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CN1200464C - Encapsulation method of electroluminescence element - Google Patents

Encapsulation method of electroluminescence element Download PDF

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Publication number
CN1200464C
CN1200464C CNB01124254XA CN01124254A CN1200464C CN 1200464 C CN1200464 C CN 1200464C CN B01124254X A CNB01124254X A CN B01124254XA CN 01124254 A CN01124254 A CN 01124254A CN 1200464 C CN1200464 C CN 1200464C
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packaging
glass substrate
package
glue
sealant
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CN1405901A (en
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白瑞芬
陈永成
周宜衡
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Hanli Photoelectric Co ltd
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Hanli Photoelectric Co ltd
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Abstract

The invention relates to a packaging method of an electroluminescent element, which comprises the steps of providing a glass substrate with the electroluminescent element and a corresponding glass cover plate under the water and oxygen control environment, coating frame glue on the cover plate corresponding to the frame position of each light-emitting element of the substrate, and reserving an opening at one side without a circuit at the periphery of the light-emitting element; secondly, pressing the cover plate and the substrate and curing the frame glue; cutting and separating the light-emitting elements to form individual packages; then, placing the packaging piece into the vacuum cavity for air suction, and immersing the packaging piece into a glue groove at the bottom of the vacuum cavity when the pressure in the vacuum cavity reaches a set value, so that the opening of the packaging piece is in contact with a packaging material; and then raising the pressure of the vacuum cavity, filling the cavity with the packaging material due to the difference between the internal pressure and the external pressure of the packaging part, and curing the packaging material in the cavity to finish the packaging of the light-emitting element.

Description

电致发光元件的封装方法Encapsulation method of electroluminescence element

技术领域technical field

本发明是有关于一种电致发光(Electro-Luminescent,EL)元件的封装方法,且特别是有关于一种有机电致发光(Organic Electro-Luminescent,OEL)元件的封装方法。The present invention relates to a packaging method for electro-luminescent (Electro-Luminescent, EL) components, and in particular to a packaging method for organic electro-luminescent (Organic Electro-Luminescent, OEL) components.

背景技术Background technique

有机电致发光的研发始于1960年代,有机电致发光元件是采用有机化合物作为发光层材料,将其夹在上金属电极和下透明阳极之间。依有机材料的种类可分为小分子发光二极管(Organic Light-Emitting Diode,OLED)及高分子发光二极管(Polymer Light-Emitting Diode,PLED)。1980年代初期,美国柯达公司利用三-(8-羟基奎林)铝(Tri-(8-Hydroxyquinoline)Aluminum,Alq3)做为有机发光层,并在发光层与阳极之间插入空穴注入层(Hole Injecting Layer),以提高再结合效率,确立了有机发光元件的实用性。1990年英国剑桥大学利用聚对位苯基乙烯(Poly(p-Phenylene Vinylene),PPV)高分子共轭聚合物(Conjugated Polymer)制造高分子有机发光二极管,由于聚对位苯基乙烯(PPV)材料具有类似半导体的特性及高分子发光二极管(PLED)工艺简单,因此引发了第二波的有机发光二极管研究热潮。有机电致发光具有自发光、广视角(达160度)、高应答速度、低驱动电压、全色彩等特点,目前已可实用化,可应用于彩色平面显示元件,例如小型显示面板、户外显示看板、计算机及电视屏幕等。The research and development of organic electroluminescence began in the 1960s. Organic electroluminescence elements use organic compounds as materials for the light-emitting layer, which are sandwiched between the upper metal electrode and the lower transparent anode. According to the types of organic materials, they can be divided into small molecule light-emitting diodes (Organic Light-Emitting Diode, OLED) and polymer light-emitting diodes (Polymer Light-Emitting Diode, PLED). In the early 1980s, Kodak Corporation of the United States used Tri-(8-Hydroxyquinoline) Aluminum (Alq 3 ) as the organic light-emitting layer, and inserted a hole injection layer between the light-emitting layer and the anode. (Hole Injecting Layer) to improve recombination efficiency and establish the practicality of organic light-emitting devices. In 1990, the University of Cambridge used Poly (p-Phenylene Vinylene), PPV (Conjugated Polymer) to manufacture polymer organic light-emitting diodes. The materials have semiconductor-like characteristics and the process of polymer light-emitting diodes (PLEDs) is simple, thus triggering the second wave of research on organic light-emitting diodes. Organic electroluminescence has the characteristics of self-illumination, wide viewing angle (up to 160 degrees), high response speed, low driving voltage, and full color. Kanban, computer and TV screens, etc.

有机电致发光二极管的技术发展,按所使用的有机材料,可大概区分为小分子及高分子发光二极管两大类,其元件的工作效率及寿命,除了取决于有机材料特性、工艺参数及工艺环境控制外,良好的封装更是保持元件性能的重要关键。就技术观点而言,目前在材料合成、工艺研发上均已达商业化的水准;然而由于目前并无快速且有效的封装技术,因此使得有机电致发光二极管仅能达到实验或试产的规模,所以无法大量生产。The technical development of organic light-emitting diodes can be roughly divided into two categories: small molecule and polymer light-emitting diodes according to the organic materials used. The working efficiency and life of the components depend on the characteristics of organic materials, process parameters and process In addition to environmental control, good packaging is an important key to maintaining component performance. From a technical point of view, material synthesis and process research and development have reached the level of commercialization; however, due to the lack of fast and effective packaging technology, organic light-emitting diodes can only reach the scale of experiment or trial production , so it cannot be mass-produced.

有机电致发光元件中的有机膜材对于水气及氧气均很敏感,是由于水气与氧气会造成有机膜材恶化,进而影响有机电致发光元件的使用寿命。为了有效排除水气、氧气等因素对有机电致发光元件的影响,延长元件的使用寿命,因此必须对有机电致发光元件进行封装。The organic membrane material in the organic electroluminescent element is very sensitive to moisture and oxygen, because moisture and oxygen will cause deterioration of the organic membrane material, thereby affecting the service life of the organic electroluminescent element. In order to effectively eliminate the influence of moisture, oxygen and other factors on the organic electroluminescent element and prolong the service life of the element, the organic electroluminescent element must be packaged.

请参照图1A至图1B,是公知一种有机电致发光二极管的封装方法,其制作工艺的剖面示意图。如图1A所示,首先提供含有机电致发光二极管102的玻璃基板100,再以点胶机将紫外光胶(即UV胶)104涂布于玻璃基板100上、有机电致发光二极管102的边框位置。再参照图1B,使用玻璃盖板106覆盖有机电致发光二极管102,并由紫外光胶104与玻璃基板100压合,再以紫外光(UV)照射封装件,使紫外光胶104固化,完成有机电致发光二极管102的封装。Please refer to FIG. 1A to FIG. 1B , which are schematic cross-sectional views of a conventional packaging method of an organic electroluminescent diode and its manufacturing process. As shown in FIG. 1A, a glass substrate 100 containing an organic electroluminescent diode 102 is first provided, and then an ultraviolet glue (ie, UV glue) 104 is coated on the glass substrate 100 and the frame of the organic electroluminescent diode 102 by a glue dispenser. Location. Referring to FIG. 1B again, the organic electroluminescent diode 102 is covered with a glass cover plate 106, and the ultraviolet glue 104 is pressed against the glass substrate 100, and then the package is irradiated with ultraviolet light (UV) to cure the ultraviolet glue 104, and the process is completed. Encapsulation of the organic electroluminescence diode 102 .

其次,请参照图2A至图2B,是公知另一种有机电致发光二极管的封装方法,其制作工艺的剖面示意图。如图2A所示,首先将冲压成型的金属盖206放在治具(未显示于图中)上,以点胶机将紫外光胶204涂布于金属盖206的边缘,并将吸湿层(Moisture Absorption Sheet)208配置于金属盖206内。而治具中金属盖206的定位,对应于玻璃基板上欲封装元件的位置。再参照图2B,将含有机电致发光二极管202的玻璃基板200覆盖在金属盖206上方,并由紫外光胶204与金属盖206的边缘压合,再以紫外光照射封装件,使紫外光胶204固化,完成有机电致发光二极管202的封装。Next, please refer to FIG. 2A to FIG. 2B , which are schematic cross-sectional views of another known packaging method of organic light-emitting diodes and its manufacturing process. As shown in FIG. 2A , first place the stamped metal cover 206 on a jig (not shown in the figure), use a dispenser to apply UV glue 204 to the edge of the metal cover 206, and apply the moisture-absorbing layer ( Moisture Absorption Sheet) 208 is disposed in the metal cover 206. The position of the metal cover 206 in the jig corresponds to the position of the components to be packaged on the glass substrate. Referring to FIG. 2B again, the glass substrate 200 containing the organic electroluminescent diode 202 is covered on the metal cover 206, and the edge of the metal cover 206 is pressed by the ultraviolet glue 204, and then the package is irradiated with ultraviolet light to make the ultraviolet glue 204 is cured to complete the packaging of the organic electroluminescent diode 202 .

前述这两种封装方式,应用于大量生产并无困难。但是,仅以元件边框位置上的紫外光胶并无法有效阻隔外界的水气及氧气,因此无法降低水气、氧气等对发光元件质量、性能的影响。而且,欲利用位于元件边框的紫外光胶来隔绝外界的水气与氧气,并达到良好的封装效果,必须使元件内呈正压(即大于大气压),例如在元件内部充入高纯度氮气,但这对工艺而言并不容易实现,而且会增加工艺步骤、降低生产效率,并导致产品合格率不好、制作成本上升。The aforementioned two packaging methods are not difficult to apply to mass production. However, only the ultraviolet glue on the frame position of the element cannot effectively block the external moisture and oxygen, so the influence of moisture and oxygen on the quality and performance of the light-emitting element cannot be reduced. Moreover, in order to use the UV glue located on the frame of the component to isolate the moisture and oxygen from the outside and achieve a good packaging effect, the component must be under positive pressure (that is, greater than atmospheric pressure), such as filling high-purity nitrogen inside the component. But this is not easy to realize for the process, and it will increase the process steps, reduce the production efficiency, lead to poor product qualification rate and increase the production cost.

请再参照图3A至图3B,是公知又一种有机电致发光二极管的封装方法,其制作工艺的剖面示意图。如图3A所示,首先提供含有机电致发光二极管302的玻璃基板300,再以点胶机将通称AB胶的环氧树脂(Epoxy Resin)304涂布于玻璃基板300上每一个有机电致发光二极管302的整个表面。再参照图3B,使用玻璃盖板306覆盖有机电致发光二极管302,并由环氧树脂304与玻璃基板300压合,再使环氧树脂304自然硬化,完成有机电致发光二极管302的封装。Please refer again to FIG. 3A to FIG. 3B , which are schematic cross-sectional views of yet another known packaging method of an organic electroluminescent diode and its manufacturing process. As shown in FIG. 3A , a glass substrate 300 containing organic electroluminescent diodes 302 is first provided, and then epoxy resin (Epoxy Resin) 304, commonly known as AB glue, is coated on each organic electroluminescent diode 300 on the glass substrate 300 by a dispenser. the entire surface of the diode 302. Referring again to FIG. 3B , the OLED 302 is covered with a glass cover 306 , and the epoxy resin 304 is bonded to the glass substrate 300 , and then the epoxy resin 304 is naturally hardened to complete the packaging of the OLED 302 .

然而上述这种封装方式,对有机电致发光二极管整面涂布环氧树脂,虽然有较良好的封装效果,但整面涂布环氧树脂,其涂胶的均匀性较难控制,并在进行批量生产上有其困难。此外,玻璃基板和玻璃盖板或金属盖压合时,在元件整面涂胶容易产生溢胶现象,导致发光元件与外部其它元件连接的线路被胶所覆盖,造成封装后发光元件无法正常使用,导致生产效率降低、产品合格率不佳、制作成本上升。而且在覆盖玻璃盖板时,容易在环氧树脂与玻璃盖板间产生气泡,对发光元件仍会造成不良的影响。However, the above-mentioned encapsulation method has a relatively good encapsulation effect on the entire surface of the organic electroluminescent diode coated with epoxy resin, but the uniformity of the epoxy resin is difficult to control when the entire surface is coated with epoxy resin. It is difficult to carry out mass production. In addition, when the glass substrate and the glass cover or the metal cover are pressed together, it is easy to cause glue overflow on the entire surface of the component, causing the circuit connecting the light-emitting component and other external components to be covered by the glue, resulting in the light-emitting component being unable to work normally after packaging , resulting in reduced production efficiency, poor product pass rate, and increased production costs. Moreover, when the glass cover is covered, air bubbles are likely to be generated between the epoxy resin and the glass cover, which will still cause adverse effects on the light-emitting element.

发明内容Contents of the invention

因此本发明提供一种电致发光元件的封装方法,可有效阻隔外界的水气及氧气,防止其造成发光元件质量恶化及性能降低等负面影响。再者,此种方法可对发光元件进行快速且有效的封装,提高生产效率及产品合格率,并降低制作成本,使其达到大量生产的规模,而且可防止盖板和基板间发生溢胶以及盖板与封装材料间产生气泡等对发光元件产生不良影响。而且,此种封装方法可应用于诸如有机发光二极管等有机电致发光元件的封装,是一种可以大量生产有机电致发光二极管的封装技术。Therefore, the present invention provides a method for encapsulating an electroluminescent element, which can effectively block moisture and oxygen from the outside and prevent negative effects such as quality deterioration and performance degradation of the light-emitting element. Furthermore, this method can quickly and effectively package the light-emitting elements, improve production efficiency and product qualification rate, and reduce production costs, so that it can reach the scale of mass production, and can prevent the occurrence of glue overflow between the cover plate and the substrate and Bubbles and the like generated between the cover plate and the encapsulation material will adversely affect the light-emitting element. Moreover, this packaging method can be applied to the packaging of organic electroluminescent elements such as organic light emitting diodes, and is a packaging technology that can mass produce organic electroluminescent diodes.

根据本发明的上述及其它目的,提出一种电致发光元件的封装方法,在水、氧浓度被控制的环境中,首先提供具有电致发光元件的玻璃基板以及对应的玻璃盖板,在盖板上对应于基板上各发光元件的边框位置涂布框胶,并在发光元件周边不具有电路的一侧预留开口;然后将盖板与基板压合并使框胶固化;再对基板进行切割,把各发光元件加以分开,形成个别的封装件;接着将封装件置入真空腔中抽气,当真空腔内压强达到设定值时,把封装件浸入真空腔底部的胶槽中,让封装件的开口与封装材料接触;再将真空腔内压强升高,使封装材料因封装件内外的压强差而灌满空腔,再将空腔内的封装材料固化,完成发光元件的封装。According to the above and other purposes of the present invention, a method for encapsulating electroluminescent elements is proposed. In an environment where the concentration of water and oxygen is controlled, a glass substrate with an electroluminescent element and a corresponding glass cover plate are first provided. Apply frame glue on the board corresponding to the frame position of each light-emitting element on the substrate, and reserve an opening on the side without the circuit around the light-emitting element; then press the cover plate and the substrate to cure the frame glue; then cut the substrate , to separate the light-emitting elements to form individual packages; then put the package into the vacuum chamber to pump air, when the pressure in the vacuum chamber reaches the set value, immerse the package in the glue groove at the bottom of the vacuum chamber, let The opening of the package is in contact with the packaging material; then the pressure in the vacuum cavity is increased to fill the cavity with the packaging material due to the pressure difference between the inside and outside of the package, and then the packaging material in the cavity is cured to complete the packaging of the light-emitting element.

附图说明Description of drawings

图1A至图1B为公知一种有机电致发光二极管封装工艺的剖面示意图;1A to 1B are schematic cross-sectional views of a known organic electroluminescent diode packaging process;

图2A至图2B为公知另一种有机电致发光二极管封装工艺的剖面示意图;2A to 2B are schematic cross-sectional views of another known organic electroluminescent diode packaging process;

图3A至图3B为公知又一种有机电致发光二极管封装工艺的剖面示意图;3A to 3B are schematic cross-sectional views of yet another known organic electroluminescent diode packaging process;

图4为依照本发明的第一实施例,一种电致发光元件的封装方法的流程图;4 is a flow chart of a packaging method for an electroluminescent element according to the first embodiment of the present invention;

图5A至图5H为依照本发明的第一实施例,一种电致发光元件的封装工艺示意图;5A to 5H are schematic diagrams of a packaging process of an electroluminescent element according to the first embodiment of the present invention;

图6为含有机电致发光二极管的玻璃基板的剖面示意图;6 is a schematic cross-sectional view of a glass substrate containing an organic electroluminescent diode;

图7为依照本发明的第二实施例,一种大面积电致发光元件的封装方法的流程图;7 is a flow chart of a packaging method for a large-area electroluminescent element according to the second embodiment of the present invention;

图8A至图8F为依照本发明的第二实施例,一种大面积电致发元件的封装工艺示意图。8A to 8F are schematic diagrams of a packaging process of a large-area electroluminescent device according to the second embodiment of the present invention.

附图标记说明:Explanation of reference signs:

100、200、300、500、500a、600、800:玻璃基板100, 200, 300, 500, 500a, 600, 800: glass substrate

102、202、302:有机电致发光二极管102, 202, 302: organic electroluminescent diodes

104、204:紫外光胶104, 204: UV glue

106、306、504、504a、804:玻璃盖板106, 306, 504, 504a, 804: glass cover

206:金属盖206: metal cover

208:吸湿层208: Hygroscopic layer

304:环氧树脂304: epoxy resin

400~414:电致发光元件的封装步骤400~414: Encapsulation steps of electroluminescent components

502、802:电致发光元件502, 802: electroluminescence element

506、806:边框位置506, 806: frame position

508、808:框胶508, 808: frame glue

510、810:隔离物510, 810: spacers

512、812:开口512, 812: opening

514、814:电路514, 814: circuit

516、816:封装件516, 816: packages

518、818:空腔518, 818: cavity

520、820:真空腔520, 820: vacuum chamber

522、822:胶槽522, 822: glue groove

524、524a、824、824a:封装材料524, 524a, 824, 824a: Packaging material

530、830:水氧控制环境530, 830: water and oxygen control environment

602:铟锡氧化层602: Indium tin oxide layer

604:有机膜材604: organic membrane material

606:金属电极层606: metal electrode layer

610:空穴注入层610: Hole injection layer

612:空穴传输层612: Hole transport layer

614:发光层614: Luminescent layer

616:电子传输层616: Electron transport layer

700~710:大面积电致发光元件的封装步骤700~710: Encapsulation steps of large-area electroluminescent elements

具体实施方式Detailed ways

请参照图4,是依照本发明的第一实施例,一种电致发光元件的封装方法的流程图。图5A至图5H,是依照本发明的第一实施例,一种电致发光元件的封装方法的制作工艺的示意图。而图4中的步骤400~414分别与图5A至图5H相对应。Please refer to FIG. 4 , which is a flow chart of a packaging method for electroluminescent elements according to the first embodiment of the present invention. 5A to 5H are schematic diagrams of the manufacturing process of a packaging method for electroluminescent elements according to the first embodiment of the present invention. Steps 400-414 in FIG. 4 correspond to FIG. 5A-FIG. 5H respectively.

如图4中的步骤400所示,并请参照图5A,首先在水气、氧气浓度被控制的环境530下,例如是在水、氧浓度小于百万分之一(1ppm)的环境下,此种控制环境包括手套箱(Dry Box)等,然后提供具有电致发光元件502的玻璃基板500以及与玻璃基板500对应的玻璃盖板504,并在玻璃盖板504上的边框位置506涂布框胶508,而且在对应于各个电致发光元件502不具有电路的侧边预留开口512,即在开口512位置不涂框胶。As shown in step 400 in FIG. 4 , and please refer to FIG. 5A , first in an environment 530 in which the concentration of water and oxygen is controlled, for example, in an environment where the concentration of water and oxygen is less than one part per million (1ppm), This kind of control environment includes a glove box (Dry Box) etc., then provide a glass substrate 500 with an electroluminescent element 502 and a glass cover plate 504 corresponding to the glass substrate 500, and coat the frame position 506 on the glass cover plate 504 Frame glue 508 , and an opening 512 is reserved on the side corresponding to each electroluminescent element 502 without a circuit, that is, no frame glue is applied at the position of the opening 512 .

图5A包括玻璃盖板504及玻璃基板500的俯视图及部分区域的剖面示意图,其中玻璃盖板504上的各个边框位置506分别对应于玻璃基板500上的各个电致发光元件502,而框胶508中含有隔离物(Spacer)510,框胶508的材料则包括热固化型胶(例如AB胶)、紫外光固化型胶(例如UV胶)等。5A includes a top view of a glass cover 504 and a glass substrate 500 and a schematic cross-sectional view of a part of the area, wherein each frame position 506 on the glass cover 504 corresponds to each electroluminescent element 502 on the glass substrate 500, and the frame glue 508 There is a spacer (Spacer) 510 in it, and the material of the frame glue 508 includes heat-curable glue (such as AB glue), ultraviolet light-curable glue (such as UV glue), and the like.

图5A中的电致发光元件502包括有机电致发光元件,例如有机电致发光二极管等。如图6所示,其为含有机电致发光二极管的玻璃基板的剖面示意图,在玻璃基板600表面具有已图案化的铟锡氧化层(Indium TinOxide,ITO)602,有机膜材604则是覆盖在铟锡氧化层602表面,而有机膜材604的表面覆有金属电极606层。在有机膜材604中包括有空穴注入层610、空穴传输层(Hole Transport Layer)612、发光层(Light EmittingLayer)614、电子传输层(Electron Transport Layer)616等。The electroluminescent element 502 in FIG. 5A includes an organic electroluminescent element, such as an organic electroluminescent diode or the like. As shown in FIG. 6 , it is a schematic cross-sectional view of a glass substrate containing an organic electroluminescent diode. There is a patterned indium tin oxide layer (Indium TinOxide, ITO) 602 on the surface of the glass substrate 600, and an organic film material 604 is covered on the The surface of the indium tin oxide layer 602 and the surface of the organic film material 604 are covered with a metal electrode 606 layer. The organic film material 604 includes a hole injection layer 610, a hole transport layer (Hole Transport Layer) 612, a light emitting layer (Light Emitting Layer) 614, an electron transport layer (Electron Transport Layer) 616 and the like.

其次,请同时参照图4中的步骤402与图5B(盖板与基板压合后部分区域的剖面示意图),在控制水、氧浓度的环境530中,将涂有框胶508的玻璃盖板504与具有电致发光元件502的玻璃基板500压合,使电致发光元件502位于框胶508、玻璃基板500与玻璃盖板504之间。其中框胶508用以接合玻璃基板500与玻璃盖板504,将发光元件502密封,其中所含的隔离物510则是用来控制玻璃基板500与玻璃盖板504接合的间距(Gap)。而在涂布框胶508时,在框胶508掺入隔离物510,可使玻璃基板500与玻璃盖板504间的距离为一固定值。Next, please refer to step 402 in FIG. 4 and FIG. 5B (the schematic cross-sectional view of a part of the area after the cover plate and the substrate are pressed together). 504 is pressed against the glass substrate 500 with the electroluminescent element 502 , so that the electroluminescent element 502 is located between the sealant 508 , the glass substrate 500 and the glass cover 504 . The sealant 508 is used to bond the glass substrate 500 and the glass cover 504 to seal the light-emitting element 502 , and the spacer 510 contained therein is used to control the gap between the glass substrate 500 and the glass cover 504 . When coating the sealant 508 , a spacer 510 is added to the sealant 508 to make the distance between the glass substrate 500 and the glass cover 504 a fixed value.

接着,请参照图4的步骤404和图5C(框胶固化后部分区域的剖面示意图),在水、氧控制环境530下,将玻璃盖板504与玻璃基板500压合后,接着使框胶508固化。若框胶508的材料为紫外光固化型胶,则以紫外光照射,使框胶508固化;若框胶508的材料为热固化型胶,则须配合紫外光固化型胶及照射紫外光,先将玻璃基板500及玻璃盖板504的相对位置加以定位,再使材料为热固化型胶的框胶508固化,例如进行热烤(Curing)使热固化型胶固化或让热固化型胶自然硬化。Next, please refer to step 404 of FIG. 4 and FIG. 5C (the schematic cross-sectional view of some areas after the sealant is cured). 508 curing. If the material of the frame glue 508 is a UV-curable glue, then irradiate with ultraviolet light to cure the frame glue 508; if the material of the frame glue 508 is a heat-curable glue, it must be combined with a UV-curable glue and irradiated with ultraviolet light. First, position the relative positions of the glass substrate 500 and the glass cover plate 504, and then cure the frame glue 508 made of thermosetting adhesive, for example, perform curing to cure the thermosetting adhesive or allow the thermosetting adhesive to naturally hardening.

然后,进行图4的步骤406并参照图5D(盖板与基板压合后的俯视图),在水、氧浓度被控制的环境530中,将压合后且接合用框胶508已固化的玻璃基板500和玻璃盖板504,依照玻璃基板500上各个电致发光元件502及其对应的边框位置506的分布状态进行切割,图5D中的虚线即为其中一种切割方式。Then, perform step 406 in FIG. 4 and refer to FIG. 5D (the top view of the cover plate and the substrate after pressing), in the environment 530 where the concentration of water and oxygen is controlled, the glass after the pressing and the sealant 508 for bonding has cured The substrate 500 and the glass cover 504 are cut according to the distribution of the electroluminescent elements 502 and their corresponding frame positions 506 on the glass substrate 500 , and the dotted line in FIG. 5D is one of the cutting methods.

再进行图4中的步骤408及参照图5E(封装件的俯视图及剖面图),在水气、氧气浓度被控制的环境下,玻璃基板500和玻璃盖板504经切割后,按各个电致发光元件502及其对应的边框位置506的分布状态将其个别分开,例如使用裂片机将各发光元件分开,并预留出各个电致发光元件502对外电连接所需的电路514,形成各自独立的封装件516。而各封装件516中包括具有电致发光元件502的元件玻璃基板500a、框胶508和元件玻璃盖板504a,以及由其所构成的空腔518。Then proceed to step 408 in FIG. 4 and refer to FIG. 5E (the top view and cross-sectional view of the package), in an environment where the concentration of water vapor and oxygen is controlled, after the glass substrate 500 and the glass cover 504 are cut, press each electrode The distribution state of the light-emitting elements 502 and their corresponding frame positions 506 separates them individually, for example, using a splitter to separate each light-emitting element, and reserves the circuit 514 required for the external electrical connection of each electroluminescent element 502 to form an independent package 516 . Each package 516 includes an element glass substrate 500 a having an electroluminescence element 502 , a sealant 508 , an element glass cover 504 a, and a cavity 518 formed therefrom.

请参照图4中的步骤410与图5F,提供真空腔520,并在其底部配置有胶槽522,胶槽522内则装有封装材料524,而封装材料524包括紫外光固化型胶或热固化型胶等。在水、氧控制环境中,将切割分开后的各封装件516置入真空腔520内。因此对真空腔520进行真空抽气时,同时对位于真空腔520内的封装件516及封装材料524等进行真空排气,此时封装件516的开口512朝向胶槽522,但并未与胶槽522内的封装材料524接触。Please refer to step 410 and FIG. 5F in FIG. 4, a vacuum chamber 520 is provided, and a glue tank 522 is disposed at the bottom thereof, and a packaging material 524 is housed in the glue tank 522, and the packaging material 524 includes UV-curable glue or heat Curing glue, etc. In a water and oxygen controlled environment, the cut packages 516 are put into a vacuum chamber 520 . Therefore, when the vacuum chamber 520 is evacuated, the package 516 and the packaging material 524 etc. located in the vacuum chamber 520 are simultaneously evacuated. The encapsulation material 524 within the groove 522 is in contact.

同时参照图4中的步骤412及图5G,当真空腔520内的真空度达到所设定的压强时,例如小于1大气压,将封装件516的高度降低,使其开口512浸入胶槽522中,并与封装材料524表面接触以进行灌胶。由于毛细现象的缘故,胶槽522中的封装材料524会从开口512被吸入封装件516的空腔518内。然后,将干燥气体(例如:高纯度氮气)导入真空腔520中让压强上升,例如将压强升至常压状态或约为1大气压,使封装材料524因封装件516内外的压强差而持续注入并充满封装件516内的空腔518,完全覆盖其中的电致发光元件502,因此在空腔518内的元件封装材料524a中不会产生气泡,防止气泡影响发光元件的质量与寿命。Referring to step 412 and FIG. 5G in FIG. 4 at the same time, when the vacuum degree in the vacuum chamber 520 reaches the set pressure, for example, less than 1 atmosphere, the height of the package 516 is lowered so that the opening 512 is immersed in the glue groove 522. , and contact with the surface of the encapsulation material 524 for potting. Due to the capillary phenomenon, the encapsulation material 524 in the glue groove 522 will be sucked into the cavity 518 of the encapsulation 516 through the opening 512 . Then, dry gas (for example: high-purity nitrogen) is introduced into the vacuum chamber 520 to increase the pressure, for example, the pressure is increased to normal pressure or about 1 atmosphere, so that the packaging material 524 is continuously injected due to the pressure difference between the inside and outside of the package 516 And fill the cavity 518 in the package 516 to completely cover the electroluminescent element 502 therein, so no air bubbles will be generated in the element packaging material 524a in the cavity 518, preventing the air bubbles from affecting the quality and life of the light-emitting element.

然后,如图4中的步骤414所示,并参照图5H,当封装件516的空腔518内填满元件封装材料524a后,再使元件封装材料524a固化,完成电致发光元件的封装。若元件封装材料524a使用的材料为紫外光固化型胶,则以紫外光照射使其固化;若元件封装材料524a使用的材料为热固化型胶,则可进行热烤使其固化,或者使其自然硬化。Then, as shown in step 414 in FIG. 4 and referring to FIG. 5H , after the cavity 518 of the package 516 is filled with the element encapsulation material 524a, the element encapsulation material 524a is cured to complete the encapsulation of the electroluminescent element. If the material used in the component encapsulation material 524a is a UV-curable glue, it can be cured by irradiating ultraviolet light; Natural hardening.

本发明所提出的电致发元件的封装方法,也可应用于大面积电致发元件的封装。请参照图7,是依照本发明的第二实施例,一种大面积电致发光元件的封装方法的流程图。图8A至图8F,是依照本发明的第二实施例,一种大面积电致发光元件的封装方法的制作工艺示意图。与第一实施例类似,图7中的步骤700~710分别与图8A至图8F相对应。The packaging method of the electroluminescent element proposed by the present invention can also be applied to the packaging of large-area electroluminescent elements. Please refer to FIG. 7 , which is a flow chart of a packaging method for large-area electroluminescent elements according to the second embodiment of the present invention. 8A to 8F are schematic diagrams of the manufacturing process of a packaging method for large-area electroluminescent elements according to the second embodiment of the present invention. Similar to the first embodiment, steps 700 to 710 in FIG. 7 correspond to FIG. 8A to FIG. 8F respectively.

如图7中的步骤700所示,并请参照图8A,与第一实施例相同,在水气、氧气浓度被控制的环境830下,提供玻璃基板800以及对应的玻璃盖板804,且玻璃基板800上具有单一的大面积电致发光元件802,其周边具有对外连接所需的电路814。然后在玻璃盖板804上、对应于电致发光元件802的边框位置806,涂布含有隔离物810的框胶808,并在对应于电致发光元件802不具有电路的侧边预留开口812,即在开口812位置不涂框胶。而电致发光元件802包括有机电致发光元件,例如图6所示的有机电致发光二极管等。As shown in step 700 in FIG. 7 , and please refer to FIG. 8A , as in the first embodiment, a glass substrate 800 and a corresponding glass cover 804 are provided in an environment 830 in which moisture and oxygen concentrations are controlled, and the glass There is a single large-area electroluminescent element 802 on the substrate 800, and a circuit 814 required for external connection is provided around it. Then, on the glass cover 804 , corresponding to the frame position 806 of the electroluminescent element 802 , coat a frame glue 808 containing spacers 810 , and reserve an opening 812 on the side corresponding to the electroluminescent element 802 without a circuit. , that is, no frame glue is applied at the position of the opening 812 . The electroluminescent element 802 includes an organic electroluminescent element, such as an organic electroluminescent diode shown in FIG. 6 .

其次,请同时参照图7中的步骤702与图8B(盖板与基板压合后的剖面示意图),在控制水、氧浓度的环境830中,将玻璃盖板804与玻璃基板800压合,使电致发光元件802位于框胶808、玻璃基板800与玻璃盖板804之间。框胶808用以接合玻璃基板800与玻璃盖板804,将发光元件802密封,其所含的隔离物810是用来控制玻璃基板800与玻璃盖板804的间距,使其为一固定值。Next, please refer to step 702 in FIG. 7 and FIG. 8B (the cross-sectional schematic diagram after the cover plate and the substrate are pressed together), in the environment 830 where the concentration of water and oxygen is controlled, the glass cover plate 804 and the glass substrate 800 are pressed together, The electroluminescent element 802 is located between the sealant 808 , the glass substrate 800 and the glass cover 804 . The sealant 808 is used to bond the glass substrate 800 and the glass cover 804 to seal the light-emitting element 802 , and the spacer 810 contained therein is used to control the distance between the glass substrate 800 and the glass cover 804 to a fixed value.

接着,请参照图7的步骤704和图8C(框胶固化后的剖面示意图),在水、氧控制环境830下,使位于玻璃盖板804与玻璃基板800间的框胶808固化。若框胶为紫外光固化型胶,则以紫外光照射使其固化;如框胶为热固化型胶,则须配合紫外光固化型胶及照射紫外光,先将玻璃基板及玻璃盖板的相对位置定位,再以热烤或自然硬化的方式使框胶固化。由于玻璃基板800与玻璃盖板804间仅封有单一个电致发元件802,因此不需要进行切割及裂片步骤,即可完成独立的封装件816。Next, please refer to step 704 of FIG. 7 and FIG. 8C (the cross-sectional schematic view of the cured sealant), the sealant 808 located between the glass cover 804 and the glass substrate 800 is cured in the water and oxygen controlled environment 830 . If the frame glue is UV-curable glue, irradiate it with ultraviolet light to cure it; if the frame glue is heat-curable glue, it must be combined with UV-curable glue and irradiated with ultraviolet light. The relative position is positioned, and then the frame glue is cured by hot baking or natural hardening. Since only a single electroluminescent element 802 is sealed between the glass substrate 800 and the glass cover 804 , the independent package 816 can be completed without cutting and splitting steps.

再参照图7中的步骤706与图8D,与第一实施例的步骤410类似,提供底部具有胶槽822的真空腔820,而胶槽822内则装有封装材料824。在水、氧控制环境中,将一个或数个封装件816置于真空腔820内,并使其开口812朝向胶槽822,但不与其中的封装材料824接触。Referring again to step 706 in FIG. 7 and FIG. 8D , similar to step 410 in the first embodiment, a vacuum chamber 820 with a glue groove 822 at the bottom is provided, and a packaging material 824 is installed in the glue groove 822 . In a water and oxygen controlled environment, one or several packages 816 are placed in the vacuum chamber 820 with their openings 812 facing the glue groove 822 but not in contact with the package material 824 therein.

然后,请参照图7中的步骤708及图8E,当真空腔820内达到设定压强时,将封装件816浸入胶槽822,使开口812与封装材料824接触进行灌胶,封装材料824因毛细现象而被吸入空腔818内。再将干燥气体导入真空腔820中,使封装材料824因封装件816内外压强差持续注入而充满其空腔818,并完全覆盖电致发光元件802。Then, please refer to step 708 and FIG. 8E in FIG. 7, when the set pressure is reached in the vacuum chamber 820, the package 816 is immersed in the glue tank 822, so that the opening 812 is in contact with the packaging material 824 for filling, and the packaging material 824 is Capillarity is sucked into cavity 818 . Then dry gas is introduced into the vacuum chamber 820 , so that the encapsulation material 824 is continuously injected due to the pressure difference between the interior and exterior of the encapsulation 816 to fill the cavity 818 and completely cover the electroluminescence element 802 .

如图7中的步骤710所示,并参照图8F,当空腔818内填满元件封装材料824a后,再使其固化,完成电致发光元件的封装。与步骤704类似,若元件封装材料824a为紫外光固化型胶,则以紫外光照射使其固化;如元件封装材料824a为热固化型胶,则可进行热烤使其固化,或者使其自然硬化。As shown in step 710 in FIG. 7 , and referring to FIG. 8F , after the cavity 818 is filled with the element encapsulation material 824a, it is cured to complete the encapsulation of the electroluminescent element. Similar to step 704, if the component encapsulation material 824a is an ultraviolet light-curable glue, then irradiate it with ultraviolet light to cure it; if the element encapsulation material 824a is a heat-curable glue, then it can be cured by hot baking, or it can be naturally hardening.

由上述的实施例可知,本发明所提出的电致发光元件的封装方法,可应用于不同面积的电致发光元件,而且是在水气及氧气浓度被控制的环境下进行,因此可有效阻隔水气及氧气,防止其影响发光元件质量及性能。而在框胶内掺入隔离物并控制胶量,可增加涂胶的均匀性,使玻璃盖板与玻璃基板的间距固定,并防止玻璃基板与玻璃盖板压合时产生溢胶,避免发光元件与外部连接的线路被胶覆盖。It can be seen from the above examples that the packaging method of the electroluminescent element proposed by the present invention can be applied to electroluminescent elements of different areas, and it is carried out in an environment where the concentration of water vapor and oxygen is controlled, so it can effectively block Moisture and oxygen to prevent them from affecting the quality and performance of light-emitting components. Adding spacers and controlling the amount of glue in the frame glue can increase the uniformity of glue application, make the distance between the glass cover plate and the glass substrate fixed, and prevent the glue from overflowing when the glass substrate and the glass cover plate are pressed together, avoiding light. The lines connecting the components to the outside are covered with glue.

其次,本发明以真空腔及封装材料使发光元件的封装件内外产生压强差,将封装材料导入封装件的空腔中完全覆盖发光元件,具有良好的封装效果,并可以防止封装材料中产生气泡,避免其影响发光元件的质量与寿命,提高产品的可靠性。再者,在真空腔中可同时置入多个发光元件的封装件,并且对这些封装件进行灌胶,因此应用本发明可对发光元件进行快速且有效的封装,提高生产效率及产品合格率,并降低制作成本,使得诸如有机电致发光二极管等元件可达批量生产规模。Secondly, the present invention uses a vacuum cavity and packaging material to generate a pressure difference inside and outside the package of the light-emitting element, and introduces the packaging material into the cavity of the package to completely cover the light-emitting element, which has a good packaging effect and can prevent the generation of air bubbles in the packaging material. , avoiding its influence on the quality and life of the light-emitting element, and improving the reliability of the product. Furthermore, packages of multiple light-emitting elements can be placed in the vacuum chamber at the same time, and these packages can be filled with glue, so the application of the present invention can quickly and effectively package the light-emitting elements, improving production efficiency and product qualification rate , and reduce production costs, so that components such as organic light-emitting diodes can reach mass production scale.

虽然本发明已以实施例说明如上,然其并非用以限定本发明,任何熟悉此技术的人,在不脱离本发明的精神和范围内,当可作各种的更动与润饰,因此本发明的保护范围以权利要求书为准。Although the present invention has been described above with embodiments, it is not intended to limit the present invention. Any person familiar with this technology can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, this The scope of protection of the invention shall be determined by the claims.

Claims (12)

1.一种电致发光元件的封装方法,其特征为:至少包括下列步骤:1. A method for encapsulating an electroluminescent element, characterized in that it comprises at least the following steps: 在一水、氧控制环境中,提供一玻璃基板与一玻璃盖板,该玻璃盖板与该玻璃基板相对应,且该玻璃基板具有多个电致发光元件;In a water and oxygen controlled environment, a glass substrate and a glass cover are provided, the glass cover corresponds to the glass substrate, and the glass substrate has a plurality of electroluminescent elements; 在该水、氧控制环境中,在该玻璃盖板上多个边框位置分别涂布一框胶,该边框位置与该电致发光元件一一对应,该框胶的每一个分别具有一开口;In the water and oxygen control environment, a frame glue is coated on a plurality of frame positions on the glass cover plate, and the frame positions correspond to the electroluminescent elements one by one, and each frame glue has an opening; 在该水、氧控制环境中,使该框胶位于该玻璃盖板与该玻璃基板之间,将该玻璃盖板与该玻璃基板压合,并使该电致发光元件位于该玻璃盖板与该玻璃基板之间;In the water and oxygen controlled environment, the sealant is positioned between the glass cover and the glass substrate, the glass cover and the glass substrate are pressed together, and the electroluminescent element is positioned between the glass cover and the glass substrate between the glass substrates; 在该水、氧控制环境中,使该框胶固化;Curing the sealant in the water and oxygen controlled environment; 在该水、氧控制环境中,依据该电致发光元件的分布,对该玻璃盖板与该玻璃基板进行切割;In the water and oxygen controlled environment, according to the distribution of the electroluminescent elements, the glass cover plate and the glass substrate are cut; 在该水、氧控制环境中,切割该玻璃盖板与该玻璃基板,将该电致发光元件的每一个分开,形成各自独立的多个封装件,而该封装件的每一个包括一元件玻璃基板、该电致发光元件的其中一个、该框胶的其中一个与一元件玻璃盖板,并由该元件玻璃盖板、该元件玻璃基板和该框胶的其中一个构成一空腔;In the water and oxygen controlled environment, the glass cover and the glass substrate are cut to separate each of the electroluminescent elements to form a plurality of independent packages, and each of the packages includes an element glass a substrate, one of the electroluminescent elements, one of the sealant, and an element glass cover, and a cavity is formed by one of the element glass cover, the element glass substrate, and the sealant; 提供一真空腔,在该真空腔的底部配置有一胶槽,该胶槽内装有一封装材料,并将该封装件置入该真空腔中,使该封装件中每一个的该框胶的该开口朝向该胶槽,且该封装件不与该封装材料接触;A vacuum chamber is provided, a glue groove is arranged at the bottom of the vacuum chamber, and a packaging material is installed in the glue groove, and the package is placed in the vacuum chamber, so that the opening of the sealant of each of the packages is facing the glue groove, and the package is not in contact with the packaging material; 对该真空腔进行真空抽气,使该封装件与该封装材料真空排气;Carrying out vacuum pumping to the vacuum cavity, so that the package and the package material are vacuum exhausted; 当该真空腔达到一设定真空度时,将该封装件浸入该胶槽中,使该封装件中每一个的该框胶的该开口与该封装材料接触进行灌胶;When the vacuum chamber reaches a set vacuum degree, immerse the package in the glue groove, make the opening of the frame glue of each of the packages contact with the packaging material for filling; 使该真空腔压强上升至一设定压强,使该封装材料分别由该封装件中每一个的该框胶的该开口注入并充满该空腔,形成一元件封装材料完全覆盖该电致发光元件;以及Raise the pressure of the vacuum chamber to a set pressure, inject the encapsulation material from the opening of the sealant of each of the encapsulations and fill the cavity, forming an element encapsulation material to completely cover the electroluminescent element ;as well as 使每一该元件封装材料固化。Each of the element encapsulating materials is cured. 2.如权利要求1所述的电致发光元件的封装方法,其特征为:该水、氧控制环境的水、氧浓度小于百万分之一。2. The packaging method of the electroluminescent element according to claim 1, characterized in that: the concentration of water and oxygen in the water and oxygen control environment is less than one millionth. 3.如权利要求1所述的电致发光元件的封装方法,其特征为:涂布该框胶时,该框胶中掺有多个隔离物。3 . The packaging method of the electroluminescent element according to claim 1 , wherein when the sealant is coated, a plurality of spacers are mixed in the sealant. 4 . 4.如权利要求1所述的电致发光元件的封装方法,其特征为:进行灌胶时,该真空腔的该设定真空度小于1大气压。4 . The packaging method of the electroluminescent element as claimed in claim 1 , wherein the set vacuum degree of the vacuum chamber is less than 1 atmosphere when glue filling is performed. 5 . 5.如权利要求1所述的电致发光元件的封装方法,其特征为:使该真空腔压强上升的方法包括将干燥气体导入该真空腔。5. The packaging method of the electroluminescent element as claimed in claim 1, wherein the method of increasing the pressure of the vacuum chamber comprises introducing dry gas into the vacuum chamber. 6.如权利要求1所述的电致发光元件的封装方法,其特征为:该设定压强为1大气压。6. The packaging method of the electroluminescent element as claimed in claim 1, wherein the set pressure is 1 atmosphere. 7.一种电致发光元件的封装方法,其特征为:至少包括下列步骤:7. A packaging method for an electroluminescent element, characterized in that: at least comprising the following steps: 在一水、氧控制环境中,提供一玻璃基板与一玻璃盖板,该玻璃盖板与该玻璃基板相对应,且该玻璃基板具有一电致发光元件;In a water and oxygen controlled environment, a glass substrate and a glass cover are provided, the glass cover corresponds to the glass substrate, and the glass substrate has an electroluminescent element; 在该水、氧控制环境中,在该玻璃盖板上的一边框位置涂布一框胶,该边框位置与该电致发光元件相对应,且该框胶具有一开口;In the water and oxygen control environment, a frame glue is coated on a frame position on the glass cover plate, the frame position corresponds to the electroluminescent element, and the frame glue has an opening; 在该水、氧控制环境中,使该框胶位于该玻璃盖板与该玻璃基板之间,将该玻璃盖板与该玻璃基板压合,并使该电致发光元件位于该玻璃盖板与该玻璃基板之间;In the water and oxygen controlled environment, the sealant is positioned between the glass cover and the glass substrate, the glass cover and the glass substrate are pressed together, and the electroluminescent element is positioned between the glass cover and the glass substrate between the glass substrates; 在该水、氧控制环境中,使该框胶固化,形成一封装件,并由该玻璃盖板、该玻璃基板和该框胶构成一空腔;In the water and oxygen controlled environment, the sealant is cured to form a package, and a cavity is formed by the glass cover plate, the glass substrate and the sealant; 提供一真空腔,在该真空腔的底部配置有一胶槽,该胶槽内装有一封装材料,并将至少一个该封装件置入该真空腔中,使该封装件中的该框胶的该开口朝向该胶槽,且该封装件不与该封装材料接触;A vacuum chamber is provided, a glue groove is arranged at the bottom of the vacuum chamber, a packaging material is installed in the glue groove, and at least one package is placed in the vacuum chamber, so that the opening of the sealant in the package facing the glue groove, and the package is not in contact with the packaging material; 对该真空腔进行真空抽气,使该封装件与该封装材料真空排气;Carrying out vacuum pumping to the vacuum cavity, so that the package and the package material are vacuum exhausted; 当该真空腔达到一设定真空度时,将该封装件浸入该胶槽中,使该封装件中的该框胶的该开口与该封装材料接触进行灌胶;When the vacuum chamber reaches a set vacuum degree, the package is immersed in the glue tank, so that the opening of the frame glue in the package is in contact with the packaging material for filling; 使该真空腔压强上升至一设定压强,使该封装材料由该封装件中的该框胶的该开口注入,并充满该封装件的该空腔,形成一元件封装材料完全覆盖该空腔中的该电致发光元件;以及Raise the pressure of the vacuum chamber to a set pressure, inject the packaging material from the opening of the sealant in the package, and fill the cavity of the package, forming an element packaging material to completely cover the cavity the electroluminescent element in; and 使该元件封装材料固化。The element encapsulating material is cured. 8.如权利要求7所述的电致发光元件的封装方法,其特征为:该水、氧控制环境的水、氧浓度小于百万分之一。8. The packaging method of the electroluminescent element as claimed in claim 7, characterized in that: the concentration of water and oxygen in the water and oxygen control environment is less than one millionth. 9.如权利要求7所述的电致发光元件的封装方法,其特征为:涂布该框胶时,该框胶中掺有多个隔离物。9 . The packaging method of the electroluminescent element as claimed in claim 7 , wherein when coating the sealant, a plurality of spacers are mixed in the sealant. 10 . 10.如权利要求7所述的电致发光元件的封装方法,其特征为:进行灌胶时,该真空腔的该设定真空度小于1大气压。10 . The packaging method of the electroluminescent element as claimed in claim 7 , wherein the set vacuum degree of the vacuum cavity is less than 1 atmosphere when glue filling is performed. 11 . 11.如权利要求7所述的电致发光元件的封装方法,其特征为:使该真空腔压强上升的方法包括将干燥气体导入该真空腔。11. The method for packaging electroluminescent elements as claimed in claim 7, wherein the method of increasing the pressure of the vacuum chamber comprises introducing dry gas into the vacuum chamber. 12.如权利要求7所述的电致发光元件的封装方法,其特征为:该设定压强为1大气压。12. The method for packaging electroluminescent elements as claimed in claim 7, wherein the set pressure is 1 atmosphere.
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