CN1214871C - Light material made from waste slag, mud and waste and old glass - Google Patents
Light material made from waste slag, mud and waste and old glass Download PDFInfo
- Publication number
- CN1214871C CN1214871C CN 01141481 CN01141481A CN1214871C CN 1214871 C CN1214871 C CN 1214871C CN 01141481 CN01141481 CN 01141481 CN 01141481 A CN01141481 A CN 01141481A CN 1214871 C CN1214871 C CN 1214871C
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- CN
- China
- Prior art keywords
- mud
- waste
- light material
- old glass
- waste residue
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000463 material Substances 0.000 title claims abstract description 34
- 239000002699 waste material Substances 0.000 title claims abstract description 28
- 239000011521 glass Substances 0.000 title claims abstract description 18
- 239000011499 joint compound Substances 0.000 title abstract description 6
- 239000002893 slag Substances 0.000 title abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 14
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 239000003381 stabilizer Substances 0.000 claims abstract description 7
- 239000006063 cullet Substances 0.000 claims description 9
- 239000004604 Blowing Agent Substances 0.000 claims description 6
- 230000004907 flux Effects 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 150000003016 phosphoric acids Chemical class 0.000 claims description 4
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- 150000004760 silicates Chemical class 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 6
- 230000000704 physical effect Effects 0.000 abstract description 3
- 238000005057 refrigeration Methods 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000010791 domestic waste Substances 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000002440 industrial waste Substances 0.000 abstract 1
- 238000005245 sintering Methods 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 239000001488 sodium phosphate Substances 0.000 description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 4
- 229910021538 borax Inorganic materials 0.000 description 3
- 238000013467 fragmentation Methods 0.000 description 3
- 238000006062 fragmentation reaction Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 235000010339 sodium tetraborate Nutrition 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- -1 flux Substances 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 238000009700 powder processing Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000005354 aluminosilicate glass Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012802 pre-warming Methods 0.000 description 1
- 239000005297 pyrex Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- Processing Of Solid Wastes (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to a light material made from waste slag, mud and waste and old glass. The light material is characterized in that the light material is made from the waste slag, the mud and the waste and old glass. The material has the components of the following weight percentage: 10 to 30 wt% of old glass and waste slag, 50 to 80 wt% of mud and 5 to 20 wt% of additive. The additives comprise a foaming agent, a fluxing agent and a stabilizer. Since the light material adopts industrial and domestic wastes and mud besides a small amount of additives, the made material has a unique structure, and has the physical properties of low density, high intensity, low heat conduction coefficient and the like. The light material can be widely used in the fields of chemical industry, buildings, communication, electric power, refrigeration, etc.
Description
(1) technical field
The present invention relates to a kind of material, the light material of particularly a kind of waste residue, mud and discarded glass preparation.
(2) background technology
The various waste residues that all trades and professions produced are serious environment pollution not only, and causes the loss and the waste of a large amount of available resources.The final outlet that solves the resource environmental pollution is exactly the regeneration and the utilization of changing rejected material to useful resource.According to incompletely statistics, China has 2,000,000 tons of cullet not to be utilized every year, and the generation of China's cast used sand is very big, approximately with annual 160 tons of speed discharging, factory in some big and medium-sized cities all exists antiquated sand, slag and dumps stacking and not only spent but also problem of environment pollution caused.Utilize discarded object to make the new material of high added value, can protect environment, can economize on resources again.
(3) summary of the invention
The objective of the invention is to propose a kind of new technical scheme of utilizing waste residue, mud and discarded glass etc. to make the light material that can be widely used in chemical industry, building, traffic, electric power and refrigeration field for primary raw material.
Technical scheme of the present invention is to implement like this, and the light material of a kind of waste residue, mud and discarded glass preparation is characterized in that being made by waste residue, mud and discarded glass its material weight percentage:
Cullet: 10～20%
Waste residue, mud: 60～80%
Additive: 10～20% additives are blowing agent, flux, stabilizing agent.
Technical scheme of the present invention can also be implemented like this, and blowing agent is: carbonate, silicates, flux is: phosphoric acid salt, borate family, stabilizing agent is: phosphoric acid salt.
Enforcement by above technical scheme has reached purpose of the present invention substantially.Main cullet, industrial residue and the mud of utilizing of the present invention is made light material for primary raw material, these materials can be cullet, waste residue, additive, or cullet, mud, additive, also can be the multinomial combination of cullet, waste residue, mud, additive etc.Material of the present invention all adopts discarded object as raw material except that additive.Blowing agent is made up of carbonate, silicate in the additive, as sodium carbonate, sodium metasilicate etc.; Flux is made up of phosphate, borate, as sodium phosphate, borax etc.; Stabilizing agent phosphate is formed, as sodium phosphate etc.Such one is the secondary utilization that has realized resource; The 2nd, made material has unique internal structure, has physical propertys such as density is little, intensity is high, thermal conductivity factor is little, makes material have functions such as insulation, heat insulation, sound absorption, fire prevention, protection against the tide.It can extensively be used in fields such as chemical industry, building, traffic, electric power, refrigeration.
Light material with waste residue, mud and discarded glass preparation is a kind of novel environmentally conscious materials.This is a kind of by the heterogeneous light material of forming.The matrix of material is aluminosilicate glass or Pyrex mutually, it is present between wild phase and the gas phase, occurs mutually as the wild phase granular boundary, and formed rack between the wild phase particle, and particle is bondd effectively, thereby give material high mechanical strength.Wild phase is silica or alundum (Al particle, and it is the main component of composite, strengthens the particle contact position and is connected by the rack of matrix phase, and what have is soaked into corrode.Gas phase is countless small bubbles.It is the most distinctive feature in this light material, and majority is present between the enhancing particle, is often surrounded by the matrix phase on every side.Isolatedly between the bubble exist or be interconnected.
This characteristics of light materials is different from simple glass.It has physical propertys such as density is little, intensity is high, thermal conductivity factor is little, makes it give functions such as insulation, heat insulation, sound absorption, protection against the tide, fire prevention.Also have many premium properties of being given by inorganic glass materials simultaneously, the nearly all chemical erosion of ability except that hydrofluoric acid can oxidation, non-efflorescing cementitious rotting, the rat eaten of not damaged by worms has good chemical stability, other article there is not corrosiveness, nontoxic, "dead" injury.Even under high-temperature fusion, can not be decomposed or emit harmful substance yet, can directly make the polychromy goods that never fade, also can not wear out by ultraviolet ray and heat radiation.The premium properties that this composite had will more and more be subject to people's attention.It is to utilize solid waste to carry out resource, and obtains one of effective way of social benefit, economic benefit, environmental benefit.
The invention will be further described below with reference to embodiment.
(4) figure explanation
Accompanying drawing 1 is a process chart
Accompanying drawing 2 is sintering curve figure
(5) specific embodiment
Example one
Cast waste sand: 80%
Cullet: 10%
Additive: 10%
Wherein: sodium carbonate: sodium phosphate: borax=6: 2: 2
900 ± 10 ℃ of sintering temperatures, constant temperature 1 hour.
Waste residue, mud and discarded glass the like waste need carry out preliminary treatment, waste residue through magnetic separation again through fragmentation, grinding, reach the required granularity requirements of technology after selecting powder processing; Mud is through dehydrating, make slag, again through fragmentation, grinding, reach the required granularity requirements of technology after selecting the powder processing; Discarded glass passes through cleaning, fragmentation, selects powder to reach the required granularity requirements of technology.Take by weighing waste residue, sludge silt and discarded glass and blowing agent, flux, foam stabilizer etc. by processing compound, evenly mix the back and form batch, the batch sintering mold of packing into, put into sintering furnace, under suitable sintering atmosphere, be prepared into light material through sintering processes such as low-temperature prewarming, high-temperature fusion, foaming, steady bubble, annealing.The material of being produced can cut into the shape of different size according to different demands.Also can adopt the method for changing sintering mold to obtain.
Example two
Cast waste sand: 30%
Cullet: 20%
Sludge silt: 30%
Additive: 20%
Wherein: sodium carbonate: sodium phosphate: borax: waterglass (sodium metasilicate)=6: 2: 2: 10
Manufacture craft such as embodiment 1.
Claims (2)
1, the light material of a kind of waste residue, mud and discarded glass preparation is characterized in that being made by waste residue, mud and discarded glass its material weight percentage:
Cullet: 10～20%
Waste residue, mud: 60～80%
Additive: 10～20% additives are blowing agent, flux and stabilizing agent.
2, the light material of waste residue as claimed in claim 1, mud and discarded glass preparation, it is characterized in that blowing agent is: carbonate, silicates, flux is: phosphoric acid salt, borate family, stabilizing agent is: phosphoric acid salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01141481 CN1214871C (en) | 2001-06-19 | 2001-09-27 | Light material made from waste slag, mud and waste and old glass |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN01129256.3 | 2001-06-19 | ||
| CN01129256 | 2001-06-19 | ||
| CN 01141481 CN1214871C (en) | 2001-06-19 | 2001-09-27 | Light material made from waste slag, mud and waste and old glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1385254A CN1385254A (en) | 2002-12-18 |
| CN1214871C true CN1214871C (en) | 2005-08-17 |
Family
ID=25740512
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01141481 Expired - Fee Related CN1214871C (en) | 2001-06-19 | 2001-09-27 | Light material made from waste slag, mud and waste and old glass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1214871C (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7780781B2 (en) | 2005-01-14 | 2010-08-24 | Alkemy, Ltd. | Pyroprocessed aggregates comprising IBA and low calcium silicoaluminous materials and methods for producing such aggregates |
| US7655088B2 (en) | 2005-01-14 | 2010-02-02 | Alkemy, Ltd. | Synthetic aggregates comprising sewage sludge and other waste materials and methods for producing such aggregates |
| GR1006855B (en) * | 2005-01-14 | 2010-07-06 | Σοφια Μπεθανη | Construction materials using aggregates from solid wastes |
| CN102219419B (en) * | 2011-04-13 | 2013-01-16 | 云南华威废弃物资源化有限公司 | Method for preparing high-strength lightweight aggregate by use of building waste residue, casting waste sand and sludge |
| CN103172383A (en) * | 2011-12-22 | 2013-06-26 | 沈阳临德陶瓷研发有限公司 | Method for producing light-weight inorganic plates by using industrial waste slag |
| CN103387339A (en) * | 2012-05-08 | 2013-11-13 | 厦门中致胜节能科技有限公司 | Regenerated lightweight silicon spar and preparation method thereof |
| TWI465300B (en) * | 2012-12-12 | 2014-12-21 | Stone & Resource Ind R & D Ct | Method for manufacturing lightweight bulk materials |
| CN103319264B (en) * | 2013-07-05 | 2015-05-20 | 江苏晶瑞特环保新材料有限公司 | Glass pumice capable of slowly releasing fertilizer and preparation method thereof |
| CN105731794A (en) * | 2016-03-15 | 2016-07-06 | 季华 | Environment-friendly glass made of waste glass |
| CN107138504A (en) * | 2017-05-18 | 2017-09-08 | 聂超 | A kind of porous environmental friendly material |
| CN109796186A (en) * | 2019-03-25 | 2019-05-24 | 涂玉波 | A kind of artificial lightweight material and the preparation method and application thereof |
-
2001
- 2001-09-27 CN CN 01141481 patent/CN1214871C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1385254A (en) | 2002-12-18 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20050817 Termination date: 20160927 |