CN1299258A - Stabilized absorbent material for personal care products and method for making same - Google Patents
Stabilized absorbent material for personal care products and method for making same Download PDFInfo
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- CN1299258A CN1299258A CN99805785A CN99805785A CN1299258A CN 1299258 A CN1299258 A CN 1299258A CN 99805785 A CN99805785 A CN 99805785A CN 99805785 A CN99805785 A CN 99805785A CN 1299258 A CN1299258 A CN 1299258A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers of the pads
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F13/534—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
- A61F13/537—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer
- A61F13/53708—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer the layer having a promotional function on liquid propagation in at least one direction
- A61F13/53713—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer the layer having a promotional function on liquid propagation in at least one direction the layer having a promotional function on liquid propagation in the vertical direction
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F13/534—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
- A61F13/537—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer
- A61F13/53708—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer the layer having a promotional function on liquid propagation in at least one direction
- A61F13/53717—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer the layer having a promotional function on liquid propagation in at least one direction the layer having a promotional function on liquid propagation in the horizontal direction
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F13/534—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
- A61F13/537—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer
- A61F13/53743—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer characterised by the position of the layer relative to the other layers
- A61F13/53747—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer characterised by the position of the layer relative to the other layers the layer is facing the topsheet
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/53—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
- A61F13/534—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
- A61F13/537—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer
- A61F13/5376—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer characterised by the performance of the layer, e.g. acquisition rate, distribution time, transfer time
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
- A61F2013/15284—Properties of the article, e.g. stiffness or absorbency characterized by quantifiable properties
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
- A61F2013/15284—Properties of the article, e.g. stiffness or absorbency characterized by quantifiable properties
- A61F2013/15406—Basis weight
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
- A61F2013/15284—Properties of the article, e.g. stiffness or absorbency characterized by quantifiable properties
- A61F2013/15422—Density
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/15203—Properties of the article, e.g. stiffness or absorbency
- A61F2013/15284—Properties of the article, e.g. stiffness or absorbency characterized by quantifiable properties
- A61F2013/15463—Absorbency
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- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Nonwoven Fabrics (AREA)
- Sheets, Magazines, And Separation Thereof (AREA)
- Laminated Bodies (AREA)
Abstract
Description
发明领域field of invention
本发明涉及个人护理制品如尿布、训练裤、吸收性衬裤、成人失禁用品、绷带以及女性卫生制品之类吸收制品中的材料结构物。The present invention relates to the construction of materials in personal care articles such as diapers, training pants, absorbent underpants, adult incontinence products, bandages, and absorbent articles such as feminine hygiene products.
发明背景Background of the invention
个人护理吸收制品包括诸如尿布、训练裤、女性卫生制品如卫生巾、女短裤衬里及棉塞、失禁服装及用具、绷带等。所有这些制品的大多数基本式样通常包括,体侧衬里和外包覆层以及布置在体侧衬里与外包覆层之间的吸收剂芯。一般地,体侧衬里与外包覆层沿周边密封起来,以便将吸收剂芯包封在内,从而能够俘获任何流体并将其保持在吸收剂芯内部。视个人护理吸收制品的具体设计之不同,还可包括其他成分。譬如,该制品可包括诸如弹性侧片、挡液侧边、系紧器件以及流体转移及保持材料的其他层。Personal care absorbent articles include items such as diapers, training pants, feminine hygiene products such as sanitary napkins, panty liners and tampons, incontinence garments and appliances, bandages, and the like. The most basic form of all of these articles generally includes a bodyside liner and an outer cover with an absorbent core disposed between the bodyside liner and outer cover. Typically, the bodyside liner is peripherally sealed to the outer cover so as to enclose the absorbent core so that any fluid can be captured and retained within the absorbent core. Depending on the specific design of the personal care absorbent article, other ingredients may also be included. For example, the article may include other layers such as elastic side panels, liquid barrier sides, fastening means, and fluid transfer and retention materials.
以往的个人护理制品一直沿袭分别制造各单层材料,然后连接成层合物的办法来制作。在这种情况下,相邻层之间的边界比较轮廓鲜明,常常显露出用以将各层维系在一起成为层合物的粘合剂。每个层分别生产并粘合在一起成为层合物的办法是一种昂贵程序,需要多台不同的生产设备。这种方法生产出的个人护理制品用材料在其每层之间的边界或界面处具有轮廓鲜明的分界,会降低相邻层之间的流体传递。In the past, personal care products have been produced by manufacturing each single-layer material separately and then connecting them into a laminate. In this case, the boundaries between adjacent layers are more defined, often revealing the adhesives used to hold the layers together into a laminate. The method of producing each layer separately and bonding them together into a laminate is an expensive procedure requiring several pieces of different production equipment. This method produces materials for personal care articles that have well-defined boundaries at the boundaries or interfaces between each layer, reducing fluid transfer between adjacent layers.
因此,本发明的一个目的是生产一种个人护理制品用材料,它不需要多个生产步骤来制作。本发明另一个目的是生产一种个人护理制品用材料,其中相邻纤维层之间具有不明显的边界,具有彼此交络和缠结的纤维,从而可改善相邻层之间的流体传递。It is therefore an object of the present invention to produce a material for personal care products which does not require multiple production steps to make. Another object of the present invention is to produce a material for personal care products in which adjacent fibrous layers have indistinct boundaries, with fibers that intertwine and entangle with each other, thereby improving fluid transfer between adjacent layers.
发明概述Summary of the invention
本发明的目的是通过这样一种个人护理制品用材料达到的,它包括:体侧层,织物单位重量介于约10~约100gsm,密度介于约0.05~约0.5g/cc,包含合成纤维和/或粘合剂;以及持液层,织物单位重量介于约50~约250gsm,密度介于约0.05~约0.5g/cc,包含合成纤维、粘合剂和/或天然纤维,其中任何两个相邻纤维层之间的边界不明显,其中,该相邻层表面或表面附近的纤维在很大程度上互相混杂。The objects of the present invention are achieved by a material for a personal care product comprising: a bodyside layer having a basis weight of about 10 to about 100 gsm and a density of about 0.05 to about 0.5 g/cc comprising synthetic fibers and/or binder; and a liquid-holding layer having a basis weight of about 50 to about 250 gsm and a density of about 0.05 to about 0.5 g/cc, comprising synthetic fibers, binders and/or natural fibers, any of which The boundary between two adjacent fiber layers is indistinct, wherein the fibers at or near the surface of the adjacent layer are largely intermingled with each other.
该材料可任选地包括流体分配层和流体转移层以及衣服侧衬里。其他任选的成分包括超吸收剂以及异味控制化合物,出于美观和流体控制的考虑,这些层还可经过压花。The material may optionally include a fluid distribution layer and a fluid transfer layer and a garment side liner. Other optional ingredients include superabsorbents and odor control compounds. These layers may also be embossed for aesthetics and fluid control.
附图简述Brief description of the drawings
图1表示一种正弦波花纹的个人护理制品用压花图案。Figure 1 shows a sinusoidal pattern embossed pattern for personal care products.
图2表示一种贝壳花纹的个人护理制品用压花图案。Figure 2 shows an embossed pattern for a scalloped personal care product.
定义definition
“一次性”涵盖,使用后便丢弃(用即弃)或者不打算洗涤并再次使用。"Disposable" encompasses items that are either discarded after use (disposable) or not intended to be washed and reused.
“正面”和“背面”在本说明全文中用以指相对于该服装制品本身的关系,而不是指当该服装处于穿戴者身上时服装所采取的任何位置。"Front" and "back" are used throughout this specification in relation to the article of clothing itself, rather than any position the garment assumes when the garment is on the wearer.
“亲水”用来描述能够被接触纤维的含水液体润湿的纤维或纤维表面。材料的润湿程度,又可采用有关液体与材料之间的接触角和表面张力来描述。适合用来测定特定纤维材料可湿性的设备和技术可由Cahn SFA-222表面力分析仪系统,或者实质上等价的系统提供。当采用这种系统测定时,接触角小于90°的纤维被规定为“可湿”或亲水,而接触角等于或大于90°的纤维则规定为“不可湿”或疏水。"Hydrophilic" is used to describe a fiber or fiber surface that is capable of being wetted by aqueous liquids that contact the fiber. The degree of wetting of materials can be described by the contact angle and surface tension between the liquid and the material. Suitable equipment and techniques for determining the wettability of particular fiber materials are provided by the Cahn SFA-222 Surface Force Analyzer system, or a substantially equivalent system. When measured using this system, fibers with contact angles of less than 90° are designated as "wettable" or hydrophilic, while fibers with contact angles of 90° or greater are designated as "non-wettable" or hydrophobic.
“朝内”和“朝外”是指相对于吸收性服装中心而言的部位,具体地说,指横向和/或纵向靠近或远离吸收性服装的纵向和横向中心。"Inwardly" and "outwardly" refer to locations relative to the center of the absorbent garment, specifically, laterally and/or longitudinally toward or away from the longitudinal and lateral center of the absorbent garment.
“层”,当以单数形式使用时,可具有双重含义,即,单个基元或者多个基元。"Layer", when used in the singular, can have the dual meaning, ie, a single element or a plurality of elements.
“液体”是指非颗粒材料,和/或某种材料,它能流动并且可采取将其倒入或放入其中的容器的形状。"Liquid" means a non-particulate material, and/or a material that is capable of flowing and can take the shape of a container into which it is poured or placed.
“液体联通”是指,液体能够从一层迁移到另一层,或者在一层内从一个部位到另一个部位。By "fluid communication" is meant that liquid is able to migrate from one layer to another, or from one location to another within a layer.
“纵向”和“横向”具有其惯用的含义。纵轴位于当放在平面上并完全展开时制品所在平面内,并大致平行于制品穿在身上时把站立的穿戴者对分为左、右各半个身体的垂直平面。横轴位于制品平面内,并大致垂直于纵轴。该制品被画成沿纵向比沿横向长。"Portrait" and "landscape" have their customary meanings. The longitudinal axis lies in the plane of the article when placed on a flat surface and fully extended, and is approximately parallel to the vertical plane that bisects a standing wearer into left and right body halves when the article is worn on the body. The transverse axis lies in the plane of the article and is approximately perpendicular to the longitudinal axis. The article is drawn longitudinally longer than transversely.
“颗粒”,就本发明的意义而言,是指任何例如但不限于下列的几何形式:球形颗粒、纤维或丝、平坦或粗糙化的表面、片状、带状、弦、线状等。"Particle" in the sense of the present invention means any geometric form such as, but not limited to, spherical particles, fibers or filaments, flat or roughened surfaces, sheets, ribbons, strings, threads, etc.
“喷雾”及其变换表述涵盖,通过小孔、喷嘴等强制射出的液体,或呈螺旋丝状的流股,或呈微粒化的颗粒,强制动力包括空气或其他气体施加的压力、重力、或者离心力。喷雾可以是连续或者是不连续的。"Spray" and variations thereof cover a liquid, or a stream in the form of a helical filament, or a stream of micronized particles, which is forced through an orifice, nozzle, etc., by force of air or other gas, gravity, or centrifugal force. The spray can be continuous or discontinuous.
本文所使用的术语“共轭纤维”是指由至少两种聚合物经各自的挤出机挤出,但在一起纺丝形成同一根的纤维。共轭纤维有时也叫做多组分或双组分纤维。所使用的聚合物通常彼此不同,虽然共轭纤维也可以是单组分纤维。这些聚合物在共轭纤维断面上排列在各自位置基本固定、彼此界限鲜明的区域内,并沿共轭纤维的全长连续地延伸。此类共轭纤维的构型(断面排列)可以是,例如皮/芯排列,其中一种聚合物被另一种聚合物包围着,或者可以是并列排列的、扇形排列的,或者是“海-岛”排列的。共轭纤维公开在授予Kaneko等人的美国专利5,108,820、授予Strack等人的美国专利5,336,552及授予Pike等人的美国专利5,382,400中。就双组分纤维而言,聚合物可以以75/25、50/50、25/75或任何其他希望的比例存在。此类纤维还可具有各种各样的形状,如可见诸于授予Hogle等人的美国专利5,277,976以及授予Largman等人的美国专利5,069,970及5,057,368。以上描述非传统形状纤维的专利和申请均全文收作本文的参考。As used herein, the term "conjugate fiber" refers to at least two polymers extruded through separate extruders but spun together to form the same fiber. Conjugate fibers are also sometimes called multicomponent or bicomponent fibers. The polymers used are usually different from each other, although the conjugate fibers can also be monocomponent fibers. These polymers are arranged in substantially fixed and well-defined regions on the cross-section of the conjugate fiber, and extend continuously along the entire length of the conjugate fiber. The configuration (cross-sectional arrangement) of such conjugate fibers may be, for example, a sheath/core arrangement in which one polymer is surrounded by another, or may be side-by-side, fan-shaped, or "sea". -island" arrangement. Conjugate fibers are disclosed in US Patent 5,108,820 to Kaneko et al., US Patent 5,336,552 to Strack et al., and US Patent 5,382,400 to Pike et al. For bicomponent fibers, the polymers may be present in a 75/25, 50/50, 25/75 or any other desired ratio. Such fibers can also have a wide variety of shapes, as seen in US Patent 5,277,976 to Hogle et al. and US Patents 5,069,970 and 5,057,368 to Largman et al. The above patents and applications describing fibers of unconventional shape are hereby incorporated by reference in their entirety.
本文所使用的术语“双成分纤维”是指由至少两种聚合物从同一挤出机以共混物形式挤出形成的纤维。术语“共混物”的定义可见诸于下文。双成分纤维所包含的各种聚合物成分不是排列在纤维横断面上位置相对固定的区内,而且,各种聚合物沿着纤维的整个长度通常不连续,而是,往往形成随机开始并随机结束的微丝(原纤)或原生原纤。双成分纤维有时也被称之为多成分纤维。这一大类纤维在例如授予Gessner的美国专利5,108,827中有所讨论。双组分及双成分纤维还在教科书《聚合物共混物及复合物》,John A.Manson及LeslieH.Sperling主编,版权1976归Plenum Press所有,Plenum出版公司(纽约)的一个分部,IBSN 0-306-30831-2,273~277页。As used herein, the term "bicomponent fiber" refers to a fiber formed by extruding a blend of at least two polymers from the same extruder. The definition of the term "blend" can be found below. The various polymer components contained in bicomponent fibers are not arranged in relatively fixed regions on the cross-section of the fiber, and the various polymers are usually discontinuous along the entire length of the fiber. Instead, they tend to form randomly and start randomly. Ended microfilaments (fibrils) or native fibrils. Biconstituent fibers are also sometimes referred to as multiconstituent fibers. This broad class of fibers is discussed, for example, in US Patent 5,108,827 to Gessner. Bicomponent and bicomponent fibers are also in the textbook Polymer Blends and Composites, edited by John A. Manson and Leslie H. Sperling, copyright 1976 by Plenum Press, a division of Plenum Publishing Company (New York), IBSN 0-306-30831-2, pages 273-277.
“气流成网”是一种熟知的纤维非织造层成形方法。在气流成网过程中,典型长度介于约3~约19mm的短小纤维束被吹过的一股空气流分散并夹带起来,然后沉积到成形网上,通常在真空源的辅助下。随后,无规沉积的纤维借助例如热空气或粘合剂喷雾,彼此粘合在一起。气流成网例如在下列文献中做了讨论:美国专利4,005,957、4,388,056、4,592,708、4,598,441、4,674,996、4,761,258、4,764,325、4,904,440、4,908,175以及5,004,579,德国专利DE3508344 A1、欧洲专利申请85300626.0以及英国专利申请2,191,793。"Airlaid" is a well known method of forming fibrous nonwoven layers. During air-laying, staple fiber bundles, typically between about 3 and about 19 mm in length, are dispersed and entrained by a passing air stream and deposited onto a forming wire, usually with the aid of a vacuum source. The randomly deposited fibers are then bonded to one another by means of, for example, hot air or a spray of adhesive.气流成网例如在下列文献中做了讨论:美国专利4,005,957、4,388,056、4,592,708、4,598,441、4,674,996、4,761,258、4,764,325、4,904,440、4,908,175以及5,004,579,德国专利DE3508344 A1、欧洲专利申请85300626.0以及英国专利申请2,191,793。
“个人护理制品”是指尿布、训练裤、吸收性衬裤、成人失禁用品、绷带及女性卫生制品。"Personal care product" means diapers, training pants, absorbent underpants, adult incontinence products, bandages, and feminine hygiene products.
“女性卫生制品”是指卫生巾或垫。"Feminine hygiene product" means a sanitary napkin or pad.
“靶区”是指正对着穿戴者通常排液的个人护理制品的区域或部位。"Target zone" refers to the area or site of a personal care article that is directed against the wearer where it normally drains.
试验方法experiment method
材料卡规(厚度):材料卡规是材料厚度的量度,采用Starret型蓬松度测定仪在0.05psi条件下测定,以毫米为单位。Material caliper (thickness): Material caliper is the measurement of material thickness, which is measured by Starret type bulkiness tester under the condition of 0.05psi, and the unit is millimeter.
密度:材料的密度是通过将单位面积样品重量即每平方米样品的重量克数(gsm)除以68.9帕下的样品厚度的毫米数,所得结果乘上0.001,便换算为每立方厘米的克数值(g/cc)。共测定3个试样,取平均作为密度值。Density: The density of the material is converted to grams per cubic centimeter by dividing the sample weight per unit area, that is, the weight of the sample in grams per square meter (gsm) by the thickness of the sample in millimeters at 68.9 Pa, and multiplying the result by 0.001 Value (g/cc). A total of 3 samples were measured, and the average value was taken as the density value.
发明详述Detailed description of the invention
个人护理吸收制品包括诸如下列物品:尿布、训练裤、女性卫生制品,如卫生巾、女衬裤衬里及棉塞,失禁服装及用具、绷带等。所有这些制品的大多数基本式样一般包括体侧衬里和外包覆层以及布置在体侧衬里与外包覆层之间的吸收剂芯。一般地,体侧衬里与外包覆层沿周边密封起来,以便将吸收剂芯包封在内,从而能够俘获任何流体并将其保持在吸收剂芯内部。视个人护理吸收制品的具体设计之不同,还可包括其他成分。譬如,该制品可包括诸如弹性侧片、挡液侧边、系紧器件以及流体转移和保持材料的其他层。Personal care absorbent articles include items such as diapers, training pants, feminine hygiene products such as sanitary napkins, panty liners and tampons, incontinence garments and devices, bandages, and the like. The most basic form of all of these articles generally includes a bodyside liner and an outer cover with an absorbent core disposed between the bodyside liner and outer cover. Typically, the bodyside liner is peripherally sealed to the outer cover so as to enclose the absorbent core so that any fluid can be captured and retained within the absorbent core. Depending on the specific design of the personal care absorbent article, other ingredients may also be included. For example, the article may include other layers such as elastic side panels, liquid barrier sides, fastening means, and fluid transfer and retention materials.
有关个人护理制品用材料的讨论可见与本申请共同受让人、同一日提交、代理文件号13303.10的专利申请。有关案例13303.10材料的制造方法的讨论可见共同受让人、共同未决的代理文件号13817的专利申请。A discussion of materials for personal care products can be found in Attorney Docket No. 13303.10, filed on the same date as the common assignee of this application. A discussion of methods of making the materials of Case 13303.10 can be found in co-assigned, co-pending Attorney Docket No. 13817.
本发明是一种个人护理制品用材料,采用一种使生产出的相邻纤维层之间边界或界面不清晰的方式制成。以往的个人护理制品的制造方法一直采取分别制造材料,然后合在一起成为层合物。在此种情况下,相邻纤维层之间的边界比较轮廓鲜明和清晰,常常被用以将各层维系在一起以形成层合物的粘合剂标出。The present invention is a material for personal care products produced in such a way that the boundaries or interfaces between adjacent fibrous layers are produced indistinctly. Previous methods of manufacturing personal care products have been to manufacture the materials separately and then join them together to form a laminate. In such cases, the boundaries between adjacent fibrous layers are more defined and defined, often marked by the adhesive used to hold the layers together to form a laminate.
本发明的材料优选按照气流成网法制成,其中纤维悬浮在气流,优选在空气流中输送,然后沉积在底层物上形成层。本发明的材料由顺序沉积上去的多个层组成。此种材料的顺序沉积可借助多排气流成网法完成。在此种方法中,各个纤维层不是分开制造、单独地稳定化,然后再合在一起成为层合物的,而是一层在另一层上形成的。当然,整个材料必须以某种方式进行稳定化,但是本发明的各个单独层则不需要。稳定化是通过粘合剂的使用实现的,该粘合剂倘若属于热活化型的,显然要求在纤维沉积之后对材料进行热处理。The materials of the present invention are preferably produced according to the airlaid process, wherein the fibers are suspended in an air stream, preferably transported in air, and then deposited on a substrate to form a layer. The materials of the present invention consist of multiple layers deposited sequentially. Sequential deposition of such materials can be accomplished by multi-gas flow-laying. In this method, the individual fibrous layers are not manufactured separately, stabilized individually, and then brought together into a laminate, but are formed one on top of the other. Of course, the entire material must be stabilized in some way, but the individual layers of the present invention do not. Stabilization is achieved through the use of a binder which, if of the heat-activated type, obviously requires a heat treatment of the material after deposition of the fibers.
本发明材料的各个单独纤维层,由于采用气流成网法的结果,包括一些与相邻纤维层的纤维彼此混合或缠结的纤维。气流成网的这一特性以及相邻层之间一般不存在粘合剂,使得相邻层之间边界或界面不是轮廓鲜明和清晰,而是很模糊。Each individual fibrous layer of the material of the present invention, as a result of the airlaid process, includes some fibers which are intermixed or entangled with the fibers of adjacent fibrous layers. This characteristic of airlaid, together with the general absence of adhesive between adjacent layers, makes the boundary or interface between adjacent layers not sharp and clear, but blurry.
与分别生产各层,然后将它们合在一起成为层合物相比,通过多排气流成网法生产材料,具有高得多的成本效益,因此可降低最终消费者的花费。Producing the material by multi-vent airlaying is much more cost-effective than producing the layers separately and then joining them together to form a laminate, thus reducing costs for the end consumer.
本发明材料具有体侧层,任选的流体转移层、持液层以及衣服一侧的层。该材料还可具有分配层或其他任选的层,以提供特殊功能。The material of the present invention has a body side layer, an optional fluid transfer layer, a liquid retention layer and a garment side layer. The material may also have distribution layers or other optional layers to provide specific functions.
体侧层有时亦称作体侧衬里或上片。沿制品的厚度方向,衬里材料是直接接触穿戴者皮肤的层,因此也就是接触来自穿戴者的液体或其他流出物的第1层。该衬里起到隔离穿戴者皮肤与保持在吸收剂结构物中液体的作用,它应当柔顺贴身、手感柔软并且无刺激。The bodyside layer is also sometimes referred to as the bodyside liner or topsheet. Along the thickness of the article, the liner material is the layer that directly contacts the wearer's skin, and therefore is the first layer that contacts liquids or other exudates from the wearer. The liner acts to insulate the wearer's skin from retaining liquids in the absorbent structure, and should conform to the skin, be soft to the touch, and be non-irritating.
体侧层的织物单位重量例如可介于约10.0g/m2(gsm)~约100gsm,密度介于约0.05g/cm3(g/cc)~约0.5g/cc。体侧衬里由合成纤维与粘合剂按大约90/10~约0/100,更具体地说约50/50~约20/80,进一步具体地说约30/70的比例组成。应当指出,优选使用粘合性纤维而不是液体粘合剂,尤其是在粘合剂含量大于10%的情况下。The body side layer may have a basis weight of, for example, about 10.0 g/m 2 (gsm) to about 100 gsm, and a density of about 0.05 g/cm 3 (g/cc) to about 0.5 g/cc. The bodyside liner is composed of synthetic fibers and binder in a ratio of about 90/10 to about 0/100, more specifically about 50/50 to about 20/80, and still more specifically about 30/70. It should be noted that it is preferred to use binder fibers rather than liquid binders, especially if the binder content is greater than 10%.
体侧衬里可利用选定数量的表面活性剂,例如约0.28%TritonX-102表面活性剂进行表面处理或者其他方式的处理,以赋予要求程度的可湿性或亲水性。倘若使用表面活性剂,它可以是内添加剂,或者按照任何传统方式,例如喷涂、刷涂之类的方法在沉积下一层之前施涂上去。The bodyside liner may be surface treated or otherwise treated with a selected amount of surfactant, such as about 0.28% Triton X-102 surfactant, to impart the desired degree of wettability or hydrophilicity. A surfactant, if used, may be an internal additive, or may be applied by any conventional means, such as spraying, brushing, etc., prior to depositing the next layer.
本发明所采用的持液层必须能按照控制的方式从相邻的体侧层吸收液体,以便将液体贮存在不接触身体的地方。适合此种用途的持液材料应具有约50~约250gsm的织物单位重量,约0.05~约0.5g/cc的密度。持液材料包含粘合剂、合成纤维及天然纤维。粘合剂必须以有效量存在,一般介于约3~15wt%,或者更具体地说约10wt%。粘合剂不算在内,合成及天然纤维可按照约0/100~约50/50,更具体地说约10/90~20/80,进一步具体地说约40/60的比例存在。虽然本发明的任何一层均可任选地包含超吸收剂,但是持液层是包含此种成分的最符合逻辑的层。这一层可包含0~85wt%超吸收剂,其含量在计算存在的材料之间比例时应算作天然纤维。The liquid-holding layer employed in the present invention must be capable of absorbing fluid from the adjacent bodyside layer in a controlled manner so as to store fluid away from the body. Liquid-holding materials suitable for this purpose should have a basis weight of from about 50 to about 250 gsm and a density of from about 0.05 to about 0.5 g/cc. Liquid-holding materials include adhesives, synthetic fibers, and natural fibers. The binder must be present in an effective amount, generally between about 3-15 wt%, or more specifically about 10 wt%. Excluding binders, synthetic and natural fibers may be present in a ratio of about 0/100 to about 50/50, more specifically about 10/90 to 20/80, more specifically about 40/60. While any layer of the present invention may optionally contain superabsorbent, the liquid-holding layer is the most logical layer to contain such a component. This layer may contain from 0 to 85% by weight of superabsorbent, the amount of which should be counted as natural fibers when calculating the ratio between the materials present.
按照本发明,可制作任意数目的层,不过,特别有用的附加层是一种第2持液层。此种第2持液层将插入到第1持液层与衣服侧衬里之间并可包含有效量粘合剂,以及,不算粘合剂,约75%天然纤维和约25%超吸收剂纤维。上面已经指出,超吸收剂在计算层内纤维比例时应算作天然纤维,因此这一层中,合成对天然纤维的比例,不算粘合剂,便是0/100。According to the present invention, any number of layers can be formed, however, a particularly useful additional layer is a second liquid-holding layer. Such a second liquid-holding layer will be inserted between the first liquid-holding layer and the garment side liner and may contain an effective amount of binder, and, not counting binder, about 75% natural fibers and about 25% superabsorbent fibers . It has been pointed out above that superabsorbents should be counted as natural fibers when calculating the fiber ratio in the layer, so in this layer, the ratio of synthetic to natural fibers, excluding binder, is 0/100.
衣服侧衬里层,亦称作后片或外包覆层,是距离穿戴者(身体)最远的一层。外包覆层传统上一直由薄热塑性膜制成,例如聚乙烯膜,它对液体应基本不可透过。外包覆层的功能是防止吸收剂结构物中包含的身体流出物打湿或弄脏穿戴者衣服、床单或其他接触个人护理制品的材料。虽然外包覆层可以是例如初始厚度介于约0.5密耳(0.012mm)~约5.0密耳(0.12mm)的聚乙烯薄膜,但优选的是,将外包覆层制作成本发明材料整体的一部分。在这种情况下,优选的是,衣服侧衬里或外包覆层具有约10~约100gsm的织物单位重量,包含约50/50~约0/100比例的合成纤维和粘合剂。The garment side liner, also known as the back panel or outer cover, is the layer furthest from the wearer (body). The outer covering layer has traditionally been made of a thin thermoplastic film, such as polyethylene film, which should be substantially impermeable to liquids. The function of the outer cover is to prevent bodily exudates contained in the absorbent structure from wetting or soiling the wearer's clothing, bed sheets, or other materials that come into contact with the personal care article. While the outer cladding may be, for example, a polyethylene film having an initial thickness ranging from about 0.5 mil (0.012 mm) to about 5.0 mil (0.12 mm), it is preferred that the outer cladding be made integral to the material of the present invention. part. In this case, it is preferred that the garment side liner or outer cover has a basis weight of about 10 to about 100 gsm, comprising synthetic fibers and binder in a ratio of about 50/50 to about 0/100.
外包覆层可经过压花和/或无光处理,以提供美学上令人愉快的外观。用作外包覆层的其他替代构造物包括通过制造或处理赋予了要求程度液体不透性的织造或非织造纤网,或者由织造或非织造织物与热塑性薄膜构成的层合物。外包覆层可任选地由蒸汽或气体可透、微孔“透气性”材料构成,它可透过蒸汽或气体然而对液体则基本不透。聚合物薄膜的透气性例如可这样造成:在聚合物配料中加入填料,然后将填料/聚合物配料挤出为薄膜,随后对薄膜施以足以形成包围着填料颗粒的空洞的拉伸,从而使薄膜变为可透气。一般地,填料用量越高,拉伸程度越大,则透气性程度越大。背衬(后片),在例如以非织造布作为外表面的情况下,还可起到机械系紧件的配合元件的作用。The outer cover can be embossed and/or matte finished to provide an aesthetically pleasing appearance. Other alternative constructions for use as the outer cover include woven or nonwoven webs imparted by fabrication or processing with the desired degree of liquid impermeability, or laminates of woven or nonwoven fabrics and thermoplastic films. The outer cover may optionally be constructed of a vapor or gas permeable, microporous "breathable" material which is permeable to vapor or gas but substantially impermeable to liquids. The air permeability of polymer films can be caused, for example, by adding fillers to the polymer formulation, then extruding the filler/polymer formulation into a film, and then stretching the film sufficiently to form cavities surrounding the filler particles so that The membrane becomes breathable. Generally, the higher the filler level, the greater the degree of stretch, and the greater the degree of breathability. The backing (back panel), in the case of eg a nonwoven as the outer surface, can also function as a cooperating element of the mechanical fastening.
任选的流体转移层,亦称作高峰层(surge layer),它夹在体侧衬里与另一层例如流体分配层或持液层之间并与之处于紧密液体联通的接触状态。流体转移层或高峰层令流体大致沿其Z-方向,即,离开体侧并朝向衣服侧移动。高峰层一般放在体侧衬里内表面(非外露面)的下面相邻位置。优选的是,高峰层的密度介于约0.05g/cc~约0.5g/cc;织物单位重量介于约10~约100gsm。高峰层可以是由合成纤维、粘合剂及天然纤维构成的层,其中粘合剂以有效量存在,而且,不算粘合剂,合成及天然纤维则以约40/60~约10/90的比例存在。An optional fluid transfer layer, also known as a surge layer, is sandwiched between and in fluid tight contact with the bodyside liner and another layer, such as a fluid distribution layer or a liquid retention layer. The fluid transfer layer or peak layer moves fluid generally in its Z-direction, ie away from the body side and towards the garment side. The peak layer is generally placed adjacently below the inner surface (non-exposed surface) of the bodyside liner. Preferably, the peak layer has a density of from about 0.05 g/cc to about 0.5 g/cc; a basis weight of from about 10 to about 100 gsm. The peak layer may be a layer of synthetic fibers, binders, and natural fibers, wherein the binder is present in an effective amount and, not counting the binder, the synthetic and natural fibers are in a ratio of about 40/60 to about 10/90 ratio exists.
任选的分配层可置于持液层上面(朝向穿戴者)并且必须能够将流体从最初沉积点迁移到要求的贮存点。因此,流体分配层,除了允许流体沿Z-方向穿过其本身,而且允许流体沿着X及Y方向迁移。分配应以可接受的速率进行,以便使排液靶区,一般在裆部区域,来得及为下一次到来的排液做好准备。两次排液之间的时间可从只有几分钟直至几小时,通常取决于穿戴者年龄以及具体的个人护理制品。为实现此种传递功能,分配层必须具有高毛细管张力数值。分配材料中的毛细管张力可简单地用8.5g/l盐溶液的平衡垂直芯吸高度来衡量,并应大于15cm。芯吸试验方法包括,将材料的一端垂直地放入到盐溶液中,等待溶液达到平衡,然后测量所达到的高度。制作分配层的材料可由合成及天然纤维构成,其中采用少量粘合剂。An optional distribution layer may be placed on top of the liquid-holding layer (facing the wearer) and must be capable of transferring fluid from the point of initial deposition to the desired point of storage. Thus, the fluid distribution layer, in addition to allowing fluid to pass through itself in the Z-direction, also allows fluid to migrate in the X and Y directions. Dispensing should be done at an acceptable rate so that the target discharge area, typically the crotch area, has time to prepare for the next incoming discharge. The time between discharges can range from just a few minutes up to several hours, usually depending on the age of the wearer and the particular personal care article. To achieve this transfer function, the distribution layer must have a high capillary tension value. Capillary tension in the dispensing material is simply measured by an equilibrium vertical wicking height of 8.5 g/l saline solution and should be greater than 15 cm. The wicking test method involves placing one end of the material vertically in a saline solution, waiting for the solution to equilibrate, and then measuring the height achieved. The material from which the distribution layer is made can consist of synthetic and natural fibers with a small amount of binder.
合成纤维包括由尼龙、聚对苯二甲酸乙二醇酯、人造丝、聚烯烃如聚丙烯、Lyocel再生纤维素制造的那些以及本领域技术人员熟知的任何其他适当合成纤维。此种合成纤维可包括共轭、双成分及均聚物纤维,它们可以是普通短纤维或者其他长度的,以及此类纤维与其他类型纤维的混合物。合成纤维还可包括用于使产品降解的kosmotropes,正如下面所讨论的。Synthetic fibers include those made from nylon, polyethylene terephthalate, rayon, polyolefins such as polypropylene, Lyocel regenerated cellulose, and any other suitable synthetic fibers known to those skilled in the art. Such synthetic fibers may include conjugate, biconstituent and homopolymer fibers, which may be staple or other lengths, and blends of such fibers with other types of fibers. Synthetic fibers may also include kosmotropes for degrading the product, as discussed below.
天然纤维包括纤维素,例如木浆、棉花等。浆粕包括标准软木短纤级,例如Kimberly-Clark公司的Coosa Mills CR-1654;高蓬松添加剂甲醛游离浆粕(HBAFF),由Weyerhaeuser公司(Tacoma,WA)生产,这是一种高温模量交联南方软木浆纤维;以及一种化学交联浆粕纤维,例如Weyerhaeuser NHB416。HBAFF具有一种将卷曲及捻回固定的化学处理剂,另外它还赋予纤维附加的干、湿挺度以及回弹。另一种合适的浆粕是Buckeye HP2浆粕,再一种是IP Supersoft,由International Paper公司出品。合适的人造丝纤维是1.5旦、批号18453的纤维,由Courtaulds纤维公司(Axis,亚拉巴马)出品。Natural fibers include cellulose such as wood pulp, cotton, and the like. Pulps include standard softwood staple fiber grades such as Coosa Mills CR-1654 from the Kimberly-Clark Company; High Loft Additive Formaldehyde Free Pulp (HBAFF) from Weyerhaeuser Company (Tacoma, WA), which is a high linked southern softwood pulp fibers; and a chemically crosslinked pulp fiber such as Weyerhaeuser NHB416. HBAFF has a chemical treatment agent that fixes crimp and twist, and it also imparts additional dry and wet stiffness and resilience to the fiber. Another suitable pulp is Buckeye HP2 pulp, and yet another is IP Supersoft, available from International Paper Company. A suitable rayon fiber is 1.5 denier, Lot No. 18453, available from Courtaulds Fiber Company (Axis, Alabama).
粘合剂包括纤维、液体或其他可热活化的粘合手段。范例粘合剂包括聚烯烃和/或聚酰胺共轭纤维以及液体粘合剂。一种合适的粘合剂是皮/芯共轭纤维,由Trevira公司出品(以前的Hoechst-Celanese)(PO Box 4,Salisbury,NC 28145-0004),商品代号T-255,不过本领域技术人员还知道许多合适的纤维,而且还有许多制造厂家,例如,Chisso and Hercules公司。另一种合适的粘合性纤维由Danaklon公司制造,设在Engdraget 22,KD-6800 Varde(丹麦),是一种2旦共轭PE/PP皮/芯纤维,切断长度6mm。一种合适的液体粘合剂是Kymene557LX粘合剂,由Hercules公司(Wilmington,DE)生产。Adhesives include fibrous, liquid, or other heat-activatable bonding means. Exemplary adhesives include polyolefin and/or polyamide conjugate fibers and liquid adhesives. One suitable binder is sheath/core conjugate fiber available from Trevira Corporation (formerly Hoechst-Celanese) (PO Box 4, Salisbury, NC 28145-0004), trade designation T-255, but those skilled in the art Many suitable fibers are also known and manufactured by, for example, Chisso and Hercules. Another suitable binder fiber is manufactured by Danaklon Corporation, Engdraget 22, KD-6800 Varde (Denmark), which is a 2 denier conjugated PE/PP sheath/core fiber with a cut length of 6 mm. A suitable liquid adhesive is Kymene(R) 557LX adhesive, available from Hercules Corporation (Wilmington, DE).
超吸收剂包括AFA-94-21-5,由道化学公司(Midland MI)生产;道化学的AFA-130-53C;Stockhausen的W77553或Stockhausen的Favor 870以及Sanwet IM 1500超吸收剂,由Trevira公司出品。Superabsorbents include AFA-94-21-5 from Dow Chemical Company (Midland MI); AFA-130-53C from Dow Chemical; W77553 from Stockhausen or Favor 870 from Stockhausen and Sanwet IM 1500 superabsorbent from Trevira Corporation produced.
目前,对于生产“可冲入”或者可投入到传统马桶中并且对于化粪池或市政废水处理系统安全的个人护理制品的关注正与日俱增。提高个人护理制品可生物降解性能的一种方法是生产一种在此类系统中存在的条件下将迅速解体的产品。有多种机理可导致这一结果,但是大多数不合适或者不可靠,会导致产品因时间不恰当而失败,或者说,产品解体需要过分长的时间。Currently, there is a growing interest in producing personal care products that are "flushable," or that can be dropped into a conventional toilet and are safe for septic or municipal wastewater treatment systems. One approach to improving the biodegradability of personal care products is to produce a product that will disintegrate rapidly under the conditions present in such systems. There are multiple mechanisms that can cause this, but most are inappropriate or unreliable, causing the product to fail due to improper timing, or it takes an unduly long time for the product to disintegrate.
可用来在可接受时间限制内诱发水降解性的一种机理是离子敏感性,这里,术语“离子”的含义是指,一种原子或原子的分子键合基团,获得或失去1个或多个电子,从而带有负或正电荷。某些聚合物包含酸基(R-COO-)成分,它们借助氢键维持在一起。在干态,这些聚合物保持为固体。在具有较高离子浓度的水溶液中,例如尿中,聚合物依然保持相对不变。然而,同样的聚合物当随后暴露于较大数量低离子含量的水,例如存在于马桶中的水时,离子浓度将降低,于是氢键开始拆散。当出现这种情况时,聚合物本身将开始在水中解体。具有此种特性的材料被称之为kosmotropes。例如参见美国专利4,419,403,授予Varona,在此全文收作参考。One mechanism that can be used to induce water degradability within acceptable time limits is ion sensitivity, where the term "ion" means an atom or molecularly bonded group of atoms that gains or loses one or Multiple electrons, thus carrying a negative or positive charge. Certain polymers contain acid group (R-COO-) components that are held together by hydrogen bonds. In the dry state, these polymers remain solid. In aqueous solutions with higher ionic concentrations, such as urine, the polymer remains relatively unchanged. However, when the same polymer is subsequently exposed to larger quantities of water with a low ion content, such as that found in toilet bowls, the concentration of ions decreases and the hydrogen bonds begin to break down. When this happens, the polymer itself will start to disintegrate in water. Materials with such properties are called kosmotropes. See, eg, US Patent 4,419,403 to Varona, which is hereby incorporated by reference in its entirety.
例如在共轭纤维中,第1组分聚合物在高离子浓度溶液环境(例如婴儿或成人尿及月经)中保持稳定,可以是磺化聚酯AQ29、AQ38或AQ55,由Eastman化学公司(金斯堡,田纳西)供应。Eastman AQ38聚合物由89mol%间苯二甲酸、11mol%间苯二甲酸磺酸钠、78mol%二甘醇及22mol%1,4-环己烷二甲醇构成。其标称分子量为14,000道尔顿(D),酸值低于2,羟基值低于10,玻璃化转变温度38℃。另一些例子,可举出聚乙烯醇-或聚乙烯醇共聚物与聚丙烯酸或聚甲基丙烯酸掺混,或者聚乙烯基甲基醚与聚丙烯酸或聚甲基丙烯酸掺混的共混物。Eastman系列聚合物在高离子溶液环境中稳定,但是在冲水(大量水)因而降低离子浓度时的马桶水中将迅速解体。Eastman聚合物可与较高熔融温度范围的第2组分聚合物,例如聚乙烯,配对使用。For example, in conjugate fibers, the first component polymer is stable in high ion concentration solution environment (such as infant or adult urine and menses), which can be sulfonated polyester AQ29, AQ38 or AQ55, manufactured by Eastman Chemical Company (gold Fort, Tennessee). Eastman AQ38 polymer is composed of 89 mol% isophthalic acid, 11 mol% sodium sulfoisophthalate, 78 mol% diethylene glycol, and 22 mol% 1,4-cyclohexanedimethanol. It has a nominal molecular weight of 14,000 Daltons (D), an acid value of less than 2, a hydroxyl value of less than 10, and a glass transition temperature of 38°C. Other examples include blends of polyvinyl alcohol or polyvinyl alcohol copolymers with polyacrylic acid or polymethacrylic acid, or polyvinyl methyl ether with polyacrylic acid or polymethacrylic acid. Eastman series polymers are stable in high ionic solution environments, but will disintegrate rapidly in toilet water where flushing (large volumes of water) reduces the ionic concentration. Eastman polymers can be paired with higher melting temperature range 2nd component polymers such as polyethylene.
其他在高离子浓度中稳定的第1组分聚合物包括“(可)诱变的水可分散聚合物”。这意思是,当共轭纤维的第1组分暴露于诱变剂成分,例如硫酸根离子或氯离子且该离子处于普通自来水那样水平的第1浓度,则构成第1组分的聚合物将在不超过30min内分散或解体。可是,当共轭纤维第1组分暴露于通常存在于诸如婴儿或成人尿或月经的第2、较高浓度水平的同一诱变剂成分时,构成第1组分的聚合物却仍保持稳定并且不分散。此种第1组分的适当例子包括水可分散聚酯或聚酰胺聚合物或共聚物,例如全国淀粉与化学公司出品、产品代号70-4395和70-4442的共聚聚酯聚合物。具有包含可诱变、水可分散聚合物的第1组分的共轭纤维,对于通常尿或月经中存在的浓度水平的特定诱变剂成分不敏感,然而当存在同样的诱变剂成分但其浓度处于不同的、较低水平,典型值例如像在大量自来水中那样,如在马桶中时,则高度敏感并在不超过30min内分散。因此,原料是或者加入了可诱变、水可分散聚合物的纤网,当接触到体液排放,例如尿液或月经时,其可分散性不受影响,然而当投入到普通自来水中时则随着共轭纤维第1组分的分散而趋于解体。Other 1st component polymers that are stable at high ionic concentrations include "()mutagenic water dispersible polymers". This means that when the first component of the conjugate fiber is exposed to a mutagen component, such as sulfate ion or chloride ion, at a first concentration of the ion at the level of ordinary tap water, the polymers making up the first component will Disperse or disintegrate within no more than 30 minutes. However, when the conjugate fiber first component is exposed to a second, higher concentration level of the same mutagen component typically found in, for example, infant or adult urine or menses, the polymers that make up the first component remain stable And don't scatter. Suitable examples of such first components include water dispersible polyester or polyamide polymers or copolymers such as the copolyester polymers available from National Starch and Chemical Company, Product Designations 70-4395 and 70-4442. Conjugate fibers having a first component comprising a mutagenic, water-dispersible polymer are insensitive to a particular mutagen component at concentrations normally found in urine or menses, however when the same mutagen component is present but Its concentration is at different, lower levels, typical values such as in large quantities of tap water, such as in toilets, are highly sensitive and disperse within no more than 30 min. Thus, webs that are or incorporate mutagenic, water-dispersible polymers are unaffected in their dispersibility when exposed to bodily fluid discharges, such as urine or menses, but are not affected when placed in ordinary tap water. With the dispersion of the first component of the conjugate fiber tends to disintegrate.
还优选的是,整个材料进行压花处理,优选从体侧衬里这一边。压花效果可以轻到只限于体侧衬里,或者可包括任选的流体转移层及持液层。压花花纹的选择应以达到最大程度致密化为准,这将提高流体的吸入能力及沿整个产品的分散,以及流体沿正面至背面轴线的分布。压花还可为穿戴者提供有关制品容量接近饱和的可视信号,告知应当丢掉,还可用来提供美观方面好处。适当压花图案的例子示于附图中。图1是被称之为正弦波图案的个人护理制品用压花图案;图2是称作贝壳图案的个人护理制品用压花图案。It is also preferred that the entire material is embossed, preferably from the body side lining side. The embossing effect can be so light that it is limited to the bodyside liner, or an optional fluid transfer layer and liquid holding layer can be included. The embossing pattern should be chosen to achieve maximum densification, which will improve fluid intake and distribution throughout the product, as well as fluid distribution along the front-to-back axis. Embossing can also provide a visual signal to the wearer that the article is nearing capacity and should be discarded, and can also be used to provide an aesthetic benefit. Examples of suitable embossing patterns are shown in the accompanying drawings. Figure 1 is an embossed pattern for a personal care product known as a sine wave pattern; Figure 2 is an embossed pattern for a personal care product known as a seashell pattern.
虽然上面仅就本发明少数几个范例实施方案做了详细描述,但是本领域技术人员很容易意识到,在这些范例实施方案基础上,在不偏离本发明新颖说教和优点的前提下,还可做出许多修改。因此,所有这些修改都应包括在下面权利要求所规定的本发明范围之内。在权利要求中,手段加功能的要求旨在涵盖为实施所述功能所描述的结构,而且不仅包括结构等价物而且包括等价结构。譬如,尽管钉子与螺钉,从钉子采取圆柱体表面将木质零件固定在一起而螺钉则利用螺旋表面的意义上,二者不是结构等价物,但是,就固定木质零件的意义上,钉子与螺钉则可以视为等价的结构。Although the above has only been described in detail with respect to a few exemplary embodiments of the present invention, those skilled in the art will readily appreciate that, on the basis of these exemplary embodiments, without departing from the novel teachings and advantages of the present invention, further Many modifications were made. Accordingly, all such modifications are intended to be included within the scope of this invention as defined in the following claims. In the claims, means-plus-function requirements are intended to cover the described structures as performing the recited function and not only structural equivalents but also equivalent structures. For example, although nails and screws are not structural equivalents in the sense that nails take a cylindrical surface to hold wooden parts together and screws use a helical surface, nails and screws can regarded as equivalent structures.
要进一步指出的是,本文所援引的任何专利、申请或出版物,均全文收作本文的参考。It should be further noted that any patent, application or publication cited herein is hereby incorporated by reference in its entirety.
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|---|---|---|---|---|
| CN101132751B (en) * | 2005-03-04 | 2010-11-17 | Sca卫生产品股份公司 | Absorbent article comprising a liquid transfer layer |
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| US10470947B2 (en) | 2012-10-31 | 2019-11-12 | Kimberly-Clark Worldwide, Inc. | Absorbent article with a fluid-entangled body facing material including a plurality of hollow projections |
| US11007093B2 (en) | 2017-03-30 | 2021-05-18 | Kimberly-Clark Worldwide, Inc. | Incorporation of apertured area into an absorbent article |
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| US10610414B2 (en) | 2014-06-18 | 2020-04-07 | Smith & Nephew Plc | Wound dressing and method of treatment |
| GB2555584B (en) | 2016-10-28 | 2020-05-27 | Smith & Nephew | Multi-layered wound dressing and method of manufacture |
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| US4223677A (en) * | 1979-05-11 | 1980-09-23 | Scott Paper Company | Absorbent fibrous structure and disposable diaper including same |
| US5069970A (en) | 1989-01-23 | 1991-12-03 | Allied-Signal Inc. | Fibers and filters containing said fibers |
| JP2682130B2 (en) | 1989-04-25 | 1997-11-26 | 三井石油化学工業株式会社 | Flexible long-fiber non-woven fabric |
| US4904521A (en) * | 1989-05-26 | 1990-02-27 | Kimberly-Clark Corporation | Melt-blown nonwoven wiper |
| US5057368A (en) | 1989-12-21 | 1991-10-15 | Allied-Signal | Filaments having trilobal or quadrilobal cross-sections |
| BR9106316A (en) * | 1990-04-02 | 1993-04-20 | Procter & Gamble | POLYMERIC COMPOSITION, ABSORBENT, PARTICULATE |
| US5277976A (en) | 1991-10-07 | 1994-01-11 | Minnesota Mining And Manufacturing Company | Oriented profile fibers |
| US5382400A (en) | 1992-08-21 | 1995-01-17 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric and method for making same |
| US5336552A (en) | 1992-08-26 | 1994-08-09 | Kimberly-Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer |
| FR2698384B1 (en) * | 1992-11-20 | 1995-02-10 | Peaudouce | Multilayer nonwoven material and absorbent hygiene article comprising such material. |
| SE503657C2 (en) * | 1994-11-07 | 1996-07-29 | Moelnlycke Ab | Device for forming fiber bodies on a continuous air-permeable path through aeration |
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1999
- 1999-03-31 AR ARP990101472A patent/AR018822A1/en unknown
- 1999-04-30 WO PCT/US1999/009404 patent/WO1999056687A1/en not_active Ceased
- 1999-04-30 RU RU2000130706/15A patent/RU2221529C2/en not_active IP Right Cessation
- 1999-04-30 CN CN99805785A patent/CN1299258A/en active Pending
- 1999-04-30 PL PL99343802A patent/PL343802A1/en unknown
- 1999-04-30 ID IDW20002246A patent/ID29460A/en unknown
- 1999-04-30 KR KR1020007012288A patent/KR20010043320A/en not_active Withdrawn
- 1999-04-30 AU AU40701/99A patent/AU740658B2/en not_active Ceased
- 1999-04-30 TR TR2000/03247T patent/TR200003247T2/en unknown
- 1999-04-30 JP JP2000546719A patent/JP2002513636A/en active Pending
- 1999-04-30 BR BR9910172-6A patent/BR9910172A/en not_active IP Right Cessation
- 1999-04-30 EP EP99924127A patent/EP1082079A1/en not_active Withdrawn
- 1999-05-03 CO CO99026684A patent/CO5121071A1/en unknown
- 1999-05-12 TW TW088107115A patent/TW431885B/en not_active IP Right Cessation
-
2000
- 2000-10-20 ZA ZA200005880A patent/ZA200005880B/en unknown
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101132751B (en) * | 2005-03-04 | 2010-11-17 | Sca卫生产品股份公司 | Absorbent article comprising a liquid transfer layer |
| US11491058B2 (en) | 2012-10-31 | 2022-11-08 | Kimberly-Clark Worldwide, Inc. | Absorbent article with a fluid entangled body facing material including a plurality of projections |
| CN104884014A (en) * | 2012-10-31 | 2015-09-02 | 金伯利-克拉克环球有限公司 | Absorbent article |
| CN104994821B (en) * | 2012-10-31 | 2019-09-13 | 金伯利-克拉克环球有限公司 | absorbent product |
| US10470947B2 (en) | 2012-10-31 | 2019-11-12 | Kimberly-Clark Worldwide, Inc. | Absorbent article with a fluid-entangled body facing material including a plurality of hollow projections |
| US10478354B2 (en) | 2012-10-31 | 2019-11-19 | Kimberly-Clark Worldwide, Inc. | Absorbent article with a fluid-entangled body facing material including a plurality of hollow projections |
| US12029633B2 (en) | 2012-10-31 | 2024-07-09 | Kimberly-Clark Worldwide, Inc. | Absorbent article with a fluid entangled body facing material including a plurality of projections |
| US10070999B2 (en) | 2012-10-31 | 2018-09-11 | Kimberly-Clark Worldwide, Inc. | Absorbent article |
| US11365495B2 (en) | 2017-02-28 | 2022-06-21 | Kimberly-Clark Worldwide, Inc. | Process for making fluid-entangled laminate webs with hollow projections and apertures |
| US11007093B2 (en) | 2017-03-30 | 2021-05-18 | Kimberly-Clark Worldwide, Inc. | Incorporation of apertured area into an absorbent article |
| US11998430B2 (en) | 2017-03-30 | 2024-06-04 | Kimberly-Clark Worldwide, Inc. | Incorporation of apertured area into an absorbent article |
| US12138143B2 (en) | 2018-11-30 | 2024-11-12 | Kimberly-Clark Worldwide, Inc. | Three-dimensional nonwoven materials and methods of manufacturing thereof |
| US12232939B2 (en) | 2018-11-30 | 2025-02-25 | Kimberly-Clark Worldwide, Inc. | Three-dimensional nonwoven materials and methods of manufacturing thereof |
| US12268584B2 (en) | 2018-11-30 | 2025-04-08 | Kimberly-Clark Worldwide, Inc. | Three-dimensional nonwoven materials and methods of manufacturing thereof |
| US12268583B2 (en) | 2018-11-30 | 2025-04-08 | Kimberly-Clark Worldwide, Inc. | Three-dimensional nonwoven materials and methods of manufacturing thereof |
| US12350134B2 (en) | 2018-11-30 | 2025-07-08 | Kimberly-Clark Worldwide, Inc. | Three-dimensional nonwoven materials and methods of manufacturing thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| AU740658B2 (en) | 2001-11-08 |
| TR200003247T2 (en) | 2001-03-21 |
| BR9910172A (en) | 2001-01-30 |
| KR20010043320A (en) | 2001-05-25 |
| ZA200005880B (en) | 2001-05-23 |
| TW431885B (en) | 2001-05-01 |
| PL343802A1 (en) | 2001-09-10 |
| ID29460A (en) | 2001-08-30 |
| RU2221529C2 (en) | 2004-01-20 |
| AR018822A1 (en) | 2001-12-12 |
| JP2002513636A (en) | 2002-05-14 |
| WO1999056687A1 (en) | 1999-11-11 |
| AU4070199A (en) | 1999-11-23 |
| EP1082079A1 (en) | 2001-03-14 |
| CO5121071A1 (en) | 2002-01-30 |
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