CN1292129A - Electronic device with contactless electronic memory, and method for making same - Google Patents
Electronic device with contactless electronic memory, and method for making same Download PDFInfo
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- CN1292129A CN1292129A CN99803383.9A CN99803383A CN1292129A CN 1292129 A CN1292129 A CN 1292129A CN 99803383 A CN99803383 A CN 99803383A CN 1292129 A CN1292129 A CN 1292129A
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- G—PHYSICS
- G06—COMPUTING OR CALCULATING; COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/067—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components
- G06K19/07—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components with integrated circuit chips
- G06K19/077—Constructional details, e.g. mounting of circuits in the carrier
- G06K19/07749—Constructional details, e.g. mounting of circuits in the carrier the record carrier being capable of non-contact communication, e.g. constructional details of the antenna of a non-contact smart card
- G06K19/0775—Constructional details, e.g. mounting of circuits in the carrier the record carrier being capable of non-contact communication, e.g. constructional details of the antenna of a non-contact smart card arrangements for connecting the integrated circuit to the antenna
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- G—PHYSICS
- G06—COMPUTING OR CALCULATING; COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/067—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components
- G06K19/07—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components with integrated circuit chips
- G06K19/077—Constructional details, e.g. mounting of circuits in the carrier
- G06K19/07749—Constructional details, e.g. mounting of circuits in the carrier the record carrier being capable of non-contact communication, e.g. constructional details of the antenna of a non-contact smart card
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Abstract
Description
本发明涉及一种制作薄的、能弯曲折叠的无接触电子器件(10)的方法,此种电子器件-如卡、标签、票券或标牌-包含至少一个微电子电路(20),该微电子电路布置在支撑体内,其具有的管脚与同样布置在支撑体内的接口天线(24)相连,而支撑体含有至少两个相对的保护片-底片(12)和顶片(16),该方法包括有下文的连续步骤。The invention relates to a method of making a thin, bendable, contactless electronic device (10) - such as a card, label, ticket or tag - comprising at least one microelectronic circuit (20), the microelectronic The electronic circuit is arranged in a support with pins connected to an interface antenna (24) also arranged in the support, and the support contains at least two opposing protective sheets - a bottom sheet (12) and a top sheet (16), the The method comprises the following sequential steps.
这些电子器件有许多实例,它们通常被称为智能卡,这些智能卡或是硬质卡,其支撑体由塑料制成,或是标签-亦被称为“电子标签”,它用于标记一次性大宗消费的产品,也就是说其目的是要一次性地粘贴在产品上,且它基本上只有一片纸。There are many examples of these electronic devices, which are commonly referred to as smart cards, either rigid cards with a support made of plastic, or tags - also known as "electronic tags", which are used to mark single-use bulk A consumer product, that is to say its purpose is to stick on the product once, and it is basically just a piece of paper.
因此,存在对上述类型电子器件的需求,例如无接触智能卡,它非常薄(例如其厚度可以小于约400微米,或者甚至280微米),且能弯曲,或者甚至能对折,也能多次使用,且其厚度与成本都很低,这样,它能用在许多依赖带有电子存储器的芯片的应用中,而由于支撑体的成本和/或厚度的原因,目前还不可能依赖带有无接触电子存储器的卡、标签、票券或标牌。Therefore, there is a need for an electronic device of the above-mentioned type, such as a contactless smart card, which is very thin (for example, its thickness may be less than about 400 microns, or even 280 microns), and which can be bent, or even folded in half, and which can also be used multiple times, And its thickness and cost are very low, so it can be used in many applications that rely on chips with electronic memory, which is not currently possible due to the cost and/or thickness of the support. memory cards, tags, tickets or tags.
同时,也需要较为结实的器件,这类器件使用起来无需小心翼翼,或者甚至可以被对折而不会损害其功能。这种例子为地铁票券。At the same time, there is a need for stronger devices that can be handled without care, or that can even be folded in half without compromising their functionality. An example of this is a subway ticket.
另外,存在对无接触器件的需求,这类器件非常细,其卓越的表面质量使其能用作高质量印刷的支撑体。这种例子主要是扑克牌或身份证。In addition, there is a need for contactless devices that are very thin and whose excellent surface quality allows them to be used as supports for high-quality printing. Examples of this are mainly playing cards or identification cards.
为此目的,本发明给出制作上述类型电子器件的方法,它包括以下的连续步骤:To this end, the invention provides a method of making an electronic device of the above-mentioned type, which comprises the following successive steps:
a)通过下述方法制作一个底层保护片:a) Make a bottom protection sheet by the following method:
a1)在底片的内表面上放置至少一个微电子电路;a1) placing at least one microelectronic circuit on the inner surface of the negative;
a2)具体用丝网印刷方法在底片的内表面上制作至少一个接口天线;a2) specifically making at least one interface antenna on the inner surface of the film by screen printing;
a3)将微电子电路的管脚与接口天线进行电气连接;a3) electrically connecting the pins of the microelectronic circuit to the interface antenna;
b)通过在底层保护片上叠加中间粘接层和顶层保护片,来制作一个叠层,其中,中间层的上下两对面都带有胶;b) making a laminate by superimposing an intermediate adhesive layer and a top protective sheet on the bottom protective sheet, wherein the upper and lower opposite sides of the intermediate layer are glued;
c)通过压缩这三个叠加的层,使其装配在一起。根据本发明方法的其它特征:c) Fit the three superimposed layers together by compressing them. Other features of the method according to the invention:
-装配步骤c)包括一个热滚压操作;- assembly step c) includes a hot rolling operation;
-中间粘接层上有一个与微电子电路垂直的凹口;- a notch in the middle adhesive layer perpendicular to the microelectronic circuit;
-中间粘接层为一热融胶层;-The middle adhesive layer is a hot-melt adhesive layer;
-中间粘接层是一层纸,其上下两对面都敷有一层热融胶;-The middle adhesive layer is a layer of paper, and a layer of hot-melt glue is applied on the upper and lower opposite sides;
-在制作底层保护片的步骤a)过程中,顺序执行操作a1)、a2)和a3);- During step a) of making the bottom protection sheet, sequentially perform operations a1), a2) and a3);
-至少有一层保护片是纸做的;- At least one protective sheet is made of paper;
-本方法包括一个补充步骤,即在支撑体的上下两个保护片的外表面的一个和/或另一个上进行印刷。优选地,印刷在天线和/或芯片安装前进行;- The method comprises a supplementary step of printing on one and/or the other of the outer surfaces of the upper and lower protective sheets of the support. Preferably, printing is performed before antenna and/or chip mounting;
-本方法包括一个补充步骤,即沿着给定的卡、标签、票券或标牌的四周剪裁这类电子器件;- the method includes the additional step of cutting such electronic devices along the perimeter of a given card, tag, ticket or sign;
-用成卷的保护片和粘接层同时制作若干电子器件,并且在补充的剪裁步骤中进行分离。- Simultaneous fabrication of several electronic components with rolls of protective sheets and adhesive layers and separation in a supplementary cutting step.
本发明也涉及上述类型的无接触电子器件,其特征在于,它包括一个这样的叠层:The invention also relates to a contactless electronic device of the above-mentioned type, characterized in that it comprises a stack of:
-一个底层保护片,其内表面承载有至少一个微电子电路和至少一个接口天线;- an underlying protective sheet, the inner surface of which carries at least one microelectronic circuit and at least one interface antenna;
-一个中间粘接层,其上下两对面均敷有胶;- an intermediate adhesive layer, the upper and lower opposite sides of which are coated with glue;
-及一个顶层保护片。- and a top protection sheet.
根据本发明器件的其它特征:Other features of the device according to the invention:
-中间粘接层有一个与微电子电路垂直的凹口;- the middle adhesive layer has a notch perpendicular to the microelectronic circuit;
-中间粘接层为热融胶层;-The middle adhesive layer is a hot-melt adhesive layer;
-中间粘接层是一层纸,其上下两对面均敷有一层热融胶;-The middle adhesive layer is a layer of paper, and its upper and lower sides are coated with a layer of hot melt glue;
-至少有一层保护片是纸做的;- At least one protective sheet is made of paper;
-该器件的厚度小于400微米,或者甚至280微米;- the thickness of the device is less than 400 microns, or even 280 microns;
-承载天线和微电子电路(芯片)的层厚度小于或等于75微米。- The thickness of the layer carrying the antenna and the microelectronic circuit (chip) is less than or equal to 75 microns.
在阅读以下的详细描述时可以知道本发明的其它特征或优点,附图则可用作理解本发明的参考,其中:Other characteristics or advantages of the present invention can be known when reading the following detailed description, and the accompanying drawings can be used as a reference for understanding the present invention, wherein:
-附图1简要示出了依照本发明所述方法制作的智能卡的第一个实施例的纵截面,同时也描述了在热滚压操作之前由三个层所组成的叠片;- Accompanying drawing 1 schematically shows a longitudinal section of a first embodiment of a smart card manufactured according to the method according to the invention, also depicting a laminate consisting of three layers before the hot rolling operation;
-附图2与附图1类似,它示出了依照本发明所述方法制作的智能卡的第二个实施例;- Accompanying drawing 2 is similar to accompanying
-附图3A到3C示意性示出了制作底层保护纸片的三个操作,该保护片用在依照本发明制作的电子器件上;- Figures 3A to 3C schematically illustrate three operations for producing a bottom layer of protective paper for use in electronic devices produced in accordance with the present invention;
-附图4示意性示出了叠片的制作,该叠片通过将组成智能卡(依照本发明所述方法制作而成)的支撑体的三个层叠加在一起得到。- Figure 4 schematically shows the manufacture of a laminate obtained by superimposing the three layers that make up the support of the smart card (produced according to the method described in the invention).
在以下说明中,相同的参考数字表示同样的、相似的或类似的元件,并且,为了方便阐述,在说明书和权利要求中,使用了参考附图中的底、顶、竖向等术语,但它们并不具备限定意义。In the following description, the same reference numerals represent the same, similar or analogous elements, and, for the convenience of explanation, in the description and claims, terms such as bottom, top, and vertical in the drawings are used, but They are not limiting.
根据定义,可弯曲是指如同扑克牌一样的机械属性。By definition, bendable refers to the mechanical properties of playing cards.
本发明的产品在应用时被设计成可以象地铁票券一样使用,卷起来或甚至用手去折都不会损害其发送和接收功能。The product of the present invention is designed to be used like a subway ticket, and its sending and receiving functions will not be damaged when it is rolled up or even folded by hand.
附图1描述了一个智能卡,它包括一个带有12、14和16三个层的竖向叠片。Figure 1 depicts a smart card comprising a vertical lamination with three
底片12为第一个纸片,其厚度为例如75微米,用Arjo-Wiggins公司出售的“Maine”纸制成。The
纸底片12构成了卡10的底层保护片,同时,与底片12有相同构造和厚度的顶片16构成了卡10的顶层保护纸片。The
中间层14则用于相互粘接底片12和顶片16,在该第一实施例中,中间层为一敷有热融胶的薄片或薄膜,也可称之为热融层,其厚度为100微米,由Polyconcept公司提供。该热融层的优点有:室温下柔软且在叠合时不伤害芯片。
根据本发明的特征,当中间粘接层14象纸一样硬时,如果需要,它可以有一个竖向布置且和放在底片12内表面22上的微电子电路20或芯片垂直的凹口或窗口18。According to the characteristics of the present invention, when the intermediate
微电子电路20与接口天线24相连接,根据已知技术,接口天线例如可以借助一种银基导电墨水(例如由Dupont de Nemours公司提供的墨水E520)在上表面22上丝网印刷而成。The
微电子电路20可以是例如“芯片Mifare Amtel AT 8100”,其厚度减至例如70微米。它能通过例如粘贴而固定在表面22上。The
根据已知技术,优选地使用导电粒26-例如以“Ablestick SilverGlue”名字出售的胶-来实现微电子电路或电子模块20与接口天线24的电气连接。The electrical connection of the microelectronic circuit or
附图2所示的第二个实施例与刚说明的第一个实施例不同,第一个实施例只是说明了中间粘接层14的结构。The second embodiment shown in FIG. 2 differs from the first embodiment just described, which only illustrates the structure of the intermediate
这是因为,此处粘接层14包含一个中间纸层14A,其正反两个外表面都涂了一层热融胶14B,这样,构成中间粘接层14的复合层就可以和附图1中的粘接层14-只包含一层热融胶薄膜-一样插在底片12和顶片16之间。This is because, here
以下说明给出了制作附图1或附图2所示卡10的方法的例子。The following description gives an example of a method of making the
为得到一种大规模生产电子器件(如卡10)的工业方法,需同时和/或一个接一个地制作多个器件,特别是在制作12、14和16三个层时要使用连续的条或卷。In order to obtain an industrial method for the mass production of electronic devices such as the
首先要生产底层保护纸片12。Firstly, the bottom
为此目的,如附图3A所示,起始点为纸片12,微电子电路或模块20粘贴在纸片12的上表面22上,对每个电子器件都是如此。For this purpose, as shown in FIG. 3A , the starting point is the
下一步,如附图3B所示,优选地通过在上表面22上进行丝网印刷而制作天线24。另一选择是,可以在固定和连接模块前制作天线。Next, as shown in FIG. 3B ,
最后,如附图3C所示,通过沉积导电粒26,实现微电子电路20与天线24的电气连接或耦合。Finally, as shown in FIG. 3C , the electrical connection or coupling between the
这样,在附图3C所示的操作结束时,已经有了一条或一卷纸底片12,接下来,它必须与其它层14和16叠合在一起。Thus, at the end of the operation shown in Figure 3C, there is a strip or roll of paper negative 12 which must next be laminated with the
下一步骤的说明显示在附图4中,它以分解透视图的形式示意性描述了底片12、中间粘接层14和顶层保护纸片16的叠合情况,其中,底片12事先已准备好,在中间层14上的合适之处,窗口或切口18也已事先做好。An illustration of the next step is shown in accompanying drawing 4, which schematically depicts the lamination of the
因此,接下来是在下一步骤中(这一步图中未显示)制作叠层或夹层结构,它通过把三个叠加在一起的层12、14和16在例如加热层压操作中进行热压装配而成,也就是说,在导致热融胶融化的温度下,在叠层内构造中间层14(图1)或在中间粘接层14(图2)上构造胶层14B。It follows, therefore, that in a next step (not shown in this step) a laminate or sandwich structure is made by thermocompression assembling the three
该滚压操作(也称为层压)最后将三个层变成了一个叠层,也将电子器件的总厚度减少至小于或等于260微米。This rolling operation, also known as lamination, turns the three layers into one stack, also reducing the overall thickness of the electronic device to less than or equal to 260 microns.
在滚压操作中,和每个微电子电路20垂直的窗口18使微电子电路避免受到损害。
为确保窗口18与微电子电路20相匹配,当然需要有装置对层12和14的卷或条进行定位。To ensure that the
通过热滚压进行装配的步骤结束时,条或卷上的电子器件,不论其是卡、标签、票券或标牌,必须用已知的方法-例如按照冲孔技术-进行剪切。At the end of the assembly step by hot rolling, the electronic device on the strip or roll, whether it be a card, label, ticket or tag, must be cut using known methods, for example according to the punching technique.
在把电子器件剪裁下来之前或之后的任何一个步骤中,当然可以在底12下或顶16上的保护纸片外的任何一个或两个表面上进行印刷。It is of course possible to print on either or both surfaces outside the protective paper under the bottom 12 or on the top 16 at any step before or after cutting the electronic device.
因此,本发明使带有无接触电子存储器的电子器件的成本降低了,且厚度也变小了,它可能取代设有标识装置的其它产品,如带有磁条或条形码的可弯曲票券等,同时,这些新电子器件也是可生物降解的。Therefore, the present invention enables electronic devices with contactless electronic memory to be reduced in cost and thickness, and it may replace other products provided with identification means, such as flexible tickets with magnetic strips or barcodes, etc. , At the same time, these new electronic devices are also biodegradable.
本发明并不仅局限于以上所述的实施例和方法。The present invention is not limited to the embodiments and methods described above.
不同的操作使带有微电子电路20和天线24的底层保护纸片12可能采用其它已知的工艺制作,比如可以先做好天线,随后在微电子电路定位过程中使其导电接触管脚朝向上表面22,并直接放在天线24的导电部分上(倒装法),这样,就自动实现了微电子电路的连接。Different operations make it possible to make the bottom
使用微型金属丝连接或焊接技术(“线接”)也能实现微电子电路20和天线24的连接,但这种连接易碎而且比较厚。The connection of
无论中间粘接层14的结构如何,热融胶的存在可以避免依赖“封装”技术-该技术包括用树脂来保护微电子电路20及其连接。Regardless of the configuration of the
所用的热融胶其性质在冷接触时也可具有轻微的粘性,这样,在热滚压操作前,可以使带有三层的叠层预先装配在一起。The nature of the hot-melt glue used can also be slightly tacky when cold to the touch, so that a stack with three layers can be preassembled together prior to the hot rolling operation.
保护纸片(12、16)和层14也可以用聚合物制作,这种聚合物主要是通常用在智能卡领域中的聚合物(PVC、PE、PP)。The protective sheets (12, 16) and the
这些层也能用混有聚合物的纤维素制作,这样可以改进其某些性能(水密性、机械强度等)。These layers can also be made of cellulose mixed with polymers, which can improve certain properties (watertightness, mechanical strength, etc.).
本发明需要几个参数的结合。除了用小芯片(小于70微米)和薄的保护片外,还需要优选地使用中间热融或热密封层来装配整个器件。由于该层在冷却时具有柔软性,所以它具有以下优点:使硅芯片在滚压过程中可以直接与其接触而不会损害到芯片。从这一点考虑,中间层上的凹口并非是必需的。The present invention requires a combination of several parameters. In addition to chiplets (less than 70 microns) and thin protective sheets, the entire device needs to be assembled, preferably using an intermediate heat-melt or heat-sealing layer. Due to the softness of this layer when it cools, it has the advantage that the silicon chip can be brought into direct contact with it during the rolling process without damaging the chip. From this point of view, the notch on the intermediate layer is not necessary.
用平滑的板子进行热滚压可以改善保护片的初始表面状态。Hot rolling with a smooth board can improve the initial surface condition of the protective sheet.
也可以采用纸片,它比先前提到的聚合物板更经济。Paper sheets can also be used, which are more economical than the previously mentioned polymer sheets.
制作天线要优选地采用丝网印刷。这是因为很多在纸片上进行蚀刻(铝、铜等)的测试表明:化学变化导致纸起皱并使纸发黄。Fabrication of the antenna is preferably by screen printing. This is because many tests of etching on sheets of paper (aluminum, copper, etc.) have shown that the chemical changes cause the paper to wrinkle and yellow the paper.
另外,不可以在用丝网印刷制作天线前先印刷保护片(优点是:可以检验印刷质量,避免在安装芯片前出现废品)。在薄保护片,特别是纸片或聚合物板上使用丝网印刷技术时,如果不是特别小心,也可能引起另外一个问题。这个问题就是:墨水的变干会导致表面起皱。这个问题及其解决办法在专利申请FR 97/13734,3.10.97中作了说明。它们被当作参考包括在本发明的方法中,以制作有优越的表面质量(不起皱)的器件。In addition, it is not possible to print the protective sheet before making the antenna with screen printing (the advantage is that the printing quality can be checked to avoid waste products before installing the chip). Another problem can arise if the screen printing technique is not used on thin protective sheets, especially paper or polymer boards, if extreme care is not taken. Here's the problem: Drying of the ink can cause the surface to wrinkle. This problem and its solution are described in patent application FR 97/13734, 3.10.97. They are included as a reference in the method of the invention to produce devices with superior surface quality (wrinkle-free).
按照以上申请,丝网印刷的优点是:其制作的天线线条有精确的形状且导电质量好(银粒子)。根据上述申请中所述的方法,如果墨水涂在聚合物上且使其部分干燥,则用手多次对折器件,如五次,也不会损害天线。According to the above application, the advantage of screen printing is that it produces antenna lines with precise shape and good conductive quality (silver particles). According to the method described in the aforementioned application, if the ink is applied to the polymer and allowed to partially dry, the device can be folded in half by hand multiple times, say five times, without damaging the antenna.
另外,使用丝网印刷制作的混有银的天线,与使用蚀刻制作的天线比较,如果它通过下述连接成份与芯片连接,则连接成本更低,也更方便。In addition, compared with the antenna made by etching, the silver-mixed antenna made by screen printing is cheaper and more convenient if it is connected to the chip through the following connection components.
优选地,连接成份或是混有银的导电粒,此时芯片正面向上固定,或是导电胶点,此时芯片颠倒着固定(倒装法)。Preferably, the connection components are either conductive grains mixed with silver, at this time the chip is fixed with the front facing up, or conductive glue dots, at this time the chip is fixed upside down (flip-chip method).
与焊接金属线(线接)连接类型相比,这些连接更薄,且更抗机械应力。These connections are thinner and more resistant to mechanical stress than soldered metal wire (wire bond) connection types.
Claims (15)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR98/02727 | 1998-02-27 | ||
| FR9802727A FR2775533B1 (en) | 1998-02-27 | 1998-02-27 | CONTACTLESS ELECTRONIC MEMORY DEVICE, AND METHOD FOR MANUFACTURED BY SUCH A DEVICE |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1292129A true CN1292129A (en) | 2001-04-18 |
Family
ID=9523715
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99803383.9A Pending CN1292129A (en) | 1998-02-27 | 1999-02-10 | Electronic device with contactless electronic memory, and method for making same |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1057139A1 (en) |
| JP (1) | JP2002505488A (en) |
| CN (1) | CN1292129A (en) |
| AU (1) | AU2428699A (en) |
| BR (1) | BR9907751A (en) |
| CA (1) | CA2321893A1 (en) |
| FR (1) | FR2775533B1 (en) |
| WO (1) | WO1999044172A1 (en) |
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-
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- 1999-02-10 EP EP99903730A patent/EP1057139A1/en not_active Withdrawn
- 1999-02-10 CN CN99803383.9A patent/CN1292129A/en active Pending
- 1999-02-10 JP JP2000533853A patent/JP2002505488A/en active Pending
- 1999-02-10 BR BR9907751-5A patent/BR9907751A/en not_active IP Right Cessation
- 1999-02-10 WO PCT/FR1999/000291 patent/WO1999044172A1/en not_active Ceased
- 1999-02-10 CA CA002321893A patent/CA2321893A1/en not_active Abandoned
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1647104B (en) * | 2002-04-19 | 2010-05-12 | 艾利丹尼森公司 | Laser Imageable RFID Labels/Tags |
| CN100363950C (en) * | 2003-01-31 | 2008-01-23 | 瓦尔达微电池有限责任公司 | thin electronic chip card |
| CN1322468C (en) * | 2003-03-27 | 2007-06-20 | 株式会社电装 | IC card |
| CN1322467C (en) * | 2003-12-30 | 2007-06-20 | 上海东方磁卡工程有限公司 | Manufacturing method of non contact type intelligent low frequency card |
| CN111491790A (en) * | 2017-10-13 | 2020-08-04 | 斯道拉恩索公司 | Method and apparatus for producing labels with integrated conductive patterns |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2775533A1 (en) | 1999-09-03 |
| CA2321893A1 (en) | 1999-09-02 |
| FR2775533B1 (en) | 2003-02-14 |
| AU2428699A (en) | 1999-09-15 |
| JP2002505488A (en) | 2002-02-19 |
| BR9907751A (en) | 2000-10-17 |
| EP1057139A1 (en) | 2000-12-06 |
| WO1999044172A1 (en) | 1999-09-02 |
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