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CN1292364A - Bubble-contained porous sintered clay block, its production process and application - Google Patents

Bubble-contained porous sintered clay block, its production process and application Download PDF

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Publication number
CN1292364A
CN1292364A CN 00126705 CN00126705A CN1292364A CN 1292364 A CN1292364 A CN 1292364A CN 00126705 CN00126705 CN 00126705 CN 00126705 A CN00126705 A CN 00126705A CN 1292364 A CN1292364 A CN 1292364A
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ball
agglomerate
clay block
sintered clay
wall
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CN 00126705
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朱遂科
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Abstract

The present invention relates to a porous sintered clay block with air bags, its production process and application. It is characterized by including the following steps: adopting clay or sludge, uniformly mixing it with plant fibre and silicone sand, wrapping them with plant fibre ball and forming, the volume of air bags and passage is 20-30% of volume of the sintered block (ball). Its form can be ball, rod and rectangular, and their sizes can be defined according to the requirements. Between external surface and fibre ball the passage can be set, and the wet blank is dehydrated (stove-dried or air-dried) and sintered so as to obtain the invented product. Its sintering temp. is identical to that of baking bricks, and its sintering kiln car be oxidation type kiln, also can be reduction type kiln. Said invented product can be used as greening and liquid-adsorbing filtering material or air-filtering material.

Description

Free contained porous sintered clay block and manufacture craft thereof and purposes are arranged
The present invention relates to a kind of multi-purpose material and preparation method thereof and purposes, be mainly used in and sinter a kind of many pores bulk or bead materials (hereinafter to be referred as ball) into after clay or mud mixed an amount of vegetable fibre, the soilless culture that this material can be used for afforesting, and the filtration of liquid or gas.
Greening environment, decontamination have been the problem when last big hot topic, also be for protect the human survival condition the most urgent problem, round this problem, people are carrying out many-sided research and trial.The pollution of environment faces big public hazards as countries in the world and mainly contains three kinds of forms, a kind of is topsoil, another kind is a water pollution, also having a kind of is that soil property is polluted, and so-called soil property is polluted the pollution that mud caused that is formed by various rubbish location exactly to a great extent, for the mud of this pollution, still there is not the good treatment way at present.Chinese patent " Environmental protection greening bricks " (patent No. is 97217494.X) discloses a kind of New Building Materials as greening usefulness.But still be confined to be improved on the existing brick body, and be by the hole of several equal diameters manually artificially is set, and in the hole, insert nutrition soil again, realize the stereo planting of plant, so still do not have help to solving mud, and this artificial making to plant hole count limited after all, the demand that is difficult to really adapt to the development of plant hair root.So the utmost point remains to be improved.
The objective of the invention is to deficiency, propose a kind of clay or mud of utilizing, and adding vegetable fibre sintering is made a kind of be free contained porous sintered clay and preparation method thereof and purposes at existing greening cultivation and sludge treatment.
According to the technology implementation scheme that purpose of the present invention proposed be: adopt 70-80 part clay or mud, mixing an amount of vegetable fibre 20-30 part (or plant slag) again mixes thoroughly, the moulding with compound parcel vegetable fibre ball, if mud plasticity is excessive, when making brick for afforesting, then should outside compound, mix 10-20 part silica sand in addition, in order to moulding, and improve and burn till intensity; Empty pocket and channel volume account for the 20-30% of agglomerate (ball) volume.Shape can be sphere, clavate, rectangle etc., size is gradable and decide, establishes passage between outside surface and the fibrous nodules, and passage can be by the some eyelets acquisitions of bundle (or cutting), also fibrous nodules can be added some fiber whips for bigger piece (ball), make whip expose grume (ball), the base that will wet dehydration (oven dry or air-dry), calcining, the sintering temperature and the basically identical of baking bricks, sintering oven can be the kiln of oxidized form, can be reduced form kiln also, adopts which kind of kiln type mainly to decide according to required color.The interior fibrous nodules of clay block has become empty pocket and many pores behind the sintering, and this kind material can be applicable to greening, liquid adsorption filtrate or effect air filting material.
Its main application is as follows:
One, the usefulness of greening
1. as moulding stone: the bubble-contained piece that sintering is crossed is as moulding stone be used to build a wall body or be assembled into and hold the greening carrier of deciding moulding.Moulding stone moulding manufacture method:
A, perforation method: the three-dimensional of every sintered clay block or four directions perforation, will each sintered clay block can be fixed in the steel pipe patchhole during assembling.
B, establish channel process: the rectangle clay block up and down two respectively establish 1-2 bar groove, make agglutinate with sand-cement slurry when building by laying bricks or stones, fill the groove of clay block, do not establish mortar joint when having had trough then to build by laying bricks or stones, generally be used to the body of building a wall.
2, mix long-acting ore deposit fertilizer
As the usefulness of greening, in order to allow plant obtain potassium, phosphorus and trace element, can in clay (or mud), mix the ore of a little rich potassium, rich phosphorus, as potassic hydromica or the long rock weathered clay of potassium, phosphorated phosphorite.
3, in order to make plant obtain abundant nutrient, also can in empty pocket, wear steel pipe, steel pipe is beaten many minute apertures, supply nutritive medium and water to big agglomerate molectron by the steel pipe minute aperture.When pouring water, tighten the terminal tap of steel pipe, open faucet, treat that for some time agglomerate (ball) irrigates after, close faucet, open terminal depotition cock, get rid of excessive moisture.Terminal water pipe is the U type, with the Bedpan water receiving.
4, the macromolecular material that also suitable filling exchange absorption resin, microsolubility composite fertilizer, height absorb water in the empty pocket is as nutriment.
5, also can in the passage of agglomerate (ball) and empty pocket, put plant seeds such as a little grass-seeds or vegetables, the gummed paper of external parcel protection against the tide, outermost layer is a ply of paper, is printed with working instructions, plant characteristics and greening moulding photo on it, and watering like this to obtain green plants.
The pore of material of the present invention and the effect of empty pocket are: the pore empty pocket plays water storage storage fertilizer and coring is taken root effect, and empty pocket also works to deposit seed and main root is taken root.
The color of material: adopt different clays, other mixes coloring element and corresponding sintering oven type, promptly can obtain different bag coloured silks, to satisfy required aesthetic feeling.
The present invention as the main application of greening is:
A, indoor wall: as bearing wall ornament layer and nonweight-bearing dividing wall, plant tolerant plant with agglomerate, this body of wall has greening, beautifies noise elimination, fire prevention, dust suction, adjusting wetness action.
B, enclosure wall, the noise elimination wall of highway and viaduct: build into construction hoarding and the permanent enclosure wall of garden by laying bricks or stones with sintered clay block, highway and viaduct noise elimination wall, the plantation plant has greening, beautifies, usefulness is regarded in noise elimination, dust suction, resistance as.
C, moulding are used: square, front door, hall, public place and dwelling house negative and positive platform are combined into the moulding object of the certain artistry of tool with sintered clay block (energy), and plant the plant that is fit to, and then are a kind of good greening artwork.
D, green grass stone: promptly with gummed paper and paper pack and give the agglomerate of putting plant seed.
E, aquatic penjing plant are taken root stone: will be placed in the water with the porous sintered clay block (ball) of empty pocket, allow waterplant take root, because porous stone has good adsorptive power, so suspended substance can be adsorbed by porous stone and water body seems limpid in the potted landscape water body.
F, also can be used for making lawn brick with for available coagulation soil grassplot brick, it is more but want little lawn brick also to can be made into the hole, be 1-2cm as aperture size, hole wall 1-1.5cm, and the aperture is littler to be convenient to the pedestrian and to walk, and does not fall pin or block the footwear root.
Two, as the liquid adsorption filtrate
1, tap water adsorption filtration: put a little alnico magnets in the empty pocket in the sintered clay block (ball), magnet can make dispersive piece (ball) body inhale and get together.When dredging a well agglomerate (ball) in (pond, bucket) clearly, ironware need only be stretched in the well (pond, bucket), agglomerate (ball) can be taken out.Magnet also plays the magnetization to water, for the antimagnetic iron oxidation also can be with magnet outsourcing plastics.Be used as and be used for sewage water filtration usefulness after porous piece (ball) that air filtration uses lost efficacy, be used for the porous piece (ball) that liquid filtering uses and after inefficacy, can be used as greening brick (ball).
2, swimming pool and aquaculture water filter: agglomerate (ball) is dropped in the water body, and adsorbable suspended substance, raising water body degree of cleaning reduce water body and change number of times.During mud matter, simple cleaning bottom dirt is very difficult in the cleaning pond, in the pool, cleaning with the agglomerate (ball) of dirt then than being easier to.
3, drinkable liquid filters with agglomerate (ball): with white clay (kaolin, agalmatolite, dickite etc.) is raw material, few and do not contain heavy metal element because of its coloring element content, fiber is preferably the particularly low vegetable fibre of iron level of mineral substance, and these fibers are best with cotton.
4, be used as the liquid adsorption filter material: should be in advance with agglomerate (ball) flushing, pickling, to remove ashes and salt of wormwood.
5, sewage disposal: do filter material with material of the present invention during the sewage work tertiary treatment, also can be used for carwash sound, dining room, restaurant sewage water filtration.
Three, as air filting material and strumbox
Allow sintered clay block (ball) drench a little Na (OH) 2The aqueous solution also keeps moistening, and when airflow burning caking (ball), agglomerate (ball) has adsorbed koniology, CO 2, SO 2Bacterium, this technology are in the serious city of atmospheric pollution and pay attention to way of great use, energy-conservation place.
Put plastics casing in the strumbox, stack agglomerate (ball) in the basin, chest has four holes, face connects a pipe and links to each other with the blast inlet at exterior wall place behind the chest, the side connects a pipe and is used to absorb room air, and the front has a hole to be used to install ventilator, and hole, case top is used to drench Na (OH) 2Solution.When need absorption chamber outer air, then will go up hole, side opening blockade, open ventilator, outdoor gas has passed through Filtration Adsorption.During opening air conditioning machinery, the wall hole can be sealed, allow side pipe air inlet, room air is by the filtration cleaning that becomes like this, thereby saved the energy owing to having significantly reduced the quantity of taking a breath with the external world.
The piece (or ball) that the present invention adopts clay or mud admixture vegetable fibre sintering to make many thin empty pockets not only provides type material for greening, filtration, and can extensively utilize and produce the mud that pollutes, its making itself have beautify the environment, the function of decontamination, the employing that is worthy to be popularized, advantage is:
1, as greening
The sculpting method of square greening now: in potted landscape combination shaping mode; Tie up numb built-in clay outward, implant seedling then, water every day.These two kinds of modes are watered often, and the moulding expense is big.
Gansu " Environmental protection greening bricks " is put on display in the 8th Chinese patent New Product expo in 1999, and it is that raw material compacting forms with coal ash, cement, gypsum, cobble, in the brick body by pack into the grass seeds of special preparation nutrition soil and special cultivation of 20: 1 ratios.
This product is adopted to fire and is formed, can utilize near clay, particularly mud, can solve municipal sewage system, sewage work and riverway sludge whereabouts, because porous and bubble-contained, this product unit weight can be less than pressed brick, because porous and empty pocket and the effect of inner macromolecule water-absorbing material thereof, the effect of present technique product preserve moisture and fertility is fine.
2, as filtering adsorbing material
Filter the coal sandstone of usefulness with respect to the waterworks, this product unit weight is little, and porosity is big, and specific surface area is big, thereby the adsorption filtration better effects if.Filter the diatomite of usefulness with respect to beverage, wet goods, this product has a typing shape and an intensity, and diatomite is loose material, thus this sample product in container, can pile the higher fill factor that improved.With respect to gac, this product valency is low, can be by foul in the calcination method cleaning hole capsula interna, and gac is used to adsorb clay matter suspended substance, then can not reuse, absorption is organic, then its more complicated of regenerating also, expense are higher if be used for.
The invention will be further described below in conjunction with embodiment:
Embodiment one:
Raw material and prescription: (by weight ratio)
3 parts of fine sands
14 parts in mud
3 parts on vegetable fibre
The material making method:
1, raw material is mixed thoroughly by proportioning water mixing mixing;
2, get the vegetable fibre ball of a band whip in addition, be rolled into the rectangular block shape whip with the compound mixed thoroughly and stretch out block surface, use and establish channel process at two troughs of respectively establishing two wide 1cm of dark 1cm up and down;
3, base dewatered drying;
4, the exsiccant blank is placed the sintering oven sintering, sintering time and temperature and the basically identical of baking bricks;
5, the blank that sinters promptly becomes stand-by material.
Purposes:
Usefulness as greening, fill full with the macromolecular material mixture of exchange polymeric adsorbent and microsolubility composite fertilizer and high suction the empty pocket in the rectangular billet that sinters, be coated on the groove of agglomerate with sand-cement slurry again, agglomerate is built by laying bricks or stones, just can locate to insert kind of green plants or seed at passage or empty pocket (forming), form the vertical planting effect by vegetable fibre whip and fibrous nodules burning back.
Embodiment two: raw material and prescription: (by weight ratio)
20 parts of clays
4 parts on vegetable fibre
The material making method:
1, raw material is mixed thoroughly by proportioning water mixing mixing;
2, get a vegetable fibre ball in addition, be rolled into rectangular block shape or bead-like body with the compound of mixing thoroughly;
3, the base dewatered drying that will wet;
4, the exsiccant blank is placed the sintering oven sintering, sintering time and temperature and the basically identical of baking bricks;
5, the blank that knot is good promptly becomes stand-by material.
Purposes:
Be mainly used in liquid filtering.If being used for drinkable liquid (as well water, beverage) filters, then should in the empty pocket of sintered balls, fill out and put a little alnico magnets in small, broken bits, magnet makes a dispersive ball pinching together, when drawing clearly, only need like this ironware is stretched into, ball all can be taken out together, magnet also can play the magnetization to water.
Embodiment three:
Raw material and prescription: (by weight ratio)
30 parts of clays
50 parts in mud
15 parts on vegetable fibre
Long rock of potassium or hydromica 5%
Phosphorite 2%
The material making method:
1, raw material is mixed thoroughly by proportioning water mixing mixing;
2, get a vegetable fibre ball in addition, be rolled into rectangular block shape, use and establish channel process at two troughs of respectively establishing two wide 1cm of dark 1cm up and down with the compound mixed thoroughly;
3, dewatered drying;
4, the exsiccant blank is placed the sintering oven sintering, sintering time and temperature and the basically identical of baking bricks;
5, the blank that knot is good promptly becomes stand-by material.
Purposes:
As the noise elimination wall of highway: build into divider wall by laying bricks or stones with the agglomerating clay block with overhead wall, in the agglomerate empty pocket, fill compound nutritional material and grass-seed, after divider wall lays, only need regularly water, grass-seed just can grow up to green plants in the agglomerate, and because agglomerate itself contains abundant rich potassium, rich phosphorus ore fertilizer, so but the plant long period do not need fertilizing management, be convenient to outdoor plantation.

Claims (10)

1, free contained porous sintered clay block and manufacture craft thereof and purposes are arranged, it is characterized in that goods of the present invention are to adopt clay or mud, mix with an amount of vegetable fibre (or plant slag) and silica sand and to mix thoroughly, wrap up the vegetable fibre ball and moulding, through the agglomerate that contains many pores and empty pocket (ball) of calcining aftershaping; Empty pocket and channel volume account for the 20-30% of agglomerate (ball) volume, and its raw material and proportioning are as follows:
0~80 part of clay
0~80 part in mud
0~20 part of silica sand
10~20 parts on vegetable fibre
2, as claimed in claim 1 be free contained porous sintered clay block and manufacture craft and purposes, the shape that it is characterized in that agglomerate (ball) can be sphere, clavate, rectangle etc., size is gradable and decide, establish passage between outside surface and the fibrous nodules, passage can obtain by pricking (or cutting) some eyelets, also fibrous nodules can be added some fiber whips for bigger piece (ball), makes whip expose grume (ball), the base that will wet dehydration (oven dry or air-dry), the calcining back obtains.
3, as claimed in claim 1 be free contained porous sintered clay block and manufacture craft and purposes, it is characterized in that the sintering temperature of agglomerate (ball) and the basically identical of baking bricks, sintering oven can be the kiln of oxidized form, can be reduced form kiln also, adopts which kind of kiln type mainly to decide according to required color.
4, free contained porous sintered clay block and manufacture craft thereof and purposes are arranged, it is characterized in that material of the present invention can be used as the greening material:
A, as moulding stone: the bubble-contained piece that sintering is crossed is as moulding stone be used to build a wall body or be assembled into and hold the greening carrier of deciding moulding.
B, as indoor wall, with agglomerate as bearing wall ornament layer and nonweight-bearing dividing wall, the plantation tolerant plant, this body of wall has greening, beautifies noise elimination, fire prevention, dust suction, adjusting wetness action.
C, as enclosure wall, the noise elimination wall of highway and viaduct: build into construction hoarding and the permanent enclosure wall of garden by laying bricks or stones with sintered clay block, highway and viaduct noise elimination wall, the plantation plant has greening, beautifies, usefulness is regarded in noise elimination, dust suction, resistance as.
D, use as moulding: square, front door, hall, public place and dwelling house negative and positive platform are combined into the moulding object of the certain artistry of tool with sintered clay block (energy), and the plant that is fit to of plantation, then are a kind of good greening artwork.
E, as green grass stone: promptly with gummed paper and paper pack and give the agglomerate of putting plant seed.
F, take root stone as aquatic penjing plant: will be placed in the water with the porous sintered clay block (ball) of empty pocket, allow waterplant take root, because porous stone has good adsorptive power, so suspended substance can be adsorbed by porous stone and water body seems limpid in the potted landscape water body.
G, as also can be used for making lawn brick with for available coagulation soil grassplot brick, it is more but want little lawn brick also to can be made into the hole, be 1-2cm as aperture size, hole wall 1-1.5cm, the aperture is littler to be convenient to the pedestrian and to walk, and does not fall pin or block the footwear root.Moulding stone moulding manufacture method:
5, as claimed in claim 4 be free contained porous sintered clay block and manufacture craft and purposes, what it is characterized in that agglomerate (ball) fixedly is to adopt perforation method: the three-dimensional of every sintered clay block or four directions perforation, during assembling with can be in the steel pipe patchhole with each sintered clay block fixed.
6, as claimed in claim 4 be free contained porous sintered clay block and manufacture craft and purposes, what it is characterized in that agglomerate (ball) fixedly is to adopt to establish channel process: respectively establish 1-2 bar groove for two about the rectangle clay block, make agglutinate with sand-cement slurry when building by laying bricks or stones, fill the groove fixed of clay block.
7, as claimed in claim 4 be free contained porous sintered clay block and manufacture craft and purposes, it is characterized in that agglomerate (ball) in order to allow plant obtain potassium, phosphorus and trace element, can mix the ore of a little rich potassium, rich phosphorus in clay (or mud).
8, as claimed in claim 4 be free contained porous sintered clay block and manufacture craft and purposes, it is characterized in that agglomerate (ball) obtains abundant nutrient in order to make plant, also can in empty pocket, wear steel pipe, steel pipe is beaten many minute apertures, supply nutritive medium and water to big agglomerate molectron by the steel pipe minute aperture.
9, free contained porous sintered clay block and manufacture craft thereof and purposes are arranged, it is characterized in that material of the present invention can be used as the liquid adsorption filtrate:
A, tap water adsorption filtration: put a little alnico magnets in the empty pocket in the sintered clay block (ball), magnet can make dispersive piece (ball) body inhale and get together.When dredging a well agglomerate (ball) in (pond, bucket) clearly, ironware need only be stretched in the well (pond, bucket), agglomerate (ball) can be taken out.Magnet also plays the magnetization to water, for the antimagnetic iron oxidation also can be with magnet outsourcing plastics.Be used as and be used for sewage water filtration usefulness after porous piece (ball) that air filtration uses lost efficacy, be used for the porous piece (ball) that liquid filtering uses and after inefficacy, can be used as greening brick (ball).
B, swimming pool and aquaculture water filter: agglomerate (ball) is dropped in the water body, and adsorbable suspended substance, raising water body degree of cleaning reduce water body and change number of times.During mud matter, simple cleaning bottom dirt is very difficult in the cleaning pond, in the pool, cleaning with the agglomerate (ball) of dirt then than being easier to.
C, drinkable liquid filter with agglomerate (ball): with white clay (kaolin, agalmatolite, dickite etc.) is raw material, few and do not contain heavy metal element because of its coloring element content, fiber is preferably the particularly low vegetable fibre of iron level of mineral substance, and these fibers are best with cotton.
D, be used as the liquid adsorption filter material: should be in advance with agglomerate (ball) flushing, pickling, to remove ashes and salt of wormwood.
E, sewage disposal: do filter material with material of the present invention during the sewage work tertiary treatment,
Also can be used for carwash sound, dining room, restaurant sewage water filtration.
10, free contained porous sintered clay block and manufacture craft thereof and purposes are arranged, it is characterized in that material of the present invention can be used as air filting material and strumbox:
Allow sintered clay block (ball) drench a little Na (OH) 2The aqueous solution also keeps moistening, put plastics casing in the strumbox, stack agglomerate (ball) in the basin, chest has four holes, face connects a pipe and links to each other with the blast inlet at exterior wall place behind the chest, the side connects a pipe and is used to absorb room air, and the front has a hole to be used to install ventilator, and hole, case top is used to drench Na (OH) 2Solution, when need absorption chamber outer air, then will go up hole, side opening blockade, open ventilator, outdoor gas has passed through Filtration Adsorption, during opening air conditioning machinery, the wall hole can be sealed, allow side pipe air inlet, room air is by the filtration cleaning that becomes like this, thereby owing to significantly reduced with the quantity of external world's ventilation and saved the energy.
CN 00126705 2000-11-23 2000-11-23 Bubble-contained porous sintered clay block, its production process and application Pending CN1292364A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 00126705 CN1292364A (en) 2000-11-23 2000-11-23 Bubble-contained porous sintered clay block, its production process and application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 00126705 CN1292364A (en) 2000-11-23 2000-11-23 Bubble-contained porous sintered clay block, its production process and application

Publications (1)

Publication Number Publication Date
CN1292364A true CN1292364A (en) 2001-04-25

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101548615A (en) * 2009-05-22 2009-10-07 山东省古窖藏酒与酒文化研究发展中心 Porous nest brick 3D green plant technology
CN102838371A (en) * 2011-06-21 2012-12-26 窦根平 Manufacturing method of porous environment-friendly and energy-saving brick
CN102874930A (en) * 2012-09-21 2013-01-16 中国矿业大学 Dedicated filler for constructed wetland and preparation method for filler
CN102921236A (en) * 2011-12-23 2013-02-13 成都杰丽净水设备有限公司 Lightweight type filtration material for water treatment
CN104058564A (en) * 2014-07-02 2014-09-24 天津壹鸣环境工程有限公司 Treatment system for preparing soilless culture medium by sintering sludge
CN104556031A (en) * 2015-01-13 2015-04-29 华南理工大学 Mud-based spherical active carbon as well as preparation method and application thereof
CN105064770A (en) * 2015-09-14 2015-11-18 煤炭工业合肥设计研究院 Green city traffic transfer system
CN104109034B (en) * 2014-08-12 2016-05-11 许盛英 The production method of magnesite tailings compression Nutrition Soil
CN108046759A (en) * 2018-01-16 2018-05-18 马鞍山市新桥工业设计有限公司 A kind of river silt illite sintered perforated brick and preparation method thereof
CN110235746A (en) * 2019-04-19 2019-09-17 湖北声荣再生资源利用有限公司 A kind of environmental-friendly plant culture medium and preparation method thereof
CN112441843A (en) * 2020-12-05 2021-03-05 任杰 Preparation process of attached-wire type porous ceramic based on organic foam impregnation method
CN114775703A (en) * 2022-05-24 2022-07-22 国网甘肃省电力公司经济技术研究院 Construction method of high-strength anti-freezing in-situ clay isolation wall based on heat loss

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101548615A (en) * 2009-05-22 2009-10-07 山东省古窖藏酒与酒文化研究发展中心 Porous nest brick 3D green plant technology
CN102838371A (en) * 2011-06-21 2012-12-26 窦根平 Manufacturing method of porous environment-friendly and energy-saving brick
CN102921236A (en) * 2011-12-23 2013-02-13 成都杰丽净水设备有限公司 Lightweight type filtration material for water treatment
CN102874930A (en) * 2012-09-21 2013-01-16 中国矿业大学 Dedicated filler for constructed wetland and preparation method for filler
CN102874930B (en) * 2012-09-21 2014-09-03 中国矿业大学 Dedicated filler for constructed wetland and preparation method for filler
CN104058564B (en) * 2014-07-02 2016-06-22 天津壹鸣环境科技股份有限公司 A kind of sewage sludge sintering soilless culture substrate processing method
CN104058564A (en) * 2014-07-02 2014-09-24 天津壹鸣环境工程有限公司 Treatment system for preparing soilless culture medium by sintering sludge
CN104109034B (en) * 2014-08-12 2016-05-11 许盛英 The production method of magnesite tailings compression Nutrition Soil
CN104556031A (en) * 2015-01-13 2015-04-29 华南理工大学 Mud-based spherical active carbon as well as preparation method and application thereof
CN105064770A (en) * 2015-09-14 2015-11-18 煤炭工业合肥设计研究院 Green city traffic transfer system
CN108046759A (en) * 2018-01-16 2018-05-18 马鞍山市新桥工业设计有限公司 A kind of river silt illite sintered perforated brick and preparation method thereof
CN110235746A (en) * 2019-04-19 2019-09-17 湖北声荣再生资源利用有限公司 A kind of environmental-friendly plant culture medium and preparation method thereof
CN112441843A (en) * 2020-12-05 2021-03-05 任杰 Preparation process of attached-wire type porous ceramic based on organic foam impregnation method
CN114775703A (en) * 2022-05-24 2022-07-22 国网甘肃省电力公司经济技术研究院 Construction method of high-strength anti-freezing in-situ clay isolation wall based on heat loss
CN114775703B (en) * 2022-05-24 2024-02-06 国网甘肃省电力公司经济技术研究院 High-strength antifreezing in-situ clay partition wall construction method based on heat loss

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