CN1298798C - Ink for ink jet printer - Google Patents
Ink for ink jet printer Download PDFInfo
- Publication number
- CN1298798C CN1298798C CNB2005100126513A CN200510012651A CN1298798C CN 1298798 C CN1298798 C CN 1298798C CN B2005100126513 A CNB2005100126513 A CN B2005100126513A CN 200510012651 A CN200510012651 A CN 200510012651A CN 1298798 C CN1298798 C CN 1298798C
- Authority
- CN
- China
- Prior art keywords
- ink
- inkjet printer
- sodium
- colorant
- printer ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 12
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910021538 borax Inorganic materials 0.000 claims abstract description 11
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 11
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 11
- AVQQQNCBBIEMEU-UHFFFAOYSA-N 1,1,3,3-tetramethylurea Chemical compound CN(C)C(=O)N(C)C AVQQQNCBBIEMEU-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003086 colorant Substances 0.000 claims abstract 5
- GWQWBFBJCRDINE-UHFFFAOYSA-M sodium;carbamodithioate Chemical compound [Na+].NC([S-])=S GWQWBFBJCRDINE-UHFFFAOYSA-M 0.000 claims abstract 3
- 239000008367 deionised water Substances 0.000 claims description 14
- 229910021641 deionized water Inorganic materials 0.000 claims description 14
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 claims description 5
- 229950004394 ditiocarb Drugs 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- GSFSVEDCYBDIGW-UHFFFAOYSA-N 2-(1,3-benzothiazol-2-yl)-6-chlorophenol Chemical compound OC1=C(Cl)C=CC=C1C1=NC2=CC=CC=C2S1 GSFSVEDCYBDIGW-UHFFFAOYSA-N 0.000 claims description 4
- -1 dihydroxyethyl dithiocarbamate Sodium Thiocarbamate Chemical compound 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- UJMBCXLDXJUMFB-GLCFPVLVSA-K tartrazine Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-GLCFPVLVSA-K 0.000 claims description 3
- 235000012756 tartrazine Nutrition 0.000 claims description 3
- 239000004149 tartrazine Substances 0.000 claims description 3
- DHQJMKJYFOHOSY-UHFFFAOYSA-L disodium 4-amino-3-[[4-[4-[(2,4-diaminophenyl)diazenyl]-3-methylphenyl]-2-methylphenyl]diazenyl]-5-oxido-6-phenyldiazenyl-7-sulfonaphthalene-2-sulfonate Chemical compound [Na+].[Na+].Cc1cc(ccc1N=Nc1ccc(N)cc1N)-c1ccc(N=Nc2c(N)c3c(O)c(N=Nc4ccccc4)c(cc3cc2S([O-])(=O)=O)S([O-])(=O)=O)c(C)c1 DHQJMKJYFOHOSY-UHFFFAOYSA-L 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000012466 permeate Substances 0.000 description 4
- 239000006184 cosolvent Substances 0.000 description 3
- UQJQVUOTMVCFHX-UHFFFAOYSA-L nabam Chemical compound [Na+].[Na+].[S-]C(=S)NCCNC([S-])=S UQJQVUOTMVCFHX-UHFFFAOYSA-L 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- LBWCDROIOCXGGV-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)ethanol Chemical compound OCCC1=NC=NC=N1 LBWCDROIOCXGGV-UHFFFAOYSA-N 0.000 description 2
- AXDJCCTWPBKUKL-UHFFFAOYSA-N 4-[(4-aminophenyl)-(4-imino-3-methylcyclohexa-2,5-dien-1-ylidene)methyl]aniline;hydron;chloride Chemical compound Cl.C1=CC(=N)C(C)=CC1=C(C=1C=CC(N)=CC=1)C1=CC=C(N)C=C1 AXDJCCTWPBKUKL-UHFFFAOYSA-N 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
本发明提供一种包含着色剂、EDTA、1，1，3，3-四甲基脲、二硫代氨基甲酸钠、异丙醇和硼砂的喷墨打印机墨水。该墨水长期存放后，没有不溶物出现，不堵塞喷嘴，经三年试用，打印的文字、图像均匀、清晰，且遇水不褪色。本发明的墨水生产方法简单，制造成本低。The invention provides an inkjet printer ink comprising colorant, EDTA, 1,1,3,3-tetramethylurea, sodium dithiocarbamate, isopropanol and borax. After the ink is stored for a long time, there will be no insoluble matter, and the nozzle will not be blocked. After three years of trial, the printed characters and images are uniform and clear, and they will not fade when exposed to water. The ink production method of the invention is simple and the production cost is low.
Description
Technical field
The present invention relates to the ink that a kind of ink-jet printer is used, a kind of non-fading ink jet ink composition of chance water that comprises tinting material of saying so more specifically.
Background technology
Generally use along with PC, the raising of ink-jet printer resolving power and the improvement of print quality, for industry, commercial, especially domestic consumer, reducing the printer cost is the urgent market requirement, by the existing market situation, and a family expenses ink-jet printer, price is hundreds of units to thousand yuan, but a box ink needs 200 yuan.One box ink often uses for some time, when also not using up, needs to change because of the plug nozzle phenomenon occurring, as seen prevents plug nozzle, is one of measure that guarantees print quality, reduction printing cost.
In order to guarantee ink-jet printer ink quality, except that tinting material, comprise cosolvent, permeate agent and wetting agent etc. in the composition for ink usually.For example the Chinese patent (application number 981080078.2) of U.S. Lexmark International Inc application is with 1, and the 2-alkyl diol is a permeate agent, and organopolysiloxane is a wetting agent, is cosolvent with replacement and unsubstituted lactan (preferred pyrrolidone).Specific embodiment is as follows:
| Component | Weight % |
| Tinting material | 3.25 |
| EDTA | 0.01 |
| 2-Pyrrolidone | 7.5 |
| TEG | 12.5 |
| 1, the 2-hexylene glycol | 4.0 |
| 1,2-benzo-isothiazoline-3-ketone | 0.2 |
| Sodium Tetraborate | 0.2 |
| Organopolysiloxane | 0.5 |
| Deionized water | Surplus |
Comprise that glycol ether (or propylene glycol), glycerol are cosolvent in the component of the disclosed composition for ink of another Chinese patent (application number 02115137.7), polyvinylpyrrolidone is a dispersion agent, and SJFC is a permeate agent, and three (hydroxyethyl) s-triazine is a sanitas.Specific embodiment is as follows:
| Component | Weight % |
| Tinting material | 2.5-9 |
| Deionized water | 40-70 |
| Glycol ether (or propylene glycol) | 10-25 |
| Glycerol | 5-15 |
| Polyvinylpyrrolidone | 0.5-2 |
| Ethylene glycol monoethyl ether | 4-8 |
| Permeate agent SJFC | 0.5-1.2 |
| Three (hydroxyethyl) s-triazine | 0.1-0.2 |
| Water-based silicone oil | 2-4 |
The composition for ink of above patent disclosure, though guaranteed the ink quality, the ink manufacturing cost is higher.
Summary of the invention
The ink that the object of the present invention is to provide a kind of printer to use is done typescripts soon, and chance water is colour-fast, and long-term storage re-uses, also nonchoking nozzle, and low cost of manufacture.
For achieving the above object, a kind of ink for ink-jet printer provided by the invention is characterized in that components based on weight percentage comprises:
Composition weight (%)
Tinting material 2.0～3.5
EDTA 0.01
1,1,3,3-tetramethyl-urea 6～8
Nabam 2～3
Virahol 6～8
Borax 0.1～0.2
The deionized water surplus
Described tinting material is: sun blue 199, directly yellow 23, acid yellow 23, fuchsin 93A, Food Red 11 or directly black 154.
Described nabam is: Sodium dimethyldithiocarbamate 40min, Thiocarb or dihydroxy ethyl nabam.
The preparation method of ink for ink-jet printer of the present invention comprises the steps: earlier will other components except that tinting material to measure in accordance with regulations and joins in the deionized water, stirs 10-30 minute under the room temperature; And then the tinting material of adding specified amount, continue at room temperature to stir 0.5-1 hour, left standstill 8-12 hour; Use the sand core funnel suction filtration, obtain the purpose product.Be filled in the print cartridge then.
That raw material nabam used in the present invention has is wetting, performances such as molten and sterilization altogether, its employing cost that not only economizes in raw materials, and improved product performance.After the ink long-term storage of the present invention, there is not insolubles to occur, nonchoking nozzle, on probation through 3 years, literal, the image of printing are even, clear, and chance water is colour-fast.
Embodiment
Embodiment 1
Composition weight (%)
Direct blue 199 3
EDTA 0.01
1,1,3,3-tetramethyl-urea 6
Thiocarb 3
Virahol 6
Borax 0.1
The deionized water surplus
Preparation method: earlier will other components except that tinting material measure in accordance with regulations and join in the deionized water, stirred 10 minutes under the room temperature; And then the tinting material of adding specified amount, continue at room temperature to stir 1 hour, left standstill 12 hours; Use the sand core funnel suction filtration, obtain the purpose product.Be filled in the print cartridge then.
Embodiment 2
Composition weight (%)
Direct blue 199 3.5
EDTA 0.01
1,1,3,3-tetramethyl-urea 7
Dihydroxy ethyl nabam 2
Virahol 8
Borax 0.2
The deionized water surplus
Embodiment 3
Composition weight (%)
Fuchsin 93A 2
EDTA 0.01
1,1,3,3-tetramethyl-urea 8
Sodium dimethyldithiocarbamate 40min 2.5
Virahol 7
Borax 0.15
The deionized water surplus
Embodiment 4
Composition weight (%)
Direct yellow 23 3
EDTA 0.01
1,1,3,3-tetramethyl-urea 7
Dihydroxy ethyl nabam 2
Virahol 7
Borax 0.1
The deionized water surplus
Embodiment 5
Composition weight (%)
Acid yellow 23 3.2
EDTA 0.01
1,1,3,3-tetramethyl-urea 8
Sodium dimethyldithiocarbamate 40min 2.5
Virahol 8
Borax 0.2
The deionized water surplus
Embodiment 6
Composition weight (%)
Food Red 11 3
EDTA 0.01
1,1,3,3-tetramethyl-urea 7
Thiocarb 2
Virahol 8
Borax 0.15
The deionized water surplus
Embodiment 7
Composition weight (%)
Directly deceive 154 2.8
EDTA 0.01
1,1,3,3-tetramethyl-urea 7
Thiocarb 2
Virahol 8
Borax 0.2
The deionized water surplus
All embodiment preparation methods are all with embodiment 1.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100126513A CN1298798C (en) | 2005-07-05 | 2005-07-05 | Ink for ink jet printer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100126513A CN1298798C (en) | 2005-07-05 | 2005-07-05 | Ink for ink jet printer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1715344A CN1715344A (en) | 2006-01-04 |
| CN1298798C true CN1298798C (en) | 2007-02-07 |
Family
ID=35821518
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100126513A Expired - Fee Related CN1298798C (en) | 2005-07-05 | 2005-07-05 | Ink for ink jet printer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1298798C (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6466120A (en) * | 1987-09-07 | 1989-03-13 | Lederle Japan Ltd | Active oxygen production increaser |
| JPH05345872A (en) * | 1992-06-15 | 1993-12-27 | Canon Inc | Recording medium and recording method solid at room temperature |
| CN1239727A (en) * | 1999-06-14 | 1999-12-29 | 洛阳石化聚丙烯有限责任公司 | Ink for ink-jet printer |
| CN1504522A (en) * | 2002-11-28 | 2004-06-16 | ������������ʽ���� | Black ink composition, ink set, recording method and recording material |
-
2005
- 2005-07-05 CN CNB2005100126513A patent/CN1298798C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6466120A (en) * | 1987-09-07 | 1989-03-13 | Lederle Japan Ltd | Active oxygen production increaser |
| JPH05345872A (en) * | 1992-06-15 | 1993-12-27 | Canon Inc | Recording medium and recording method solid at room temperature |
| CN1239727A (en) * | 1999-06-14 | 1999-12-29 | 洛阳石化聚丙烯有限责任公司 | Ink for ink-jet printer |
| CN1504522A (en) * | 2002-11-28 | 2004-06-16 | ������������ʽ���� | Black ink composition, ink set, recording method and recording material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1715344A (en) | 2006-01-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070207 |