975A (en) 2005-02-23

Similar Documents

Publication Publication Date Title
CN1226396C (en) Clean alcohol fuel
CN102660337A (en) Method for preparing novel clean synthetic diesel oil
CN101085938A (en) Biomass synthetic fuel
CN101240200B (en) Methanol Clean Fuel for Vehicles
CN1219858C (en) Clean alcohol fuel for vehicle
UA109561C2 (en) METHOD OF CO-OPERATION OF LOW OCTAN NUMBER AND HIGH-OCTAN GASOLINE
CN101580747B (en) Fuel composition capable of meeting motor vehicle pollutant emission limit
CN1315491A (en) Gasoline additive
CN101144041A (en) Gasoline anti-knock agent mixture for vehicle
CN113355139A (en) Alcohol-based fuel with high combustion value for vehicle
CN1233802C (en) Gasoline power and tail gas discharge improved type additive
CN1580204A (en) Vehicular methanol petrol
CN101525554A (en) Environmentally-friendly alternative fuel composition and method for manufacturing same
CN1526798A (en) Lead-less clean environment protection gasoline additive
CN1508234A (en) Vehicular clean environmental-protection methanol gasoline
CN101985570A (en) Low-carbon gasoline
CN1530428A (en) Motor light naphtholite and mixed fuel
CN1155685C (en) Clean gasoline containing alcohol and its preparing process
AU2021103811A4 (en) Vehicle gasoline produced by replacing methyl tertiary butyl ether
CN101195769B (en) Low-carbon mixed alcohol gasoline
CN1249330A (en) Anti-knock additive of lead-free gasoline
CN102206517A (en) Fuel substituting gasoline for vehicles
CN1258582C (en) Additive of automotive liquefied petroleum gas
CN1317551A (en) Additive compsn. for raising octane number of gasoline and its preparing process
CN1073619C (en) Ether-base gasoline additive

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20190117

Address after: 150000 68 Xingbin Avenue, Bin Xi development area, Bin County, Harbin, Heilongjiang

Patentee after: Heilongjiang Zhong Dan Institute of Biotechnology

Address before: 150040 14th Floor, 54 Heping Road, Harbin, Heilongjiang Province

Patentee before: HEILONGJIANG JIANYE FUEL Co.,Ltd.

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20050921

CF01 Termination of patent right due to non-payment of annual fee