CN1213201C - Process for producing black core card paper - Google Patents
Process for producing black core card paper Download PDFInfo
- Publication number
- CN1213201C CN1213201C CN 02136407 CN02136407A CN1213201C CN 1213201 C CN1213201 C CN 1213201C CN 02136407 CN02136407 CN 02136407 CN 02136407 A CN02136407 A CN 02136407A CN 1213201 C CN1213201 C CN 1213201C
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- China
- Prior art keywords
- stirring
- low speed
- add
- minute
- black core
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title abstract description 9
- 230000008569 process Effects 0.000 title description 5
- 239000000123 paper Substances 0.000 claims abstract description 52
- 238000004519 manufacturing process Methods 0.000 claims abstract description 18
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 17
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 17
- 229920000570 polyether Polymers 0.000 claims abstract description 16
- 229920002472 Starch Polymers 0.000 claims abstract description 14
- 235000019698 starch Nutrition 0.000 claims abstract description 14
- 239000008107 starch Substances 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 238000000576 coating method Methods 0.000 claims abstract description 9
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 61
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 30
- 239000007788 liquid Substances 0.000 claims description 24
- 239000002002 slurry Substances 0.000 claims description 16
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000002585 base Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 5
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- 239000005871 repellent Substances 0.000 claims description 5
- 230000002940 repellent Effects 0.000 claims description 5
- 238000003892 spreading Methods 0.000 claims description 5
- 230000007480 spreading Effects 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 239000002518 antifoaming agent Substances 0.000 claims description 3
- 239000000084 colloidal system Substances 0.000 claims description 3
- 239000002270 dispersing agent Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000004816 latex Substances 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 7
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000011087 paperboard Substances 0.000 abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229940068984 polyvinyl alcohol Drugs 0.000 description 11
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 11
- 238000001035 drying Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 241000276498 Pollachius virens Species 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Paper (AREA)
Abstract
The present invention relates to a manufacturing technique for black core paperboards. The manufacturing technique comprises the following steps: black core pulp is prepared; copper plate base paper is selected as coating base paper; the black core pulp is coated on the base paper by an air blade and dried to manufacture black core coating paper; two pieces of black core coating paper are compounded in such a way that with the corresponding black surfaces are opposite to each other to manufacture black core paper, then, one layer of black core paper is clamped between two layers of surface paper and compounded through mechanical mount, and the air blade is flailed to manufacture the black core paperboards after the mechanical mount, wherein the preparation of the black core pulp comprises the following steps: mixed white material is manufactured; polyvinyl alcohol, phosphonolipid starch and polyether are prepared; and the black core pulp is manufactured. The black core paperboards have the advantage of low production cost, and can prevent the perspectivity of positive patterns and back patterns of playing cards after being manufactured into the playing cards; and the playing cards of the black core paperboards have the advantages of slipperiness, good hand feeling and strong elasticity.
Description
One, technical field
The present invention relates to a kind of manufacture craft of black core card paper, in particular for making the black core card paper of playing card.
Two, background technology
To the paper of using of high-grade playing card, adopt inner core basically on the present world and the domestic market, adopt the playing card of this paper production, mainly can prevent the perspective of the positive back side of playing card card pattern for black paper adds the coated paper of two coating whites outward.But it is domestic to also not having at present oneself to produce the manufacturer of black core card paper, use as need, it all is external import, and the flow process more complicated of producing black core card paper abroad, cost is relatively also higher, so, adopt the import black core card paper, the cost of playing card is obviously increased, and for consumers, cost is also just increased relatively.
Three, summary of the invention
It is low that the technical problem to be solved in the present invention provides a kind of cost of investment, and the manufacture craft of the simple a kind of black core card paper of production procedure is to solve the shortcoming of domestic this technological gap.For this reason, the present invention takes following technical scheme:
A kind of manufacture craft of black core card paper may further comprise the steps:
(1) the black core slurry of preparation;
Make (by mass percentage following) 1.1 mix white material:
DC dispersant 0.21%, calgon 0.13%, sheet alkali 0.09%, antifoaming agent 0.21%, kaolin 64.47%, CMC-50:0.52%, all the other are water, are invested in the high speed dispersion cylinder, stir 3-4 hour, and then pass through the round glue mill of high speed colloid 10 times, store standby;
1.2 latex boils:
A, polyvinyl alcohol reserve liquid:
In 50-60 ℃ water, preparation 8% (g/g) polyvinyl alcohol water solution stirs while heating, and temperature to 100 ℃ is dissolved fully to polyvinyl alcohol, is incubated standby (temperature is controlled between 90 ℃-100 ℃);
B, phosphoric acid fat starch reserve liquid:
Under the normal temperature, the phosphoric acid fat amidin of preparation 10% (g/g) stirs while heating, and temperature to 100 ℃ treats that phosphoric acid fat starch dissolves fully, and is standby under the normal temperature;
C, polyethers reserve liquid:
Under the normal temperature, the polyether aqueous solution of preparation 10% (g/g) stirs while heating, and temperature rises to 100 ℃, treats that polyethers dissolves fully, and is standby under the normal temperature;
1.3 raw material quantity (mass percent) and order are made and thrown in to black core slurry:
Under the normal temperature, will mix white material: 52.3%-53.7%, and be invested in and join stirring at low speed in the slurry cylinder;
Add polyvinyl alcohol reserve liquid: 24.2%-25%, stirring at low speed 15-20 minute again;
Add phosphoric acid fat starch reserve liquid: 7.4%-7.66%, stirring at low speed 15-20 minute again;
Add polyethers reserve liquid: 4.93%-5.09%, stirring at low speed 15-20 minute again;
Add butadiene-styrene rubber: 1.79%-1.85%, stirring at low speed 5-10 minute again;
Add acrylic acid: 2.24%-2.32%, stirring at low speed 5-10 minute again;
Add lubricant: 0.67%-0.69%, stirring at low speed 5-10 minute again;
Add water repellent agent: 0.118%-0.122%, stirring at low speed 3-5 minute again;
Add ammoniacal liquor: 0.118%-0.122%, stirring at low speed 3-5 minute again;
Add stamp pasting mill base (black): 4.76%-4.92%, stirring at low speed 30-40 minute again;
(2) select art base paper as bodystock paper;
(3) black core slurry adopts the airblade coating method to be coated on the body paper, and black core spreading paper is made in oven dry;
(4) black core spreading paper black flour is compound to black flour, makes black core paper, mounts compoundly again through machine with the black core paper of two aspect paper therebetween one decks, and machine is the back press polish again, and flail knife is made black core card paper; Raw material quantity (mass percent) and in proper order as follows is made and thrown in to further described black core slurry:
Under the normal temperature, will mix white material: 53.00%, be invested in and join stirring at low speed in the slurry cylinder;
Add the polyvinyl alcohol reserve liquid again: 24.60%, stirring at low speed 15-20 minute;
Add phosphoric acid fat starch reserve liquid again: 7.53%, stirring at low speed 15-20 minute;
Add the polyethers reserve liquid again: 5.01%, stirring at low speed 15-20 minute;
Add butadiene-styrene rubber again: 1.82%, stirring at low speed 5-10 minute;
Add acrylic acid again: 2.28%, stirring at low speed 5-10 minute;
Add lubricant again: 0.68%, stirring at low speed 5-10 minute;
Add water repellent agent again: 0.12%, stirring at low speed 3-5 minute;
Add ammoniacal liquor again: 0.12%, stirring at low speed 3-5 minute;
Add stamp pasting mill base (black) again: 4.84%, stirring at low speed 30-40 minute;
The manufacture craft of a kind of black core card paper of the present invention has following advantage:
1, fill up the technological gap in domestic this field, external relatively like products, manufacture craft is simple; 2, the black core card paper that adopts above technology to produce, external relatively imported material, cost is low; 3, after the black core card paper of the above explained hereafter of employing is made into playing card, can prevent the perspective of the positive back side of playing card card pattern; 4, this black core card paper is through the refining playing card that form of special process technology, and its card is more smooth, and feel is better, and elasticity is stronger; 5, this black core card paper also has the inferior light characteristics that integrate with international standard, has reached vision protection, purpose good for health.
Four, specific implementation method
Embodiment 1
Manufacture craft of the present invention comprises following flow process:
(1) mixing white material makes: DC dispersant 0.21%, calgon 0.13%, sheet alkali 0.09%, antifoaming agent 0.21%, kaolin 64.47%, CMC-50:0.52%, all the other are water, be invested in the high speed dispersion cylinder, stirred 3-4 hour, and then process high speed colloid comes and goes glue mill 10 times, store standbyly, it is as follows that this mixes white material mass parameter, solid content: 42%; Viscosity: 110MPS; PH value: 6.3.
(2) latex boils:
A, polyvinyl alcohol reserve liquid:
Earlier in reaction pot, add entry, be heated to water temperature when reaching 60 ℃, throw in polyvinyl alcohol, making polyvinyl alcohol content is 8% (g/g), stirs temperature to 100 ℃ on the reaction pot inner edge limit of heating, dissolve fully to polyvinyl alcohol, be incubated standby (temperature is controlled between 90-100 ℃);
B, phosphoric acid fat starch reserve liquid:
Add earlier entry in reaction pot, throw in phosphoric acid fat starch, making phosphoric acid fat content of starch is 10% (g/g), stirs on the reaction pot inner edge limit of heating, and temperature to 100 ℃ is dissolved fully to phosphoric acid fat starch, and is standby under the normal temperature;
C, polyethers reserve liquid:
Add earlier entry in reaction pot, throw in polyethers, making content of polyether is 10% (g/g), stirs on the reaction pot inner edge limit of heating, and temperature to 100 ℃ is dissolved fully to polyethers, and is standby under the normal temperature;
(3) raw material quantity (mass percent) and order are made and thrown in to black core slurry:
Under the normal temperature, will mix white material: 53%, be invested in and join stirring at low speed in the slurry cylinder;
Add the polyvinyl alcohol reserve liquid again: 24.6%, stirring at low speed 15-20 minute;
Add phosphoric acid fat starch reserve liquid again: 7.53%, stirring at low speed 15-20 minute;
Add the polyethers reserve liquid again: 5.01%, stirring at low speed 15-20 minute;
Add butadiene-styrene rubber again: 1.82%, stirring at low speed 5-10 minute;
Add acrylic acid again: 2.28%, stirring at low speed 5-10 minute;
Add lubricant again: 0.68%, stirring at low speed 5-10 minute;
Add water repellent agent again: 0.12%, stirring at low speed 3-5 minute;
Add ammoniacal liquor again: 0.12%, stirring at low speed 3-5 minute;
Add stamp pasting mill base (black) again: 4.84%, stirring at low speed 30-40 minute;
This stock quality parameter is as follows, solid content: 33%; Viscosity: 3000MPS; PH value: 8.5.
(4) black core card paper is made:
The above black core slurry for preparing is carried out airblade coating, and the equipment of employing is: Kohler coater, rewinding machine etc.Bodystock paper is an art base paper, and Substance, specification can be regulated arbitrarily by required specification; During airblade coating, last powder amount is 15-28g/m
2, arrive collection through dispense tip, drying tunnel, rubber rollers, drying cylinder; Whole Kohler coater height is 15 meters, is 5 meters by drying tunnel length, and drying tunnel temperature is controlled between 120 ℃-140 ℃, make paper dry substantially to moisture be 5-8%, speed of a motor vehicle per minute is controlled between the 20-24 rice; Black core spreading paper employing machine after the coating is mounted equipment such as compounding machine and stock mixing system rewinding machine, it is compound for deceiving core paper to black flour to mount black flour by machine, rewinding is cut again, mounting the black core paper of compound employing two aspect paper therebetween one decks by machine again, to mount compounding machine through machine compound, and compound after press polish, flail knife are made the black core card paper of required specification.
Embodiment 2-6
Raw material quantity (mass percent) and order are made and thrown in to black core slurry in the manufacture craft of the present invention, the temperature such as the following table of preparation poly-vinyl alcohol solution:
Other technological operation steps such as embodiment 1.
Claims (2)
1, a kind of manufacture craft of black core card paper may further comprise the steps:
(1) the black core slurry of preparation;
Make 1.1 mix white material, below by mass percentage:
DC dispersant 0.21%, calgon 0.13%, sheet alkali 0.09%, antifoaming agent 0.21%, kaolin 64.47%, CMC-50:0.52%, all the other are water, are invested in the high speed dispersion cylinder, stir 3-4 hour, and then pass through the round glue mill of high speed colloid 10 times, store standby;
1.2 latex boils:
A, polyvinyl alcohol reserve liquid:
In 50-60 ℃ water, the preparation mass percent is 8% polyvinyl alcohol, stirs while heating, and temperature to 100 ℃ is dissolved fully to polyvinyl alcohol, is incubated standbyly, and temperature is controlled between 90 ℃-100 ℃;
B, phosphoric acid fat starch reserve liquid:
Under the normal temperature, the preparation mass percent is 10% phosphoric acid fat amidin, stirs while heating, and temperature to 100 ℃ treats that phosphoric acid fat starch dissolves fully, and is standby under the normal temperature;
C, polyethers reserve liquid:
Under the normal temperature, the preparation mass percent is 10% polyether aqueous solution, stirs while heating, and temperature rises to 100 ℃, treats that polyethers dissolves fully, and is standby under the normal temperature;
1.3 raw material quantity and order are made and thrown in by mass percentage to black core slurry:
Under the normal temperature, will mix white material: 52.3%-53.7%, and be invested in and join stirring at low speed in the slurry cylinder;
Add polyvinyl alcohol reserve liquid: 24.2%-25%, stirring at low speed 15-20 minute again;
Add phosphoric acid fat starch reserve liquid: 7.4%-7.66%, stirring at low speed 15-20 minute again;
Add polyethers reserve liquid: 4.93%5.09%, stirring at low speed 15-20 minute again;
Add butadiene-styrene rubber: 1.79%-1.85%, stirring at low speed 5-10 minute again;
Add acrylic acid: 2.24%-2.32%, stirring at low speed 5-10 minute again;
Add lubricant: 0.67%-0.69%, stirring at low speed 5-10 minute again;
Add water repellent agent: 0.118%-0.122%, stirring at low speed 3-5 minute again;
Add ammoniacal liquor: 0.118%-0.122%, stirring at low speed 3-5 minute again;
Add black printed pasting mill base: 4.76%-4.92%, stirring at low speed 30-40 minute again;
(2) select art base paper as bodystock paper;
(3) black core slurry adopts the airblade coating method to be coated on the body paper, and black core spreading paper is made in oven dry;
(4) black core spreading paper black flour is compound to black flour, makes black core paper, mounts compoundly again through machine with the black core paper of two aspect paper therebetween one decks, and machine is the back press polish again, and flail knife is made black core card paper.
2, the manufacture craft of a kind of black core card paper as claimed in claim 1 is characterized in that: raw material quantity made and throw in by mass percentage by described black core slurry and order is as follows:
Under the normal temperature, will mix white material: 53.00%, be invested in and join stirring at low speed in the slurry cylinder;
Add the polyvinyl alcohol reserve liquid again: 24.60%, stirring at low speed 15-20 minute;
Add phosphoric acid fat starch reserve liquid again: 7.53%, stirring at low speed 15-20 minute;
Add the polyethers reserve liquid again: 5.01%, stirring at low speed 15-20 minute;
Add butadiene-styrene rubber again: 1.82%, stirring at low speed 5-10 minute;
Add acrylic acid again: 2.28%, stirring at low speed 5-10 minute;
Add lubricant again: 0.68%, stirring at low speed 5-10 minute;
Add water repellent agent again: 0.12%, stirring at low speed 3-5 minute;
Add ammoniacal liquor again: 0.12%, stirring at low speed 3-5 minute;
Add black printed pasting mill base again: 4.84%, stirring at low speed 30-40 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02136407 CN1213201C (en) | 2002-08-05 | 2002-08-05 | Process for producing black core card paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02136407 CN1213201C (en) | 2002-08-05 | 2002-08-05 | Process for producing black core card paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1473991A CN1473991A (en) | 2004-02-11 |
| CN1213201C true CN1213201C (en) | 2005-08-03 |
Family
ID=34146454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02136407 Expired - Fee Related CN1213201C (en) | 2002-08-05 | 2002-08-05 | Process for producing black core card paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1213201C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1312355C (en) * | 2004-08-11 | 2007-04-25 | 山东太阳纸业股份有限公司 | Black paperboard and production method thereof |
| CN105755891B (en) * | 2016-02-17 | 2018-04-10 | 金东纸业（江苏）股份有限公司 | A kind of folding stock and preparation method thereof |
| JP6831821B2 (en) | 2017-10-02 | 2021-02-17 | エンゼルプレイングカード株式会社 | Playing cards |
-
2002
- 2002-08-05 CN CN 02136407 patent/CN1213201C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1473991A (en) | 2004-02-11 |
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Granted publication date: 20050803 Termination date: 20100805 |