CN1293160C - Watermark-free heat transfer printing adhesive - Google Patents
Watermark-free heat transfer printing adhesive Download PDFInfo
- Publication number
- CN1293160C CN1293160C CNB2005100378552A CN200510037855A CN1293160C CN 1293160 C CN1293160 C CN 1293160C CN B2005100378552 A CNB2005100378552 A CN B2005100378552A CN 200510037855 A CN200510037855 A CN 200510037855A CN 1293160 C CN1293160 C CN 1293160C
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- CN
- China
- Prior art keywords
- portions
- water
- transfer printing
- add
- pvp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000010023 transfer printing Methods 0.000 title claims abstract description 24
- 239000000853 adhesive Substances 0.000 title claims description 8
- 230000001070 adhesive effect Effects 0.000 title claims description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 22
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 22
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 235000010338 boric acid Nutrition 0.000 claims abstract description 17
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 13
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims abstract description 13
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 13
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims abstract description 12
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims abstract description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 11
- -1 polyoxyethylene Polymers 0.000 claims abstract description 11
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 6
- 239000004327 boric acid Substances 0.000 claims description 16
- 239000001587 sorbitan monostearate Substances 0.000 claims description 12
- 229940035048 sorbitan monostearate Drugs 0.000 claims description 12
- 235000011076 sorbitan monostearate Nutrition 0.000 claims description 12
- 239000004160 Ammonium persulphate Substances 0.000 claims description 11
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 11
- 239000012467 final product Substances 0.000 claims description 10
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000007599 discharging Methods 0.000 claims description 5
- 230000000630 rising effect Effects 0.000 claims description 5
- 235000010265 sodium sulphite Nutrition 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims 1
- 239000003292 glue Substances 0.000 abstract description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 abstract description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 229960002645 boric acid Drugs 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 abstract 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 abstract 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 abstract 1
- 239000000047 product Substances 0.000 description 5
- 238000004132 cross linking Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000012797 qualification Methods 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002313 adhesive film Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention discloses non-watermark heat transfer printing glue which is used in heat transfer technology for cementing action, and makes the color on transfer paper completely get through a transfer printing rubber film up to materials which need transfer printing. A recipe of the present invention comprises 1000 portions of water, 100 to 150 portions of polyvinyl alcohol 0588, 20 to 30 portions of polyvinylpyrrolidone, 3 to 4.5 portions of boracic acid, 30 to 80 portions of acrylamide, 20 to 50 portions of glycerol, 0.05 to 0.2 portions of ammonium persulfate, 0.05 to 0.2 portions of sodium bisulfite, 2 to 4 portions of sodium dodecylbenzene sulfonate, 2 to 4 portions of sorbitan monooctadecanoate and 2 to 4 portions of polyoxyethylene alkylphenol ether. The present invention has the advantages that compared with similar products, one-time transfer printing qualified rate is increased from 80 to 99 %. The present invention is widely used for being coated on security doors, fireproof doors, iron furniture, filing cabinets, profiles, wooden furniture, ceramics, etc. and among pieces of transfer paper with all kinds of patterns and is an improved product in industry.
Description
Technical field
The present invention relates to a kind of tackiness agent, specifically relate to the watermark-free heat transfer printing adhesive between a kind of transfer paper that is coated in materials such as antitheft door, fire door, iron furniture, file cabinet, section bar, wood furniture, pottery and various patterns.
Background technology
Along with improving constantly of standard of living, people to life goods and environment to beautify requirement more and more higher, the therefore various decoration doors that have a pattern, furniture, cabinet, Al-alloy products, pottery etc. continue to bring out.The common hot transfer printing glue of common seal that adopts carries out adhesive transfer on door, furniture, cabinet, Al-alloy products, the pottery and the transfer paper that will be painted with various patterns sticks to.The hot transfer printing glue that uses on the current market adopts the pure and mild auxiliary agent of common polythene to form merely, forming through high temperature (150 °-180 ℃) transfer printing rear section can't the dissolved gum trace and cause that to clean the difficulty influence attractive in appearance, because the little heap glue that on slick seven, easily forms of traditional transfer printing glue surface tension, make that the decorative pattern of transfer printing is imperfect, and can't be removed with transfer paper by glued membrane behind the high temperature, cause peeling difficulty, make disposable transfer printing qualification rate low, increase production cost.
Summary of the invention
In order to overcome above-indicated technical problem, basic goal of the present invention is: proposed to play bonding effect in caloric transfer printing technology, can make color on the transfer paper fully by a kind of watermark-free heat transfer printing adhesive of transfer printing adhesive film on the material of required transfer printing again.
Technical scheme of the present invention is achieved in that a kind of watermark-free heat transfer printing adhesive, and its technical recipe is:
1000 parts in water;
Polyvinyl alcohol 0588
100-150 part;
Polyvinylpyrolidone (PVP)
20-30 part;
Boric acid H
3BO
33-4.5 part;
Acrylamide
30-80 part;
Ammonium persulphate (NH
4)
2S
2O
40.05-0.2 part;
Sodium bisulfite NaHSO
30.05-0.2 part;
Glycerol
20-50 part
Sodium dodecylbenzene sulfonate
2-4 part;
Sorbitan monostearate
2-4 part;
Alkylphenol polyoxyethylene
2-4 part.
Its technological operation step is as follows:
The first step: dissolving is with crosslinked
With 890 parts in water, polyvinyl alcohol 0588 (PVA) is that 100-150 part, Polyvinylpyrolidone (PVP) (PVP) 20-30 part, boric acid 3-4.5 part add in 1.5 tons the reactor of band stirrer, rising temperature for dissolving, 80 °-85 ℃ are incubated 1.5 hours, up to dissolving fully, at dissolved simultaneously, boric acid has been finished the crosslinking reaction with polyvinyl alcohol, and dissolving is not had influence.
Second step: polyreaction
When being cooled to 52 °-54 ℃,, stirred 10-30 minute, add the ammonium persulfate solution that is made into 5 parts of water, 0.05-0.2 part ammonium persulphate, initiated polymerization, the about 1.5-2.5 of polymerization hour again disposable adding after 100 parts of dissolvings of acrylamide 30-80 part water distribution.
The 3rd step: end polyreaction
Add the sodium sulfite solution that is made into 5 parts of water, 0.05-0.2 part sodium bisulfite, get final product termination reaction.
The 4th step: add mixed aid
Add glycerol 20-50 part, Sodium dodecylbenzene sulfonate 2-4 part, sorbitan monostearate 2-4 part, mix half an hour after, get final product discharging below 40 ℃.
Above raw material is all bought from Suzhou industrial chemicals supply and marketing company.
Protective colloid in the above-mentioned prescription---PVP is a Polyvinylpyrolidone (PVP), be a kind of non-ionic macromolecule compound, have film-forming properties and water absorbability, water white transparency, its water absorbability is stronger than PVA, adds polymerization single polymerization monomer on this basis---and acrylamide can reduce cost; And adding film coalescence aid---glycerol can make glued membrane softness, tack good; Boric acid is a kind of PVA linking agent, and is water insoluble because the PVA film is heated to meeting flavescence more than 160 ℃, and crosslinked PVA solution glued membrane can improve the flavescence temperature, satisfies the needs of transfer printing temperature; The surface tension modifier of forming by Sodium dodecylbenzene sulfonate, sorbitan monostearate, alkylphenol polyoxyethylene, be in order to change the surface tension of glue, make glue on slick seven and unlikely contraction, so both can improve the qualification rate of transfer printing, glue-line can be adsorbed on again and tear away together on the transfer paper and do not stay the glue trace, because the singularity of this prescription, also used water is cleaned easily.Generally when transfer printing, use after can adding the mixed of water 1: 2-5.
Below be the comparison sheet of the present invention and like product:
| Solid content % | Disposable transfer printing qualification rate % | Blending ratio with water | |
| The Zhejiang area like product | 11-12 | 80 | 1∶1.5-2 |
| Product of the present invention | 15-21 | ＞99 | 1∶2-5 |
Embodiment
Embodiment one:
Technical recipe of the present invention is: water 1000kg; Polyvinyl alcohol 0588 is 100kg; Polyvinylpyrolidone (PVP) 25kg; Boric acid 3kg; Acrylamide 50kg; Ammonium persulphate 0.06kg; Sodium bisulfite 0.06kg; Glycerol 20kg; Sodium dodecylbenzene sulfonate 3.3kg; Sorbitan monostearate 3.3kg; Alkylphenol polyoxyethylene 3.3kg.
Its technological operation step is as follows:
The first step: dissolving is with crosslinked
With water 890kg, polyvinyl alcohol 0588 is that 100kg, Polyvinylpyrolidone (PVP) 25kg, boric acid 3kg add in 1.5 tons the reactor of band stirrer, rising temperature for dissolving, 80 °-85 ℃ are incubated 1.5 hours, up to dissolving fully, at dissolved simultaneously, boric acid has been finished the crosslinking reaction with polyvinyl alcohol, and dissolving is not had influence.
Second step: polyreaction
When being cooled to 52 °-54 ℃, acrylamide 50kg, water 100kg are made into the disposable adding of liquid, mixed 10-30 minute, add again by water 5kg, 0.06 ammonium persulphate and be made into ammonium persulfate solution, initiated polymerization, the about 1.5-2.5 of polymerization hour.
The 3rd step: end polyreaction
Adding gets final product termination reaction by the sodium sulfite solution that water 5kg, 0.06 sodium bisulfite are made into.
The 4th step: add mixed aid
Add glycerol 20kg, Sodium dodecylbenzene sulfonate 3.3kg, sorbitan monostearate 3.3kg, after alkylphenol polyoxyethylene 3.3kg mixes half an hour, get final product discharging below 40 ℃.
Embodiment two:
Technical recipe of the present invention is: water 1000kg; Polyvinyl alcohol 0588 is 120kg; Polyvinylpyrolidone (PVP) 25kg; Boric acid 3.5kg; Acrylamide 35kg; Ammonium persulphate 0.08kg; Sodium bisulfite 0.08kg; Glycerol 45kg; Sodium dodecylbenzene sulfonate 3.2kg; Sorbitan monostearate 3.2kg; Alkylphenol polyoxyethylene 3.2kg.
Its technological operation step is as follows:
The first step: dissolving is with crosslinked
With water 890kg, polyvinyl alcohol 0588 is that 120kg, Polyvinylpyrolidone (PVP) 25kg, boric acid 3.5kg add in 1.5 tons the reactor of band stirrer, rising temperature for dissolving, 80 °-85 ℃ are incubated 1.5 hours, up to dissolving fully, at dissolved simultaneously, boric acid has been finished the crosslinking reaction with polyvinyl alcohol, and dissolving is not had influence.
Second step: polyreaction
When being cooled to 52 °-54 ℃, acrylamide 35kg, water 100kg are made into the disposable adding of liquid, dissolved 10-30 minute, add the ammonium persulfate solution that is made into by water 5kg, ammonium persulphate 0.08kg again, initiated polymerization, the about 1.5-2.5 of polymerization hour.
The 3rd step: end polyreaction
Adding gets final product termination reaction by the sodium sulfite solution that water 5kg, sodium bisulfite 0.08kg are made into.
The 4th step: add mixed aid
Add glycerol 45kg, Sodium dodecylbenzene sulfonate 3.2kg, sorbitan monostearate 3.2kg, after alkylphenol polyoxyethylene 3.2kg mixes half an hour, get final product discharging below 40 ℃.
Embodiment three:
Technical recipe of the present invention is: water 1000kg; Polyvinyl alcohol 0588 is 150kg; Polyvinylpyrolidone (PVP) 20kg; Boric acid 4.5kg; Acrylamide 30kg; Ammonium persulphate 0.1kg; Sodium bisulfite 0.1kg; Glycerol 50kg; Sodium dodecylbenzene sulfonate 2kg; Sorbitan monostearate 2kg; Alkylphenol polyoxyethylene 2kg.
Its technological operation step is as follows:
The first step: dissolving is with crosslinked
With water 890kg, polyvinyl alcohol 0588 is that 150kg, Polyvinylpyrolidone (PVP) 20kg, boric acid 4.5kg add in 1.5 tons the reactor of band stirrer, rising temperature for dissolving, 80 °-85 ℃ are incubated 1.5 hours, up to dissolving fully, at dissolved simultaneously, boric acid has been finished the crosslinking reaction with polyvinyl alcohol, and dissolving is not had influence.
Second step: polyreaction
When being cooled to 52 °-54 ℃, acrylamide 30kg, water 100kg are made into the disposable adding of liquid, dissolved 10-30 minute, add the ammonium persulfate solution that is made into by water 5kg, ammonium persulphate 0.1kg again, initiated polymerization, the about 1.5-2.5 of polymerization hour.
The 3rd step: end polyreaction
Adding gets final product termination reaction by the sodium sulfite solution that water 5kg, sodium bisulfite 0.1kg are made into.
The 4th step: add mixed aid
Add glycerol 50kg, Sodium dodecylbenzene sulfonate 2kg, sorbitan monostearate 2kg, after alkylphenol polyoxyethylene 2kg mixes half an hour, get final product discharging below 40 ℃.
Claims (2)
1. watermark-free heat transfer printing adhesive, it is characterized in that: this prescription is 1000 parts in water by weight; Polyvinyl alcohol 0588 is 100-150 part; Polyvinylpyrolidone (PVP) 20-30 part; Boric acid 3-4.5 part; Acrylamide 30-80 part; Glycerol 20-50 part; Ammonium persulphate 0.05-0.2 part; Sodium bisulfite 0.05-0.2 part; Sodium dodecylbenzene sulfonate 2-4 part; Sorbitan monostearate 2-4 part; Alkylphenol polyoxyethylene 2-4 part;
Its technological operation step is as follows:
A: dissolving is with crosslinked: with 890 parts in water, polyvinyl alcohol 0588 (PVA) is in 100-150 part, Polyvinylpyrolidone (PVP) (PVP) 20-30 part, the boric acid 3-4.5 part adding reactor, rising temperature for dissolving, and 80-85 ℃ is incubated 1.5 hours, up to dissolving fully;
B: polyreaction: when being cooled to 52-54 ℃,, stirred 10-30 minute, add the ammonium persulfate solution that is made into 5 parts of water, 0.05-0.2 part ammonium persulphate, initiated polymerization again with disposable adding after 100 parts of dissolvings of acrylamide 30-80 part water distribution;
C: end polyreaction: add the sodium sulfite solution that is made into 5 parts of water, 0.05-0.2 part sodium bisulfite, get final product termination reaction;
D: add mixed aid: add glycerol 20-50 part, Sodium dodecylbenzene sulfonate 2-4 part, sorbitan monostearate 2-4 part, stir, get final product discharging below 40 ℃.
2. watermark-free heat transfer printing adhesive according to claim 1 is characterized in that: this prescription is water 1000kg by weight; Polyvinyl alcohol 0588 is 120kg; Polyvinylpyrolidone (PVP) 25kg; Boric acid 3.5kg; Acrylamide 35kg; Ammonium persulphate 0.08kg; Sodium bisulfite 0.08kg; Glycerol 45kg; Sodium dodecylbenzene sulfonate 3.2kg; Sorbitan monostearate 3.2kg; Alkylphenol polyoxyethylene 3.2kg.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100378552A CN1293160C (en) | 2005-02-25 | 2005-02-25 | Watermark-free heat transfer printing adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100378552A CN1293160C (en) | 2005-02-25 | 2005-02-25 | Watermark-free heat transfer printing adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1670101A CN1670101A (en) | 2005-09-21 |
| CN1293160C true CN1293160C (en) | 2007-01-03 |
Family
ID=35041552
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100378552A Expired - Fee Related CN1293160C (en) | 2005-02-25 | 2005-02-25 | Watermark-free heat transfer printing adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1293160C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102757747B (en) * | 2012-08-06 | 2014-02-05 | 河南中医学院 | Aldehyde-free odorless environment-friendly and transparent polyvinyl alcohol (PVA) glue and preparation method thereof |
| CN105504821A (en) * | 2016-01-13 | 2016-04-20 | 宁波创源文化发展股份有限公司 | Base glue for glitter powder pad printing film processing |
| CN108329412B (en) * | 2017-01-20 | 2019-07-02 | 中国科学院化学研究所 | A kind of polyvinyl alcohol ester benzene sulfonate and its synthesis method, printing hydrophilic plate and application and printing plate |
| CN119081599B (en) * | 2024-08-12 | 2025-11-11 | 福建蓝海黑石新材料科技有限公司 | Hard carbon negative electrode bi-component acrylic ester aqueous adhesive for sodium ion battery, and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5182328A (en) * | 1992-03-04 | 1993-01-26 | Air Products And Chemicals, Inc. | RF curable Type I wood adhesive composition comprising vinyl acetate/NMA copolymer emulsions containing tetramethylol glycoluril |
| US5434216A (en) * | 1993-05-07 | 1995-07-18 | National Starch And Chemical Investment Holding Corporation | Woodworking latex adhesives with improved water, heat and creep resistance |
| CN1350008A (en) * | 2000-10-20 | 2002-05-22 | 孙益成 | Modified polyvinyl acetate emulsion |
| US20030000643A1 (en) * | 1997-10-27 | 2003-01-02 | Bernhard Herlfterkamp | Aqueous adhesive preparation |
-
2005
- 2005-02-25 CN CNB2005100378552A patent/CN1293160C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5182328A (en) * | 1992-03-04 | 1993-01-26 | Air Products And Chemicals, Inc. | RF curable Type I wood adhesive composition comprising vinyl acetate/NMA copolymer emulsions containing tetramethylol glycoluril |
| US5434216A (en) * | 1993-05-07 | 1995-07-18 | National Starch And Chemical Investment Holding Corporation | Woodworking latex adhesives with improved water, heat and creep resistance |
| US20030000643A1 (en) * | 1997-10-27 | 2003-01-02 | Bernhard Herlfterkamp | Aqueous adhesive preparation |
| CN1350008A (en) * | 2000-10-20 | 2002-05-22 | 孙益成 | Modified polyvinyl acetate emulsion |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1670101A (en) | 2005-09-21 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Shanghai East Adhesive Co., Ltd. Assignor: Suzhou Congling Adhesives Co., Ltd. Contract fulfillment period: 2007.2.1 to 2012.2.1 contract change Contract record no.: 2008310000227 Denomination of invention: Watermark-free heat transfer printing adhesive Granted publication date: 20070103 License type: Exclusive license Record date: 20081119 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.2.1 TO 2012.2.1; CHANGE OF CONTRACT Name of requester: SHANGHAI CITY DONGHE ADHESIVE AGENT CO., LTD. Effective date: 20081119 |
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| ASS | Succession or assignment of patent right |
Owner name: SUZHOU ADHESIVE FACTORY CO., LTD. Free format text: FORMER OWNER: SUZHOU CITY CONGLING ADHESIVES CO., LTD. Effective date: 20120327 |
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Effective date of registration: 20120327 Address after: 215144 spring and Autumn Road, Pan Yang Industrial Zone, Suzhou, Xiangcheng District, Jiangsu Patentee after: Suzhou Adhesive Factory Co., Ltd. Address before: 215144 Jinfeng Industrial Park, Lingfeng village, North Town, Suzhou, Jiangsu, Xiangcheng District Patentee before: Suzhou Congling Adhesives Co., Ltd. |
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| ASS | Succession or assignment of patent right |
Owner name: SUZHOU CITY CONGLING ADHESIVES CO., LTD. Free format text: FORMER OWNER: SUZHOU ADHESIVE FACTORY CO., LTD. Effective date: 20130927 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20130927 Address after: 215144, Lingfeng Town, North Qiao Town, Suzhou, Jiangsu, Xiangcheng District Patentee after: Suzhou Congling Adhesives Co., Ltd. Address before: 215144 spring and Autumn Road, Pan Yang Industrial Zone, Suzhou, Xiangcheng District, Jiangsu Patentee before: Suzhou Adhesive Factory Co., Ltd. |
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| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070103 Termination date: 20140225 |